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CN100442572C - Organic Electroluminescence Panel - Google Patents

Organic Electroluminescence Panel Download PDF

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CN100442572C
CN100442572C CNB2004100310875A CN200410031087A CN100442572C CN 100442572 C CN100442572 C CN 100442572C CN B2004100310875 A CNB2004100310875 A CN B2004100310875A CN 200410031087 A CN200410031087 A CN 200410031087A CN 100442572 C CN100442572 C CN 100442572C
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electrode
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light
panel
diffuse reflection
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CN1541031A (en
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大下勇
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Tohoku Pioneer Corp
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/80Constructional details
    • H10K59/8791Arrangements for improving contrast, e.g. preventing reflection of ambient light
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
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Abstract

一种有机电致发光面板及其制造方法,可以防止由于入射到面板内的外部入射光被面板内的漫反射部反射而导致的显示性能劣化。在支撑基板11的一面上设置由圆偏振片构成的光学滤波器18,在支撑基板11的另一面形成有机EL元件,所述有机EL元件具有第一电极12和第二电极14以及夹在该第一、第二电极间的有机层13,第一电极12和第二电极14至少一方由透明电极构成,所述有机层13至少含有发光层,利用粘接剂16把形成有用于密封该有机EL元件的密封凹部15A的密封部件15粘贴到支撑基板11的另一面上。密封凹部15A中的斜面a为粗糙面而形成漫反射部,在支撑基板11的另一面上设置第二电极14的延伸部14A,使其遮盖该斜面a,形成漫反射防止单元。

Figure 200410031087

An organic electroluminescence panel and a manufacturing method thereof, capable of preventing display performance degradation caused by external incident light entering the panel being reflected by a diffuse reflection part in the panel. An optical filter 18 made of a circular polarizing plate is provided on one side of the supporting substrate 11, and an organic EL element is formed on the other side of the supporting substrate 11. The organic EL element has a first electrode 12 and a second electrode 14 and is sandwiched between the In the organic layer 13 between the first and second electrodes, at least one of the first electrode 12 and the second electrode 14 is made of a transparent electrode. The organic layer 13 contains at least a light-emitting layer. The sealing member 15 of the sealing recess 15A of the EL element is pasted on the other surface of the support substrate 11 . The slope a in the sealing recess 15A is a rough surface to form a diffuse reflection part, and the extension part 14A of the second electrode 14 is provided on the other surface of the support substrate 11 to cover the slope a to form a diffuse reflection preventing means.

Figure 200410031087

Description

有机电致发光面板 Organic Electroluminescence Panel

技术领域 technical field

本发明涉及一种有机电致发光(Electroluminescence,下面简称为EL)面板及其制造方法。The invention relates to an organic electroluminescence (EL) panel and a manufacturing method thereof.

背景技术 Background technique

专利文献1:特开平8-321381号公报Patent Document 1: JP-A-8-321381

专利文献2:特开平9-127885号公报Patent Document 2: Japanese Unexamined Patent Publication No. 9-127885

有机EL面板是以有机EL元件为基本结构,把该有机EL元件作为单位面发光部件排列在平面基板上而形成的,该有机EL元件是通过在支撑基板上形成第一电极,在其上形成包含由有机化合物构成的发光层的有机层,再在其上形成第二电极而构成的。The organic EL panel is based on an organic EL element, which is formed by arranging the organic EL element as a unit surface light-emitting component on a flat substrate. The organic EL element is formed by forming a first electrode on a supporting substrate, and then forming An organic layer including a light-emitting layer made of an organic compound, on which a second electrode is formed.

在该有机EL元件中,将所述第一电极、第二电极中的一方制成由ITO等构成的透明电极,同时将另一方制成由Al、Mg等构成的光反射性金属电极,从透明电极侧获取由发光层等发出的光。可以考虑以下方式:将透明的支撑基板上的第一电极制成透明电极,从支撑基板侧获取光的底部发光(bottom emission)方式;将支撑基板上的第一电极制成金属电极,同时将第二电极制成透明电极,从第二电极侧获取光的顶部发光(top emission)方式。In this organic EL element, one of the first electrode and the second electrode is made of a transparent electrode made of ITO or the like, while the other is made of a light-reflective metal electrode made of Al, Mg, or the like. The transparent electrode side acquires light emitted from the light emitting layer and the like. The following methods can be considered: the first electrode on the transparent support substrate is made into a transparent electrode, and the bottom emission (bottom emission) method in which light is obtained from the side of the support substrate; the first electrode on the support substrate is made into a metal electrode, and at the same time the The second electrode is made of a transparent electrode, and a top emission method is used to obtain light from the second electrode side.

在这种有机EL元件中,为了使由发光层等发出的光从透明电极侧有效射出,使与透明电极相对设置的金属电极为高反射率以提高发光亮度。可是,由于对从外部入射到面板内的光而言,金属电极也成为高反射率的反射镜而反射该光,因此产生以下问题:由于该外部入射光,在非发光时映出外界景色,而在发光时对比度降低或处于不能显示黑色等的状态,显示性能降低。In such an organic EL element, in order to efficiently emit light emitted from the light-emitting layer or the like from the transparent electrode side, the metal electrode provided opposite to the transparent electrode has a high reflectance to increase luminance. However, since the metal electrode also serves as a reflective mirror with high reflectance to reflect the light incident on the panel from the outside, the following problems arise: the outside scene is reflected when the light is not emitted due to the external incident light, On the other hand, when the light is emitted, the contrast is lowered, or black is not displayed, and the display performance is lowered.

作为处理该问题的有效对策,提出了专利文献1、2中记载的技术方案。该技术方案是在有机EL面板的光射出面上设置由圆偏振片构成的光学滤波器。这样,虽然从外部入射并通过圆偏振片的光成为右或左圆偏振光,但在通过面板内的金属电极反射该圆偏振光时,圆偏振光的方向发生翻转,所以从外部入射又由面板内的金属电极反射回来的光被圆偏振片截止,不能射出到外部。As effective countermeasures for dealing with this problem, the technical solutions described in Patent Documents 1 and 2 have been proposed. The technical solution is to arrange an optical filter composed of a circular polarizing plate on the light exit surface of the organic EL panel. In this way, although the light incident from the outside and passing through the circular polarizing plate becomes right or left circularly polarized light, when the circularly polarized light is reflected by the metal electrodes in the panel, the direction of the circularly polarized light is reversed, so the light incident from the outside is changed by The light reflected by the metal electrodes in the panel is cut off by the circular polarizer and cannot be emitted to the outside.

