CN100387545C - Preparation method of glazed ceramic brink with stone imitation pattern based on fused block wrapping pigment - Google Patents
Preparation method of glazed ceramic brink with stone imitation pattern based on fused block wrapping pigment Download PDFInfo
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- CN100387545C CN100387545C CNB2006101524599A CN200610152459A CN100387545C CN 100387545 C CN100387545 C CN 100387545C CN B2006101524599 A CNB2006101524599 A CN B2006101524599A CN 200610152459 A CN200610152459 A CN 200610152459A CN 100387545 C CN100387545 C CN 100387545C
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Abstract
The invention discloses a new artifical stone pattern glazed ceramic wall tile based on fused block covering coloring technology, which comprises the following steps: spraying; coating; sprinkling; drying; paving fundamental background on the ceramic brick.
Description
Technical field
The present invention relates to glaze method ceramic coloring field, be specifically related in glass (or being called the thickening glaze) layer on stone imitation pattern glazed ceramic brick top, form the beautiful decorative pattern of imitating broad variety lithotome appearance effect true to nature, come down to utilize the color glaze slip to be wrapped in the look effect the surface colour of initial glass frit particulate.
Technical background
In existing glazed ceramic brick field, mainly contain two kinds with the similar currently available products of the present invention: 1. quartzy ornamental brick, this is a kind of thick clear ceramic glaze tile in fact, under this glaze, have directly by screen printing and be printed on muffle painting pattern or cosmetic soil multi color pattern on the ceramic base, and under many occasions, described decorative pattern is also imitated lithotome.Its special feature is, specially the surface finish of this glaze layer is processed, thereby has obtained luxurious decorative effect especially bright, style.2. fill out glazed brick, its characteristics are, the upper surface at the bottom of ceramic base has suppressed a kind of pattern that is made of depression texture or patch in advance, look the effect that quite is similar to slabstone notch board engraving, spray printing colour style on this surface just when needing.Then transparent glaze frit is filled on such picture on surface resulting picture on surface after oversintering and polishing are processed, rich three-dimensional decorative effect preferably through the cloth technology.In addition, in the obvious little many Ceramic glaze mosaic fields of size, also exist with above-mentioned quartzy ornamental brick and fill out the quite similar product of glazed brick.
The pattern of quartzy ornamental brick is under the glaze of transparent back, compares with lithotome, still lacks enough gradation sense and stereoscopic sensation.Make pattern obtain certain modelling effect though fill out glazed brick by the mode that makes up, but glazed layer itself still lacks gradation sense, does not also have enough stereoscopic sensations in fact, although it is so more progressive to some extent than quartzy ornamental brick, but still can not reach lithotome abundant like that level and stereoscopic sensation eventually, its artistic effect still remains to continue to improve.
In existing glass-ceramic clad plate field, also have and product like the our Noodles: Chinese invention patent application " a kind of glaze slip permeating coloring process of devitrified glass " (application number: 200510034095.x) with " glaze slip of devitrified glass surface large flower lattice pattern oozes and dyes coloring process " (application number: 200510034094.5).Disclosed technology in these two parts of files in fact all is the initial glass particulate surface colour that utilizes the osmosis of glaze slip that devitrified glass is used.And, also introduced the similar techniques that before it, has just existed in " a kind of glaze slip permeating coloring process of devitrified glass " literary composition, all be in order to painted (that is wrapping up painted) wrapped up in the mother glass particle surface embedding of microcrystal glass plate and glass-ceramic clad plate, here specially quote from as follows: " ... the painted approach of a kind of special being referred to as " colored glaze powder entrapping method " has following two schemes in the middle of the enforcement.The first string is " a sticking glaze slurries hybrid packet logos ": will be mixed with the suitable color glaze slurry of binding agent and viscosity and mix oven dry again with the glass ceramics frit particle by suitable proportion; just can in fact make skim colored glaze powder film in all enough all even embedding securely of all glass ceramics frit particles; through the dress mould; burn till; on the microcrystal glass plate face after the grinding and polishing; whole reticulate pattern background (being to be made of the female glass frit particulate of original devitrified glass border) just manifests the color that is interacted and formed by glaze colours and glass ceramics frit color; and when glass ceramics frit very slight color or white; whole reticulate pattern background just manifests the basic color corresponding with described color glaze; the colony corresponding with described primary particle then still sill keep the inherent colour of described glass ceramics frit; colourless glass ceramics frit is just obtained breast from look; in some specific occasion; especially in entire body plate (that is the simple microcrystal glass plate) Production Flow Chart; even second scheme that is " dry color powdered frit wet glass particle mixes pack " that can use simplification: the glass ceramics frit particle of the water ratio that will suit directly mixes the purpose that the realization colored glaze powder is wrapped up glass particle with the colored glaze powder of suitable proportion; as long as take advantage of the wet glass ceramics frit particle and the fashionable dress mould that will wrap up like this; advance klining, just can satisfy the painted technology purpose of reticulate pattern ".
