CA2832741A1 - Generation of polyols from saccharides - Google Patents

Generation of polyols from saccharides Download PDF

Info

Publication number: CA2832741A1
Authority: CA; Canada
Prior art keywords: group; feedstock; saccharide; catalyst; component
Prior art date: 2011-07-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA2832741A

Other languages

English (en)

French (fr)

Inventor

John Q. Chen

Tom N. Kalnes

Joseph A. Kocal

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Honeywell UOP LLC

Original Assignee

UOP LLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2011-07-28

Filing date

2012-07-03

Publication date

2013-01-31

2011-07-28 Priority claimed from US13/192,970 external-priority patent/US8222462B2/en

2011-07-28 Priority claimed from US13/192,907 external-priority patent/US20110312487A1/en

2012-07-03 Application filed by UOP LLC filed Critical UOP LLC

2013-01-31 Publication of CA2832741A1 publication Critical patent/CA2832741A1/en

Status Abandoned legal-status Critical Current

Links

150000001720 carbohydrates Chemical class 0.000 title claims abstract description 78
229920005862 polyol Polymers 0.000 title claims abstract description 36
150000003077 polyols Chemical class 0.000 title claims abstract description 36
239000003054 catalyst Substances 0.000 claims abstract description 124
238000000034 method Methods 0.000 claims abstract description 37
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 33
239000001257 hydrogen Substances 0.000 claims abstract description 32
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 32
238000006243 chemical reaction Methods 0.000 claims description 77
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 24
150000001875 compounds Chemical class 0.000 claims description 24
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 21
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 18
229910052759 nickel Inorganic materials 0.000 claims description 17
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 16
229910052751 metal Inorganic materials 0.000 claims description 16
239000002184 metal Substances 0.000 claims description 16
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
150000004676 glycans Chemical class 0.000 claims description 14
229920001282 polysaccharide Polymers 0.000 claims description 14
239000005017 polysaccharide Substances 0.000 claims description 14
239000011949 solid catalyst Substances 0.000 claims description 13
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 10
150000002431 hydrogen Chemical class 0.000 claims description 10
229920005610 lignin Polymers 0.000 claims description 10
-1 CexZrOy Chemical compound 0.000 claims description 8
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 8
229910052741 iridium Inorganic materials 0.000 claims description 8
239000005078 molybdenum compound Substances 0.000 claims description 8
150000002752 molybdenum compounds Chemical class 0.000 claims description 8
229910052763 palladium Inorganic materials 0.000 claims description 8
229910052697 platinum Inorganic materials 0.000 claims description 8
229910052703 rhodium Inorganic materials 0.000 claims description 8
229910052707 ruthenium Inorganic materials 0.000 claims description 8
150000003658 tungsten compounds Chemical class 0.000 claims description 8
239000002028 Biomass Substances 0.000 claims description 7
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 7
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 7
239000000377 silicon dioxide Substances 0.000 claims description 7
229910052799 carbon Inorganic materials 0.000 claims description 6
150000002772 monosaccharides Chemical class 0.000 claims description 6
150000002989 phenols Chemical class 0.000 claims description 6
150000001298 alcohols Chemical class 0.000 claims description 5
150000001299 aldehydes Chemical class 0.000 claims description 5
229930195733 hydrocarbon Natural products 0.000 claims description 5
150000002430 hydrocarbons Chemical class 0.000 claims description 5
150000007524 organic acids Chemical class 0.000 claims description 5
235000005985 organic acids Nutrition 0.000 claims description 5
102000004169 proteins and genes Human genes 0.000 claims description 5
108090000623 proteins and genes Proteins 0.000 claims description 5
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 5
CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 claims description 5
239000010457 zeolite Substances 0.000 claims description 5
239000002253 acid Substances 0.000 claims description 4
238000000354 decomposition reaction Methods 0.000 claims description 4
229910003465 moissanite Inorganic materials 0.000 claims description 4
229910010271 silicon carbide Inorganic materials 0.000 claims description 4
229920002527 Glycogen Polymers 0.000 claims description 3
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
