CA2293495C - Galvanisation des aciers reactifs - Google Patents
Galvanisation des aciers reactifs Download PDFInfo
- Publication number
- CA2293495C CA2293495C CA002293495A CA2293495A CA2293495C CA 2293495 C CA2293495 C CA 2293495C CA 002293495 A CA002293495 A CA 002293495A CA 2293495 A CA2293495 A CA 2293495A CA 2293495 C CA2293495 C CA 2293495C
- Authority
- CA
- Canada
- Prior art keywords
- vanadium
- amount
- alloy
- titanium
- zinc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 103
- 239000010959 steel Substances 0.000 title claims abstract description 103
- 238000005246 galvanizing Methods 0.000 title claims abstract description 68
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 86
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 85
- 239000010936 titanium Substances 0.000 claims abstract description 72
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 64
- 239000000956 alloy Substances 0.000 claims abstract description 64
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 60
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 59
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 57
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 55
- 229910052718 tin Inorganic materials 0.000 claims abstract description 55
- 238000000034 method Methods 0.000 claims abstract description 45
- 239000011701 zinc Substances 0.000 claims abstract description 43
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 42
- 230000008569 process Effects 0.000 claims abstract description 42
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 42
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 32
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 32
- 238000007654 immersion Methods 0.000 claims abstract description 28
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 27
- 229910001297 Zn alloy Inorganic materials 0.000 claims abstract description 20
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 16
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 16
- 230000009257 reactivity Effects 0.000 claims description 34
- 229910052710 silicon Inorganic materials 0.000 abstract description 61
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 59
- 239000010703 silicon Substances 0.000 abstract description 59
- 239000000203 mixture Substances 0.000 abstract description 23
- QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical compound [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 abstract description 7
- 229910000990 Ni alloy Inorganic materials 0.000 abstract description 4
- 241000518994 Conta Species 0.000 abstract 1
- 238000000576 coating method Methods 0.000 description 48
- 239000011248 coating agent Substances 0.000 description 29
- 238000007792 addition Methods 0.000 description 20
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 13
- 238000012360 testing method Methods 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 6
- 230000004580 weight loss Effects 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 229910000756 V alloy Inorganic materials 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- 229910001128 Sn alloy Inorganic materials 0.000 description 3
- 229910020938 Sn-Ni Inorganic materials 0.000 description 3
- 229910008937 Sn—Ni Inorganic materials 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229910008839 Sn—Ti Inorganic materials 0.000 description 2
- UKUJCSBWRBWNAV-UHFFFAOYSA-N [Sn].[V] Chemical compound [Sn].[V] UKUJCSBWRBWNAV-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 238000005275 alloying Methods 0.000 description 2
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000009749 continuous casting Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 230000001965 increasing effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- 229910021332 silicide Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 229910000976 Electrical steel Inorganic materials 0.000 description 1
- 229910002593 Fe-Ti Inorganic materials 0.000 description 1
- 229910000655 Killed steel Inorganic materials 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 238000004125 X-ray microanalysis Methods 0.000 description 1
- BLOIXGFLXPCOGW-UHFFFAOYSA-N [Ti].[Sn] Chemical compound [Ti].[Sn] BLOIXGFLXPCOGW-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- XEPNJJFNSJKTSO-UHFFFAOYSA-N azanium;zinc;chloride Chemical compound [NH4+].[Cl-].[Zn] XEPNJJFNSJKTSO-UHFFFAOYSA-N 0.000 description 1
- 238000011021 bench scale process Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009675 coating thickness measurement Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000399 optical microscopy Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/06—Zinc or cadmium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C18/00—Alloys based on zinc
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coating With Molten Metal (AREA)
- Electroplating Methods And Accessories (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
