CN101430369B - Self-generating broadband laminated magneto-inducible piezoelectric effect AC magnetic field sensor and manufacturing method - Google Patents
Self-generating broadband laminated magneto-inducible piezoelectric effect AC magnetic field sensor and manufacturing method Download PDFInfo
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Abstract
Description
技术领域technical field
本发明涉及一种新型交流磁场传感器,具体是一种发电型宽频层叠磁致压电效应交流磁场传感器。The invention relates to a novel AC magnetic field sensor, in particular to a power generation type broadband laminated magneto-induced piezoelectric effect AC magnetic field sensor.
背景技术Background technique
随着信息技术的发展,对传感器的要求越来越高,在汽车电子、航空航天、交通运输、自动控制、机器人技术等领域对新型、微型、无源、高灵敏度、线性、宽带、快响应、小质量、低成本传感器需求越来越强烈。With the development of information technology, the requirements for sensors are getting higher and higher. In the fields of automotive electronics, aerospace, transportation, automatic control, robotics and other fields, new, miniature, passive, high-sensitivity, linear, broadband, fast response , small mass, and low-cost sensors demand more and more intense.
在电磁兼容、电力工程、电机工程等领域需监测与磁信号有关的物理量,如空间杂散交变磁场、电机产生的磁场、电流产生的磁场等。目前市场上对动态磁场测量的传感器主要有:霍耳(Hall)效应传感器、各向异性磁阻(AMR)传感器、巨磁阻(GMR)效应传感器、巨磁阻抗(GMI)效应传感器,这些传感器可对交变磁场进行测量,但这些传感器都需有电源供电才可工作,Hall传感器温度稳定性较差,且Hall传感器及AMR传感器灵敏度都较小。无需供电且可测磁的传感器主要有根据法拉第电磁感应原理的电磁线圈,但这种线圈输出信号随被测信号频率改变,在小尺寸低频下,输出信号很微弱。In fields such as electromagnetic compatibility, power engineering, and electrical engineering, it is necessary to monitor physical quantities related to magnetic signals, such as space stray alternating magnetic fields, magnetic fields generated by motors, and magnetic fields generated by currents. The sensors currently on the market for dynamic magnetic field measurement mainly include: Hall effect sensors, anisotropic magnetoresistance (AMR) sensors, giant magnetoresistance (GMR) effect sensors, giant magnetoresistance (GMI) effect sensors, these sensors The alternating magnetic field can be measured, but these sensors need power supply to work, the temperature stability of the Hall sensor is poor, and the sensitivity of the Hall sensor and the AMR sensor is small. The sensors that do not need power supply and can measure magnetism mainly include electromagnetic coils based on Faraday’s electromagnetic induction principle, but the output signal of this coil changes with the frequency of the measured signal, and the output signal is very weak at small sizes and low frequencies.
本发明所制作的传感器具有无需电源供电即可工作,且具有高灵敏度、线性、宽带、快响应、小质量的特点,可广泛应用于交通运输、机械加工工业、航空航天、地球环境、电力工程、自动控制等行业,具有广阔的应用前景。The sensor produced by the present invention can work without power supply, and has the characteristics of high sensitivity, linearity, broadband, fast response and small quality, and can be widely used in transportation, mechanical processing industry, aerospace, earth environment, electric power engineering , automatic control and other industries, has broad application prospects.
