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AU660473B2 - Attracting and ingestion-stimulating agent for cockroach - Google Patents

Attracting and ingestion-stimulating agent for cockroach Download PDF

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Publication number
AU660473B2
AU660473B2 AU20004/92A AU2000492A AU660473B2 AU 660473 B2 AU660473 B2 AU 660473B2 AU 20004/92 A AU20004/92 A AU 20004/92A AU 2000492 A AU2000492 A AU 2000492A AU 660473 B2 AU660473 B2 AU 660473B2
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ingestion
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tetrahydro
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AU2000492A (en
Inventor
Masami Nemoto
Kazumasa Ogino
Haruo Shimamura
Kazuyuki Tomisawa
Fumio Urushizaki
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Taisho Pharmaceutical Co Ltd
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Taisho Pharmaceutical Co Ltd
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/04—Nitrogen directly attached to aliphatic or cycloaliphatic carbon atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/002—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits
    • A01N25/006—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits insecticidal
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/06—Nitrogen directly attached to an aromatic ring system

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Dentistry (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Insects & Arthropods (AREA)
  • Food Science & Technology (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Description

OPT. DATE 02/03/93 APPLN. ID 20004/92fllllftlll111I1111Nlll AOJP DATE 13/05/93 PCT NUMBER PCT/JP92/00795 AU9220004 INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (51) International Patent Clasairication 5 AO1N 33/06, 31/08, 25/00 (Il) International Publication Number: Al (43) International Publication Date: WO 93/02554 18 February 1993 (18,02.93) (21) International Application Number: (22) International Filing Date: Priority data: 3/200822 9 August PCT/JP92/00795 22 June 1992 (22,06.92) 1991 (09.08.91) (74) Agent: KITAGA WA, Tomizo; Taisho Pharmaceutical Co., Ltd,, 24-1, Takata 3-chome, Toshima-ku, Tokyo 171 (3 P).
(81) Designated States: AU, BR, CA, KR, US, European patent (AT, BE, CH, DE, DK, ES, FR, GB, OR, IT, LU, MC, NL, SE).
Published Prith international search report.
660473 (71) Applicant (for all designated States except US): TAISHO PHARMACEUTICAL CO., LTD. [JP/JPI; 24-1, Takata 3-chome, Toshima-ku, Tokyo 171 (JP).
(72) Inventors; and Inventors/Applicants (for US only) OGINO, Kazumasa [JP/JPI; 2-2-304, Haraichi-danchi, 3336, Oaza-Haraichi, Ageo-shi, Saitama 362 ti0), SHIMAMURA, Haruo [JP/ JPI;, 1-5-15, Sakuragaoka, Yono-shi, Saitarna 338 (JP).
TOMISAWA, Kazuyuki [JP/JP]; 4-191-3, Sakae, Inamachi, Kita-adachi-gun, Saitama 362 URUSHIZA- KI, Fumio [JP/JP]; A1110, Sofia-ageo, 2-1-1, Yatsu, Ageo-shi, Saitama 362 NEMOTO, Masami fJP/JP];, 12 14-75, Sakata, Okegawa-shi, Saitama 363 (JP).
(54) Title: ATT'RACTING AND INGESTION-STIMULATING AGENT FOR COCKROACH (57) Abstract There are provided attracting and ingestion-stimulating agents for cockroach comprising as the active ingredient. one or more compounds selected from the group of I-amino-5,6,7,8-tetrahydronaphthalene, 2-amino-5,6,7,8-tetrahydronaphthalene, 2.aminomethyl-5,6,7,8-tetrahydronaphthalene and a salt thereof; and one or more compounds selected from the group of p-nbutylphenol, p-n-amylphtnol, 5,6,7,8-tetrahydro- I-naphthol and 5,6,7,8-tetrahydro-2- naphthol. The attracting and ingestion-stimulating agents for cockroach exhibit the very potent attracting and ingestion-stimulating activities in the known species of house cockroach, both male and female.
DESCRIPTION