Be worth pointing out, on the devitrified glass grinding and polishing plate face as each particle of fundamental unit, all be high milkiness in appearance, just because of these essence characteristics, no matter any in above-mentioned " colored glaze powder embedding method " painted two kinds of modification in fact all can only be obviously painted to the reticulate pattern that granule boundary constitutes. and can not make that the particle itself that occupies plate surface overwhelming majority areas is obviously painted.Like this, not only can not accomplish painted distinctness, and in fact also not be similar to the kind of this " only have particle reticulate pattern painted " on the lithotome market.Thereby as seen, go to develop the technological angle evaluation of imitating lithotome from the theory of uphold nature, the painted art of above-mentioned devitrified glass " colored glaze powder entrapping method " is also unsatisfactory, and scoring is not high yet in fact.
Summary of the invention
As mentioned above, glass ceramics frit is in fact opaque in the painted art of devitrified glass " colored glaze powder entrapping method ", thereby hinders the stone imitation pattern effect that reaches good.At effective improvement project of this shortcoming, its whole process flow comprises just in the present invention: 1. with the suitable technology of color glaze slip process, paint glass frit surface immediately through super-dry, forms the color glaze integument of suitable depth on described frit surface; 2. then with described glass frit with color glaze integument or described mixture with the glass frit of color glaze integument and the glass frit that does not have the color glaze integument according to the pre-designed scheme of controlling (that is cloth) to the prior process as ground add in advance the background color background or on the ceramic adobe that adds the background color background in advance; 3. during this period as needing, can inject the operation steps that some can change final pattern decorative effect; 4. after long-pending (that is cloth) operation in aforesaid shop, replenish on the described ceramic adobe immediately and apply the suitable viscosity aqueous slurry of an amount of viscosity, be fixed on the described ceramic adobe so that spread all glass frit particle bond of amassing on top; 5. make then the ceramic adobe experience that has experienced above-mentioned each step process dry, burn till, grinding and polishing processing, promptly in glass (or being called the thickening glaze) layer on gained ceramic tile top, form the beautiful decorative pattern of imitating broad variety lithotome appearance effect true to nature.
In brief, mix again by suitable proportion with transparent glass frit particle and dry, the core content of " frit wraps up painted art " that is exactly among the present invention to be adopted being mixed with the suitable color glaze slip of binding agent and viscosity.Because described glass frit is transparent, so the present invention has just had distinct difference with color glaze embedding (that is parcel) art of glass ceramics frit.The stone imitation pattern glazed ceramic brick that wraps up painted art based on frit of the present invention, its outstanding feature that is advantage are, on the surface after the grinding and polishing processing, by means of the transparent characteristic of frit, can express the painted speciality in the three-dimensional border of each frit particulate very clear fine and smoothly, so just reach convergence ideal effect aspect the artistic speciality of lithotome fully approaching, obviously surpassed above various existing other similar processing methodes that outlined.
