CN101469090B - Polymer modified membrane material and air-conditioner using the same - Google Patents
Polymer modified membrane material and air-conditioner using the same Download PDFInfo
- Publication number
- CN101469090B CN101469090B CN2007101255421A CN200710125542A CN101469090B CN 101469090 B CN101469090 B CN 101469090B CN 2007101255421 A CN2007101255421 A CN 2007101255421A CN 200710125542 A CN200710125542 A CN 200710125542A CN 101469090 B CN101469090 B CN 101469090B
- Authority
- CN
- China
- Prior art keywords
- modified membrane
- polymer modified
- conditioner
- membrane material
- mass ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000463 material Substances 0.000 title claims abstract description 35
- 239000012528 membrane Substances 0.000 title claims abstract description 28
- 229920000642 polymer Polymers 0.000 title claims description 22
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 33
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 claims abstract description 21
- 239000003365 glass fiber Substances 0.000 claims abstract description 12
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 24
- 239000002985 plastic film Substances 0.000 claims description 10
- 229920006255 plastic film Polymers 0.000 claims description 10
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 5
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 abstract description 8
- 239000004033 plastic Substances 0.000 abstract description 4
- 229920003023 plastic Polymers 0.000 abstract description 4
- 238000009434 installation Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000007769 metal material Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 12
- 239000011787 zinc oxide Substances 0.000 description 9
- 239000000428 dust Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 230000037303 wrinkles Effects 0.000 description 4
- 238000004378 air conditioning Methods 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 238000013517 stratification Methods 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 2
- 239000005341 toughened glass Substances 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 206010023126 Jaundice Diseases 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 208000007578 phototoxic dermatitis Diseases 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000003248 secreting effect Effects 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
Images
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The invention provides high molecular modified membrane material and an air conditioner using the material. The high molecular modified membrane material comprises the ETFE plastic membrane material which is added with glass fibers, anatase type nanometer TiO2 and rutile type nanometer TiO2, and nanometer ZnO. The high molecular modified membrane material which can be applied to the panel of an indoor unit of the air conditioner can bring about light texture and very high strength, high hardness, high pressure resistance, fire resistance, heat resistance, the resistance to various chemicals, and a long service life for the panel of the air conditioner. The high molecular modified membrane material has a self cleaning function without furrowing; in addition, the high molecular modified membrane material can be perfectly compounded with metal materials, thereby facilitating the production and installation.
Description
Technical field
The invention belongs to the conditioner field, relate in particular to the application of a kind of polymer modified membrane on conditioner.
Background technology
Conditioner is used widely, existing indoor machine of air-conditioner panel is a basic material with plastics and toughened glass generally, yet, the easy dust stratification of general plastic front board, do not have self-cleaning function, ABS plastic then is subjected to rayed jaundice variable color easily, influences outward appearance, and plastic component intensity is not high, and thermotolerance is relatively poor; And toughened glass weight is bigger, produces inconvenience is installed, and also have broken potentially dangerous.Therefore, provide a kind of quality light and handy, intensity higher and possess the air-conditioning panel material of self-cleaning function real belong to necessary.
Summary of the invention
First purpose of the present invention is to provide that a kind of quality is light and handy, intensity is higher and possess the self-cleaning function polymer modified membrane.
Second purpose of the present invention is to provide a kind of conditioner, solve existing conditioner the easy dust stratification of panel, problem such as inconvenience is installed.
For realizing above-mentioned first purpose, the invention provides a kind of polymer modified membrane, it comprises the ETFE plastic film material, and adds glass fibre, anatase type nano TiO in above-mentioned ETFE plastic film material
2With rutile type nano TiO
2, nano-ZnO.
The mass ratio of described glass fibre is 3-5%.
Described anatase type nano TiO
2, rutile type nano TiO
2With the total mass ratio of nano-ZnO be 2-4%.
Described anatase type nano TiO
2, rutile type nano TiO
2, the mass ratio between the ZnO is 4: 1: 1.
The ethene in the described ETFE plastic film material and the mass ratio of tetrafluoroethylene are 1: 1.
Polymer modified membrane provided by the present invention makes that texture material is light and handy, intensity is higher, and possesses self-cleaning function by the ETFE plastic film is carried out modification.
