CN100360029C - Synergistic compound pesticide contg. pyrimidifen and S-fenvalerate, and its application - Google Patents
Synergistic compound pesticide contg. pyrimidifen and S-fenvalerate, and its application Download PDFInfo
- Publication number
- CN100360029C CN100360029C CNB2005100414402A CN200510041440A CN100360029C CN 100360029 C CN100360029 C CN 100360029C CN B2005100414402 A CNB2005100414402 A CN B2005100414402A CN 200510041440 A CN200510041440 A CN 200510041440A CN 100360029 C CN100360029 C CN 100360029C
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- Prior art keywords
- fluacrypyrim
- sumicidin
- gram
- fenvalerate
- grams
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- 230000002195 synergetic effect Effects 0.000 title claims abstract description 11
- 150000001875 compounds Chemical class 0.000 title description 8
- 239000000575 pesticide Substances 0.000 title description 6
- ITKAIUGKVKDENI-UHFFFAOYSA-N pyrimidifen Chemical compound CC1=C(C)C(CCOCC)=CC=C1OCCNC1=NC=NC(CC)=C1Cl ITKAIUGKVKDENI-UHFFFAOYSA-N 0.000 title 1
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 7
- 235000009566 rice Nutrition 0.000 claims abstract description 7
- 239000002917 insecticide Substances 0.000 claims abstract description 6
- 239000000546 pharmaceutical excipient Substances 0.000 claims abstract description 4
- 240000007594 Oryza sativa Species 0.000 claims abstract 2
- MXWAGQASUDSFBG-RVDMUPIBSA-N fluacrypyrim Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1COC1=CC(C(F)(F)F)=NC(OC(C)C)=N1 MXWAGQASUDSFBG-RVDMUPIBSA-N 0.000 claims description 40
- 239000000203 mixture Substances 0.000 claims description 17
- 241000607479 Yersinia pestis Species 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 11
- 239000004530 micro-emulsion Substances 0.000 claims description 11
- 241000500437 Plutella xylostella Species 0.000 claims description 10
- 230000000749 insecticidal effect Effects 0.000 claims description 8
- 241000255777 Lepidoptera Species 0.000 claims description 7
- 210000004894 snout Anatomy 0.000 claims description 6
- 239000004480 active ingredient Substances 0.000 claims description 2
- 239000002671 adjuvant Substances 0.000 claims description 2
- 241000255969 Pieris brassicae Species 0.000 abstract description 3
- 239000002131 composite material Substances 0.000 abstract description 2
- -1 methoxy acrylic ester compounds Chemical class 0.000 description 19
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 9
- 239000003814 drug Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 8
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- 238000005303 weighing Methods 0.000 description 7
- 229910019142 PO4 Inorganic materials 0.000 description 6
- 230000008485 antagonism Effects 0.000 description 6
- 210000000481 breast Anatomy 0.000 description 6
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 6
- 238000009313 farming Methods 0.000 description 6
- 235000021317 phosphate Nutrition 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 241000209094 Oryza Species 0.000 description 5
- 230000000361 pesticidal effect Effects 0.000 description 5
- 230000003449 preventive effect Effects 0.000 description 5
- 241000238631 Hexapoda Species 0.000 description 4
- 229940079593 drug Drugs 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 230000002265 prevention Effects 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- 239000003905 agrochemical Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 230000002438 mitochondrial effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000005660 Abamectin Substances 0.000 description 2
- 241000256247 Spodoptera exigua Species 0.000 description 2
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 description 2
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 2
- HCWYXKWQOMTBKY-UHFFFAOYSA-N calcium;dodecyl benzenesulfonate Chemical class [Ca].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 HCWYXKWQOMTBKY-UHFFFAOYSA-N 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 231100000636 lethal dose Toxicity 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 230000000241 respiratory effect Effects 0.000 description 2
- 230000029058 respiratory gaseous exchange Effects 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241001124076 Aphididae Species 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 102100025287 Cytochrome b Human genes 0.000 description 1
- 102000019265 Cytochrome c1 Human genes 0.000 description 1
- 108010075028 Cytochromes b Proteins 0.000 description 1
- 108010007528 Cytochromes c1 Proteins 0.000 description 1
- 239000005784 Fluoxastrobin Substances 0.000 description 1
- 241000255967 Helicoverpa zea Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000488581 Panonychus citri Species 0.000 description 1
- 241000488583 Panonychus ulmi Species 0.000 description 1
- 241000220324 Pyrus Species 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
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- 230000002708 enhancing effect Effects 0.000 description 1
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 210000003470 mitochondria Anatomy 0.000 description 1
- 238000003012 network analysis Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000007115 recruitment Effects 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A synergistic composite insecticide for preventing and treating cabbage caterpillar and rice borer contains two primary active components including S-fenvalerate, assistant and excipient.
