CN100360021C - Synergistic compound pesticide contg. fluacrypyrim and vermectins or methyl amino Avermectins benzoate, and its application Avermectins - Google Patents
Synergistic compound pesticide contg. fluacrypyrim and vermectins or methyl amino Avermectins benzoate, and its application Avermectins Download PDFInfo
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- CN100360021C CN100360021C CNB2005100414417A CN200510041441A CN100360021C CN 100360021 C CN100360021 C CN 100360021C CN B2005100414417 A CNB2005100414417 A CN B2005100414417A CN 200510041441 A CN200510041441 A CN 200510041441A CN 100360021 C CN100360021 C CN 100360021C
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- avermectin
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Abstract
A synergistic composite insecticide for preventing and treating cabbage caterpillar and rice borer contains two primary active components including abamectin or methylamino abamectin benzoate, assistant and excipient.
Description
One, technical field
The present invention relates to a kind of Pesticidal combination and uses thereof, especially a kind of Synergistic insecticidal compositions and application thereof that contains fluacrypyrim and Avermectin or emamection benaoate.
Two, technical background
Fluacrypyrim (test code number: NA83, adopted name: fluacrypyrim, trade name: Titaron) be first methoxy acrylic miticide by BASF AG development, the exploitation of Japanese Cao Da company.Fluacrypyrim is on the basis of methoxy acrylic bactericide, and is synthetic at random, and find through optimization.The chemical name of fluacrypyrim is methyl (E)-2-{a-[2-isopropoxy-6-(trifluoromethyl) pyrimidine-4-base oxygen base]-o-tolyl }-the 3-methoxy-methyl acrylate.
Fluacrypyrim is that the mitochondrial respiratory inhibitor promptly shifts the mitochondrial breathing of inhibition by electronics between cytochrome b and c1.Extranuclear mitochondria mainly by breathing to cell provides energy (ATP), if mitochondrial respiratory is obstructed, can not produce ATP, and cell will be dead.
Fluacrypyrim is mainly used in multiple mite class such as European red mite, the citrus red mite etc. in control fruit tree such as apple, citrus, the pears etc.The mixture main component is that methoxy acrylic ester compounds such as fluacrypyrim and a lot of organophosphorus compound are formed in the patent, is used for anti-ly curing the disease, insect pest.And the relevant report of not finding antibiotic combinations such as Fluoxastrobin and Avermectin occurs.
The main insecticidal constituent of Avermectin (abamectin) (Avermectin B1a+B1b, wherein B1a is not less than 90%, B1b is no more than 5%) is demarcated with the content of B1a.Since the harmful utmost point in 1991 goes out after (abamectin) enter China agricultural chemicals market, the Avermectin series pesticide occupies than critical role in the control of insect system of China.
Report abamectin pest killing spectrum has 84 kinds at present, China be used for preventing and treating more polypide little, from generation to generation many, be prone to drug-fast insect such as pear sucker, cotten aphid etc., the insect of leaf mining such as Americal rice leaf miner etc., evil mite such as Tetranychus urticae, tea orange tetranychid, tetranychus viennensis and the host is wide, feeding habits are assorted insect such as diamond-back moth etc.The insecticidal mechanism of Avermectin uniqueness: Avermectin is a kind of never poison, its mechanism is the GABAA acceptor that acts on insect synapse or neuromuscular synapse, nerve endings is in the GABAA of insect synapse or neuromuscular synapse acceptor in the interference insect body, the information transmission of nerve endings in the interference insect body, promptly excite nerve not the tip emit neurotransmission inhibitor γ-An Jidingsuan (GA-BA), impel the chloride channel of GABA gate to prolong open, chloride channel had activation, a large amount of chlorions pour in and cause the hyperpolarization of neu current potential, cause neu to be in holddown, thereby block nerves is getting in touch of the tip and muscle not, makes the insect paralysis, food refusal, dead.Because of its mechanism of action uniqueness, so do not have cross resistance with the medicament of using always.
It is reported that except that the chloride channel of GABA acceptor control, Avermectin can also influence the chloride channel of other ligand controls, can induce the irreversible increase of the myofibrillar film conduction of the innerv locust of no GABA energy as Ivermectin.