另一方面,已知当所述有机层和电极暴露于外气中时,有机EL面板的特性会劣化。这是由于水分浸入有机层和电极的界面而妨碍了电子注入、产生非发光区域或电极腐蚀现象而造成的,为了提高有机EL元件的稳定性和耐久性,使有机EL元件隔绝于外气的密封技术是必不可少的。关于该密封技术,一般采用以下方法:在形成有电极和有机层的支撑基板上,通过粘接剂粘贴覆盖该电极和有机层的密封部件。On the other hand, it is known that the characteristics of an organic EL panel deteriorate when the organic layers and electrodes are exposed to outside air. This is caused by the penetration of water into the interface between the organic layer and the electrode, which hinders electron injection, produces a non-luminous area, or causes corrosion of the electrode. In order to improve the stability and durability of the organic EL element, it is necessary to isolate the organic EL element from the outside air. Sealing technology is essential. As for this sealing technique, a method of affixing a sealing member covering the electrodes and the organic layer with an adhesive to a support substrate on which the electrodes and the organic layer are formed is generally employed.

图1是表示以往的具有密封部件的有机EL面板的说明图。有机EL面板1中,在支撑基板2的一面上形成有有机EL元件,该有机EL元件是将由透明电极构成的第一电极3、含有发光层的有机层4和由金属电极构成的第二电极5层叠而成的,该有机EL元件由通过粘接剂6粘贴在支撑基板2的一面上的密封部件7所密封。另外,在支撑基板2的另一面上设置有由前述的圆偏振片构成的光学滤波器8。FIG. 1 is an explanatory view showing a conventional organic EL panel having a sealing member. In the organic EL panel 1, an organic EL element is formed on one side of a support substrate 2. The organic EL element is formed by a first electrode 3 composed of a transparent electrode, an organic layer 4 including a light emitting layer, and a second electrode composed of a metal electrode. 5, the organic EL element is sealed by a sealing member 7 bonded to one side of the support substrate 2 with an adhesive 6. In addition, on the other surface of the support substrate 2, the optical filter 8 composed of the aforementioned circular polarizing plate is provided.

此处,作为密封部件7多使用玻璃制基板,也有用包含隔离物的粘接剂6粘贴平坦的玻璃基板的情况,但一般如图1所示,在密封部件7的一面侧形成由密封凹部7A形成的密封空间,在该密封凹部7A的底面上设置有干燥剂9。这种密封凹部7A通常是通过利用研磨材料进行喷砂处理或使用药液进行蚀刻处理而形成的,但是用这种方法,密封凹部7A的斜面a成为粗糙面,在该处形成了漫反射部。Here, a glass substrate is often used as the sealing member 7, and a flat glass substrate is also bonded with an adhesive 6 containing a spacer. However, as shown in FIG. In the sealed space formed by 7A, the desiccant 9 is provided on the bottom surface of the sealed concave portion 7A. Such a sealing recess 7A is usually formed by blasting with an abrasive material or etching with a chemical solution, but in this method, the slope a of the sealing recess 7A becomes a rough surface, and a diffuse reflection portion is formed there. .

在这种以往的有机EL元件1中,来自外部的光L01通过光学滤波器8入射到面板内时,成为右或左方向的圆偏振光L02,其被由金属电极构成的第二电极5镜面反射后,成为方向相反的圆偏振光L03。因此,如前面所述,从外部入射并被第二电极5反射后的光被光学滤波器8截止,不能射出到外部。但是,如前面所述,如果在面板内形成有漫反射部,则即使来自外部的光L11通过光学滤波器8入射到面板内而成为右或左方向的圆偏振光L12,也会被漫反射部反射成为偏振面紊乱的光L13,所以产生通过光学滤波器8的反射光L14,局部地产生光学滤波器8不能有效起作用的部位。In such a conventional organic EL element 1, when light L 01 from the outside enters the panel through the optical filter 8, it becomes circularly polarized light L 02 in the right or left direction, which is captured by the second electrode composed of a metal electrode. 5 After specular reflection, it becomes circularly polarized light L 03 in the opposite direction. Therefore, as described above, the light incident from the outside and reflected by the second electrode 5 is cut off by the optical filter 8 and cannot be emitted to the outside. However, as described above, if the diffuse reflection part is formed in the panel, even if the light L 11 from the outside enters the panel through the optical filter 8 and becomes circularly polarized light L 12 in the right or left direction, it will be detected. The diffuse reflection part reflects the light L 13 having a disordered polarization plane, so that reflected light L 14 passing through the optical filter 8 is generated, and a portion where the optical filter 8 cannot function effectively occurs locally.

因此,产生以下问题:在发光时在面板的周边部等射出反射光而导致对比度降低,而在非发光时产生外部景色被映出的现象而使显示性能劣化。Therefore, there arises a problem that the contrast is lowered due to reflected light emitted from the peripheral portion of the panel etc. during light emission, and the external scenery is reflected during non-light emission, thereby deteriorating display performance.

发明内容 Contents of the invention

本发明将解决这种问题作为一个课题。即,本发明的目的在于,防止由于入射到面板内的外部入射光被面板内的漫反射部反射而导致显示性能劣化。The present invention makes it a subject to solve such a problem. That is, an object of the present invention is to prevent display performance from deteriorating due to external incident light entering the panel being reflected by the diffuse reflection portion within the panel.

为了达到上述目的,本发明至少具备以下的构成。In order to achieve the above objects, the present invention has at least the following configurations.

