CN101214201A - Nourishing anti-dandruff shampoo composition - Google Patents
Nourishing anti-dandruff shampoo composition Download PDFInfo
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- CN101214201A CN101214201A CNA2008100256934A CN200810025693A CN101214201A CN 101214201 A CN101214201 A CN 101214201A CN A2008100256934 A CNA2008100256934 A CN A2008100256934A CN 200810025693 A CN200810025693 A CN 200810025693A CN 101214201 A CN101214201 A CN 101214201A
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Abstract
The present invention relates to a shampoo combination with the efficacies of nourishing and removing dandruff. The shampoo comprises (A) anionic surfactant which takes 5.0 percent to 30 percent of the weight of the combination, amphoteric surfactant which takes 0.5 percent to 5.0 percent of the weight of the combination, thickening agent which takes 0.5 percent to 5.0 percent of the weight of the combination and conditioner which takes 2.0 percent to 10 percent of the weight of the combination and also comprises (B) anti-dandruff agent which takes 0.2 percent to 8.0 percent of the weight of the combination, wherein, the anti-dandruff agent is a combination of pyrithione salt and di-pyrithione, the proportion of which is 1 : 100 to 2 : 3, and shampoo also comprises (C) nutrient additive which takes 0.5 percent to 5.0 percent of the weight of the combination and is selected from vitamin, aminopeptodrate and plant extract. The present invention has the efficacies of nourishing and removing the dandruff.
Description
Technical field
The invention belongs to household chemicals field, be specifically related to the shampoo composite of a kind of tool nourishing and anti-dandruff effect.
Background technology
Dandruff is the metabolic product of human body head epidermis cell, and to be epidermis cell breed ripe outwards layer from basal layer to hair normal metabolic process gradually passes, and forms horny layer and comes off.The modern is because excessive, the psychentonia of pressure, fatigue, shampoo inferior, the use of medicine, air-polluting increase the weight of and the effect of microorganism, antibacterial makes the scalp cells Developmental and Metabolic Disorder, cell becomes greatly, thickens, comes off into the dandruff, brings great inconvenience for people's life.It has been generally acknowledged that the incomplete keratinization of scalp cells of superficial layer and the parasitism of pityrosporum ovale are the main causes that dandruff increases, the generation of dandruff has been created advantage for microbial growth and breeding again, and then cause scalp irritation, cause pruritus, the unusual breeding of accelerometer chrotoplast.Therefore suppressing cellular keratinization speed, is the main path of control dandruff thereby reduce the metabolic speed of epidermis and sterilize.Present anti-dandruff shampoo mainly is to adopt anti-dandruff dose of prescription that adds surfactant to form, though can play certain anti-dandruff effect, but its conditioning property but reduces greatly, slippery during bath reduces, acerbity increases, wash dry dry, the coarse combing that is difficult in back, simultaneously the scalp spinosity is swashed effect, can not satisfy the consumption demand of consumer.
Summary of the invention
The purpose of this invention is to provide a kind of shampoo composite, said composition has remarkable nourishing and anti-dandruff effect.
The present composition comprises: (A) be applicable to the anion surfactant that accounts for composition weight 5.0% to 30% in the shampoo composite, account for composition weight 1.5% to 8.0% amphoteric surfactant, account for the thickening agent of composition weight 0.5% to 5.0% and account for the conditioner of composition weight 2.0% to 10%; Also contain (B) and account for anti-dandruff dose of composition weight 0.2% to 8.0%; Wherein said anti-dandruff dose is the compositions of pyrithione and two pyrithione, and both ratios are 1: 100 to 2: 3; (C) account for the nourishing additive agent of composition weight 0.5% to 5.0%, described nourishing additive agent is selected from vitamin E, provitamin B
5, at least a in the hydrolyzed protein, plant extraction liquid; Reaching (D), surplus is a water.
Shampoo composite of the present invention, wherein said anion surfactant are selected from Laurel alkyl ammonium sulfate or polyoxyethylene lauryl ether ammonium sulfate, and described amphoteric surfactant is a cocamido propyl betaine, and described thickening agent is the phthalic acid amide.
Shampoo composite of the present invention, wherein said conditioner are selected from least a in cationic cellulose polymer, cation melon glue, the emulsified silicone oil.