Avermectin has good layer and moves activity, and layer moves activity and refers to Avermectin and can infiltrate after spraying in the crop leaf tissue, formation anther sac in the epidermis parenchyma cell, and long term storage is so avermitilis strain have the lasting period preferably.Because its good layer moves activity, make Avermectin have efficiently to the insect that evil mite, Liriomyza, leaf miner and conventional dose such as other borer pests or sucking pest are difficult to prevent and treat.Avermectin is easily degraded in soil and water, and in soil by adsorption by soil, can leaching, noresidue does not pollute the environment; It is residual also not have accumulation and persistence in vivo, so Avermectin should belong to public nuisance-free agricultural chemicals.Avermectin can also resolve into by edaphon has more highly active derivative, as the insecticidal action that produces for Plant nematode.
Emamection benaoate is the derivative of Avermectin, and its insecticidal action principle is identical with Avermectin.
The synergistic complex of agricultural chemicals is expanding prevention spectrum and the effective measures that improve preventive effect, still finds no the Pesticidal combination and the application on the control cabbage caterpillar and the snout moth's larva of rice thereof of closing fluacrypyrim and Avermectin or emamection benaoate up to now.
Summary of the invention
But the Pesticidal combination that contains fluacrypyrim and Avermectin or emamectin-benzoate that the purpose of this invention is to provide a kind of high-efficiency prevention and control resistance lepidoptera pest.
Technical scheme of the present invention is:
A kind of Synergistic insecticidal compositions that contains fluacrypyrim and Avermectin or emamection benaoate, it is characterized in that it by effective ingredient fluacrypyrim and Avermectin or emamectin-benzoate, its weight portion is respectively 0.1～30 part and 0.1～20 part.
Described effective ingredient is present in the composition with the synergy effective dose.
Optimum weight part of effective ingredient fluacrypyrim is 0.1～25; Optimum weight part of effective ingredient Avermectin or emamectin-benzoate is 0.2～10.
The Synergistic insecticidal compositions that contains fluacrypyrim and Avermectin or emamection benaoate of the present invention is based on effective ingredient fluacrypyrim and Avermectin or emamectin-benzoate, is equipped with insecticides adjuvant, excipients is mixed with missible oil, aqueous emulsion, microemulsion.
The Synergistic insecticidal compositions that contains fluacrypyrim and Avermectin or emamection benaoate of the present invention can prevented and treated being applicable on the resistance lepidoptera pest.Especially on the control diamond-back moth and the snout moth's larva of rice, apply.
For achieving the above object, the present invention is by the network analysis to fluacrypyrim and Avermectin or emamection benaoate insecticidal properties, make full use of both mutual supplement with each other's advantages, fluacrypyrim and Avermectin or emamection benaoate is composite according to certain ratio, obtain a kind of new and effective multifunctional insecticide composition.The various pests that this insecticide antagonism diamond-back moth, the snout moth's larva of rice, beet armyworm etc. are easy to generate resistance has good preventive effect; And the inhibition insect is to the pesticide resistance generation of unitary agent (fluacrypyrim or Avermectin or emamection benaoate).
Beneficial effect of the present invention:
Pesticidal combination of the present invention compared with prior art produces following beneficial effect: (1) is compared with single agent, and the said composition antagonism lepidoptera pest such as the snout moth's larva of rice, resistance diamond-back moth etc. has notable synergistic, obviously improved control efficiency; (2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously, reduce control recruitment cost; (3) alternative high-toxic pesticide; (4) have concurrently quick-acting and long-acting; (5) compare with Avermectin or emamection benaoate or the agent of fluacrypyrim list, produce and the use cost reduction; (6) suppress the resistance enhancing of lepidoptera pest to agricultural chemicals; (7) reduction is to the toxicity of warm blooded animal.
Embodiment
The present invention is further illustrated below in conjunction with embodiment.
Embodiment 1:
Take by weighing fluacrypyrim 4 gram, Avermectin 1 gram, calcium dodecyl benzene sulfonate 4 grams, phenethyl phenol polyethenoxy ether 3 grams, surplus dimethylbenzene and add to gross weight 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 5% fluacrypyrim-abamectin emulsifiable concentrate.
Carry out indoor synergy biologicall test, selecting the resistance diamond-back moth is target pest, and every processing repeats 3 times, and every concentration is handled 60, presses the abundant method of Sun Yun with the LC50 value and calculates co-toxicity coefficient:
The indoor measurement result of table 1. 5% fluacrypyrim-Avermectin or emamection benaoate missible oil and single agent antagonism diamond-back moth thereof:
| Medicament | The mensuration project | Drug concentration (mg/l) | ||||||
| 0 | 2.5 | 5 | 10 | 20 | 40 | 80 | ||
| 1.8% abamectin emulsifiable concentrate | Death toll | 3 | 27 | 36 | 41 | 47 | 55 | 60 |
| Corrected mortality % | 42.1 | 57.9 | 66.7 | 77.2 | 91.2 | 99.9 | ||
| 4.5% fluacrypyrim missible oil | Death toll | 3 | 12 | 31 | 43 | 50 | 55 | 57 |
| Corrected mortality % | 15.8 | 49.1 | 70.2 | 82.5 | 91.2 | 94.7 | ||
| 5% fluacrypyrim abamectin emulsifiable concentrate | Death toll | 3 | 29 | 35 | 43 | 52 | 58 | 60 |
| Corrected mortality % | 45.6 | 56.1 | 70.2 | 86.0 | 96.5 | 99.9 | ||
Annotate: the resistance diamond-back moth that every drug concentration is handled adds up to 60.
Calculate toxicity regression equation and the lethal concentration of 50 LC50 of each medicament antagonism diamond-back moth with probability value method, the results are shown in Table 2:
Toxicity regression equation and the lethal concentration of 50 LC of table 2 5% fluacrypyrim abamectin emulsifiable concentrate and single agent antagonism diamond-back moth
50
| Medicament | Virulence regression equation | LC 50(mg/l) | LC 95(mg/l) | Co-toxicity coefficient |
| Avermectin | Y＝3.63040+1.728332X | 6.20065 | 55.4801 | |
| Fluacrypyrim missible oil | Y＝4.17070+1.373014X | 4.01788 | 63.3848 | |
| The fluacrypyrim Avermectin | Y＝4.09841+1.594831X | 3.67554 | 39.5081 | 132.6645 |
Embodiment 2:
Take by weighing fluacrypyrim 4 grams, emamection benaoate 0.2 gram, phenethyl phenol polyethenoxy ether phosphate 3 grams, polyoxyethylene polyoxy third rare block compound as farming breast 33
#2 grams, alkylphenol polyoxyethylene 1 gram, dimethylbenzene 13 grams add water to gross weight 100 grams.The method of above raw material being prepared routinely aqueous emulsion drops into the mixing of mixing kettle high speed, forms aqueous emulsion preparation 4.2% fluacrypyrim-emamection benaoate aqueous emulsion.
Embodiment 3:
Take by weighing fluacrypyrim 2 grams, Avermectin 0.5 gram, calcium dodecyl benzene sulfonate 6 grams, phenethyl phenol polyethenoxy ether phosphate 3 grams, polyoxyethylene polyoxy third rare block compound as farming breast 33
#2 grams, alkylphenol polyoxyethylene 1 gram, cyclohexanone 10 grams add water to gross weight 100.The method that above raw material is prepared microemulsion routinely drops in the mixing kettle mixes, and forms microemulsion formulation 2.5% fluacrypyrim-Avermectin or emamection benaoate microemulsion.
