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BR112012019183A8 - PROCESS FOR MANUFACTURING AN EPOXIDE, AND DEVICE FOR CARRYING OUT THE PROCESS - Google Patents

PROCESS FOR MANUFACTURING AN EPOXIDE, AND DEVICE FOR CARRYING OUT THE PROCESS

Info

Publication number
BR112012019183A8
BR112012019183A8 BR112012019183A BR112012019183A BR112012019183A8 BR 112012019183 A8 BR112012019183 A8 BR 112012019183A8 BR 112012019183 A BR112012019183 A BR 112012019183A BR 112012019183 A BR112012019183 A BR 112012019183A BR 112012019183 A8 BR112012019183 A8 BR 112012019183A8
Authority
BR
Brazil
Prior art keywords
epoxide
reaction mixture
carrying
terminal olefin
oxidant
Prior art date
Application number
BR112012019183A
Other languages
Portuguese (pt)
Other versions
BR112012019183A2 (en
Inventor
Van Den Berg Bart
Stock Juergen
Rausch Hans
Schallenberg Jörg
Bernhardt Stefan
Muppa Prasad
Postma Ron
Wiederhold Holger
Original Assignee
Momentive Specialty Chem Inc
Hexion Inc
Evonik Degussa Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Momentive Specialty Chem Inc, Hexion Inc, Evonik Degussa Gmbh filed Critical Momentive Specialty Chem Inc
Publication of BR112012019183A2 publication Critical patent/BR112012019183A2/en
Publication of BR112012019183A8 publication Critical patent/BR112012019183A8/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/14—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic peracids, or salts, anhydrides or esters thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
    • B01D17/02—Separation of non-miscible liquids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
    • B01D17/02—Separation of non-miscible liquids
    • B01D17/0208—Separation of non-miscible liquids by sedimentation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40—Static mixers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B01J19/2435—Loop-type reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00—Feed or outlet devices; Feed or outlet control devices
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40—Static mixers
    • B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B01F25/43—Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
    • B01F25/431—Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0213—Complexes without C-metal linkages
    • B01J2531/0216—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/96—Water
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PROCESSO PARA FORMAR UM PRODUTO EPÓXIDO, E, DISPOSITIVO PARA REALIZAR O PROCESSO. Aparelho e processos são providos para formar compostos de epóxido. Em uma forma de realização, um processo para a fabricação de um epóxido é provido incluindo a adição de um oxidante, um complexo de manganês solúvel em água e uma olefina terminal para formar uma mistura de reação de múltiplas fases, reagindo a olefina terminal com o oxidante na mistura de reação de múltiplas fases tendo pelo menos uma fase orgânica na presença do complexo de manganês solúvel em água, separando a mistura de reação em uma pelo menos fase orgânica e uma fase aquosa, e reutilização de pelo menos parte da fase aquosa. A invenção está também relacionada com um dispositivo para realizar o processo acima.PROCESS FOR FORMING AN EPOXID PRODUCT, AND DEVICE FOR PERFORMING THE PROCESS. Apparatus and processes are provided for forming epoxide compounds. In one embodiment, a process for making an epoxide is provided including adding an oxidant, a water-soluble manganese complex and a terminal olefin to form a multiphase reaction mixture, the terminal olefin reacting with the terminal olefin. oxidant in the multiphase reaction mixture having at least one organic phase in the presence of the water-soluble manganese complex, separating the reaction mixture into at least an organic phase and an aqueous phase, and reusing at least part of the aqueous phase. The invention also relates to a device for carrying out the above process.

BR112012019183A 2010-02-02 2011-01-26 PROCESS FOR MANUFACTURING AN EPOXIDE, AND DEVICE FOR CARRYING OUT THE PROCESS BR112012019183A8 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP10001035A EP2354131A1 (en) 2010-02-02 2010-02-02 Process for the manufacture of a 1,2-epoxide and a device for carrying out said process
PCT/EP2011/000320 WO2011107188A2 (en) 2010-02-02 2011-01-26 Process for the manufacture of a 1,2-epoxide and a device for carrying out said process

Publications (2)

Publication Number Publication Date
BR112012019183A2 BR112012019183A2 (en) 2018-02-06
BR112012019183A8 true BR112012019183A8 (en) 2018-04-03

Family

ID=42062455

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112012019183A BR112012019183A8 (en) 2010-02-02 2011-01-26 PROCESS FOR MANUFACTURING AN EPOXIDE, AND DEVICE FOR CARRYING OUT THE PROCESS

Country Status (16)

Country Link
US (2) US8859790B2 (en)
EP (3) EP2354131A1 (en)
JP (2) JP6000856B2 (en)
KR (3) KR101475579B1 (en)
CN (2) CN105566250B (en)
AR (1) AR080113A1 (en)
AU (2) AU2011223288B2 (en)
BR (1) BR112012019183A8 (en)
ES (1) ES2653794T3 (en)
HU (1) HUE035587T2 (en)
MY (1) MY162533A (en)
PT (1) PT2947076T (en)
RU (1) RU2540864C2 (en)
SA (1) SA111320159B1 (en)
TW (2) TWI457329B (en)
WO (1) WO2011107188A2 (en)

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Also Published As

Publication number Publication date
ES2653794T3 (en) 2018-02-08
US20140171666A1 (en) 2014-06-19
WO2011107188A3 (en) 2012-02-02
RU2540864C2 (en) 2015-02-10
EP2947076B1 (en) 2017-11-01
MY162533A (en) 2017-06-15
TWI519526B (en) 2016-02-01
US8859790B2 (en) 2014-10-14
RU2012137285A (en) 2014-03-10
BR112012019183A2 (en) 2018-02-06
JP6125479B2 (en) 2017-05-10
KR20120130105A (en) 2012-11-28
CN105566250B (en) 2019-02-22
EP2539329A2 (en) 2013-01-02
SA111320159B1 (en) 2015-04-26
US9102640B2 (en) 2015-08-11
JP6000856B2 (en) 2016-10-05
CN105566250A (en) 2016-05-11
JP2015061841A (en) 2015-04-02
CN102844310A (en) 2012-12-26
KR20140141668A (en) 2014-12-10
AR080113A1 (en) 2012-03-14
AU2011223288A1 (en) 2012-08-23
TWI457329B (en) 2014-10-21
PT2947076T (en) 2018-01-04
KR101622504B1 (en) 2016-05-31
EP2947076A1 (en) 2015-11-25
JP2013518835A (en) 2013-05-23
TW201441209A (en) 2014-11-01
WO2011107188A2 (en) 2011-09-09
AU2014204452A1 (en) 2014-07-31
HUE035587T2 (en) 2018-05-28
US20130023680A1 (en) 2013-01-24
KR101475579B1 (en) 2014-12-22
KR20140056381A (en) 2014-05-09
AU2011223288B2 (en) 2014-05-01
TW201139393A (en) 2011-11-16
EP2354131A1 (en) 2011-08-10
AU2014204452B2 (en) 2016-03-03
CN102844310B (en) 2016-01-13

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