Attracting and ingestion-stimulating agent for cockroach -TECHNICAL FIELD The present invention relates to attracting and ingestion-stimulating agents for cockroaches.
BACKGROUND ART Cockroach is one of the sanitarily harmful insects most widely known throughout the world.
In Japan, as the house cockroach are known Periplaneta fuliginosa P.japFnica P.americana Blattella .germanic etc.
In general, it is important for extermination of cockroach to possess both an attracting activity and an ingestion-stimulating activity.
We have already provided several cockroach attracting and ingestion-stimulating agents which stimulataneously possess the activities both (USP 4,627,981; USP 4,911,907).
Tetralol, naphthol and phenol compounds and 3,7-dimethyl-lOisopropyl-2,6-cyclodecadien-l-ol, which are active ingredients of these cockroach attracting and ingestion-stimulating agents, are sufficiently active without any additives. However, they are often active against male P.americana L. only, and thus when T, applied to colonies of other species of cockroach or A -2 colonies of female cockroach only, they sometimes produce lower effects.
DISCLOSURE OF INVENTION In order to provide more effectively attracting and £ingestion- stimulating agrents for cockroach than the prior art agents., we have investigated a composition comprising.
(a)one or more compounds selected from the group of I-amino-5,6,7,8-tetrahydronapbthalene, 2-amino-5,6,7,8tetrahydronaphthalene, 2-aminomethyl-S,6,7,8-tetrahydronaphthalene and a salt thereof and (b)one or more compounds selected from the group of p-n-butylphenol, p-n-amylphenol, 5,6,7,8-tetrabydro-Inaphthol and 5,6,7,8-tett-ahydro-2-naphthol show a hight attractant and ingestion-stimulating activity fur cockroach.
iSA more prefer-red agent for cockroach of the invention is concerned with an attracting and ingestion-stimulating agent for cockroach comprising as active ingredients a compound selected from the group consisting of 1-amino--5,6,7,8tetrahydronaphthalene, 2-amino-5,6,7 ,8-tetrahydronaphthalene, 2-aminomethyl-56,78-tetrahydronaphthalene and a salt thereof, and a compound selected from the group consisting of p-n-amylphenol, p-n-butylphenol, E5,6,7,8-tetrahydro-1naphthol and 5,6,7,8-tetrahydro-2-naphthol.
-3 All of the c~.mpound are known compounds.
I-Amino-5,6,7,8-tetrahydronaphthalene, 2-amino-5,6,7,8tetrahydronaphthalene and 2-aminomethyl-5,6 8-tetr-ahydronaphthalene are disclosed, for example, in the literature .cited below.
Misra et al, J,Indian Chem. Soc. 1959, 36, 803 S.W. Fenton et al., 32.'m.Chem. Soc., 1955, 77, 979 V. Grinsteins et al. Lav. RSR Zinat. Akad. Vestis, Kim. Ser. 1967, 7, 128 As the salt of the compounds, th2re can be mentioned, for example, hydrochloric acid salt, oxalic acid salt, citric acid salt, acetic acid salt, phosphoric acid salt, malonic acid salt, sulfric acid salt, tartaric acid salt, maleic acid salt, lactic acid salt and pyrophosphoric acid salt.
2-mtinomethyl-5,6,7,8-tetrahydronaphtbalene is allowed to stand in air to give a salt.
The salt compound has a chemical structure as shown below; U H2NH3(D C H2NHCO2e However, none of 1-amino-5,6, 7.,8-tetrahydronaphthalene 2.o 2-amino-5,6,7,8-tetrahydronanhthalene and 2-aminomethyl- 4 5,6,7,8-tetrahydronaphthalene are known for their cockroach attracting and ingestion-stimulating activities. p-n-Amylphenol, p-n-butylphenol, 5,6,7,8-tetrahydro-1-naphthol and 5,6,7,8-tetrahydro-2-naphthol are known for their cockroach attracting and ingestion-stimulating activities as described in USP 4,911,907 and USP 4,627,981, Attracting and ingestion-stimulating agents for cockroach according to the invention can be prepared, for example, by dissolving these compounds in an appropriate solvent (for example, a hydrophilic organic solvent such as acetone, methanol, ethanol, tetrahydrofuran, ethylene glycol, diethylene glycol or N,N-dimethyl- formamide or lipophilic organic solvent such as benzene, chloroform, ether, methylene chloride or n-hexane) then impregnating an appropriate carrier (for paper, cardboad, non-woven cloth, or flannel) with the solution and drying off the solvent to give attracting tapes or the like. The active-ingredient compounds according to the invention can also be used in such a form as granule, pill or tablet prepared by a conventional method using binder, excioient, lubricant, stabilizer and others as usually employed to give a bait.