It is as follows that embodiment is carried out test of pesticide effectiveness result:
| Handle (extension rate) | Radix before the medicine | Behind the medicine 2 days | Behind the medicine 5 days | Behind the medicine 10 days | ||||
| Residual borer population | Preventive effect | Residual borer population | Preventive effect | Residual borer population | Preventive effect | |||
| Embodiment 1 | 500 | 360 | 40 | 88.44a | 32 | 90.20a | 22 | 91.22a |
| 1000 | 372 | 52 | 85.45ab | 60 | 82.12b | 42 | 83.78b | |
| 1500 | 572 | 164 | 70.16c | 132 | 74.41c | 88 | 77.91c | |
| Embodiment 2 | 500 | 330 | 85 | 85.16 | 88 | 88.87A | 79 | 83.22a |
| 1000 | 328 | 81 | 80.6 | 80 | 82.04B | 74 | 78.61b | |
| 1500 | 467 | 72 | 71.95 | 73 | 75.65C | 64 | 70.92c | |
| Embodiment 3 | 500 | 352 | 63 | 82.2a | 41 | 88.32a | 31 | 91.25a |
| 1000 | 435 | 87 | 80.1ab | 64 | 85.2b | 46 | 89.38b | |
| 1500 | 467 | 111 | 76.2c | 101 | 78.3c | 119 | 74.56c | |
| 1.8% Avermectin 1000 | 512 | 100 | 79.24b | 78 | 83.12b | 52 | 85.40b | |
| Fluacrypyrim 1000 | 390 | 110 | 70.64c | 108 | 69.05c | 98 | 63.90d | |
| Contrast | 408 | 392 | 368 | 284 | ||||
Annotate: a is illustrated on α=0.05 level remarkable, and b is illustrated on α=0.05 level variant, and c is illustrated on α=0.05 level not remarkable
Embodiment 4:
Taking by weighing fluacrypyrim 0.1 gram, Avermectin 0.1 gram, calcium dodecyl benzene sulfonate 4 grams, phenethyl phenol polyethenoxy ether 3 grams, surplus dimethylbenzene ad pond om is 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 0.2% fluacrypyrim-abamectin emulsifiable concentrate.
Embodiment 5:
Take by weighing fluacrypyrim 30 grams, emamection benaoate 20 grams, phenethyl phenol polyethenoxy ether phosphate 3 grams, polyoxyethylene polyoxy third rare block compound as farming breast 33
#2 grams, alkylphenol polyoxyethylene 1 gram, dimethylbenzene 13 grams add water to gross weight 100 grams.The method of above raw material being prepared routinely aqueous emulsion drops into the mixing of mixing kettle high speed, forms aqueous emulsion preparation 50% fluacrypyrim-emamection benaoate aqueous emulsion.
Embodiment 6:
Take by weighing fluacrypyrim 0.1 gram, Avermectin 20 grams, calcium dodecyl benzene sulfonate 6 grams, phenethyl phenol polyethenoxy ether phosphate 3 grams, polyoxyethylene polyoxy third rare block compound as farming breast 33
#2 grams, alkylphenol polyoxyethylene 1 gram, cyclohexanone 10 grams add water to gross weight 100 grams.The method that above raw material is prepared microemulsion routinely drops in the mixing kettle mixes, and forms microemulsion formulation 20.1% fluacrypyrim-Avermectin or emamection benaoate microemulsion.
Embodiment 7:
Taking by weighing fluacrypyrim 30 gram, Avermectin 0.1 gram, calcium dodecyl benzene sulfonate 4 grams, phenethyl phenol polyethenoxy ether 3 grams, surplus dimethylbenzene ad pond om is 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 30.1% fluacrypyrim-abamectin emulsifiable concentrate.
Embodiment 8:
Take by weighing fluacrypyrim 25 grams, emamection benaoate 10 grams, phenethyl phenol polyethenoxy ether phosphate 3 grams, polyoxyethylene polyoxy third rare block compound as farming breast 33
#2 grams, alkylphenol polyoxyethylene 1 gram, dimethylbenzene 13 grams add water to gross weight 100 grams.The method of above raw material being prepared routinely aqueous emulsion drops into the mixing of mixing kettle high speed, forms aqueous emulsion preparation 35% fluacrypyrim-emamection benaoate aqueous emulsion.