一种有机EL面板,在支撑基板的一面上设置由圆偏振片构成的光学滤波器,在所述支撑基板的另一面上形成有机EL元件,所述有机EL元件具有第一电极和第二电极以及夹在该第一、第二电极之间的有机层,所述第一电极和第二电极至少一方由透明电极构成,所述有机层至少含有发光层,在所述另一面上粘贴着形成有用于密封所述有机EL元件的密封凹部的密封部件,其特征在于,所述密封部件由玻璃形成,在所述密封凹部的底面设置有干燥剂,该密封凹部的斜面为粗糙面,在支撑基板的设置光学滤波器的面之外的另一面上设有漫反射防止单元,该漫反射防止单元防止入射到所述有机电致发光面板内的外部入射光被所述密封凹部的粗糙面反射。An organic EL panel, an optical filter composed of a circular polarizing plate is provided on one side of a supporting substrate, an organic EL element is formed on the other side of the supporting substrate, and the organic EL element has a first electrode and a second electrode and an organic layer sandwiched between the first and second electrodes, at least one of the first electrode and the second electrode is made of a transparent electrode, the organic layer includes at least a light-emitting layer, and is formed by pasting on the other surface There is a sealing member for sealing the sealing recess of the organic EL element, wherein the sealing member is formed of glass, a desiccant is provided on the bottom surface of the sealing recess, the slope of the sealing recess is a rough surface, and the support Anti-diffuse reflection means for preventing external incident light entering the organic electroluminescent panel from being reflected by the rough surface of the sealing recess is provided on the surface of the substrate other than the surface on which the optical filter is provided. .

附图说明 Description of drawings

图1是现有技术的说明图。FIG. 1 is an explanatory diagram of the prior art.

图2是说明本发明的实施方式涉及的有机EL面板的说明图。FIG. 2 is an explanatory diagram illustrating an organic EL panel according to an embodiment of the present invention.

图3是说明本发明的另一实施方式涉及的有机EL面板的说明图。FIG. 3 is an explanatory diagram illustrating an organic EL panel according to another embodiment of the present invention.

图4是说明本发明的再一实施方式涉及的有机EL面板的说明图。FIG. 4 is an explanatory diagram illustrating an organic EL panel according to still another embodiment of the present invention.

符号说明Symbol Description

10、20、30:有机EL面板;11:支撑基板;12:第一电极;13:有机层;14:第二电极;14A:延伸部;15:密封部件;15A密封凹部;15B:切口部;16:粘接剂;17:干燥剂;18:光学滤波器。10, 20, 30: organic EL panel; 11: supporting substrate; 12: first electrode; 13: organic layer; 14: second electrode; 14A: extension; 15: sealing member; 15A sealing recess; 15B: notch ; 16: adhesive; 17: desiccant; 18: optical filter.

具体实施方式 Detailed ways

以下,参照附图说明本发明的实施方式。图2是表示本发明的一实施方式涉及的有机EL面板的说明图。首先,说明本发明的实施方式涉及的有机EL面板10的基本结构,在支撑基板11的一面上设置由圆偏振片构成的光学滤波器18,在所述支撑基板11的另一面上形成有机EL元件,所述有机EL元件具有第一电极12和第二电极14以及夹在该第一、第二电极之间的有机层13,所述第一电极12和第二电极14至少一方由透明电极构成,所述有机层13至少含有发光层,利用粘接剂16把形成有用于密封所述有机EL元件的密封凹部15A的密封部件15粘贴在支撑基板11的另一面上。在以下所示的实施方式中,以支撑基板11侧为光射出面的底部发光方式为例,但本发明不限定于此。Hereinafter, embodiments of the present invention will be described with reference to the drawings. FIG. 2 is an explanatory view showing an organic EL panel according to an embodiment of the present invention. First, the basic structure of the organic EL panel 10 according to the embodiment of the present invention will be described. An optical filter 18 composed of a circular polarizing plate is provided on one side of a support substrate 11, and an organic EL panel is formed on the other surface of the support substrate 11. The organic EL element has a first electrode 12 and a second electrode 14 and an organic layer 13 sandwiched between the first and second electrodes, at least one of the first electrode 12 and the second electrode 14 is formed by a transparent electrode The organic layer 13 includes at least a light-emitting layer, and the sealing member 15 formed with the sealing recess 15A for sealing the organic EL element is attached to the other surface of the supporting substrate 11 with an adhesive 16 . In the embodiments described below, the bottom emission method in which the supporting substrate 11 side is the light exit surface is taken as an example, but the present invention is not limited thereto.

而且,在密封部件15上形成的密封凹部15A的底面上安装有干燥剂17,该密封凹部15A的斜面a为粗糙面,形成漫反射部。有时这种漫反射部不仅是由所述斜面a形成的,而是在各种形成过程中形成在面板内的。以下的各实施方式具有防止入射到面板内的外部入射光被这种漫反射部反射的漫反射防止单元,这样,不会出现外部入射光被漫反射部反射并通过光学滤波器18射出的情况,可以在支撑基板整个面上确保光学滤波器18的功能,防止有机EL面板的显示性能劣化。Furthermore, the desiccant 17 is attached to the bottom surface of the sealing recess 15A formed on the sealing member 15, and the slope a of the sealing recess 15A is a rough surface, forming a diffuse reflection part. Sometimes such a diffuse reflection part is not only formed by the slope a, but is formed in the panel during various forming processes. Each of the following embodiments has a diffuse reflection prevention means that prevents external incident light entering the panel from being reflected by such a diffuse reflection part, so that external incident light does not reflect by the diffuse reflection part and exit through the optical filter 18. Therefore, the function of the optical filter 18 can be ensured on the entire surface of the supporting substrate, thereby preventing deterioration of the display performance of the organic EL panel.

以下说明各个实施方式的特征。在以下说明中,以由斜面a形成的漫反射部为例进行说明,但对其他漫反射部也可以进行相同处理。在图2所示的实施方式中,在支撑基板11的另一面上设置由光反射性电极构成的第二电极14的延伸部14A,使其遮盖密封凹部15A的斜面a,形成漫反射防止单元。Features of each embodiment will be described below. In the following description, the diffuse reflection part formed by the slope a is used as an example for description, but the same process can also be performed on other diffuse reflection parts. In the embodiment shown in FIG. 2 , an extension 14A of the second electrode 14 made of a light-reflective electrode is provided on the other surface of the support substrate 11 so as to cover the slope a of the sealing recess 15A to form a diffuse reflection prevention unit. .

在图2的实施方式中,设置了第二电极14的延伸部,但也可以设置由透明电极构成的第一电极12的延伸部,并在其表面上层叠光反射性材料。In the embodiment shown in FIG. 2 , an extension of the second electrode 14 is provided, but an extension of the first electrode 12 made of a transparent electrode may be provided and a light reflective material may be laminated on the surface.