In the present invention, be used for described frit is wrapped up painted described color glaze slip, be exactly the various no clay color glaze slip of the existing use of ceramics: its matching principle that is used for various concrete use occasions is, thermal expansivity with mated by the glass frit of its parcel, after experience is burnt till operation, do not make product crackle occur even burst, and still maintenance has the color of decorative effect, not can owing to described color glaze and described glass frit or and described ceramic body between interaction and the havoc decorative quality, such as producing tangible pinhole (that is small bubbles) thus or form dirty color of destroying artistic effect or the like.For example, be elected to when using the usual cellulose sodium carboxymethyl that uses as suspension agent, the optimum proportion of described color glaze slip is, with (colored glaze powder+water) is 100 weight quota, the weight quota of suspension agent adds outside (colored glaze powder+water) 100 parts separately, promptly get following numerical value: colored glaze powder 20～40, water 60～80, Xylo-Mucine 0.2～0.4, when adopting other existing glaze slip suspension agent, its adding proportion can suitably be adjusted as required; Form the colored glaze powder consumption of the color glaze integument of described glass frit, weight ratio with described colored glaze powder and described frit is represented, common ratio is 1: 10000～1: 50, and concrete consumption depends on the granularity specification of the needs and the described glass frit of decoration occasions.
Carry out the method for the formation glaze slip integument that adopted when described frit wraps up painted operation, it is exactly the shades of colour glaze slip application technique of the existing use of ceramics, such as spraying, showering or get rid of mode such as spill, for example one of measure that is suitable for relatively flexibly, conventional revolution is puddled-" being coated with glaze-drying " integration of operation line that drying operation is united in spraying or showering operation and the existing industry exactly.
Be used for carrying out the painted glass frit of described frit parcel, be exactly the various glass frits of the existing use of ceramics, its matching principle that is used for various concrete use occasions is, base coupling at the bottom of thermal expansivity and the ceramic tile, after experience is burnt till operation, do not make product crackle occur even burst, and still keep transparent or have only slight breast erosion, guarantee to burn till the glass coating that forms by described frit afterwards with this and still have enough transparencys, thereby make to have enough light depths of penetration, produce the good result of levels are rich according to the decorative pattern that the inventive method obtained.
The material that constitutes described background color background on as the described ceramic adobe of ground has two series, its first series comprises the color glaze coating or the cosmetic soil coating of the existing use of ceramic industry, and be used to form this class color glaze coating or the method for application of cosmetic soil coating, be exactly the various application technique of the existing use of ceramics, such as spraying, showering or get rid of measure such as spill; Realize painted frit and the second series of described background color background material still also is based on " frit wraps up painted art " of the present invention: used for this reason color glaze slip, frit and method of application, respectively as mentioned above, described frit has superscribed after the color glaze slip, through super-dry, just form the color glaze integument of suitable depth immediately on described frit surface.
The described background color background that on ceramic adobe, is constituted as ground, it both can be solid color, also can be that multiple color forms certain pattern, its effect is, play the effect of setting off being wrapped in the darker bottom of chromatograph than described frit, thereby increase the gradation of whole decorative pattern.
In with the described operation process that has wrapped up painted frit cloth (shop is long-pending) on the described ceramic adobe ground, the operation steps that can change final pattern decorative effect of described available reeve, can be to be chosen to be on the granitic typical grain type basis at the ultimate aim pattern, remove the color glaze integument should monochrome or polychrome develop simultaneously (as simple black, red-Hei or red-Bai-Hei etc.) outside, also the measure that can take has: the kind of described frit is taken several and mutual blending, make it combined from the becoming of single pure transparent type " transparent-slight milkiness-height milkiness ", for example: the slight emulsion opal glass frit and the paramount milkiness glass ceramics frit that mix suitable proportion in the common clear frit: or from another angle, only use single clear frit, but change the kind of integument color glaze, be improved to the certain density ceramic transparent pigment of also parallel use simultaneously from the opaque beramic color of single use (or being called ceramic stain), also can also parallel without hesitation use finite concentration not with the clear frit of parcel color glaze layer; The function of described these measures is promptly to make that the final pattern that obtains has decorative effect colorful, levels are rich.