文献检索发现较早提出关于此类层叠复合材料压磁效应概念的研究论文发表在2002年的Applied Physics letters,Vol.81,P100-101,由美国马里兰大学的Kiyotaka Mori andManfred Wuttig提出“Magnetoelectric coupling in Terfenol—D/polyvinylidenedifluoridecomposites”。此后在美国费吉尼亚的Dong Shuxiang等人于2003年在美国的AppliedPhysics letters,Vol.83,p4812-4814发表了关于片状磁致伸缩材料/压电材料/片状磁致伸缩材料结构器件磁电效应的研究论文,其实验中的偏置磁场由大型电磁铁产生,他们的研究注重于对该效应进行实验探讨及对该效应的理论进行较为深入的研究,未构成本发明所提出的传感器。国内重庆大学的文玉梅在《传感技术学报》上对Terfenol-D和PZT超声变幅杆结构的电磁换能器进行过研究(传感技术学报,Vol.20,No.8,2007,P1742-1746),他们还对“GMM/弹性板/PZT层状复合结构的纵振磁电响应”进行过研究(物理学报,Vol.57,No.7,2008,P4545-4551),但她们提出的器件结构与本发明提出的传感器结构有很大区别。Literature search found that the research paper on the concept of piezomagnetic effect of such laminated composite materials was published in Applied Physics letters in 2002, Vol. Terfenol-D/polyvinylidenedifluoridecomposites". Afterwards, Dong Shuxiang et al. in Virginia, USA published in AppliedPhysics letters, Vol.83, p4812-4814 in the United States in 2003 about the structural devices of sheet magnetostrictive materials/piezoelectric materials/sheet magnetostrictive materials. The research paper on magnetoelectric effect, the bias magnetic field in its experiment is produced by large-scale electromagnet, their research focuses on carrying out experiment discussion to this effect and the theory of this effect is carried out comparatively in-depth research, does not constitute the present invention's proposed sensor. Wen Yumei from Chongqing University in China has studied the electromagnetic transducers with Terfenol-D and PZT ultrasonic horn structures in the Journal of Sensing Technology (Journal of Sensing Technology, Vol.20, No.8, 2007, P1742-1746), they have also conducted research on "The longitudinal vibration magnetoelectric response of GMM/elastic plate/PZT layered composite structure" (Acta Physica Acta, Vol.57, No.7, 2008, P4545-4551), but they The proposed device structure is quite different from the proposed sensor structure of the present invention.
发明内容Contents of the invention
本发明的目的在于使以上的实验室中的原理性研究成果变成一种在实际中可实现的传感器,提供了一种发电型宽频层叠磁致压电效应微型磁场传感器的制作具体方法,特别是在本发明中采用巨磁致伸缩系数的细棒而不用薄板,另一主要特别之处在于本发明将一小块永磁与以上层叠结构合为一体,从而构成具有真正意义上的传感器,且能保持宽的频带范围。The purpose of the present invention is to make the above theoretical research results in the laboratory into a sensor that can be realized in practice, and provides a specific method for making a power-generating broadband laminated magneto-piezoelectric effect miniature magnetic field sensor, especially In the present invention, a thin rod with a giant magnetostriction coefficient is used instead of a thin plate. Another main special feature is that the present invention combines a small piece of permanent magnet with the above laminated structure to form a real sensor. And can maintain a wide frequency band range.
本发明的原理是,巨磁致伸缩材料在偏置磁场的作用下有较大的磁致伸缩系数,交变磁场将引起磁致伸缩材料伸缩,伸缩所产生的应力传递给压电材料,压电材料内形成交变电场,该电场对应一电压信号,这就对该传感器给出了定性的原理解释,其定量解释较为复杂。但理论结果表明,磁电效应与巨磁致伸缩材料与层叠结构的体积比、压电材料的压电系数、机电耦合系数等参数有关。The principle of the present invention is that the giant magnetostrictive material has a large magnetostrictive coefficient under the action of the bias magnetic field, and the alternating magnetic field will cause the magnetostrictive material to expand and contract, and the stress generated by the expansion and contraction is transmitted to the piezoelectric material, and the piezoelectric material is compressed. An alternating electric field is formed in the electric material, and the electric field corresponds to a voltage signal, which gives a qualitative principle explanation of the sensor, and its quantitative explanation is more complicated. However, theoretical results show that the magnetoelectric effect is related to parameters such as the volume ratio of the giant magnetostrictive material to the stacked structure, the piezoelectric coefficient of the piezoelectric material, and the electromechanical coupling coefficient.
本发明是通过以下技术方案实现的:The present invention is achieved through the following technical solutions:
一种自发电宽频层叠磁致压电效应交流磁场传感器,为磁致伸缩棒/压电材料/磁致伸缩棒/永磁材料的层叠结构;所说的压电材料的上下表面有银薄膜电极,磁致伸缩棒上设置有信号输出引线。A self-generating broadband laminated magnetostrictive piezoelectric effect AC magnetic field sensor, which is a laminated structure of magnetostrictive rod/piezoelectric material/magnetostrictive rod/permanent magnetic material; the upper and lower surfaces of the piezoelectric material have silver film electrodes , signal output leads are arranged on the magnetostrictive rod.
上述所说的传感器,其中磁致伸缩棒为矩形截面,长宽比≥5。The above-mentioned sensor, wherein the magnetostrictive rod has a rectangular cross-section and an aspect ratio ≥ 5.
上述所说的传感器,其中压电材料具有和磁致伸缩棒相同的长度和宽度。The above-mentioned sensor, wherein the piezoelectric material has the same length and width as the magnetostrictive rod.