229940096919 glycogen Drugs 0.000 claims description 3
229910052750 molybdenum Inorganic materials 0.000 claims description 3
239000011733 molybdenum Substances 0.000 claims description 3
229910052721 tungsten Inorganic materials 0.000 claims description 3
239000010937 tungsten Substances 0.000 claims description 3
229910001930 tungsten oxide Inorganic materials 0.000 claims description 3
241000219310 Beta vulgaris subsp. vulgaris Species 0.000 claims description 2
229920002261 Corn starch Polymers 0.000 claims description 2
240000000111 Saccharum officinarum Species 0.000 claims description 2
235000007201 Saccharum officinarum Nutrition 0.000 claims description 2
235000021536 Sugar beet Nutrition 0.000 claims description 2
239000011111 cardboard Substances 0.000 claims description 2
235000013339 cereals Nutrition 0.000 claims description 2
239000008120 corn starch Substances 0.000 claims description 2
XAYGUHUYDMLJJV-UHFFFAOYSA-Z decaazanium;dioxido(dioxo)tungsten;hydron;trioxotungsten Chemical compound [H+].[H+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O XAYGUHUYDMLJJV-UHFFFAOYSA-Z 0.000 claims description 2
239000004744 fabric Substances 0.000 claims description 2
239000010842 industrial wastewater Substances 0.000 claims description 2
229910000476 molybdenum oxide Inorganic materials 0.000 claims description 2
239000010841 municipal wastewater Substances 0.000 claims description 2
PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical class [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims description 2
VVRQVWSVLMGPRN-UHFFFAOYSA-N oxotungsten Chemical class [W]=O VVRQVWSVLMGPRN-UHFFFAOYSA-N 0.000 claims description 2
239000000123 paper Substances 0.000 claims description 2
PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical class [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 claims description 2
239000002916 wood waste Substances 0.000 claims description 2
229910052681 coesite Inorganic materials 0.000 claims 1
229910052593 corundum Inorganic materials 0.000 claims 1
229910052906 cristobalite Inorganic materials 0.000 claims 1
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims 1
235000012239 silicon dioxide Nutrition 0.000 claims 1
229910052682 stishovite Inorganic materials 0.000 claims 1
229910052905 tridymite Inorganic materials 0.000 claims 1
229910001845 yogo sapphire Inorganic materials 0.000 claims 1
125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 52
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 35
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 25
239000001913 cellulose Substances 0.000 description 25
229920002678 cellulose Polymers 0.000 description 25
235000010980 cellulose Nutrition 0.000 description 25
239000000047 product Substances 0.000 description 23
238000011282 treatment Methods 0.000 description 18
239000011541 reaction mixture Substances 0.000 description 14
230000003197 catalytic effect Effects 0.000 description 13
239000002002 slurry Substances 0.000 description 13
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 12
229920002488 Hemicellulose Polymers 0.000 description 10
239000000463 material Substances 0.000 description 8
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 8
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 6
238000006555 catalytic reaction Methods 0.000 description 6
239000000376 reactant Substances 0.000 description 6
238000001914 filtration Methods 0.000 description 5
238000004519 manufacturing process Methods 0.000 description 5
239000000203 mixture Substances 0.000 description 5
238000011027 product recovery Methods 0.000 description 5
239000007787 solid Substances 0.000 description 5
239000000126 substance Substances 0.000 description 5
239000000543 intermediate Substances 0.000 description 4
239000007788 liquid Substances 0.000 description 4
239000000395 magnesium oxide Substances 0.000 description 4
239000012071 phase Substances 0.000 description 4
229910000975 Carbon steel Inorganic materials 0.000 description 3
239000010962 carbon steel Substances 0.000 description 3
238000010924 continuous production Methods 0.000 description 3
238000001035 drying Methods 0.000 description 3
238000000227 grinding Methods 0.000 description 3
230000007062 hydrolysis Effects 0.000 description 3
238000006460 hydrolysis reaction Methods 0.000 description 3
239000003622 immobilized catalyst Substances 0.000 description 3
238000005272 metallurgy Methods 0.000 description 3
239000002245 particle Substances 0.000 description 3
238000004513 sizing Methods 0.000 description 3
239000007790 solid phase Substances 0.000 description 3
238000007669 thermal treatment Methods 0.000 description 3
UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 3
239000002699 waste material Substances 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
238000009903 catalytic hydrogenation reaction Methods 0.000 description 2