The bait form of the active-ingredient compounds according to the invention can be formulated together with an insecticidal ingredient. As the typical examples of the insecticidal ingredient, there can be mentioned, organophosphorous insecticides such as 0,0O-dimethyl 0-4-nitrom-tolyl. phosphorothicate (fenitrothion), 0, 0-diethyl 2,3dihydro-3--oxo-2-phenylpyridazin-6-yl )phosphorothioate (pyridafenthion), 0-3,5, 6-trichloro-2-pyridy. 0, 0-dimethyl phosphorothicate (chiorpyrifos-methyl), pyrethroids such as (RS )-3-allyl-2-methyl-4-oxocylopent-2-enyI. (IRS) cis, trans- 2, 2-dimethyl-3- (2-methylprop-1-enyl) cyclopropanecarboxylate (allethrin), (S)-a-cyano-3-phenoxy-benzyl (1R,3R)-3-(2,2dibromovinyl)-2,2-dimethylcyclopropane-carboxylate (deltamethrin), 3-phenoxybenzyl (1RS)cis, trans-2, 2-dimethyl-3- (2-methylprop-l-enyl) cyclopropanecarboxyl ate (phenothrin), benzyl-3-furylmethyl-(1RS)cis, trans-2,2--dimethyl-3-(2methyprop-1-enyl )cyclopropane-carboxylate (resmethrin), acyano-3-phenoxybenzyl(lRS,3SR)-(lRS,3RS)-2,2-dimethyl-3-(2methylprop-1-enyl) cyclopropanecarboxylate (cyphenothrin), 3phenoxybenzyl (IRS) cis, trans-3-(2,2-dichlorovinyl)-2,2dimethyl-cyclopropanecarboxylate (permethrin), 4ethoxyphenyl )-2-methylpropyl 3-phenoxybenzyl ether (ethofenprox), (RS) -a-cyano-3-phenoxybenzyl (RS )-a-isopropyl-4chiorophenyl acetate (fenvalerate), (RS 2-methyl- 4 -oxo-3 -prop- 2-ynylcyclopent-2-enyl(lRS,3SR)-(1RS,3SR)-2,2-dimethyl-3-(2methylpro-1-enyl) cyciopropanecarboxylate (prallethrin), carbamates such as 1-naphtyl methylcarbamate, 2isopropoxypheny. methylcarbamate, dodecadienote oxime-ether benzoylphenyl urea, insect growth regulator compounds such as dodecadienoate compounds, oxime-ether compounds, pyriyl compounds, benzoylphenyl compounds urea and other insecticides such as tetrahydro-5, 5-dimethyl-2( 1H)- 13M11:LN14954SPS ~h19 I Mamb 1995 5a pyrimidinone-[3-(4-triflyuoromethyl)phenyl]-1-[2-[4-(trifluoromethyl)phenyl]ethyl]-2-propenylidene hydrazone, boric acid etc.
If desired, the cockroach bait may contain ote or more conventional adjuvants. Examples of conventional adjuvants include pulverized grain, biscuit powder, sweetening, water, sugar, maltose excipient, excipients, stabirizer, surfactant, plant oil, dextrin and microcristallin cellulose.
The active ingredient according to the invention show an attracting and ingestion-stimulating activity in a very small amount so that no particular care should be taken for amount to be used.
It is preferable, for example, that a bait would contain the ingredient in a concentration of 0.01 by weight or more of whole amount.
The attracting and ingestion-stimulating action of the agents according to the iavention will be described below in i L ~l .)T1 17=1: C Uf= F7 WVO 93/02554 P~r/JP92/00795 -6-6 detail with reference to test examples.
Test example 1 (Test material) A test material was prepared by the similar method in example The test material contained 0.05% by weight of the compound in Table 1.
