ATE253027T1 - Verfahren zur alkylierung von benzol - Google Patents
Verfahren zur alkylierung von benzolInfo
- Publication number
- ATE253027T1 ATE253027T1 AT00202434T AT00202434T ATE253027T1 AT E253027 T1 ATE253027 T1 AT E253027T1 AT 00202434 T AT00202434 T AT 00202434T AT 00202434 T AT00202434 T AT 00202434T AT E253027 T1 ATE253027 T1 AT E253027T1
- Authority
- AT
- Austria
- Prior art keywords
- liquid phase
- reaction
- alkyling
- benzene
- phase conditions
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 title 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract 2
- 150000001491 aromatic compounds Chemical class 0.000 abstract 2
- 239000007791 liquid phase Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- 230000029936 alkylation Effects 0.000 abstract 1
- 238000005804 alkylation reaction Methods 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000012295 chemical reaction liquid Substances 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000012071 phase Substances 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/02—Monocyclic hydrocarbons
- C07C15/085—Isopropylbenzene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
- C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
- C07C409/08—Compounds containing six-membered aromatic rings
- C07C409/10—Cumene hydroperoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
- C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
- C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
- C07C39/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring monocyclic with no unsaturation outside the aromatic ring
- C07C39/04—Phenol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1999MI001531A IT1313008B1 (it) | 1999-07-13 | 1999-07-13 | Processo per l'alchilazione di composti aromatici. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE253027T1 true ATE253027T1 (de) | 2003-11-15 |
Family
ID=11383323
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT00202434T ATE253027T1 (de) | 1999-07-13 | 2000-07-10 | Verfahren zur alkylierung von benzol |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6512153B1 (de) |
| EP (1) | EP1069100B1 (de) |
| JP (1) | JP4837162B2 (de) |
| KR (1) | KR100500272B1 (de) |
| AT (1) | ATE253027T1 (de) |
| DE (1) | DE60006191T2 (de) |
| ES (1) | ES2208219T3 (de) |
| IT (1) | IT1313008B1 (de) |
| MX (1) | MXPA00006809A (de) |
| RU (1) | RU2234490C2 (de) |
| SG (1) | SG91293A1 (de) |
| TW (1) | TW526183B (de) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10008924A1 (de) * | 2000-02-25 | 2001-09-06 | Phenolchemie Gmbh & Co Kg | Verfahren zur Herstellung von Phenol |
| ITMI20012707A1 (it) * | 2001-12-20 | 2003-06-20 | Enichem Spa | Processo per l'alchilazione di composti aromatici |
| US6921843B2 (en) | 2001-12-21 | 2005-07-26 | Council Of Scientific And Industrial Research | Process for the preparation of diemethyl cumenes |
| ATE362904T1 (de) * | 2002-03-21 | 2007-06-15 | Council Scient Ind Res | Verfahren zur herstellung von dimethylcumolen |
| ITMI20022712A1 (it) * | 2002-12-20 | 2004-06-21 | Polimeri Europa Spa | Composizione catalitica e processo per la transalchilazione di idrocarburi. |
| CN101913973B (zh) | 2003-07-24 | 2013-11-20 | 皇后医学中心 | 烷基化剂的制备和用途 |
| US7476774B2 (en) * | 2005-02-28 | 2009-01-13 | Exxonmobil Research And Engineering Company | Liquid phase aromatics alkylation process |
| US7425659B2 (en) * | 2006-01-31 | 2008-09-16 | Exxonmobil Chemical Patents Inc. | Alkylaromatics production |
| US7649122B2 (en) * | 2006-11-15 | 2010-01-19 | Exxonmobile Chemical Patents Inc. | Alkylaromatics production |
| US7919421B2 (en) * | 2006-12-21 | 2011-04-05 | Exxonmobil Chemical Patents Inc. | Catalyst composition, the method of manufacturing and the process of use thereof in aromatics alkylation |
| IT1392325B1 (it) * | 2008-09-11 | 2012-02-28 | Polimeri Europa Spa | Processo per l'alchilazione di benzene con isopropanolo o miscele di isopropanolo e propilene |
| TWI458695B (zh) * | 2008-10-06 | 2014-11-01 | Badger Licensing Llc | 異丙苯的製造方法 |
| KR20110082156A (ko) * | 2008-10-06 | 2011-07-18 | 바져 라이센싱 엘엘씨 | 큐멘의 제조방법 |
| WO2010047364A1 (ja) * | 2008-10-23 | 2010-04-29 | 三井化学株式会社 | アルキル化芳香族化合物の製造方法、クメンの製造方法およびフェノールの製造方法 |
| US8395006B2 (en) * | 2009-03-13 | 2013-03-12 | Exxonmobil Research And Engineering Company | Process for making high octane gasoline with reduced benzene content by benzene alkylation at high benzene conversion |
| IT1394721B1 (it) * | 2009-06-10 | 2012-07-13 | Polimeri Europa Spa | Processo per l'alchilazione di benzene con etanolo o miscele di etanolo ed etilene |
| IT1397885B1 (it) | 2009-12-23 | 2013-02-04 | Polimeri Europa Spa | Processo per preparare etilbenzene. |
| IT1397886B1 (it) | 2009-12-23 | 2013-02-04 | Eni Spa | Procedimento per la produzione di componenti di carburanti per autotrazione. |
| ITMI20111143A1 (it) | 2011-06-23 | 2012-12-24 | Polimeri Europa Spa | Procedimento per l'alchilazione di idrocarburi aromatici con alcoli c1-c8 |
| RU2484898C2 (ru) * | 2011-07-07 | 2013-06-20 | Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) | Способ повышения времени стабильной работы катализатора в реакции гидроалкилирования бензола ацетоном с получением кумола и способ получения кумола гидроалкилированием бензола ацетоном |
| KR102074021B1 (ko) | 2012-07-05 | 2020-02-05 | 바져 라이센싱 엘엘씨 | 큐멘의 제조방법 |
| SG11201500058VA (en) * | 2012-07-13 | 2015-02-27 | Badger Licensing Llc | Process for producing phenol |
| ES2716530T3 (es) * | 2012-08-14 | 2019-06-13 | Badger Licensing Llc | Proceso integrado para la producción de cumeno y la purificación de isopropanol |
| ITMI20131704A1 (it) | 2013-10-15 | 2015-04-16 | Versalis Spa | Composizione catalitica e processo che la utilizza per l'alchilazione di idrocarburi aromatici con alcoli, o miscele di alcoli e olefine |
| IT201900015066A1 (it) | 2019-08-27 | 2021-02-27 | Versalis Spa | Procedimento per il trattamento di idrocarburi polialchilaromatici. |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4891448A (en) * | 1987-11-23 | 1990-01-02 | The Dow Chemical Company | Alkylation of polycyclic aromatic compounds to alkylates enriched in the para-substituted isomers |
| DE3819455A1 (de) | 1988-06-08 | 1989-12-14 | Basf Ag | 2-((meth)acrylamidomethyl)-1,3-diketone |
| RU1839668C (ru) * | 1988-11-28 | 1993-12-30 | МИЦУИ ПЕТРОКЕМИКАЛ ИНДАСТРИЗ, Лтд (JP) | Способ получени фенола |
| JPH02231442A (ja) * | 1988-11-28 | 1990-09-13 | Mitsui Petrochem Ind Ltd | フェノールの製造方法 |
| US5030786A (en) * | 1989-06-23 | 1991-07-09 | Fina Technology, Inc. | Liquid phase aromatic conversion process |
| FR2662438B1 (fr) * | 1990-05-22 | 1993-10-29 | Institut Francais Petrole | Procede de production d'alkylbenzenes utilisant des catalyseurs a base de zeolithe y desaluminee. |
| EP0538518A1 (de) | 1991-10-16 | 1993-04-28 | Council of Scientific and Industrial Research | Verbessertes Verfahren zur Herstellung von Cumol |
| JPH07223978A (ja) * | 1994-02-10 | 1995-08-22 | Mitsubishi Chem Corp | 芳香族化合物の製造方法 |
| IT1270230B (it) * | 1994-06-16 | 1997-04-29 | Enichem Sintesi | Composizione catalitica e processo per l'alchilazione di composti aromatici |
| JPH11169719A (ja) * | 1997-12-17 | 1999-06-29 | Asahi Chem Ind Co Ltd | 芳香族のアルキル化用Ａ１−βゼオライト触媒 |
-
1999
- 1999-07-13 IT IT1999MI001531A patent/IT1313008B1/it active
-
2000
- 2000-07-05 RU RU2000117488/04A patent/RU2234490C2/ru active
- 2000-07-07 US US09/612,256 patent/US6512153B1/en not_active Expired - Lifetime
- 2000-07-10 AT AT00202434T patent/ATE253027T1/de not_active IP Right Cessation
- 2000-07-10 EP EP00202434A patent/EP1069100B1/de not_active Expired - Lifetime
- 2000-07-10 ES ES00202434T patent/ES2208219T3/es not_active Expired - Lifetime
- 2000-07-10 SG SG200003825A patent/SG91293A1/en unknown
- 2000-07-10 DE DE60006191T patent/DE60006191T2/de not_active Expired - Lifetime
- 2000-07-11 MX MXPA00006809A patent/MXPA00006809A/es unknown
- 2000-07-12 KR KR10-2000-0039757A patent/KR100500272B1/ko not_active Expired - Lifetime
- 2000-07-13 JP JP2000212526A patent/JP4837162B2/ja not_active Expired - Lifetime
- 2000-08-16 TW TW089116515A patent/TW526183B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DE60006191T2 (de) | 2004-07-29 |
| SG91293A1 (en) | 2002-09-17 |
| TW526183B (en) | 2003-04-01 |
| KR100500272B1 (ko) | 2005-07-11 |
| ITMI991531A0 (it) | 1999-07-13 |
| IT1313008B1 (it) | 2002-05-29 |
| EP1069100B1 (de) | 2003-10-29 |
| DE60006191D1 (de) | 2003-12-04 |
| MXPA00006809A (es) | 2002-03-15 |
| ITMI991531A1 (it) | 2001-01-13 |
| RU2234490C2 (ru) | 2004-08-20 |
| ES2208219T3 (es) | 2004-06-16 |
| JP2001055351A (ja) | 2001-02-27 |
| KR20010066920A (ko) | 2001-07-11 |
| JP4837162B2 (ja) | 2011-12-14 |
| US6512153B1 (en) | 2003-01-28 |
| EP1069100A1 (de) | 2001-01-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |