CN101173360A - Stainless steel etching technique - Google Patents
Stainless steel etching technique Download PDFInfo
- Publication number
- CN101173360A CN101173360A CNA2006101231850A CN200610123185A CN101173360A CN 101173360 A CN101173360 A CN 101173360A CN A2006101231850 A CNA2006101231850 A CN A2006101231850A CN 200610123185 A CN200610123185 A CN 200610123185A CN 101173360 A CN101173360 A CN 101173360A
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- Prior art keywords
- stainless steel
- etching
- etching solution
- piece
- processing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 238000005530 etching Methods 0.000 title claims abstract description 50
- 229910001220 stainless steel Inorganic materials 0.000 title claims abstract description 40
- 239000010935 stainless steel Substances 0.000 title claims abstract description 40
- 238000000034 method Methods 0.000 title claims abstract description 13
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000004140 cleaning Methods 0.000 claims abstract description 8
- MIMUSZHMZBJBPO-UHFFFAOYSA-N 6-methoxy-8-nitroquinoline Chemical compound N1=CC=CC2=CC(OC)=CC([N+]([O-])=O)=C21 MIMUSZHMZBJBPO-UHFFFAOYSA-N 0.000 claims abstract description 6
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims abstract description 6
- 239000002184 metal Substances 0.000 claims abstract description 5
- 229910052751 metal Inorganic materials 0.000 claims abstract description 5
- 239000011248 coating agent Substances 0.000 claims abstract description 3
- 238000000576 coating method Methods 0.000 claims abstract description 3
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 12
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 10
- 229920002120 photoresistant polymer Polymers 0.000 claims description 10
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical group ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 claims description 5
- 239000012528 membrane Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 230000003628 erosive effect Effects 0.000 claims description 4
- 230000004913 activation Effects 0.000 claims description 3
- 238000005238 degreasing Methods 0.000 claims description 2
- 239000006166 lysate Substances 0.000 claims description 2
- 238000002203 pretreatment Methods 0.000 claims description 2
- 239000003292 glue Substances 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000007781 pre-processing Methods 0.000 abstract 1
- 230000001172 regenerating effect Effects 0.000 abstract 1
- 150000003585 thioureas Chemical class 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000003637 basic solution Substances 0.000 description 3
- 238000007598 dipping method Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000010129 solution processing Methods 0.000 description 1
Landscapes
- ing And Chemical Polishing (AREA)
Abstract
The invention provides an etching process for stainless steel, which comprises a plurality of steps: a. pre-processing, used to do surface cleaning operations like cleaning and deoiling of the initial stainless steel workpiece; b. coating, in which the surface of the stainless steel is applied with photosensitive glue, and the operations of exposure, development and hardening are conducted; c. etching, in which stainless steel etching solution is used to erode the exposed metal part of the stainless steel workpiece; wherein, the stainless steel etching solution is mainly composed of: ferric trichloride 400 to 600 g/L, hydrochloric acid 2 to 5 g/L, ammonium bifluoride 1 to 2 g/L, thioureas 2.5 to 5 g/L, etching promoter 1 to 5 g/L and regenerator 2 to 5 g/L; d. demoulding, when the etching is done to a certain extent, the remaining glue on the surface of the workpiece can be removed by means of dissolving liquid, and thus the intended product can be obtained after cleaning. The invention has the advantages of good etching speed, high precision, regenerating capacity of the etching solution, simple manufacturing process and broad market prospect.
Description
Technical field
The present invention relates to a kind of metal surface treatment process, particularly relate to a kind of surface treatment technique for stainless steel.
Background technology
Stainless steel has hardness height, wear-resisting, good stability, shock-resistant characteristic such as strong, and the product that stainless steel obtains through etching does not have the rim stress of machinery processing, obtained using widely, particularly aspect ornamental label and shell, used wider at aspects such as national defence, electronics, electrical equipment.But,, limited the application of stainless steel etching and processing product because stainless high rigidity and high stability do not react or react too slow with strong acid and strong base.
Summary of the invention
In view of above problem, main purpose of the present invention is to provide a kind of stainless steel etching solution, and this solution processing procedure is simple, and etching speed is fast.
