CN101337771B - Method of preparing golden yellow film-coating glass or ceramic - Google Patents
Method of preparing golden yellow film-coating glass or ceramic Download PDFInfo
- Publication number
- CN101337771B CN101337771B CN2007100706715A CN200710070671A CN101337771B CN 101337771 B CN101337771 B CN 101337771B CN 2007100706715 A CN2007100706715 A CN 2007100706715A CN 200710070671 A CN200710070671 A CN 200710070671A CN 101337771 B CN101337771 B CN 101337771B
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- China
- Prior art keywords
- golden yellow
- plating
- nickel
- glass
- wire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims abstract description 22
- 239000011521 glass Substances 0.000 title claims abstract description 21
- 239000000919 ceramic Substances 0.000 title claims abstract description 11
- 239000007888 film coating Substances 0.000 title claims description 11
- 238000009501 film coating Methods 0.000 title claims description 11
- 238000007747 plating Methods 0.000 claims abstract description 31
- 239000000463 material Substances 0.000 claims abstract description 17
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 claims abstract description 16
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 12
- 239000010937 tungsten Substances 0.000 claims abstract description 12
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 8
- 238000010438 heat treatment Methods 0.000 claims abstract description 7
- 238000009413 insulation Methods 0.000 claims description 13
- 229910001235 nimonic Inorganic materials 0.000 claims description 9
- 229910001120 nichrome Inorganic materials 0.000 claims description 8
- 230000008021 deposition Effects 0.000 claims description 7
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 239000011651 chromium Substances 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 239000010936 titanium Substances 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 238000001704 evaporation Methods 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 8
- 238000000151 deposition Methods 0.000 abstract description 6
- 238000001035 drying Methods 0.000 abstract description 5
- 238000004040 coloring Methods 0.000 abstract description 4
- 238000012423 maintenance Methods 0.000 abstract description 2
- 229910001069 Ti alloy Inorganic materials 0.000 abstract 3
- VHHVGPDQBHJHFB-UHFFFAOYSA-N [Ti].[Cr].[Ni] Chemical compound [Ti].[Cr].[Ni] VHHVGPDQBHJHFB-UHFFFAOYSA-N 0.000 abstract 3
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 230000008020 evaporation Effects 0.000 description 11
- 238000007738 vacuum evaporation Methods 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 5
- 238000007733 ion plating Methods 0.000 description 4
- 239000005329 float glass Substances 0.000 description 3
- 238000010849 ion bombardment Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000004134 energy conservation Methods 0.000 description 2
- 238000007669 thermal treatment Methods 0.000 description 2
- 238000001771 vacuum deposition Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229910052571 earthenware Inorganic materials 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005546 reactive sputtering Methods 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Landscapes
- Physical Vapour Deposition (AREA)
Abstract
The invention discloses a golden yellow plating glass or a manufacturing method of a ceramic. The manufacturing method comprises the following steps: plating nickel-chromium-titanium alloy on the surface of the glass or the ceramic by using a vacuum vapor plating method; then entering a drying oven for heat treatment; and finally obtaining a golden yellow plating layer. The vacuum vapor plating method comprises the following steps: placing a plating material under the high vacuum condition for electrifying and heating through tungsten twisted filaments; evaporating and depositing on the surface of a body simultaneously; and then agglomerating a film. The golden yellow filming glass has the advantages of the adoption of the vacuum vapor plating method to plate the golden yellow plating layer, low cost of a device, simple process, lower production cost, convenient operation and easy maintenance and repair of the device A double stranded wire of a nickel-chromium-titanium alloy wire or a nickel chrome wire and a titanium wire is adopted as the plating material, thereby enhancing the coloring effect, in particular to better golden yellow coloring effect of the nickel chrome wire and titanium wire after being subjected to mixed vapor plating. The implementation of the heat treatment is improved by adopting the nickel-chromium-titanium alloy; the requirements on the temperature are lower; the power consumption is less; and the energy is saved.
Description
[technical field]
The present invention relates to Coating Materials and film coating method field, relate in particular to the manufacture method of golden yellow film-coating glass or pottery.
[background technology]
The metal of glass and ceramic surface plating single or multiple lift, alloy, compound book film to change different wavelengths of light to specific absorption, reflectivity, the transmission of glass and pottery and produce effect such as interference, reach predetermined optics, aesthetics and effect such as energy-conservation.
In aesthstic and decoration field, golden yellow is that people like and one of the color used always.Make glass and ceramic surface golden yellow with methods such as vacuum platings, except aesthstic and decorative effect, effects such as energy-conservation are often arranged also.
Golden yellow plated film has many methods, and present Vacuum Coating method is used the most generally.Vacuum plating has many concrete grammars again, and conclusion is got up, and roughly is divided into vacuum evaporation, sputter plating and three kinds of basic skills of ion plating.
