Hend Abu Salem

This study integrates multivariate statistical analysis and hydrogeochemical modeling to investigate the processes controlling the groundwater composition of a shallow aquifer where increased pumping rates and anthropogenic impacts were prevalent. Eighteen groundwater samples were collected and analyzed for major elements and selected heavy metals. The data were classified on the basis of multivariate statistical analysis into three clusters: C1 (Na-Cl facies), C2 (Ca-SO4 facies), and C3 (Ca-HCO3 facies). The application of factor analysis gave four factors affecting the groundwater chemistry, namely the salinization factor, anthropogenic/secondary enrichment factor, the secondary and the micro-nutrient fertilizers, and the aluminum fertilizer factor. The hydrogeochemical study of the groundwater revealed that the processes controlling the groundwater chemistry in the study area are mainly affected by the groundwater occurrence either to the east or to the west of Bahr Youssef Canal...

The arsenic (As) pollution of water has been eliminated via intensive scientific efforts, with the purpose of giving safe drinking water to millions of people across the world. In this study, the adsorption of As(V) from a synthetic aqueous solution was verified using a Bentonite-Anthracite@Zetag (BT-An@Zetag) composite. The SEM, FT-IR, XRD, DSC, TGA, and SBET techniques were used to characterize the (BT-An@Zetag) composite. The adsorption of As(V) was explored using batch adsorption under varied operating scenarios. Five kinetic modelswere used to investigate kinetic data, whereas three isotherms had been used to fit empirical equilibrium data. According to the findings, the adsorption mechanism of As(V) was best described by the Freundlich isotherm with a maximum monolayer coverage of 38.6 mg/g showing pseudo-second-order mode. The estimated enthalpy (H°) indicates that the adsorption process is both chemical and endothermic.The calculated free energy (G°) indicates that the react...

For managing the freshwater in the worldwide coastal aquifers, it is imperative to understand the hydrogeochemical processes and flow patterns in the mixing freshwater/saltwater zone. The Egyptian Nile Delta aquifer is a typical example. The management of seawater intrusion (SWI) requires detailed investigations of the intrusion wedge and the dynamic processes in the mixing zone. Thus, a multidisciplinary approach was applied based on holistic hydrogeochemical, statistical analysis, and DC resistivity measurements to investigate the lateral and vertical changes in groundwater characteristics undergoing salinization stressor. The results of cross plots and ionic deviations of major ions, hydrochemical facies evolution diagram (HFE-D), and seawater mixing index (SMI) were integrated with the resistivity results to show the status of the SWI where the intrusion phase predominates in ~2/3 of the study are (~70 km radius) and the compositional thresholds of Na, Mg, Cl, and SO4 are 600, 1...

Groundwater pollution is a global issue in highly populated areas, the Eastern Nile Delta region is a typical example; especially around artificial wastewater drains. In the present work, a multidisciplinary approach using hydrogeochemical, geostatistical, microbiological and geophysical data was applied to determine the vulnerability conditions and to identify potential pathways through which contaminants could potentially percolate to shallow aquifers in the southern boundary of the Eastern Nile Delta. An organized groundwater sampling was conducted for hydrogeochemical investigation in rural areas along the Belbies unlined drain. This drain is known of being heavily polluted by agricultural and municipal wastewater. The hydrogeochemical analysis reveals high pollution levels by Pb, Cd, and Cr for most of the collected shallow groundwater samples nearby the drain. Additionally, NO3-, fecal and total coliform bacteria were observed in many samples with high concentrations. Six factors were distinguished on the basis of principal component analysis and varimax rotation, with total variance more than 78%. These factors reflected sewage contamination, lithogenic and anthropogenic effects on the shallow groundwater. Hierarchical cluster analysis revealed two main clusters of groundwater groups. Accordingly, Electrical Resistivity Tomography (ERT) was carried out in the areas of the distinguished clusters to locate potential preferential flow paths and horizons of lateral flow around the drain. The obtained resistivity models illustrate breakthrough behavior in parts of the measured profiles due to the presence of permeable paths close to the drain. The applied integrative approach is valuable for understanding the ambiguities during the interpretation process and for characterizing water quality and the aquifer vulnerability conditions. Additionally, it may guide to understand the surface water-groundwater links in order to supply the growing population with safe water.

Wadi El Raiyan depression represents a discharge area of excess wastewater from the Faiyum province. It comprises two lakes: the upper lake connects the lower one through a channel. The intensive agriculture in the area hazardously affects both lakes. To assess the status of these lakes, this work studies the change detection using image classification and post-classification comparison, physicochemical parameters, concentration of trace elements, and microbiological contents. The classified images indicate a maintained constant area of the upper lake from 1990 to 2012 and decreased by 1.6% in 2014. The lower lake area increased by 4.8% between 1990 and 2001, then decreased till 2014 and increased again by 8.4% in 2015. The change detection concluded that the lake could be disappeared by 2019 if the exploitation of water from the upper lake continues, or the lake could be rebounded if the government planned to increase the recharge. The factor analysis implies that the total Fe, Mn, Ni, Ba, and As are controlled by pH–Eh relationship, Cu by TDS, Pb by temperature, while Cd is attributed to anthropogenic factor. The upper and lower lake samples exhibit biological oxygen demand (BOD) and chemical oxygen demand (COD) values lower than fish farm samples. The high BOD and COD values were coupled by high nitrate contents in the studied water samples. The cultivated land drains and the fish farms samples have total coliform (TC) and fecal coliform (FC) higher than the samples collected from the upper lake.