Description
Technical field
The present invention relates to a kind of Pesticidal combination and uses thereof, especially a kind of is the Pesticidal combination and the application thereof of main active with fluacrypyrim and S-sumicidin.
Background technology
Fluacrypyrim (test code number: NA83, adopted name: fluacrypyrim, trade name: Titaron) be first methoxy acrylic miticide by BASF AG development, the exploitation of Japanese Cao Da company.Fluacrypyrim is on the basis of methoxy acrylic bactericide, and is synthetic at random, and find through optimization.The chemical name of fluacrypyrim is methyl (E)-2-{a-[2-isopropoxy-6-(trifluoromethyl) pyrimidine-4-base oxygen base]-o-tolyl }-the 3-methoxy-methyl acrylate.
Fluacrypyrim is that the mitochondrial respiratory inhibitor promptly shifts the mitochondrial breathing of inhibition by electronics between cytochrome b and c1.Extranuclear mitochondria mainly by breathing to cell provides energy (ATP), if mitochondrial respiratory is obstructed, can not produce ATP, and cell will be dead.
Fluacrypyrim is mainly used in multiple mite class such as European red mite, the citrus red mite etc. in control fruit tree such as apple, citrus, the pears etc.The mixture main component is that methoxy acrylic ester compounds such as fluacrypyrim and a lot of organophosphorus compound are formed in the patent, is used for anti-ly curing the disease, insect pest.And the relevant report of not finding antibiotic combinations such as Fluoxastrobin and Avermectin occurs.
Lepidoptera pest as cabbage caterpillar, cotton bollworm, aphid, beet armyworm, the snout moth's larva of rice etc., increases gradually in present resistance, and the agent of agricultural chemicals list descends gradually to the effect of control of insect, and agriculture chemical compounding can obviously improve drug effect, and delays the generation of pest resistance.
The synergistic complex of Avermectin and agricultural chemicals is expanding prevention spectrum and the effective measures that improve preventive effect, still finds no the Pesticidal combination that closes fluacrypyrim and S-sumicidin up to now.
Summary of the invention
But the purpose of this invention is to provide a kind of multifunctional insecticide composition and application thereof of high-efficiency prevention and control resistance lepidoptera pest.
Technical scheme of the present invention is:
A kind of Synergistic insecticidal compositions that contains fluacrypyrim and S-sumicidin is characterized in that it contains fluacrypyrim and S-sumicidin, and its weight portion is respectively 0.1～30 and 0.1～20.
Effective ingredient is present in the composition with the synergy effective dose.
Optimum weight part of fluacrypyrim is 0.1～25; Optimum weight part of S-sumicidin is 0.1～10.
The Synergistic insecticidal compositions that contains fluacrypyrim and S-sumicidin is that active ingredient is equipped with insecticides adjuvant and excipients is mixed with missible oil, aqueous emulsion, microemulsion with fluacrypyrim and S-sumicidin.
Above-mentioned Pesticidal combination is in the application that prevents and treats on the resistance lepidoptera pest, especially in the application that prevents and treats on the diamond-back moth and the snout moth's larva of rice.
For achieving the above object, the present invention is by the network analysis to fluacrypyrim and S-sumicidin insecticidal properties, make full use of both mutual supplement with each other's advantages, fluacrypyrim and S-sumicidin is composite according to certain ratio, obtain a kind of new and effective multifunctional insecticide composition.The various pests that this insecticide antagonism diamond-back moth, the snout moth's larva of rice, beet armyworm etc. are easy to generate resistance has good preventive effect; And the inhibition insect is to the pesticide resistance generation of unitary agent (fluacrypyrim or S-sumicidin).