WO 93/02554 WO 93/2554 Cri/ P92/00795 -7- Table 1 Test material Test compound's name a 1-amino-5, 6,7, 8-tetrahydronaphthalene b 2-amino-5, 6,7, 8-tetrahydronaphthalene c 2-aminomethyl-5, 6,7, 8-tetrahydronaphthalene d p-n-amylphenol e p-n--butylphenol f 5,6, 7, 8-tetrahydro-1-naphthol g 5,6,7, 8-tetrahydro-2-naphthol h 2-aminomethyl-5, 6, 7, 8-tetrahydr-onaphthalene 5,6,7, 8-tetrahydro-2-naphthol i 1-amino-S. 6,7, 8-tetrahydronaphthalene 5,6, 7.8-tetrahydro-1-naphthol 6,7, 8-tetrahydronaphthalene p-n-axnylphenol k 2-amino-S. 6,7. 8-tetrahydronaphthalene p-n-butylphenol 1 without compound (as the control/' (Test insect) Groups of Periplaneata fuliginosa. P. japonica P.
australasiae P.americana Blattella germanic Blatta, orientalis L. each consisting of 100 adult male and female cockroaches were prepared per one test materials.
(Test methods) 8 A group of the test insects was placed individually in a cage. After three days, the bait of the test material was examined for the degree of ingestion. The degree of ingestion of test materials were compared with test material The experiment was repeated three times, and the average number of degree of ingestion was taken.
(Test results) Results are shown in Table 2.
i C i C to* I g dd ~>4 Table 2 Test material P..americana L. P.fuliginosa S. B.orientalis L. P.japonica K. P.australasiae L- B.gerinanic L.
a 1.83 1.30 1.34 1.18 1.60 1-16 b 1.95 1.44 1.48 1.25 1.80 1.18 c2.51 2.20 2.05 1.39 2.05 1.40 d 11-5 1.26 1.56 1.66 1.63 1.38 e 1.35 1l10 1.28 1.38 1.43 1.19 f 1.26 1.12 1.29 1.40 1.38 1.21 9 1.38 1.20 1.36 1.46 1.50 1.29 h 3.15 3.05 3.28 2.01 2.18 1.61 i2.38 2.29 2-56 1.87 2.03 1.42 j4.02 3.83 4,04 2.48 2.39 1.79 k 2-86 2,56 3.13 1.95 2.10 1.44 These values are expressed as compared with 1.0 o h A fcnrlsml~) t (i e, of the A 31 EA 33 r-P of control sample(l).
10 Test example 2 (Test materials) The same test procedures as in Test example 1 were employed except that two parts of hydramethylnon ,was formulated as an insecticide to give test materials (Test insects) As test insects were employed 12 groups of Periplaneata fuliginosa P,americana Blattella germanic Blatta orientalis L. consisting of 30 adult cockroaches and to larvae cockroaches per one test material.
(Test method) 48 rooms, approximately 6 mats in size, were used. One week before initiation of the test each room was stocked with a group of different species of the cockroach, which was given IS food and water.
The test material baits were set at five positions in each room.
Effect of the attractants was evaluated on the basis of the number of dead cockroach.
2j (Test results) The results are shown in Table 3.
Table 3 P. qp'ericana L. P. f u Iigi nosa S. B.orientalis L. B.germani,- L.
Test LT90 3 days after LT90 3 days af ter LT90 3 days after ILT90 3 days afteF material (day) mortality(X.) (day) mortalIi ty (day) mortality(YX) {(day) mortality(X) A 27.8 16.7 15.2 33.3 18.3 23.3 [8.2 50.0 B 24-51 20.0 12.2 46.7 16.0 30.0 7.8 56.7 C 23.7 23.3 12-4 46.7 15.8 30.0 7.3 58.3 D 26.3 20.0 14-0 35.0 17-1 28-3 7.5 55.0 E28.0 18.3 15.0 1 30.0 19.6 28-3 7.6 56.7 F 28.9 20.0 15.8 28.3 20.1 30 8.5 50.0 G 2 18.3 13.8 40.0 16-9 28.3 7.6 55,0 11 10.9 40.0 7.8 56-7 8.6 43.3 4.8 78.3 1 11-3{ 38.3 8.2 51.7 9.8 36.7 5.0 75.0 1 9.8 41.7 6.3 61.7 7.2 53.3 4.2 81.7 K 10.7 40.0 6.9 58.3 8.0 j 50.0 4.5 80.0 I.1 60( 0 24.8 13.3 43.5 j 1.6 11.2 28.3 days within which 90 mortality 12 BEST MODE FOR CARRYING OUT THE INVENTION Some examples of this invention will be explained as the following examples.
However, this invention is not limited to these examples.
Unless otherwise indicated, all parts are by weight Ex:ample 1 A mixture of 75 parts powdery fish meal, 5 parts of maltose, 5 parts of L-arabiinose, 5 parts of oleic acid, parts of rice brain oil, 0.06 part of permethrin, 0.05 part of p-n-batylphenol and 0.03 part of 2-amino-5,6,7,8-tetraiydronaphthalene was kneaded together with some water, and the mixture was formed into a small granular bait of the invention weighing about 0.7 g per granule.