根据这些实施方式,来自外部的光L21通过光学滤波器18入射到面板内而成为右或左方向的圆偏振光L22,但不会到达由斜面a形成的漫反射部,而是全部被第二电极14等的反射面反射。因此,圆偏振光L22通过被第二电极14等的反射面反射而成为反方向的圆偏振光L23,由于其被光学滤波器18截止,所以反射光不会射出到外部。According to these embodiments, the light L 21 from the outside enters the panel through the optical filter 18 and becomes circularly polarized light L 22 in the right or left direction. The reflection surface of the second electrode 14 etc. reflects. Therefore, the circularly polarized light L 22 is reflected by the reflective surface of the second electrode 14 or the like to become circularly polarized light L 23 in the reverse direction, and since this is cut off by the optical filter 18 , the reflected light is not emitted to the outside.

图3是表示本发明的另一实施方式涉及的有机EL面板的说明图。对相同部分赋予相同符号,省略重复部分的说明。该实施方式涉及的有机EL面板20的基本结构和前述的有机EL元件10相同,但作为漫反射防止单元,通过使斜面a不朝向光射出侧来根本性地解决问题。即,为了使密封凹部15A的斜面a不朝向支撑基板11侧,在密封凹部15A的底面上形成切口部15B,由此使斜面a和底面的夹角不是直角而是锐角。FIG. 3 is an explanatory view showing an organic EL panel according to another embodiment of the present invention. The same symbols are given to the same parts, and descriptions of overlapping parts are omitted. The basic structure of the organic EL panel 20 according to this embodiment is the same as that of the above-mentioned organic EL element 10 , but the problem is fundamentally solved by making the slope a not face the light emitting side as the diffuse reflection preventing means. That is, the notch 15B is formed on the bottom surface of the sealing recess 15A so that the slope a of the sealing recess 15A does not face the support substrate 11 side, so that the angle between the slope a and the bottom is not a right angle but an acute angle.

这样,来自外部的光L31也通过光学滤波器18入射到面板内而成为右或左方向的圆偏振光L32,但它不会被由斜面a形成的漫反射部反射,而是被密封凹部15A的底面或第二电极14的反射面反射。因此,圆偏振光L32通过被密封凹部15A的底面等反射而成为反方向的圆偏振光L33,由于其被光学滤波器18截止,所以反射光不会射出到外部。In this way, the light L 31 from the outside also enters the panel through the optical filter 18 and becomes circularly polarized light L 32 in the right or left direction, but it is not reflected by the diffuse reflection portion formed by the slope a, but is sealed. The bottom surface of the concave portion 15A or the reflection surface of the second electrode 14 reflects. Therefore, the circularly polarized light L 32 is reflected by the bottom surface of the sealing recess 15A and becomes the circularly polarized light L 33 in the opposite direction. Since this is cut off by the optical filter 18 , the reflected light is not emitted to the outside.

图4是表示本发明的再一实施方式涉及的有机EL面板的说明图。对相同部分赋予相同符号,省略重复部分的说明。该实施方式涉及的有机EL面板30的基本结构和前述的有机EL元件10、20相同,但作为漫反射防止单元,通过在与由斜面a形成的漫反射部相对的支撑基板11的表面上形成遮光部31来更根本地解决问题。即,设置遮光部31使来自外部的光不朝向密封凹部15A的斜面a入射,这样,来自外部的光也不会通过光学滤波器18入射到面板内而到达由斜面a形成的漫反射部,面板内部的漫反射光不会射出到外部。遮光部31可以用密封材料形成,使用着色成光吸收性颜色的部件,但优选的是利用可以均匀吸收可见光区域的所有波长的近黑色或近灰色等来形成。FIG. 4 is an explanatory view showing an organic EL panel according to still another embodiment of the present invention. The same symbols are given to the same parts, and descriptions of overlapping parts are omitted. The basic structure of the organic EL panel 30 according to this embodiment is the same as that of the above-mentioned organic EL elements 10 and 20, but as the diffuse reflection preventing means, by forming The light shielding part 31 is used to solve the problem more fundamentally. That is, the light shielding portion 31 is provided so that the light from the outside does not enter the inclined surface a of the sealing recess 15A, so that the light from the outside does not enter the panel through the optical filter 18 and reach the diffuse reflection portion formed by the inclined surface a, Diffuse light from the inside of the panel is not emitted to the outside. The light-shielding portion 31 can be formed of a sealing material and a member colored in a light-absorbing color, but it is preferably formed of near black or near gray that uniformly absorbs all wavelengths in the visible light region.

下面说明这种有机EL元件10、20、30的制造方法。首先,作为元件形成工序,在支撑基板11上形成层叠了第一电极12、有机层13、第二电极14的有机EL元件,形成在一对电极之间夹着至少含有发光层的有机层13的有机EL元件。此处,有机EL元件12的形成中采用一般采用的众所周知的成膜工序和图案形成工序。此外,另一方面,通过对密封部件15进行喷砂处理或蚀刻处理等来形成密封凹部15A,在该密封凹部15A的底面上安装干燥剂17。然后,利用粘接剂16把密封部件15粘贴在支撑基板11上,形成面板。A method of manufacturing such organic EL elements 10, 20, 30 will be described below. First, as an element forming step, an organic EL element in which a first electrode 12, an organic layer 13, and a second electrode 14 are laminated is formed on a support substrate 11, and an organic layer 13 including at least a light emitting layer is formed between a pair of electrodes. organic EL elements. Here, for the formation of the organic EL element 12, well-known film-forming steps and patterning steps that are generally employed are employed. Furthermore, on the other hand, the sealing recess 15A is formed by sandblasting, etching, or the like on the sealing member 15 , and the desiccant 17 is attached to the bottom surface of the sealing recess 15A. Then, the sealing member 15 is pasted on the support substrate 11 with an adhesive 16 to form a panel.