In with the described operation process that has wrapped up painted frit cloth (shop is long-pending) on the described ceramic adobe ground, the operation steps that can change final pattern decorative effect of described available reeve, it can be the basis that is chosen as what is called " marble " type at the ultimate aim pattern, be wrapped on the background color that coloured particles constitutes toward described color glaze and increase the lines zonal texture, way is to adopt the existing registering based on dry powder cloth technology " xerography " technology of ceramics, look the needs of design effect, or add simply heterochromatic (or homochromy but be of different shades) lines to pursue thick spacious style, or registering prints off abundant heterochromatic (or homochromy but be of different shades) lines to pursue more fine and smooth laminated striation style: described cover platemaking technology, its basic meaning are to coordinate processing step by step and form the technology of a pattern (no matter shelter or superpose or the two makes up) through a plurality of masterplates; Described " xerography " technology, its basic meaning are directly with the color glaze powder of reasonable quantity, leak the have pierced pattern masterplate of (for example lines), and dry state scatters on the granular layer of formation background, thus the formation pattern corresponding with this masterplate; In applying viscosity aqueous slurry operation process subsequently, originally only drop on the described xerography fine powder colour glaze of surface location, will be driven drive and penetrate into the painted frit layer inside of described parcel by described viscosity aqueous slurry, the result experiences grinding and polishing and adds man-hour after burning till, just be unlikely to be ground, can finally express the pattern of design shape (for example lines).
The painted frit granular layer of whole described parcel that will be in adobe top is fixed on described viscosity aqueous slurry and applying method thereof used on the described ceramic adobe, all identical with the customary viscosity aqueous slurry of using in the field actual production of devitrified glass ceramics composite brick, for example, mix in the water ceramic glaze field existing the glaze of increasing slurry viscosity arranged, the additive of denseness function (also just being applicable to suspension agent simultaneously), as Xylo-Mucine, just can be mixed with described viscosity aqueous slurry, its compound concentration is as long as the viscous liquid that is made into is can mobile, also just necessarily can pass through suitable technology in principle, such as spraying, showering, or get rid of mode such as spill and apply and put in place, thereby reach the viscosifying power that the inventive method is suitable for.For example, when preparing the viscosity aqueous slurry with Xylo-Mucine, the weight proportion optimum range is that 100 share water add 0.2～0.4 part of Xylo-Mucine, can suitably adjust when its adding proportion needs when adopting other existing glaze suspension agent.
" wrapping up the stone imitation pattern glazed ceramic brick product of painted art based on frit " of the present invention, follow the exploitation route of existing ceramic brick surface " light microscopic face gloss type and sub-smooth type develop simultaneously ", also develop simultaneously, contained inferior photochemical remodeling, that is, make suitable variation in the cold working operation process after described product sheet material of the present invention burns till: the first, it is not specular gloss with surface finish, but directly adopt commercially available " inferior tarry matter is thrown the special-purpose nylon the brush "-a kind of nylon wire and the matrix material one grinding and polishing technology of abrasive mixed casting, perhaps adopt " the dull surface sandblast technology " of existing routine, perhaps even adopt market existing some " inferior light acid corrosion technology " based on hydrofluoric acid (or its esters), opposite with the ideological trend of pursuing bright mirror surface, described plate surface is processed into soft inferior light decorative effect, this also is a school that quite makes good in existing decorative stone field: it two is, inferior photochemical treatment technology to described plate surface is made meticulousr improvement, above-mentioned ceramics existing " inferior light acid corrosion technology " or ceramics existing " dull surface sandblast technology " are implemented with described registering technical combinations, the result is on the surface of same block of sheet material, the effect that honed pattern on the realization specular gloss background or inferior light background are being set off the specular gloss figure by contrast, thereby unique style, on the basis of the natural stone texture of height emulation, the artificial art pattern that superposes helps to embody more brightly Designers's whole decorative art theme.
Description of drawings
The invention will be further described below in conjunction with accompanying drawing.Fig. 1 is the structural representation of product of the present invention.
About the explanation at each position of arrow indication in the accompanying drawing, referring to table 1.
The explanation at each position of arrow indication in table 1. accompanying drawing
| The position sequence number | Title | Explanation |
| 1 | The thick glaze in surface | Formed by the painted frit sintering of parcel of the present invention, form the high stone imitation pattern of naturalness in this layer, thickness needn't be greater than 5mm |
| 2 | The background background color layer (options) on ceramic adobe surface | Select for use when needing, play the effect that color sets off by contrast, increase gradation sense, thickness needn't be greater than 1mm |
| 3 | Ceramic adobe | Material, thickness and the length of side all with used consistent of commercially available existing glass-ceramic clad plate; For example: the thickness of 800mm square brick is 12～16mm. |
| 4 | Frit in the thick glaze enlarged partial view in surface | After the grinding and polishing processing, as shown in the figure, top layer, frit particulate top, top layer is worn away, thereby reveals out the level that enriches of pattern. |
| 3 | Parcel color glaze layer in the thick glaze enlarged partial view in surface around the frit | See through surface observation, the spatial network that this parcel color glaze layer constitutes changes all the time, and guarantees the stone material pattern degree of imitating true to nature. |
Embodiment
Some embodiment that below will introduce wherein can provide some concrete processing parameters; These parameters only only are intended for the example of explanation, and never meaning is being hidden the present invention and only is only limited to these parameters.
