CA2913682C - Procedes pour la preparation de chlorure de magnesium par lixiviation par hcl de divers materiaux - Google Patents
Procedes pour la preparation de chlorure de magnesium par lixiviation par hcl de divers materiaux Download PDFInfo
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- CA2913682C CA2913682C CA2913682A CA2913682A CA2913682C CA 2913682 C CA2913682 C CA 2913682C CA 2913682 A CA2913682 A CA 2913682A CA 2913682 A CA2913682 A CA 2913682A CA 2913682 C CA2913682 C CA 2913682C
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- Prior art keywords
- hci
- leachate
- precipitate
- concentration
- solid
- Prior art date
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- 238000000034 method Methods 0.000 title claims abstract description 394
- 230000008569 process Effects 0.000 title claims abstract description 369
- 239000000463 material Substances 0.000 title claims abstract description 170
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 title claims description 132
- 238000002386 leaching Methods 0.000 title claims description 127
- 229910001629 magnesium chloride Inorganic materials 0.000 title claims description 66
- 229910052751 metal Inorganic materials 0.000 claims abstract description 193
- 239000002184 metal Substances 0.000 claims abstract description 193
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 144
- 239000007787 solid Substances 0.000 claims abstract description 141
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 85
- 239000011777 magnesium Substances 0.000 claims abstract description 65
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 61
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 53
- 239000010936 titanium Substances 0.000 claims abstract description 40
- 229910001510 metal chloride Inorganic materials 0.000 claims abstract description 35
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 25
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 620
- 239000002244 precipitate Substances 0.000 claims description 163
- 239000007788 liquid Substances 0.000 claims description 161
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 91
- 239000002253 acid Substances 0.000 claims description 89
- -1 aluminum ions Chemical class 0.000 claims description 85
- 239000000203 mixture Substances 0.000 claims description 78
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 75
- 238000001354 calcination Methods 0.000 claims description 74
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 71
- 238000010438 heat treatment Methods 0.000 claims description 69
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 65
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 64
- 238000002425 crystallisation Methods 0.000 claims description 61
- 230000008025 crystallization Effects 0.000 claims description 59
- 235000012245 magnesium oxide Nutrition 0.000 claims description 54
- 238000011084 recovery Methods 0.000 claims description 54
- 239000000395 magnesium oxide Substances 0.000 claims description 52
- 238000004519 manufacturing process Methods 0.000 claims description 45
- 150000001805 chlorine compounds Chemical class 0.000 claims description 44
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 36
- 238000006243 chemical reaction Methods 0.000 claims description 32
- 239000000377 silicon dioxide Substances 0.000 claims description 32
- 229910052681 coesite Inorganic materials 0.000 claims description 28
- 229910052906 cristobalite Inorganic materials 0.000 claims description 28
- 239000007789 gas Substances 0.000 claims description 28
- 230000001376 precipitating effect Effects 0.000 claims description 28
- 229910052682 stishovite Inorganic materials 0.000 claims description 28
- 229910052905 tridymite Inorganic materials 0.000 claims description 28
- 235000011149 sulphuric acid Nutrition 0.000 claims description 25
- 238000001556 precipitation Methods 0.000 claims description 24
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims description 23
- 229910001425 magnesium ion Inorganic materials 0.000 claims description 23
- 239000012530 fluid Substances 0.000 claims description 22
- 229910052593 corundum Inorganic materials 0.000 claims description 21
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 21
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 19
- 239000001110 calcium chloride Substances 0.000 claims description 18
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 18
- 235000011148 calcium chloride Nutrition 0.000 claims description 18
- 239000012528 membrane Substances 0.000 claims description 13
- 238000000638 solvent extraction Methods 0.000 claims description 13
- 229910052799 carbon Inorganic materials 0.000 claims description 12
- 238000002485 combustion reaction Methods 0.000 claims description 10
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims description 9
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 8
- 238000004064 recycling Methods 0.000 claims description 8
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 7
- 229910021577 Iron(II) chloride Inorganic materials 0.000 claims description 7
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 230000009467 reduction Effects 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000004821 distillation Methods 0.000 claims description 5
- 238000005243 fluidization Methods 0.000 claims description 5
- 229920002215 polytrimethylene terephthalate Polymers 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 4
- 239000003245 coal Substances 0.000 claims description 4
- 238000010924 continuous production Methods 0.000 claims description 4
- 229910010068 TiCl2 Inorganic materials 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 239000002737 fuel gas Substances 0.000 claims description 3
- 239000003345 natural gas Substances 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 239000011819 refractory material Substances 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 claims description 3
- 229910003074 TiCl4 Inorganic materials 0.000 claims description 2