Shampoo composite of the present invention, wherein said anti-dandruff dose is the compositions of pyrithione and two pyrithione, described pyrithione is selected from least a in Zinc Pyrithione, pyrithione sodium, the copper pyrithione.Anti-dandruff dose is Zinc Pyrithione and two pyrithione compositionss, the ratio of Zinc Pyrithione and two pyrithione 1: 50 to 1: 2.
Shampoo composite of the present invention, wherein said pair of pyrithione satisfies structural formula (I), and the mean diameter of wherein said pair of pyrithione is at most 20 μ m, and the particulate mean diameter of Zinc Pyrithione is at most 10 μ m, is preferably mean diameter and is at most 5 μ m
Shampoo composite of the present invention, wherein nourishing additive agent is selected from provitamin B
5, at least a in 200 to 10000 hydrolyzed protein, Radix Ginseng extractive solution, Aloe extraction solution, Sucus Zingberis extracting solution of molecular weight.
Shampoo composite of the present invention also comprises the INCROQUAT TMC-80 ECONOL TM22 that accounts for composition weight 0.25% to 8.0%, and content is preferably 0.5% to 5.0%.
Shampoo composite of the present invention, the preferable range of each component is: (A) be applicable to the anion surfactant that accounts for composition weight 10% to 25% in the shampoo composite, account for composition weight 2.0% to 6.0% amphoteric surfactant, account for the thickening agent of composition weight 1.0% to 4.0% and account for the conditioner of composition weight 3.0% to 8.0%; Also contain (B) and account for anti-dandruff dose of composition weight 0.5% to 5.0%; Wherein said anti-dandruff dose is the compositions of pyrithione and two pyrithione, and both ratios are 1: 50 to 1: 2; (C) account for the nourishing additive agent of composition weight 0.8% to 3.0%, described nourishing additive agent is selected from provitamin B
5, at least a in 200 to 10000 hydrolyzed protein, Radix Ginseng extractive solution, Aloe extraction solution, Sucus Zingberis extracting solution of molecular weight; Reaching (D), surplus is a water.
Compared with prior art, the present invention has the following advantages:
The surfactant that shampoo composite of the present invention is comprised, thickening agent, the conditioner, also contain anti-dandruff dose and nourishing additive agent in containing conventional shampoo.Anti-dandruff dose of two pyrithione and the composite of Zinc Pyrithione are suitable for, and have brought improved anti-dandruff effect, and the adding of nourishing additive agent provides deep nourishing effect to hair.
To be elaborated to component selection of the present invention and effect below.
A. solvent
Nourishing anti-dandruff shampoo composition solvent of the present invention comprises anion surfactant, amphoteric surfactant, thickening agent and conditioner, and each in these components is all described in detail hereinafter.
Surfactant in the shampoo utilizes its infiltration, emulsifying and peptizaiton, and dirt is gone out from hair, scalp, plays the effect of cleaning.Nourishing anti-dandruff shampoo composition of the present invention comprises and accounts for composition weight 5.0% to 30%, preferred 10% to 25% the suitable anion surfactant that is used on hair or the skin, the compositions of preferred Laurel alkyl ammonium sulfate, polyoxyethylene lauryl ether ammonium sulfate, oxirane in the compositions of described polyoxyethylene lauryl ether ammonium sulfate (EO) adduct number is 2 to 4, and the optimization ethylene oxide adduct number is 3.Other non-limiting example that is applicable to anion surfactant of the present invention also has: sodium laurylsulfate, lauryl alcohol potassium sulfate, polyoxyethylene lauryl ether sodium sulfate, polyoxyethylene lauryl ether potassium sulfate, glycerine monofatty ester sulfate, aliphatic alcohol sodium isethionate, N-lauroyl musculamine acid sodium, lauroyl Herba bromi japonici amino acid sodium, 1-isobutyl-3,5-dimethylhexylphosphoric acid potassium salt etc.Nourishing anti-dandruff shampoo composition of the present invention also comprises and accounts for composition weight 1.5% to 8.0%, preferred 2.0% to 6.0% the suitable amphoteric surfactant that is used on hair or the skin, preferred cocamido propyl betaine.Other is applicable to that the non-limiting example of amphoteric surfactant of the present invention also has dodecyldimethylammonium hydroxide inner salt, fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium salt, imidazoline type betanin, cocos nucifera oil both sexes sodium acetate, cocamidopropyl propyl amide hydroxyl sulphonic acid betaine etc.