Embodiment
Embodiment 1～embodiment 5 to bottom, 1.-5. the preparation of sample is all carried out according to aforesaid standard step: in these 5 operation stepss, 2. step comprises two kinds of selections: the first, on the described adobe ground in advance through add in advance the background color background process (below be labeled as step 2. a), it two is, on the described adobe ground in advance not through adding background color background process (below be labeled as 2. b of step) in advance; 3. step comprises two types selection: first type is, purpose at artificial grantie particle typical case pattern, selecting definite basic measures is, make the color variation of described frit through wrapping up painted formation (below be labeled as step 3. (i)), make the kind variation (below be labeled as step 3. (ii)) of described frit, with two types of (opaque type and transparent type) compoundization of used beramic color in the painted art of described parcel (below be labeled as step 3. (iii)), second type is, purpose at scagliola lines laminated striation typical case pattern, selecting definite basic measures is, be wrapped on the background color that coloured particles constitutes toward described color glaze and increase the lines zonal texture, way is to adopt the existing registering of ceramics " xerography " technology, (below be labeled as 3. b of step): and step is 1., 4., 5. all only comprise simple clear and definite a kind of situation.In the embodiment that bottom is introduced, will in the related column of appropriate cards, concisely point out used operation steps above-mentioned sequence number (that is step is 1., 2. a, 2. b, 3. a, 3. b, 4., 5.).For ease of reading, existing that the sequence number and the content of each step is tabulating, see table 2 for details.Among these embodiment at the bottom of the used composition board porcelain brick base area be 850mm * 850mm, the material quantity that provides in described each embodiment list data is all corresponding to a 850mm square brick base; The slurries method of application that is adopted all is the spray gun spraying; Used calcination equipment is the glass-ceramic clad plate roller kiln of 155 meters of total lengths, and unified order is consistently finished dry and burnt till the crystallization operation; Used grinding and polishing machine is the continuous grinding and polishing line of one 28 bistrique.
Standard operating procedure sequence number and the implication of each embodiment of table 2.
The particular content of embodiment 1～embodiment 5 is set out in table 3a～table 3e respectively.
Table 3a. embodiment 1 (CMC: the english abbreviation of Xylo-Mucine)
Table 3b. embodiment 2
Table 3c. embodiment 3
Table 3d. embodiment 4
Table 3e. embodiment 5
The present invention is not limited to the foregoing description, the scope that these embodiment do not limit the present invention in any way.Any change that those skilled in the art have done within the scope of the claims and adjust also should be thought and belongs to scope of the present invention.
Claims (16)
1. manufacture method of wrapping up the stone imitation pattern glazed ceramic brick of painted art based on frit, this method comprises:
(1), thereby forms the color glaze integument on described glass frit surface with color glaze slip paint glass frit surface;
(2) described glass frit with color glaze integument is amassed to the ceramic adobe as ground according to the pre-designed scheme of controlling shop, described ceramic adobe is added with the background color background in advance or does not add the background color background in advance;
(3) the additional viscosity aqueous slurry that applies on described ceramic adobe is so that all glass frit particle bond that amass on top the shop are fixed on the described ceramic adobe; With
(4) will experience drying through the ceramic adobe that above-mentioned steps is handled, burn till and grinding and polishing processing, and in the glass coating on gained ceramic tile top, form subsequently and imitate the decorative pattern of various lithotome appearance effect.
2. the manufacture method of the stone imitation pattern glazed ceramic brick of claim 1, it is characterized in that, described color glaze slip is no clay color glaze slip, it comprises colored glaze powder, water and suspension agent, the thermal expansivity of described colored glaze powder with by the frit of its parcel coupling, make after experience is burnt till operation, not make product crackle occur or burst.
