CA1211624A - Treatment of aqueous systems - Google Patents
Treatment of aqueous systemsInfo
- Publication number
- CA1211624A CA1211624A CA000425925A CA425925A CA1211624A CA 1211624 A CA1211624 A CA 1211624A CA 000425925 A CA000425925 A CA 000425925A CA 425925 A CA425925 A CA 425925A CA 1211624 A CA1211624 A CA 1211624A
- Authority
- CA
- Canada
- Prior art keywords
- phosphonate
- nitrite
- water soluble
- weight percent
- ppm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims abstract description 28
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims abstract description 27
- 238000000034 method Methods 0.000 claims abstract description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 14
- 238000005260 corrosion Methods 0.000 claims abstract description 14
- 230000007797 corrosion Effects 0.000 claims abstract description 14
- 239000002253 acid Substances 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims description 19
- 229910052739 hydrogen Inorganic materials 0.000 claims description 17
- 239000001257 hydrogen Substances 0.000 claims description 17
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 13
- 229920000620 organic polymer Polymers 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 150000002431 hydrogen Chemical group 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 5
- 239000012964 benzotriazole Substances 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical group CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 235000010288 sodium nitrite Nutrition 0.000 claims description 4
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 claims description 3
- FVELLNXPMFCHQJ-UHFFFAOYSA-N 2-phosphono-2-(2-phosphonoethyl)butanedioic acid Chemical compound OC(=O)CC(P(O)(O)=O)(C(O)=O)CCP(O)(O)=O FVELLNXPMFCHQJ-UHFFFAOYSA-N 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- 229920000388 Polyphosphate Polymers 0.000 claims description 3
- 125000003342 alkenyl group Chemical group 0.000 claims description 3
- 125000000304 alkynyl group Chemical group 0.000 claims description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 3
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 3
- 229920005610 lignin Polymers 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 239000001205 polyphosphate Substances 0.000 claims description 3
- 235000011176 polyphosphates Nutrition 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- 150000002391 heterocyclic compounds Chemical class 0.000 claims description 2
- 229910052816 inorganic phosphate Inorganic materials 0.000 claims description 2
- 239000004584 polyacrylic acid Substances 0.000 claims description 2
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 2
- 229920003169 water-soluble polymer Polymers 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphonic acid group Chemical group P(O)(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 abstract description 8
- 125000002843 carboxylic acid group Chemical group 0.000 abstract description 3
- 230000002401 inhibitory effect Effects 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 description 12
- 239000000463 material Substances 0.000 description 9
- 239000000654 additive Substances 0.000 description 4
- -1 alkali metal nitrites Chemical class 0.000 description 4
- 230000005764 inhibitory process Effects 0.000 description 4
- 150000002826 nitrites Chemical class 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000272161 Charadriiformes Species 0.000 description 1
- 241000543381 Cliftonia monophylla Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical group OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- RAFRTSDUWORDLA-UHFFFAOYSA-N phenyl 3-chloropropanoate Chemical compound ClCCC(=O)OC1=CC=CC=C1 RAFRTSDUWORDLA-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB08211321A GB2118159B (en) | 1982-04-20 | 1982-04-20 | The treatment of aqueous systems |
GB8211321 | 1982-04-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1211624A true CA1211624A (en) | 1986-09-23 |
Family
ID=10529783
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA000425925A Expired CA1211624A (en) | 1982-04-20 | 1983-04-15 | Treatment of aqueous systems |
Country Status (10)
Country | Link |
---|---|
JP (1) | JPS58189380A (de) |
CA (1) | CA1211624A (de) |
DE (1) | DE3314008A1 (de) |
ES (1) | ES8406391A1 (de) |
FR (1) | FR2525241B1 (de) |
GB (1) | GB2118159B (de) |
IT (1) | IT1164190B (de) |
MY (1) | MY8600404A (de) |
PH (1) | PH19173A (de) |
SE (1) | SE8302161L (de) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2168359B (en) * | 1984-11-08 | 1988-05-05 | Grace W R & Co | A method of inhibiting corrosion in aqueous systems |
GB2184109A (en) * | 1985-10-29 | 1987-06-17 | Grace W R & Co | The treatment of aqueous systems |
CA1332138C (en) * | 1985-10-29 | 1994-09-27 | Brian Greaves | Treatment of aqueous systems |
GB9027921D0 (en) * | 1990-12-21 | 1991-02-13 | D D D Limited | Descaling composition |
DE4331910C2 (de) * | 1993-09-20 | 1997-05-28 | Aisan Ind | Hubkolben-Strömungsmittelpumpe |
AU2205900A (en) * | 1998-12-29 | 2000-07-31 | Calgon Corporation | Corrosion inhibitor compositions and methods to control metal corrosion in brinesystems |
US9994755B2 (en) | 2012-09-07 | 2018-06-12 | Prestone Products Corporation | Heat transfer fluids and corrosion inhibitor formulations for use thereof |
US8617416B1 (en) * | 2012-09-07 | 2013-12-31 | Prestone Products Corporation | Heat transfer fluids and corrosion inhibitor formulations for use thereof |
JP2017088993A (ja) * | 2015-11-17 | 2017-05-25 | 三浦工業株式会社 | 防食用水処理剤及び防食方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1392044A (en) * | 1971-06-26 | 1975-04-23 | Ciba Geigy Ag | Corrosion inhibiting composition |
DE2225645A1 (de) * | 1972-05-26 | 1974-01-17 | Bayer Ag | Verfahren zur verhinderung von korrosion und steinansatz in wasserfuehrenden systemen |
US4052160A (en) * | 1975-07-23 | 1977-10-04 | Ciba-Geigy Corporation | Corrosion inhibitors |
GB2084128B (en) * | 1980-09-25 | 1983-11-16 | Dearborn Chemicals Ltd | Inhibiting corrosion in aqueous systems |
-
1982
- 1982-04-20 GB GB08211321A patent/GB2118159B/en not_active Expired
-
1983
- 1983-04-15 CA CA000425925A patent/CA1211624A/en not_active Expired
- 1983-04-18 SE SE8302161A patent/SE8302161L/ not_active Application Discontinuation
- 1983-04-18 PH PH28786A patent/PH19173A/en unknown
- 1983-04-18 DE DE19833314008 patent/DE3314008A1/de not_active Withdrawn
- 1983-04-19 FR FR8306370A patent/FR2525241B1/fr not_active Expired
- 1983-04-19 JP JP58067919A patent/JPS58189380A/ja active Pending
- 1983-04-19 IT IT20678/83A patent/IT1164190B/it active
- 1983-04-19 ES ES521607A patent/ES8406391A1/es not_active Expired
-
1986
- 1986-12-30 MY MY404/86A patent/MY8600404A/xx unknown
Also Published As
Publication number | Publication date |
---|---|
FR2525241A1 (fr) | 1983-10-21 |
SE8302161L (sv) | 1983-10-21 |
IT8320678A0 (it) | 1983-04-19 |
IT1164190B (it) | 1987-04-08 |
MY8600404A (en) | 1986-12-31 |
DE3314008A1 (de) | 1983-10-20 |
FR2525241B1 (fr) | 1987-05-07 |
GB2118159B (en) | 1985-09-04 |
SE8302161D0 (sv) | 1983-04-18 |
ES521607A0 (es) | 1984-07-01 |
GB2118159A (en) | 1983-10-26 |
PH19173A (en) | 1986-01-16 |
ES8406391A1 (es) | 1984-07-01 |
JPS58189380A (ja) | 1983-11-05 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MKEX | Expiry |