CA2126718A1 - Process for the production of mixed oxide powders for catalysts for the removal of nitrogen oxides - Google Patents
Process for the production of mixed oxide powders for catalysts for the removal of nitrogen oxidesInfo
- Publication number
- CA2126718A1 CA2126718A1 CA002126718A CA2126718A CA2126718A1 CA 2126718 A1 CA2126718 A1 CA 2126718A1 CA 002126718 A CA002126718 A CA 002126718A CA 2126718 A CA2126718 A CA 2126718A CA 2126718 A1 CA2126718 A1 CA 2126718A1
- Authority
- CA
- Canada
- Prior art keywords
- process according
- filter cake
- removal
- nitrogen oxides
- production
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims abstract description 40
- 230000008569 process Effects 0.000 title claims abstract description 40
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 239000003054 catalyst Substances 0.000 title claims abstract description 20
- 239000000843 powder Substances 0.000 title claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 41
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000725 suspension Substances 0.000 claims abstract description 15
- 239000012065 filter cake Substances 0.000 claims abstract description 11
- 238000001354 calcination Methods 0.000 claims abstract description 8
- 239000000470 constituent Substances 0.000 claims abstract description 8
- 239000007787 solid Substances 0.000 claims abstract description 7
- IYVLHQRADFNKAU-UHFFFAOYSA-N oxygen(2-);titanium(4+);hydrate Chemical compound O.[O-2].[O-2].[Ti+4] IYVLHQRADFNKAU-UHFFFAOYSA-N 0.000 claims abstract description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims abstract description 5
- 150000003839 salts Chemical class 0.000 claims abstract description 5
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 5
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 5
- 238000005406 washing Methods 0.000 claims abstract description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 4
- 239000001117 sulphuric acid Substances 0.000 claims abstract description 4
- 235000011149 sulphuric acid Nutrition 0.000 claims abstract description 4
- 229910052751 metal Inorganic materials 0.000 claims abstract description 3
- 239000002184 metal Substances 0.000 claims abstract description 3
- 150000002739 metals Chemical class 0.000 claims abstract description 3
- 238000001914 filtration Methods 0.000 claims abstract 4
- 230000003472 neutralizing effect Effects 0.000 claims abstract 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 12
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 10
- 239000000047 product Substances 0.000 claims description 4
- 150000003863 ammonium salts Chemical class 0.000 claims description 3
- 239000003546 flue gas Substances 0.000 claims description 2
- 238000001694 spray drying Methods 0.000 claims 2
- 230000003197 catalytic effect Effects 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 12
- 239000000243 solution Substances 0.000 description 10