For achieving the above object, stainless steel etching solution provided by the invention, it mainly comprises following component:
Iron trichloride 400～600g/L;
Hydrochloric acid 2～5g/L;
Ammonium bifluoride 1～2g/L;
Thiocarbamide 2.5～5g/L;
Etching promotor 1～5g/L;
Regenerator 2～5g/L.
Wherein, described etching promotor is preferably hydrogen peroxide; Described regenerator is preferably hypochlorous acid; Described thiocarbamide is as inhibiter and anti-lateral erosion agent.
In addition, another object of the present invention then is to provide a kind of stainless steel etching technique, and its technology is simple, and is easy to operate.
Chemical milling is to utilize the corrosive nature of chemical solution that unwanted metal is dissolved the process of removing fast by chemical reaction.
This kind stainless steel etching technique provided by the invention, its step is as follows substantially:
1. pre-treatment, it mainly comprises steps such as degreasing, activation, it is in order to clean initial stainless steel work-piece, to remove the wet goods cleaning surfaces;
2. coating, this step can comprise steps such as making luxuriant and rich with fragrance continuous heavy rain, exposure imaging, making web plate, silk-screen, and, carry out the exposure of photoresists according to the processing pattern more normally with its surface-coated photoresists of the stainless steel work-piece after the above-mentioned processing, then develop and the post bake processing;
3. etching, the exposing metal position that utilizes the stainless steel etching solution of above-mentioned preparation to corrode this stainless steel work-piece;
4. demoulding is treated above-mentioned eroding to a certain degree, its surperficial remaining glued membrane is removed with lysate again, and last water cleans up and obtains etching and processing workpiece product.
Therefore, stainless steel etching technique provided by the invention merges stainless activation and etching and carries out, make technology become simpler, in addition, in the stainless steel etching solution, add etching promotor, to accelerate etching speed, cooperate again simultaneously and add suitable inhibiter and anti-lateral erosion agent, improve precision, add regenerator again, make this etching solution repeatedly to use.Thus, it is fast that this technology has etching speed, the precision height, and characteristics such as etching solution is renewable, and processing procedure is simple are with a wide range of applications.
Embodiment
Embodiment 1
At first according to following formulated stainless steel etching solution:
Iron trichloride 400g/L;
Hydrochloric acid 4g/L;
Ammonium bifluoride 2g/L;
Thiocarbamide 3g/L;
Hydrogen peroxide 3.5g/L;
Hypochlorous acid 5g/L.
Select a stainless steel work-piece sample to clean then, remove the wet goods cleaning surfaces, and then at its surface-coated photoresists, carry out the exposure of photoresists according to the processing pattern again, then develop and the post bake processing, then this sample be impregnated in the stainless steel etching solution of above-mentioned preparation after handling, the etching reaction temperature is controlled to be 25 ℃, dipping time is 5 minutes, after the time, remove with basic solution with this sample taking-up and with its surperficial remaining glued membrane, last water cleans up and obtains product, resulting product etch effect obviously and accurately, etch depth reaches 0.15 millimeter.
Embodiment 2
At first according to following formulated stainless steel etching solution:
Iron trichloride 500g/L;
Hydrochloric acid 3g/L;
Ammonium bifluoride 1.5g/L;
Thiocarbamide 4g/L;
Hydrogen peroxide 5g/L;
Hypochlorous acid 5g/L.
Select a stainless steel work-piece sample to clean then, remove the wet goods cleaning surfaces, and then at its surface-coated photoresists, carry out the exposure of photoresists according to the processing pattern again, then develop and the post bake processing, then this sample be impregnated in the stainless steel etching solution of above-mentioned preparation after handling, the etching reaction temperature is controlled to be 25 ℃, dipping time is 4 minutes, after the time, remove with basic solution with this sample taking-up and with its surperficial remaining glued membrane, last water cleans up and obtains product, resulting product etch effect obviously and accurately, etch depth reaches 0.10 millimeter.
Embodiment 3
At first according to following formulated stainless steel etching solution:
Iron trichloride 600g/L;
Hydrochloric acid 3g/L;
Ammonium bifluoride 2g/L;
Thiocarbamide 5g/L;
Hydrogen peroxide 3g/L;
Hypochlorous acid 5g/L.
