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AR049382A1 - Derivados de la urea ciclica substituida - Google Patents

Derivados de la urea ciclica substituida

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Publication number
AR049382A1
AR049382A1 ARP050102020A ARP050102020A AR049382A1 AR 049382 A1 AR049382 A1 AR 049382A1 AR P050102020 A ARP050102020 A AR P050102020A AR P050102020 A ARP050102020 A AR P050102020A AR 049382 A1 AR049382 A1 AR 049382A1
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AR
Argentina
Prior art keywords
alkyl
hydrogen
optionally substituted
aryl
haloalkyl
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ARP050102020A
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English (en)
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Fmc Corp
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Publication of AR049382A1 publication Critical patent/AR049382A1/es

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C07D249/10—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D249/12—Oxygen or sulfur atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/04—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/66—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D233/72—Two oxygen atoms, e.g. hydantoin
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D253/00—Heterocyclic compounds containing six-membered rings having three nitrogen atoms as the only ring hetero atoms, not provided for by group C07D251/00
    • C07D253/02—Heterocyclic compounds containing six-membered rings having three nitrogen atoms as the only ring hetero atoms, not provided for by group C07D251/00 not condensed with other rings
    • C07D253/06—1,2,4-Triazines
    • C07D253/065—1,2,4-Triazines having three double bonds between ring members or between ring members and non-ring members
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D257/00—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms
    • C07D257/02—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D257/04—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/10—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/04—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D407/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00
    • C07D407/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00 containing two hetero rings
    • C07D407/10—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00 containing two hetero rings linked by a carbon chain containing aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
    • C07D417/10—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a carbon chain containing aromatic rings

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Fertilizers (AREA)

Abstract

La presente se refiere a derivados de la urea cíclica substituida. Adicionalmente, también se revelen las composiciones que comprenden una cantidad insecticidamente efectiva de al menos un compuesto de la formula (1), y opcionalmente una cantidad efectiva de al menos un segundo compuesto, con al menos un vehículo insecticidamente compatible; junto con los métodos para controlar los insectos que comprende aplicar dichas composiciones a un lugar donde los insectos están presente o se espera que estén presentes. Reivindicacion 1: Un compuesto de la formula (1), donde: R y R3 están independientemente seleccionados del hidrogeno, halogeno, hidroxi, alquilo C1-6, cicloalquilo C3-6, alquenilo C2-6, alquinilo C2-6, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, alquiltio C1-3, haloalquiltio C1-3, alquilsulfonilo C1-3, haloalquilsulfonilo C1-3, ciano, nitro; amino opcionalmente substituido en la que el substituyente opcional está seleccionado desde alquilo C1-4, alquil C1-3carbonilo y alcoxi C1-3carbonilo; imidazolilo opcionalmente substituido, imidazolinilo opcionalmente substituido, oxazolinilo opcionalmente substituido, oxazolilo opcionalmente substituido, oxadiazolilo opcionalmente substituido, tiazolilo opcionalmente substituido, pirazolilo opcionalmente substituido, triazolilo opcionalmente substituido, furanilo opcionalmente substituido, tetrahidrofuranilo opcionalmente substituido, dioxolanilo opcionalmente substituido, dioxanilo opcionalmente substituido, - C(=K)-L, y -C(R16)-MR17, en la que el substituyente opcional está seleccionado desde alquilo C1-4, halogeno, haloalquilo C1-4, alcoxi C1-4, alcoxi C1-4-alquilo C1-4, cicloalquilo C3-6, alquenilo C2-6, alquinilo C2-6, ciano, nitro y arilo; donde K está seleccionado desde O, S, NR18, y NOR18, donde R18 es hidrogeno, alquilo C1-4, haloalquilo C1-4, arilo y arilo-alquilo C1-4; L está seleccionado desde hidrogeno, alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, alquilamino C1-3 y dialquilamino C1-3; M está seleccionado desde O, S, y NR18, donde R18 es como se describio previamente; R16 y R17 están independientemente seleccionados del hidrogeno, alquilo C1-4 y haloalquilo C1-4, o R16 y R17 pueden estar tomados juntos con -Q(CHR18)e, donde e es un entero de 2 a 4; Q está seleccionado desde O, S, y NR18, donde R18 es como se describio previamente; R1 y R2 están independientemente seleccionados del hidrogeno, halogeno y alquilo C1-3; A está seleccionado desde O, S, *OCH2 y (CH2)f donde el asterisco denota union a B, y f es un entero seleccionado desde 1, 2, y 3; B está seleccionado desde CH2, O, S y NR19 donde R19 está seleccionado desde hidrogeno, alquilo C1-3, alcoxi C1-3-alquilo C1-3, arilo-alquilo C1-3, alquenil C2-4-alquilo C1- 3, haloalquenil C2-4-alquilo C1-3, dialquil C1-3fosfonato, alquil C1-3carbonilo, haloalquil C1-3carbonilo, alcoxi C1-3-alquil C1-3carbonilo, arilcarbonil, alquilsulfonilo C1-3; con la condicion de que A y B no son simultáneamente O o S; R4 es hidrogeno; R5 y R6 están independientemente seleccionados del halogeno; a es un entero seleccionado desde 0 o 1; y cuando a es 1, D es O, CH2, OCH2, CH2O, OCH=CH, C(=O), S(O)g, -CH=CH-, -OC(=O)-, -OC(=O)NH-, -NHC(=O)-, -NHSO2-, -N=CH-, NR19, o N(oxido)R19 donde R19 es como se describio previamente, y g es un entero seleccionado desde 0, 1 o 2; b es un entero seleccionado desde 0,1, 2, 3, 4, 5 o 6; y cuando b es 1 o más, R7 y R8 están independientemente seleccionados del hidrogeno, halogeno, alquilo C1-4, cicloalquilo C3-6, haloalquilo C1-4 y arilo; E es un grupo puente seleccionado desde -CR20=CR21-, *-CR20=N-, *-N=CR20-, -N=N-, *-C(=O)CR20R21-, *-CR20R21C(=O)-, -(CR20R21)n-, *-N=CR20C(=O)-, *-C(=O)CR20=N-, *-C(=O)NR20-, *- NR20C(=O)-, *-CR20=CR21C(=O)-, *-C(=O)CR21=CR20-, -CR20R21OCR22R23-, -C(=O)C(=O)-, *-S(O)gCR20R21-, *-S(O)gNR20-, *-OCR22R23-, *-CR22R23O- y -C(=O)-, donde el asterisco denota union en la posicion designada como 1 en la formula (1), g es como se describio previamente, n es un entero seleccionado desde 2, 3 y 4; y R20 hasta R23, inclusive, están independientemente seleccionados del hidrogeno, halogeno, alquilo C1-4, alcoxi C1-4, alcoxi C1-4-alquilo C1-4, haloalquilo C1-4, alcoxi C1- 4carbonilo, nitro, ciano, amino, alquilamino C1-4 y arilo; y R20 hasta R23 en posicion geminal pueden estar tomados juntos para formar anillos de 5-, 6- o 7-miembros espiro comprendidos de carbono, nitrogeno u oxígeno, o R20 hasta R23 en posiciones adyacentes pueden estar tomados juntos para formar anillos de 5-, 6- o 7-miembros comprendidos de carbono, nitrogeno y oxígeno o un anillo benzo fusionado; G está seleccionado desde O, S, N-Q, o C-Q, donde Q es ciano o nitro; c es un entero seleccionado desde 0, 1, 2, 3 o 4; y cuando c es 1 o más, R9 y R10 están independientemente seleccionados del hidrogeno, alquilo C1-4, haloalquilo C1-4 o alcoxi C1-4 y arilo; d es un entero seleccionado desde 0 o 1; y cuando d es 1, J está seleccionado desde O, CH=CH, S(O)g, HC=N, C(=O), OC(=O), C(=O)O, C(=O)NH, NR19, N(oxido)R19 y NR19C(=O) donde g y R19 son como se describio previamente; X está seleccionado desde un arilo substituido o un heteroarilo substituido, en la que los substituyentes están independientemente seleccionados del hidrogeno, halogeno, alquilo C1-6, alquenilo C2-4, alquinilo C2-4, haloalquilo C1-6, haloalcoxi C1-6, hidroxi-alquilo C1-6, cicloalquilo C3-6, haloalquenilo C2-4, haloalquinilo C2-4, alcoxi C1-6, alcoxi C1-6-alquilo C1-6, alqueniloxi C2-4, alquiniloxi C2-4, haloalcoxi C1-6, haloalqueniloxi C2-4, haloalquiniloxi C2-4, alquiltio C1-6, pentahalotio, alquilsulfinilo C1-6, alquilsulfonilo C1-6, haloalquiltio C1-6, haloalquilsulfinilo C1-6, haloalquilsulfonilo C1-6, ciano, nitro; NRcRd, donde Rc y Rd están independientemente seleccionados del hidrogeno, alquilo C1-6, haloalquilo C1-6, alquil C1-6carbonilo, y alcoxi C1-6carbonilo, o donde Rc y Rd pueden estar tomados juntos para formar un anillo de 5- o 6-miembros saturados o no-saturados que contienen carbono, O, N, o S; alquil C1-6carbonilo, alquil C1-6carboniloxi, alcoxi C1-6carbonilo, alcoxi C1-6carboniloxi, alquilamino C1-6carbonilo, alquilamino C1-6carboniloxi, trialquilsililo C1-6, dialquilfosfinoilo C1-6, arilo, ariloxi, y arilo-alcoxi C1-6; con la condicion de que cuando X es un arilo substituido que tiene la estructura de formula (2), R11 y R12, o R12 y R13, o R13 y R14, o R14 y R15 son tomados juntos con -CR24=CR25CR26=CR27-, -OCR24R25CH2-, -CH2CR24R25O-, -OCR24R25O-, -OCR24R25CR26R27O-, -OCR24R25CH=CH-, -OCR24R25CH2CH2-, -OCR24=N-, -N=CR24O-, -ON=CR24-, -ONR24C(=O)-, -CH2NR24C(=O)-, -C3H6-, -C2H4(C=O)-, -SCR24=N-, -OCR24R25C(=O)-, - CR24=CR25NR26-, -CR24=NNR25-, -N=NNR24- o -N=CR24N=N- para formar un anillo fusionado, donde R24 hasta R27, inclusive, están independientemente seleccionados del hidrogeno, halogeno, alquilo C1-3, haloalquilo C1-3, haloalcoxi C1-3 y arilo; y las sales agrícolamente aceptables de los mismos.
ARP050102020A 2004-05-18 2005-05-17 Derivados de la urea ciclica substituida AR049382A1 (es)

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EP (1) EP1755613A4 (es)
JP (1) JP2007538107A (es)
KR (1) KR20070011596A (es)
CN (1) CN1980903A (es)
AR (1) AR049382A1 (es)
BR (1) BRPI0511294A (es)
MX (1) MXPA06013278A (es)
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CN105517995B (zh) * 2013-07-08 2018-10-02 拜耳作物科学股份公司 作为农药的六元c-n键合的芳基硫化物和芳基硫氧化物衍生物
CN104326986B (zh) * 2014-10-08 2016-05-04 南通大学 二氯丙烯基苯醚类化合物的制备方法及其应用
WO2017205709A1 (en) 2016-05-27 2017-11-30 Bristol-Myers Squibb Company Triazolones and tetrazolones as inhibitors of rock
EP3560913A1 (en) 2018-04-25 2019-10-30 Dynamit Nobel GmbH Explosivstoff- und Systemtechnik Process for the production of tetrazolinones

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US4487773A (en) * 1981-03-16 1984-12-11 Mead Johnson & Company 1,2,4-Triazol-3-one antidepressants
US4338317A (en) * 1981-03-16 1982-07-06 Mead Johnson & Company Phenoxyethyl-1,2,4,-triazol-3-one antidepressants
TW307746B (es) * 1994-10-14 1997-06-11 Sumitomo Chemical Co
US5952386A (en) * 1995-04-18 1999-09-14 Sumitomo Chemical Company, Limited Dihalopropene compounds, insecticides containing them as active ingredients, and intermediates for their production
US6294573B1 (en) * 1997-08-06 2001-09-25 Abbott Laboratories Reverse hydroxamate inhibitors of matrix metalloproteinases
US6706739B2 (en) * 2001-08-21 2004-03-16 National Health Research Institute Imidazolidinone compounds
AU2003211534A1 (en) 2002-03-05 2003-09-16 Sumitomo Chemical Company, Limited Cyclic compound, process for producing the same, and pest control agent
AR043048A1 (es) * 2002-08-30 2005-07-13 Syngenta Participations Ag Derivados de 4-(3,3-dihalo- aliloxi) fenol con propiedades pesticidas
MXPA05011336A (es) * 2003-04-30 2005-11-28 Fmc Corp Derivados de dihidrobenzofurano y dihidrobenzopirano sustituidos por (dihalopropenil)-fenilalquilo insecticidas.
WO2005019147A2 (en) * 2003-08-26 2005-03-03 Syngenta Participations Ag Pesticidally active phenol derivatives
JP2007519639A (ja) * 2004-01-08 2007-07-19 シンジェンタ パーティシペーションズ アクチェンゲゼルシャフト 複素環アリル誘導体

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EP1755613A2 (en) 2007-02-28
CN1980903A (zh) 2007-06-13
TW200612961A (en) 2006-05-01
KR20070011596A (ko) 2007-01-24
US20080200518A1 (en) 2008-08-21
ZA200609447B (en) 2008-06-25
WO2005112941A2 (en) 2005-12-01
JP2007538107A (ja) 2007-12-27
US7713970B2 (en) 2010-05-11
WO2005112941A3 (en) 2006-11-23
MXPA06013278A (es) 2007-05-09
EP1755613A4 (en) 2010-08-25
BRPI0511294A (pt) 2007-12-04

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