在这样的制造工序中,在图2所示的实施方式中,在元件形成工序中的成膜第二电极14的工序,形成前述的延伸部14A(在第一电极12上设置延伸部的情况下,在形成第一电极12时形成延伸部),在图3所示的实施方式中,在密封部件15的形成工序,在加工密封凹部15A时形成前述的切口部15B。而在图4所示的实施方式中,在支撑基板11的形成工序或最终的粘贴工序之后,在支撑基板11的表面上形成前述的遮光部31。In such a manufacturing process, in the embodiment shown in FIG. 2 , in the process of forming the second electrode 14 in the element forming process, the above-mentioned extension portion 14A is formed (when the extension portion is provided on the first electrode 12 Next, the extension portion is formed when the first electrode 12 is formed), and in the embodiment shown in FIG. On the other hand, in the embodiment shown in FIG. 4 , the aforementioned light shielding portion 31 is formed on the surface of the supporting substrate 11 after the forming step of the supporting substrate 11 or the final bonding step.

下面,更具体地说明前述的有机EL面板10、20、30的各构成部件及面板制造方法。Next, each constituent member of the above-mentioned organic EL panels 10, 20, 30 and a panel manufacturing method will be described more specifically.

(a)支撑基板(a) Support substrate

作为支撑基板11,优选具有透明性的平板状或薄膜状物品,材质可以用玻璃或塑料等。As the supporting substrate 11, a transparent plate-like or film-like article is preferable, and the material may be glass or plastic.

(b)光学滤波器(b) Optical filter

作为光学滤波器18的一例,由线偏振片和1/4λ偏振片构成,1/4λ偏振片是通过粘贴多个双折射板形成的,以便在宽的波长范围内获得1/4波长的相位差。而且,通过使1/4λ偏振片具有相对于线偏振片的偏光轴成45度或与其同等的交叉角的偏光轴,使来自外部的入射光通过该光学滤波器18成为右或左圆偏振光。As an example of the optical filter 18, it is composed of a linear polarizing plate and a 1/4λ polarizing plate formed by pasting a plurality of birefringent plates so as to obtain a phase of 1/4 wavelength in a wide wavelength range Difference. And, by making the 1/4λ polarizing plate have a polarizing axis with a crossing angle equal to or equal to 45 degrees with respect to the polarizing axis of the linear polarizing plate, the incident light from the outside passes through the optical filter 18 to become right or left circularly polarized light .

(c)电极(c) electrode

以从支撑基板11侧射出光的方式(底部发光方式)为前提的情况下,可以把第一电极12制成由透明电极构成的阳极,把第二电极14制成由光反射性金属电极构成的阴极,但基本上把哪方设为阳极或阴极都没有关系(阳极使用功函数比阴极高的材料来构成)。On the premise that light is emitted from the side of the supporting substrate 11 (bottom emission method), the first electrode 12 may be an anode made of a transparent electrode, and the second electrode 14 may be made of a light-reflective metal electrode. The cathode, but basically it does not matter which side is set as the anode or the cathode (the anode is made of a material with a higher work function than the cathode).

作为适用的阳极材料,可以使用氧化铟(In2O3)、ITO、IZO等的透明电极、功函数比阴极高的Cr、Mo、Ni、Pt等金属膜,通过蒸镀、溅射等成膜方法来形成。As applicable anode materials, transparent electrodes such as indium oxide (In 2 O 3 ), ITO, and IZO, and metal films such as Cr, Mo, Ni, and Pt with higher work functions than the cathode can be used, formed by evaporation, sputtering, etc. Membrane method to form.

作为阴极,使用功函数小的金属、金属氧化物、金属氟化物、合金等,具体来讲可以使用Al、In、Mg等的单层结构、LiO2/Al等的层叠结构,用蒸镀、溅射等成膜方法来形成。另外,除金属外,还可以使用已掺杂的聚苯胺或已掺杂的聚苯乙炔等非晶质半导体、Cr2O3、NiO、Mn2O5等氧化物。第一、第二电极均由透明材料形成的情况下,也可以形成在与光射出侧相反的电极侧设置反射膜的结构。As the cathode, metals with small work functions, metal oxides, metal fluorides, alloys, etc. are used. Specifically, single-layer structures such as Al, In, and Mg, and stacked structures such as LiO 2 /Al can be used. film formation methods such as sputtering. In addition to metals, amorphous semiconductors such as doped polyaniline and doped polyphenylene vinylene, and oxides such as Cr 2 O 3 , NiO, and Mn 2 O 5 can also be used. When both the first and second electrodes are formed of a transparent material, a reflective film may be provided on the electrode side opposite to the light emitting side.

在把第二电极14制成光反射性电极,用它形成延伸部14A的情况下,由于要利用该延伸部14A反射外部光(白色光),所以最好使用不带颜色的反射整个可见光区域的银色膜。In the case of making the second electrode 14 a light-reflective electrode and using it to form the extension portion 14A, since the extension portion 14A is used to reflect external light (white light), it is preferable to use a non-colored electrode that reflects the entire visible light region. silver film.

而在把第一电极12制成透明电极,用它形成延伸部(未图示)的情况下,可以在延伸部上层叠Cr等银色膜来形成反射面。On the other hand, when the first electrode 12 is a transparent electrode and an extension (not shown) is formed using it, a silver film such as Cr may be laminated on the extension to form a reflective surface.

(d)有机层(d) Organic layer

在以第一电极12为阳极、以第二电极14为阴极的情况下,有机层13一般是空穴传输层/发光层/电子传输层的层叠结构,但也可以设置各自不只一层的多层层叠的发光层、空穴传输层、电子传输层,还可以省略空穴传输层、电子传输层中的其中一层,也可以两层均省略只设发光层。此外,作为有机层13,可以根据用途插入空穴注入层、电子注入层、空穴阻挡层、电子阻挡层等有机功能层。In the case where the first electrode 12 is used as the anode and the second electrode 14 is used as the cathode, the organic layer 13 is generally a stacked structure of hole transport layer/light emitting layer/electron transport layer, but multiple layers of more than one layer may also be provided. For the stacked light-emitting layer, hole transport layer, and electron transport layer, one of the hole transport layer and the electron transport layer may be omitted, or both layers may be omitted and only the light-emitting layer may be provided. In addition, as the organic layer 13, an organic functional layer such as a hole injection layer, an electron injection layer, a hole blocking layer, and an electron blocking layer may be inserted according to the application.

有机层13的材料可以根据有机EL元件的用途进行适当选择。以下列举出示例,但不限定于此。The material of the organic layer 13 can be appropriately selected according to the use of the organic EL element. Examples are listed below, but are not limited thereto.