Embodiment 9:
Take by weighing fluacrypyrim 0.1 gram, Avermectin 10 grams, calcium dodecyl benzene sulfonate 6 grams, phenethyl phenol polyethenoxy ether phosphate 3 grams, polyoxyethylene polyoxy third rare block compound as farming breast 33
#2 grams, alkylphenol polyoxyethylene 1 gram, cyclohexanone 10 grams add water to gross weight 100 grams.The method that above raw material is prepared microemulsion routinely drops in the mixing kettle mixes, and forms microemulsion formulation 11.1% fluacrypyrim-Avermectin or emamection benaoate microemulsion.
Embodiment 10:
Take by weighing fluacrypyrim 25 grams, Avermectin 0.1 gram, calcium dodecyl benzene sulfonate 6 grams, phenethyl phenol polyethenoxy ether phosphate 3 grams, polyoxyethylene polyoxy third rare block compound as farming breast 33
#2 grams, alkylphenol polyoxyethylene 1 gram, cyclohexanone 10 grams add water to gross weight 100 grams.The method that above raw material is prepared microemulsion routinely drops in the mixing kettle mixes, and forms microemulsion formulation 25.1% fluacrypyrim-Avermectin or emamection benaoate microemulsion.
Field efficacy is the result show, fluacrypyrim Avermectin or emamection benaoate composition antagonism diamond-back moth have good control efficiency, and control efficiency all is better than single agent kind.
Claims (5)
1, a kind of Pesticidal combination is characterized in that it by effective ingredient fluacrypyrim and Avermectin or emamectin-benzoate, and its weight portion is respectively 0.1～30 part and 0.1～20 part.
2, Pesticidal combination according to claim 1, the weight portion that it is characterized in that the effective ingredient fluacrypyrim is 0.1～25; The weight portion of effective ingredient Avermectin or emamectin-benzoate is 0.2～10.
3, Pesticidal combination according to claim 1 is characterized in that it based on effective ingredient fluacrypyrim and Avermectin or emamectin-benzoate, is equipped with insecticides adjuvant, excipients is mixed with missible oil, aqueous emulsion, microemulsion.
4, the described Pesticidal combination of claim 1 is in the application that prevents and treats on the resistance lepidoptera pest.
5, application according to claim 4 is characterized in that being used to prevent and treat the diamond-back moth and the snout moth's larva of rice.
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| CNB2005100414417A CN100360021C (en) | 2005-08-12 | 2005-08-12 | Synergistic compound pesticide contg. fluacrypyrim and vermectins or methyl amino Avermectins benzoate, and its application Avermectins |
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| CNB2005100414417A CN100360021C (en) | 2005-08-12 | 2005-08-12 | Synergistic compound pesticide contg. fluacrypyrim and vermectins or methyl amino Avermectins benzoate, and its application Avermectins |
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| CN1911018A CN1911018A (en) | 2007-02-14 |
| CN100360021C true CN100360021C (en) | 2008-01-09 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101422155B (en) * | 2007-10-29 | 2013-02-27 | 山东京博控股股份有限公司 | Insecticide and miticide composition |
| CN102599174A (en) * | 2008-12-31 | 2012-07-25 | 浙江世佳科技有限公司 | Wettable powder of propylene glycol alginate and avermectin |
| CN102613213A (en) * | 2008-12-31 | 2012-08-01 | 浙江世佳科技有限公司 | Seed coating containing propylene glycol alginate and abamectin |
| CN102232380A (en) * | 2008-12-31 | 2011-11-09 | 浙江世佳科技有限公司 | Insecticidal composition containing propylene glycol alginate and abamectin |
| CN105638671B (en) * | 2012-05-05 | 2018-05-18 | 陕西美邦农药有限公司 | A kind of high-efficient pesticide composition |
| CN105707080B (en) * | 2012-05-18 | 2018-07-03 | 陕西美邦农药有限公司 | A kind of Pesticidal combination containing fluacrypyrim |
| CN107660545A (en) * | 2017-11-27 | 2018-02-06 | 陈荷芬 | A kind of insecticide pesticide preparation containing fluacrypyrim and emamection benaoate |
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Non-Patent Citations (1)
| Title |
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| 新型甲氧基丙烯酸酯类杀螨剂嘧螨酯. 刘长令等.世界农药，第24卷第4期. 2004 * |
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