AR023991A1 - A CATALYTIC SYSTEM THAT INCLUDES A METALLIC CATALYTIC COMPOUND CONTAINING AN ATOM OF GROUP 15, A PROCEDURE FOR POLYMERIZING OLEFINS, AND A PROCEDURE TO PRODUCE A COMPONENT OF HIGH AND LOW MOLECULAR COMPONENTS IN A POLYMOLOUS COMPOSITION, A COMPOSITION OF A POLYMOD - Google Patents
A CATALYTIC SYSTEM THAT INCLUDES A METALLIC CATALYTIC COMPOUND CONTAINING AN ATOM OF GROUP 15, A PROCEDURE FOR POLYMERIZING OLEFINS, AND A PROCEDURE TO PRODUCE A COMPONENT OF HIGH AND LOW MOLECULAR COMPONENTS IN A POLYMOLOUS COMPOSITION, A COMPOSITION OF A POLYMODInfo
- Publication number
- AR023991A1 AR023991A1 ARP000102335A ARP000102335A AR023991A1 AR 023991 A1 AR023991 A1 AR 023991A1 AR P000102335 A ARP000102335 A AR P000102335A AR P000102335 A ARP000102335 A AR P000102335A AR 023991 A1 AR023991 A1 AR 023991A1
- Authority
- AR
- Argentina
- Prior art keywords
- composition
- procedure
- atom
- compound containing
- low molecular
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 5
- 230000003197 catalytic effect Effects 0.000 title abstract 4
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 title abstract 2
- 230000000379 polymerizing effect Effects 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 abstract 5
- 239000003054 catalyst Substances 0.000 abstract 2
- 150000002736 metal compounds Chemical class 0.000 abstract 2
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 230000002902 bimodal effect Effects 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000012968 metallocene catalyst Substances 0.000 abstract 1
- -1 polyethylene Polymers 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Sistemas catalíticos soportados y no soportados de composiciones catalíticas, que son utiles en procesos de polimerizacion, que incluyen un compuestocatalítico metálico que contiene un átomo del Grupo 15, o composiciones catalíticas mixtas que incluyen el compuesto metálico que contiene un átomo del Grupo15, y un segundo compuesto metálico que preferiblemente es un catalizador de metaloceno de ligando voluminoso. Un procedimiento para polimerizar olefinas, y unprocedimiento para producir un componente de alto y bajo peso molecular en una composicion de un polímero multimodal en presencia de los mismos. Un polímero ocopolímero de producido por el procedimiento, generalmente polietileno, particularmente un polímero bimodal. Una composicion polimérica y una película extruídasoplada o moldeada a partir del polímero.Supported and unsupported catalyst systems of catalytic compositions, which are useful in polymerization processes, which include a metal catalytic compound containing a Group 15 atom, or mixed catalyst compositions that include the metal compound containing a Group15 atom, and a second metal compound that is preferably a voluminous ligand metallocene catalyst. A process for polymerizing olefins, and a process for producing a high and low molecular weight component in a multimodal polymer composition in the presence thereof. An ocopolymer polymer produced by the process, generally polyethylene, particularly a bimodal polymer. A polymer composition and an extruded film blown or molded from the polymer.