For realizing second purpose of the present invention, the invention provides a kind of conditioner, it adopts above-mentioned polymer modified membrane as panel.
Conditioner provided by the present invention has adopted above-mentioned polymer modified membrane as panel, and quality is light and handy, intensity is higher and possess self-cleaning function because the macromolecule member material after the modification has, and therefore makes conditioner be difficult for dust stratification and convenient production and installation.
Description of drawings
Fig. 1 is the polymer modified membrane of the present invention that is embedded in the conditioner metal construction framework.
Embodiment
In order to make purpose of the present invention, technical scheme and advantage clearer,, the present invention is further elaborated below in conjunction with drawings and Examples.Should be appreciated that specific embodiment described herein only in order to explanation the present invention, and be not used in qualification the present invention.
The main raw of the polymer modified membrane that the embodiment of the invention provided is ETFE (/ ethylene-tetrafluoroethylene copolymer) plastic film material, and the interpolation mass ratio is glass fibre and the anatase type nano TiO of 3-5% in this ETFE plastic film material
2, rutile type nano TiO
2(titanium dioxide) and nano-ZnO (zinc oxide), wherein the mass ratio of glass fibre is 3-5%, anatase type nano TiO
2, rutile type nano TiO
2The total mass ratio 2-4% of (titanium dioxide) and nano-ZnO.As preferred embodiment, Detitanium-ore-type TiO
2, rutile TiO
2, the mass ratio between the ZnO is 4: 1: 1, the ethene among the ETFE and the mass ratio of tetrafluoroethylene are 1: 1.
Conditioner provided by the present invention promptly is to adopt above-mentioned polymer modified membrane on the indoor unit panel of air-conditioning, it is mould material about 0.2mm that above-mentioned materials is made thickness, adopt duplicature material and conditioner structured material (sheet metal component or aluminium alloy) commonly used to be bonded together, as the panel of indoor machine of air-conditioner.The surface can reduce the transmittance of this material by the pattern of brushing shades of colour and decorative pattern, and the member of air-conditioning inside is not seen by the outside.Below set forth the principle and the effect of use on conditioner of polymer modified membrane of the present invention.
The shortcoming of ETFE multipolymer is: when the film of ETFE material is connected with the metal construction framework, the junction grows mould easily in a large number under the influence of temperature and humidity, produce many stains, and the secretory product that mould-growth is discharged also can influence its structural performance and functional performance to this macromolecular material generation of ETFE corrosive effect.Therefore, in the above embodiment of the present invention, add nano-TiO
2With the effect of nano-ZnO is that the antibacterial effect of ETFE is increased, and avoids the generation of the problems referred to above; Simultaneously, add nano-TiO
2The self-cleaning performance of ETFE material is strengthened greatly, and anti-contamination and wash-resistant property strengthen, nano-TiO
2Ultraviolet ray can be effectively absorbed again, the fire performance of ETFE can also be strengthened.
On the other hand, because the ETFE material has certain elasticity and thermoplasticity, when solar radiation makes that local temperature raises, the inequality of being heated can cause the lax distortion of material, because film is attached on the metal construction, all can not make it reach tight state on physical property, chemical property and actual needs, adds unbalance stress, be easy to produce wrinkle, the then the easiest dust that adheres in fold place.Therefore, can obviously improve the hardness of film in the polymer modified membrane of the present invention behind a certain proportion of glass fibre of interpolation, the employing of glass fibre has also reduced the appearance of wrinkle greatly, difference when unbalance stress or temperature, the deformation of film is owing to the effect of pullling of fiber can not show clearly yet, the wrinkle nature obtained inhibition, and glass fibre inherent optical lens photosensitiveness can not influence the transparency of new film.
Because polymer modified membrane quality provided by the present invention very light (being approximately one of percentage of same volume glass weight), but its intensity is very big, and stronger stretchiness can be arranged, and still keeps elasticity (not can tension set) after 3 times stretching.
Shown in Fig. 1, according to the foregoing description, after being installed in polymer modified membrane of the present invention on the air conditioner indoor unit panel framework, can make that the panel quality of conditioner is light and handy and intensity is high, the hardness height, can corrode by withstand voltage, fire-resistant, heat-resisting, anti-various pharmaceutical chemicalss, long service life has self-cleaning function, wrinkle resistant line, and can be compound with the metallic substance ideal, convenient production and installation.