3. the manufacture method of the stone imitation pattern glazed ceramic brick of claim 2 is characterized in that described color glaze slip comprises 20-40 part colored glaze powder, 60-80 part water and 0.2-0.4 part Xylo-Mucine, is 100 parts based on the gross weight of colored glaze powder and water.
4. the manufacture method of the stone imitation pattern glazed ceramic brick of claim 2, the weight ratio that it is characterized in that described colored glaze powder and described glass frit is 1: 10000-1: 50.
5. the manufacture method of the stone imitation pattern glazed ceramic brick of claim 1 is characterized in that the method for application of the formation color glaze integument that adopted in the step (1) comprises spraying, showering, gets rid of and spill or its combination.
6. the manufacture method of the stone imitation pattern glazed ceramic brick of claim 1, the thermal expansivity that it is characterized in that described glass frit is complementary with ceramic adobe as ground, makes described glass frit not make product crackle occur after experience is burnt till operation or bursts.
7. the manufacture method of the stone imitation pattern glazed ceramic brick of claim 1, it is characterized in that, the material that constitutes background color background described in the step (2) is color glaze coating or cosmetic soil coating, and described coating is by being selected from spraying, showering, getting rid of the method for application that spills and make up and form; Or apply the glass frit layer of parcel through the color glaze slip.
8. the manufacture method of the stone imitation pattern glazed ceramic brick of claim 1 is characterized in that, the color glaze integument has multiple color described in the step (1).
9. the manufacture method of the stone imitation pattern glazed ceramic brick of claim 1 is characterized in that, glass frit described in the step (1) is selected from transparent glass frit, slight emulsion opal glass frit, height emulsion opal glass frit or its combination.
10. the manufacture method of the stone imitation pattern glazed ceramic brick of claim 1 is characterized in that, also comprises the glass frit that uses the colourless glaze integument in step (2).
11. the manufacture method of the stone imitation pattern glazed ceramic brick of claim 1 is characterized in that, the color glaze slip described in the step (1) comprises at least a in the color glaze slip of opaque beramic color and crystalline ceramics pigment.
12. the manufacture method of the stone imitation pattern glazed ceramic brick of claim 1, it is characterized in that, step (2) step (3) is afterwards inserted an operation steps before, this operation steps comprises, utilize at least one masterplate, amass on the glass frit on the ceramic adobe finely powdered colour glaze that spreading is an amount of toward spreading with color glaze integument.
13. the manufacture method of the stone imitation pattern glazed ceramic brick of claim 1 is characterized in that, the viscosity aqueous slurry in the step (3) contains the additive that increases glaze slurry viscosity, denseness, and by spraying, showering or get rid of the mode of spilling and apply.
14. the manufacture method of the stone imitation pattern glazed ceramic brick of claim 13, it is characterized in that, described additive is an Xylo-Mucine, and during with Xylo-Mucine preparation viscosity aqueous slurry, the weight proportion scope is to add 0.2～0.4 part of Xylo-Mucine in 100 parts of water.
15. the manufacture method of the stone imitation pattern glazed ceramic brick of claim 1, it is characterized in that, also comprise inferior photochemical remodeling step afterwards in step (3), comprise: utilize dull surface grinding and polishing method or dull surface blasting method or acid corrosion method used, will become to have soft inferior light decorative effect through the glass coating surface working that step (3) are processed to form based on the dull surface of hydrofluoric acid or its salt; Perhaps use a plurality of templates to make up step by step to implement the caustic solution of dull surface grinding and polishing method, dull surface blasting method or dull surface hydrofluoric acid or its salt, thereby in the effect that realizes on the same described surface that honed pattern on the specular gloss background or inferior light background are being set off the specular gloss figure by contrast.
16. the made goods of manufacture method according to each stone imitation pattern glazed ceramic brick among the claim 1-15.
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| JP5236342B2 (en) * | 2008-04-16 | 2013-07-17 | 株式会社ハイテック | Decorative materials and decorative articles |
| CN102218960B (en) * | 2011-04-18 | 2013-01-02 | 陈伟煊 | Manufacture method for polished electrooptic mirror face ceramic product |
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