作为空穴传输层,只要具有空穴迁移率高的性能即可,其材料可以选择使用以往公知的化合物中的任意物质。作为具体示例,可以使用铜酞菁蓝等血卟啉化合物、4,4’-双[N-(1-萘基)-N-苯氨基]-联苯(NPB)等芳香族叔胺、4-(二-对甲苯氨基)-4’-[4-(二-对甲苯氨基)苯乙烯基]二苯乙烯等二苯乙烯化合物、或三唑衍生物、苯乙烯基胺化合物等有机材料。另外,也可以使用聚碳酸酯等高分子中分散有低分子的空穴传输用有机材料的高分子分散类材料。As the hole transport layer, any material can be selected from conventionally known compounds as long as it has a high hole mobility. As specific examples, hematoporphyrin compounds such as copper phthalocyanine blue, aromatic tertiary amines such as 4,4'-bis[N-(1-naphthyl)-N-phenylamino]-biphenyl (NPB), 4 -Stilbene compounds such as (di-p-tolylamino)-4'-[4-(di-p-tolylamino)styryl]stilbene, or organic materials such as triazole derivatives and styrylamine compounds. In addition, a polymer-dispersed material in which a low-molecular organic material for hole transport is dispersed in a polymer such as polycarbonate can also be used.

发光层可以使用公知的发光材料,作为具体示例,可以使用4,4’-双(2,2’-联苯基乙烯基)-联苯(DPVBi)等芳香族二次甲基化合物、1,4-双(2-甲基苯乙烯基)苯等苯乙烯苯化合物、3-(4-联苯基)-4-苯基-5-叔丁苯基-1,2,4-三唑(TAZ)等三唑衍生物、蒽醌衍生物、芴酮衍生物等荧光性有机材料、(8-羟基喹啉)铝络合物(Alq3)等荧光性有机金属化合物、聚对苯乙炔(PPV)类、聚芴(ポリフルォレン)类、聚乙烯咔唑(PVK)类等高分子材料、白金络合物或铱络合物等可用于从三态激子中发出磷光的有机材料(特表2001-520450)。发光层既可以是仅由上述的发光材料构成,也可以含有空穴传输材料、电子传输材料、添加剂(供体、受体等)或发光性掺杂物等。另外,也可以将它们分散在高分子材料或无机材料中。Known light-emitting materials can be used for the light-emitting layer. As specific examples, aromatic dimethyl compounds such as 4,4'-bis(2,2'-biphenylvinyl)-biphenyl (DPVBi), 1, 4-bis(2-methylstyryl) benzene and other styrene benzene compounds, 3-(4-biphenyl)-4-phenyl-5-tert-butylphenyl-1,2,4-triazole ( TAZ) and other triazole derivatives, anthraquinone derivatives, fluorenone derivatives and other fluorescent organic materials, (8-hydroxyquinoline) aluminum complex (Alq 3 ) and other fluorescent organometallic compounds, polyphenylene vinylene ( Polymer materials such as PPV), polyfluorene (polyfluorolene), polyvinylcarbazole (PVK) and other polymer materials, platinum complexes or iridium complexes, etc., can be used to emit phosphorescence from triplet excitons. 2001-520450). The light-emitting layer may consist of only the above-mentioned light-emitting materials, or may contain hole-transport materials, electron-transport materials, additives (donors, acceptors, etc.), light-emitting dopants, and the like. Alternatively, they may be dispersed in a polymer material or an inorganic material.

电子传输层只要具有把由阴极注入的电子传递到发光层的功能即可,其材料可以选择使用以往公知的化合物中的任意物质。作为具体示例,可以使用硝基取代的芴酮衍生物、蒽金鸡纳甲烷衍生物等有机材料、8-羟基喹啉衍生物的金属络合物、金属酞菁蓝等。The electron transport layer is only required to have the function of transferring electrons injected from the cathode to the light emitting layer, and its material can be selected from conventionally known compounds. As specific examples, organic materials such as nitro-substituted fluorenone derivatives and anthracenomethane derivatives, metal complexes of 8-hydroxyquinoline derivatives, metal phthalocyanine blue, and the like can be used.

上述的空穴传输层、发光层、电子传输层可以用旋转余覆法、浸渍法等涂覆法、喷射法、丝网印刷法等印刷法的湿式工艺、或蒸镀法、激光转印法等的干式工艺来形成。The above-mentioned hole transport layer, light-emitting layer, and electron transport layer can be wet-processed by coating methods such as spin coating method and dipping method, printing methods such as spray method and screen printing method, or vapor deposition method and laser transfer printing method. And other dry process to form.

(e)密封部件(e) Sealing parts

密封部件15的材质无特别限制,但优选由玻璃形成。对应形成于支撑基板11上的有机EL元件的排列(有机EL元件可以是单个也可以是多个),在密封部件15上形成密封凹部15A。也可以在该密封凹部15A中形成装填干燥剂的凹部(pocket部)的两级凹入型。The material of the sealing member 15 is not particularly limited, but is preferably formed of glass. The sealing recess 15A is formed on the sealing member 15 corresponding to the arrangement of the organic EL elements formed on the supporting substrate 11 (the organic EL elements may be single or plural). A two-stage concave type in which a desiccant-filled pocket (pocket) may be formed in the sealing recess 15A may also be used.

对玻璃制平板来说,密封凹部15A的形成是通过进行冲压、蚀刻、喷砂处理等加工而形成的,对树脂制平板来说,密封凹部15A的形成是通过模塑成型等而形成的。The sealing recess 15A is formed by processing such as punching, etching, sandblasting, etc. for a glass plate, and the sealing recess 15A is formed by molding or the like for a resin plate.