Nourishing anti-dandruff shampoo composition of the present invention comprises and accounts for composition weight 0.5% to 5.0%, preferred 1.0% to 4.0% be used to the suspend thickening agent of granular anti-dandruff dose and thickener composition, improve the stability of shampoo composite, the preferred phthalic acid amide of wherein said thickening agent, described phthalic acid amide trade name is TAB-2, make by two hydrogenated-tallow group secondary amine and phthalic anhydride, it is a kind of multifunctional suspending stabilizing agent, can be used as emulsifying agent, suspending agent, can effectively stablize the shampoo composite that contains silicone oil and anti-dandruff dose, can with all components compatibility in the present composition, salt tolerance is preferably arranged, have constant thickening effect in wider pH scope, can make compositions viscosity at room temperature is 6000mPa.s to 12000mPa.s, preferred 8000mPa.s to 10000mPa.s.Other non-limiting example that is applicable to thickening agent of the present invention also has: sodium chloride, ammonium chloride, the monoethanolamine chloride, the diethanolamine chloride, sodium sulfate, ammonium sulfate, disodium hydrogen phosphate, electrolyte and polyglycol distearates such as phosphoric acid five sodium, polyethylene glycol mono stearate, polyethylene glycol dilaurate, Carboxymethyl cellulose sodium, hydroxyethyl-cellulose, hydroxypropyl emthylcellulose, trade name is acrylic acid/polyoxyethylene (20) octadecanol ether methyl acid copolymer of Aculyn22, trade name is the anionic thickeners such as acrylic copolymer of Aculyn33, trade name is the non-ionic thickening agent C of Aculyn44
10Poly-carbamyl macrogol ester, Polyethylene Glycol, polyvinylpyrrolidone etc.
Nourishing anti-dandruff shampoo composition of the present invention comprises and accounts for composition weight 2.0% to 10.0%, preferred 3.0% to 8.0% be applicable to conditioner on hair and the skin, the adding of conditioner mainly is the feel of washing the back hair in order to improve, make hair smooth, soft, be easy to combing.Wherein said conditioner is selected from, one or more compositionss in cationic cellulose polymer, cation melon glue, the emulsified silicone oil.Described cationic cellulose polymer, have another name called poly-cellulose ether quaternary ammonium salt, be to carry out the product that obtains after quaternized by the cellulose or derivatives thereof, mainly contain polyquaternary ammonium salt-4, polyquaternary ammonium salt-6, polyquaternary ammonium salt-7, polyquaternary ammonium salt-10, polyquaternary ammonium salt-17, polyquaternary ammonium salt-18 etc., preferred polyquaternary ammonium salt-10.Described cation melon glue is the product that melon glue is obtained after quaternized, its key component is a melon glue oxypropyl trimethyl ammonium chloride, difference according to substitution value can obtain a series of cation melon glue product, preferred substitution value is 0.1 to 0.2, be used for cation melon glue of the present invention under 25 ℃ of conditions, the viscosity of its 1% aqueous solution is 2000mPa.s to 4000mPa.s, and its consumption is 0.02% to 3.0%, preferred again 0.05% to 1.0%; Described emulsified silicone oil is non-volatile polydimethylsiloxane, its consumption is 0.5% to 10%, preferred 1.0% to 8.0%, be used for the viscosity that emulsified silicone oil of the present invention records and be preferably 100mPa.s to 2500000mPa.s, preferred again 500mPa.s to 1500000mPa.s under 25 ℃.Select big particle diameter emulsified silicone oil and small particle diameter emulsified silicone oil to be used, improve the dried cardability and the wet cardability of shampoo, described big particle diameter emulsified silicone oil number average particle diameter is at 10 μ m to 30 μ m, preferred 15 μ m to 25 μ m; Described small particle diameter emulsified silicone oil number average particle diameter is at 0.01 μ m to 5 μ m, preferred 0.01 μ m to 2 μ m.Other is applicable to that conditioner of the present invention gets non-limiting example and also has: L-sodium lactate, Oleum Ricini maleic acid glyceride, quaternary ammonium salt-82, different hard ester group ethyl imidazol(e) ethoxy sulfate, Fructus Hordei Germinatus amido propyl ammonio methacrylate etc.