上述所说的传感器,其中永磁材料的长或宽、或者长和宽都小于磁致伸缩棒,永磁材料相对于磁致伸缩棒的中心呈非对称设置。In the aforementioned sensor, the permanent magnet material is smaller in length or width, or both in length and width than the magnetostrictive rod, and the permanent magnet material is arranged asymmetrically with respect to the center of the magnetostrictive rod.
上述所说的传感器,其中磁致伸缩棒是具有磁致伸缩特性的Td-Dy-Fe(Terfenol-D)棒。In the aforementioned sensor, the magnetostrictive rod is a Td-Dy-Fe (Terfenol-D) rod with magnetostrictive properties.
上述所说的传感器,其中的压电材料是PZT材料,也可以是PMN-PT材料,或其他具有高的压电系数的压电材料;压电材料可以沿厚度方向极化也可沿纵向(长度方向)极化;压电材料的上下表面的银薄膜电极,沿厚度方向极化。Above-mentioned said sensor, wherein piezoelectric material is PZT material, also can be PMN-PT material, or other piezoelectric material with high piezoelectric coefficient; length direction) polarization; the silver film electrodes on the upper and lower surfaces of the piezoelectric material are polarized along the thickness direction.
上述所说的传感器,其中的永磁材料是Nd-Fe-B永磁,磁化沿厚度方向。In the aforementioned sensor, the permanent magnet material is Nd-Fe-B permanent magnet, and the magnetization is along the thickness direction.
采用具有巨磁致伸缩系数的细棒,一方面可减小传感器体积,另一方面由于采用了细棒结构,使退磁场大大减小,故巨磁致伸缩棒可在较小的偏置磁场下产生较大的磁致伸缩,因此可实现用一小磁铁提供的偏置磁场即可使传感器工作,且能保持大的磁场灵敏度;采用永磁材料与层叠结构合为一体,可使传感器灵敏度提高,是由于单个磁铁在两棒中产生的偏置磁场有一差值,形成类似悬臂梁的结构,增大了输出电压的灵敏度。The use of thin rods with giant magnetostrictive coefficients can reduce the volume of the sensor on the one hand, and on the other hand, due to the use of thin rod structures, the demagnetization field is greatly reduced, so the giant magnetostrictive rods can be used in a small bias magnetic field Therefore, the bias magnetic field provided by a small magnet can be used to make the sensor work, and can maintain a large magnetic field sensitivity; the combination of permanent magnetic material and laminated structure can make the sensor sensitive The improvement is due to a difference in the bias magnetic field generated by a single magnet in the two rods, forming a structure similar to a cantilever beam, which increases the sensitivity of the output voltage.
本发明具体制作方法的步骤如下:The steps of concrete preparation method of the present invention are as follows:
(1)制作两个相同的磁致伸缩棒;(1) make two identical magnetostrictive rods;
(2)制作与磁致伸缩棒具有同样长度和宽度的压电材料,该压电材料沿厚度方向极化或可长度方向极化,在压电材料的上下表面镀银,形成银薄膜电极,沿厚度方向极化;(2) Make a piezoelectric material with the same length and width as the magnetostrictive rod, which is polarized along the thickness direction or can be polarized in the longitudinal direction, and silver-plated on the upper and lower surfaces of the piezoelectric material to form a silver film electrode, Polarized along the thickness direction;
(3)用银导电胶将磁致伸缩细棒与压电材料粘接,在一定温度下施压处理;(3) bonding the magnetostrictive thin rod and the piezoelectric material with silver conductive glue, and applying pressure at a certain temperature;
(4)在磁致伸缩材料上引出信号输出引线,包括在压电材料镀导电层上制作电信号引线;(4) Leading out signal output leads on the magnetostrictive material, including making electrical signal leads on the piezoelectric material plating conductive layer;
(5)在以上磁致伸缩棒的一面上粘贴一永磁,磁化沿厚度方向。(5) Paste a permanent magnet on one side of the above magnetostrictive rod, and the magnetization is along the thickness direction.