Select a stainless steel work-piece sample to clean then, remove the wet goods cleaning surfaces, and then at its surface-coated photoresists, carry out the exposure of photoresists according to the processing pattern again, then develop and the post bake processing, then this sample be impregnated in the stainless steel etching solution of above-mentioned preparation after handling, the etching reaction temperature is controlled to be 25 ℃, dipping time is 4 minutes, after the time, remove with basic solution with this sample taking-up and with its surperficial remaining glued membrane, last water cleans up and obtains product, resulting product etch effect obviously and accurately, etch depth reaches 0.13 millimeter.
Therefore, stainless steel etching technique provided by the invention, its etching speed can reach 0.02～0.04 mm/min.
Above embodiment is the detailed description that the present invention is done.Notice that these embodiments are not in order to limit the present invention, for those skilled in the art, the improvement of being made and additional should be considered as within protection scope of the present invention without departing from the spirit of the invention.
Claims (4)
1. a stainless steel etching solution is characterized in that, mainly comprises following component:
Iron trichloride 400～600g/L;
Hydrochloric acid 2～5g/L;
Ammonium bifluoride 1～2g/L;
Thiocarbamide 2.5～5g/L;
Etching promotor 1～5g/L;
Regenerator 2～5g/L.
2. a kind of stainless steel etching solution according to claim 1 is characterized in that described etching promotor is preferably hydrogen peroxide.
3. a kind of stainless steel etching solution according to claim 1 is characterized in that described regenerator is preferably hypochlorous acid..
4. a stainless steel etching technique is characterized in that, key step is as follows substantially:
A. pre-treatment, it mainly comprises steps such as degreasing, activation, it is in order to clean initial stainless steel work-piece, to remove the wet goods cleaning surfaces;
B. coating, and then, carry out the exposure of photoresists according to the processing pattern again with its surface-coated photoresists of this stainless steel work-piece, then develop and the post bake processing;
C. etching utilizes any exposing metal position that described stainless steel etching solution corrodes this stainless steel work-piece of claim 1-3;
D. demoulding is treated above-mentioned eroding to a certain degree, its surperficial remaining glued membrane is removed with lysate again, and last water cleans up and obtains etching and processing workpiece product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610123185A CN100582306C (en) | 2006-10-31 | 2006-10-31 | Stainless steel etching technique |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610123185A CN100582306C (en) | 2006-10-31 | 2006-10-31 | Stainless steel etching technique |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101173360A true CN101173360A (en) | 2008-05-07 |
| CN100582306C CN100582306C (en) | 2010-01-20 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200610123185A Expired - Fee Related CN100582306C (en) | 2006-10-31 | 2006-10-31 | Stainless steel etching technique |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100582306C (en) |
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101914776A (en) * | 2010-07-16 | 2010-12-15 | 上海希尔彩印制版有限公司 | Chromic acid-free environmental-friendly type surface opening liquid for laser engraving etching plate |
| CN102108512A (en) * | 2009-12-25 | 2011-06-29 | 比亚迪股份有限公司 | Chemical etching liquid for metals and etching method |
