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CA2626296A1 - Polymer foams comprising chemically modified carbonaceous filler - Google Patents

Polymer foams comprising chemically modified carbonaceous filler Download PDF

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Publication number
CA2626296A1
CA2626296A1 CA002626296A CA2626296A CA2626296A1 CA 2626296 A1 CA2626296 A1 CA 2626296A1 CA 002626296 A CA002626296 A CA 002626296A CA 2626296 A CA2626296 A CA 2626296A CA 2626296 A1 CA2626296 A1 CA 2626296A1
Authority
CA
Canada
Prior art keywords
polymer foam
polymer
foam composition
carbonaceous filler
polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002626296A
Other languages
French (fr)
Other versions
CA2626296C (en
Inventor
Dennis M. Dalton
David A. Kinsman
Lynn M. Krajkowski
Adam L. Mackay
Collin P. Galloway
Eugene Wu
Agathagelos Kyrlidis
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cabot Corp
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/317,287 external-priority patent/US6258864B1/en
Application filed by Individual filed Critical Individual
Publication of CA2626296A1 publication Critical patent/CA2626296A1/en
Application granted granted Critical
Publication of CA2626296C publication Critical patent/CA2626296C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066Use of inorganic compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/04Ingredients treated with organic substances
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/04Ingredients treated with organic substances
    • C08K9/06Ingredients treated with organic substances with silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/44Carbon
    • C09C1/48Carbon black
    • C09C1/56Treatment of carbon black ; Purification

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Cephalosporin Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

An aggregate having attached at least one type of polymer is described, wherein the aggregate comprises at least one carbon phase and at least one species phase selected from a silicon-containing species phase and a metal-containing species phase. Methods of making the aggregate are further described which involve combining the starting aggregate with a reactive polymer and mixing in order to attach the polymer onto the aggregate. Uses of the aggregate are further described such as incorporating the aggregate into polymer foams and other polymeric products as well as elastomeric products.

Claims (18)

1. A polymer foam composition comprising polymer foam and at least one chemically modified carbonaceous filler, wherein said chemically modified carbonaceous filler comprises carbonaceous filler having attached polymer moieties.
2. The polymer foam composition of claim 1, wherein said carbonaceous filler is carbon black, activated carbon, graphite, carbon fibers, fibrils or mixtures thereof.
3. The polymer foam composition of claim 1 or 2, wherein said polymer foam composition is a closed-cell, rigid polymer foam, and said chemically modified carbonaceous filler is present in an amount of from about .01 to 10 wt %.
4. The polymer foam composition of claim 3, wherein the chemically modified carbonaceous filler is present in the foam in an amount from about .01 to about 5 wt %.
5. The polymer foam composition of any one of claims 1 to 4, wherein the polymer moieties comprise the reaction residue of reactively functionalized polymers selected from polyethylene, poly(vinylchloride), polyisobutylene, polystyrene, polycaprolactam (nylon), polyisoprene, polyamides, polycarbonates, polyelectrolytes, polyesters, polyethers, (polyhydroxy)benzenes, polyimides, polymers containing sulfur, polyolefins, polymethylbenzenes, polystyrene, styrene copolymers, acetal polymers, acrylic polymers, acrylonitrile polymers and copolymers, polyolefins containing halogen, fluoropolymers, ionomeric polymers, polymers containing ketone group(s), liquid crystal polymers, polyamide-imides, polymers containing olefinic double bond(s), polyolefin copolymers, polyphenylene oxides, polyurethanes, thermoplastic elastomers, silicone polymers, alkyd, epoxy, unsaturated polyester, or combinations thereof.
6. The polymer foam composition of any one of claims 1 to 5, wherein the polymer foam is polyurethane foam, polyisocyanurate, polystyrene, or a mixture thereof.
7. The polymer foam composition of claim 1, wherein the polymer foam is rigid, closed-cell polymer foam.
8. The polymer foam composition of claim 1 or 2, wherein the chemically modified carbonaceous filler is present in the polymer foam in an amount of from about .01 to about 18 wt. %.
9. The polymer foam composition of claim 7, wherein the polymer moieties includes functional groups selected from isocyanates, acyl azides, alcohols, amines, thiols, alkoxides, or combinations thereof.
10. The rigid, closed-cell polymer foam in accordance with claim 7 or 9, wherein the polymer foam is polyurethane foam, polyisocyanurate foam or polystyrene foam.
11. A reaction injection molding method of making the polymer foam composition of claim 1, wherein said reaction injection molding method comprises the steps of:
dispersing the chemically modified carbonaceous filler into a first reactant for the polymer foam, and then mixing a stream of the first reactant with a stream of second reactant for the polymer foam, wherein the polymer moieties are not stripped in substantial quantity from the carbonaceous filler by the mixing step.
12. A reactive component for a polymer foam, comprising chemically modified carbonaceous filler comprising polymer moieties attached to carbonaceous particulates.
13. A thermal insulation product comprising the rigid, closed-cell polymer foam of claim 7.
14. A method of insulating a structure, comprising incorporating into a wall of the structure the polymer foam composition of claim 7.
15. The method of insulating a structure in accordance with claim 14, wherein the structure is an architectural structure or a refrigeration appliance.
16. The polymer foam composition of any one of claims 1 to 4, wherein the polymer moieties comprise the reaction residue of reactively functionalized polymers selected from polyalkylene oxides.
17. The polymer foam composition of claim 16, where the alkylene moiety of the polyalkylene oxide is a C2 to C4 moiety.
18. The polymer foam composition of any one of claims 1 to 3, wherein the polymer moieties comprise the reaction residue of reactively functionalized polymers selected from polyethylene oxides and polypropylene oxides.
CA2626296A 1999-01-20 2000-01-19 Polymer foams comprising chemically modified carbonaceous filler Expired - Fee Related CA2626296C (en)