更具体的操作是:More specific operations are:
1、对巨磁致伸缩圆柱形材料进行切割加工,制作出长为10-15mm,截面为1×1mm2的具有巨磁致伸缩特性的Td-Dy-Fe(Terfenol-D)具有矩形截面的细棒,这样得到的材料具有大的长宽比及长厚比;1. Cut and process the giant magnetostrictive cylindrical material to produce a Td-Dy-Fe (Terfenol-D) with a rectangular cross-section with a length of 10-15mm and a cross-section of 1×1mm 2 with giant magnetostriction properties. Thin rods, the resulting material has a large aspect ratio and aspect ratio;
2、制作出由PZT或其它具有高的压电系数的压电材料,压电材料可以是PZT材料,也可以是PMN-PT材料,材料可以沿厚度方向极化也可沿纵向(长度方向)极化,它与上述巨磁致伸缩材料具有同样长度和宽度,压电材料的上下表面镀银,形成银薄膜电极,对压电材料沿厚度方向加电场进行极化;2. Make PZT or other piezoelectric materials with high piezoelectric coefficient. The piezoelectric material can be PZT material or PMN-PT material. The material can be polarized along the thickness direction or along the longitudinal direction (length direction) Polarization, which has the same length and width as the above-mentioned giant magnetostrictive material, the upper and lower surfaces of the piezoelectric material are plated with silver to form silver film electrodes, and the piezoelectric material is polarized by adding an electric field along the thickness direction;
3、用银导电胶将巨磁致伸缩细棒与压电材料粘接,在80℃温度下施压处理;3. Bond the giant magnetostrictive thin rod with the piezoelectric material with silver conductive glue, and apply pressure at a temperature of 80°C;
4、在巨磁致伸缩材料上各引出一根信号输出引线;4. Lead out a signal output lead wire on the giant magnetostrictive material;
5、在以上巨磁致伸缩材料的一面上粘贴一5×1×0.5mm3,质量约0.15g的Nd-Fe-B永磁,该磁铁沿厚度方向磁化;5. Paste a 5×1×0.5mm 3 Nd-Fe-B permanent magnet with a mass of about 0.15g on one side of the above giant magnetostrictive material, and the magnet is magnetized along the thickness direction;
6、对以上层叠结构进行封装,即制成一实用的传感器。6. Encapsulate the above laminated structure to make a practical sensor.
本发明具有以下优点:The present invention has the following advantages:
本发明采用Terfenol-D细棒,而非Terfenol-D片状材料。由于细棒的退磁因子小,易于磁化,因此可实现采用微小磁铁构成整个传感器;The present invention utilizes Terfenol-D thin rods rather than Terfenol-D flakes. Because the demagnetization factor of the thin rod is small and easy to magnetize, it is possible to use tiny magnets to form the entire sensor;
(1)本发明微型永磁与Terfenol-D棒/压电材料/Terfenol-D棒合为一体,使磁场传感器成为一整体;(1) The miniature permanent magnet of the present invention is integrated with the Terfenol-D rod/piezoelectric material/Terfenol-D rod, so that the magnetic field sensor becomes a whole;
(2)本发明采用Terfenol-D棒,使传感器体积大大减小,但却能保持高的灵敏度;(2) The present invention adopts Terfenol-D rod, makes sensor volume reduce greatly, but can keep high sensitivity;
(3)本发明制作的传感器体积小,其共振频率高,使其具有高的频带宽度;(3) the sensor volume that the present invention makes is little, and its resonant frequency is high, makes it have high frequency bandwidth;
(4)本发明磁铁的非对称结构设计可明显增强传感器的灵敏度;(4) The asymmetric structure design of the magnet of the present invention can obviously enhance the sensitivity of the sensor;
(5)本发明由于采用细棒后可使永磁材料质量减小,使共振频率增大。(5) The present invention can reduce the mass of the permanent magnet material and increase the resonant frequency due to the use of thin rods.
附图说明Description of drawings
图1是发电型宽频层叠磁致压电效应交流磁场传感器实例的结构示意图。图中1为NdFeB永磁材料,2和8为电信号输出线,3为上层Terfenol-D巨磁致伸缩材料,4为压电PZT材料上表面镀银层,5为PZT压电材料,6为PZT材料下表面镀银层,7为下层Terfenol-D巨磁致伸缩材料。Fig. 1 is a structural schematic diagram of an example of a generator-type broadband laminated magneto-piezoelectric effect AC magnetic field sensor. In the figure, 1 is the NdFeB permanent magnet material, 2 and 8 are electrical signal output lines, 3 is the upper layer Terfenol-D giant magnetostrictive material, 4 is the silver-plated layer on the upper surface of the piezoelectric PZT material, 5 is the PZT piezoelectric material, 6 7 is the lower layer of Terfenol-D giant magnetostrictive material.