Example 2 150 parts of water-soluble starch, 150 parts of potato starch, 100 parts of boric acid,0.6 part of sodium beuzoate, 0.2 part of dibutyihydroxytoluene, 0.03 part of 2-amino-5,6,7,8-tetrahydronaphthalene,, 0.1 part of 5,6,7,8tetrahydro-1-naphthol and 599,5 parts of water were blended S 2 and formed into a cockroach bait of the invention weighing about 1I g per piece.
Example 3 100 parts of wheat powders, 35 parts of water-soluble 13 starch, 35 parts of starch, one part of methoprene, 0.06 part of sodium benzoate, 0.02 part of dibutylhydroxytoluene, 0.05 part of 5,6,7,8-tetrahydro-2-naphthol and 0.03 part of 2-amino-5,6,7,8- tetrahydronaphthalene hydrocarbonate were blend.d together with an appropriate amount of water a' i formed into a cockroach bait of the invention weighing about g per piece.
Example 4 100 parts of corn syrup, 30 parts of sorbitol, 14 parts of I( gelatin, 48 parts of water, 2 parts of pyriproxyfen, 0.06 part of sodium benzoate, 0.02 part of dibutylhydroxytoluene, 0.05 part of p-n-butylphenol and 0.1 part of 2-aminomethyl-5,6,7,8tetrahydronaphthalene were blended and formed into a cockroach bait of the invention weighing about 10 g per piece.
'S Example parts of thick malt syrup, 45 parts of oats powder, 11 S parts of macrogol, 0.5 part of cyphenothrin, one part of diflubenzurone, 0.06 part of sodium benzoate, 0,02 part of dibutylhydroxytoluene, 0.05 part of p-n-amylphenol and 0.1 part of 2 2-amino-5,6,7,8-tetrahydro- naphthalene were blended and formed into a cockroach bait of the invention weighing about g per piece.
Example 6 14 parts of brown sugar, 2 parts of corn oil, 2 parts of chrysalis powder, 20 parts of biscuit powder, 50 parts. of dextrin, 0.06 part of sodium benzoate, 0.02 part of dibutylhydroxytoluene, 2 parts of hydramethylnon, 0.02 part Sof p-n-amylphenol and 0.03 part of 2-amino-.5,6,7,8-tetrahydronaphthalene were blended and formed into a cockroach bait of the invention weighing about 5 g per piece.
Example 7 parts of powdery sugar, 10 parts of corn oil, 30 parts d of sweet corn oil, 60 parts of crystalline cellulose, 2 parts of ethofenprox, 0.06 parts sodium benzoate, 0.02 part of dibutylhydroxytoluene, 0.02 part of p-n-amylphenol and 0. 03 part of 2-amino-5,6,7,8-tetrahydronaphthalene were blended and formed into a cockroach bait of the invention weighing about (S g per piece.
Example 8 15 parts of mineral oil, 2 parts of ammonium hydroxide, 2 parts of polyoxyethylene nonylphenyl ether, 0.5 part of carboxymethyl cellulose, 3.5 parts of potato starch, one part 0 of propoxur, 0.5 part of fenoxycarb, 0.06 part of sodium benozate, 0.02 part of dibutylhydroxytoluene, 0.05 part of 5,6,7,8-tetrahydro-2-naphthol and 0.03 part of 2-amino- 5,6,7,8-tetrahydronaphthalene were blended and formed into a 15 cockroach bait of the invention weighing about 5 g per piece.
Example 9 parts of white mineral oil, 1.5 parts of polyoxyethylene glycol dioleate, 2 parts of polyoxyethylene nonylphenyl ether, S one part of hydroxyethyl cellulose, 0.5 part of xanthane gum, parts of corn starch, 2 parts of chloropyrifosmethyl, 0.06 part of sodium benzoate, 0.02 part of 5,6,7,8-tetrahydro- 2-naphthol and 0.03 part of 2-amino-5,6,7,8-tetrahydronaphthalene were blended and formed into a cockroach bait of 0o the invention weighing about 5 g per piece.
INDUSTRIAL APPLICABILITY The attracting and ingestion-stimulating agents of the invention not only exhibit a potent attracting and ingestion-stimulating activity on various species of cockroach but also are highly effective in cockroach extermination even when male and female cockroaches live together.
This brings about low production cost and minimizes the size of the preparation for easiness on use.
The attracting and ingestion-stimulating component of the 74 invention can also provide each of the cockroach controlling ow: agents with fast acting effect.