238000005119 centrifugation Methods 0.000 description 2
239000011248 coating agent Substances 0.000 description 2
238000000576 coating method Methods 0.000 description 2
238000010586 diagram Methods 0.000 description 2
150000002016 disaccharides Chemical class 0.000 description 2
238000001704 evaporation Methods 0.000 description 2
230000008020 evaporation Effects 0.000 description 2
238000000605 extraction Methods 0.000 description 2
239000008394 flocculating agent Substances 0.000 description 2
235000013305 food Nutrition 0.000 description 2
238000005194 fractionation Methods 0.000 description 2
239000008103 glucose Substances 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
239000007791 liquid phase Substances 0.000 description 2
238000001556 precipitation Methods 0.000 description 2
238000000197 pyrolysis Methods 0.000 description 2
238000011084 recovery Methods 0.000 description 2
229910052726 zirconium Inorganic materials 0.000 description 2
229920002101 Chitin Polymers 0.000 description 1
240000008892 Helianthus tuberosus Species 0.000 description 1
235000003230 Helianthus tuberosus Nutrition 0.000 description 1
229920000168 Microcrystalline cellulose Polymers 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
229920002472 Starch Polymers 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
240000008042 Zea mays Species 0.000 description 1
235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
235000002017 Zea mays subsp mays Nutrition 0.000 description 1
238000005903 acid hydrolysis reaction Methods 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
238000012271 agricultural production Methods 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
238000009835 boiling Methods 0.000 description 1
CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical class CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
235000014633 carbohydrates Nutrition 0.000 description 1
239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
238000000975 co-precipitation Methods 0.000 description 1
235000005822 corn Nutrition 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
239000002537 cosmetic Substances 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
238000005265 energy consumption Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
230000007071 enzymatic hydrolysis Effects 0.000 description 1
238000006047 enzymatic hydrolysis reaction Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000002803 fossil fuel Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
238000004128 high performance liquid chromatography Methods 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
239000012535 impurity Substances 0.000 description 1
229910052809 inorganic oxide Inorganic materials 0.000 description 1
239000012263 liquid product Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
235000019813 microcrystalline cellulose Nutrition 0.000 description 1
239000008108 microcrystalline cellulose Substances 0.000 description 1
229940016286 microcrystalline cellulose Drugs 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
238000003541 multi-stage reaction Methods 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 1
229920001542 oligosaccharide Polymers 0.000 description 1
150000002482 oligosaccharides Chemical class 0.000 description 1
238000005580 one pot reaction Methods 0.000 description 1
239000008188 pellet Substances 0.000 description 1
IYDGMDWEHDFVQI-UHFFFAOYSA-N phosphoric acid;trioxotungsten Chemical compound O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.OP(O)(O)=O IYDGMDWEHDFVQI-UHFFFAOYSA-N 0.000 description 1
239000006187 pill Substances 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000010926 purge Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
238000007086 side reaction Methods 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
239000008107 starch Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000003826 tablet Substances 0.000 description 1
238000005979 thermal decomposition reaction Methods 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
239000010936 titanium Substances 0.000 description 1
230000000699 topical effect Effects 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/652—Chromium, molybdenum or tungsten
- B01J23/6525—Molybdenum
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/652—Chromium, molybdenum or tungsten
- B01J23/6527—Tungsten
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/883—Molybdenum and nickel
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8871—Rare earth metals or actinides
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
- B01J23/8885—Tungsten containing also molybdenum
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B01J27/19—Molybdenum
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Saccharide Compounds (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