The compound pesticide compositions of high-efficiency prevention and control lepidoptera pest of the present invention is made up of fluacrypyrim and two kinds of active components of S-sumicidin and auxiliary agent, excipients.
Beneficial effect of the present invention:
The Pesticidal combination that contains fluacrypyrim and S-sumicidin of the present invention compared with prior art, can produce higher cooperative synergism, overcome and delay the pesticide resistance of insect, the expanding prevention spectrum, it is fast to have desinsection speed, and drug cost is low, the advantage that toxicity is little, especially can be used for preventing and treating the cabbage caterpillar and the snout moth's larva of rice, its effect is used apparently higher than its single agent.
Concrete effect has:
(1) compare with single agent, the said composition antagonism lepidoptera pest such as the snout moth's larva of rice, resistance diamond-back moth etc. has notable synergistic, obviously improved control efficiency;
(2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously, reduce control recruitment cost;
(3) alternative high-toxic pesticide;
(4) have concurrently quick-acting and long-acting;
(5) compare with S-sumicidin or the agent of fluacrypyrim list, produce and the use cost reduction;
(6) suppress the resistance enhancing of lepidoptera pest to agricultural chemicals;
(7) reduction is to the toxicity of warm blooded animal.
Embodiment
The present invention is further illustrated below in conjunction with embodiment.
Embodiment 1:
Take by weighing fluacrypyrim 4 gram, S-sumicidin 3 grams, calcium dodecyl benzene sulfonate 4 grams, phenethyl phenol polyethenoxy ether 3 grams, surplus dimethylbenzene and add to gross weight 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 7% fluacrypyrim-S-fenvalerate missible oil.
Carry out indoor synergy biologicall test, selecting the resistance diamond-back moth is target pest, and every processing repeats 3 times, and every concentration is handled 60, presses the abundant method of Sun Yun with the LC50 value and calculates co-toxicity coefficient, as shown in table 1.
The indoor measurement result of table 1 7% fluacrypyrim-S-fenvalerate missible oil and single agent antagonism diamond-back moth thereof:
| Medicament | The mensuration project | Drug concentration (mg/l) | ||||||
| 0 | 2.5 | 5 | 10 | 20 | 40 | 80 | ||
| The 5%S-fenvalerate missible oil | Death toll | 3 | 27 | 36 | 41 | 47 | 55 | 60 |
| Corrected mortality % | 42.1 | 57.9 | 66.7 | 77.2 | 91.2 | 99.9 | ||
| 4.5% fluacrypyrim missible oil | Death toll | 3 | 12 | 31 | 43 | 50 | 55 | 57 |
| Corrected mortality % | 15.8 | 49.1 | 70.2 | 82.5 | 91.2 | 94.7 | ||
| 7% fluacrypyrim S-fenvalerate missible oil | Death toll | 3 | 29 | 35 | 43 | 52 | 58 | 60 |
| Corrected mortality % | 45.6 | 56.1 | 70.2 | 86.0 | 96.5 | 99.9 | ||
Annotate: the resistance diamond-back moth that every drug concentration is handled adds up to 60.
Calculate toxicity regression equation and the lethal concentration of 50 LC50 of each medicament antagonism diamond-back moth with probability value method, the results are shown in Table 2.
Toxicity regression equation and the lethal concentration of 50 LC of table 2 7% fluacrypyrim S-fenvalerate missible oil and single agent antagonism diamond-back moth
50
| Medicament | Virulence regression equation | LC 50(mg/l) | LC 95(mg/l) | Co-toxicity coefficient |
| The S-fenvalerate missible oil | Y＝3.63040+1.728332X | 6.20065 | 55.4801 | |
| Fluacrypyrim missible oil | Y＝4.17070+1.373014X | 4.01788 | 63.3848 | |
| Fluacrypyrim S-sumicidin | Y＝4.09841+1.594831X | 3.67554 | 39.5081 | 132.6645 |
Embodiment 2:
Take by weighing fluacrypyrim 4 grams, S-sumicidin 2 grams, phenethyl phenol polyethenoxy ether phosphate 3 grams, polyoxyethylene polyoxy third rare block compound as farming breast 33
#2 grams, alkylphenol polyoxyethylene 1 gram, dimethylbenzene 13 exists, and adds water to gross weight 100 grams.The method of above raw material being prepared routinely aqueous emulsion drops into the mixing of mixing kettle high speed, forms aqueous emulsion preparation 6% fluacrypyrim-S-fenvalerate aqueous emulsion.
