AU721755B2 - Absorbent material including coir fibres and/or coir dust - Google Patents

Description

1 ABSORBENT MATERIAL INCLUDING COIR FIBRES AND/OR COIR DUST Field of the Invention This invention relates to absorbent materials.

Background of the Invention The use of coir dusts as an absorber of spills of various types has been known for some time, although not widely used. In United States Patent No.

3,703,464, the use of coir dust or coconut short fibres is described as a satisfactory absorbent material for oil spills on water and on other surfaces. The widespread use of this material as a spill absorbent has been restricted to situations where exposure to high levels of heat or fire are not present since coir dust is capable of burning and is therefore regarded as a potential fire hazard.

Summary of Invention and Object It is the object of the present invention to provide an improved absorbent material which can be used in situations involving high levels of heat or fire.

15 The invention therefore provides An absorbent material including coir fibres and/or coir dust, a fire retardant material in the form of small particles, the particle size of the fire retardant material being smaller than the particle size of the coir fibres and/or dust to ensure that the fire retardant material substantially penetrates or substantially coats at least a substantial proportion of the coir fibres and/or dust 20 present in the absorbent material.

Preferably, the fire retardant is in the form of a powder, the particle size of which is smaller than the particle size of the coir fibres and/or coir dust to ensure that the fire retardant material substantially penetrates the coir fibres present in the absorbent material.

The fire retardant may include a suitable phosphate material, such ammonium polyphosphate. In its most preferred form, the fire retardant material comprises superphosphate. The inventors have found that superphosphate functions adequately as a fire retardant and that the above defined combination of coir fibres and/or coir dust and superphosphate in the form of a powder results in an absorbent material which is essentially self-extinguishing in the presence of high levels of heat s or fire.

:YJ:40389735 (#30262).RS I I 1 May 2000 WO 98/07804 PCT/AU97/00535 2 It has been found that superphosphate in fine powder form, similar to talcum powder, and preferably having a particle size less than 10 micron, and preferably less than 5 micron, and most preferably of the order of one micron performs satisfactorily in that it adequately penetrates the coconut fibres present in the absorbent material to provide a self-extinguishing property in these fibres.

In a preferred form, the absorbent material includes from about 4 to at least about 8 grams of powdered superphosphate to 115 grams or 1 litre of dry coir dust, together with sufficient water or other suitable liquid to ensure intimate mixing.

In another aspect, the invention provides a method of producing an absorbent material including intimately mixing coir fibres and/or coir dust with an effective quantity of a fire retardant material in the form of small particles, and adding an effective quantity of a liquid such as water to promote intimate mixing of the coir fibres and the fire retardant material whereby the fire retardant penetrates or coats the coir fibres, the particle size of the fire retardant material being selected to ensure that the fire retardant penetrates or coats the coir fibres in the absorbent material.

Preferably, the fire retardant is in the form of a powder, the particle size of which is smaller than the particle size of the coir fibres and/or coir dust to ensure that the fire retardant material substantially penetrates the coir fibres present in the absorbent material.

In a preferred form of the method, powdered superphosphate is used as the fire retardant. It has been found that satisfactory results are achieved by the following mixtures: from about 4 grams to at least about 8 grams of powdered superphosphate to 115 grams or 1 litre of dry coir dust and approximately water intimately mixed together to ensure penetration of the powdered superphosphate into the coir fibres.

An inspection of the absorbent material according to the above combination shows evidence of small crystals of superphosphate embedded in the walls of the coir fibre nodules. These crystals are believed to contain water of crystallisation which is released when the absorbent material is heated thereby producing the desired self-extinguishing properties.

WO 98/07804 PCT/AU97/00535 3 Description of Preferred Embodiment Coir dust in the form of compressed bricks 200mm x 100mm x 50mm are reconstituted as coir dust and then intimately mixed with superphosphate and water in the ratio about 115 grams or 1 litre of dry coir dust to about 8 grams superphosphate to about 65mL of water. To ensure proper reconstitution of the bricks and intimate mixing of the resultant coir dust, the coir dust bricks are placed in a rotating hammer mill and a fine mist of water is sprayed onto the bricks as they are converted to the constituent coir dust by the hammer mill. At the same time, superphosphate in the form of a fine powder having a particle size of the order of 1 micron is added to the mill.