CA2832741A 2011-07-28 2012-07-03 Generation of polyols from saccharides Abandoned CA2832741A1 (en)

Applications Claiming Priority (5)

Application Number	Priority Date	Filing Date	Title
US13/192,970 US8222462B2 (en)	2011-07-28	2011-07-28	Process for generation of polyols from saccharides
US13/192,907		2011-07-28
US13/192,907 US20110312487A1 (en)	2011-07-28	2011-07-28	Catalyst system for generation of polyols from saccharides
US13/192,970		2011-07-28
PCT/US2012/045343 WO2013015955A2 (en)	2011-07-28	2012-07-03	Generation of polyols from saccharides

Publications (1)

Publication Number	Publication Date
CA2832741A1 true CA2832741A1 (en)	2013-01-31

Family

ID=47601711

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA2832741A Abandoned CA2832741A1 (en)	2011-07-28	2012-07-03	Generation of polyols from saccharides

Country Status (6)

Country	Link
EP (1)	EP2736869A4 (zh)
CN (1)	CN103608320A (zh)
BR (1)	BR112013026705A2 (zh)
CA (1)	CA2832741A1 (zh)
TW (1)	TWI539994B (zh)
WO (1)	WO2013015955A2 (zh)

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EP3532453B1 (en) *	2016-10-28	2022-08-03	Shell Internationale Research Maatschappij B.V.	Process for the production of glycols
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2012
- 2012-07-03 BR BR112013026705A patent/BR112013026705A2/pt not_active IP Right Cessation
- 2012-07-03 EP EP12817777.1A patent/EP2736869A4/en not_active Withdrawn
- 2012-07-03 CA CA2832741A patent/CA2832741A1/en not_active Abandoned
- 2012-07-03 WO PCT/US2012/045343 patent/WO2013015955A2/en active Application Filing
- 2012-07-03 CN CN201280028835.7A patent/CN103608320A/zh active Pending
- 2012-07-25 TW TW101126858A patent/TWI539994B/zh not_active IP Right Cessation

Also Published As

Publication number	Publication date
EP2736869A2 (en)	2014-06-04
EP2736869A4 (en)	2015-01-07
CN103608320A (zh)	2014-02-26
WO2013015955A2 (en)	2013-01-31
WO2013015955A3 (en)	2013-03-21
TW201315540A (zh)	2013-04-16
TWI539994B (zh)	2016-07-01
BR112013026705A2 (pt)	2016-12-27

Publication	Publication Date	Title
US8222462B2 (en)	2012-07-17	Process for generation of polyols from saccharides
US8222463B2 (en)	2012-07-17	Process for generation of polyols from saccharide containing feedstock
US20110312487A1 (en)	2011-12-22	Catalyst system for generation of polyols from saccharides
US20110312488A1 (en)	2011-12-22	Catalyst system for generation of polyols from saccharide containing feedstock
CA2832741A1 (en)	2013-01-31	Generation of polyols from saccharides
US8222465B2 (en)	2012-07-17	Catalytic process for continuously generating polyols
US8222464B2 (en)	2012-07-17	Catalytic process for continuously generating polyols
US8323937B2 (en)	2012-12-04	Continuous catalytic generation of polyols from cellulose
US8410319B2 (en)	2013-04-02	Continuous catalytic generation of polyols from cellulose with recycle
EP3039002B1 (en)	2018-07-25	Process for the conversion of saccharide-containing feedstock
EP3551600A1 (en)	2019-10-16	Process for the preparation of glycols
CA2954327C (en)	2022-08-30	Processes for catalytic hydrogenation of saccharide feedstocks that exhibit reduced reactor fouling due to saccharide degradation
TWI477481B (zh)	2015-03-21	由包含醣類之原料生產多元醇
EP2981516B1 (en)	2018-09-26	Process for the conversion of saccharide-containing feedstock
US20160168061A1 (en)	2016-06-16	Methods and apparatuses for generating a polyol from biomass using multiple reaction zones and catalysts

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Date	Code	Title	Description
2013-11-30	EEER	Examination request	Effective date: 20131008
2016-08-15	FZDE	Dead	Effective date: 20160704