Applications Claiming Priority (13)

Application Number Priority Date Filing Date Title
US11650099P 1999-01-20 1999-01-20
US60/116,500 1999-01-20
US13555899P 1999-05-24 1999-05-24
US09/317,287 US6258864B1 (en) 1999-01-20 1999-05-24 Polymer foam containing chemically modified carbonaceous filler
US60/135,558 1999-05-24
US09/317,287 1999-05-24
US16371699P 1999-11-05 1999-11-05
US43527399A 1999-11-05 1999-11-05
US16385799P 1999-11-05 1999-11-05
US60/163,716 1999-11-05
US60/163,857 1999-11-05
US09/435,273 1999-11-05
CA002358848A CA2358848C (en) 1999-01-20 2000-01-19 Aggregates having attached polymer groups and polymer foams

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CA002358848A Division CA2358848C (en) 1999-01-20 2000-01-19 Aggregates having attached polymer groups and polymer foams

Publications (2)

Publication Number Publication Date
CA2626296A1 true CA2626296A1 (en) 2000-07-27
CA2626296C CA2626296C (en) 2011-12-13

Family

ID=27557884

Family Applications (2)

Application Number Title Priority Date Filing Date
CA002358848A Expired - Fee Related CA2358848C (en) 1999-01-20 2000-01-19 Aggregates having attached polymer groups and polymer foams
CA2626296A Expired - Fee Related CA2626296C (en) 1999-01-20 2000-01-19 Polymer foams comprising chemically modified carbonaceous filler

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CA002358848A Expired - Fee Related CA2358848C (en) 1999-01-20 2000-01-19 Aggregates having attached polymer groups and polymer foams

Country Status (9)

Country Link
EP (3) EP1222224B1 (en)
JP (3) JP2002535430A (en)
AT (2) ATE530594T1 (en)
AU (1) AU3210800A (en)
CA (2) CA2358848C (en)
DE (1) DE60037439T2 (en)
DK (1) DK1222224T3 (en)
ES (1) ES2295010T3 (en)
WO (1) WO2000043446A1 (en)

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Also Published As

Publication number Publication date
DK1222224T3 (en) 2008-03-25
JP2002535430A (en) 2002-10-22
ES2295010T3 (en) 2008-04-16
EP2316873A1 (en) 2011-05-04
DE60037439D1 (en) 2008-01-24
EP1222224B1 (en) 2007-12-12
AU3210800A (en) 2000-08-07
CA2626296C (en) 2011-12-13
WO2000043446A1 (en) 2000-07-27
CA2358848A1 (en) 2000-07-27
ATE380843T1 (en) 2007-12-15
EP1900766A1 (en) 2008-03-19
CA2358848C (en) 2009-03-24
EP1222224A1 (en) 2002-07-17
EP1900766B1 (en) 2011-10-26
DE60037439T2 (en) 2008-12-04
JP2015157959A (en) 2015-09-03
JP2011084748A (en) 2011-04-28
ATE530594T1 (en) 2011-11-15
EP2316873B1 (en) 2013-09-18

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