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- -1 forl example clays Substances 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- 239000003518 caustics Substances 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 150000003608 titanium Chemical class 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 241000264877 Hippospongia communis Species 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000003113 alkalizing effect Effects 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- XAYGUHUYDMLJJV-UHFFFAOYSA-Z decaazanium;dioxido(dioxo)tungsten;hydron;trioxotungsten Chemical compound [H+].[H+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O XAYGUHUYDMLJJV-UHFFFAOYSA-Z 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000003311 flocculating effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical class [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8628—Processes characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4321555.6 | 1993-06-29 | ||
DE4321555A DE4321555C1 (de) | 1993-06-29 | 1993-06-29 | Verfahren zur Herstellung von Mischoxidpulvern für Entstickungskatalysatoren |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2126718A1 true CA2126718A1 (en) | 1994-12-30 |
Family
ID=6491479
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002126718A Abandoned CA2126718A1 (en) | 1993-06-29 | 1994-06-24 | Process for the production of mixed oxide powders for catalysts for the removal of nitrogen oxides |
Country Status (8)
Country | Link |
---|---|
US (1) | US5723404A (es) |
EP (1) | EP0640386B1 (es) |
JP (1) | JP3694537B2 (es) |
CA (1) | CA2126718A1 (es) |
DE (2) | DE4321555C1 (es) |
ES (1) | ES2094012T3 (es) |
FI (1) | FI115507B (es) |
NO (1) | NO302339B1 (es) |
Families Citing this family (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0762925B1 (de) * | 1994-05-30 | 1999-08-11 | Siemens Aktiengesellschaft | Katalysator zur stickoxidminderung in einem strömungsmedium und verfahren zu seiner herstellung |
DK0768110T3 (da) * | 1995-10-09 | 2002-05-27 | Shell Int Research | Katalysator og fremgangsmåde til omdannelse af nitrogenoxidforbindelser |
DE19721440A1 (de) * | 1997-05-21 | 1998-11-26 | Degussa | Verfahren zur Reinigung eines mageren Abgases und Katalysatorsystem hierfür |
DE19806266C1 (de) * | 1998-02-16 | 1999-08-26 | Siemens Ag | Katalysator und Verfahren zur Abgasreinigung |
KR20010043862A (ko) * | 1998-05-29 | 2001-05-25 | 칼 하인쯔 호르닝어 | 디젤 엔진 배기 가스 정화 방법 |
DE19840404A1 (de) | 1998-09-04 | 2000-03-09 | Siemens Ag | Verfahren zur katalytischen Entfernung von polyzyklischen aromatischen Nitro-, Nitroso- und/oder Amino-Verbindungen |
US7070746B1 (en) | 1999-05-26 | 2006-07-04 | Solutia Inc. | Process for nitrous oxide purification |
JP4167039B2 (ja) * | 2002-04-10 | 2008-10-15 | 三菱重工業株式会社 | ガスタービン単独プラントの改造方法、触媒の再利用方法 |
JP2004275852A (ja) * | 2003-03-14 | 2004-10-07 | Mitsubishi Heavy Ind Ltd | 排煙脱硝触媒及びその製造方法 |
KR100549778B1 (ko) * | 2003-09-27 | 2006-02-08 | 한국전력기술 주식회사 | 저온 탈질 특성을 갖는 바나듐/티타니아계 질소산화물제거용 촉매, 이의 사용방법 및 이의 탈질방법 |
US7491676B2 (en) * | 2004-10-19 | 2009-02-17 | Millennium Inorganic Chemicals | High activity titania supported metal oxide DeNOx catalysts |
KR100641694B1 (ko) * | 2005-01-28 | 2006-11-03 | 주식회사 나노 | 탈질촉매 압출성형용 티타니아 제조방법 |
CA2676953A1 (en) * | 2007-01-30 | 2008-08-07 | Babcock-Hitachi Kabushiki Kaisha | Exhaust gas purification catalyst and method of producing the same |
