AU651436B2 - A method of preparing a pillared layered oxide material - Google Patents

A method of preparing a pillared layered oxide material Download PDF

Info

Publication number: AU651436B2
Authority: AU; Australia
Prior art keywords: pillared; swollen; layered; oxide; ray diffraction
Prior art date: 1991-01-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Ceased

Application number

AU12541/92A

Other languages

English (en)

Other versions

AU1254192A (en

Inventor

Charles Theodore Kresge

Wieslaw Jerzy Roth

Kenneth Gregory Simmons

James Clarke Vartuli

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mobil Oil AS

Original Assignee

Mobil Oil AS

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1991-01-11

Filing date

1992-01-10

Publication date

1994-07-21

1991-12-20 Priority claimed from US07/811,384 external-priority patent/US5229341A/en

1992-01-10 Application filed by Mobil Oil AS filed Critical Mobil Oil AS

1992-08-17 Publication of AU1254192A publication Critical patent/AU1254192A/en

1994-07-21 Application granted granted Critical

1994-07-21 Publication of AU651436B2 publication Critical patent/AU651436B2/en

2012-01-10 Anticipated expiration legal-status Critical

Status Ceased legal-status Critical Current

Links

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239000000203 mixture Substances 0.000 claims description 24
238000001354 calcination Methods 0.000 claims description 23
239000011541 reaction mixture Substances 0.000 claims description 18
239000010457 zeolite Substances 0.000 claims description 14
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 11
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VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 81
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229910052785 arsenic Inorganic materials 0.000 description 1
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
QXNDZONIWRINJR-UHFFFAOYSA-N azocane Chemical compound C1CCCNCCC1 QXNDZONIWRINJR-UHFFFAOYSA-N 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
239000011324 bead Substances 0.000 description 1
239000000440 bentonite Substances 0.000 description 1
229910000278 bentonite Inorganic materials 0.000 description 1
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
229910001423 beryllium ion Inorganic materials 0.000 description 1
LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 1
230000000740 bleeding effect Effects 0.000 description 1
229910001593 boehmite Inorganic materials 0.000 description 1
229910052792 caesium Inorganic materials 0.000 description 1
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
238000004364 calculation method Methods 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
238000004523 catalytic cracking Methods 0.000 description 1
238000005341 cation exchange Methods 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
230000008859 change Effects 0.000 description 1
238000001311 chemical methods and process Methods 0.000 description 1
238000007385 chemical modification Methods 0.000 description 1
239000008119 colloidal silica Substances 0.000 description 1
230000000295 complement effect Effects 0.000 description 1
239000000470 constituent Substances 0.000 description 1
239000003431 cross linking reagent Substances 0.000 description 1
VXVVUHQULXCUPF-UHFFFAOYSA-N cycloheptanamine Chemical compound NC1CCCCCC1 VXVVUHQULXCUPF-UHFFFAOYSA-N 0.000 description 1
NISGSNTVMOOSJQ-UHFFFAOYSA-N cyclopentanamine Chemical compound NC1CCCC1 NISGSNTVMOOSJQ-UHFFFAOYSA-N 0.000 description 1
238000010908 decantation Methods 0.000 description 1
238000006356 dehydrogenation reaction Methods 0.000 description 1
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
229910001649 dickite Inorganic materials 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 1
208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
208000035475 disorder Diseases 0.000 description 1
238000006073 displacement reaction Methods 0.000 description 1
VRDILKQMBBCHKM-UHFFFAOYSA-L dodecyl(trimethyl)azanium dichloride Chemical compound [Cl-].[Cl-].CCCCCCCCCCCC[N+](C)(C)C.CCCCCCCCCCCC[N+](C)(C)C VRDILKQMBBCHKM-UHFFFAOYSA-L 0.000 description 1
DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 description 1
230000009977 dual effect Effects 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
238000001493 electron microscopy Methods 0.000 description 1
230000009881 electrostatic interaction Effects 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
238000011049 filling Methods 0.000 description 1
238000009472 formulation Methods 0.000 description 1
239000003517 fume Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
239000010439 graphite Substances 0.000 description 1
229910002804 graphite Inorganic materials 0.000 description 1
229910052621 halloysite Inorganic materials 0.000 description 1
JYVHOGDBFNJNMR-UHFFFAOYSA-N hexane;hydrate Chemical compound O.CCCCCC JYVHOGDBFNJNMR-UHFFFAOYSA-N 0.000 description 1
238000003837 high-temperature calcination Methods 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
238000007654 immersion Methods 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
239000012535 impurity Substances 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
238000003780 insertion Methods 0.000 description 1
230000037431 insertion Effects 0.000 description 1
239000000138 intercalating agent Substances 0.000 description 1
238000009830 intercalation Methods 0.000 description 1
239000001282 iso-butane Substances 0.000 description 1
229910052622 kaolinite Inorganic materials 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000002648 laminated material Substances 0.000 description 1
229910052746 lanthanum Inorganic materials 0.000 description 1
FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000005259 measurement Methods 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
239000012229 microporous material Substances 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
229910052901 montmorillonite Inorganic materials 0.000 description 1
101150006061 neur gene Proteins 0.000 description 1
229910052758 niobium Inorganic materials 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
229910000510 noble metal Inorganic materials 0.000 description 1
IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
238000010525 oxidative degradation reaction Methods 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-O oxonium Chemical compound [OH3+] XLYOFNOQVPJJNP-UHFFFAOYSA-O 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
239000012071 phase Substances 0.000 description 1
239000000049 pigment Substances 0.000 description 1
150000003058 platinum compounds Chemical class 0.000 description 1
CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
239000002798 polar solvent Substances 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000000634 powder X-ray diffraction Methods 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
125000001453 quaternary ammonium group Chemical group 0.000 description 1
230000005855 radiation Effects 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000011084 recovery Methods 0.000 description 1
230000003014 reinforcing effect Effects 0.000 description 1
229910052702 rhenium Inorganic materials 0.000 description 1
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
150000003377 silicon compounds Chemical class 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
229920002379 silicone rubber Polymers 0.000 description 1
239000004945 silicone rubber Substances 0.000 description 1
239000002356 single layer Substances 0.000 description 1
150000003384 small molecules Chemical class 0.000 description 1
229910021647 smectite Inorganic materials 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
230000003068 static effect Effects 0.000 description 1
239000000758 substrate Substances 0.000 description 1
229910021653 sulphate ion Inorganic materials 0.000 description 1
238000001308 synthesis method Methods 0.000 description 1
229910052715 tantalum Inorganic materials 0.000 description 1
LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
APSPVJKFJYTCTN-UHFFFAOYSA-N tetramethylazanium;silicate Chemical compound C[N+](C)(C)C.C[N+](C)(C)C.C[N+](C)(C)C.C[N+](C)(C)C.[O-][Si]([O-])([O-])[O-] APSPVJKFJYTCTN-UHFFFAOYSA-N 0.000 description 1
229940095070 tetrapropyl orthosilicate Drugs 0.000 description 1
ZQZCOBSUOFHDEE-UHFFFAOYSA-N tetrapropyl silicate Chemical compound CCCO[Si](OCCC)(OCCC)OCCC ZQZCOBSUOFHDEE-UHFFFAOYSA-N 0.000 description 1
LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
150000003609 titanium compounds Chemical class 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
230000007704 transition Effects 0.000 description 1
125000005208 trialkylammonium group Chemical group 0.000 description 1
150000004684 trihydrates Chemical class 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
239000010937 tungsten Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1
150000003738 xylenes Chemical class 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/049—Pillared clays
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