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/425,387 US6274684B1 (en) | 1999-10-22 | 1999-10-22 | Catalyst composition, method of polymerization, and polymer therefrom |
| US09/435,409 US6300439B1 (en) | 1999-11-08 | 1999-11-08 | Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process |
| US09/443,551 US6265505B1 (en) | 1999-11-18 | 1999-11-18 | Catalyst system and its use in a polymerization process |
| US09/442,813 US6417304B1 (en) | 1999-11-18 | 1999-11-18 | Method of polymerization and polymer produced therefrom |
| US09/451,792 US6399722B1 (en) | 1999-12-01 | 1999-12-01 | Solution feed of multiple catalysts |
| US09/460,179 US6380328B1 (en) | 1999-12-10 | 1999-12-10 | Catalyst systems and their use in a polymerization process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR023991A1 true AR023991A1 (en) | 2002-09-04 |
Family
ID=27559972
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP000102335A AR023991A1 (en) | 1999-10-22 | 2000-05-15 | A CATALYTIC SYSTEM THAT INCLUDES A METALLIC CATALYTIC COMPOUND CONTAINING AN ATOM OF GROUP 15, A PROCEDURE FOR POLYMERIZING OLEFINS, AND A PROCEDURE TO PRODUCE A COMPONENT OF HIGH AND LOW MOLECULAR COMPONENTS IN A POLYMOLOUS COMPOSITION, A COMPOSITION OF A POLYMOD |
Country Status (18)
| Country | Link |
|---|---|
| EP (1) | EP1226190A1 (en) |
| JP (1) | JP4117822B2 (en) |
| KR (1) | KR100553288B1 (en) |
| CN (1) | CN100484969C (en) |
| AR (1) | AR023991A1 (en) |
| AU (1) | AU767697B2 (en) |
| BR (1) | BR0015235A (en) |
| CA (1) | CA2388137A1 (en) |
| CZ (1) | CZ20021402A3 (en) |
| IL (1) | IL149262A0 (en) |
| MX (1) | MXPA02003999A (en) |
| MY (1) | MY129717A (en) |
| NO (1) | NO20021862L (en) |
| PL (1) | PL355103A1 (en) |
| SA (1) | SA00210262B1 (en) |
| SK (1) | SK5502002A3 (en) |
| TR (1) | TR200201767T2 (en) |
| WO (1) | WO2001030861A1 (en) |
Families Citing this family (74)
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|---|---|---|---|---|
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| KR100844062B1 (en) * | 2001-02-21 | 2008-07-07 | 미쓰이 가가쿠 가부시키가이샤 | Catalyst for olefin polymerizaion and method for producing olefin polymers using the catalyst |
| US6875828B2 (en) * | 2002-09-04 | 2005-04-05 | Univation Technologies, Llc | Bimodal polyolefin production process and films therefrom |
| US7094848B2 (en) | 2003-05-13 | 2006-08-22 | Exxonmobil Chemical Patents Inc. | Olefin polymerization catalyst system |
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| EP2357203B1 (en) * | 2004-03-17 | 2017-05-24 | Dow Global Technologies LLC | Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation |
| CN1976965B (en) * | 2004-03-17 | 2012-10-10 | 陶氏环球技术有限责任公司 | Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation |
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| US8722804B2 (en) | 2010-04-13 | 2014-05-13 | Univation Technologies, Llc | Polymer blends and films made therefrom |
| WO2012009215A1 (en) | 2010-07-16 | 2012-01-19 | Univation Technologies, Llc | Systems and methods for measuring static charge on particulates |
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| US12202920B2 (en) | 2019-01-08 | 2025-01-21 | ExxonMobil Engineering & Technology Company | Olefin polymerization processes featuring in situ blending of an oil extension |
| US12466902B2 (en) | 2019-08-02 | 2025-11-11 | Exxonmobil Chemical Patents Inc. | Non-coordinating anion type activators for use with polyolefin polymerization catalysts |
| WO2021119089A1 (en) | 2019-12-11 | 2021-06-17 | Exxonmobil Chemical Patents Inc. | Processes for introduction of liquid activators in olefin polymerization reactions |
| WO2021126523A1 (en) | 2019-12-19 | 2021-06-24 | Exxonmobil Chemical Patents Inc. | Production of impact copolymer polypropylene using metallocene and ziegler-natta catalysts in parallel reactors |
| US12528892B2 (en) | 2020-03-25 | 2026-01-20 | Exxonmobil Chemical Patents Inc. | Alkylation of transition metal coordination catalyst complexes |