Embodiment 3:
Take by weighing fluacrypyrim 2 grams, S-sumicidin 4 grams, calcium dodecyl benzene sulfonate 6 grams, phenethyl phenol polyethenoxy ether phosphate 3 grams, polyoxyethylene polyoxy third rare block compound as farming breast 33
#2 grams, alkylphenol polyoxyethylene 1 gram, cyclohexanone 10 grams add water to gross weight 100 grams.The method that above raw material is prepared microemulsion routinely drops in the mixing kettle mixes, and forms microemulsion formulation 30% fluacrypyrim-S-sumicidin microemulsion.
It is as follows that embodiment is carried out test of pesticide effectiveness result:
| Handle (extension rate) | Radix approximately | Behind the medicine 2 days | Behind the medicine 5 days | Back approximately 10 days | ||||
| Residual borer population | Preventive effect | Residual borer population | Preventive effect | Residual borer population | Preventive effect | |||
| Embodiment 1 | 500 | 360 | 40 | 88.44a | 32 | 90.20a | 22 | 91.22a |
| 1000 | 372 | 52 | 85.45ab | 60 | 82.12b | 42 | 83.78b | |
| 1500 | 572 | 164 | 70.16c | 132 | 74.41c | 88 | 77.91c | |
| Embodiment 2 | 500 | 330 | 85 | 85.16 | 88 | 88.87A | 79 | 83.22a |
| 1000 | 328 | 81 | 80.6 | 80 | 82.04B | 74 | 78.61b | |
| 1500 | 467 | 72 | 71.95 | 73 | 75.65C | 64 | 70.92c | |
| Embodiment 3 | 500 | 352 | 63 | 82.2a | 41 | 88.32a | 31 | 91.25a |
| 1000 | 435 | 87 | 80.1ab | 64 | 85.2b | 46 | 89.38b | |
| 1500 | 467 | 111 | 76.2c | 101 | 78.3c | 119 | 74.56c | |
| S-sumicidin 1000 | 512 | 100 | 79.24b | 78 | 83.12b | 52 | 85.40b | |
| Fluacrypyrim 1000 | 390 | 110 | 70.64c | 108 | 69.05c | 98 | 63.90d | |
| Contrast | 408 | 392 | 368 | 284 | ||||
Annotate: a is illustrated on α=0.05 level remarkable, and b is illustrated on α=0.05 level variant, and c is illustrated on α=0.05 level not remarkable; A is illustrated on α=0.01 level remarkable, and B is illustrated on α=0.01 level variant, and C is illustrated on α=0.01 level not remarkable;
Field efficacy is the result show, fluacrypyrim S-sumicidin composition antagonism diamond-back moth has good control efficiency, and control efficiency all is better than single agent kind.
Embodiment 4:
Take by weighing 0.1 gram fluacrypyrim, 0.1 gram S-sumicidin, 3 gram phenethyl phenol polyethenoxy ether phosphates, 2 gram polyoxyethylene polyoxies, third rare block compound as farming breast 33
#, 1 the gram alkylphenol polyoxyethylene, 13 the gram dimethylbenzene, add water to 100 the gram.The method of above raw material being prepared routinely aqueous emulsion drops into the mixing of mixing kettle high speed, forms aqueous emulsion preparation 0.2% fluacrypyrim-S-fenvalerate aqueous emulsion.
Embodiment 5:
Take by weighing 30 gram fluacrypyrims, 20 gram S-sumicidins, 6 gram calcium dodecyl benzene sulfonates, 3 gram phenethyl phenol polyethenoxy ether phosphates, 2 gram polyoxyethylene polyoxies, third rare block compound as farming breast 33
#, 1 the gram alkylphenol polyoxyethylene, 10 the gram cyclohexanone, add water to 100 the gram.The method that above raw material is prepared microemulsion routinely drops in the mixing kettle mixes, and forms microemulsion formulation 50% fluacrypyrim-S-sumicidin microemulsion.