CN101371970B (zh) * | 2008-09-15 | 2011-07-13 | 江苏科行环境工程技术有限公司 | 一种适用于含有碱金属氧化物烟气脱硝的催化剂及其制备方法 |
JP2011005475A (ja) * | 2009-05-29 | 2011-01-13 | Sumitomo Chemical Co Ltd | 光触媒体分散液およびそれを用いた光触媒機能製品 |
US8545796B2 (en) * | 2009-07-31 | 2013-10-01 | Cristal Usa Inc. | Silica-stabilized ultrafine anatase titania, vanadia catalysts, and methods of production thereof |
CN101658793B (zh) * | 2009-09-29 | 2011-10-05 | 浙江三龙催化剂有限公司 | 用于火电厂烟气scr脱硝中的钛基催化剂及其制备方法 |
JP2011189262A (ja) * | 2010-03-15 | 2011-09-29 | Babcock Hitachi Kk | 二酸化炭素回収装置からの排ガスの処理方法及び装置 |
EP2444150A1 (de) | 2010-10-22 | 2012-04-25 | crenox GmbH | Trägerkatalysator aus Aufschlussrückständen der titanylsulfathaltigen Schwarzlösung |
EP2522418A1 (de) | 2011-05-11 | 2012-11-14 | Sachtleben Pigment GmbH | Rohstoffe für vanadiumfreie oder vanadiumreduzierte DeNOx-Katalysatoren und Verfahren zu ihrer Herstellung |
WO2013013704A1 (en) | 2011-07-25 | 2013-01-31 | Toyota Motor Europe Nv/Sa | Cost-effective core-shell catalyst with high electrochemical stability |
FI3721994T3 (fi) | 2012-08-24 | 2023-03-30 | Tronox Llc | Katalyyttituki, joka käsittää titaniaa, molybdenaa, fosforia ja piidioksidia |
GB201300810D0 (en) | 2013-01-16 | 2013-02-27 | Llika Technologies Ltd | Composite Materials |
GB2509916A (en) | 2013-01-16 | 2014-07-23 | Ilika Technologies Ltd | A mixed metal oxide material of tantalum and titanium |
GB2517394A (en) | 2013-01-16 | 2015-02-25 | Ilika Technologies Ltd | Composite materials |
TWI651269B (zh) * | 2013-09-23 | 2019-02-21 | 歐洲泰奧色得有限公司 | 二氧化鈦粒子及其製備方法 |
CN104226372B (zh) * | 2014-10-08 | 2017-01-11 | 镇江市亚东高压电器厂 | 一种平板式脱硝催化剂及其制备方法 |
EP3482825A1 (de) * | 2017-11-14 | 2019-05-15 | Umicore Ag & Co. Kg | Scr-katalysator |
CN108212180B (zh) * | 2018-03-20 | 2021-03-02 | 攀枝花市正源科技有限责任公司 | 一种中低温scr脱硝用钛钼复合粉及其制备方法 |
CN111468103B (zh) * | 2019-01-23 | 2021-07-20 | 中国科学院过程工程研究所 | 一种废弃scr脱硝催化剂回收制备新scr脱硝催化剂的方法 |
CN112408470A (zh) * | 2020-10-30 | 2021-02-26 | 甘肃盈华环保科技有限公司 | 基于高温煅烧法以废脱硝催化剂生产钛白粉的方法 |
CN112221485A (zh) * | 2020-11-13 | 2021-01-15 | 重庆新华化工有限公司 | 一种降低烧损的Ti-Mo或Ti-Mo-V催化剂钛白粉的制备方法 |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3898321A (en) * | 1973-02-28 | 1975-08-05 | American Cyanamid Co | Preparation of macroporous, heat-stable titania having high pore volume |
US4085193A (en) * | 1973-12-12 | 1978-04-18 | Mitsubishi Petrochemical Co. Ltd. | Catalytic process for reducing nitrogen oxides to nitrogen |
FR2327814A1 (fr) * | 1975-10-15 | 1977-05-13 | Hitachi Ltd | Procede pour traiter par catalyse un gaz d'echappement renfermant de l'ammoniac gazeux et de l'oxygene gazeux. |
EP0159959B1 (en) * | 1984-04-05 | 1992-01-15 | Mitsubishi Jukogyo Kabushiki Kaisha | Method for recovering denitrating catalyst for ammonia catalytic reduction |
DE3439217A1 (de) * | 1984-10-26 | 1986-04-30 | Kronos Titan-Gmbh, 5090 Leverkusen | Verfahren zur faellung von titandioxidhydrat aus einer titansulfatloesung durch thermische hydrolyse |
JPH064126B2 (ja) * | 1985-06-10 | 1994-01-19 | 株式会社日本触媒 | 排ガス浄化方法 |
JPS61291026A (ja) * | 1985-06-17 | 1986-12-20 | Hitachi Ltd | 窒素酸化物と一酸化炭素とを同時に除去する方法 |