作为前述的漫反射部的一例,通过加工密封凹部15A来形成。例如,在进行喷砂处理的情况下,在密封部件15上形成干式薄膜抗蚀剂(DFR),利用光掩模掩盖密封凹部15A形成部,向密封凹部15A以外的部分照射UV光,对DFR进行曝光、显影处理。然后,利用研磨材料进行喷砂处理,形成密封凹部15A,但由于密封凹部15A的斜面a的表面变成了粗糙面,所以在面板内部形成了漫反射部。另外,在进行湿式蚀刻处理的情况下,通过前述的DFR的曝光、显影处理,形成密封凹部15A开口的抗蚀剂图案。之后,利用药液氟酸进行蚀刻,形成密封凹部15A,但由于密封凹部15A的斜面a附近的底部表面因药液而成为粗糙面,所以形成前述的漫反射部。As an example of the aforementioned diffuse reflection portion, it is formed by processing the sealing recess 15A. For example, in the case of sandblasting, a dry film resist (DFR) is formed on the sealing member 15, a portion where the sealing recess 15A is formed is masked with a photomask, and UV light is irradiated to a portion other than the sealing recess 15A. DFR performs exposure and development processing. Then, the sealing recess 15A is formed by blasting with an abrasive material, but since the surface of the slope a of the sealing recess 15A becomes rough, a diffuse reflection part is formed inside the panel. In addition, when the wet etching process is performed, the above-described DFR exposure and development processes form a resist pattern that seals the opening of the concave portion 15A. Afterwards, the sealing recess 15A is formed by etching with the chemical solution hydrofluoric acid, but since the bottom surface near the slope a of the sealing recess 15A is roughened by the chemical solution, the above-mentioned diffuse reflection part is formed.

作为安装在密封凹部15A的底面上的干燥剂17,可以使用以下干燥剂来形成:沸石、硅胶、碳、碳纳米管等物理干燥剂;碱金属氧化物、金属卤化物、过氧化氯等化学干燥剂;在甲苯、二甲苯、脂肪族有机溶剂等石油类溶剂中溶解了有机金属络合物的干燥剂;把这些干燥剂颗粒分散在具有透明性的聚乙烯、聚异戊二烯、聚肉硅酸乙烯酯(ポリビニルシンナェ-ト)等粘合剂中的干燥剂等。As the desiccant 17 installed on the bottom surface of the sealing recess 15A, the following desiccants can be used to form: physical desiccants such as zeolite, silica gel, carbon, carbon nanotubes; chemical desiccants such as alkali metal oxides, metal halides, chlorine peroxide, etc. Desiccant; a desiccant in which organic metal complexes are dissolved in petroleum solvents such as toluene, xylene, and aliphatic organic solvents; these desiccant particles are dispersed in transparent polyethylene, polyisoprene, poly Desiccants in adhesives such as polyvinyl silicate (polyvinyl chinate-to), etc.

(f)粘接剂(f) Adhesive

粘接剂16使用热固型、化学固化型(双溶剂混合)、光(紫外线)固化型等粘接剂,其材料可以使用丙烯酸树脂、环氧树脂、聚酯、聚烯烃等。特别优选使用紫外线固化型环氧树脂。在这种粘接剂中混合适量(约0.1~0.5重量%)的粒径为1~100m的隔离物(优选玻璃或塑料隔离物),使用配合器等进行涂覆。As the adhesive 16, a thermosetting type, a chemical curing type (two-solvent mixture), or a light (ultraviolet) curing type adhesive is used, and its material can be acrylic resin, epoxy resin, polyester, polyolefin, or the like. In particular, ultraviolet curable epoxy resins are preferably used. An appropriate amount (about 0.1 to 0.5% by weight) of a spacer (preferably a glass or plastic spacer) having a particle diameter of 1 to 100 m is mixed with this adhesive, and coated using a dispenser or the like.

(g)有机EL面板的各种方式(g) Various forms of organic EL panels

有机EL元件可以形成单一的有机EL元件,也可以具有所需的图案结构,构成多个象素。The organic EL element may be formed as a single organic EL element, or may have a desired pattern structure to form a plurality of pixels.

而且,在后者的情况下,其显示方式可以是单色发光,也可以是2色或多于2色的多色发光,特别是为了实现多色发光的有机EL面板,可以用以下方式来构成:包含形成对应RGB的3种发光功能层的方式的形成2色或多于2色的发光功能层的方式(分涂方式)、将滤色器或由荧光材料形成的色变换层组合到白色或蓝色等单色发光功能层的方式(CF方式、CCM方式)、通过向单色发光功能层的发光区域照射电磁波等实现多色发光的方式(光致褪色方式)等。另外,有机EL元件的驱动方式可以是无源驱动方式或有源驱动方式中的任一种。Moreover, in the case of the latter, the display method can be monochromatic light emission, or multicolor light emission with two colors or more than two colors, especially in order to realize an organic EL panel with multicolor light emission, the following methods can be used: Configuration: A method of forming two or more light-emitting functional layers (separate coating method), including a method of forming three types of light-emitting functional layers corresponding to RGB, combining a color filter or a color conversion layer formed of a fluorescent material A method of monochromatic light emitting functional layer such as white or blue (CF method, CCM method), a method of realizing multicolor light emission by irradiating electromagnetic waves to the light emitting region of a monochromatic light emitting functional layer (photofading method), etc. In addition, the driving method of the organic EL element may be either a passive driving method or an active driving method.

(h)制造方法(h) Manufacturing method

实施方式涉及的有机EL面板10、20、30是经过以下工序制造而成的:在透明的平板玻璃制支撑基板11上形成有机EL元件的元件形成工序;密封部件15的形成工序;利用粘接剂16粘贴密封部件15和支撑基板11的密封工序。The organic EL panels 10, 20, and 30 according to the embodiment are manufactured through the following steps: an element forming process of forming an organic EL element on a transparent plate glass support substrate 11; a forming process of the sealing member 15; A sealing step in which the sealing member 15 and the support substrate 11 are pasted together with the agent 16 .

以前述的无源驱动方式的面板制造为例,元件形成工序在支撑基板11上将作为阳极的ITO等的第一电极12通过蒸镀、溅射等方法形成为薄膜,利用照相平版印刷法等形成带状图案。然后,用旋转涂覆法、浸渍法等涂覆法、喷射法、丝网印刷法等印刷法等的湿式工艺、或蒸镀法、激光转印法等的干式工艺形成有机层。作为一个示例,通过蒸镀依次层叠空穴传输层、发光层、电子传输层的各材料,最后形成作为阴极的带状第二电极14,使其与第一电极12正交,由第一电极12和第二电极14形成矩阵。第二电极14是利用使用带状图案的掩模的蒸镀或溅射等方法形成的。Taking the aforementioned passive drive panel manufacturing as an example, the element forming process forms a first electrode 12 such as ITO as an anode on the supporting substrate 11 into a thin film by evaporation, sputtering, etc., and uses photolithography, etc. Form a ribbon pattern. Then, the organic layer is formed by a coating method such as a spin coating method or a dipping method, a wet process such as a printing method such as a spray method or a screen printing method, or a dry process such as a vapor deposition method or a laser transfer method. As an example, each material of the hole transport layer, the light-emitting layer, and the electron transport layer is sequentially stacked by vapor deposition, and finally a strip-shaped second electrode 14 as a cathode is formed so that it is perpendicular to the first electrode 12. 12 and the second electrode 14 form a matrix. The second electrode 14 is formed by a method such as vapor deposition or sputtering using a stripe pattern mask.