A typical analysis of the absorbent product described above is as follows: Nitrogen as Protein 0.52% Phosphorus as Phosphate 0.57% Potassium 0.19% Calcium (Ca) 1.2% Sulphur as Sulphate 0.72% pH of water extract 5.6 As mentioned above, a microscopic inspection of the coir fibre nodules contained in the coir dust shows evidence of small crystals of superphosphate embedded in the walls of the nodules. These crystals are believed to contain water of crystallisation which is released when the absorbent material is heated thereby aiding in fire retardation.

Acceptable results are achieved using as little as about 4 grams of powdered superphosphate to 115 grams or 1 litre of dry coir dust and about 65mL of water.

Better results are achieved using 6 grams of powdered superphosphate and best results are achieved using 8 grams of superphosphate. The use of more than 8 grams of superphosphate does not seem to improve performance to any material extent.

The absorbent material is relatively inert and of low toxicity and is biodegradable. Where the product is used to absorb oil spills, the absorbed oil may WO 98/07804 PCT/AU97/0035 bum if exposed to sufficient heat or flame, but this burning can be controlled by spreading further absorbent product over the fire.

Claims (22)

1. An absorbent material including coir fibres and/or coir dust, a fire retardant material in the form of small particles, the particle size of the fire retardant material being smaller than the particle size of the coir fibres and/or dust to ensure that the fire retardant material substantially penetrates or substantially coats at least a substantial proportion of the coir fibres and/or dust present in the absorbent material.

2. The absorbent material of claim 1, wherein the fire retardant is in the form of a powder, the particle size of which is smaller than the particle size of the coir fibres and/or coir dust to ensure that the fire retardant material substantially penetrates the coir fibres present in the absorbent material.

3. The absorbent material of claim 2, wherein the powder is of a particle size °oo similar to talcum powder.

4. The absorbent material of claim 3, wherein the powder has a particle size of S 15 the order of less than 10 micron.

The absorbent material of claim 4, wherein the powder has a particle size of the order of less than 5 micron.

6. The absorbent material of claim 5, wherein the powder has a particle size of 2 the order of less than 1 micron to enable adequate penetration of the coconut fibres in the absorbent material.

7. The absorbent material of any one of claim 1 to 6, wherein the fire retardant includes a phosphate material.

8. The absorbent material of claim 7, wherein the phosphate material is an ammonium polyphosphate.

9. The absorbent material of claim 8, wherein the phosphate material is superphosphate.

The absorbent material of any preceding claim, including from about 4 to at least about 8 grams of powdered superphosphate to about 115 grams or 1 litre of dry coir dust, together with sufficient water or other suitable liquid to ensure intimate mixing.

11. A method of producing an absorbent material including intimately mixing LTNB:YJ:40389735 (#30262).RS I I1 May 2000 coir fibres and/or coir dust with an effective quantity of a firre retardant material in the form of small particles, and adding an effective quantity f a liquid such as water to promote intimate mixing of the coir fibres and the fire retardant material whereby the fire retardant penetrates or coats the coir fibres, the particle size of the fire retardant material being smaller than the particle size of the coir fibres and/or dust to ensure that the fire retardant penetrates or coats the coir fibres and/or dust in the absorbent material.

12. The method of claim 11, wherein the fire retardant is in the form of a powder, the particle size of which is smaller than the particle size of the coir fibres and/or coir dust to ensure that the fire retardant material substantially penetrates the coir fibres present in the absorbent material.

13. The method of claim 12, wherein the superphosphate is in powder form similar to talcum powder.

14. The method of claim 13, wherein the powder has a particle size of the order S: 15 of less than 10 micron.

The method of claim 14, wherein the powder has a particle size of the order of less than 5 micron. r

16. The method of claim 15, wherein the powder has a particle size of the order of less than 1 micron. 20

17. The method of any one of claim 11 to 16, wherein the fire retardant includes ooe° a phosphate material.

18. The method of claim 17, wherein the phosphate material is an ammonium polyphosphate.

19,. The method of claim 18, wherein the phosphate material is superphosphate.

20. The method of any one of claims 11 to 20, including from about 4 to at least about 8 grams of powdered superphosphate to 115 grams or 1 litre of dry coir dust, together with sufficient water or other suitable liquid to ensure intimate mixing.

21. An absorbent material substantially as hereinbefore described. 'J:40389735 (#30262).RS I I I May 2000

22. The method of any one of claims 11 to 20 substantially as hereinbefore described. DATED: 11I May 2000 FREEHILLS CARTER SMITH BEADLE Patent Attorneys for -the Applicant: COIR PEAT AUST PTY LTD S S S i S 99 9 S S S. S 9 5555 S. 9 S. *S '1:40389735 (#30262).RS IIIMy20 I I May 2000