B. anti-dandruff dose
Nourishing anti-dandruff shampoo composition of the present invention comprises and accounts for composition weight 0.2% to 8.0%, preferred 0.5% to 5.0% suitable anti-dandruff dose of being used on hair or the skin, and anti-dandruff dose adding has improved the antimicrobial acivity of shampoo composite.Wherein said anti-dandruff dose is the compositions of pyrithione and two pyrithione.Described pair of pyrithione trade name is this spirit of bits, its structural formula is (I), this chemical compound has antimicrobial activity, effective to many Glan formula positives and negative bacterium and many mycetes and yeast, preferably pair pyrithione is that white is to brown suspension, particulate mean diameter is at most 20 μ m, preferably is at most 5 μ m.
Described pyrithione structural formula is (II), and M is metal ions such as Cu, Zn, Na in the formula, and preferred M is Zn,
It is Zinc Pyrithione; Described Zinc Pyrithione is itch agent and a high-effective broad-spectrum fungicide of the anti-dandruff system that is acknowledged as highly effective and safe, but the zest of this chemical compound is strong, and is big to the zest of eyes.The preferred particulate mean diameter of Zinc Pyrithione is at most 10 μ m, most preferably is at most 5 μ m.
Preferred 1: 50 to 1: 2 of the ratio of Zinc Pyrithione and two pyrithione can obtain good anti-dandruff effect among the present invention.Other is applicable to that non-limiting example of the present invention anti-dandruff dose also has: endecatylene acid derivative, 1-hydroxyl-4 methyl-6-(2,4, the 4-tri-methyl-amyl)-2 (1H)-pyridone and ethanolamine (1: 1), 1-(4-chlorophenoxy)-1-(1H-imidazole radicals)-3,3-dimethyl-2-butanone etc.
C. nourishing additive agent
Nourishing anti-dandruff shampoo composition of the present invention comprises and accounts for composition weight 0.5% to 5.0%, preferred 0.8% to 3.0% nourishing additive agent, wherein said nourishing additive agent is selected from, a kind of in vitamin, hydrolyzed protein and derivant thereof, the plant extraction liquid, the former B of preferred vitamin
5, a kind of in 200 to 10000 hydrolyzed protein, Radix Ginseng extractive solution, Aloe extraction solution, Sucus Zingberis extracting solution of molecular weight.Described vitamin comprises vitamin E, provitamin B
5, described vitamin E claims tocopherol again, can be divided into four kinds of a, β, γ and d, has good antioxygenic property, and hair growth promoting, hair care are had clinical effect; Described provitamin B
5Having another name called pantothenylol, is vitamin B
5Hydrogenation products, provitamin B in skin and hair
5Can change vitamin B into, be deep into root of hair, moisture in the control hair, prevent trichoxerosis, come off, bifurcated, be entangled with, give hair luster, quicken hair growth, the specific rotatory power of preferred pantothenylol is+29.0 °～+ 31.5 °, and index of refraction is 1.495～1.502.Described hydrolyzed protein mainly contains hydrolyzed silk protein, hydrolyzed wheat protein, hydrolyzed gluten, hydrolyzed soybean protein, hydrolytic collagen, hydrolysis of keratin, elastin hydrolysis, hydrolysis milk proem etc., the molecular weight of described hydrolyzed protein between 200 to 10000, the little peptide of preferred molecular weight between 300 to 2000; Described hydrolyzed protein derivant comprises: Laurel hydroxypropyl hydrolyzed protein alkyl dimethyl ammonium chloride, cocoyl hydroxypropyl hydrolyzed protein alkyl dimethyl ammonium chloride, hydroxypropyl hydrolyzed protein trimethyl ammonium chloride etc.Described plant extraction liquid comprises Radix Ginseng extractive solution, Aloe extraction solution, Sucus Zingberis extracting solution, camellia oleosa seed elite, seaweed extracted liquor and feverfew extracting solution etc.
Nourishing anti-dandruff shampoo composition of the present invention also comprises and accounts for composition weight 0.25% to 8.0%, preferred 0.5% to 5.0% cationic surfactant, preferred INCROQUAT TMC-80 ECONOL TM22.
Nourishing anti-dandruff shampoo composition of the present invention also comprises and accounts for composition weight 0.2% to 5.0%, preferred 0.5% to 2.5% foam stabilizer, described foam stabilizer is meant the surfactant with prolongation and stable foam, mainly is selected from alkylolamides, the preferred fatty acid single ethanol amide.