NZ215457A (en) * | 1985-06-27 | 1988-07-28 | Mobil Oil Corp | Catalytically activating crystalline aluminium phosphate by contacting with steam |
DE3684739D1 (de) * | 1985-08-19 | 1992-05-14 | Mitsubishi Heavy Ind Ltd | Verfahren zur aufbereitung eines katalysators zur entfernung von stickstoffoxiden. |
DE3779209D1 (de) * | 1986-07-25 | 1992-06-25 | Mitsubishi Petrochemical Co | Katalysatoren und ihr gebrauch zur entfernung von stickoxiden in abgasen. |
FI873445L (fi) * | 1986-09-30 | 1988-03-31 | Kraftwerk Union Ag | Katalysatorbaerare. |
JPH0817939B2 (ja) * | 1986-11-19 | 1996-02-28 | 三菱化学株式会社 | 排煙脱硝触媒 |
JPS63291628A (ja) * | 1987-05-22 | 1988-11-29 | Babcock Hitachi Kk | 窒素酸化物除去方法 |
DE3740289A1 (de) * | 1987-11-27 | 1989-06-08 | Degussa | Katalysator zur selektiven reduktion von stickoxiden mit ammoniak |
US4929586A (en) * | 1988-06-09 | 1990-05-29 | W. R. Grace & Co.-Conn. | Catalysts for selective catalytic reduction DeNOx technology |
DE3821480A1 (de) * | 1988-06-25 | 1989-12-28 | Basf Ag | Verfahren zur entfernung von stickoxiden aus verbrennungsabgasen |
DE3840195A1 (de) * | 1988-11-29 | 1990-05-31 | Bayer Ag | Titandioxid, verfahren zu seiner herstellung und dessen verwendung |
US5198403A (en) * | 1989-02-28 | 1993-03-30 | Degussa Ag | Process for producing a catalyst for selective reduction of nitrous oxides with ammonia |
JP2879738B2 (ja) * | 1989-03-28 | 1999-04-05 | 触媒化成工業株式会社 | 排ガスの浄化方法およびそれに使用する触媒成型体 |
EP0614692A1 (en) * | 1990-05-03 | 1994-09-14 | Sakai Chemical Industry Co., Ltd., | Catalysts and methods for denitrization |
DE4025587A1 (de) * | 1990-08-11 | 1992-02-13 | Basf Ag | Verfahren zur herstellung von katalysatoren |
FR2677012B1 (fr) * | 1991-05-31 | 1993-09-03 | Rhone Poulenc Chimie | Dioxyde de titane sous forme de plaquettes et son procede de preparation. |
DE4141936C2 (de) * | 1991-12-19 | 1993-10-28 | Metallgesellschaft Ag | Verfahren zur Herstellung von aus TiO¶2¶ bestehenden Pellets |
-
1993
- 1993-06-29 DE DE4321555A patent/DE4321555C1/de not_active Expired - Fee Related
-
1994
- 1994-06-16 EP EP94109282A patent/EP0640386B1/de not_active Expired - Lifetime
- 1994-06-16 DE DE59400939T patent/DE59400939D1/de not_active Expired - Fee Related
- 1994-06-16 ES ES94109282T patent/ES2094012T3/es not_active Expired - Lifetime
- 1994-06-23 JP JP16333094A patent/JP3694537B2/ja not_active Expired - Fee Related
- 1994-06-24 CA CA002126718A patent/CA2126718A1/en not_active Abandoned
- 1994-06-27 FI FI943080A patent/FI115507B/fi active IP Right Grant
- 1994-06-28 NO NO942444A patent/NO302339B1/no unknown
-
1996
- 1996-05-16 US US08/649,924 patent/US5723404A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE4321555C1 (de) | 1994-09-15 |
ES2094012T3 (es) | 1997-01-01 |
EP0640386A1 (de) | 1995-03-01 |
JP3694537B2 (ja) | 2005-09-14 |
FI943080A0 (fi) | 1994-06-27 |
FI115507B (fi) | 2005-05-31 |
DE59400939D1 (de) | 1996-12-05 |
FI943080L (fi) | 1994-12-30 |
NO942444D0 (no) | 1994-06-28 |
US5723404A (en) | 1998-03-03 |
NO302339B1 (no) | 1998-02-23 |
JPH0796185A (ja) | 1995-04-11 |
NO942444L (no) | 1994-12-30 |
EP0640386B1 (de) | 1996-10-30 |
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EEER | Examination request | ||
FZDE | Discontinued |