BR0311438A - Composição catalisadora sólida, heterogênea, em partìculas - Google Patents
Composição catalisadora sólida, heterogênea, em partìculasInfo
- Publication number
- BR0311438A BR0311438A BR0311438-4A BR0311438A BR0311438A BR 0311438 A BR0311438 A BR 0311438A BR 0311438 A BR0311438 A BR 0311438A BR 0311438 A BR0311438 A BR 0311438A
- Authority
- BR
- Brazil
- Prior art keywords
- solid
- catalyst composition
- heterogeneous
- group
- particulate catalyst
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 5
- 239000007787 solid Substances 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 2
- 239000003085 diluting agent Substances 0.000 abstract 2
- 229910052749 magnesium Inorganic materials 0.000 abstract 2
- 239000011777 magnesium Substances 0.000 abstract 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- 230000002411 adverse Effects 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 239000002638 heterogeneous catalyst Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 238000001694 spray drying Methods 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
"COMPOSIçãO CATALISADORA SóLIDA, HETEROGêNEA, EM PARTìCULAS". A presente invenção refere-se a uma composição catalisadora, secada por atomização, heterogênea, em partículas, sólida, para a polimerização de monómeros polimerizáveis de adição compreendendo a) um composto de metaloceno de Grupo 4; b) um complexo sólido de metal de Grupo 4 - haleto de magnésio compreendendo porções de pelo menos magnésio, um metal de transição de Grupo 4, e um haleto; c) carga inerte, finamente dividida, e d) um aglutinante opcional capaz de ligar componentes a) e b) e/ou c) em um aglomerado heterogêneo, em partículas, sem adversamente afetar as propriedades catalíticas deste; e um método para a fabricação desta compreendendo formar uma mistura da composição acima em um diluente líquido e secar por atomização a mesma para remover diluente.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US38579602P | 2002-06-03 | 2002-06-03 | |
PCT/US2003/016266 WO2003102037A1 (en) | 2002-06-03 | 2003-05-22 | Solid, particulated, spray dried, heterogenous catalyst composition |
Publications (1)
Publication Number | Publication Date |
---|---|
BR0311438A true BR0311438A (pt) | 2005-03-22 |
Family
ID=29712212
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR0311438-4A BR0311438A (pt) | 2002-06-03 | 2003-05-22 | Composição catalisadora sólida, heterogênea, em partìculas |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP1509552A1 (pt) |
JP (1) | JP2005526175A (pt) |
CN (1) | CN1284805C (pt) |
AU (1) | AU2003233649B2 (pt) |
BR (1) | BR0311438A (pt) |
CA (1) | CA2482640A1 (pt) |
WO (1) | WO2003102037A1 (pt) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2478299T3 (es) | 2003-11-20 | 2014-07-21 | Union Carbide Chemicals & Plastics Technology Llc | Composiciones de catalizador Ziegler de metal mixto, secadas por pulverización |
US20050182210A1 (en) * | 2004-02-17 | 2005-08-18 | Natarajan Muruganandam | De-foaming spray dried catalyst slurries |
US7973112B2 (en) | 2004-02-17 | 2011-07-05 | Univation Technologies, Llc | De-foaming spray dried catalyst slurries |
CN102492062B (zh) * | 2011-11-11 | 2014-03-26 | 上海立得催化剂有限公司 | 一种自成型乙烯聚合催化剂颗粒的制备方法 |
US8653208B2 (en) * | 2012-05-18 | 2014-02-18 | Union Carbide Chemicals & Plastics Technology Llc | Process for preparing catalysts and catalysts made thereby |
CN110452318A (zh) * | 2013-01-14 | 2019-11-15 | 尤尼威蒂恩技术有限责任公司 | 制备高产率催化剂系统的方法 |
WO2018063900A1 (en) * | 2016-09-29 | 2018-04-05 | Dow Global Technologies Llc | Method of polymerizing an olefin |
EP3559058A1 (en) * | 2016-12-22 | 2019-10-30 | ExxonMobil Chemical Patents Inc. | Spray-dried olefin polymerization catalyst compositions and polymerization processes for using the same |
US11485802B2 (en) | 2018-03-26 | 2022-11-01 | Dow Global Technologies Llc | Spray-dried zirconocene catalyst system |
WO2022260896A1 (en) * | 2021-06-10 | 2022-12-15 | Dow Global Technologies Llc | Catalyst compositions that have modified activity and processes to make them |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5290745A (en) * | 1992-08-10 | 1994-03-01 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing ethylene polymers having reduced hexane extractable content |
US5648310A (en) * | 1993-12-23 | 1997-07-15 | Union Carbide Chemicals & Plastics Technology Corporation | Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture |
ATE166887T1 (de) * | 1994-02-17 | 1998-06-15 | Union Carbide Chem Plastic | Sprühgetrocknete füllstoffe enthaltende metallocenkatalysatorzusammensetzung zur herstellung von polyolefinen |
ATE194993T1 (de) * | 1994-04-07 | 2000-08-15 | Bp Chem Int Ltd | Polymerisationsverfahren |
US5622906A (en) * | 1994-09-16 | 1997-04-22 | Phillips Petroleum Company | Compositions useful for olefin polymerization and processes therefor and therewith |
JP2000513402A (ja) * | 1996-06-21 | 2000-10-10 | ダブリュー・アール・グレース・アンド・カンパニー―コーン | 凝集担体およびそれに保持されたオレフィン重合触媒 |
US6313061B1 (en) * | 1998-12-22 | 2001-11-06 | W. R. Grace & Co.-Conn. | Method of making frangible spray dried agglomerated supports and olefin polymerization catalysts supported thereon |
JP2004512166A (ja) * | 2000-10-24 | 2004-04-22 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング | 触媒担体、それらの製造とオレフィン重合における使用 |
US6689847B2 (en) * | 2000-12-04 | 2004-02-10 | Univation Technologies, Llc | Polymerization process |
JP2005511802A (ja) * | 2001-11-30 | 2005-04-28 | エクソンモービル・ケミカル・パテンツ・インク | チーグラー・ナッタ/メタロセン混合触媒の製造方法 |
-
2003
- 2003-05-22 BR BR0311438-4A patent/BR0311438A/pt not_active IP Right Cessation
- 2003-05-22 AU AU2003233649A patent/AU2003233649B2/en not_active Ceased
- 2003-05-22 EP EP03729088A patent/EP1509552A1/en not_active Withdrawn
- 2003-05-22 JP JP2004509725A patent/JP2005526175A/ja active Pending
- 2003-05-22 WO PCT/US2003/016266 patent/WO2003102037A1/en active Application Filing
- 2003-05-22 CN CN 03811156 patent/CN1284805C/zh not_active Expired - Fee Related
- 2003-05-22 CA CA002482640A patent/CA2482640A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
EP1509552A1 (en) | 2005-03-02 |
CN1284805C (zh) | 2006-11-15 |
AU2003233649B2 (en) | 2006-04-13 |
CA2482640A1 (en) | 2003-12-11 |
CN1653093A (zh) | 2005-08-10 |
AU2003233649A1 (en) | 2003-12-19 |
WO2003102037A1 (en) | 2003-12-11 |
JP2005526175A (ja) | 2005-09-02 |
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Legal Events
Date | Code | Title | Description |
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B08F | Application fees: dismissal - article 86 of industrial property law |
Free format text: REFERENTE A 5A,6A E 7A ANUIDADES |
|
B08K | Lapse as no evidence of payment of the annual fee has been furnished to inpi (acc. art. 87) |
Free format text: REFERENTE AO DESPACHO PUBLICADO NA RPI 2064 DE 27/07/2010. |