| WO2021262842A1 (en) | 2020-06-26 | 2021-12-30 | Exxonmobil Chemical Patents Inc. | COPOLYMERS OF ETHYLENE, α-OLEFIN, NON-CONJUGATED DIENE, AND ARYL-SUBSTITUTED CYCLOALKENE, METHODS TO PRODUCE, BLENDS, AND ARTICLES THEREFROM |
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| CN116209683B (en) | 2020-08-10 | 2025-05-13 | 埃克森美孚化学专利公司 | Method for delivering non-aromatic solutions to a polymerization reactor |
| KR102579813B1 (en) * | 2020-08-20 | 2023-09-19 | 한화솔루션 주식회사 | Catalyst Comprising Mixed Transition Metal Compounds, Polyolefin Prepared Using the Same, and Processes for Preparing the Same |
| US12503529B2 (en) | 2021-02-26 | 2025-12-23 | Exxonmobil Chemical Patents Inc. | Polymers of 4-substituted hexadiene and processes for production thereof |
| WO2025117117A1 (en) | 2023-11-28 | 2025-06-05 | ExxonMobil Technology and Engineering Company | Quantifying entrainment in a fluidized bed reactor |
| WO2025136637A1 (en) | 2023-12-20 | 2025-06-26 | ExxonMobil Technology and Engineering Company | Recovery method for polyolefin synthesis |
| WO2025136609A1 (en) | 2023-12-20 | 2025-06-26 | ExxonMobil Technology and Engineering Company | Finishing systems and methods thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2251471A1 (en) | 1997-02-07 | 1998-08-13 | Mitsui Chemicals, Incorporated | Olefin polymerization catalyst and process for the production of olefin polymers |
| US6451938B1 (en) * | 1997-02-25 | 2002-09-17 | Exxon Mobil Chemical Patents Inc. | Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands |
| TWI246520B (en) * | 1997-04-25 | 2006-01-01 | Mitsui Chemicals Inc | Processes for olefin polymerization |
| JPH10330412A (en) * | 1997-05-27 | 1998-12-15 | Mitsui Chem Inc | Catalyst for olefin polymerization and polymerization of the same |
| US6103657A (en) * | 1997-07-02 | 2000-08-15 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
| CA2323476A1 (en) * | 1998-03-12 | 1999-09-16 | Bp Chemicals Limited | Polymerization catalyst comprising a pyridine-bis(imine) complex |
| ID27209A (en) * | 1998-03-12 | 2001-03-08 | Bp Chem Int Ltd | POLYMERIZATION CATALYSTS |
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2000
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- 2000-05-15 AU AU47139/00A patent/AU767697B2/en not_active Ceased
- 2000-05-15 SK SK550-2002A patent/SK5502002A3/en unknown
- 2000-05-15 KR KR1020027005182A patent/KR100553288B1/en not_active Expired - Fee Related
- 2000-05-15 MX MXPA02003999A patent/MXPA02003999A/en active IP Right Grant
- 2000-05-15 IL IL14926200A patent/IL149262A0/en unknown
- 2000-05-15 EP EP00928987A patent/EP1226190A1/en not_active Withdrawn
- 2000-05-15 WO PCT/US2000/013313 patent/WO2001030861A1/en not_active Ceased
- 2000-05-15 AR ARP000102335A patent/AR023991A1/en unknown
- 2000-05-15 CZ CZ20021402A patent/CZ20021402A3/en unknown
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- 2000-05-15 PL PL00355103A patent/PL355103A1/en not_active Application Discontinuation
- 2000-05-15 CA CA002388137A patent/CA2388137A1/en not_active Abandoned
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| EP1226190A1 (en) | 2002-07-31 |
| JP2003513114A (en) | 2003-04-08 |
| NO20021862D0 (en) | 2002-04-19 |
| AU4713900A (en) | 2001-05-08 |
| CA2388137A1 (en) | 2001-05-03 |
| AU767697B2 (en) | 2003-11-20 |
| IL149262A0 (en) | 2002-11-10 |
| MY129717A (en) | 2007-04-30 |
| WO2001030861A1 (en) | 2001-05-03 |
| CZ20021402A3 (en) | 2002-11-13 |
| CN100484969C (en) | 2009-05-06 |
| JP4117822B2 (en) | 2008-07-16 |
| SA00210262B1 (en) | 2006-06-04 |
| SK5502002A3 (en) | 2002-12-03 |
| KR20020060956A (en) | 2002-07-19 |
| NO20021862L (en) | 2002-06-24 |
| KR100553288B1 (en) | 2006-02-22 |
| PL355103A1 (en) | 2004-04-05 |
| TR200201767T2 (en) | 2002-11-21 |
| MXPA02003999A (en) | 2002-10-23 |
| BR0015235A (en) | 2002-12-31 |
| CN1402739A (en) | 2003-03-12 |
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