Claims (4)

1. An attracting and ingestion-stimulating composition for cockroaches wherein the active ingredient comprises: one or more compounds selected from the group of 1- amino-5, 6, 7, 8-tetrahydronaphtahalene, 2-amino-5, 6, 7, 8- tetrahydronaphtahalene, 2-aminomethyl-5,6,7,8- tetrahydronaphthalene and a salt thereof; and one or more compounds selected from the group of p-n- butylphenol, p-n-amylphenol, 5, 6, 7, 8-tetrahydro-l-naphthol and 5, 6, 7, 8-tetrahydro-2-naphthol.
2. An attracting and ingestion-stimulating composition for cockroaches wherein the active ingredient comprises one compound selected from the group consisting of 6, 7, 8-tetrahydronaphthalene, l-amino-5, 6, 7, 8- tetrahydronaphthalene, 2-amino-5, 6, 7, 8-tetrahydro- naphthalene and a salt thereof, and one compound selected from the group consisting of p-n-amylphenol, p-n-butylphenol, 5, 6, 7, 8-tetrahydro-l-naphthol and 5, 6, 7, 8-tetrahydro-2- naphthol.
3. An attracting and ingestion-stimulating composition, substantially as hereinbefore described with reference to any one of more of the non-comparative examples. DATED: 1 March 1995 CARTER SMITH BEADLE Patent Attorneys for the Applicant: TAISHO PHARMACEUTICAL CO., LTD, BMI11:D;:14954SPB 1 MIMA 199S 0 0 !NTERNATIONAL.SEARCH REPORT International Application Ni. PCT/JP 92/00795 1. CLASSIFICATION OF SUBJECT MATTrER (if several classificaton symbols applyindicate all)' According to International Patent Classification (IPC) or to both National Classification and IPC ~Int.C1. 5 A01N33/06; A01N31/08; AO1N25/0O
11. FIELDS SEARCHED Minimum Documentation Searchedl Classification Systems Classification Symbols Int.Cl. 5 A01N Documentation Searched other tban Minimum Documentation to the Extent that such Documents are Included in the Fields Searcheds III. DOCUMENTS CONSIDERED TO BE RELEVANT9 Category Citation of Document, It with indication, whtere appropirate, of th-cralevant passage$ 1 2 Relevant to Claim No.3 PX WO,A,9 202 134 (TAISHO PHARMACEUTICAL) 20 1-4 February 1992 WORLD PATENTS INDEX LATEST Section Ch, Week 9210, 6 May 1992 Derwent Publications Ltd., London, GB; Class C, AN 92-079725/10 see abstract A US,A,4 911 907 (H.SHIMAMVURA ET 27 March 1-4 1990 cited in the application see column 1, line 59 column 3, line 12 see claim 1 CSpecial categories of cited documents 10 '17 later document published after the international filing date A doumet df~nig te gnerl stre f te ar whch s ~or prlort date and not in conflict with the application hut 'Vdcndefin toe geea tt fteatwihI o cited to understand the princi;ple or theory underlyfog the consdere tobe o paticuar elevnceinvention earlier document but published on or after the international 1V document of particular relevance; the claimed Invention filing date cannot be considered novel or cannot be considered tv WL document which may throw doubts on priority clm(s) or Involve an inventive step which Is cited to establish the publication date of another document of particular relwvnce; the claimed Invention citation or other special reason (as specified) cannot be considered to Involve an inventive step when the '0 document referring to an oral disclosure, use, exhbition or document Is comblnt with one or more other sudh docu. other means meota, such comnbination bWag obvious to a person skilled document published prior to the International filing date but In thwM art later than the priority date claimed document member of the same patent family IV. CERTIFICATION Date of the Actual Completion ofthe International Search Date of Mailing of this International Search Report 22 SEPTEMBER 1992 1 4.10. 92 International Searching Authority Signature of Authorized 'Q 9cer EUROPEAN PATENT OFFICE W. Lamers I Form PCTIISA/2tO tacm skd lJsuisr' 19851 PCT/JP 92/00795 International Application No III. DOCUMENTS CONSIDERED TO BE RELEVANT (CONTINUED FROM THE SECOND SHEET) Category [Citation of Document, with indication, where appropriate, of the relevant passages Relevant to Claim No. US,A,4 627 981 (K.SHIMANO ET AL.) 9 December 1986 cited In the application see column 1, line 49 column 3, line 58 see claim I Form FCTIIsA121O (etra amet) (JIMSgy IR9" ANNEX TO THE INTERNATIONAL SEARCH REPORT ON INTERNATIONAL PATENT APPLICATION NO. JP SA 9200795 60745 This annex fists the patent family members relating to the patent documents cited in the above-mentioned international search report. The members are as contained in the European Patent Office EDP file on The European Patent Office is in no way liable for these particulars which are merely given for the purpose of information. 22/09/92 Patent document I Publication Patent familyPulcto cited in search report date member(s) -7date WO-A-9202134 20-02-92 None US-A-4911907 27-03-90 JP-A- 63096101 27-04-88 AU-B- 602922 01-11-90 AU-A- 7947687 21-04-88 US-A-4627981 09-12-86 JP-A- 61069701 10-04-86 JP-A- 61072702 14-04-86 'W For m'ore details about this annex :see Official Journal of the European Patent Oice, No. 12/82
AU20004/92A 1991-08-09 1992-06-22 Attracting and ingestion-stimulating agent for cockroach Expired - Fee Related AU660473B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP3-200822 1991-08-09
JP20082291 1991-08-09
PCT/JP1992/000795 WO1993002554A1 (en) 1991-08-09 1992-06-22 Attracting and ingestion-stimulating agent for cockroach