- 238000005485 electric heating Methods 0.000 claims description 2
- 239000002803 fossil fuel Substances 0.000 claims description 2
- 239000001294 propane Substances 0.000 claims description 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 2
- 239000011592 zinc chloride Substances 0.000 claims description 2
- 235000005074 zinc chloride Nutrition 0.000 claims description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical group [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 2
- 238000009626 Hall-Héroult process Methods 0.000 claims 1
- 238000010793 Steam injection (oil industry) Methods 0.000 claims 1
- 239000003638 chemical reducing agent Substances 0.000 claims 1
- 229910052594 sapphire Inorganic materials 0.000 claims 1
- 229910006587 β-Al2O3 Inorganic materials 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 92
- 229910052761 rare earth metal Inorganic materials 0.000 abstract description 67
- 150000002739 metals Chemical class 0.000 abstract description 60
- 229910052742 iron Inorganic materials 0.000 abstract description 52
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 39
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 20
- 229910052759 nickel Inorganic materials 0.000 abstract description 18
- 239000010949 copper Substances 0.000 abstract description 17
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract description 16
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract description 16
- 239000011701 zinc Substances 0.000 abstract description 15
- 229910052802 copper Inorganic materials 0.000 abstract description 14
- 229910052725 zinc Inorganic materials 0.000 abstract description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 11
- 229910052744 lithium Inorganic materials 0.000 abstract description 11
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 10
- 229910017052 cobalt Inorganic materials 0.000 abstract description 10
- 239000010941 cobalt Substances 0.000 abstract description 10
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract description 10
- 229910052763 palladium Inorganic materials 0.000 abstract description 9
- 229910052697 platinum Inorganic materials 0.000 abstract description 9
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract description 8
- 229910052737 gold Inorganic materials 0.000 abstract description 8
- 239000010931 gold Substances 0.000 abstract description 8
- 229910052709 silver Inorganic materials 0.000 abstract description 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract description 7
- 229910052750 molybdenum Inorganic materials 0.000 abstract description 7
- 239000011733 molybdenum Substances 0.000 abstract description 7
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 abstract description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052776 Thorium Inorganic materials 0.000 abstract description 6
- 229910052770 Uranium Inorganic materials 0.000 abstract description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract description 6
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract description 6
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 6
- 239000011574 phosphorus Substances 0.000 abstract description 6
- 239000004332 silver Substances 0.000 abstract description 6
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 abstract description 6
- 229910044991 metal oxide Inorganic materials 0.000 abstract description 4
- 150000004706 metal oxides Chemical class 0.000 abstract description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 83
- 239000000047 product Substances 0.000 description 60
- 229940091250 magnesium supplement Drugs 0.000 description 46
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 42
- 229910052595 hematite Inorganic materials 0.000 description 37
- 239000011019 hematite Substances 0.000 description 37
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 37
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 36
- 239000000243 solution Substances 0.000 description 35
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 26
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 25
- 238000000605 extraction Methods 0.000 description 24
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 24
- 238000000746 purification Methods 0.000 description 23
- 229960002337 magnesium chloride Drugs 0.000 description 22
- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 description 21
- 239000007858 starting material Substances 0.000 description 20
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 19
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 19
- 238000000926 separation method Methods 0.000 description 18
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 17
- 230000008901 benefit Effects 0.000 description 17
- 150000002500 ions Chemical class 0.000 description 17
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 17
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 16
- 230000014509 gene expression Effects 0.000 description 15
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 15
- 241000196324 Embryophyta Species 0.000 description 14
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 14
- 229940063656 aluminum chloride Drugs 0.000 description 14
- 239000000126 substance Substances 0.000 description 14
- 239000004927 clay Substances 0.000 description 13
- 239000011780 sodium chloride Substances 0.000 description 13
- 229910052938 sodium sulfate Inorganic materials 0.000 description 13
- 235000011152 sodium sulphate Nutrition 0.000 description 13
- 239000002585 base Substances 0.000 description 12
- 238000010586 diagram Methods 0.000 description 12
- 239000010881 fly ash Substances 0.000 description 12
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 12
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 12
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 12
- 229910052939 potassium sulfate Inorganic materials 0.000 description 12
- 239000002994 raw material Substances 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 11
- 239000012535 impurity Substances 0.000 description 11
- 239000011734 sodium Substances 0.000 description 11
- 239000007832 Na2SO4 Substances 0.000 description 10
- 239000011575 calcium Substances 0.000 description 10
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 10
- 238000005868 electrolysis reaction Methods 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 10
- 230000000704 physical effect Effects 0.000 description 10
- PMVSDNDAUGGCCE-TYYBGVCCSA-L Ferrous fumarate Chemical compound [Fe+2].[O-]C(=O)\C=C\C([O-])=O PMVSDNDAUGGCCE-TYYBGVCCSA-L 0.000 description 9
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 9
- 239000000292 calcium oxide Substances 0.000 description 9
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- 239000013078 crystal Substances 0.000 description 9
- 235000013980 iron oxide Nutrition 0.000 description 9
- 239000012452 mother liquor Substances 0.000 description 9
- 239000012071 phase Substances 0.000 description 9
- 235000002639 sodium chloride Nutrition 0.000 description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
- 229910001570 bauxite Inorganic materials 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 239000001103 potassium chloride Substances 0.000 description 8
- 235000011164 potassium chloride Nutrition 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
- 239000003513 alkali Substances 0.000 description 7
- JGDITNMASUZKPW-UHFFFAOYSA-K aluminium trichloride hexahydrate Chemical compound O.O.O.O.O.O.Cl[Al](Cl)Cl JGDITNMASUZKPW-UHFFFAOYSA-K 0.000 description 7
- 229940009861 aluminum chloride hexahydrate Drugs 0.000 description 7
- 239000011651 chromium Substances 0.000 description 7
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 7
- 239000000347 magnesium hydroxide Substances 0.000 description 7
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 7
- 235000012254 magnesium hydroxide Nutrition 0.000 description 7
- 229910052700 potassium Inorganic materials 0.000 description 7
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 6
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 6
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 6
- 239000010425 asbestos Substances 0.000 description 6
- 239000012267 brine Substances 0.000 description 6
- 229910052791 calcium Inorganic materials 0.000 description 6
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 6
- 238000001914 filtration Methods 0.000 description 6
- 229910001679 gibbsite Inorganic materials 0.000 description 6
- 230000007062 hydrolysis Effects 0.000 description 6
- 238000006460 hydrolysis reaction Methods 0.000 description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 description 6
- 235000010755 mineral Nutrition 0.000 description 6
- 239000011707 mineral Substances 0.000 description 6
- 230000008929 regeneration Effects 0.000 description 6
- 238000011069 regeneration method Methods 0.000 description 6
- 229910052895 riebeckite Inorganic materials 0.000 description 6
- 239000002893 slag Substances 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 5
- 238000013459 approach Methods 0.000 description 5
- 239000007844 bleaching agent Substances 0.000 description 5
- 239000000470 constituent Substances 0.000 description 5
- 239000011737 fluorine Substances 0.000 description 5
- 229910052731 fluorine Inorganic materials 0.000 description 5
- 239000002609 medium Substances 0.000 description 5
- 230000002829 reductive effect Effects 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- 239000011133 lead Substances 0.000 description 4
- 229910052748 manganese Inorganic materials 0.000 description 4
- 239000011572 manganese Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 238000004094 preconcentration Methods 0.000 description 4
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 3
- 229910010066 TiC14 Inorganic materials 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 229910052614 beryl Inorganic materials 0.000 description 3
- 239000010430 carbonatite Substances 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 3
- 229910001610 cryolite Inorganic materials 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 229910052733 gallium Inorganic materials 0.000 description 3
- 239000002223 garnet Substances 0.000 description 3
- 150000004687 hexahydrates Chemical class 0.000 description 3
- 239000002440 industrial waste Substances 0.000 description 3
- 229910001710 laterite Inorganic materials 0.000 description 3
- 239000011504 laterite Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 235000006408 oxalic acid Nutrition 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical compound [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 description 3
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- 238000012546 transfer Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
- ZXAUZSQITFJWPS-UHFFFAOYSA-J zirconium(4+);disulfate Chemical compound [Zr+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZXAUZSQITFJWPS-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Les procédés décrits peuvent être efficaces pour traiter divers matériaux comprenant plusieurs métaux différents. Ces matériaux peuvent être lessivés avec HCl pour obtenir un lixiviat et un solide. Ensuite, ils peuvent être séparés lun de lautre et un premier métal peut être isolé du lixiviat. Ensuite, un second métal peut encore être isolé du lixiviat. Les premier et second métaux peuvent chacun être sélectivement isolés du lixiviat. Cela peut se faire en contrôlant la température du lixiviat, en ajustant le pH, en réagissant davantage sur le lixiviat avec HCl, etc. Les métaux qui peuvent être récupérés sous forme de chlorures métalliques peuvent éventuellement être transformés en oxydes métalliques correspondants, ce qui permet de récupérer le HCl. Les différents métaux peuvent être choisis parmi laluminium, le fer, le zinc, le cuivre, lor, largent, le molybdène, le cobalt, le magnésium, le lithium, le manganèse, le nickel, le palladium, le platine, le thorium, le phosphore, luranium, le titane, les terres rares et les métaux rares.
Applications Claiming Priority (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261705898P | 2012-09-26 | 2012-09-26 | |
| US61/705,898 | 2012-09-26 | ||
| US201261713795P | 2012-10-15 | 2012-10-15 | |
| US61/713,795 | 2012-10-15 | ||
| US201261726971P | 2012-11-15 | 2012-11-15 | |
| US61/726,971 | 2012-11-15 | ||
| US201361837715P | 2013-06-21 | 2013-06-21 | |
| US61/837,715 | 2013-06-21 | ||
| CA2885255A CA2885255C (fr) | 2012-09-26 | 2013-09-26 | Procedes pour la preparation d'alumine et de chlorure de magnesium par lixiviation par hcl de divers materiaux |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2885255A Division CA2885255C (fr) | 2012-09-26 | 2013-09-26 | Procedes pour la preparation d'alumine et de chlorure de magnesium par lixiviation par hcl de divers materiaux |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2913682A1 CA2913682A1 (fr) | 2014-04-03 |
| CA2913682C true CA2913682C (fr) | 2017-06-13 |
Family
ID=50382821
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2820631A Abandoned CA2820631A1 (fr) | 2012-09-26 | 2013-06-21 | Procedes pour traiter divers materiaux |
| CA2913682A Active CA2913682C (fr) | 2012-09-26 | 2013-09-26 | Procedes pour la preparation de chlorure de magnesium par lixiviation par hcl de divers materiaux |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2820631A Abandoned CA2820631A1 (fr) | 2012-09-26 | 2013-06-21 | Procedes pour traiter divers materiaux |
Country Status (1)
| Country | Link |
|---|---|
| CA (2) | CA2820631A1 (fr) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016049777A1 (fr) * | 2014-10-03 | 2016-04-07 | Orbite Technologies Inc. | Procédés de purification d'ions d'aluminium |
| CN107012341A (zh) * | 2017-04-21 | 2017-08-04 | 郭泽武 | 一种控缓释碱定向溶出有价金属的工艺 |
| CN107130120B (zh) * | 2017-04-28 | 2018-09-25 | 广西师范大学 | 一种非稀土杂质和稀土元素萃取分离方法 |
| CN114269955A (zh) * | 2020-07-22 | 2022-04-01 | 环保金属有限公司 | 从冶金残留物浸出有价元素的方法 |
| CN113234921A (zh) * | 2021-05-10 | 2021-08-10 | 贵州轻工职业技术学院 | 从含氟钨矿中提取钨和氟的方法及应用 |
| CN113388741A (zh) * | 2021-06-11 | 2021-09-14 | 紫金矿业集团股份有限公司 | 一种氧化铜钴矿综合回收铜和钴的方法 |
| CN115261604B (zh) * | 2022-03-04 | 2023-07-25 | 中南大学 | 一种蛇纹石酸浸提镁的方法 |
| CN115487816B (zh) * | 2022-08-16 | 2023-08-04 | 中国地质大学（武汉） | 一种基于蛭石的钼酸铁纳米酶及其制备方法和应用 |
| CN116004988A (zh) * | 2022-12-30 | 2023-04-25 | 中国科学院赣江创新研究院 | 一种从钕铁硼废料回收液中去除亚铁离子的方法 |
-
2013
- 2013-06-21 CA CA2820631A patent/CA2820631A1/fr not_active Abandoned
- 2013-09-26 CA CA2913682A patent/CA2913682C/fr active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CA2913682A1 (fr) | 2014-04-03 |
| CA2820631A1 (fr) | 2014-03-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20151127 |