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BR9915708A - Processo para preparação de monoariloxi-metalocenos, metaloceno, e, uso do composto de metal de transição - Google Patents

Processo para preparação de monoariloxi-metalocenos, metaloceno, e, uso do composto de metal de transição

Info

Publication number
BR9915708A
BR9915708A BR9915708-0A BR9915708A BR9915708A BR 9915708 A BR9915708 A BR 9915708A BR 9915708 A BR9915708 A BR 9915708A BR 9915708 A BR9915708 A BR 9915708A
Authority
BR
Brazil
Prior art keywords
transition metal
metal compound
monoaryloxy
metallocenes
preparation
Prior art date
Application number
BR9915708-0A
Other languages
English (en)
Other versions
BR9915708B1 (pt
Inventor
Carsten Bingel
Hans-Herbert Brintzinger
Hans-Robert-Hellmuth Damrau
Original Assignee
Basell Polyolefine Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE1999112576 external-priority patent/DE19912576A1/de
Application filed by Basell Polyolefine Gmbh filed Critical Basell Polyolefine Gmbh
Publication of BR9915708A publication Critical patent/BR9915708A/pt
Publication of BR9915708B1 publication Critical patent/BR9915708B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

"PROCESSO PARA PREPARAçãO DE MONOARILOXI-METALOCENOS, METALOCENO, E, USO DO COMPOSTO DE METAL DE TRANSIçãO" A invenção refere-se ao processo para produção de mono-ariloxi metalocenos de fórmula (II), <MU>caracterizado<MV> em que o composto ligando de partida de fórmula (III) é reagido com o composto de metal de transição de fórmula (I). Nestas fórmulas os símbolos têm os significados dados nas reivindicações. A realização especial da invenção refere-se à produção estereosseletiva de mono-ariloxi metalocenos usando o composto de metal de transição de fórmula (Ia).
BRPI9915708-0A 1998-11-25 1999-11-18 processo para preparação de monoariloxi-metalocenos. BR9915708B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19854350 1998-11-25
DE1999112576 DE19912576A1 (de) 1999-03-19 1999-03-19 Verfahren zur Herstellung von Monoaryloxy-Ansa-Metallocenen
PCT/EP1999/008854 WO2000031091A1 (de) 1998-11-25 1999-11-18 Verfahren zur herstellung von monoaryloxy-ansa-metallocenen

Publications (2)

Publication Number Publication Date
BR9915708A true BR9915708A (pt) 2001-08-14
BR9915708B1 BR9915708B1 (pt) 2010-07-13

Family

ID=26050368

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9915708-0A BR9915708B1 (pt) 1998-11-25 1999-11-18 processo para preparação de monoariloxi-metalocenos.

Country Status (7)