Nourishing anti-dandruff shampoo composition of the present invention can also comprise other optional components, comprises chelating agen, pearling agent, pH regulator agent, antiseptic, pigment and spice etc.The non-limiting example of described chelating agen has: ethylenediaminetetraacetic acid, disodiumedetate, tetrasodium ethylenediamine tetraacetate, citric acid, phosphoric acid, ascorbic acid etc., preferred disodiumedetate; The non-limiting example of described pearling agent has: ethylene glycol stearate, polyglycol distearate, preferred ethylene glycol bisthioglycolate sodium stearate; The non-limiting example of described pH regulator agent has: citric acid, phosphoric acid etc., optimization citric acid, the pH of regulation system are 5.0 to 8.0, and preferred 5.5 to 6.5; Choosing of described antiseptic, essence, pigment meets the regulation of hygienic standards for cosmetics, selects safe raw material for use.
In the nourishing anti-dandruff shampoo composition of the present invention, except the above component, water is mended to aequum.
Preparation method
Nourishing anti-dandruff shampoo composition of the present invention can by any known or other effectively be applicable to the technology preparation that shampoo composite is provided, the method for preparing nourishing anti-dandruff shampoo composition of the present invention comprises conventional preparation and hybrid technology.
Using method
Nourishing anti-dandruff shampoo composition of the present invention uses with the cleaning of routine and the mode of conditioning hair, mainly comprises following step:
(A) water is with the hair moistening;
(B) use the shampoo composite of aforementioned each claim of effective dose on described hair, the scope of described effective dose is generally 1 gram to 50 grams, preferred 2 to 20 grams;
(C) with the shampoo composite on the described hair of water rinse.
These steps can repeat repeatedly as required, to reach the effect of cleaning, conditioning and the anti-dandruff looked for.
Embodiment
Be the non-limiting example of nourishing anti-dandruff shampoo composition of the present invention below.Providing of these embodiment only is for illustrative purposes, can not be interpreted as limitation of the invention, because without departing from the spirit and scope of the present invention, can carry out many changes to the present invention.In these embodiments, unless stated otherwise, all concentration all is percentage by weight.Used term " small amount of matter " refers to those optional materials, as antiseptic, viscosity modifier, pH regulator agent, spice, pigment etc., the selection of these small amount of matter will change in order to the physics for preparing special component of the present invention and chemical characteristic along with selected.
Preparation example I-XV
The suitable method for preparing nourishing anti-dandruff shampoo composition described in example I-XV is as follows: suitable quantity of water is joined in the retort, adding melon glue and polyquaternary ammonium salt-10 disperse under slowly stirring, slowly be stirred and heated to 60 ℃ to 80 ℃, then add pH regulator agent (for example citric acid), Laurel alkyl ammonium sulfate, polyoxyethylene lauryl ether ammonium sulfate, cocamido propyl betaine, fatty monoethanol amide, the ethylene glycol bisthioglycolate sodium stearate, acrylic copolymer, the phthalic acid amide, disodiumedetate (if using these materials) makes these materials disperse the back cooling fully.Add anti-dandruff dose of two pyrithione when treating that temperature is reduced to 65 ℃ of left and right sides, be cooled to below 50 ℃ after being uniformly dispersed add emulsified silicone oil, nourishing additive agent is uniformly dispersed, and adds antiseptic, pigment, essence etc. again and continues to stir, and guarantees to obtain uniform mixture.After adding all components, can add viscosity modifier and pH regulator agent as required, the viscosity and the pH that regulate product arrive suitable degree.Randomly can add low amounts of water at last supplies.
Example I-V
| Component | Weight (%) | ||||
| I | II | III | IV | V | |
| Laurel alkyl ammonium sulfate | 8.0 | 8.0 | 8.0 | 8.0 | 8.0 |
| Polyoxyethylene lauryl ether ammonium sulfate | 10.0 | 10.0 | 12.0 | 12.0 | 12.0 |
| Cocamido propyl betaine | 3.0 | 3.0 | 4.0 | 4.0 | 4.0 |
| Fatty monoethanol amide | 0.5 | 0.5 | 0.8 | 0.8 | 0.8 |
| Melon glue | 0.1 | 0.1 | 0.2 | 0.2 | 0.2 |
| Polyquaternary ammonium salt-10 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
| The ethylene glycol bisthioglycolate sodium stearate | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 |
| The phthalic acid amide | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 |
| Disodiumedetate | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
| Zinc Pyrithione | 0 | 0.1 | 0.15 | 0.2 | 0.25 |
| Two pyrithione | 0.8 | 0.7 | 0.65 | 0.6 | 0.55 |
| Emulsified silicone oil | 2.0 | 2.0 | 2.5 | 2.5 | 2.5 |
| INCROQUAT TMC-80 ECONOL TM22 | 1.2 | 1.2 | 1.4 | 1.4 | 1.4 |
| The Sucus Zingberis extracting solution | 1.2 | 1.2 | 1.5 | 1.5 | 1.8 |
| Water | Add to 100% | ||||
Above-mentioned nourishing anti-dandruff shampoo has good anti-dandruff and antipruritic effect.