Chemical & Material Sciences (AREA)
Dispersion Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Crystallography & Structural Chemistry (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)
Glass Compositions (AREA)
Oxygen, Ozone, And Oxides In General (AREA)

AU12541/92A 1991-01-11 1992-01-10 A method of preparing a pillared layered oxide material Ceased AU651436B2 (en)

Applications Claiming Priority (5)

Application Number	Priority Date	Filing Date	Title
US64034091A	1991-01-11	1991-01-11
US640340		1991-01-11
US811384		1991-12-20
US07/811,384 US5229341A (en)	1991-01-11	1991-12-20	Crystalline oxide material
PCT/US1992/000096 WO1992011935A1 (en)	1991-01-11	1992-01-10	A method of preparing a pillared layered oxide material

Publications (2)

Publication Number	Publication Date
AU1254192A AU1254192A (en)	1992-08-17
AU651436B2 true AU651436B2 (en)	1994-07-21

Family

ID=27093544

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AU12541/92A Ceased AU651436B2 (en)	1991-01-11	1992-01-10	A method of preparing a pillared layered oxide material

Country Status (6)

Country	Link
EP (1)	EP0548296A1 (da)
JP (1)	JPH06504979A (da)
KR (1)	KR930703069A (da)
AU (1)	AU651436B2 (da)
CA (1)	CA2098395A1 (da)
WO (1)	WO1992011935A1 (da)

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* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP1242343B1 (en) *	1999-09-20	2004-06-23	Consejo Superior De Investigaciones Cientificas	Aromatics alkylation
US7358401B2 (en) *	2005-03-31	2008-04-15	Sumitomo Chemical Company, Limited	Method for manufacturing cycloalkanol and/or cycloalkanone
JP2007223992A (ja) *	2006-02-27	2007-09-06	Sumitomo Chemical Co Ltd	シクロアルカノール及び／又はシクロアルカノンの製造方法
BRPI0714609B1 (pt) *	2006-07-28	2016-11-08	Exxonmobil Chemical Patents Inc	peneira molecular cristalina e seu processo de produção, bem como processo para conversão de hidrocarboneto
KR101044495B1 (ko) *	2006-07-28	2011-06-27	엑손모빌 케미칼 패턴츠 인코포레이티드	분자체 조성물(ｅｍｍ-10), 이의 제조 방법, 및 탄화수소 전환에 있어서의 용도
US8501068B2 (en)	2007-11-05	2013-08-06	Regents Of The University Of Minnesota	Layered zeolite materials and methods related thereto