Alliage et procédé qui permettent de galvaniser des aciers contenant du silicium par une technique de galvanisation par immersion. L'alliage est un alliage de zinc de pureté commerciale renfermant, en poids, de l'aluminium en une quantité égale à au moins 0,001 % environ, de l'étain en une quantité comprise entre 0,5 et 2 % environ, et soit du vanadium en une quantité égale à au moins 0,02 %, de préférence comprise entre 0,05 et 0,12 %, soit du titane en une quantité égale à au moins 0,03 %, de préférence comprise entre 0,06 et 0,1 %, soit du vanadium avec du titane en une quantité égale à au moins 0,02 % de vanadium et au moins 0,01 % de titane pour au moins 0,03 %, de préférence 0,05 à 0,15 % de vanadium et de titane ensemble, le solde de zinc contenant jusqu'à 1,3 % en poids de plomb. Cet alliage peut améliorer les bains d'alliage zinc-nickel dont la plage d'utilisation normale est comprise entre 0,05 et 0,08 % de nickel jusqu'à un maximum de 0,1 % de nickel. Un mode de réalisation de la composition d'alliage pour bains d'alliage zinc-nickel peut renfermer du vanadium avec du nickel en une quantité d'au moins 0,02 % de vanadium et d'au moins 0,02 % de nickel jusqu'à un maximum de 0,15 % de vanadium et de nickel ensemble. On peut ajouter du titane en une quantité d'au moins 0,01 % de titane jusqu'à un maximum de 0,2 % de vanadium, de nickel et de titane. Un autre mode de réalisation de la composition d'alliage destinée à un bain d'alliage de zinc est constitué d'aluminium en une quantité égale à au moins 0,001 %, d'étain en une quantité comprise entre 0,5 et 2 % environ, de vanadium en une quantité comprise entre 0,02 et 0,12 %, de bismuth en une quantité comprise entre 0,05 et 0,5 %, de préférence comprise entre 0,05 et 0,2 %, et du solde de zinc. Ce procédé convient pour galvaniser une vaste gamme d'aciers, y compris les aciers réactifs. Le taux maximum contrôlé de silicium varie entre 0,5 et 1 % en fonction de la combinaison et des quantités d'étain, de vanadium et de titane dans l'alliage.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US87016497A | 1997-06-06 | 1997-06-06 | |
| US08/870,164 | 1997-06-06 | ||
| PCT/CA1998/000506 WO1998055664A1 (fr) | 1997-06-06 | 1998-05-22 | Galvanisation des aciers reactifs |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2293495A1 CA2293495A1 (fr) | 1998-12-10 |
| CA2293495C true CA2293495C (fr) | 2006-01-03 |
Family
ID=25354894
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002293495A Expired - Lifetime CA2293495C (fr) | 1997-06-06 | 1998-05-22 | Galvanisation des aciers reactifs |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0996763B1 (fr) |
| AT (1) | ATE263850T1 (fr) |
| AU (1) | AU730209B2 (fr) |
| CA (1) | CA2293495C (fr) |
| DE (1) | DE69823032T2 (fr) |
| ES (1) | ES2217555T3 (fr) |
| WO (1) | WO1998055664A1 (fr) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0852264A1 (fr) * | 1997-01-02 | 1998-07-08 | Industrial Galvanizadora S.A. | Alliages de zinc donnant des revêtements anticorrosifs sur matériaux ferreux |
| WO1998053109A1 (fr) * | 1997-05-23 | 1998-11-26 | N.V. Union Miniere S.A. | Alliage et procede de galvanisation d'acier |
| US6569268B1 (en) * | 2000-10-16 | 2003-05-27 | Teck Cominco Metals Ltd. | Process and alloy for decorative galvanizing of steel |
| FR2894255B1 (fr) * | 2005-12-01 | 2008-04-04 | Electro Rech Sarl | Bain de galvanisation a chaud de pieces en une nuance d'acier quelconque |
| DE102010031439A1 (de) * | 2010-07-16 | 2012-01-19 | Aktiebolaget Skf | Wälzlager und Verfahren zur Beschichtung eines Bauteils eines Wälzlagers |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2366376A1 (fr) * | 1976-10-01 | 1978-04-28 | Dreulle Noel | Alliage destine a la galvanisation au trempe d'aciers, y compris aciers contenant du silicium, et procede de galvanisation adapte a cet alliage |
| JP2918434B2 (ja) * | 1993-11-30 | 1999-07-12 | 富士電気化学株式会社 | 電池の負極亜鉛缶 |
-
1998
- 1998-05-22 ES ES98922555T patent/ES2217555T3/es not_active Expired - Lifetime
- 1998-05-22 EP EP98922555A patent/EP0996763B1/fr not_active Expired - Lifetime
- 1998-05-22 AU AU75171/98A patent/AU730209B2/en not_active Ceased
- 1998-05-22 AT AT98922555T patent/ATE263850T1/de not_active IP Right Cessation
- 1998-05-22 CA CA002293495A patent/CA2293495C/fr not_active Expired - Lifetime
- 1998-05-22 DE DE69823032T patent/DE69823032T2/de not_active Expired - Fee Related
- 1998-05-22 WO PCT/CA1998/000506 patent/WO1998055664A1/fr active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| AU730209B2 (en) | 2001-03-01 |
| DE69823032D1 (de) | 2004-05-13 |
| EP0996763B1 (fr) | 2004-04-07 |
| ATE263850T1 (de) | 2004-04-15 |
| WO1998055664A1 (fr) | 1998-12-10 |
| AU7517198A (en) | 1998-12-21 |
| EP0996763A1 (fr) | 2000-05-03 |
| ES2217555T3 (es) | 2004-11-01 |
| CA2293495A1 (fr) | 1998-12-10 |
| DE69823032T2 (de) | 2005-04-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKEX | Expiry |
Effective date: 20180522 |