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AU660473B2 true AU660473B2 (en) 1995-06-29

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AU (1) AU660473B2 (en)
BR (1) BR9206343A (en)
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994014323A1 (en) * 1991-07-09 1994-07-07 Taisho Pharmaceutical Co., Ltd. Attracting and ingestion-stimulating agent for cockroach
AU692053B2 (en) * 1995-01-09 1998-05-28 S.C. Johnson & Son, Inc. Liquid insect bait
AUPR709901A0 (en) * 2001-08-17 2001-09-06 Grotech Australia Pty Ltd Edible pesticidal formulations
US8404260B2 (en) 2008-04-02 2013-03-26 Bayer Cropscience Lp Synergistic pesticide compositions
WO2017079684A1 (en) * 2015-11-06 2017-05-11 Gries Gerhard J Baits for cockroaches

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4911907A (en) * 1986-10-14 1990-03-27 Taisho Pharmaceutical Co., Ltd. Cockroach attractants
WO1992002134A1 (en) * 1990-08-09 1992-02-20 Taisho Pharmaceutical Co., Ltd. Attractant and feeding stimulant for cockroach
AU3172393A (en) * 1991-07-09 1994-07-19 Taisho Pharmaceutical Co., Ltd. Attracting and ingestion-stimulating agent for cockroach

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4627981A (en) * 1984-09-14 1986-12-09 Taisho Pharmaceutical Co., Ltd. Attractant-ingestion stimulant preparations for Periplaneta americana L

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4911907A (en) * 1986-10-14 1990-03-27 Taisho Pharmaceutical Co., Ltd. Cockroach attractants
WO1992002134A1 (en) * 1990-08-09 1992-02-20 Taisho Pharmaceutical Co., Ltd. Attractant and feeding stimulant for cockroach
AU3172393A (en) * 1991-07-09 1994-07-19 Taisho Pharmaceutical Co., Ltd. Attracting and ingestion-stimulating agent for cockroach

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WO1993002554A1 (en) 1993-02-18
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EP0598122A1 (en) 1994-05-25

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