Vacuum evaporation is that workpiece is put into vacuum chamber, and with the certain method heating, makes Coating Materials (being called for short the plating material) evaporation or distillation, is deposited on workpiece surface cohesion film forming.The sputter plating is that workpiece is put into vacuum chamber, and with the target (plating material) of positive ion bombardment as negative electrode, atom, molecule in the target is overflowed, and is deposited on workpiece surface cohesion film forming.Ion plating is that workpiece is put into vacuum chamber, and with the vapor particles ionization of gas discharge principle with portion gas and evaporation source (plating material) effusion, evaporant or its reaction product is deposited on workpiece surface cohesion film forming.
These three kinds of basic Vacuum Coating methods of vacuum evaporation, sputter plating and ion plating respectively have certain relative merits.Ion plating at present commonly used or reactive sputtering plating, at the golden yellow plated film of glass or ceramic surface, not only apparatus expensive, and equipment, technology are all comparatively complicated, the production cost height.
[summary of the invention]
Purpose of the present invention solves the problems of the prior art exactly, proposes the manufacture method of a kind of golden yellow film-coating glass or pottery, can reduce equipment cost, simplifies technical process, reduces production costs.
For achieving the above object, the present invention proposes the manufacture method of a kind of golden yellow film-coating glass or pottery, nimonic is plated on glass or ceramic surface, enter baking oven then and heat-treat, obtain golden yellow coating with vacuum vapour deposition.
As preferably, described vacuum vapour deposition is placed on high vacuum condition under by tungsten hank knotting energising heating for plating material earlier, evaporates simultaneously and is deposited on workpiece surface, condenses film forming.
As preferably, described plating material adopts the nimonic silk.
As preferably, the bifilar silk union that described plating material adopts nichrome wire and titanium silk to form.
As preferably, nickel, chromium mass percent are in the described nichrome wire: nickel 80%, chromium 20%.
As preferably, what enter that baking oven heat-treats is operating as 110 ℃ of insulations 1 hour down, and again 160 ℃ of insulations 1 hour down, 210 ℃ of insulations 3-6 hour down are cooled to room temperature then then.
As preferably, what enter that baking oven heat-treats is operating as 150 ℃ of insulations 1 hour down, and again 180 ℃ of insulations 1 hour down, 210 ℃ of insulations 3-6 hour down are cooled to room temperature then then.
Beneficial effect of the present invention: the present invention adopts vacuum vapour deposition at golden yellow plating plated film on glass, and equipment cost is low, and technology is simple, and production cost is lower, and is easy to operate, equipment easy care, maintenance.The bifilar silk that adopts nimonic silk or nichrome wire and titanium silk can increase coloring effect for the plating material, and especially nichrome wire is better with the golden yellow coloring effect of titanium silk mixing evaporation.Adopt nimonic to improve heat treated exploitativeness, lower to temperature requirement, current consumption is few, saves the energy.
Feature of the present invention and advantage will be elaborated by embodiment.
[embodiment]
Embodiment one:
The manufacture method of golden yellow plated film pottery is plated on ceramic surface with vacuum vapour deposition with nimonic, enters baking oven then and heat-treats, and obtains golden yellow coating.Concrete operations are:
1. clean with dry: will thoroughly remove greasy dirt and other fouls on the ceramic surface earlier, after degreasing, scrub with cleaning and deionized water respectively generally speaking, enter baking oven or drying tunnel drying then.
2. vacuum evaporation: press workpiece size, shape and turnout and select vacuum evaporation equipment, work rest and evaporation source (tungsten hank knotting) to distribute.Be example with long 100 millimeters, wide 80 millimeters, thick 5 millimeters earthenware slab small workpiece and single tungsten hank knotting now: with diameter is that the nichrome wire that 0.5 millimeter titanium silk and diameter are 0.35 millimeter twists together with machine in advance, becomes bifilar silk union.Cut length and be 400 millimeters bifilar silk union, put into the tungsten hank knotting.Vacuumize.Be evacuated to rough vacuum earlier, the ion bombardment device is applied voltage, cause glow discharge, make workpiece bear icon bombardment cleaning.Close the ion bombardment device after 15 minutes.Be evacuated to high vacuum, vacuum tightness is not less than 2x10
-2Pa makes tungsten hank knotting energising heating then, and evaporation plating material is deposited on workpiece surface with nimonic rapidly.Nickel, chromium mass percent are in the described nichrome wire: nickel 80%, chromium 20%.
3. thermal treatment: film-coating workpiece is put into baking oven carry out heat tracing, concrete technology is the 150 ℃ of insulations 1 hour down that are operating as that enter that baking oven heat-treats, and again 180 ℃ of insulations 1 hour down, 210 ℃ of insulations 3-6 hour down are cooled to room temperature then then.Best soaking time is 6 hours under 210 ℃.
