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ATE102615T1 - Selektive epoxidation von olefinen. - Google Patents

Selektive epoxidation von olefinen.

Info

Publication number
ATE102615T1
ATE102615T1 AT89300776T AT89300776T ATE102615T1 AT E102615 T1 ATE102615 T1 AT E102615T1 AT 89300776 T AT89300776 T AT 89300776T AT 89300776 T AT89300776 T AT 89300776T AT E102615 T1 ATE102615 T1 AT E102615T1
Authority
AT
Austria
Prior art keywords
olefins
selective
epoxydation
contacted
oxygen
Prior art date
Application number
AT89300776T
Other languages
English (en)
Inventor
John Robert Monnier
Peter James Muehlbauer
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/149,297 external-priority patent/US4897498A/en
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Application granted granted Critical
Publication of ATE102615T1 publication Critical patent/ATE102615T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Plural Heterocyclic Compounds (AREA)
AT89300776T 1988-01-28 1989-01-27 Selektive epoxidation von olefinen. ATE102615T1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/149,297 US4897498A (en) 1988-01-28 1988-01-28 Selective monoepoxidation of olefins
US07/292,589 US4950773A (en) 1988-01-28 1988-12-30 Selective epoxidation of olefins
EP89300776A EP0326392B1 (de) 1988-01-28 1989-01-27 Selektive Epoxidation von Olefinen

Publications (1)

Publication Number Publication Date
ATE102615T1 true ATE102615T1 (de) 1994-03-15

Family

ID=26846613

Family Applications (1)

Application Number Title Priority Date Filing Date
AT89300776T ATE102615T1 (de) 1988-01-28 1989-01-27 Selektive epoxidation von olefinen.

Country Status (12)

Country Link
US (1) US4950773A (de)
EP (2) EP0397793A1 (de)
JP (1) JP2854059B2 (de)
KR (1) KR960011382B1 (de)
CN (1) CN1023225C (de)
AT (1) ATE102615T1 (de)
AU (1) AU618792B2 (de)
BR (1) BR8907211A (de)
CA (1) CA1338268C (de)
DE (1) DE68913563T2 (de)
ES (1) ES2051994T3 (de)
WO (1) WO1989007101A1 (de)

Families Citing this family (68)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5145968A (en) * 1988-11-14 1992-09-08 Eastman Kodak Company Selective monoepoxidation of styrene, styrene analogs, and styrene derivatives to the corresponding oxide with molecular oxygen
EP0464149A1 (de) * 1989-03-20 1992-01-08 Eastman Kodak Company Selektive epoxidierung von bicyclischen olefinen
US5138077A (en) * 1991-07-29 1992-08-11 Eastman Kodak Company Selective epoxidation of diolefins and aryl olefins
US5117012A (en) * 1991-10-07 1992-05-26 Eastman Kodak Company Recovery of 3,4-epoxy-1-butene from 1,3-butadiene oxidation effluents
US5155242A (en) * 1991-12-05 1992-10-13 Shell Oil Company Process for starting-up an ethylene oxide reactor
US5326873A (en) * 1992-06-05 1994-07-05 Eastman Kodak Company Palladium catalyzed addition of amines to 3,4-epoxy-1-butene
DE4241942A1 (de) * 1992-12-11 1994-06-16 Basf Ag Verfahren zur Herstellung von 3,4-Epoxy-1-buten
US5418202A (en) * 1993-12-30 1995-05-23 Shell Oil Company Ethylene oxide catalyst and process
DE4422671A1 (de) 1994-06-30 1996-01-04 Basf Ag Verfahren zur Herstellung von 2,5-Dihydrofuran
DE4424219A1 (de) 1994-07-09 1996-01-11 Basf Ag Verfahren zur Herstellung von 2,5-Dihydrofuran
US5466832A (en) * 1995-02-13 1995-11-14 Eastman Chemical Company Process for the manufacture of 2,5-dihydrofurans from γ, δ-epoxybutenes
US5908942A (en) * 1995-09-15 1999-06-01 Eastman Chemical Company Epoxidation of butadiene using cesium fluoride promoted silver catalyst with enhanced thermal stability under reaction conditions
US5780657A (en) * 1997-06-23 1998-07-14 Arco Chemical Technology, L.P. Propylene epoxidation using chloride-containing silver catalysts
US6323351B1 (en) * 1997-06-30 2001-11-27 The Dow Chemical Company Process for the direct oxidation of olefins to olefin oxides
US6562986B2 (en) 1997-06-30 2003-05-13 Dow Global Technologies, Inc. Process for the direct oxidation of olefins to olefin oxides
US5973209A (en) * 1997-07-11 1999-10-26 The Nutrasweet Company Method for preparing 3, 3-dimethybutyraldehyde
US5756779A (en) * 1997-09-29 1998-05-26 Eastman Chemical Company Recovery of 3,4-epoxy-1-butene from 1,3-butadiene oxidation effluents
US6222058B1 (en) 1998-03-30 2001-04-24 Eastman Chemical Company Process for the manufacture of cyclopropanecarbonitrile
US5945550A (en) * 1998-07-24 1999-08-31 Eastman Chemical Company Gas phase process for the epoxidation of non-allylic olefins
US6455713B1 (en) 1998-09-14 2002-09-24 Eastman Chemical Company Reactivation of Cs-promoted, Ag catalysts for the selective epoxidation of butadiene to 3,4-epoxy-1-butene
CN1172921C (zh) 1998-12-16 2004-10-27 陶氏环球技术公司 将烯烃直接氧化成烯烃氧化物的方法
US6018061A (en) * 1999-05-05 2000-01-25 Eastman Chemical Company Process for recovering 3,4-epoxy-1-butene
US6610878B1 (en) 1999-05-10 2003-08-26 Eastman Chemical Company Poly(3-cyclopropyl-3-hydroxypropionate) and processes for its preparation and derivatives thereof
EP1086743B1 (de) 1999-09-21 2006-08-16 Nippon Shokubai Co., Ltd. Katalysator für die Herstellung von Epoxiden und Verfahren für die Bereitung derselben und die Herstellung von Epoxiden
US6172245B1 (en) 1999-12-16 2001-01-09 Eastman Chemical Company Gas phase process for the epoxidation of non-allylic olefins
US7678343B2 (en) 1999-12-24 2010-03-16 Ineos Vinyls Uk Ltd. Metallic monolith catalyst support for selective gas phase reactions in tubular fixed bed reactors
JP3825217B2 (ja) * 1999-12-28 2006-09-27 株式会社日本触媒 酸化エチレンの製造方法
US6270739B1 (en) 2000-06-16 2001-08-07 Eastman Chemical Company Process for the removal of carbon dioxide from 3,4-epoxy-1-butene process recycle streams
US6353140B1 (en) 2000-10-19 2002-03-05 Eastman Chemical Company Process for the purification of cyclopropanecarboxaldehyde
US6388106B1 (en) * 2001-05-24 2002-05-14 Eastman Chemical Company Selective epoxidation of conjugated diolefins
US6596882B2 (en) 2001-07-20 2003-07-22 Eastman Chemical Company Recovery and purification of 3,4-epoxy-1-butene using water-miscible solvents
US6500970B1 (en) 2001-07-20 2002-12-31 Eastman Chemical Company Recovery and purification of 3,4-epoxy-1-butene using high-boiling solvents
US6395913B1 (en) 2001-07-20 2002-05-28 Eastman Chemical Company Recovery and purification of 3,4-epoxy-1-butene
US7193094B2 (en) 2001-11-20 2007-03-20 Shell Oil Company Process and systems for the epoxidation of an olefin
US6582565B1 (en) 2002-01-17 2003-06-24 Eastman Chemical Company Recovery of 3,4-epoxy-1-butene by extractive distillation
KR101098051B1 (ko) * 2002-06-28 2011-12-26 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 에폭시화 방법의 개시방법, 올레핀 에폭시화 촉매 및 방법
EP1517751B2 (de) 2002-06-28 2016-06-01 Shell Internationale Research Maatschappij B.V. Verfahren zur verbesserung der selektivität eines katalysators und verfahren zum epoxidieren eines olefins
CN1665797B (zh) 2002-06-28 2011-09-14 国际壳牌研究有限公司 环氧化方法的开车方法和烯烃环氧化方法
DE10231976A1 (de) 2002-07-15 2004-01-29 Basf Ag Strukturierte Katalysator-Schüttung
DE10300526A1 (de) * 2003-01-09 2004-07-22 Hte Ag The High Throughput Experimentation Company Silberhaltige Katalysatoren zur Umsetzung von Substraten mit C-C-Doppelbindungen
JP4572551B2 (ja) * 2003-03-25 2010-11-04 住友化学株式会社 酸化オレフィンの製造法
KR20060002920A (ko) * 2003-04-01 2006-01-09 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 올레핀 에폭시화 방법 및 그 방법에 사용하기 위한 촉매
US7348444B2 (en) 2003-04-07 2008-03-25 Shell Oil Company Process for the production of an olefin oxide
US8148555B2 (en) 2003-06-26 2012-04-03 Shell Oil Company Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
WO2005016852A2 (de) 2003-08-06 2005-02-24 Basf Aktiengesellschaft Verfahren zum betreiben einer kontinuierlichen heterogen katalysierten gasphasen-partialoxidation wenigstens einer organischen verbindung
JP2005200323A (ja) * 2004-01-14 2005-07-28 Mitsubishi Chemicals Corp ３，４−ジアセトキシ−１−ブテン及びそれを用いた誘導体の製造方法
DE102004025445A1 (de) 2004-05-19 2005-02-10 Basf Ag Verfahren zum Langzeitbetrieb einer heterogen katalysierten Gasphasenpartialoxidation wenigstens einer organischen Verbindung
WO2006041209A1 (ja) * 2004-10-14 2006-04-20 Sumitomo Chemical Company, Limited ２－ヒドロキシ－４－（メチルチオ）酪酸の製造方法
US7439389B2 (en) 2005-03-01 2008-10-21 Basf Aktiengesellschaft Process for preparing at least one organic target compound by heterogeneously catalyzed gas phase partial oxidation
DE102006000996A1 (de) 2006-01-05 2007-07-12 Basf Ag Verfahren der heterogen katalysierten Gasphasen-Partialoxidation wenigstens einer organischen Ausgangsverbindung
EP1734030A1 (de) 2006-01-18 2006-12-20 BASF Aktiengesellschaft Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation einer organischen Ausgangsverbindung
DE102007004961A1 (de) 2007-01-26 2008-07-31 Basf Se Verfahren zur Herstellung von Katalysatorformkörpern, deren Aktivmasse ein Multielementoxid ist
DE102007017080A1 (de) 2007-04-10 2008-10-16 Basf Se Verfahren zur Beschickung eines Längsabschnitts eines Kontaktrohres
EP2152411B1 (de) 2007-05-09 2019-12-04 Shell International Research Maatschappij B.V. Epoxidationskatalysator, verfahren zur herstellung des katalysators und verfahren zur herstellung eines olefinoxids, eines 1,2-diols, eines 1,2-diolethers, eines 1,2-carbonats oder eines alkanolamins
DE102007028332A1 (de) 2007-06-15 2008-12-18 Basf Se Verfahren zum Beschicken eines Reaktors mit einem Katalysatorfestbett, das wenigstens ringförmige Katalysatorformkörper K umfasst
DE102007028333A1 (de) 2007-06-15 2008-12-18 Basf Se Verfahren zum Einbringen einer wenigstens einer Produktionscharge von ringförmigen Schalenkatalysatoren K entnommenen Teilmenge in ein Reaktionsrohr eines Rohrbündelreaktors
DE102008018968A1 (de) 2008-04-16 2009-10-22 Ticona Gmbh Polyoxymethylen-Formmassen und Formkörper und deren Verwendung
KR101629037B1 (ko) 2008-05-07 2016-06-09 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 에폭시화 방법의 스타트업 방법, 산화에틸렌, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법
WO2009137431A2 (en) 2008-05-07 2009-11-12 Shell Oil Company A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
US8840976B2 (en) 2010-10-14 2014-09-23 Ticona Llc VOC or compressed gas containment device made from a polyoxymethylene polymer
EP2505609B1 (de) 2011-04-01 2015-01-21 Ticona GmbH Polyoxymethylen mit hoher schlagfestigkeit für extrusionsblasformung
JP2013028590A (ja) 2011-06-21 2013-02-07 Sumitomo Chemical Co Ltd アミノアルコール化合物の製造方法
JP2013028591A (ja) 2011-06-21 2013-02-07 Sumitomo Chemical Co Ltd アミノアルコール化合物の製造方法
US8968858B2 (en) 2011-12-30 2015-03-03 Ticona Llc Printable molded articles made from a polyoxymethylene polymer composition
US9745467B2 (en) 2012-12-27 2017-08-29 Ticona, Llc Impact modified polyoxymethylene composition and articles made therefrom that are stable when exposed to ultraviolet light
CN104888855B (zh) * 2015-04-03 2017-03-01 江南大学 一种用于烯烃环氧化反应的乙酰丙酮氧钼固体催化剂及其制备方法
RU2757051C2 (ru) 2016-12-02 2021-10-11 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способы обработки катализатора эпоксидирования этилена и связанные способы получения оксида этилена
CN108283943B (zh) * 2017-01-10 2021-07-02 中国石油化工股份有限公司 氧化铝载体及其制备方法、乙烯环氧化反应用银催化剂及乙烯环氧化制备环氧乙烷的方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA488990A (en) * 1952-12-23 J. Carlson George Process for forming ethylene oxide
US2279470A (en) * 1938-04-12 1942-04-14 Carbide & Carbon Chem Corp Process of making olefin oxides
US2404438A (en) * 1943-09-07 1946-07-23 Shell Dev Process for the manufacture of olefin oxides
US2709173A (en) * 1950-01-09 1955-05-24 California Research Corp Oxidation of olefins and catalyst therefor
GB1327497A (en) * 1972-05-25 1973-08-22 Bp Chem Int Ltd Propylene oxide
EP0003642B1 (de) * 1978-02-10 1984-07-18 Imperial Chemical Industries Plc Herstellung von Olefinoxyden
DE2936036A1 (de) * 1979-09-06 1981-04-02 EC Erdölchemie GmbH, 5000 Köln Verfahren zur herstellung von ethylenoxid
US4760042A (en) * 1982-03-24 1988-07-26 Scientific Design Company, Inc. Process for preparing an alkali metal-promoted silver catalyst
GB8611121D0 (en) * 1986-05-07 1986-06-11 Shell Int Research Silver catalyst

Also Published As

Publication number Publication date
KR960011382B1 (ko) 1996-08-22
JP2854059B2 (ja) 1999-02-03
JPH03502330A (ja) 1991-05-30
EP0326392B1 (de) 1994-03-09
AU618792B2 (en) 1992-01-09
DE68913563T2 (de) 1994-09-29
US4950773A (en) 1990-08-21
CN1023225C (zh) 1993-12-22
WO1989007101A1 (en) 1989-08-10
KR900700473A (ko) 1990-08-13
ES2051994T3 (es) 1994-07-01
EP0326392A1 (de) 1989-08-02
CN1036012A (zh) 1989-10-04
DE68913563D1 (de) 1994-04-14
CA1338268C (en) 1996-04-23
EP0397793A1 (de) 1990-11-22
AU3182589A (en) 1989-08-25
BR8907211A (pt) 1991-03-05

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REN Ceased due to non-payment of the annual fee