Example VI-X
| Component | Weight (%) | ||||
| VI | VII | VIII | IX | X | |
| Laurel alkyl ammonium sulfate | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 |
| Polyoxyethylene lauryl ether ammonium sulfate | 10.0 | 10.0 | 12.0 | 12.0 | 14.0 |
| Cocamido propyl betaine | 4.0 | 4.0 | 5.0 | 5.0 | 5.0 |
| Fatty monoethanol amide | 0.9 | 0.9 | 1.0 | 1.0 | 1.0 |
| Melon glue | 0.4 | 0.4 | 0.6 | 0.6 | 0.6 |
| Polyquaternary ammonium salt-10 | - | - | 0.2 | 0.2 | 0.2 |
| The ethylene glycol bisthioglycolate sodium stearate | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 |
| The phthalic acid amide | 1.0 | 1.0 | 1.2 | 1.2 | 1.2 |
| Disodiumedetate | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
| Zinc Pyrithione | 0 | 0.1 | 0.15 | 0.2 | 0.25 |
| Two pyrithione | 1.2 | 1.1 | 1.05 | 1.0 | 0.95 |
| Emulsified silicone oil | 3.0 | 3.0 | 3.0 | 3.0 | 3.0 |
| INCROQUAT TMC-80 ECONOL TM22 | 1.5 | 1.5 | 1.8 | 1.8 | 1.8 |
| Pantothenylol | 1.5 | 1.5 | 2.0 | 2.0 | 2.0 |
| Water | Add to 100% | ||||
Above-mentioned nourishing anti-dandruff shampoo has good anti-dandruff and moistening effect.
Embodiment XI-XV
| Component | Weight (%) | ||||
| XI | XII | XIII | XIV | XV | |
| Laurel alkyl ammonium sulfate | 5.0 | 5.0 | 5.0 | 5.0 | 5.0 |
| Polyoxyethylene lauryl ether ammonium sulfate | 12.0 | 12.0 | 15.0 | 15.0 | 15.0 |
| Cocamido propyl betaine | 4.0 | 4.0 | 4.0 | 4.0 | 4.0 |
| Fatty monoethanol amide | 0.7 | 0.7 | 1.5 | 1.5 | 1.5 |
| Melon glue | 0.65 | 0.65 | 0.8 | 0.8 | 0.8 |
| The ethylene glycol bisthioglycolate sodium stearate | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 |
| The phthalic acid amide | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 |
| Disodiumedetate | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
| Zinc Pyrithione | 0 | 0.1 | 0.15 | 0.2 | 0.25 |
| Two pyrithione | 1.5 | 1.4 | 1.35 | 1.3 | 1.25 |
| Emulsified silicone oil | 3.5 | 3.5 | 3.5 | 3.5 | 3.5 |
| INCROQUAT TMC-80 ECONOL TM22 | 2.0 | 2.0 | 2.5 | 2.5 | 2.5 |
| Hydrolyzed silk protein | 1.5 | 1.5 | 2.0 | 2.0 | 2.0 |
| Water | Add to 100% | ||||
Above-mentioned nourishing anti-dandruff shampoo has good anti-dandruff and suitable sliding effect.
Effect is estimated embodiment
Effect evaluation methodology for embodiment is divided into sensory evaluation method and cardability test two parts.
Described sensory evaluation method is: will prepare example I-XV, and issue 60 testers respectively and contrast use.According to identical method hair washing, every kind of shampoo used for two weeks when the tester used the shampoo sample.The tester according to oneself feel mark, wherein antipruritic effect is that the time that begins according to head pruritus and the degree of head pruritus are marked, anti-dandruff effect is to mark according to what and size of dandruff.Standards of grading adopt 7 fens systems, and 1 minute the poorest, and 7 minutes best, and the high more effect of mark is good more good more.Various shampoo composite result of use evaluation results are listed in table 1.