密封部件15的形成工序是:在对玻璃制密封部件15进行冲压成形、蚀刻、喷砂处理等加工形成密封凹部15A后,利用粘接剂等使干燥剂17附着在密封凹部15A的底面上,根据情况用由布、纸或合成树脂构成的透气性薄片覆盖干燥剂17进行固定。The forming process of the sealing member 15 is to form the sealing recess 15A by processing the sealing member 15 made of glass, such as press molding, etching, and sandblasting, and then attach the desiccant 17 to the bottom surface of the sealing recess 15A using an adhesive or the like. Depending on the situation, the desiccant 17 is covered and fixed with an air-permeable sheet made of cloth, paper, or synthetic resin.

密封工序是:例如在紫外线固化型环氧树脂粘接剂16中混合适量(约0.1~0.5重量%)的粒径为1~100m的隔离物(优选玻璃或塑料隔离物),使用配合器等将其涂覆在支撑基板11上对应于密封部件15的粘接面的部位。然后,在氩气等惰性气体氛围下,通过粘接剂16使密封部件15和支撑基板11对接。之后,从支撑基板11侧(或密封部件15侧)向粘接剂16照射紫外线,使其固化。这样,以在密封部件15和支撑基板11的密封空间内封入了氩气等惰性气体的状态密封有机EL元件。The sealing process is: for example, mixing an appropriate amount (about 0.1 to 0.5% by weight) of a spacer (preferably glass or plastic spacer) with a particle diameter of 1 to 100 m in the ultraviolet curing epoxy resin adhesive 16, using a dispenser, etc. This is applied to a portion of the support substrate 11 corresponding to the bonding surface of the sealing member 15 . Then, the sealing member 15 and the support substrate 11 are brought into butt-joint contact with the adhesive 16 in an inert gas atmosphere such as argon gas. Thereafter, the adhesive 16 is irradiated with ultraviolet rays from the side of the supporting substrate 11 (or the side of the sealing member 15 ) to be cured. In this way, the organic EL element is sealed in a state where an inert gas such as argon gas is sealed in the sealed space between the sealing member 15 and the support substrate 11 .

根据这种实施方式的有机EL面板及其制造方法,入射到面板内的外部入射光不会被面板内的漫反射部反射,所以能够在设有光学滤波器18的整个面板面上发挥该滤波器的的功能。因此,不会出现非发光时映出外界景色的不良情况、发光时对比度降低或变成不能显示黑色等状态的不良情况,可以基本完全防止因外部入射光而造成的显示性能劣化。According to the organic EL panel of this embodiment and its manufacturing method, external incident light entering the panel is not reflected by the diffuse reflection part in the panel, so the optical filter 18 can be provided on the entire panel surface. function of the device. Therefore, there is no disadvantage of reflecting the outside scene when not emitting light, lowering the contrast or becoming unable to display black when emitting light, and almost completely preventing the deterioration of display performance due to external incident light.

Claims (3)

1.一种有机电致发光面板,在支撑基板的一面上设置由圆偏振片构成的光学滤波器,在所述支撑基板的另一面上形成有机电致发光元件,所述有机电致发光元件具有第一电极和第二电极以及夹在该第一、第二电极之间的有机层,所述第一电极和第二电极至少一方由透明电极构成,所述有机层至少含有发光层,在所述另一面上粘贴着形成有用于密封所述有机电致发光元件的密封凹部的密封部件,其特征在于,1. An organic electroluminescence panel, an optical filter made of a circular polarizer is arranged on one side of a support substrate, an organic electroluminescence element is formed on the other side of the support substrate, and the organic electroluminescence element It has a first electrode and a second electrode and an organic layer sandwiched between the first and second electrodes, at least one of the first electrode and the second electrode is composed of a transparent electrode, and the organic layer includes at least a light-emitting layer. A sealing member formed with a sealing recess for sealing the organic electroluminescent element is pasted on the other surface, wherein, 所述密封部件由玻璃形成,在所述密封凹部的底面设置有干燥剂,该密封凹部的斜面为粗糙面,The sealing member is formed of glass, a desiccant is provided on the bottom surface of the sealing recess, the slope of the sealing recess is a rough surface, 在支撑基板的设置光学滤波器的面之外的另一面上设有漫反射防止单元,该漫反射防止单元防止入射到所述有机电致发光面板内的外部入射光被所述密封凹部的粗糙面反射。On the surface of the support substrate other than the surface on which the optical filter is provided, a diffuse reflection prevention unit is provided, which prevents external incident light entering the organic electroluminescent panel from being affected by the roughness of the sealing recess. surface reflection. 2.根据权利要求1所述的有机电致发光面板,其特征在于,2. The organic electroluminescence panel according to claim 1, characterized in that, 作为所述漫反射防止单元,在所述支撑基板的另一面上设置由光反射性电极构成的所述第一或第二电极的延伸部,使其遮盖所述漫反射部。As the diffuse reflection preventing means, an extension portion of the first or second electrode formed of a light reflective electrode is provided on the other surface of the support substrate so as to cover the diffuse reflection portion. 3.根据权利要求1所述的有机电致发光面板,其特征在于,3. The organic electroluminescence panel according to claim 1, characterized in that, 作为所述漫反射防止单元,在所述支撑基板的另一面上设置由透明电极构成的所述第一或第二电极的延伸部,使其遮盖所述漫反射部,在该延伸部的表面上层叠有光反射性材料。As the diffuse reflection preventing means, an extension of the first or second electrode made of a transparent electrode is provided on the other surface of the support substrate so as to cover the diffuse reflection part, and on the surface of the extension part A light reflective material is laminated on top.
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