具体实施方式Detailed ways
以下结合附图作进一部的描述:Make further description below in conjunction with accompanying drawing:
实施例1:Example 1:
图1所示的传感器的制备如下:The sensor shown in Figure 1 was prepared as follows:
(1)将大尺寸的Terfenol-D圆柱形棒材切割,获得长10mm,宽1mm,高1mm的Terfenol-D细棒3和细棒7,细棒3和细棒7相对两面经抛光处理;(1) Cut the large-sized Terfenol-D cylindrical rod to obtain Terfenol-D thin rod 3 and thin rod 7 with a length of 10 mm, a width of 1 mm, and a height of 1 mm. The opposite sides of the thin rod 3 and thin rod 7 are polished. ;
(2)制作与(1)描述的Terfenol-D细棒3同宽,而厚为0.8mm的PZT-5H材料5,在压电材料5的上下表面分别镀银层4和6,用CLD-5导电胶在80℃下烘30分钟升温至120℃保持3小时,再冷却至室温,将PZT-5H材料5粘贴于Terfenol-D材料3和7之间,形成Terfenol-D/压电材料/Terfenol-D层叠结构,该PZT材料沿厚度方向用强电场进行极化,在Terfenol-D的细棒上经信号输出线2、8输出电压信号;(2) Make the same width as the Terfenol-D thin rod 3 described in (1), and the PZT-5H material 5 with a thickness of 0.8mm, silver-plated layers 4 and 6 respectively on the upper and lower surfaces of the piezoelectric material 5, use CLD- 5 Bake the conductive adhesive at 80°C for 30 minutes and raise the temperature to 120°C for 3 hours, then cool to room temperature, paste PZT-5H material 5 between Terfenol-D materials 3 and 7 to form Terfenol-D/piezoelectric material/ Terfenol-D laminated structure, the PZT material is polarized with a strong electric field along the thickness direction, and the voltage signal is output through the signal output lines 2 and 8 on the thin rod of Terfenol-D;
(3)将宽为1mm,厚为0.5mm,长为5mm,质量为0.15g的NdFeB永磁1用胶粘剂粘于Terfenol-D棒3上,该磁体沿厚度方向磁化,其表面磁场为320Oe;(3) Be 1mm wide, be 0.5mm thick, be 5mm long, the NdFeB permanent magnet 1 that quality is 0.15g sticks on the Terfenol-D rod 3 with adhesive agent, this magnet is magnetized along the thickness direction, and its surface magnetic field is 320Oe;
实施例2:Example 2:
用Agilent33220A型信号发生器产生正弦信号,给亥姆赫兹圈提供励磁电流,从而在亥姆赫兹轴线中心附近产生模拟的被测交变磁场,将实施例1制作的传感器放入该磁场中,则传感器会输出与输入交变磁场成正比的输出电压信号或电荷信号,对横向极化的PZT材料,压电电压系数达到35mV/Oe;Use an Agilent33220A signal generator to generate a sinusoidal signal, and provide an excitation current to the Helmertz circle, thereby generating a simulated measured alternating magnetic field near the center of the Helmertz axis. Put the sensor made in Example 1 into this magnetic field, then The sensor will output an output voltage signal or charge signal that is proportional to the input alternating magnetic field. For laterally polarized PZT materials, the piezoelectric voltage coefficient reaches 35mV/Oe;
在0.5~70KHz的频率范围内,传感器输出电压在恒定输入磁场下保持不变。频率增至80KHz为共振频率点,此时输出电压有一峰值出现,此时dV/dH很高,共振时磁灵敏度可达1.5V/Oe。In the frequency range of 0.5 ~ 70KHz, the sensor output voltage remains unchanged under a constant input magnetic field. When the frequency increases to 80KHz, it is the resonance frequency point. At this time, the output voltage has a peak value. At this time, the dV/dH is very high, and the magnetic sensitivity can reach 1.5V/Oe during resonance.
交变信号频率在0~500Hz,在输入幅值恒定下,输出随频率增大而增大。The frequency of the alternating signal is between 0 and 500 Hz. When the input amplitude is constant, the output increases as the frequency increases.
该传感器不仅可检测交变磁场,还可检测与交变磁场相关的其它物理量,也可设计成对其它物理量的检测。The sensor can not only detect the alternating magnetic field, but also detect other physical quantities related to the alternating magnetic field, and can also be designed to detect other physical quantities.
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