CN101403060B - High damnification resistant aluminum alloy - Google Patents
High damnification resistant aluminum alloy Download PDFInfo
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- CN101403060B CN101403060B CN2008101435768A CN200810143576A CN101403060B CN 101403060 B CN101403060 B CN 101403060B CN 2008101435768 A CN2008101435768 A CN 2008101435768A CN 200810143576 A CN200810143576 A CN 200810143576A CN 101403060 B CN101403060 B CN 101403060B
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Abstract
Description
技术领域technical field
本发明涉及冶金领域的有色金属合金技术,具体的说属于经过微合金化的一种先进铝合金材料。The invention relates to the non-ferrous metal alloy technology in the field of metallurgy, and specifically belongs to an advanced aluminum alloy material through microalloying.
背景技术Background technique
铝合金具有密度小、强度高、耐腐蚀、易加工、资源丰富等一系列优点,在航空、交通运输、电力电子、建筑包装等行业得到极其广泛的应用。它不仅是一类量大、面广的基础材料,而且在国防建设中占有十分重要的地位,发挥着不可替代的作用。如何不断开发新品种,进一步提高铝材料性能已成为当今国际铝业界共同关心的问题。目前铝合金的研究开发目标已由过去的单纯追求高强度转变为材料综合性能的整体提升,即在提高铝合金强塑性的同时进一步提高合金的耐久性和损伤容限。铝合金正朝向高比强、高比模、高损伤容限和耐热、耐蚀方向发展,而某些元素的少量甚至痕量存在会显著影响铝合金的组织和性能,微合金化正成为挖掘合金潜力、改善合金性能并进一步开发新型铝合金的重要手段,引起了国内外的广泛关注。Aluminum alloy has a series of advantages such as low density, high strength, corrosion resistance, easy processing, and rich resources, and is widely used in aviation, transportation, power electronics, construction packaging and other industries. It is not only a kind of basic material with large quantity and wide range, but also occupies a very important position in national defense construction and plays an irreplaceable role. How to continuously develop new varieties and further improve the performance of aluminum materials has become a common concern of the international aluminum industry today. At present, the research and development goal of aluminum alloy has changed from the simple pursuit of high strength in the past to the overall improvement of the comprehensive performance of materials, that is, to further improve the durability and damage tolerance of the alloy while improving the strong plasticity of the aluminum alloy. Aluminum alloys are developing towards high specific strength, high specific modulus, high damage tolerance, heat resistance, and corrosion resistance, and the existence of small or even trace amounts of certain elements will significantly affect the structure and properties of aluminum alloys. Microalloying is becoming It is an important means to tap the potential of alloys, improve the properties of alloys and further develop new aluminum alloys, which has attracted widespread attention at home and abroad.
发明内容Contents of the invention
本发明所要解决的问题是寻求一种适用的铝合金微合金化的元素,对铝合金产生强韧化作用的同时,提高合金的耐疲劳损伤性能,从而整体提升材料的综合性能。The problem to be solved by the present invention is to seek a suitable aluminum alloy microalloying element, which can strengthen and toughen the aluminum alloy while improving the fatigue damage resistance of the alloy, so as to improve the comprehensive performance of the material as a whole.
本发明所提供的高耐损伤铝合金,其特征在于铝合金的基体中加入了重量百分比为0.001%-1.0%的铋。The high damage-resistant aluminum alloy provided by the present invention is characterized in that bismuth with a weight percentage of 0.001%-1.0% is added to the matrix of the aluminum alloy.
以上所述的金属铋的最佳含量范围为:0.001-0.3%。The optimal content range of the metal bismuth mentioned above is: 0.001-0.3%.
本发明由于添加微量铋,显著改变了合金的析出动力学,增大了强化相的析出密度并使其均匀分布;同时,被吸附在再结晶晶界的铋原子降低了界面的界面能,阻碍了晶界的移动,使得再结晶晶粒的长大使到抑制,即微量铋的存在不仅细化了晶粒,而且强化了晶界。Due to the addition of a small amount of bismuth, the present invention significantly changes the precipitation kinetics of the alloy, increases the precipitation density of the strengthening phase and makes it evenly distributed; at the same time, the bismuth atoms adsorbed on the recrystallized grain boundary reduce the interface energy of the interface, hinder The movement of grain boundaries makes the growth of recrystallized grains suppressed, that is, the presence of trace bismuth not only refines grains, but also strengthens grain boundaries.
附图说明Description of drawings
附图1为添加微量Bi前(a)后(b)Al-4.2Cu-1.4Mg-0.08Zr-0.6Mn合金在R=0.1时的疲劳裂纹扩展速率试验结果。Accompanying drawing 1 is the test result of the fatigue crack growth rate of Al-4.2Cu-1.4Mg-0.08Zr-0.6Mn alloy before (a) and after (b) adding a small amount of Bi at R=0.1.
具体实施方式Detailed ways
实施例采用石墨坩埚和铁模铸造法制备合金铸锭,所用原料为99.99%高纯铝、纯镁、纯铋,以及10.12%Mn、2.98%Zr的中间合金。铸锭经均匀化之后热轧、冷轧而成为2mm的板材。两种材料均经T4热处理(500℃固溶处理后水淬,室温自然时效96h)后测试室温拉伸性能及疲劳性能。表1列出了添加微量铋前后两种合金的力学性能,从表中可以看出,添加微量Bi后的Al-4Cu-1.5Mg合金,T4态下的抗拉强度σb、屈服强度σ0.2和延伸率δ都同时得到了显著提高。图1给出了添加微量Bi前后两种合金经T4处理后在R=0.1时的疲劳裂纹扩展速率试验结果,从图中可以看出,含微量Bi的合金疲劳裂纹扩展速率da/dn显著小于不含Bi的合金。EXAMPLE An alloy ingot was prepared by graphite crucible and iron mold casting, and the raw materials used were 99.99% high-purity aluminum, pure magnesium, pure bismuth, and an intermediate alloy of 10.12% Mn and 2.98% Zr. The cast ingot was homogenized and then hot-rolled and cold-rolled to form a 2mm plate. Both materials were subjected to T4 heat treatment (water quenching after solution treatment at 500°C, natural aging at room temperature for 96 hours), and then the tensile properties and fatigue properties at room temperature were tested. Table 1 lists the mechanical properties of the two alloys before and after the addition of trace bismuth. It can be seen from the table that the tensile strength σ b and yield strength σ 0.2 And elongation δ have been significantly improved at the same time. Figure 1 shows the test results of the fatigue crack growth rate of the two alloys before and after T4 treatment at R = 0.1, before and after the addition of trace Bi. It can be seen from the figure that the fatigue crack growth rate da/dn of the alloy containing trace Bi is significantly less than Alloys that do not contain Bi.
表1 合金Al-4.2Cu-1.4Mg-0.08Zr-0.6Mn-(0.05Bi)T4态处理后的拉伸性能Table 1 Tensile properties of alloy Al-4.2Cu-1.4Mg-0.08Zr-0.6Mn-(0.05Bi)T4 state after treatment
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CN2008101435768A CN101403060B (en) | 2008-11-13 | 2008-11-13 | High damnification resistant aluminum alloy |
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CN2008101435768A CN101403060B (en) | 2008-11-13 | 2008-11-13 | High damnification resistant aluminum alloy |
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CN101403060B true CN101403060B (en) | 2010-08-25 |
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