| CN102174699A (en) * | 2010-09-07 | 2011-09-07 | 沈阳东北大学冶金技术研究所有限公司 | Dendritic crystal corrosion macroscopic examination reagent for solidification structures and defects of continuous cast blank and preparation method thereof |
| CN102199762A (en) * | 2010-03-26 | 2011-09-28 | 宝山钢铁股份有限公司 | Method for increasing hardness and abrasion resistance of surface of iron and steel material |
| CN102234810A (en) * | 2010-04-20 | 2011-11-09 | 深圳富泰宏精密工业有限公司 | Cleaning agent for etched stainless steel and using method thereof |
| CN102383131A (en) * | 2011-11-03 | 2012-03-21 | 模德模具(东莞)有限公司 | Formula for corrosive medicinal liquid used for high hardness die steel and preparation method for same |
| CN102680380A (en) * | 2011-03-10 | 2012-09-19 | 宝山钢铁股份有限公司 | Method for quickly detecting corrosion resistance of stainless steel BA (bright annealed) plate |
| CN102897096A (en) * | 2012-10-26 | 2013-01-30 | 丹阳市国美汽配有限公司 | Manufacture method for ushering pedal identification with stainless steel bright strip |
| CN103194755A (en) * | 2013-04-15 | 2013-07-10 | 昆山市板明电子科技有限公司 | Selective iron etching solution and etching method |
| CN103397329A (en) * | 2013-07-08 | 2013-11-20 | 裘华见 | Production technology for stainless steel dot matrix friction plate |
| CN104233300A (en) * | 2013-06-21 | 2014-12-24 | 镇江江城金属制品有限公司 | Etching method of stainless steel markplates |
| CN105039987A (en) * | 2015-08-18 | 2015-11-11 | 广东富行洗涤剂科技有限公司 | Stainless steel etching solution composition |
| CN105274534A (en) * | 2014-06-25 | 2016-01-27 | 日照旭日电子有限公司 | Surface pretreatment process for Kovar alloy |
| CN105506630A (en) * | 2016-02-06 | 2016-04-20 | 温州佳凯实业有限公司 | Stainless steel tray etching method |
| CN107039658A (en) * | 2017-03-08 | 2017-08-11 | 同济大学 | A kind of method of low cost batch production metal polar plate |
| CN107815686A (en) * | 2017-11-03 | 2018-03-20 | 安徽新合富力科技有限公司 | A kind of stainless steel nano method for treating |
| CN108611639A (en) * | 2018-07-10 | 2018-10-02 | 昆山迪卡特精密电子有限公司 | Steel disc etch passivation surface treatment |
| CN108754497A (en) * | 2018-07-02 | 2018-11-06 | 景瓷精密零部件（桐乡）有限公司 | A kind of the etching formula of liquid and production method of Molybdenum grid product |
| CN108760419A (en) * | 2018-04-09 | 2018-11-06 | 东北大学 | A kind of cold acid corrosion reagent and its preparation and application of high nitrogen Retaining Ring Steel |
| CN110144589A (en) * | 2018-02-11 | 2019-08-20 | 扬昕科技(苏州)有限公司 | The manufacturing method of stainless steel etching solution and the light-conducting board mold element using it |
| CN111607794A (en) * | 2020-06-17 | 2020-09-01 | 宁波福至新材料有限公司 | Method for improving etching quality of metal product |
| CN115896786A (en) * | 2022-10-17 | 2023-04-04 | 湖北兴福电子材料股份有限公司 | A stainless steel etchant |
-
2006
- 2006-10-31 CN CN200610123185A patent/CN100582306C/en not_active Expired - Fee Related
Cited By (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102108512A (en) * | 2009-12-25 | 2011-06-29 | 比亚迪股份有限公司 | Chemical etching liquid for metals and etching method |
| CN102108512B (en) * | 2009-12-25 | 2013-09-18 | 比亚迪股份有限公司 | Chemical etching liquid for metals and etching method |
| CN102199762A (en) * | 2010-03-26 | 2011-09-28 | 宝山钢铁股份有限公司 | Method for increasing hardness and abrasion resistance of surface of iron and steel material |
| CN102199762B (en) * | 2010-03-26 | 2012-12-12 | 宝山钢铁股份有限公司 | Method for increasing hardness and abrasion resistance of surface of iron and steel material |
| CN102234810A (en) * | 2010-04-20 | 2011-11-09 | 深圳富泰宏精密工业有限公司 | Cleaning agent for etched stainless steel and using method thereof |
| CN101914776A (en) * | 2010-07-16 | 2010-12-15 | 上海希尔彩印制版有限公司 | Chromic acid-free environmental-friendly type surface opening liquid for laser engraving etching plate |
| CN101914776B (en) * | 2010-07-16 | 2011-07-06 | 上海希尔彩印制版有限公司 | Laser cutting corroding platemaking surface opening liquid and usage thereof |