Through aforesaid operations, can obtain golden yellow plated film pottery.Above-mentioned technology extends on many ceramic workpieces, but will select the distribution and the quantity of vacuum evaporation equipment, work rest and evaporation source (tungsten hank knotting) according to workpiece size, shape and turnout, and the amount of putting into of plating material also will be adjusted by testing in each tungsten hank knotting.In addition, the appropriate design evaporation source to distribute and quantity, and correctly implement evaporation process, to guarantee the homogeneity of plated film at workpiece surface.
Embodiment two:
The manufacture method of golden yellow film-coating glass is plated on glass surface with vacuum vapour deposition with nimonic, enters baking oven then and heat-treats, and obtains golden yellow coating.Concrete operations are:
1. clean with dry: will thoroughly remove the various fouls on the glass surface earlier.Use the float glass (after promptly making soon float glass) of " fresh " as far as possible.Heat drying in drying tunnel or baking oven will be washed away totally at last with clear water and deionized water.
2. vacuum evaporation: elementary operation and embodiment one are roughly the same.As another example, also can adopt double membrane structure.For example 100 millimeters of length, wide 80 millimeters, thick 5 millimeters float glass small workpiece are adopted two tungsten hank knottings evaporations: evaporate the bifilar silk union of 300 millimeters long in the tungsten hank knotting earlier, 500 millimeters long titanium silks in another tungsten hank knotting of back evaporation.
3. thermal treatment: what enter that baking oven heat-treats is operating as 110 ℃ of insulations 1 hour down, and again 160 ℃ of insulations 1 hour down, 210 ℃ of insulations 3-6 hour down are cooled to room temperature then then.
In the actual production, design or selection equipment, work rest, evaporation source and plating material amount according to workpiece size, shape and turnout.
The foregoing description is to explanation of the present invention, is not limitation of the invention, any structure after the simple transformation of the present invention is all belonged to protection scope of the present invention.
Claims (3)
- Golden yellow film-coating glass or the pottery manufacture method, it is characterized in that: nimonic is plated on glass or ceramic surface with vacuum vapour deposition, entering baking oven then heat-treats, obtain golden yellow coating, described vacuum vapour deposition is placed under the high vacuum condition by tungsten hank knotting energising heating for plating material earlier, evaporate simultaneously and be deposited on workpiece surface, the cohesion film forming, described plating material adopts the nimonic silk, what enter that baking oven heat-treats is operating as 110 ℃ of insulations 1 hour down, be incubated 1 hour down at 160 ℃ again, 210 ℃ are incubated 3-6 hour down then, are cooled to room temperature then.
- 2. the manufacture method of golden yellow film-coating glass as claimed in claim 1 or pottery is characterized in that: the bifilar silk union that described plating material adopts nichrome wire and titanium silk to form.
- 3. the manufacture method of golden yellow film-coating glass as claimed in claim 2 or pottery, it is characterized in that: nickel, chromium mass percent are in the described nichrome wire: nickel 80%, chromium 20%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100706715A CN101337771B (en) | 2007-08-31 | 2007-08-31 | Method of preparing golden yellow film-coating glass or ceramic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100706715A CN101337771B (en) | 2007-08-31 | 2007-08-31 | Method of preparing golden yellow film-coating glass or ceramic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101337771A CN101337771A (en) | 2009-01-07 |
| CN101337771B true CN101337771B (en) | 2011-10-05 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007100706715A Expired - Fee Related CN101337771B (en) | 2007-08-31 | 2007-08-31 | Method of preparing golden yellow film-coating glass or ceramic |
Country Status (1)
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| CN (1) | CN101337771B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103910496A (en) * | 2013-01-04 | 2014-07-09 | 杭州畅翔玻璃有限公司 | High light transmission golden curtain wall glass and processing technology thereof |
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- 2007-08-31 CN CN2007100706715A patent/CN101337771B/en not_active Expired - Fee Related
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| Publication number | Publication date |
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| CN101337771A (en) | 2009-01-07 |
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Owner name: HUZHOU TIAHE AUTOMOBILE PART CO., LTD. Free format text: FORMER OWNER: HUZHOU JINTAI SCIENCE AND TECHNOLOGY CO., LTD. Effective date: 20150304 |
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Free format text: CORRECT: ADDRESS; FROM: 313001 HUZHOU, ZHEJIANG PROVINCE TO: 313028 HUZHOU, ZHEJIANG PROVINCE |
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| TR01 | Transfer of patent right |
Effective date of registration: 20150304 Address after: 313028 8 building, No. seven, 999 fortune road, Zhejiang, Huzhou Patentee after: HUZHOU TIAHE AUTOMOBILE PART CO., LTD. Address before: 313001, Zhejiang Province, Wuxing District, Huzhou ring village Wan Cun Patentee before: Huzhou Jintai Science and Technology Co., Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20111005 Termination date: 20190831 |
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| CF01 | Termination of patent right due to non-payment of annual fee |