The above only is preferred embodiment of the present invention, in order to restriction the present invention, does not for example add above-mentioned glass fibre, anatase type nano TiO
2With rutile type nano TiO
2, nano-ZnO ratio can be according to the practical situation adjustment, the ethene among the ETFE and the ratio of tetrafluoroethylene also can be done suitable adjustment.All any modifications of being done within the spirit and principles in the present invention, be equal to and replace and improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. polymer modified membrane, it comprises the ETFE plastic film material, it is characterized in that: add glass fibre, anatase type nano TiO in above-mentioned ETFE plastic film material
2With rutile type nano TiO
2, nano-ZnO.
2. polymer modified membrane according to claim 1 is characterized in that, the mass ratio of described glass fibre is 3-5%.
3. polymer modified membrane according to claim 2 is characterized in that, described anatase type nano TiO
2, rutile type nano TiO
2With the total mass ratio of nano-ZnO be 2-4%.
4. polymer modified membrane according to claim 3 is characterized in that, described anatase type nano TiO
2, rutile type nano TiO
2, the mass ratio between the ZnO is 4: 1: 1.
5. polymer modified membrane according to claim 1 is characterized in that, the ethene in the described ETFE plastic film material and the mass ratio of tetrafluoroethylene are 1: 1.
6. a conditioner comprises indoor unit panel, it is characterized in that, described indoor unit panel adopts the polymer modified membrane described in the claim 1.
7. according to the conditioner described in the claim 6, it is characterized in that, described polymer modified membrane is made the mould material that thickness is 0.2mm, and adopt the structured material of double-deck this kind mould material and conditioner bonding.
8. conditioner according to claim 6 is characterized in that, the mass ratio of described glass fibre is 3-5%.
9. conditioner according to claim 8 is characterized in that, described anatase type nano TiO
2, rutile type nano TiO
2With the total mass ratio of nano-ZnO be 2-4%, and anatase type nano TiO
2, rutile type nano TiO
2, the mass ratio between the ZnO is 4: 1: 1.
10. conditioner according to claim 6 is characterized in that, the ethene in the described ETFE plastic film material and the mass ratio of tetrafluoroethylene are 1: 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007101255421A CN101469090B (en) | 2007-12-27 | 2007-12-27 | Polymer modified membrane material and air-conditioner using the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007101255421A CN101469090B (en) | 2007-12-27 | 2007-12-27 | Polymer modified membrane material and air-conditioner using the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101469090A CN101469090A (en) | 2009-07-01 |
| CN101469090B true CN101469090B (en) | 2011-06-08 |
Family
ID=40826905
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007101255421A Expired - Fee Related CN101469090B (en) | 2007-12-27 | 2007-12-27 | Polymer modified membrane material and air-conditioner using the same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101469090B (en) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA3046529C (en) | 2010-06-24 | 2023-01-31 | University Of Saskatchewan | Liquid-to-air membrane energy exchanger |
| US8915092B2 (en) | 2011-01-19 | 2014-12-23 | Venmar Ces, Inc. | Heat pump system having a pre-processing module |
| US9810439B2 (en) | 2011-09-02 | 2017-11-07 | Nortek Air Solutions Canada, Inc. | Energy exchange system for conditioning air in an enclosed structure |
| CN102604280B (en) * | 2012-03-14 | 2013-11-13 | 北京化工大学 | Mixed crystal form inorganic nanometer filler/polymer-based composite dielectric film |
| US9816760B2 (en) * | 2012-08-24 | 2017-11-14 | Nortek Air Solutions Canada, Inc. | Liquid panel assembly |
| US9109808B2 (en) | 2013-03-13 | 2015-08-18 | Venmar Ces, Inc. | Variable desiccant control energy exchange system and method |
| US9772124B2 (en) | 2013-03-13 | 2017-09-26 | Nortek Air Solutions Canada, Inc. | Heat pump defrosting system and method |
| US10352628B2 (en) | 2013-03-14 | 2019-07-16 | Nortek Air Solutions Canada, Inc. | Membrane-integrated energy exchange assembly |