| CN102174699A (en) * | 2010-09-07 | 2011-09-07 | 沈阳东北大学冶金技术研究所有限公司 | Dendritic crystal corrosion macroscopic examination reagent for solidification structures and defects of continuous cast blank and preparation method thereof |
| CN102680380B (en) * | 2011-03-10 | 2014-07-09 | 宝山钢铁股份有限公司 | Method for quickly detecting corrosion resistance of stainless steel BA (bright annealed) plate |
| CN102680380A (en) * | 2011-03-10 | 2012-09-19 | 宝山钢铁股份有限公司 | Method for quickly detecting corrosion resistance of stainless steel BA (bright annealed) plate |
| CN102383131A (en) * | 2011-11-03 | 2012-03-21 | 模德模具(东莞)有限公司 | Formula for corrosive medicinal liquid used for high hardness die steel and preparation method for same |
| CN102897096A (en) * | 2012-10-26 | 2013-01-30 | 丹阳市国美汽配有限公司 | Manufacture method for ushering pedal identification with stainless steel bright strip |
| CN102897096B (en) * | 2012-10-26 | 2014-09-03 | 丹阳市国美汽配有限公司 | Manufacture method for ushering pedal identification with stainless steel bright strip |
| CN103194755B (en) * | 2013-04-15 | 2015-03-25 | 昆山市板明电子科技有限公司 | Selective iron etching solution and etching method |
| CN103194755A (en) * | 2013-04-15 | 2013-07-10 | 昆山市板明电子科技有限公司 | Selective iron etching solution and etching method |
| CN104233300A (en) * | 2013-06-21 | 2014-12-24 | 镇江江城金属制品有限公司 | Etching method of stainless steel markplates |
| CN103397329A (en) * | 2013-07-08 | 2013-11-20 | 裘华见 | Production technology for stainless steel dot matrix friction plate |
| CN103397329B (en) * | 2013-07-08 | 2015-11-25 | 浙江工业职业技术学院 | A kind of production technique of stainless steel dot matrix friction plate |
| CN105274534A (en) * | 2014-06-25 | 2016-01-27 | 日照旭日电子有限公司 | Surface pretreatment process for Kovar alloy |
| CN105274534B (en) * | 2014-06-25 | 2018-05-15 | 日照旭日电子有限公司 | A kind of kovar alloy surface pre-treating process |
| CN105039987A (en) * | 2015-08-18 | 2015-11-11 | 广东富行洗涤剂科技有限公司 | Stainless steel etching solution composition |
| CN105506630B (en) * | 2016-02-06 | 2017-10-24 | 温州佳凯实业有限公司 | A kind of engraving method of stainless steel pallet |
| CN105506630A (en) * | 2016-02-06 | 2016-04-20 | 温州佳凯实业有限公司 | Stainless steel tray etching method |
| CN107039658A (en) * | 2017-03-08 | 2017-08-11 | 同济大学 | A kind of method of low cost batch production metal polar plate |
| CN107039658B (en) * | 2017-03-08 | 2020-07-28 | 同济大学 | A low-cost method for mass production of metal plates |
| CN107815686A (en) * | 2017-11-03 | 2018-03-20 | 安徽新合富力科技有限公司 | A kind of stainless steel nano method for treating |
| CN110144589A (en) * | 2018-02-11 | 2019-08-20 | 扬昕科技(苏州)有限公司 | The manufacturing method of stainless steel etching solution and the light-conducting board mold element using it |
| CN108760419A (en) * | 2018-04-09 | 2018-11-06 | 东北大学 | A kind of cold acid corrosion reagent and its preparation and application of high nitrogen Retaining Ring Steel |
| CN108754497A (en) * | 2018-07-02 | 2018-11-06 | 景瓷精密零部件（桐乡）有限公司 | A kind of the etching formula of liquid and production method of Molybdenum grid product |
| CN108611639A (en) * | 2018-07-10 | 2018-10-02 | 昆山迪卡特精密电子有限公司 | Steel disc etch passivation surface treatment |
| CN111607794A (en) * | 2020-06-17 | 2020-09-01 | 宁波福至新材料有限公司 | Method for improving etching quality of metal product |
| CN111607794B (en) * | 2020-06-17 | 2022-05-27 | 宁波福至新材料有限公司 | Method for improving etching quality of metal product |
| CN115896786A (en) * | 2022-10-17 | 2023-04-04 | 湖北兴福电子材料股份有限公司 | A stainless steel etchant |
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| Publication number | Publication date |
|---|---|
| CN100582306C (en) | 2010-01-20 |
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