Country Link
US (1) US6620953B1 (pt)
EP (1) EP1133504B1 (pt)
JP (1) JP2002530416A (pt)
BR (1) BR9915708B1 (pt)
DE (1) DE59904565D1 (pt)
ES (1) ES2192408T3 (pt)
WO (1) WO2000031091A1 (pt)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU1272100A (en) * 1998-11-25 2000-06-13 Targor Gmbh Metallocene monohalogenides
US6900343B1 (en) 1998-11-25 2005-05-31 Basell Polyolefine Gmbh Method for the purification of metallocenes
EP1254075B1 (en) 2000-01-21 2007-02-21 U.S. Borax Inc. Nonaborate compositions and their preparation
US7122498B2 (en) * 2000-06-30 2006-10-17 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US6376412B1 (en) * 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380122B1 (en) * 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376410B1 (en) * 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376413B1 (en) * 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
DE10200422A1 (de) * 2002-01-08 2003-07-17 Basell Polyolefine Gmbh Verfahren zur Herstellung von Dialkyl-ansa-Metallocenen
DE10250025A1 (de) * 2002-10-25 2004-05-06 Basell Polyolefine Gmbh Verfahren zur Darstellung teilweise hydrierter rac-ansa-Metallocen-Komplexe
EP1554297B1 (en) * 2002-10-25 2006-07-12 Basell Polyolefine GmbH Racemoselective synthesis of rac-diorganosilylbis(2-methylbenzo¬e|indeyl) zirconium componds
US7446072B2 (en) * 2002-12-16 2008-11-04 Basell Polyolefine Gmbh Preparation of supported catalyst systems containing reduced amounts of aluminoxanes
ATE399056T1 (de) * 2002-12-20 2008-07-15 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe
DE10360060A1 (de) * 2003-12-19 2005-07-21 Basell Polyolefine Gmbh Verfahren zur meso-selektiven Synthese von anso-Metallocen
DE102004020524A1 (de) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
DE102004022861A1 (de) * 2004-05-06 2005-12-01 Basell Polyolefine Gmbh Verfahren zur racemo-selectiven Herstellung von ansa-Metallocenen
DE102006001959A1 (de) 2006-01-13 2007-07-19 Basell Polyolefine Gmbh Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen
EP2114567B1 (en) 2007-03-06 2015-04-15 Basell Polyolefine GmbH Iron complexes and their use in polymerization processes
DE102007017903A1 (de) * 2007-04-13 2008-10-16 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung
US20100093953A1 (en) * 2007-05-04 2010-04-15 Basell Polyolefine Gmbh Polyethylene, process and catalyst composition for the preparation thereof
JP2010534749A (ja) * 2007-07-27 2010-11-11 バーゼル・ポリオレフィン・ゲーエムベーハー オレフィンモノマー類の重合用触媒系、ポリマー類の製造法及び当該方法により製造したポリマー類
US20100249346A1 (en) * 2007-10-19 2010-09-30 Basell Polyolefine Gmbh Metallocene compounds based on ethanediyl-bridged indene and cyclopentadithiophene ligands
US8207281B2 (en) * 2007-12-18 2012-06-26 Basell Polyolefine Gmbh Process for preparing transition metal compounds for olefins polymerization
US8247587B2 (en) 2007-12-19 2012-08-21 Basell Polyolefine Gmbh Mono-hydroindacenyl complexes
US20100234548A1 (en) * 2007-12-21 2010-09-16 Basell Polyolefine Gmbh Phenanthroline-comprising complexes
US8435911B2 (en) * 2008-10-16 2013-05-07 Basell Polyolefine Gmbh Hybrid catalyst composition for polymerization of olefins
JP5837514B2 (ja) * 2010-02-19 2015-12-24 ダウ グローバル テクノロジーズ エルエルシー 金属−配位子錯体及び触媒
US9376518B2 (en) 2013-08-28 2016-06-28 Exxonmobil Chemical Patents Inc. Racemo selective metallation process
EP3039026A4 (en) * 2013-08-28 2016-08-24 Exxonmobil Chem Patents Inc RACEMIC SELECTIVITY METALLIZATION METHOD

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JP3371118B2 (ja) 1991-11-30 2003-01-27 バーゼル・ポリオレフィン・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング 配位子としてベンゼン融合したインデニル誘導体を持つメタロセン、その製造方法および触媒としてのその用途
US5830821A (en) 1991-11-30 1998-11-03 Targor Gmbh Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands
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Also Published As

Publication number Publication date
ES2192408T3 (es) 2003-10-01
WO2000031091A1 (de) 2000-06-02
JP2002530416A (ja) 2002-09-17
EP1133504B1 (de) 2003-03-12
EP1133504A1 (de) 2001-09-19
BR9915708B1 (pt) 2010-07-13
DE59904565D1 (de) 2003-04-17
US6620953B1 (en) 2003-09-16

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Legal Events

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B06A Notification to applicant to reply to the report for non-patentability or inadequacy of the application [chapter 6.1 patent gazette]
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