| US11408681B2 (en) | 2013-03-15 | 2022-08-09 | Nortek Air Solations Canada, Iac. | Evaporative cooling system with liquid-to-air membrane energy exchanger |
| US10584884B2 (en) | 2013-03-15 | 2020-03-10 | Nortek Air Solutions Canada, Inc. | Control system and method for a liquid desiccant air delivery system |
| CN107249715B (en) | 2014-08-19 | 2020-11-06 | 北狄空气应对加拿大公司 | Liquid-Gas Membrane Energy Exchanger |
| EP3295088B1 (en) | 2015-05-15 | 2022-01-12 | Nortek Air Solutions Canada, Inc. | Using liquid to air membrane energy exchanger for liquid cooling |
| US11092349B2 (en) | 2015-05-15 | 2021-08-17 | Nortek Air Solutions Canada, Inc. | Systems and methods for providing cooling to a heat load |
| CN108027221B (en) | 2015-06-26 | 2021-03-09 | 北狄空气应对加拿大公司 | Three-fluid liquid-gas film energy exchanger |
| EP4510795A3 (en) | 2016-03-08 | 2025-04-16 | Nortek Air Solutions Canada, Inc. | Systems and methods for providing cooling to a heat load |
| EP4194763A1 (en) | 2017-04-18 | 2023-06-14 | Nortek Air Solutions Canada, Inc. | Systems and methods for managing conditions in enclosed space |
| US11892193B2 (en) | 2017-04-18 | 2024-02-06 | Nortek Air Solutions Canada, Inc. | Desiccant enhanced evaporative cooling systems and methods |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1203610A (en) * | 1995-12-01 | 1998-12-30 | W·L·戈尔有限公司 | Microporous polytetrafluoroethylene products containing fillers |
-
2007
- 2007-12-27 CN CN2007101255421A patent/CN101469090B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1203610A (en) * | 1995-12-01 | 1998-12-30 | W·L·戈尔有限公司 | Microporous polytetrafluoroethylene products containing fillers |
Non-Patent Citations (2)
| Title |
|---|
| JP特开2005-144896A 2005.06.09 |
| 胥传喜等.ETFE薄膜的材料性能及其工程应用综述.《钢结构》.2003,第18卷(第68期),第1-4页. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101469090A (en) | 2009-07-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101469090B (en) | Polymer modified membrane material and air-conditioner using the same | |
| CN100462395C (en) | A kind of transparent heat insulation film and preparation method thereof | |
| CN101255237B (en) | High-water-repellency and high-slidability coating member, fabrication method for same, and high-water-repellency and high-slidability product using same | |
| JP2005047179A (en) | Heat ray shielding resin sheet | |
| JP3994191B2 (en) | Thermal barrier antifouling film material | |
| JP5559486B2 (en) | Heat ray shielding glass and multilayer glass using the same | |
| CN100569508C (en) | Colored sheet with light shading effect | |
| CN202986256U (en) | Novel heat insulation window film | |
| JP4341752B2 (en) | Thermal barrier antifouling film material | |
| CN201187226Y (en) | Nanometer antibiotic decontamination LOW-E hollow glass | |
| WO2022068017A1 (en) | Photovoltaic module back sheet and photovoltaic module having same | |
| JP2001064582A (en) | Photocatalytic hydrophilic coating composition and preparation of photocatalytic hydrophilic composite by using the same | |
| JP5124135B2 (en) | Film or sheet and method for producing the same, exterior material, glass, and exterior construction method | |
| JP2014216492A (en) | Solar cell module | |
| CN201187225Y (en) | Nanometer antibiotic decontamination film coating glass | |
| CN215882810U (en) | High temperature resistant ageing resistance thermoplasticity combined material board | |
| CN102503172A (en) | Low-radiation temperable double-silver LOW-E glass | |
| TW202103952A (en) | Fluorine-containing sheet and laminated steel plate comprising same | |
| CN214694856U (en) | Antibacterial tent fabric | |
| CN109808260A (en) | A kind of colour doubling glass | |
| CN115895490A (en) | TPU color-changing film and preparation method thereof | |
| CN108410281A (en) | A kind of water nano compound heat-insulation coating and preparation method thereof | |
| CN210553437U (en) | Fingerprint-free color-changing steel plate | |
| KR102827808B1 (en) | Building-integrated multi-layer color laminated glass manufacturing method with thermal barrier properties | |
| CN204022678U (en) | A kind of low radiation coated glass |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110608 Termination date: 20181227 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |