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CN100576553C - Solid-state imaging device and manufacturing method thereof - Google Patents

Solid-state imaging device and manufacturing method thereof Download PDF

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Publication number
CN100576553C
CN100576553C CN200610071648A CN200610071648A CN100576553C CN 100576553 C CN100576553 C CN 100576553C CN 200610071648 A CN200610071648 A CN 200610071648A CN 200610071648 A CN200610071648 A CN 200610071648A CN 100576553 C CN100576553 C CN 100576553C
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resin
mentioned
solid
hardening resin
state imaging
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CN1838422A (en
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佐藤知广
前田光男
吉田贺英
井手淳一
小西正芳
松见泰夫
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Toshiba Corp
Sumitomo Chemical Co Ltd
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Sumitomo Chemical Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/4805Shape
    • H01L2224/4809Loop shape
    • H01L2224/48091Arched
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/481Disposition
    • H01L2224/48151Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/48221Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/48245Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic
    • H01L2224/48247Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic connecting the wire to a bond pad of the item
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/73Means for bonding being of different types provided for in two or more of groups H01L2224/10, H01L2224/18, H01L2224/26, H01L2224/34, H01L2224/42, H01L2224/50, H01L2224/63, H01L2224/71
    • H01L2224/732Location after the connecting process
    • H01L2224/73251Location after the connecting process on different surfaces
    • H01L2224/73265Layer and wire connectors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/80Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected
    • H01L2224/85Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a wire connector
    • H01L2224/85909Post-treatment of the connector or wire bonding area
    • H01L2224/8592Applying permanent coating, e.g. protective coating
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/15Details of package parts other than the semiconductor or other solid state devices to be connected
    • H01L2924/161Cap
    • H01L2924/1615Shape
    • H01L2924/16195Flat cap [not enclosing an internal cavity]

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  • Solid State Image Pick-Up Elements (AREA)

Abstract

Certain 1 position at the junction surface of the boundary portion of inner surface portion, metallic conductor terminal and the hollow case inner surface of hollow case and hollow case and transparent panel, the configuration hardening resin forms the hardening resin after the constituent sclerosis, and the duro-meter hardness of hardening resin is below 80 in the A level.

Description

固体摄像装置及其制造方法 Solid-state imaging device and manufacturing method thereof

技术领域 technical field

本发明涉及固体摄像装置及其制造方法。The present invention relates to a solid-state imaging device and a manufacturing method thereof.

背景技术 Background technique

现在,在固体摄像装置上是使用中空的玻璃·陶瓷型盒子,但由于成本高,所以最近正开发树脂制中空盒子(参照专利文献1)。At present, a hollow glass-ceramic type case is used for a solid-state imaging device, but since the cost is high, a resin-made hollow case is recently being developed (see Patent Document 1).

但是,使用树脂中空制盒子的固体摄像装置在实用化上还有些问题。However, a solid-state imaging device using a resin hollow case still has some problems in practical use.

例如,经常在盒子成形时产生树脂溶液溢出金属模的缝脊,即所谓溢料,该溢料在固体摄像装置的制造时变成粉屑,即使利用清洗工序也难以完全除去。结果,封闭该树脂中空制盒子后粉屑在盒子内飞散,附着在固体摄像元件的受光面上,往往引起摄像元件的误动作。For example, ridges where the resin solution overflows the metal mold often occur during box molding, so-called flash. This flash becomes dust during the manufacture of the solid-state imaging device, and it is difficult to completely remove it even through a cleaning process. As a result, after the resin hollow case is closed, powder dust is scattered in the case and adheres to the light-receiving surface of the solid-state imaging device, often causing malfunction of the imaging device.

又,作为封闭树脂制中空盒子的盖材,主要使用透明玻璃、透明树脂等透明板,但由于形成盒子的树脂与形成盖材的金属或玻璃等的热膨胀差大,所以使通常因成形时或安装时的热引起的盒子的翘曲等变形增大。当存在这样的变形时,往往在入射光的焦点上发生偏差,存在固体摄像元件不正确读取影像等问题。为了防止上述那样的变形,对于将盖材贴在盒子上时使用的粘接剂,提出使用弹性率在5GPa以下的产品(参照专利文献2)。但是其效果不够好,特别是一维图像传感器那样的长方形的盒子时,依然容易发生翘曲。Also, as the lid material of the closed resin hollow box, transparent plates such as transparent glass and transparent resin are mainly used, but since the thermal expansion difference between the resin forming the box and the metal or glass forming the lid material is large, it is usually caused by molding or Distortion such as warping of the case due to heat during mounting increases. When such deformation exists, the focus of incident light may deviate, causing problems such as incorrect image reading by the solid-state imaging device. In order to prevent the above-mentioned deformation, it is proposed to use an adhesive having an elastic modulus of 5 GPa or less for the adhesive used when attaching the cover material to the box (see Patent Document 2). But its effect is not good enough, especially for a rectangular box like a one-dimensional image sensor, it is still prone to warping.

因此,固体摄像装置存在不能正确发挥功能的问题。Therefore, there is a problem that the solid-state imaging device cannot function correctly.

专利文献1:特开平6-163950号公报Patent Document 1: Japanese Unexamined Patent Publication No. 6-163950

专利文献2:特开2000-12719号公报Patent Document 2: JP-A-2000-12719

发明内容 Contents of the invention

本发明是鉴于上述情况作出的,目的在于提供:可防止因树脂制中空盒子的成形过程中产生的溢料等导致的粉屑引起的固体摄像元件的误动作,并且在改良中空盒子的气密性方面或者改良树脂制中空盒子自身的翘曲方面至少实现一个,可正确发挥摄像功能的固体摄像装置及其制造方法。The present invention has been made in view of the above-mentioned circumstances, and its object is to provide: the malfunction of the solid-state imaging element caused by the powder dust caused by the flash etc. generated during the molding process of the resin hollow case can be prevented, and the airtightness of the hollow case can be improved. A solid-state imaging device and a manufacturing method thereof that realize at least one of the properties and the warpage of the resin-made hollow box itself and can correctly perform the imaging function.

本发明者们深入研究的结果,发现通过利用热可塑性树脂成形上述树脂制中空盒子,且在盒子的特定部位具有使用了硬化性树脂的树脂,可解决上述课题的至少一个,从而完成了本发明。即,本发明提供下述[1]所示的固体摄像装置。As a result of intensive research, the present inventors have found that at least one of the above-mentioned problems can be solved by molding the above-mentioned resin-made hollow box with a thermoplastic resin, and having a resin using a hardening resin in a specific part of the box, and completed the present invention. . That is, the present invention provides a solid-state imaging device described in the following [1].

[1]一种固体摄像装置,具有由大致矩形的树脂制底板和大致垂设在其周缘上的树脂制侧壁一体形成,并插设金属制导线端子,开口部被透明板封闭的热可塑性树脂制中空盒子,在该中空盒子的内底面上设置有金属制岛,在该岛上粘固有固体摄像元件,其特征在于:在[1] A solid-state imaging device that is integrally formed with a substantially rectangular resin base plate and a resin side wall approximately vertically placed on its peripheral edge, and inserted with metal lead terminals, the opening is closed by a transparent plate. The resin hollow box is provided with a metal island on the inner bottom surface of the hollow box, and a solid-state imaging element is glued on the island, and it is characterized in that:

(a)上述中空盒子的内表面部、(a) the inner surface of the above-mentioned hollow box,

(b)上述金属制导线端子与上述中空盒子内表面的分界部、以及(b) The boundary between the above-mentioned metal lead terminal and the inner surface of the above-mentioned hollow box, and

(c)上述中空盒子与上述透明板的接合部的至少1个部位上,配置硬化树脂形成组成物硬化后的硬化树脂,前述硬化树脂的小型携带式硬度计硬度在A级中是80以下。(c) At least one part of the junction between the hollow case and the transparent plate is provided with a hardened resin formed by hardening the hardened resin composition, and the hardened resin has a small portable durometer hardness of 80 or less in the A class.

又,[2]硬化树脂优选包含从环氧树脂、不饱和聚酯树脂、酚醛树脂、尿素-三聚氰胺树脂、聚氨脂树脂、硅酮树脂、聚酰亚胺树脂以及丙烯酸树脂群中选出的至少1种。In addition, [2] the hardening resin preferably includes epoxy resins, unsaturated polyester resins, phenolic resins, urea-melamine resins, polyurethane resins, silicone resins, polyimide resins, and acrylic resins. At least 1 species.

又,本发明关于设有固体摄像元件的金属制岛以及中空盒子内底面,提供下述[3][4]所示的固体摄像装置。Furthermore, the present invention provides the solid-state imaging device shown in the following [3][4] with respect to the metal island provided with the solid-state imaging element and the inner bottom surface of the hollow box.

[3]是如上述[1]或[2]所述的固体摄像装置,其特征在于:在上述金属制岛上沿着上述固体摄像元件的纵向设置突堤部。[3] The solid-state imaging device according to the above [1] or [2], wherein a dike portion is provided on the metal island along a longitudinal direction of the solid-state imaging element.

[4]是如上述[1]~[3]任何一项所述的固体摄像装置,其特征在于:接近上述金属制岛的侧面,在上述盒子的内底面上,沿着其纵向配设有槽。[4] The solid-state imaging device according to any one of the above [1] to [3], characterized in that: on the inner bottom surface of the above-mentioned case, a side surface close to the above-mentioned metal island is arranged along the longitudinal direction thereof. groove.

并且,本发明在上述硬化树脂形成组成物是下述的[5]时制造上更简便,优选。In addition, in the present invention, it is more convenient and preferable in terms of production when the above-mentioned curable resin-forming composition is the following [5].

[5]是如上述[1]~[4]任何一项所述的固体摄像装置,其特征在于:该硬化树脂组成物包含紫外线硬化性树脂。[5] The solid-state imaging device according to any one of [1] to [4] above, wherein the curable resin composition contains an ultraviolet curable resin.

又,本发明提供上述固体摄像装置的下述制造方法。Furthermore, the present invention provides the following method of manufacturing the above-mentioned solid-state imaging device.

[6]是一种固体摄像元件的制造方法,按以下顺序设有,[6] is a method of manufacturing a solid-state imaging device, provided in the following order,

(I)成形由大致矩形的树脂制底板以及大致垂设在该底板周缘上的树脂制侧壁一体形成,并插设金属制导线端子,且开口部可被透明板封闭的热可塑性树脂制中空盒子的工序;(I) Forming is integrally formed by a substantially rectangular resin base plate and a resin side wall approximately vertically placed on the periphery of the base plate, and inserts a metal lead terminal, and a thermoplastic resin hollow that can be closed by a transparent plate at the opening. box process;

(II)在该盒子的内底面上粘固固体摄像元件的工序;(II) the process of cementing the solid-state imaging element on the inner bottom surface of the box;

(III)利用接合线电气连接该固体摄像元件的电极与该金属制导线端子的工序;(III) A step of electrically connecting the electrode of the solid-state imaging element and the metal lead terminal with a bonding wire;

(IV)由透明板封闭该盒子开口部的工序;(IV) The process of closing the opening of the box with a transparent plate;

其特征在于,具有以下工序中选出的至少一个工序:It is characterized in that it has at least one process selected from the following processes:

(i)通过在该盒子内表面赋予硬化树脂形成组成物A并使其硬化形成硬化树脂A,从而利用硬化树脂覆盖该盒子内表面的至少一部分以及/或该盒子内的该导线端子与该盒子内表面的分界部的工序,以及(i) Forming the composition A by applying a hardening resin to the inner surface of the case and hardening it to form the hardening resin A, thereby covering at least a part of the inner surface of the case and/or the lead terminal and the case in the case with the hardening resin the process of the boundary portion of the inner surface, and

(ii)在该盒子的开口部的与该透明板接触的部位赋予硬化树脂组成物B,并利用透明板封闭该开口部后,利用该硬化树脂组成物B硬化后的硬化树脂B封死该开口部的工序。(ii) Apply cured resin composition B to the portion of the opening of the box that is in contact with the transparent plate, and after closing the opening with a transparent plate, seal the opening with cured resin B cured from the cured resin composition B. The process of the opening.

但下述的硬化树脂形成组成物A与硬化树脂组成物B可以一样也可不一样。However, the following curable resin composition A and curable resin composition B may be the same or different.

上述[6]的制造方法中的硬化树脂形成组成物A优选下述[7]~[9]所述的任何一种。The curable resin-forming composition A in the production method of the above [6] is preferably any one of the following [7] to [9].

[7]是如上述[6]所述的固体摄像装置的制造方法,其特征在于:上述硬化树脂形成组成物A的粘度在5000mPa·sec以下。[7] The method for manufacturing a solid-state imaging device according to [6] above, wherein the viscosity of the cured resin-forming composition A is 5000 mPa·sec or less.

[8]是如上述[6]或[7]所述的固体摄像装置的制造方法,其特征在于:伴随上述硬化树脂形成组成物A的硬化的体积收缩率在5%以下。[8] The method for manufacturing a solid-state imaging device according to [6] or [7] above, wherein the volume shrinkage rate accompanying the curing of the cured resin forming composition A is 5% or less.

[9]是如上述[6]~[8]任何一项所述的固体摄像装置的制造方法,其特征在于:上述硬化树脂形成组成物A是紫外线硬化性的。[9] The method for manufacturing a solid-state imaging device according to any one of [6] to [8] above, wherein the curable resin forming composition A is ultraviolet curable.

上述[9]所示的硬化树脂形成组成物A是紫外线硬化性的时,其中也优选下述的制造方法。When the curable resin-forming composition A shown in the above [9] is ultraviolet curable, the following production method is also preferable among them.

[10]是如上述[9]任何一项所述的固体摄像装置的制造方法,其特征在于:在上述硬化树脂形成组成物A上照射紫外线,形成硬化树脂A时,该硬化树脂A的重量是硬化前的硬化树脂形成组成物A的重量的99.8%以上、100%以下。[10] The method for manufacturing a solid-state imaging device according to any one of the above [9], wherein when the cured resin forming composition A is irradiated with ultraviolet rays to form the cured resin A, the weight of the cured resin A It is 99.8% or more and 100% or less of the weight of the cured resin forming composition A before curing.

[11]是如上述[9]或[10]所述的固体摄像装置的制造方法,其特征在于:上述工序(i)是,在上述中空盒子内表面上赋予紫外线硬化性的硬化树脂形成组成物A,通过封死的透明板照射紫外线使该树脂形成组成物A成为硬化树脂A,从而利用硬化树脂覆盖该中空盒子内表面的至少一部分以及/或该盒子内的金属制导线端子与树脂部分的分界部分的工序。[11] The method for manufacturing a solid-state imaging device according to [9] or [10] above, wherein the step (i) is formed by forming a curable resin that imparts ultraviolet curability on the inner surface of the hollow case. Object A, irradiating ultraviolet rays through a sealed transparent plate to make the resin forming composition A a hardened resin A, thereby covering at least a part of the inner surface of the hollow box and/or the metal wire terminal and the resin part in the box with the hardened resin The process of the boundary part.

另一方面,上述[6]的制造方法中的硬化树脂形成组成物B优选下述[12]~[13]所述的任何一种。On the other hand, the curable resin-forming composition B in the production method of the above [6] is preferably any one of the following [12] to [13].

[12]是如上述[6]任何一项所述的固体摄像装置的制造方法,其特征在于:上述硬化性树脂形成组成物B的粘度在10000mPa·sec以上。[12] The method for manufacturing a solid-state imaging device according to any one of [6] above, wherein the curable resin-forming composition B has a viscosity of 10000 mPa·sec or more.

[13]是如上述[6]或[11]任何一项所述的固体摄像装置的制造方法,其特征在于:该硬化树脂形成组成物B是紫外线硬化性的。[13] The method for manufacturing a solid-state imaging device according to any one of [6] or [11] above, wherein the curable resin-forming composition B is ultraviolet curable.

上述[13]所示的硬化树脂组成物A是紫外线硬化性的时,其中也优选下述的制造方法。When the curable resin composition A shown in the above [13] is ultraviolet curable, the following production method is also preferable among them.

[14]一种固体摄像装置的制造方法,其特征在于:上述工序(ii)是在上述中空盒子上面与透明板之间赋予紫外线硬化性的树脂形成组成物B,通过该透明板照射紫外线使该树脂形成组成物成为硬化树脂从而封闭该盒子的工序。[14] A method of manufacturing a solid-state imaging device, wherein the step (ii) is to provide an ultraviolet-curable resin-forming composition B between the upper surface of the hollow case and a transparent plate, and irradiate ultraviolet rays through the transparent plate to make the A process of closing the case by turning the resin-forming composition into a hardened resin.

如果采用上述[6]~[14]所示的制造方法,则可容易制造本发明的固体摄像装置,优选上述[2]~[5]所示的固体摄像装置。The solid-state imaging device of the present invention can be easily produced by employing the production methods described in [6] to [14] above, and the solid-state imaging devices described in [2] to [5] above are preferable.

这样,制造出[15]的固体摄像装置。In this way, the solid-state imaging device of [15] was manufactured.

又,本发明提供下述[16]所示的固体摄像装置。Furthermore, the present invention provides a solid-state imaging device described in the following [16].

[16]一种固体摄像装置,其特征在于:备有:具有凹部的树脂制的盒主体(中空盒子);设在凹部的底面上的岛;固定在岛上的固体摄像元件;从凹部内经由盒主体的侧壁延伸到外部的导线端子;连接固体摄像元件和导线端子的接合线;与岛的宽度方向两端相接触,沿着岛的纵向延伸的一对突起部(突堤部);以及与突起部的各外侧侧面相接触的第1硬化树脂。[16] A solid-state imaging device, characterized in that: a resin box body (hollow box) having a concave portion; an island provided on the bottom surface of the concave portion; a solid-state imaging element fixed on the island; Lead terminals extending to the outside through the side wall of the case main body; bonding wires connecting the solid-state imaging element and the lead terminals; a pair of protrusions (dikes) extending in the longitudinal direction of the island in contact with both ends of the island in the width direction; and the first cured resin in contact with each outer side surface of the protruding portion.

一对突起部能够限制岛在宽度方向上的移动。固体摄像元件的受光面露出,能够使充足光量的光入射到该受光面上。第1硬化树脂被突起部外侧的侧面阻挡,不存在于受光面上。因此,根据本固体摄像装置,能够进行正确的摄像。The pair of protrusions can restrict the movement of the island in the width direction. The light-receiving surface of the solid-state imaging element is exposed, and light of a sufficient amount can be incident on the light-receiving surface. The first cured resin is blocked by the side surface outside the protrusion and does not exist on the light receiving surface. Therefore, according to the solid-state imaging device, accurate imaging can be performed.

又,本发明提供下述[17]所示的固体摄像装置。Furthermore, the present invention provides a solid-state imaging device described in the following [17].

[17]是如上述[16]所述的固体摄像装置,其特征在于:备有:封闭盒主体的凹部的透明板;以及加装在盒主体与透明板之间的第2硬化树脂。第2硬化树脂能够粘接透明板和盒主体。[17] The solid-state imaging device according to [16] above, comprising: a transparent plate that closes the recess of the case body; and a second cured resin interposed between the case body and the transparent plate. The second curable resin can bond the transparent plate and the case body.

又,本发明提供下述[18]所示的固体摄像装置。Furthermore, the present invention provides a solid-state imaging device described in the following [18].

[18]是如上述[17]所述的固体摄像装置,其特征在于:第1硬化树脂与第2硬化树脂是连续的。[18] The solid-state imaging device according to the above [17], wherein the first cured resin and the second cured resin are continuous.

第1硬化树脂和第2硬化树脂可在相同的工序中涂敷,结构简单。The first hardening resin and the second hardening resin can be applied in the same process, and the structure is simple.

又,本发明提供下述[19]所示的固体摄像装置。Furthermore, the present invention provides a solid-state imaging device described in the following [19].

[19]是如上述[16]所述的固体摄像装置,其特征在于:第1硬化树脂被覆接合线和导线端子的连接部。[19] The solid-state imaging device according to the above [16], wherein the first cured resin coats the connecting portion between the bonding wire and the lead terminal.

由于第1硬化树脂被覆了连接部,所以能够防止该连接部劣化。Since the connecting portion is covered with the first curable resin, the connecting portion can be prevented from deteriorating.

如果采用上述发明,则可防止因粉屑引起的固体摄像元件的误动作,使中空盒子内的气密性更可靠。因此,也可防止水分从盒子外侵入而在盒子内结露。又,如果采用本发明,则可显著减少封闭透明板后的固体摄像装置的翘曲。同时具有这些效果的固体摄像装置,即使在具有可望低成本化的树脂制中空盒子的固体摄像装置中,也可提供实用性更优良的固体摄像装置。因此,如果采用本固体摄像装置,则可进行正确的摄像。According to the above invention, it is possible to prevent the malfunction of the solid-state imaging element caused by dust, and to make the airtightness in the hollow case more reliable. Therefore, moisture intrusion from the outside of the case and condensation inside the case can also be prevented. Also, according to the present invention, the warpage of the solid-state imaging device after sealing the transparent plate can be significantly reduced. A solid-state imaging device having these effects at the same time can provide a solid-state imaging device with better practicality even among solid-state imaging devices having a resin hollow case that is expected to be cost-effective. Therefore, according to this solid-state imaging device, accurate imaging can be performed.

附图说明 Description of drawings

图1是将本发明的固体摄像装置的一例在该装置的中央部剖开的概要剖面图。FIG. 1 is a schematic cross-sectional view of an example of a solid-state imaging device according to the present invention cut at the center of the device.

图2是表示可用于本发明的固体摄像装置的树脂制中空盒子的一例的俯视图。2 is a plan view showing an example of a resin hollow case that can be used in the solid-state imaging device of the present invention.

图3是模式性表示可用于本发明的固体摄像装置的树脂制中空盒子的一例的立体图。硬化树脂没有图示。3 is a perspective view schematically showing an example of a resin hollow case that can be used in the solid-state imaging device of the present invention. Hardened resin is not shown.

图4是备有固体摄像元件收纳盒的固体摄像装置的详细立体图。4 is a detailed perspective view of a solid-state imaging device equipped with a solid-state imaging device housing case.

图5是备有具有切口的岛的固体摄像元件收纳盒中央部的立体图。5 is a perspective view of a central portion of a solid-state imaging device housing case provided with an island having a cutout.

图6是备有分割的岛的固体摄像元件收纳盒中央部的立体图。6 is a perspective view of a central portion of a solid-state imaging device housing case provided with divided islands.

图7是用于说明固体摄像元件收纳盒的制造方法的图。FIG. 7 is a diagram for explaining a method of manufacturing the solid-state imaging device storage case.

具体实施方式 Detailed ways

以下,说明实施形式的固体摄像装置及其制造方法。同样的部分采用同样的标记,省去重复的说明。Hereinafter, the solid-state imaging device and its manufacturing method according to the embodiment will be described. The same parts adopt the same symbols, and repeated explanations are omitted.

本发明的固体摄像装置是在由大致矩形的树脂制底板22和大致垂设在其周缘上的树脂制侧壁24一体形成,并插设金属制导线端子40,且开口部可被透明板26封闭的树脂制中空盒子20上,树脂制中空盒子20内表面的树脂部分的至少一部分以及导线端子40与树脂部分的分界部被树脂形成组成物硬化后的硬化树脂32覆盖着。The solid-state imaging device of the present invention is integrally formed by a substantially rectangular resin base plate 22 and a resin side wall 24 substantially vertically placed on its periphery, and a metal lead terminal 40 is inserted, and the opening can be covered by a transparent plate 26. In the closed resin hollow case 20 , at least a part of the resin portion on the inner surface of the resin hollow case 20 and the boundary between the lead terminal 40 and the resin portion are covered with cured resin 32 after curing the resin forming composition.

又,本发明的固体摄像装置的制造方法,按以下顺序包含:在由大致矩形的树脂制底板22和大致垂设在其周缘上的树脂制侧壁24一体形成,并插设导线端子40,且开口部可被透明板26封闭的树脂制中空盒子20的内底面上固定固体摄像元件12的工序;利用接合线电气连接固体摄像元件12的电极与导线端子40的工序;以及通过在树脂制中空盒子20的内表面赋予树脂形成组成物而形成硬化树脂32从而利用硬化树脂覆盖树脂制盒子20内表面的树脂部分的至少一部分以及盒子内的导线端子40与树脂部分的分界部的工序。In addition, the method of manufacturing the solid-state imaging device of the present invention includes the steps of: integrally forming a substantially rectangular resin base plate 22 and a resin side wall 24 vertically provided on its periphery, and inserting the lead terminals 40, The process of fixing the solid-state imaging device 12 on the inner bottom surface of the resin hollow box 20 whose opening can be closed by the transparent plate 26; The inner surface of the hollow case 20 is provided with a resin forming composition to form the cured resin 32, and the hardened resin covers at least a part of the resin part of the inner surface of the resin case 20 and the boundary between the lead terminal 40 and the resin part in the case.

图1是将图2所示的固体摄像装置在导线端子的插设部分剖开的概要剖面图(I-I箭头剖面图)。FIG. 1 is a schematic cross-sectional view (cross-sectional view by arrow I-I) of the solid-state imaging device shown in FIG. 2 at a portion where a lead terminal is inserted.

本发明的固体摄像装置10具有收纳固体摄像元件12的树脂制中空盒子20、封闭该中空盒子的开口部的透明板26,为了粘固固体摄像元件12而具有设置在该中空盒子20的内部底面上的金属制岛30(以下也只叫做“岛”)。固体摄像元件12,可对通过透明板26从摄像装置外入射的光摄像,该固体摄像元件12应答入射光而记录的电信号,可通过与固体摄像元件12电气连接的导线端子40等取出固体摄像装置10外。The solid-state imaging device 10 of the present invention has a resin hollow case 20 for accommodating the solid-state imaging device 12, a transparent plate 26 for closing the opening of the hollow case, and an inner bottom surface of the hollow case 20 for fixing the solid-state imaging device 12. The metal island 30 (hereinafter also only referred to as "island") on the top. The solid-state imaging element 12 can take an image of light incident from the outside of the imaging device through the transparent plate 26, and the electrical signal recorded by the solid-state imaging element 12 in response to the incident light can be taken out of the solid-state imaging element 12 through the lead terminal 40 or the like electrically connected to the solid-state imaging element 12. camera device 10 outside.

也可代替导线端子40,在电极座上设置金属突起,使绝缘性膜与导体配线构成的配线基板通过前述电极座电气连接。Instead of the lead terminal 40, a metal protrusion may be provided on the electrode holder, and a wiring board composed of an insulating film and conductor wiring may be electrically connected through the electrode holder.

固体摄像元件12具有读出部,读出部具有应答入射光而顺序读出发生信号电荷的像素的排列和像素排列的信号电荷的功能。固体摄像元件,优选具有多个像素排列的半导体摄像元件,大致分为一维状像素排列的一维图像传感器(线性传感器)和二维状像素排列的二维图像传感器(面传感器)。在本发明的固体摄像装置或其制造方法中,作为固体摄像元件,既可使用线性传感器也可使用面传感器,但优选使用线性传感器。作为摄像元件,可例示CCD图像传感器、C0MS图像传感器、CMD、电荷注入器件、红外图像传感器等。又,线性传感器的代表长度是2~15cm,优选3~10cm。The solid-state imaging device 12 has a readout unit that has a function of sequentially reading out the arrangement of pixels generating signal charges and the signal charges of the pixel arrangement in response to incident light. Solid-state imaging devices, preferably semiconductor imaging devices having a plurality of pixel arrays, are broadly classified into one-dimensional image sensors (line sensors) with one-dimensional pixel arrays and two-dimensional image sensors (area sensors) with two-dimensional pixel arrays. In the solid-state imaging device or its manufacturing method of the present invention, either a linear sensor or an area sensor may be used as the solid-state imaging element, but a linear sensor is preferably used. As the imaging element, a CCD image sensor, a COMS image sensor, a CMD, a charge injection device, an infrared image sensor, etc. can be illustrated. Also, the representative length of the linear sensor is 2 to 15 cm, preferably 3 to 10 cm.

作为本发明的固体摄像装置,可例示传真机、扫描仪、条形码读出器。Examples of the solid-state imaging device of the present invention include facsimile machines, scanners, and barcode readers.

树脂制中空盒子20,由大致矩形的树脂制底板22和大致垂设在底板22的周缘上的树脂制侧壁24一体形成。大致矩形的树脂制底板22以及树脂制侧壁24为了具有机械强度都具有适当的厚度。The resin-made hollow box 20 is integrally formed of a substantially rectangular resin-made bottom plate 22 and a resin-made side wall 24 substantially suspended from the peripheral edge of the bottom plate 22 . Both the substantially rectangular resin base plate 22 and the resin side wall 24 have an appropriate thickness for mechanical strength.

所谓树脂制底板22是「大致矩形」,指包含除正方形以及矩形形状以外大体矩形的形状。所谓「大体矩形」,是指具有平行的长边但短边即使是直线状也不与长边正交或短边不是直线的形状,以及极其纵长的椭圆等。另外,具有平行的长边的中空盒子20的底板形状,矩形缺四角的形状、矩形的角带圆的形状、或短边不是直线状而是半圆形的形状也含在上述「大体矩形的形状」内。The resin base plate 22 is "substantially rectangular" and includes substantially rectangular shapes other than square and rectangular shapes. The term "substantially rectangular" refers to a shape that has parallel long sides but the short side is not perpendicular to the long side even if the short side is straight or the short side is not a straight line, and an extremely vertically elongated ellipse. In addition, the bottom plate shape of the hollow box 20 having parallel long sides, the shape of a rectangle missing four corners, the shape of a rectangle with rounded corners, or the shape of a semicircle instead of a straight line on the short side is also included in the above-mentioned "substantially rectangular shape". shape".

树脂制侧壁24大致垂设在大致矩形的树脂制底板22的周缘上。树脂制侧壁24与树脂制底板22接触的形状和外形面积与树脂制底板22的大致一样。所谓「大致垂设」,是指除严格垂直设置的树脂制侧壁以外,也包含朝向开口部稍微扩大地设置的树脂制侧壁。所谓「稍微扩大」,是指具有离垂直方向45°以内、优选30°以内的倾斜。The resin side wall 24 is substantially vertically provided on the peripheral edge of the substantially rectangular resin base plate 22 . The shape and outer area of the resin side wall 24 in contact with the resin base plate 22 are substantially the same as those of the resin base plate 22 . The term "approximately vertical" means not only the resin side walls that are strictly vertical, but also the resin side walls that are slightly enlarged toward the opening. The term "slightly enlarged" means having an inclination within 45°, preferably within 30°, from the vertical direction.

可任意组合以上的树脂制底板的形状和树脂制侧壁的设置角度而设计中空盒子的整体形状。中空盒子,与上述整体形状无关,在中空盒子20的内底面上具有可设置金属性岛的区域。The overall shape of the hollow box can be designed by arbitrarily combining the shapes of the above resin bottom plate and the setting angles of the resin side walls. The hollow box has an area on the inner bottom surface of the hollow box 20 where metallic islands can be provided regardless of the above overall shape.

在本发明上使用的树脂制中空盒子20内插设(埋设)金属制导线端子40。Metal lead terminals 40 are inserted (embedded) in the hollow resin case 20 used in the present invention.

导线端子40,电气以及机械连接固体摄像装置与外部电路。导线端子40是金属制的,可使用金属制的众所周知的形式。作为金属可例示铜、铜合金、铁合金,可优选使用作为铜或铁58%镍42%的合金的42合金。这些金属(合金)可施加镀层使用,用于镀层的材料可例示金、银、镍以及焊锡。The lead terminal 40 electrically and mechanically connects the solid-state imaging device and an external circuit. The lead terminal 40 is made of metal, and a well-known metal type can be used. As the metal, copper, copper alloy, and iron alloy can be exemplified, and 42 alloy, which is an alloy of copper or iron 58% nickel 42%, can be preferably used. These metals (alloys) can be used by plating, and examples of materials used for the plating include gold, silver, nickel, and solder.

导线端子40优选:使用引线框在中空盒子20成形时与树脂组成物一体成形,之后进行弯曲或切断等加工,作为导线端子。The lead terminal 40 is preferably formed integrally with the resin composition when the hollow case 20 is formed using a lead frame, and then subjected to processing such as bending or cutting to serve as a lead terminal.

粘固在岛30上的固体摄像元件12与用于将读出的信号电荷传递到固体摄像装置10外部的导线端子40电气连接。在图1中,固体摄像元件12利用接合线42与导线端子40连接。为了将从固体摄像元件读出的信号电荷传到固体摄像装置的外部,利用接合线等连接固体摄像元件的电极与导线端子。接合线42是金属细线,优选由金、铝、铜以及以它们为主要成分的合金构成。接合线的连接方法,根据导线的材质等确定,但可例举球焊法或楔焊法等。The solid-state imaging element 12 bonded to the island 30 is electrically connected to a lead terminal 40 for transferring read signal charges to the outside of the solid-state imaging device 10 . In FIG. 1 , the solid-state imaging element 12 is connected to a lead terminal 40 by a bonding wire 42 . In order to transmit signal charges read from the solid-state imaging device to the outside of the solid-state imaging device, the electrodes of the solid-state imaging device and lead terminals are connected with bonding wires or the like. The bonding wire 42 is a fine metal wire, and is preferably composed of gold, aluminum, copper, or an alloy mainly composed of these. The method of connecting the bonding wires is determined according to the material of the wire, and examples thereof include ball bonding, wedge bonding, and the like.

利用接合线等电气配线后,利用透明板26封死中空盒子20的开口部而获得固体摄像装置10。封死,可使用放射线硬化性、湿气硬化性、或热硬化性的树脂形成组成物,后面详细叙述。The solid-state imaging device 10 is obtained by sealing the opening of the hollow case 20 with the transparent plate 26 after wiring such as a bonding wire. For sealing, a radiation-curable, moisture-curable, or thermosetting resin-forming composition can be used, which will be described in detail later.

在树脂制侧壁24的开口部的内侧周缘上也可设置埋入透明板的切槽。Inner peripheral edges of the openings of the side walls 24 made of resin may also be provided with notches for filling the transparent plates.

中空盒子20被透明板26封闭。在此,所谓透明板,指用于摄像的入射光,一般在可见光(400~700nm)以及近红外区域透过率80%以上,优选90%以上的板状部件。摄像装置是条形码读出器时,重要的是红色半导体激光的波长650nm的透过率。The hollow box 20 is closed by a transparent panel 26 . Here, the term "transparent plate" refers to a plate-shaped member with a transmittance of 80% or more, preferably 90% or more, for incident light used for imaging, generally in the visible light (400-700nm) and near-infrared regions. When the imaging device is a barcode reader, the transmittance of the red semiconductor laser with a wavelength of 650 nm is important.

作为透明板26的材质,可例示玻璃、丙烯树脂、聚碳酸酯、含有环烯烃单元的聚合物。Examples of the material of the transparent plate 26 include glass, acrylic resin, polycarbonate, and polymers containing cycloolefin units.

利用透明板26封闭中空盒子开口部后,可利用热硬化性或光硬化性的粘接剂RE封闭该开口部。也可通过透明板26照射紫外线使盒子内表面被覆用以及透明板封闭用的树脂形成组成物32硬化。也可使盒子内表面被覆用树脂形成组成物32热硬化后,使透明板封闭用的树脂形成组成物32(粘接剂RE)光硬化。玻璃或含有环烯烃单元的聚合物构成的透明板26,出于紫外线透过性以及耐热性的观点优选使用。After closing the opening of the hollow box with the transparent plate 26, the opening can be closed with a thermosetting or photosetting adhesive RE. The resin-forming composition 32 for coating the inner surface of the case and for sealing the transparent plate may be cured by irradiating ultraviolet rays through the transparent plate 26 . It is also possible to light-cure the resin-forming composition 32 (adhesive RE) for sealing the transparent plate after thermosetting the resin-forming composition 32 for case inner surface coating. The transparent plate 26 made of glass or a polymer containing a cycloolefin unit is preferably used from the viewpoint of ultraviolet light permeability and heat resistance.

该中空盒子内表面的树脂部分的至少一部分以及导线端子40与树脂部分(盒子内表面)的分界部由树脂组成物硬化后的硬化树脂32覆盖。利用该硬化树脂32的覆盖,即使由于中空树脂盒子成形时产生的溢料带来的粉屑混在盒子内,也可防止其飞散,且在开口部上封闭透明板26可使封闭的中空盒子的气密性更可靠,所以可防止固体摄像元件的误动作。出于防止粉屑产生的目的以及提高气密性的目的,如图1所示,优选由硬化树脂32覆盖盒子内表面的所有处或几乎所有处的树脂部分以及该树脂部分/金属制导线端子部分的分界部的所有处以及导线端子40的表面的所有处。在此,所谓「几乎所有处」,是指盒子内表面的树脂部分的80%以上。At least a part of the resin portion on the inner surface of the hollow case and the boundary between the lead terminal 40 and the resin portion (inner surface of the case) are covered with cured resin 32 after the resin composition has been cured. Utilize the cover of this cured resin 32, even if the dust that the overflow that produces when hollow resin box is molded brings is mixed in the box, also can prevent it from flying, and sealing transparent plate 26 on the opening can make the closed hollow box Since the airtightness is more reliable, malfunction of the solid-state imaging device can be prevented. For the purpose of preventing dust generation and improving airtightness, as shown in FIG. 1 , it is preferable to cover all or almost all of the resin part and the resin part/metal lead terminal on the inner surface of the box with hardened resin 32 All parts of the boundary portion and all parts of the surface of the lead terminal 40 . Here, "substantially everywhere" refers to 80% or more of the resin portion of the inner surface of the case.

本发明的固体摄像装置的制造方法,在前述树脂制中空盒子20的内底面上粘固固体摄像元件12的工序、利用接合线42电气连接固体摄像元件12的电极与金属制导线端子40的工序之后,具有以下工序:通过在该中空盒子20的内表面赋予树脂形成组成物而形成硬化树脂32,从而利用硬化树脂32覆盖树脂制盒子内表面的树脂部分的至少一部分以及该盒子内的导线端子40与树脂部分的分界部的工序。The manufacturing method of the solid-state imaging device according to the present invention includes a step of adhering the solid-state imaging device 12 on the inner bottom surface of the resin hollow case 20, and a step of electrically connecting the electrodes of the solid-state imaging device 12 and the metal lead terminals 40 with bonding wires 42. Thereafter, there is a step of forming hardened resin 32 by applying a resin-forming composition to the inner surface of the hollow box 20, thereby covering at least a part of the resin portion of the inner surface of the resin box and the lead terminals in the box with hardened resin 32 40 and the process of the boundary part of the resin part.

优选粘固固体摄像元件12之前清洗中空盒子20。该清洗可使用超声波清洗、喷射清洗、喷雾清洗等众所周知的清洗方法。It is preferable to clean the hollow case 20 before bonding the solid-state imaging device 12 . For this cleaning, well-known cleaning methods such as ultrasonic cleaning, spray cleaning, and spray cleaning can be used.

作为透明板封闭用以及中空盒子内表面被覆用的硬化树脂32,可使用众所周知的热硬化性树脂、湿气硬化性树脂、可见光硬化性树脂以及紫外线硬化性树脂,可例示环氧树脂、不饱和聚酯树脂、酚醛树脂、尿素-三聚氰胺树脂、聚氨脂树脂、硅酮树脂、聚酰亚胺树脂、丙烯酸树脂等。形成这些树脂的树脂形成组成物,对形成树脂的单体或低聚物或聚合物,根据需要,配合用途适当组合聚合开始剂、交联剂、反应促进剂等添加剂,以及二氧化硅等无机填充剂等而构成。在透明板封闭用硬化树脂、中空盒子内表面被覆用的硬化树脂上可使用同一种物质,也可使用分别不同的硬化树脂。As the hardening resin 32 for sealing the transparent plate and coating the inner surface of the hollow box, well-known thermosetting resins, moisture curing resins, visible light curing resins, and ultraviolet curing resins can be used, and epoxy resins, unsaturated resins, etc. can be exemplified. Polyester resin, phenolic resin, urea-melamine resin, polyurethane resin, silicone resin, polyimide resin, acrylic resin, etc. For the resin-forming composition forming these resins, additives such as polymerization initiators, cross-linking agents, and reaction accelerators, and inorganic components such as silica, etc. fillers etc. The same hardening resin for sealing the transparent plate and the hardening resin for coating the inner surface of the hollow box may be used, or different hardening resins may be used respectively.

作为透明板封闭用以及中空盒子内表面被覆用的硬化树脂32,为了可短时间硬化,在上述各种硬化性树脂中优选使用紫外线硬化性树脂,透明板封闭用以及中空盒子内表面被覆用的硬化树脂两者最优选紫外线硬化性树脂。透明板封闭用硬化树脂以及中空盒子内表面被覆用的硬化树脂两方是紫外线硬化性树脂时,可通过在利用透明板封闭中空盒子上面后从盒子上面照射紫外线使覆盖中空盒子内表面的树脂形成组成物和封闭透明板的树脂形成组成物同时硬化,可降低制造成本。As the hardening resin 32 for sealing the transparent plate and coating the inner surface of the hollow box, in order to be hardened in a short time, among the above-mentioned various curable resins, it is preferable to use an ultraviolet curable resin for sealing the transparent plate and coating the inner surface of the hollow box. Both curable resins are most preferably ultraviolet curable resins. When both the hardening resin for sealing the transparent plate and the hardening resin for covering the inner surface of the hollow box are ultraviolet curable resins, the resin covering the inner surface of the hollow box can be formed by irradiating ultraviolet rays from the top of the box after closing the top of the hollow box with a transparent plate The composition and the resin-forming composition closing the transparent plate are cured at the same time, so that the manufacturing cost can be reduced.

作为紫外线硬化性树脂,例举根据丙烯酸脂单体、聚脂-丙烯酸脂低聚物、尿烷-丙烯酸脂低聚物、环氧-丙烯酸脂低聚物等利用自由基聚合形成的丙烯酸脂树脂,根据环氧化合物、辛腙化合物化合物(オキタセン)等利用阳离子催化聚合形成的环氧树脂,根据聚硅氧烷衍生物利用自由基聚合或阳离子催化聚合形成的硅酮树脂等。其中优选使用环氧树脂、硅酮树脂。Examples of ultraviolet curable resins include acrylate resins formed by radical polymerization of acrylate monomers, polyester-acrylate oligomers, urethane-acrylate oligomers, epoxy-acrylate oligomers, etc. , Epoxy resins formed by cationic catalyzed polymerization based on epoxy compounds, octylhydrazone compounds (Okitasen), etc., silicone resins formed by free radical polymerization or cationic catalyzed polymerization based on polysiloxane derivatives, etc. Among these, epoxy resins and silicone resins are preferably used.

本发明中使用的紫外线硬化性的树脂形成组成物,是利用紫外线(数十~400nm)的照射而硬化的即可,也可同时具有可见光(400超~700nm)硬化性、热硬化性、或湿气硬化性的性质。The UV-curable resin-forming composition used in the present invention can be cured by irradiation with ultraviolet rays (tens to 400 nm), and may also have visible light (400 to 700 nm) curability, thermosetting properties, or Moisture-curing properties.

中空盒子内表面被覆用紫外线硬化性的树脂形成组成物优选是利用紫外线照射的硬化重量变化率(硬化后的硬化树脂的重量相对硬化前的树脂形成组成物的重量的百分率)在99.8%以上、100%以下,更优选在99.9%以上、100%以下。又,作为本发明的固体摄像装置,优选将具有这样的硬化重量变化率的紫外线硬化性的树脂形成组成物赋予中空盒子的内表面的既定部位,照射紫外线而覆盖该既定部位。在硬化后的硬化树脂的重量相对硬化前的树脂形成组成物的重量大大减少时,硬化时挥发的成分可能对固体摄像元件造成不良影响,又,通过透明板照射紫外线时挥发的成分可能附着在透明板上导致模糊不清。The UV-curable resin-forming composition for coating the inner surface of the hollow box preferably has a curing weight change rate (the weight percentage of the cured resin after curing relative to the weight of the resin-forming composition before curing) by ultraviolet irradiation of 99.8% or more, 100% or less, more preferably 99.9% or more and 100% or less. In addition, as the solid-state imaging device of the present invention, it is preferable to apply an ultraviolet-curable resin-forming composition having such a cured weight change rate to a predetermined portion of the inner surface of the hollow case, and to cover the predetermined portion by irradiating ultraviolet rays. When the weight of the cured resin after curing is greatly reduced relative to the weight of the resin-forming composition before curing, components volatilized during curing may adversely affect the solid-state imaging device, and components volatilized when irradiated with ultraviolet rays through a transparent plate may adhere to the solid-state imaging device. Causes blur on transparent boards.

该硬化重量变化率利用以下条件测定。所谓硬化后的硬化树脂的重量,是在直径约25mm的上面开放的玻璃制的容器中放入硬化前的树脂形成组成物达到厚度约3mm,在23℃、50%RH的气氛中对其照射约3000mJ/cm2的紫外线(365nm)而硬化的硬化树脂刚硬化后的重量;所谓硬化前的树脂形成组成物的重量,是从密闭的紫外线遮蔽性容器取出而刚放入上述玻璃制容器的树脂形成组成物的重量。This curing weight change rate is measured under the following conditions. The weight of the hardened resin after hardening is to put the resin-forming composition before hardening into a glass container with a diameter of about 25 mm and an open top to a thickness of about 3 mm, and irradiate it in an atmosphere of 23 ° C and 50 % RH. The weight of the cured resin hardened by ultraviolet rays (365nm) of about 3000mJ/cm 2 immediately after hardening; the weight of the resin-forming composition before hardening is taken out from the sealed ultraviolet-shielding container and put into the above-mentioned glass container The weight of the resin-forming composition.

用于封闭中空盒子开口部的硬化树脂也优选具有上述硬化重量变化率。The cured resin for closing the opening of the hollow case also preferably has the aforementioned rate of change in cured weight.

作为将树脂形成组成物赋予中空盒子内表面的至少一部分以及该导线端子40与树脂部分的分界部的方法,例示使用喷射器将树脂形成组成物从喷嘴注入中空盒子内的方法。As a method of applying the resin-forming composition to at least a part of the inner surface of the hollow case and the boundary between the lead terminal 40 and the resin portion, a method of injecting the resin-forming composition into the hollow case from a nozzle using an injector is exemplified.

图2是固体摄像装置10的俯视图。图3是图2所示固体摄像装置10的立体图。在同图中透明板被取下。FIG. 2 is a plan view of the solid-state imaging device 10 . FIG. 3 is a perspective view of the solid-state imaging device 10 shown in FIG. 2 . In the same figure the transparent plate is removed.

金属制岛30是任意的部件,可用作粘固固体摄像元件12的平坦部。设置金属制岛30时,在截面凹状的树脂制中空盒子20的内底面上与之接触地形成。可在该岛30上粘固固体摄像元件12。该固定方法没有特别限制。固体摄像元件12可利用粘接剂、焊锡等粘固,优选利用粘接剂粘固,更优选使用绝缘性的树脂粘固。用于粘固固体摄像元件12的粘接剂优选导热率高的,优选导热率在1W/mK以上,更优选3W/mK以上。The metal island 30 is an arbitrary member and can be used as a flat portion on which the solid-state imaging device 12 is fixed. When the metal island 30 is provided, it is formed so as to be in contact with the inner bottom surface of the resin hollow box 20 having a concave cross section. The solid-state imaging device 12 can be bonded to the island 30 . The fixing method is not particularly limited. The solid-state imaging device 12 can be fixed with an adhesive, solder, or the like, preferably with an adhesive, and more preferably with an insulating resin. The adhesive used to fix the solid-state imaging device 12 is preferably one with high thermal conductivity, preferably 1 W/mK or higher, more preferably 3 W/mK or higher.

中空盒子的内底面由树脂形成组成物硬化的硬化树脂32覆盖着。The inner bottom surface of the hollow box is covered with hardened resin 32 hardened by the resin forming composition.

设置金属制岛30时,其形状没有特别的限制,但优选具有4以上的纵横比的矩形,更优选具有4~100的纵横比。When the metal island 30 is provided, its shape is not particularly limited, but is preferably a rectangle having an aspect ratio of 4 or more, and more preferably has an aspect ratio of 4-100.

也优选在岛纵向的侧缘的一处以上设置相邻的切口。该相邻的切口从岛的相向的长边的相反侧交错地设置。又,该切口没有在岛的纵向同样地设置,在设置多个相邻的切口群时,优选以一定的距离分散开设置。It is also preferable to provide adjacent cutouts at one or more locations along the side edges in the longitudinal direction of the island. The adjacent cutouts are staggered from opposite sides of the facing long sides of the island. In addition, the notches are not uniformly provided in the longitudinal direction of the island, and when a plurality of adjacent notch groups are provided, they are preferably dispersed and provided at a certain distance.

岛30是金属制的,作为金属可例示铜、铜合金、铝、铝合金、铁合金,可优选使用铜、铝、铝合金、镀金的铜以及42合金。岛30也可具有向垂直于纵向的方向突出的突出部,该突出部形成其一部分埋设在盒子中固定的岛压紧部。The island 30 is made of metal. Examples of the metal include copper, copper alloy, aluminum, aluminum alloy, and iron alloy. Copper, aluminum, aluminum alloy, gold-plated copper, and 42 alloy are preferably used. The island 30 may also have a protruding portion protruding in a direction perpendicular to the longitudinal direction, the protruding portion forming an island pressing portion, a part of which is buried in the case and fixed.

本发明使用的树脂制中空盒子,可利用注射成形法、注射压缩成形法、压缩成形法、多工位成形法等形成。作为可用于成形的树脂,可大致分为可成形的热硬化性树脂以及热可塑性树脂,任何树脂也优选从阻燃性、电绝缘性、强度·刚性的观点选择。从可缩短成形周期,可削减成形成本的观点出发,优选使用热可塑性树脂,利用注射成形法形成中空盒子。The resin hollow box used in the present invention can be formed by injection molding, injection compression molding, compression molding, multi-station molding, or the like. Resins usable for molding are roughly classified into moldable thermosetting resins and thermoplastic resins, and any resin is preferably selected from the viewpoints of flame retardancy, electrical insulation, and strength and rigidity. From the viewpoint of shortening the molding cycle and reducing the molding cost, it is preferable to form the hollow box by injection molding using a thermoplastic resin.

作为可用于制造本发明的中空盒子的热硬化性树脂,可例示出酚醛树脂、尿素树脂、三聚氰胺树脂、邻苯二甲酸二烯丙基酯树脂、环氧树脂、聚氨酯树脂、聚酰亚胺树脂以及不饱和聚酯树脂等,优选使用酚醛树脂、环氧树脂。Examples of thermosetting resins that can be used to manufacture the hollow box of the present invention include phenolic resins, urea resins, melamine resins, diallyl phthalate resins, epoxy resins, polyurethane resins, and polyimide resins. As well as unsaturated polyester resins, phenolic resins and epoxy resins are preferably used.

又,作为可用于本发明的热可塑性树脂,可例示出聚苯乙烯树脂、丙烯酸树脂、聚碳酸酯树脂、聚酯树脂、聚酰胺树脂、聚缩醛树脂、聚苯醚树脂、氟树脂、聚苯硫醚树脂、聚砜树脂、聚芳酯、聚醚酰亚胺树脂、聚醚砜树脂、聚醚酮树脂、液晶性聚合物、聚酰胺酰亚胺树脂、聚酰亚胺树脂等,优选使用聚酯树脂、聚酰胺树脂、聚苯硫醚树脂、液晶性聚合物。这些树脂可单独使用也可作为聚合物共混物同时使用多种。液晶性聚合物,由于流动性、耐热性、刚性优良,本发明中优选使用。In addition, examples of thermoplastic resins usable in the present invention include polystyrene resins, acrylic resins, polycarbonate resins, polyester resins, polyamide resins, polyacetal resins, polyphenylene ether resins, fluororesins, polycarbonate resins, Phenylsulfide resin, polysulfone resin, polyarylate, polyetherimide resin, polyethersulfone resin, polyetherketone resin, liquid crystal polymer, polyamideimide resin, polyimide resin, etc., preferably Polyester resin, polyamide resin, polyphenylene sulfide resin, liquid crystal polymer are used. These resins may be used alone or in combination as a polymer blend. Liquid crystalline polymers are preferably used in the present invention because they are excellent in fluidity, heat resistance, and rigidity.

关于上述树脂的概要情况,记载于「高分子大辞典」(丸善株式会社发行,平成6年9月20日)以及其上引用的文献等。The summary of the above-mentioned resins is described in "Polymer Encyclopedia" (published by Maruzen Co., Ltd., September 20, 2016) and documents cited therein.

形成本发明中使用的中空盒子时,可使用在树脂中添加适当填充剂的树脂组成物。使用的填充剂,出于提高强度或刚性、耐热性,提高尺寸精度,降低线膨胀系数等目的,可适当选择。作为可以以这样的目的使用的填充剂,可例示玻璃纤维(磨碎玻璃纤维、短玻璃纤维等)、玻璃珠、中空玻璃球、玻璃粉末、云母、滑石、粘土、二氧化硅、氧化铝、钛酸钾、硅灰石、碳酸钙、碳酸镁、硫酸苏打、硫酸钙、硫酸钡、亚硫酸钙、氢氧化铝、氢氧化镁、氢氧化钙、硅酸钙、硅砂、硅石、石英、氧化钛、氧化锌、氧化铁、石墨、钼、石棉、硅酸铝纤维、氧化铝纤维、石膏纤维、碳素纤维、炭黑、白炭黑、硅藻土、膨润土、绢云母、白砂(sirasu)、石墨等无机填料,钛酸钾晶须、氧化铝晶须、硼酸铝晶须、碳化硅晶须、氮化硅晶须等金属晶须或非金属须晶类等。另外,优选使用具有遮光效果以及防止在盒子内部的光的衍射的效果等的炭黑。When forming the hollow box used in the present invention, a resin composition in which a suitable filler is added to the resin can be used. The filler used can be appropriately selected for the purpose of improving strength, rigidity, heat resistance, improving dimensional accuracy, and reducing the coefficient of linear expansion. Examples of fillers that can be used for such purposes include glass fibers (ground glass fibers, short glass fibers, etc.), glass beads, hollow glass spheres, glass powder, mica, talc, clay, silica, alumina, Potassium titanate, wollastonite, calcium carbonate, magnesium carbonate, soda sulfate, calcium sulfate, barium sulfate, calcium sulfite, aluminum hydroxide, magnesium hydroxide, calcium hydroxide, calcium silicate, silica sand, silica, quartz, oxide Titanium, zinc oxide, iron oxide, graphite, molybdenum, asbestos, aluminum silicate fiber, alumina fiber, gypsum fiber, carbon fiber, carbon black, silica, diatomaceous earth, bentonite, sericite, white sand (sirasu) , graphite and other inorganic fillers, potassium titanate whiskers, alumina whiskers, aluminum borate whiskers, silicon carbide whiskers, silicon nitride whiskers and other metal whiskers or non-metal whiskers, etc. In addition, it is preferable to use carbon black having a light-shielding effect, an effect of preventing diffraction of light inside the case, and the like.

(比较例1)(comparative example 1)

将在铜合金上镀金的引线框嵌在金属模内,通过注射成形液晶性聚合物[スミカス-バ-E6008B(住友化学(株)制)]获得插设有导线端子的树脂制中空盒子(宽50mm×进深10mm×高4mm、厚2mm)。将获得的树脂制中空盒子在等级1,000的净化车间内用超纯水清洗后,浸渍在500ml的超纯水中进行20秒的超声波清洗(38kHz),测定了取出树脂制中空盒子后的水中存在的粉屑的数量。粉屑数量的测定使用液中颗粒计数器CLS-700(PMS社制)。测定的结果,存在于超声波清洗后的水中的大小2微米以上的粉屑约1,030个/ml。A lead frame plated with gold on a copper alloy was embedded in a metal mold, and a resin hollow box (wide 50mm×depth 10mm×height 4mm, thickness 2mm). After cleaning the obtained resin hollow box with ultrapure water in a purification workshop of grade 1,000, immerse it in 500ml of ultrapure water for 20 seconds for ultrasonic cleaning (38kHz), and measure the presence of amount of dust. The measurement of the amount of dust used a liquid particle counter CLS-700 (manufactured by PMS). As a result of the measurement, there were about 1,030 pieces/ml of powder particles with a size of 2 micrometers or more existing in the water after ultrasonic cleaning.

(实施例1)(Example 1)

在比较例1中获得的树脂制中空盒子内表面上使用喷射器涂抹紫外线硬化性的硅酮树脂形成组成物[(株)スリ-ボンド制TB3161]后,利用水银灯照射约3000mJ/cm2的紫外线(365nm)使树脂形成组成物硬化。对获得的树脂制中空盒子与比较例1一样进行了粉屑数的测定。测定的结果,存在于超声波清洗后的水中的大小2微米以上的粉屑约180个/ml,确认了通过利用树脂覆盖盒子内表面而大大抑制从盒子内表面脱落粉屑的效果。另外,上述TB3161的UV硬化重量变化率是99.93%。The inner surface of the resin hollow box obtained in Comparative Example 1 was coated with a UV-curable silicone resin forming composition [TB3161 manufactured by Suri-Bond Co., Ltd.] with a sprayer, and then irradiated with ultraviolet rays of about 3000 mJ/ cm2 by a mercury lamp (365nm) to harden the resin-forming composition. The measurement of the number of dust particles was carried out in the same manner as in Comparative Example 1 for the obtained resin-made hollow box. As a result of the measurement, there were about 180 pieces/ml of powder particles with a size of 2 microns or more in the water after ultrasonic cleaning, and it was confirmed that by covering the inner surface of the case with resin, the effect of greatly suppressing the dust falling off from the inner surface of the case was confirmed. In addition, the UV curing weight change rate of the above-mentioned TB3161 was 99.93%.

(比较例2)(comparative example 2)

对比较例1中获得的树脂制中空盒子,在盒子上面的透明板封闭位置使用喷射器涂抹紫外线硬化性的上述硅酮树脂形成组成物[(株)スリ-ボンド制TB3161]后,利用玻璃制的透明板封闭盒子上面后利用水银灯照射约3000mJ/cm2的紫外线(365nm)使树脂形成组成物硬化,密封中空盒子。对获得的中空盒子使用氦气泄漏试验机HELEN A-250M-LD[アネルバテクニクス(株)制]评价气密性的结果,检测到了氦气的泄漏。For the resin hollow box obtained in Comparative Example 1, the above-mentioned ultraviolet curable silicone resin forming composition [TB3161 manufactured by Tri-Bond Co., Ltd.] was applied with a sprayer to the closed position of the transparent plate on the top of the box, and then the glass box was used. After sealing the top of the box with a transparent plate, irradiate ultraviolet light (365nm) of about 3000mJ/cm 2 with a mercury lamp to harden the resin forming composition and seal the hollow box. As a result of evaluating the airtightness of the obtained hollow box using a helium gas leak tester HELEN A-250M-LD (manufactured by Anelba Technics Co., Ltd.), leakage of helium gas was detected.

(实施例2)(Example 2)

对利用硬化树脂覆盖实施例1中获得的盒子内表面的树脂制中空盒子,与比较例2一样获得利用透明板封闭上面的中空盒子。对获得的中空盒子与比较例2一样评价气密性的结果,几乎没有检测到氦气的泄漏,确认了通过利用硬化树脂覆盖盒子内表面的树脂部分/金属制导线端子部分的分界从而提高盒子的气密性的效果。With respect to the hollow box made of resin covering the inner surface of the box obtained in Example 1 with hardened resin, a hollow box with the upper surface closed with a transparent plate was obtained as in Comparative Example 2. As a result of evaluating the airtightness of the hollow box obtained in the same manner as in Comparative Example 2, almost no leakage of helium gas was detected, and it was confirmed that the boundary between the resin part and the metal lead terminal part on the inner surface of the box was covered with a hardened resin to improve the quality of the box. The effect of airtightness.

(实施例3)(Example 3)

将实施例1中制造的带导线端子的树脂制中空盒子在等级1,000的净化车间内用超纯水清洗后,浸渍在500ml的超纯水中进行20秒的超声波清洗(38kHz),清洗干燥树脂制中空盒子。在利用粘接剂将线性传感器固定在该树脂制盒子的内表面上后,利用接合线在线性传感器与导线端子间配线。The hollow box made of resin with lead wire terminals produced in Example 1 was cleaned with ultrapure water in a clean room of grade 1,000, then immersed in 500 ml of ultrapure water and ultrasonically cleaned (38kHz) for 20 seconds to wash and dry the resin. Hollow box. After the linear sensor is fixed to the inner surface of the resin case with an adhesive, wiring is performed between the linear sensor and the lead terminal with bonding wires.

在配线完的树脂制中空盒子的内表面上,使用喷射器涂抹紫外线硬化性的前述硅酮树脂形成组成物[(株)スリ-ボンド制TB3161],并且在透明板与开口部之间涂抹同一硅酮树脂形成组成物后,利用水银灯照射约3000mJ/cm2的紫外线(365nm)使树脂形成组成物硬化,获得固体摄像装置。观察获得的树脂制中空盒子时在透明板上没发现有模糊不清。On the inner surface of the resin hollow box after wiring, apply the above-mentioned ultraviolet curable silicone resin forming composition [TB3161 manufactured by Suri-Bond Co., Ltd.] with a sprayer, and apply it between the transparent plate and the opening. After the same silicone resin composition was formed, the resin formation composition was cured by irradiating ultraviolet rays (365 nm) at about 3000 mJ/cm 2 with a mercury lamp to obtain a solid-state imaging device. Observation of the obtained resin-made hollow case did not reveal blurring on the transparent plate.

下面详细说明覆盖树脂制盒子内表面的至少一部分以及盒子内的导线端子与树脂部分的分界部的硬化树脂32。The cured resin 32 covering at least a part of the inner surface of the resin case and the boundary between the lead terminals in the case and the resin part will be described in detail below.

本发明的固体摄像装置10的制造方法按以下顺序包含:成形由大致矩形的树脂制底板22和大致垂设在其周缘上的树脂制侧壁24一体形成,并插设导线端子40,且开口部可被透明板26封闭的树脂制中空盒子20的工序;在盒子的内底面上粘固固体摄像元件12的工序;利用接合线42电气连接固体摄像元件12的电极与金属制导线端子40的工序;以及通过在中空盒子20的内表面赋予树脂形成组成物而形成硬化树脂32从而利用硬化树脂32覆盖树脂制盒子的内表面的至少一部分以及盒子内的导线端子40与树脂部分的分界部的工序。其中树脂形成组成物的粘度25℃时在10,000mPa·sec以下。The manufacturing method of the solid-state imaging device 10 of the present invention includes in the following order: forming a substantially rectangular resin base plate 22 and a resin side wall 24 substantially vertically formed on its periphery, inserting the lead terminal 40, and opening The process of resin hollow box 20 whose part can be closed by transparent plate 26; the process of bonding the solid-state imaging element 12 on the inner bottom surface of the box; process; and forming a hardening resin 32 by applying a resin forming composition to the inner surface of the hollow box 20 so that at least a part of the inner surface of the resin box and the boundary portion between the lead terminal 40 and the resin part in the box are covered with the hardening resin 32 process. Among them, the viscosity of the resin-forming composition is 10,000 mPa·sec or less at 25°C.

在此,树脂形成组成物的粘度为以JIS K7233所述的单一圆筒转动粘度计法为基准测定的。当树脂形成组成物的粘度超过10,000mPa·sec时,由于供给到盒子20内的树脂形成组成物的流动性不足,所以存在不能在短时间在盒子20内扩散成薄膜的倾向。Here, the viscosity of the resin-forming composition is measured based on the single cylinder rotational viscometer method described in JIS K7233. When the viscosity of the resin-forming composition exceeds 10,000 mPa·sec, the fluidity of the resin-forming composition supplied into the cartridge 20 is insufficient, so it tends not to spread into a thin film in the cartridge 20 in a short time.

另外,中空盒子20形成后,优选在固定固体摄像元件12前清洗、干燥中空盒子20。该清洗,可使用超声波清洗、喷射清洗、喷雾清洗等众所周知的清洗方法。In addition, after the hollow case 20 is formed, it is preferable to wash and dry the hollow case 20 before fixing the solid-state imaging device 12 . For this cleaning, well-known cleaning methods such as ultrasonic cleaning, spray cleaning, and spray cleaning can be used.

中空盒子内表面被覆用的树脂形成组成物,25℃时的粘度在10,000mPa·sec以下,优选在10~10,000mPa·sec,更优选在10~5,000mPa·sec。在此,上述粘度是以JIS K7233所述的单一圆筒转动粘度计法为基准测定所获得的值。The resin-forming composition for coating the inner surface of a hollow box has a viscosity at 25°C of 10,000 mPa·sec or less, preferably 10 to 10,000 mPa·sec, more preferably 10 to 5,000 mPa·sec. Here, the above-mentioned viscosity is a value measured based on the single cylinder rotational viscometer method described in JIS K7233.

当硬化前的树脂形成组成物的粘度高时,利用喷射器(液体精密定量喷射装置)等在树脂制盒子内表面赋予树脂形成组成物的作业性降低,由于混入气泡,或覆盖盒子内表面的树脂形成组成物的厚度增厚从而利用紫外线照射的硬化可能不充分。When the viscosity of the resin-forming composition before hardening is high, the workability of applying the resin-forming composition to the inner surface of the resin case by using an injector (liquid precision quantitative injection device) or the like is reduced, because air bubbles are mixed in, or the inner surface of the case is covered. The thickness of the resin-forming composition increases, and curing by ultraviolet irradiation may be insufficient.

又,为了调节树脂形成组成物的粘度或调节体积收缩率,或调节硬化树脂的小型携带式硬度计A硬度,可适当同时使用单一功能的硬化性成分而变成多功能的硬化性成分。In addition, in order to adjust the viscosity of the resin forming composition, adjust the volume shrinkage, or adjust the hardness of the small portable durometer A of the cured resin, it is possible to use a single-functional curable component at the same time as appropriate to become a multi-functional curable component.

为了由透明板封闭开口部,可使用上述中空盒子内表面被覆用的硬化树脂。在透明板封闭用的硬化树脂、中空盒子内表面被覆用的硬化树脂上可使用同一种物质,也可使用分别不同的硬化树脂。In order to close the opening with the transparent plate, the above-mentioned cured resin for coating the inner surface of the hollow box can be used. The same hardening resin may be used for the hardening resin for sealing the transparent plate and the hardening resin for coating the inner surface of the hollow box, or different hardening resins may be used respectively.

本发明使用的硬化树脂优选具有既定的按压硬度。The hardening resin used in the present invention preferably has a predetermined pressing hardness.

中空盒子内表面被覆用的硬化树脂32,优选JIS K7215所规定的小型携带式硬度计硬度(肖氏硬度)在类型A(也叫做「小型携带式硬度计A硬度」)中是80以下,更优选是1~50,更加优选是1~30。当小型携带式硬度计硬度在上述范围时,由于硬化树脂具有适度的硬度,所以硬化树脂32不会从树脂制盒子内壁上剥离而产生粉屑,也不会导致盒子内的气密性的下降,也不用担心引起连接导线端子40与摄像元件12的接合线42的切断等所以优选。The hardening resin 32 for covering the inner surface of the hollow box preferably has a small portable durometer hardness (Shore hardness) specified in JIS K7215 of type A (also called "small portable durometer A hardness") of 80 or less. Preferably it is 1-50, More preferably, it is 1-30. When the hardness of the small-sized portable durometer is within the above range, since the hardened resin has moderate hardness, the hardened resin 32 will not be peeled off from the inner wall of the resin box to generate dust, nor will it cause the airtightness in the box to drop. Therefore, there is no fear of cutting the bonding wire 42 connecting the lead terminal 40 and the imaging element 12, etc., so it is preferable.

由透明板封闭开口部用的粘接层所使用的硬化树脂(粘接剂RE)也优选小型携带式硬度计A硬度在80以下,更优选在1~50,更加优选在1~30。当粘接剂RE具有上述的一小型携带式硬度计硬度时,由于粘接剂具有适度的硬度,所以可防止因树脂制盒子20与透明板26的线膨胀系数的不同而产生的覆盖透明板26后的固体摄像装置的翘曲的发生,可防止影响摄像元件的摄像性能所以优选。The cured resin (adhesive RE) used in the adhesive layer for closing the opening with the transparent plate also preferably has a small portable durometer A hardness of 80 or less, more preferably 1-50, and still more preferably 1-30. When the adhesive RE has the above-mentioned hardness of a small portable durometer, since the adhesive has moderate hardness, it is possible to prevent the covering of the transparent plate due to the difference in linear expansion coefficient between the resin case 20 and the transparent plate 26. It is preferable that warpage of the solid-state imaging device after 26 years can be prevented from affecting the imaging performance of the imaging element.

体积收缩率,以JIS K6901:1999的附录3所规定的方法为基准,利用室温下硬化的树脂的处理,测定树脂形成组成物及其硬化后的硬化物的密度并根据这些值利用下式算出体积收缩率。The volume shrinkage rate is based on the method stipulated in Appendix 3 of JIS K6901:1999, using the treatment of the resin cured at room temperature, measuring the density of the resin forming composition and the cured product after curing, and calculating from these values using the following formula volumetric shrinkage.

体积收缩率=((D2-D1)/D2)×100Volume shrinkage=((D2-D1)/D2)×100

在此,D1表示硬化前的树脂形成组成物的密度,D2表示硬化的硬化物的密度。UV硬化反应,设为对使用主波长365nm的水银灯,照射约3,000mJ/cm2以上的紫外线而获得的硬化树脂在23±0.1℃下进行测定的。Here, D1 represents the density of the resin-forming composition before curing, and D2 represents the density of the cured product after curing. The UV curing reaction was measured at 23±0.1°C on a cured resin obtained by irradiating ultraviolet rays of approximately 3,000 mJ/cm 2 or more using a mercury lamp with a dominant wavelength of 365 nm.

对于在高于室温的温度下硬化的树脂形成组成物,也可利用上述附录3所规定的方法测定体积收缩率。具体的测定操作,以对环氧树脂或不饱和聚酯树脂规定的操作为准。For resin-forming compositions that harden at temperatures higher than room temperature, the volume shrinkage rate can also be measured by the method specified in Appendix 3 above. The specific measurement operation is subject to the operation specified for epoxy resin or unsaturated polyester resin.

本发明使用的树脂形成组成物随着硬化的体积收缩率在5%以下,优选在4%以下。The resin-forming composition used in the present invention has a volume shrinkage rate of 5% or less, preferably 4% or less, with curing.

体积收缩率在上述范围时,不担心随着硬化树脂的形成而损坏线接合,并且生成的硬化树脂不会从盒子内表面剥离,所以可稳定保持中空盒子的气密性所以优选。When the volume shrinkage ratio is in the above range, there is no fear of damage to the wire bonding due to the formation of the hardened resin, and the formed hardened resin does not peel off from the inner surface of the box, so the airtightness of the hollow box can be stably maintained, so it is preferable.

可利用热硬化性或光硬化性的粘接剂等封闭中空盒子开口端。也可通过透明板照射紫外线而同时硬化盒子内表面被覆用以及透明板封闭用的树脂形成组成物。也可热硬化盒子内表面被覆用树脂形成组成物后,光硬化透明板封闭用的树脂形成组成物。The open end of the hollow box can be closed with a thermosetting or photosetting adhesive or the like. It is also possible to simultaneously harden the resin-forming composition for coating the inner surface of the case and for sealing the transparent plate by irradiating ultraviolet rays through the transparent plate. It is also possible to heat-cure the resin-forming composition for coating the inner surface of the case, and then light-cure the resin-forming composition for sealing the transparent plate.

(实施例A)(Example A)

将在铜合金上镀金的引线框嵌在金属模内,通过注射成形液晶性聚合物[スミカス-バ-E6008B(住友化学(株)制)]获得插设有导线端子的树脂制中空盒子(宽50mm×进深10mm×高4mm、厚2mm)。A lead frame plated with gold on a copper alloy was embedded in a metal mold, and a resin hollow box (wide 50mm×depth 10mm×height 4mm, thickness 2mm).

将上述带导线端子的树脂制中空盒子在等级1,000的净化车间内用超纯水清洗后,浸渍在500ml的超纯水中进行20秒的超声波清洗(38kHz),清洗干燥树脂制中空盒子。在利用粘接剂将线性传感器粘固在该树脂制盒子的内表面上后,利用接合线在线性传感器与导线端子间配线。The above-mentioned resin hollow box with lead terminals was cleaned with ultrapure water in a class 1,000 clean room, then immersed in 500ml of ultrapure water for 20 seconds of ultrasonic cleaning (38kHz), and the resin hollow box was cleaned and dried. After the linear sensor is bonded to the inner surface of the resin case with an adhesive, the linear sensor and the lead terminal are wired with bonding wires.

在配线完的树脂制中空盒子的内表面上,使用喷射器供给紫外线硬化性的硅酮树脂形成组成物[(株)スリ-ボンド制TB3080,23℃下的粘度是500mPa·sec,体积收缩率是2.7%。],并且在透明板26与开口部之间也膜状地赋予同一硅酮树脂形成组成物(粘接剂RE)。利用喷射器供给到盒子内表面上的树脂形成组成物在盒子内表面上大致均匀薄薄铺开。利用水银灯照射约3000mJ/cm2的紫外线(365nm)使树脂形成组成物硬化,获得固体摄像装置。On the inner surface of the resin hollow box after wiring, a UV-curable silicone resin forming composition [TB3080 manufactured by Suri-Bond Co., Ltd., the viscosity at 23°C is 500mPa·sec, and the volume shrinks is supplied using an injector. The rate is 2.7%. ], and the same silicone resin forming composition (adhesive RE) is also applied in a film form between the transparent plate 26 and the opening. The resin-forming composition supplied onto the inner surface of the case by the sprayer is spread substantially uniformly and thinly on the inner surface of the case. The resin-forming composition was cured by irradiating about 3000 mJ/cm 2 of ultraviolet rays (365 nm) with a mercury lamp to obtain a solid-state imaging device.

上述TB3080硬化后的树脂试验片,小型携带式硬度计A硬度是A10。The above-mentioned TB3080 hardened resin test piece has a hardness of A10 on a small portable hardness tester.

紫外线硬化后也没有看到硬化树脂从盒子内表面剥离。There was also no peeling of the hardened resin from the inner surface of the box after UV curing.

(比较例A)(comparative example A)

除了代替在实施例A中使用(株)スリ-ボンド制TB3080而使用(株)スリ-ボンド制TB3164(粘度50,000mPa·sec,体积收缩率0.39%,硬化后的小型携带式硬度计A硬度是A30)外完全一样地实施。利用喷射器供给的树脂形成组成物(硬化树脂32)在盒子内表面上没有均匀铺开,并且盒子内表面与硬化树脂组成物之间容易残留气泡。In Example A, instead of using TB3080 manufactured by Tri-Bond Co., Ltd., TB3164 manufactured by Tri-Bond Co., Ltd. was used (viscosity 50,000 mPa·sec, volume shrinkage rate 0.39%, and the hardness of the small portable hardness tester A after hardening was A30) Exactly the same implementation. The resin forming composition (cured resin 32 ) supplied by the injector is not evenly spread on the case inner surface, and air bubbles tend to remain between the case inner surface and the cured resin composition.

(比较例B)(comparative example B)

除了代替在实施例A中使用(株)スリ-ボンド制TB3080而使用(株)スリ-ボンド制TB3026(粘度19,000mPa·sec,体积收缩率7.5%,硬化后的小型携带式硬度计D硬度是D85)外完全一样地实施。利用喷射器供给的树脂形成组成物(硬化树脂32)在盒子内表面上没有均匀铺开,并且确认利用照射紫外线硬化的树脂从盒子内表面局部剥离。In Example A, instead of using TB3080 manufactured by Tri-Bond Co., Ltd., TB3026 manufactured by Tri-Bond Co., Ltd. (viscosity 19,000 mPa·sec, volume shrinkage rate 7.5%) was used, and the hardness of the small portable hardness tester D after hardening was D85) Exactly the same implementation. The resin-forming composition (cured resin 32 ) supplied by the injector was not evenly spread on the case inner surface, and it was confirmed that the resin cured by irradiating ultraviolet rays was partially peeled off from the case inner surface.

下面说明将透明板贴在盒子上的粘接剂RE。Adhesive RE for attaching the transparent board to the box will be described below.

本发明的固体摄像装置的制造方法,包含以下工序:成形由大致矩形的树脂制底板22和大致垂设在底板22的周缘上的树脂制侧壁24一体形成,并插设金属制导线端子40,且具有开口部的树脂制中空盒子20的工序;在中空盒子20的内底面上粘固固体摄像元件12的工序;  电气连接固体摄像元件12的电极与金属制导线端子40的工序;以及向中空盒子的开口部赋予粘接剂RE,利用透明板26封闭开口部后使粘接剂RE硬化而封闭开口部的工序。该粘接剂RE的粘度在10,000mPa·sec以上,硬化后的粘接剂RE的小型携带式硬度计硬度在A级中是80以下。The manufacturing method of the solid-state imaging device of the present invention includes the following steps: forming a substantially rectangular resin base plate 22 and a resin side wall 24 vertically provided on the periphery of the base plate 22 to form an integral body, and inserting the metal lead terminal 40 , and the process of resin hollow box 20 having an opening; the process of bonding the solid-state imaging element 12 on the inner bottom surface of the hollow box 20; the process of electrically connecting the electrodes of the solid-state imaging element 12 and the metal lead terminal 40; The process of applying the adhesive RE to the opening of the hollow box, closing the opening with the transparent plate 26, and curing the adhesive RE to close the opening. The adhesive RE has a viscosity of 10,000 mPa·sec or more, and the hardness of the hardened adhesive RE is 80 or less in the A class.

以下详细说明。Details are given below.

本发明的固体摄像装置的制造方法中使用的粘接剂RE,粘度在10,000mPa·sec以上,硬化后的小型携带式硬度计硬度在A级中是80以下。在此,粘接剂RE的粘度设为以JIS K7233所述的单一圆筒转动粘度计法为基准测定的。又,硬化后的粘接剂RE的小型携带式硬度计硬度设为以JIS K7215所述的按压硬度测定法为基准测定的。The adhesive RE used in the method of manufacturing the solid-state imaging device of the present invention has a viscosity of 10,000 mPa·sec or more, and a hardness of 80 or less in A-grade hardness after curing. Here, the viscosity of the adhesive RE is measured based on the single cylinder rotational viscometer method described in JIS K7233. In addition, the small-sized portable durometer hardness of the adhesive RE after hardening was measured based on the pressing hardness measurement method described in JIS K7215.

本发明使用的粘接剂,25℃时的粘度是10,000mPa·sec以上,优选是10,000~150,000mPa·sec,更优选是30,000~100,000mPa·sec。在此,上述粘度是以JIS K7233所述的单一圆筒转动粘度计法为基准测定所获得的值。当粘接剂的粘度小于10,000mPa·sec时,该中空盒子与透明板之间的粘接剂层变薄,在该中空盒子上容易发生翘曲或歪斜。The adhesive used in the present invention has a viscosity at 25° C. of 10,000 mPa·sec or more, preferably 10,000 to 150,000 mPa·sec, more preferably 30,000 to 100,000 mPa·sec. Here, the above-mentioned viscosity is a value measured based on the single cylinder rotational viscometer method described in JIS K7233. When the viscosity of the adhesive is less than 10,000 mPa·sec, the adhesive layer between the hollow box and the transparent plate becomes thin, and warpage or distortion easily occurs on the hollow box.

又,本发明使用的粘接剂RE,优选硬化后的小型携带式硬度计硬度(肖氏硬度)在类型A(A级)(也叫做「小型携带式硬度计A硬度」)中是80以下,更优选是1~50,更加优选是1~30。在此上述的小型携带式硬度计硬度是以JIS K7233所述的按压硬度测定法为基准测定所获得的值。当硬化后的粘接剂的小型携带式硬度计硬度是超过80的值时,不能防止因树脂制盒子与透明板的线膨胀系数的不同而产生的覆盖开口部后的固体摄像装置的翘曲的发生,使固体摄像元件的摄像性能下降。In addition, the adhesive RE used in the present invention preferably has a small portable durometer hardness (Shore hardness) of type A (grade A) (also called "small portable durometer A hardness") after hardening is 80 or less , more preferably 1-50, more preferably 1-30. The hardness of the above-mentioned small portable hardness tester is a value obtained by measuring based on the pressing hardness measurement method described in JIS K7233. When the hardness of the hardened adhesive exceeds 80, the warping of the solid-state imaging device after covering the opening due to the difference in linear expansion coefficient between the resin case and the transparent plate cannot be prevented. occurs, the imaging performance of the solid-state imaging element is degraded.

作为将粘接剂RE赋予该中空盒子的开口部的方法,可使用众所周知的方法,例示使用喷射器将粘接剂从喷嘴赋予目标部位的方法。As a method of applying the adhesive RE to the opening of the hollow case, well-known methods can be used, and a method of applying the adhesive to the target site from a nozzle using a sprayer is exemplified.

作为本发明中使用的粘接剂RE,可使用满足上述粘度以及小型携带式硬度计硬度的放射线硬化性、湿气硬化性、或热硬化性的粘接剂,优选使用紫外线硬化性树脂、可见光硬化性树脂、热硬化性树脂、以及湿气硬化性树脂。As the adhesive RE used in the present invention, radiation-curable, moisture-curable, or thermosetting adhesives satisfying the above-mentioned viscosity and hardness of a small portable durometer can be used, preferably ultraviolet-curable resins, visible light Curing resins, thermosetting resins, and moisture-curing resins.

又,本发明中使用的粘接剂,也可同时具有紫外线(数十~400nm)硬化性、可见光(400超~700nm)硬化性、热硬化性或湿气硬化性的性质。In addition, the adhesive used in the present invention may have ultraviolet (tens to 400 nm) curable properties, visible light (400 to 700 nm) curable properties, heat curable properties, or moisture curable properties at the same time.

作为这些树脂的具体例,可例示丙烯酸树脂、环氧树脂、硅酮树脂、不饱和聚酯树脂、酚醛树脂、尿素-三聚氰胺树脂、聚氨脂树脂、聚酰亚胺树脂等。Specific examples of these resins include acrylic resins, epoxy resins, silicone resins, unsaturated polyester resins, phenol resins, urea-melamine resins, polyurethane resins, and polyimide resins.

即使其中,作为本发明中使用的粘接剂,也优选紫外线硬化性树脂。当粘接剂是紫外线硬化性树脂时,可在短时间使其硬化所以生产性强,且硬化时盒子或透明板26的温度上升小,所以不易发生因该中空盒子20与透明板26的线膨胀系数之差产生的翘曲或歪斜等的应力。Among them, ultraviolet curable resins are preferable as the adhesive used in the present invention. When the adhesive is an ultraviolet curable resin, it can be hardened in a short time, so the productivity is strong, and the temperature rise of the box or the transparent plate 26 is small during hardening, so it is difficult to cause a line between the hollow box 20 and the transparent plate 26. Stress such as warpage or skew caused by the difference in expansion coefficient.

紫外线硬化性树脂如上所述。The ultraviolet curable resin is as described above.

在本发明中使用的粘接剂中,也可根据需要,配合用途适当添加聚合开始剂、交联剂、反应促进剂等添加剂,以及二氧化硅等无机填充剂、橡胶成分等,这些添加剂或填充剂等也可适当组合使用。In the adhesive used in the present invention, additives such as polymerization initiators, crosslinking agents, and reaction accelerators, inorganic fillers such as silica, and rubber components can also be added appropriately according to the purpose according to the needs. These additives or Fillers and the like can also be used in appropriate combination.

又,为了调节粘接剂的粘度或调节硬化后的粘接剂的小型携带式硬度计A硬度,可适当将单一功能的硬化性成分设为多功能的硬化性成分,还可同时使用它们。In addition, in order to adjust the viscosity of the adhesive or adjust the hardness of the cured adhesive, the single-functional curable component can be appropriately used as a multi-functional curable component, or they can be used in combination.

本发明的固体摄像装置的制造方法,包含以下工序:成形由大致矩形的树脂制底板22和大致垂设在底板22的周缘上的树脂制侧壁24一体形成,并插设导线端子40,且具有开口部的树脂制中空盒子20的工序;在中空盒子20的内底面上粘固固体摄像元件12的工序;  电气连接固体摄像元件12的电极与金属制导线端子40的工序;以及向中空盒子20的开口部赋予粘接剂RE,利用透明板26封闭开口部后使粘接剂RE硬化而封闭开口部的工序。上述各工序其自身是一般的工序,可使用众所周知的方法。The method for manufacturing a solid-state imaging device according to the present invention includes the steps of forming a substantially rectangular resin base plate 22 integrally formed with a resin side wall 24 vertically provided on the periphery of the base plate 22, inserting the lead terminals 40, and The operation of the hollow box 20 made of resin with an opening; the operation of bonding the solid-state imaging element 12 on the inner bottom surface of the hollow box 20; the operation of electrically connecting the electrodes of the solid-state imaging element 12 and the metal lead terminal 40; The process of applying adhesive RE to the opening of 20 , closing the opening with the transparent plate 26 , and curing the adhesive RE to close the opening. Each of the above-mentioned steps itself is a general step, and a well-known method can be used.

形成本发明中使用的中空盒子20时,可使用在树脂中添加了适当的填充剂的树脂组成物。When forming the hollow box 20 used in this invention, the resin composition which added the appropriate filler to resin can be used.

(实施例I)(Embodiment 1)

将在铜合金上镀金的引线框嵌在金属模内,通过注射成形液晶性聚合物[スミカス-バ-E6008B(住友化学(株)制)]而获得插设有导线端子的树脂制中空盒子(宽50mm×进深10mm×高4mm、厚2mm)。A lead frame plated with gold on a copper alloy was embedded in a metal mold, and a resin hollow box ( Width 50mm×depth 10mm×height 4mm, thickness 2mm).

将上述带导线端子的树脂制中空盒子在等级1,000的净化车间内用超纯水清洗后,浸渍在500ml的超纯水中进行20秒的超声波清洗(38kHz),清洗干燥树脂制中空盒子。在利用粘接剂将线性传感器粘固在该树脂制盒子的内底面上后,利用接合线在线性传感器与导线端子间配线。The above-mentioned resin hollow box with lead terminals was cleaned with ultrapure water in a class 1,000 clean room, then immersed in 500ml of ultrapure water for 20 seconds of ultrasonic cleaning (38kHz), and the resin hollow box was cleaned and dried. After the linear sensor is bonded to the inner bottom surface of the resin case with an adhesive, the linear sensor and the lead terminal are wired with bonding wires.

对配线完的树脂制中空盒子干燥后,在其开口部使用喷射器赋予紫外线硬化性粘接剂密封胶5088[ヘンケルジャパン(株)制,25℃时的粘度:65,000mPa·sec],利用透明板封闭该开口部后,利用水银灯照射约3000mJ/cm2的紫外线(365nm)使粘接剂硬化,获得固体摄像装置。After drying the resin hollow box after wiring, apply UV-curable adhesive sealant 5088 [manufactured by Henkell Japan Co., Ltd., viscosity at 25°C: 65,000mPa·sec] to the opening with a sprayer, and use After closing the opening with a transparent plate, ultraviolet rays (365 nm) of about 3000 mJ/cm 2 were irradiated with a mercury lamp to harden the adhesive to obtain a solid-state imaging device.

上述密封胶5088硬化后的树脂试验片,小型携带式硬度计A硬度是30。The resin test piece after hardening of the above-mentioned sealant 5088 has a hardness of 30 on a small portable durometer A.

在获得的固体摄像装置上,以连结该盒子底板的纵向两端的直线为基准的最大翘曲量是20μm。In the obtained solid-state imaging device, the maximum amount of warpage was 20 μm on the basis of a straight line connecting both longitudinal ends of the bottom plate of the case.

(比较例I)(comparative example 1)

除了在实施例I中使用紫外线硬化性树脂XE17-303[GE东芝硅酮(株)制,25℃时的粘度:4,000mPa·sec,硬化后的小型携带式硬度计A硬度:17]作为粘接剂以外,与实施例1完全一样地制造了固体摄像装置。Except that in Example 1, ultraviolet curable resin XE17-303 [manufactured by GE Toshiba Silicone Co., Ltd., viscosity at 25° C.: 4,000 mPa·sec, small portable durometer A hardness after hardening: 17] was used as the adhesive. A solid-state imaging device was manufactured in exactly the same manner as in Example 1 except for the bonding agent.

获得的固体摄像装置的最大翘曲量是55μm。The maximum warpage amount of the obtained solid-state imaging device was 55 μm.

(比较例II)(Comparative Example II)

除了在实施例I中使用紫外线硬化性树脂XE17-303[ケミテック(株)制,25℃时的粘度:600mPa·sec,硬化后的小型携带式硬度计D硬度:80]作为粘接剂以外,与实施例1完全一样地制造了固体摄像装置。另外,小型携带式硬度计D硬度与小型携带式硬度计A硬度一样,利用以JIS K7215所述的按压硬度测定法为基准的测定获得。In Example 1, UV curable resin XE17-303 [manufactured by Chemitec Co., Ltd., viscosity at 25° C.: 600 mPa·sec, small portable durometer D hardness after hardening: 80] was used as an adhesive, A solid-state imaging device was manufactured in exactly the same manner as in Example 1. In addition, the D hardness of the small portable durometer is the same as the A hardness of the small portable durometer, and is obtained by measurement based on the pressing hardness measurement method described in JIS K7215.

获得的固体摄像装置的最大翘曲量是102μm,且在透明板与树脂制盒子开口部的粘接面的一部分看到了剥离。The maximum warpage amount of the obtained solid-state imaging device was 102 μm, and peeling was observed on a part of the adhesive surface between the transparent plate and the opening of the resin case.

以下,对备有上述的固体摄像元件收纳盒的固体摄像装置的具体结构进行说明。Hereinafter, a specific configuration of a solid-state imaging device including the above-mentioned solid-state imaging device storage case will be described.

图4是备有固体摄像元件收纳盒的固体摄像装置的详细分解立体图。4 is a detailed exploded perspective view of a solid-state imaging device equipped with a solid-state imaging device housing case.

如上所述,固体摄像元件收纳盒20具有固体摄像元件12要配置在起内部的收纳用凹部DP,并备有纵向X的尺寸是宽度方向的尺寸的3倍以上的树脂制的盒主体(中空盒)100,和从收纳用凹部DP的内部经由与盒主体100的纵向X平行的侧壁2 4向外部延伸的多个导线端子40。As described above, the solid-state imaging device storage case 20 has the recessed portion DP for housing in which the solid-state imaging device 12 is to be disposed, and has a resin-made case main body (hollow) in which the dimension in the longitudinal direction X is three times or more the dimension in the width direction. box) 100, and a plurality of lead terminals 40 extending outward from the inside of the storage recess DP via the side wall 24 parallel to the longitudinal direction X of the box main body 100.

该固体摄像装置备有固体摄像元件收纳盒20,设在收纳用凹部DP中的固体摄像元件12,以及封闭收纳用凹部DP的开口的透明板26。盒主体的纵向与横向的纵横比较高,在3以上。当采用液晶性聚合物作为纵横比高的盒主体100的材料时,能够获得在纵向上对齐的高分子的取向状态,耐热性、强度特性、低膨胀性优良。而且,如上所述,优选地是在树脂内包含无机材料构成的填料。即,通过在树脂内含有无机材料构成的填料,能够进一步提高刚性。通过液晶性聚合物与无机材料填料的组合,可构成具有高刚性的盒子。填料由多个纤维状体或针状体构成,各纤维状体或针状体的纵横比为5以上。This solid-state imaging device includes a solid-state imaging device storage case 20, a solid-state imaging device 12 provided in the storage recess DP, and a transparent plate 26 that closes the opening of the storage recess DP. The vertical and horizontal aspect ratio of the box main body is high, more than 3. When a liquid crystalline polymer is used as the material of the cell main body 100 with a high aspect ratio, an alignment state of the polymer aligned in the longitudinal direction can be obtained, and the heat resistance, strength characteristics, and low expansion are excellent. Furthermore, as described above, it is preferable to contain a filler composed of an inorganic material in the resin. That is, rigidity can be further improved by including a filler made of an inorganic material in the resin. A highly rigid case can be constructed by combining a liquid crystalline polymer and an inorganic material filler. The filler is composed of a plurality of fibrous bodies or acicular bodies, and each fibrous body or acicular body has an aspect ratio of 5 or more.

而且,固体摄像元件12的纵横比也为3以上。固体摄像元件12是一维CCD(线形传感器)。由于纵横比高的固体摄像元件12容易挠曲,所以,本发明在使用这种固体摄像元件12的情况下特别有效。另外,固体摄像元件12也可以仅通过岛30的纵向两端部固定在岛30上。Furthermore, the aspect ratio of the solid-state imaging device 12 is also 3 or more. The solid-state imaging device 12 is a one-dimensional CCD (line sensor). Since the solid-state imaging device 12 with a high aspect ratio is easily deflected, the present invention is particularly effective when such a solid-state imaging device 12 is used. In addition, the solid-state imaging device 12 may be fixed to the island 30 only by both longitudinal ends of the island 30 .

在固体摄像元件收纳盒20的纵向两端部上,分别设有加强部105。加强部105与侧壁24一体形成,从盒主体100的纵向两端,沿着纵向X向外突出。加强部105的XY截面与盒主体100的两端部一起构成大致的U字型。加强部105抑制垂直于侧壁24的方向上的翘曲或挠曲。引线框的一部分在加强部105内侧的空间内露出。Reinforcing portions 105 are respectively provided at both ends in the longitudinal direction of the solid-state imaging device housing case 20 . The reinforcing portion 105 is integrally formed with the side wall 24 and protrudes outward along the longitudinal direction X from both longitudinal ends of the box main body 100 . The XY cross-section of the reinforcement part 105 forms a substantially U-shape together with both ends of the cartridge body 100 . The reinforcing portion 105 suppresses warpage or deflection in a direction perpendicular to the side wall 24 . A part of the lead frame is exposed in the space inside the reinforcement part 105 .

盒主体100的侧壁24具有宽度方向Y为深度方向、沿着纵向X延伸的多个凹部(薄壁部、凹槽)104。这样一来,树脂成形时树脂的流动均匀,并且能够进行轻量化。The side wall 24 of the box main body 100 has a plurality of concave portions (thin-walled portions, grooves) 104 extending in the longitudinal direction X in which the width direction Y is the depth direction. In this way, the flow of the resin is uniform during resin molding, and the weight can be reduced.

图5是备有具有狭缝(切口)132的岛30的固体摄像元件收纳盒中央部的立体图。FIG. 5 is a perspective view of a central portion of a solid-state imaging device housing case provided with an island 30 having a slit (notch) 132 .

在盒主体100上,沿着盒主体100的底板22的纵向X、与底板22一体地设有一对树脂制的肋103。通过一对肋103,在其间形成有凹槽LGR。盒主体100是容易产生应变的纵横比小的盒主体,并且,无论是否由树脂构成,在这种装置中,由于具有在纵向X上延伸的肋103,能够抑制垂直于盒主体100的纵向X方向上的翘曲或挠曲。肋103优选有多个,从提高刚性的观点考虑,肋103优选位于侧壁24的高度方向Z的延长线上。A pair of resin-made ribs 103 are integrally provided with the bottom plate 22 of the box main body 100 along the longitudinal direction X of the bottom plate 22 of the box main body 100 . A groove LGR is formed therebetween by a pair of ribs 103 . The case main body 100 is a case main body with a small aspect ratio that tends to be strained, and, regardless of whether it is made of resin, in this device, since there are ribs 103 extending in the longitudinal direction X, the vertical direction X perpendicular to the case main body 100 can be suppressed. Warpage or deflection in direction. There are preferably a plurality of ribs 103, and the ribs 103 are preferably located on the extension line in the height direction Z of the side wall 24 from the viewpoint of improving rigidity.

固体摄像元件收纳盒20设在凹部DP的底面上,备有要固定固体摄像元件12的岛30,与岛30相连续、向沿着盒主体100的纵向的侧壁24内延伸的岛压紧部34。由于岛压紧部34向侧壁24的内部延伸,所以能够限制岛30相对于盒主体100的移动,因此,可抑制岛30的翘曲及固体摄像元件12的翘曲,能够抑制其特性的劣化。而且,还可以经由岛压紧部34向外部进行散热。The solid-state imaging device storage case 20 is provided on the bottom surface of the recess DP, and is provided with an island 30 to fix the solid-state imaging device 12, which is continuous with the island 30 and pressed against the island extending in the side wall 24 along the longitudinal direction of the case main body 100. Section 34. Since the island pressing portion 34 extends toward the inside of the side wall 24, the movement of the island 30 relative to the cartridge main body 100 can be restricted, so that the warping of the island 30 and the solid-state imaging device 12 can be suppressed, and variations in the characteristics thereof can be suppressed. deteriorating. In addition, it is also possible to dissipate heat to the outside via the island pressing portion 34 .

岛30在除了其两端部的位置上备有从宽度方向的一端朝向另一端延伸的狭缝(切口)132。由于应力容易集中在狭缝132附近的岛部分上,该岛部分挠曲,而且吸收膨胀和收缩,所以能够抑制固体摄像元件12的挠曲。The island 30 is provided with slits (notches) 132 extending from one end toward the other end in the width direction at positions other than both ends thereof. Since stress tends to concentrate on the island portion in the vicinity of the slit 132, the island portion bends, and absorbs expansion and contraction, so that the bending of the solid-state imaging element 12 can be suppressed.

而且,固体摄像元件收纳盒20备有至少一对岛压紧部34,其与岛30相连续,向沿着盒主体100的纵向的侧壁24内延伸。一对岛压紧部34在纵向X上是分离的,狭缝132设在一对岛压紧部34之间的中央位置J附近。岛压紧部34的位置限定在沿着岛30的宽度方向的岛压紧部34的中心线的位置。当将一对岛压紧部34之间的距离作为X0,将从一个岛压紧部34的位置到中央位置J的距离作为X1时,从另一个岛压紧部34到中央位置J的距离X2等于X0/2。Furthermore, the solid-state imaging device storage case 20 includes at least a pair of island pressing portions 34 , which are continuous with the island 30 and extend inwardly of the side wall 24 along the longitudinal direction of the case main body 100 . The pair of island pressing parts 34 are separated in the longitudinal direction X, and the slit 132 is provided near the center position J between the pair of island pressing parts 34 . The position of the island pressing part 34 is defined at the position of the center line of the island pressing part 34 along the width direction of the island 30 . When X 0 is the distance between a pair of island pressing portions 34 and X 1 is the distance from the position of one island pressing portion 34 to the central position J, the distance from the other island pressing portion 34 to the central position J is The distance X 2 is equal to X 0 /2.

如上所述,虽然由于存在一对岛压紧部34,到岛30的翘曲受到抑制,但由于一对岛压紧部34的位置固定在侧壁24上,所以应力容易加在其间的岛30的中央位置J的附近。由于在该中央位置J附近设有狭缝132,所以在该位置吸收应力,该岛部分挠曲,而且吸收膨胀和收缩,所以能够抑制固体摄像元件12的挠曲。As described above, although warpage to the island 30 is suppressed due to the presence of the pair of island pressing portions 34, since the positions of the pair of island pressing portions 34 are fixed on the side wall 24, stress is easily applied to the island therebetween. 30 near central location J. Since the slit 132 is provided in the vicinity of the central position J, stress is absorbed at this position, and the island part deflects and absorbs expansion and contraction, so that the deflection of the solid-state imaging device 12 can be suppressed.

狭缝132备有第1狭缝132A和第2狭缝132B,第1狭缝132A从岛30的宽度方向的一端向另一端延伸,第2狭缝132B从岛的宽度方向的另一端向一端延伸,第1狭缝132A和第2狭缝132B隔着中央位置J配置。The slit 132 includes a first slit 132A and a second slit 132B, the first slit 132A extends from one end to the other end in the width direction of the island 30, and the second slit 132B extends from the other end to one end in the width direction of the island. Extending, the first slit 132A and the second slit 132B are disposed across the central position J.

在这种情况下,由于第1狭缝132A的形成位置上的岛30绕纵向扭转的朝向与第2狭缝132B的形成位置上的岛30绕纵向的扭转的朝向相反,所以可抵消岛30绕纵向的扭转,能够抑制岛30的两端部绕纵向的扭转。而且,由于第1狭缝132A和第2狭缝132B具有绕第1狭缝132A及第2狭缝132B之间的岛30上的1点P点对称的倾向,所以在岛30产生了纵向的热膨胀的情况下,岛30的宽度方向相对于岛30的纵向的中心线的移动受到限制。In this case, since the twisting direction of the island 30 in the longitudinal direction at the position where the first slit 132A is formed is opposite to that of the twisting direction in the longitudinal direction of the island 30 at the position where the second slit 132B is formed, the island 30 can be canceled out. The twisting in the longitudinal direction can suppress the twisting in the longitudinal direction of both ends of the island 30 . Moreover, since the first slit 132A and the second slit 132B have a tendency to be symmetrical around a point P on the island 30 between the first slit 132A and the second slit 132B, a longitudinal gap is generated in the island 30. In the case of thermal expansion, the movement of the island 30 in the width direction with respect to the longitudinal center line of the island 30 is restricted.

狭缝132的最深部D由曲面构成。该曲面局部包含以平行于岛30的厚度方向的Z轴为中心的圆筒面。在这种情况下,由于应力集中在狭缝132的形成部位上的岛30上时能够缓和最深部D上的局部应力集中,所以岛30的耐久性优良。而且,由于由曲面构成狭缝的最深部,所以还能够减少成形时产生溢料。The deepest portion D of the slit 132 is formed of a curved surface. The curved surface partially includes a cylindrical surface centered on the Z-axis parallel to the thickness direction of the island 30 . In this case, when stress is concentrated on the island 30 at the portion where the slit 132 is formed, the local stress concentration on the deepest portion D can be alleviated, so the durability of the island 30 is excellent. Furthermore, since the deepest part of the slit is formed of a curved surface, it is also possible to reduce flashing during molding.

在狭缝132的内部填充有比较软的硬化树脂32,狭缝132的形成部位上的岛30容易挠曲,而且能够吸收膨胀和收缩。硬化树脂32涂敷在盒主体100的内表面部上,而且也涂敷在导线端子40和盒主体100的内表面的边界部上。硬化树脂32及RE的小型携带式硬度计硬度在A级中是80以下The interior of the slit 132 is filled with a relatively soft cured resin 32 , and the island 30 at the portion where the slit 132 is formed is easily deflected and can absorb expansion and contraction. The hardening resin 32 is applied on the inner surface portion of the case main body 100 , and is also applied on the boundary portion between the lead terminal 40 and the inner surface portion of the case main body 100 . Hardened resin 32 and RE's small portable durometer hardness is 80 or less in A grade

而且,盒主体100备有与岛30的宽度方向两端接触的一对突起部(突堤部)101。突起部101沿着岛30的纵向延伸。一对突起部101能够抑制岛30的宽度方向的移动。盒主体100备有沿着岛30的纵向延伸的一对凹槽SGR,各突起部101的侧面构成各凹槽SGR的一个侧面。即,在靠近岛30的侧面、盒子的内底面上,抑制其纵向配设有凹槽(槽)SGR,另外,突起部101未设在狭缝132的形成位置上,狭缝132的形成部位上的岛30容易变形。Furthermore, the case main body 100 is provided with a pair of protrusions (embankments) 101 that are in contact with both ends in the width direction of the island 30 . The protrusion 101 extends in the longitudinal direction of the island 30 . The pair of protrusions 101 can suppress movement of the island 30 in the width direction. The case main body 100 is provided with a pair of grooves SGR extending in the longitudinal direction of the island 30, and the side surfaces of each protrusion 101 constitute one side surface of each groove SGR. That is, on the side surface close to the island 30 and the inner bottom surface of the box, the groove (groove) SGR is suppressed from being arranged in the longitudinal direction. In addition, the protrusion 101 is not provided at the formation position of the slit 132, and the formation position of the slit 132 The upper island 30 is easily deformed.

而且,固体摄像元件12的受光面露出,能够使充足光亮的光入射到受先面上。第1硬化树脂32被突起部101外侧的侧面阻挡,不存在于受光面上。因此,根据本固体摄像装置,能够进行正确的摄像。Furthermore, the light-receiving surface of the solid-state imaging device 12 is exposed, so that sufficiently bright light can be incident on the receiving surface. The first cured resin 32 is blocked by the side surface outside the protrusion 101 and does not exist on the light receiving surface. Therefore, according to the solid-state imaging device, accurate imaging can be performed.

透明板26(参照图4)封闭盒主体100的凹部DP,但在盒主体100与透明板26之间加装有第2硬化树脂RE。即,在盒主体100与透明板26之间的接合部上存在硬化树脂RE。第2硬化树脂RE能够粘接透明板26和盒主体100。The transparent plate 26 (see FIG. 4 ) closes the recess DP of the case main body 100 , but the second hardening resin RE is interposed between the case main body 100 and the transparent plate 26 . That is, the cured resin RE exists on the junction between the cartridge main body 100 and the transparent plate 26 . The second curable resin RE can bond the transparent plate 26 and the case main body 100 .