Embodiment 6:
Take by weighing 1 gram fluacrypyrim, 2 gram S-sumicidins, 3 gram phenethyl phenol polyethenoxy ether phosphates, 2 gram polyoxyethylene polyoxies, third rare block compound as farming breast 33
#, 1 the gram alkylphenol polyoxyethylene, 13 the gram dimethylbenzene, add water to 100 the gram.The method of above raw material being prepared routinely aqueous emulsion drops into the mixing of mixing kettle high speed, forms aqueous emulsion preparation 3% fluacrypyrim-S-fenvalerate aqueous emulsion.
Embodiment 7:
Take by weighing 25 gram fluacrypyrims, 10 gram S-sumicidins, 6 gram calcium dodecyl benzene sulfonates, 3 gram phenethyl phenol polyethenoxy ether phosphates, 2 gram polyoxyethylene polyoxies, third rare block compound as farming breast 33
#, 1 the gram alkylphenol polyoxyethylene, 10 the gram cyclohexanone, add water to 100 the gram.The method that above raw material is prepared microemulsion routinely drops in the mixing kettle mixes, and forms microemulsion formulation 35% fluacrypyrim-S-sumicidin microemulsion.
Claims (5)
1, a kind of Synergistic insecticidal compositions that contains fluacrypyrim and S-sumicidin is characterized in that it contains fluacrypyrim and S-sumicidin, and its weight portion is respectively 0.1～30 and 0.1～20.
2, the Synergistic insecticidal compositions that contains fluacrypyrim and S-sumicidin according to claim 1, the weight portion that it is characterized in that fluacrypyrim is 0.1～25; The weight portion of S-sumicidin is 0.1～10.
3, the Synergistic insecticidal compositions that contains fluacrypyrim and S-sumicidin according to claim 1 is characterized in that it is that active ingredient is equipped with insecticides adjuvant and excipients is mixed with missible oil, aqueous emulsion, microemulsion with fluacrypyrim and S-sumicidin.
4, the described Synergistic insecticidal compositions that contains fluacrypyrim and S-sumicidin of claim 1 is used to prevent and treat the resistance lepidoptera pest.
5, application according to claim 4 is characterized in that being used to prevent and treat the diamond-back moth and the snout moth's larva of rice.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100414402A CN100360029C (en) | 2005-08-12 | 2005-08-12 | Synergistic compound pesticide contg. pyrimidifen and S-fenvalerate, and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100414402A CN100360029C (en) | 2005-08-12 | 2005-08-12 | Synergistic compound pesticide contg. pyrimidifen and S-fenvalerate, and its application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1911026A CN1911026A (en) | 2007-02-14 |
| CN100360029C true CN100360029C (en) | 2008-01-09 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNB2005100414402A Expired - Fee Related CN100360029C (en) | 2005-08-12 | 2005-08-12 | Synergistic compound pesticide contg. pyrimidifen and S-fenvalerate, and its application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100360029C (en) |
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2005
- 2005-08-12 CN CNB2005100414402A patent/CN100360029C/en not_active Expired - Fee Related
Non-Patent Citations (1)
| Title |
|---|
| 新型甲氧基丙烯酸酯类杀螨剂嘧螨酯. 刘长令等.世界农药，第24卷第4期. 2002 * |
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| CN1911026A (en) | 2007-02-14 |
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Address after: 211300 Pagoda Road 269, Gaochun County, Jiangsu, Nanjing Patentee after: Nanjing No.1 Pesticide Group Co.,Ltd. Address before: 211300 Pagoda Road 269, Gaochun County, Jiangsu, Nanjing Patentee before: NANJING NO 1 PESTICIDE Co.,Ltd. |
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Effective date of registration: 20111021 Address after: Dongfeng Road, Xi Zhen Gaochun County of Nanjing City, Jiangsu province 211318, No. 8 Patentee after: NANJING RED SUN Co.,Ltd. Address before: 211300 Pagoda Road 269, Gaochun County, Jiangsu, Nanjing Patentee before: Nanjing No.1 Pesticide Group Co.,Ltd. |
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Granted publication date: 20080109 Termination date: 20200812 |
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| CF01 | Termination of patent right due to non-payment of annual fee |