Table 1 shampoo composite result of use is estimated
Described cardability test comprises dried cardability, wet cardability test, described wet cardability test is: at first with the hair moistening, rub and wash 2-3min with 2g example I-XV (blank sample with 3% sodium laurylsulfate), rinse well with flowing water then, with the comb combing once to remove redundant moisture, measure wet cardability on Instron 2343 miniature spring testers, rate of extension is 300mm/min; Repeat above-mentioned steps, each sample determination 6 times, the measurement result after the 6th flushing of each embodiment is listed in table 2.
Described dried cardability test is: after wet cardability test is finished hair sample is placed on air drying, treats to measure its dried cardability after its drying.The dried cardability test result of each embodiment is listed in table 2.
Table 2 shampoo composite cardability test result
Claims (11)
1. one kind is nourished and anti-dandruff shampoo composition, being characterised in that it removes comprises: (A) be applicable to the anion surfactant that accounts for composition weight 5.0% to 30% in the shampoo composite, account for the amphoteric surfactant of composition weight 1.5% to 8.0%, account for the thickening agent and the conditioner that accounts for composition weight 2.0% to 10% of composition weight 0.5% to 5.0%; Also contain (B) and account for anti-dandruff dose of composition weight 0.2% to 8.0%; Wherein said anti-dandruff dose is the compositions of pyrithione and two pyrithione, and both ratios are 1: 100 to 2: 3; (C) account for the nourishing additive agent of composition weight 0.5% to 5.0%, described nourishing additive agent is selected from vitamin E, provitamin B
5, at least a in the hydrolyzed protein, plant extraction liquid; Reaching (D), surplus is a water.
2. shampoo composite according to claim 1, wherein said anion surfactant is selected from Laurel alkyl ammonium sulfate or polyoxyethylene lauryl ether ammonium sulfate, described amphoteric surfactant is a cocamido propyl betaine, and described thickening agent is the phthalic acid amide.
3. according to the described shampoo composite of aforementioned each claim, wherein said conditioner is selected from, at least a in cationic cellulose polymer, cation melon glue, the emulsified silicone oil.
4. according to the described shampoo composite of aforementioned each claim, wherein said anti-dandruff dose is the compositions of pyrithione and two pyrithione, and described pyrithione is selected from least a in Zinc Pyrithione, pyrithione sodium, the copper pyrithione.
5. shampoo composite according to claim 4, wherein said anti-dandruff dose is Zinc Pyrithione and two pyrithione compositionss, the ratio of Zinc Pyrithione and two pyrithione 1: 50 to 1: 2.
6. shampoo composite according to claim 4, wherein said pair of pyrithione satisfies structural formula (I), and the mean diameter of wherein said pair of pyrithione is at most 20 μ m, and the particulate mean diameter of Zinc Pyrithione is at most 10 μ m
7. require 6 described shampoo composites according to power, the mean diameter of wherein two pyrithione and Zinc Pyrithione is at most 5 μ m.
8. according to the described shampoo composite of aforementioned each claim, wherein nourishing additive agent is selected from vitamin E, provitamin B
5, at least a in 200 to 10000 hydrolyzed protein, Radix Ginseng extractive solution, Aloe extraction solution, Sucus Zingberis extracting solution of molecular weight.
9. according to the described shampoo composite of aforementioned each claim, it is characterized in that said composition also comprises the INCROQUAT TMC-80 ECONOL TM22 that accounts for composition weight 0.25% to 8.0%.
10. shampoo composite according to claim 9, wherein INCROQUAT TMC-80 ECONOL TM22 accounts for 0.5% to 5.0% of composition weight.
11. shampoo composite according to claim 1 is characterised in that it comprises: (A) be applicable to the anion surfactant that accounts for composition weight 10% to 25% in the shampoo composite, account for composition weight 2.0% to 6.0% amphoteric surfactant, account for the thickening agent of composition weight 1.0% to 4.0% and account for the conditioner of composition weight 3.0% to 8.0%; Also contain (B) and account for anti-dandruff dose of composition weight 0.5% to 5.0%; Wherein said anti-dandruff dose is the compositions of pyrithione and two pyrithione, and both ratios are 1: 50 to 1: 2; (C) account for the nourishing additive agent of composition weight 0.8% to 3.0%, described nourishing additive agent is selected from least a in 200 to 10000 hydrolyzed protein, Radix Ginseng extractive solution, Aloe extraction solution, Sucus Zingberis extracting solution of provitamin B5, molecular weight; Reaching (D), surplus is a water.
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