而且,第1硬化树脂32与第2硬化树脂RE是连续的。由于第1硬化树脂32与第2硬化树脂RE可在同一工序中涂敷,所以结构简单。另外,第1硬化树脂32被覆接合线42和导线端子40的连接部(参照图1),能够防止该连接部劣化。Furthermore, the first curable resin 32 is continuous with the second curable resin RE. Since the first curable resin 32 and the second curable resin RE can be applied in the same process, the structure is simple. In addition, the first curable resin 32 covers the connecting portion (see FIG. 1 ) between the bonding wire 42 and the lead terminal 40 , thereby preventing deterioration of the connecting portion.

图6是备有分隔的岛的固体摄像元件收纳盒中央部的立体图。Fig. 6 is a perspective view of the central portion of the solid-state imaging device housing case provided with partitioned islands.

一对岛30、30在盒主体100的纵向上是分开的。即,由于岛30、30分离,在双方的岛30、30之间的盒主体部位100A上未固定有岛100,所以该盒主体部位100A容易挠曲,而且可吸收膨胀和收缩,能够抑制固定摄像元件12的挠曲。The pair of islands 30 , 30 are separated in the longitudinal direction of the box main body 100 . That is, since the islands 30, 30 are separated, the island 100 is not fixed to the box body portion 100A between the islands 30, 30 of both sides, so the box body portion 100A is easy to bend, and expansion and contraction can be absorbed, and the fixing can be suppressed. Deflection of the imaging element 12 .

图7是用于说明固体摄像元件收纳盒的制造方法的图。FIG. 7 is a diagram for explaining a method of manufacturing the solid-state imaging device storage case.

在进行上述固体摄像元件收纳盒的注射成形的情况下,将树脂RE流入在对向面之间具有上述盒子形成的模腔的第1金属模M1和第2金属模M2之间。第1金属模M1和第2金属模M2构成盒子成形用金属模。在第1金属模M1和第2金属模M2之间插入有引线框。In the case of performing injection molding of the solid-state imaging device storage case, the resin RE is poured between the first mold M1 and the second mold M2 having the cavity formed by the case between opposing surfaces. The first mold M1 and the second mold M2 constitute a box molding mold. A lead frame is inserted between the first mold M1 and the second mold M2.

第2金属模M2具有在Z方向上延伸的锥状树脂导入孔M21,并具有从树脂导入孔M21的前端在X方向上延伸的联络通路M22。联络通路22的前端部构成浇口部,树脂RE1从此处被导入模腔内,树脂沿着X方向流入模腔内。因此,在树脂RE1为液晶性聚合物的情况下,构成其的高分子的取向在X方向上对齐。The second mold M2 has a tapered resin introduction hole M21 extending in the Z direction, and has a communication path M22 extending in the X direction from the tip of the resin introduction hole M21. The front end portion of the communication passage 22 constitutes a gate portion, from which the resin RE1 is introduced into the cavity, and the resin flows into the cavity along the X direction. Therefore, when the resin RE1 is a liquid crystalline polymer, the orientations of the polymers constituting it are aligned in the X direction.

在树脂填充、固化后,通过贯通第1金属模M1的多个推杆EP,将固化的树脂向第2金属模M2的方向推压时,完成固体摄像元件收纳盒。即,本发明的方法包含将树脂注入金属模M1、M2的模腔部中进行固化的工序。之后,将固体摄像元件12粘固、连接在岛30上,通过线接合线电气连接固体摄像元件12和导线端子40,最后,用透明板26封闭盒子的上部开口,完成上述的固体摄像装置。After the resin is filled and cured, when the solidified resin is pushed in the direction of the second mold M2 by a plurality of push pins EP penetrating the first mold M1, the solid-state imaging device housing case is completed. That is, the method of the present invention includes a step of injecting and curing resin into the cavities of the molds M1 and M2. Afterwards, the solid-state imaging device 12 is bonded and connected to the island 30, and the solid-state imaging device 12 and the wire terminal 40 are electrically connected by wire bonding. Finally, the upper opening of the box is closed with a transparent plate 26, and the above-mentioned solid-state imaging device is completed.

如上所述,上述的固体摄像装置的制造方法按以下顺序设置:As described above, the above-mentioned method of manufacturing a solid-state imaging device is set up in the following order:

(I)成形由大致矩形的树脂制底板22以及大致垂设在底板22周缘上的树脂制侧壁24一体形成,并插设金属制导线端子40,且开口部可被透明板26封闭的热可塑性树脂制中空盒子20的工序;(II)在盒子20的内底面上粘固固体摄像元件12的工序;(III)利用接合线电气连接该固体摄像元件12的电极与该金属制导线端子40的工序;(IV)由透明板26封闭盒子开口部的工序。(1) Forming is integrally formed by a substantially rectangular resin base plate 22 and a resin side wall 24 approximately vertically placed on the periphery of the base plate 22, and a metal lead terminal 40 is inserted, and the opening can be closed by a transparent plate 26. The process of the hollow box 20 made of plastic resin; (II) the process of bonding the solid-state imaging element 12 on the inner bottom surface of the box 20; (III) electrically connecting the electrodes of the solid-state imaging element 12 and the metal lead terminal 40 with bonding wires (IV) the process of closing the opening of the box with the transparent plate 26.

而且,具有从以下工序中选出的任何一个工序:And, have any one process selected from the following processes:

(i)通过在该盒子内表面赋予硬化树脂形成组成物A并使其硬化而形成硬化树脂A(32),从而利用硬化树脂覆盖盒子内表面的至少一部分以及/或盒子内的该导线端子40与盒子内表面的分界部的工序,以及(ii)在盒子的开口部的与该透明板26接触的部位赋予硬化树脂组成物B(RE),并利用透明板26封闭该开口部后,利用硬化树脂组成物B硬化后的硬化树脂B封死开口部的工序。(i) Form hardening resin A (32) by imparting hardening resin forming composition A on the inner surface of the case and hardening it, thereby covering at least a part of the inner surface of the case and/or the lead terminal 40 inside the case with the hardening resin The process of the boundary portion with the inner surface of the case, and (ii) applying hardened resin composition B (RE) to the portion of the opening of the case that is in contact with the transparent plate 26, and after closing the opening with the transparent plate 26, use A step of sealing the opening with the cured resin B after the cured resin composition B has been cured.

硬化树脂形成组成物A的粘度在5000mPa·sec以下。该硬化树脂形成组成物A是伴随硬化树脂形成组成物A的硬化的体积收缩率在5%以下的硬化树脂形成组成物A,在上述硬化性树脂形成组成物A上照射紫外线、形成硬化树脂A时,硬化树脂A的重量在硬化前的硬化性树脂形成组成物A的重量的99.8%以上、100%以下。The viscosity of cured resin-forming composition A is 5000 mPa·sec or less. The curable resin-forming composition A is a curable resin-forming composition A having a volume shrinkage rate of 5% or less due to the curing of the curable resin-forming composition A, and the curable resin-forming composition A is irradiated with ultraviolet rays to form the curable resin A In this case, the weight of the curable resin A is 99.8% or more and 100% or less of the weight of the curable resin forming composition A before hardening.

另外,上述工序(i)是,在中空盒子内表面上赋予紫外线硬化性的硬化树脂形成组成物A,通过封死的透明板26照射紫外线使树脂形成组成物A成为硬化树脂A,从而利用硬化树脂32覆盖中空盒子内表面的至少一部分以及盒子内的该金属制导线端子40与树脂部分的分界部的工序。In addition, the above-mentioned step (i) is to impart ultraviolet curable curable resin forming composition A on the inner surface of the hollow box, and irradiate ultraviolet rays through the sealed transparent plate 26 to make resin forming composition A into curable resin A, thereby utilizing hardening A step of covering at least a part of the inner surface of the hollow case with the resin 32 and the boundary portion between the metal lead terminal 40 and the resin portion in the case.

而且,如上所述,硬化性树脂形成组成物B的粘度优选在10000mPa·sec以上。Furthermore, as described above, the viscosity of the curable resin-forming composition B is preferably 10000 mPa·sec or more.

硬化树脂形成组成物B优选是紫外线硬化性的,上述工序(ii)是,在中空盒子上面与透明板26之间赋予紫外线硬化性的树脂形成组成物B(RE),通过该透明板26照射紫外线而使该树脂形成组成物B成为硬化树脂从而封闭该盒子的工序。The curable resin forming composition B is preferably ultraviolet curable, and the above step (ii) is to impart ultraviolet curable resin forming composition B (RE) between the upper surface of the hollow box and the transparent plate 26, and irradiate through the transparent plate 26. The process of sealing the box by turning the resin-forming composition B into a hardened resin by ultraviolet rays.

Claims (18)

1, a kind of solid camera head, have by the resin system base plate of essentially rectangular and the roughly vertical resin system sidewall that is located on its periphery integrally formed, and plug the metallic conductor terminal, the thermoplastic resin system hollow case that peristome is sealed by transparent panel, the inner bottom surface of this hollow case is provided with the metallic island, cementation has solid-state imager on this island, it is characterized in that:
(a) inner surface portion of above-mentioned hollow case,
(b) the boundary portion of above-mentioned metallic conductor terminal and above-mentioned hollow case inner surface and
(c) junction surface of above-mentioned hollow case and above-mentioned transparent panel
Certain 1 position on, the configuration hardening resin forms the hardening resin after the constituent sclerosis, the duro-meter hardness of aforementioned hardening resin is below 80 in the A level.
2, solid camera head as claimed in claim 1 is characterized in that: aforementioned hardening resin comprises at least a kind that selects from epoxy resin, unsaturated polyester resin, phenolic resins, urea-Melamine resin sheet, polyurethane resin, silicone resin, polyimide resin and acrylic resin group.
3, solid camera head as claimed in claim 1 is characterized in that: on above-mentioned metallic island along the jetty portion that vertically is provided with of above-mentioned solid-state imager.
4, solid camera head as claimed in claim 1 is characterized in that: the side near above-mentioned metallic island on the inner bottom surface of above-mentioned box, vertically is equipped with groove along it.
5, solid camera head as claimed in claim 1 is characterized in that: aforementioned hardening resin constituent comprises uv-hardening resin.
6, a kind of manufacture method of solid-state imager is provided with in the following order:
(I) be shaped integrally formedly, and plug the metallic conductor terminal by the resin system base plate of essentially rectangular and the roughly vertical resin system sidewall that is located on this base plate periphery, and the operation of the thermoplastic resin system hollow case that can be sealed by transparent panel of peristome;
(II) operation of cementation solid-state imager on the inner bottom surface of this box;
(III) utilize closing line to be electrically connected the operation of electrode and this metallic conductor terminal of this solid-state imager;
(IV) seal the operation of this box peristome by transparent panel;
It is characterized in that having some operations of from following operation, selecting:
(i) form constituent A and make its sclerosis form hardening resin A by give hardening resin at this box inner surface, thereby utilize at least a portion that hardening resin covers this box inner surface with and/or this box in this conductor terminal and the operation of the boundary portion of this box inner surface, and
(ii) give hardening resin constituent B at the position that contacts with this transparent panel of the peristome of this box, above-mentioned hardening resin forms the viscosity of constituent B more than 10000mPasec, and after utilizing transparent panel to seal this peristome, utilize hardening resin B after this hardening resin constituent B sclerosis to shut the operation of this peristome.
7, the manufacture method of solid camera head as claimed in claim 6 is characterized in that: above-mentioned hardening resin forms the viscosity of constituent A below 5000mPasec.
8, the manufacture method of solid camera head as claimed in claim 6 is characterized in that: follow above-mentioned hardening resin to form the cubical contraction of sclerosis of constituent A below 5%.
9, the manufacture method of solid camera head as claimed in claim 6 is characterized in that: it is UV cured property that above-mentioned hardening resin forms constituent A.
10, the manufacture method of solid camera head as claimed in claim 9, it is characterized in that: when above-mentioned hardening resin formed irradiation ultraviolet radiation on the constituent A, formation hardening resin A, the weight of this hardening resin A was at more than 99.8% of weight of presclerotic hardening resin formation constituent A, below 100%.
11, the manufacture method of solid camera head as claimed in claim 9, it is characterized in that: above-mentioned operation (i) is, the hardening resin of giving UV cured property on above-mentioned hollow case inner surface forms constituent A, make this resin-shaped become constituent A to become hardening resin A by the transparent panel irradiation ultraviolet radiation of shutting, thus utilize at least a portion that hardening resin covers this hollow case inner surface with and/or this box in this metallic conductor terminal and the operation of the boundary portion of resin part.
12, the manufacture method of solid camera head as claimed in claim 6 is characterized in that: it is UV cured property that this hardening resin forms constituent B.
13, the manufacture method of solid camera head as claimed in claim 12, it is characterized in that: above-mentioned operation (ii) is, on above-mentioned hollow case with transparent panel between give UV cured property resin-shaped become constituent B, thereby make this resin-shaped become constituent B to become the operation that hardening resin seals this box by this transparent panel irradiation ultraviolet radiation.
14, a kind of solid camera head that utilizes the described manufacture method of claim 6 to make.
15, a kind of solid camera head is characterized in that: have:
Resinous box main body with recess;
Be located at the island on the bottom surface of above-mentioned recess;
Be fixed on the solid-state imager on the above-mentioned island;
Sidewall via above-mentioned box main body in the above-mentioned recess extends to outside conductor terminal;
The closing line that connects above-mentioned solid-state imager and above-mentioned conductor terminal;
With above-mentioned to the Width two ends contact, along above-mentioned arrive vertically more than a pair of jut;
With contacted the 1st hardening resin of each outer lateral side of above-mentioned jut.
16, solid camera head as claimed in claim 15 is characterized in that: have:
Seal the transparent panel of the recess of above-mentioned box main body;
Be installed at the 2nd hardening resin between above-mentioned box main body and the above-mentioned transparent panel.
17, solid camera head as claimed in claim 16 is characterized in that: above-mentioned the 1st hardening resin and above-mentioned the 2nd hardening resin are continuous.
18, solid camera head as claimed in claim 15 is characterized in that: the be covered connecting portion of above-mentioned closing line and above-mentioned conductor terminal of above-mentioned the 1st hardening resin.
CN200610071648A 2005-03-25 2006-03-27 Solid-state imaging device and manufacturing method thereof Expired - Fee Related CN100576553C (en)

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CN102176549A (en) * 2010-12-30 2011-09-07 蔡彭博 Transparent security box of cable intermediate head

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TW200820386A (en) * 2006-07-21 2008-05-01 Sumitomo Chemical Co Case for housing solid-state imaging element, manufacturing method thereof, and solid-state imaging device
JP5684491B2 (en) * 2010-04-27 2015-03-11 セミコンダクター・コンポーネンツ・インダストリーズ・リミテッド・ライアビリティ・カンパニー Semiconductor device and manufacturing method thereof
JP2012079914A (en) * 2010-10-01 2012-04-19 Mitsubishi Electric Corp Power module and method for manufacturing the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102176549A (en) * 2010-12-30 2011-09-07 蔡彭博 Transparent security box of cable intermediate head

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