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US4248739A (en) *	1979-09-04	1981-02-03	W. R. Grace & Co.	Stabilized pillared interlayered clays
US4859648A (en) *	1984-12-28	1989-08-22	Mobil Oil Corporation	Layered metal chalcogenides containing interspathic polymeric chalcogenides
US4954325A (en) *	1986-07-29	1990-09-04	Mobil Oil Corp.	Composition of synthetic porous crystalline material, its synthesis and use

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US4176090A (en) *	1975-11-18	1979-11-27	W. R. Grace & Co.	Pillared interlayered clay materials useful as catalysts and sorbents
FR2563446A1 (fr) *	1984-04-25	1985-10-31	Raffinage Cie Francaise	Nouvelle zeolite a structure bidimensionnelle et application de ladite zeolite
JPH04504557A (ja) *	1990-02-06	1992-08-13	モービルオイルコーポレーション	ケニヤイト型積層シリケート物質の合成

1992
- 1992-01-10 JP JP4505298A patent/JPH06504979A/ja active Pending
- 1992-01-10 AU AU12541/92A patent/AU651436B2/en not_active Ceased
- 1992-01-10 CA CA002098395A patent/CA2098395A1/en not_active Abandoned
- 1992-01-10 EP EP92904784A patent/EP0548296A1/en not_active Withdrawn
- 1992-01-10 KR KR1019930702065A patent/KR930703069A/ko active IP Right Grant
- 1992-01-10 WO PCT/US1992/000096 patent/WO1992011935A1/en not_active Application Discontinuation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4248739A (en) *	1979-09-04	1981-02-03	W. R. Grace & Co.	Stabilized pillared interlayered clays
US4859648A (en) *	1984-12-28	1989-08-22	Mobil Oil Corporation	Layered metal chalcogenides containing interspathic polymeric chalcogenides
US4954325A (en) *	1986-07-29	1990-09-04	Mobil Oil Corp.	Composition of synthetic porous crystalline material, its synthesis and use

Also Published As

Publication number	Publication date
EP0548296A1 (en)	1993-06-30
WO1992011935A1 (en)	1992-07-23
CA2098395A1 (en)	1992-07-12
JPH06504979A (ja)	1994-06-09
AU1254192A (en)	1992-08-17
EP0548296A4 (da)	1994-01-12
KR930703069A (ko)	1993-11-29

Publication	Publication Date	Title
US5250277A (en)	1993-10-05	Crystalline oxide material
CA1283647C (en)	1991-04-30	Layered silicates and their synthesis
CA2161414C (en)	2005-03-01	Synthetic layered material, mcm-56, its synthesis and use
JP3742100B2 (ja)	2006-02-01	合成多孔質結晶性ｍｃｍ−５８，その合成及び用途
US5229341A (en)	1993-07-20	Crystalline oxide material
US5827491A (en)	1998-10-27	Process for preparing the synthetic porous crystalline material MCM-56
EP2328839A2 (en)	2011-06-08	Uzm-35 aluminosilicate zeolite, method of preparation and processes using uzm-35
WO2010080242A2 (en)	2010-07-15	Uzm-27 family of crystalline aluminosilicate compositions, a method of preparing the compositions and methods of using the compositions
US5284643A (en)	1994-02-08	Gallium-containing zeolite MCM-22
EP2046684A2 (en)	2009-04-15	Uzm-22 aluminosilicate zeolite, method of preparation and processes using uzm-22
WO2010074889A2 (en)	2010-07-01	Uzm-26 family of crystalline aluminosilicate compositions, method of preparing the compositions and processes using the compositions
AU654329B2 (en)	1994-11-03	Layered oxide materials and swollen and pillared forms thereof
US5296428A (en)	1994-03-22	Catalyst comprising MCM-36 and a hydrogenation/dehydrogenation component
US5266541A (en)	1993-11-30	Crystalline oxide material
US5310715A (en)	1994-05-10	Method for preparing a pillared layered oxide material
AU651436B2 (en)	1994-07-21	A method of preparing a pillared layered oxide material
US5278116A (en)	1994-01-11	Method for preparing a pillared layered oxide material
US5278115A (en)	1994-01-11	Method for preparing a pillared layered oxide material
AU2002219833A1 (en)	2002-06-03	Crystalline molecular sieve composition MCM-65, its synthesis and use
US5364999A (en)	1994-11-15	Organic conversion with a catalyst comprising a crystalline pillared oxide material
US5256617A (en)	1993-10-26	Vacancy titanates intercalated with cationic hydroxy aluminum complexes
US5155076A (en)	1992-10-13	Vacancy titanates intercalated with cationic hydroxy aluminum complexes