4.
1 Chemical Energy and ATP
      CHEMICAL ENERGY AND ATP
4.1 Chemical Energy and ATP
  GUIDE QUESTIONS:
  1. WHAT IS AN ATP?
  2. WHAT IS THE USE OF AN ATP?
  3. HOW DO WE FORM AN ATP?
4.1 Chemical Energy and ATP
 KEY CONCEPT
  The cells of all organisms need chemical energy to carry
  out their life sustaining processes.
4.1 Chemical Energy and ATP
  What do the cells need chemical energy for?
•To move
•To reproduce
•To grow
•To actively transport materials across the cell
membrane
   (Ex. Endocytosis, exocytosis, sodium-potassium
pumps)
•To carry out chemical reactions –Activation Energy
  Ex. Photosynthesis, respiration , All metabolism
4.1 Chemical Energy and ATP
Energy is stored in Food Molecules
•Chemical E is stored in the organic molecules
  found in food.
4.1 Chemical Energy and ATP
• Carbohydrates and lipid molecules are the most
  important energy containing molecules in foods
  we eat.
4.1 Chemical Energy and ATP
4.1 Chemical Energy and ATP
     1. AUTOTROPHS –
  MAKE THEIR OWN FOOD MOLECULES
USING ENERGY AND CARBON DIOXIDE
(CO2) gas FROM THE ENVIRONMENT
*
4.1 Chemical Energy and ATP
         2 Groups of Autotrophs
  • Photoautotrophs           • Chemoautotrophs
4.1 Chemical Energy and ATP
Photoautotroph – use light E to make
their food through Photosynthesis
 CyanoBacteria   Protists (Algae)   Plants
4.1 Chemical Energy and ATP
  Chemoautotrophs use chemical E
  to make their food through
  Chemosynthesis
  Ex. Archaebacteria
4.1 Chemical Energy and ATP
           Autotrophs make the
  organic compounds that serve as
  food for themselves and all other
  organisms on Earth
4.1 Chemical Energy and ATP
2. Heterotrophs –
Organisms that eat other organisms (or
their products) to obtain energy and
carbon compounds
                • Animals
                • Fungus
                • Some Protists
                • Most Bacteria
4.1 Chemical Energy and ATP
  Are We Autotrophs or Heterotrophs?
4.1 Chemical Energy and ATP
       Autotroph or Heterotroph?
4.1 Chemical Energy and ATP
Law of Conservation of Energy
Energy cannot be created or destroyed
but it can be changed from one form to
another
4.1 Chemical Energy and ATP
      Energy Transformations that
              Support Life
4.1 Chemical Energy and ATP
Two processes are needed to
convert the sun’s light energy into
chemical energy the cell can use.
                 PHOTOSYNTHESIS
                         and
               CELL RESPIRATION
4.1 Chemical Energy and ATP
In photosynthesis, sunlight E is transformed
into chemical E stored in food molecules
                    Starch
                    Glucose
4.1 Chemical Energy and ATP
 In cell respiration, the chemical E stored in
food molecules is released and repackaged
into high energy molecules called ATP the
cells can use.
4.1 Chemical Energy and ATP
What happens to the E released from
food in cellular respiration?
    It is used to make high energy
molecules called
                 ATP
4.1 Chemical Energy and ATP
What is ATP?
ATP stands for the molecule
     Adenosine Triphosphate
4.1 Chemical Energy and ATP
• ATP is a high energy containing molecule used
  by all cells to carry out cellular functions..
• Sodium-Potassium Pump
• Muscle contraction
4.1 Chemical Energy and ATP
                  ATP – ADP
                               adenosine    triphosphate
ATP – Adenosine Triphosphate
                                adenosine   diphosphate
 ADP – Adenosine Diphosphate
4.1 Chemical Energy and ATP
           The ATP – ADP cycle
ATP –High energy molecule ADP –Low energy molecule
                                  phosphate removed
4.1 Chemical Energy and ATP
  • When ATP loses a phosphate molecule it gives
    off E and becomes ADP.
  • The E given off is used to power chemical
    reactions in the cell
4.1 Chemical Energy and ATP
  • When ADP gains E and a phosphate molecule,
    it becomes “recharged” to form ATP.
  • The E source to “recharge” ADP comes from
    the breakdown of food through respiration.
4.1 Chemical Energy and ATP
  • This process is called the
          ATP – ADP Cycle
4.1 Chemical Energy and ATP
Removing a Phosphate - Release Energy “use the battery”
           ATP          Energy + P + ADP
Adding a Phosphate – Stores Energy “recharge battery”
             ADP + Energy + P         ATP
4.1 Chemical Energy and ATP
  This is constantly occuring in every
  cell of your body, millions of times
               a minute!
• The E given off is used to power every
  chemical reaction occuring in the cell
4.1 Chemical Energy and ATP
                 ATP to ADP
 Recharging your body’s batteries
4.1 Chemical Energy and ATP
4.1 Chemical Energy and ATP
        Where does ATP come from?
  • ATP comes indirectly from the food that we
    eat.
  • Molecules of carbohydrates (glucose) and
    lipids are broken down through the process of
    cellular respiration to produce ATP.
4.1 Chemical Energy and ATP
  An ATP Molecule is composed of the following:
  •A Nitrogenous Base – Adenine
  •A Sugar – Ribose
  •Three phosphate groups
4.1 Chemical
13.1 Ecologists
             Energy
                Studyand
                      Relationships
                         ATP
              ATP-ADP Cycle
4.1 Chemical Energy and ATP
                  ATP-ADP Cycle
  • Transformation of Energy
    – Energy is the ability to do work.
    – Thermodynamics is the study of the flow and transformation
      of energy in the universe.
4.1 Chemical Energy and ATP
                 ATP-ADP Cycle
  • Laws of Thermodynamics
    – First law - Energy can be converted from one form to another,
      but it cannot be created nor destroyed.
    – Second law - Energy cannot be converted without the loss of
      usable energy.
4.1 Chemical Energy and ATP
                  ATP-ADP Cycle
  • ATP – ADP Cycle
    – ATP (Adenosine Triphosphate) transfers energy from the
      breakdown of food molecules to cell functions
    – Energy is released when a phosphate group (Pi) is removed
    – ADP (Adenosine Diphosphate) is changed into ATP when a
      phosphate group (Pi) is added
4.1 Chemical Energy and ATP
             ATP-ADP Cycle
  • ATP – ADP Cycle
4.1 Chemical Energy and ATP
                 ATP-ADP Cycle
  • Carbohydrates
    – Carbohydrates are the molecules most commonly broken down
      to make ATP.
       – not stored in large amounts
       – up to 36 ATP from one glucose molecule
4.1 Chemical Energy and ATP
                  ATP-ADP Cycle
  • Lipids
    – Lipids store the most energy.
       – 80 percent of the energy in your body
       – About 146 ATP from a triglyceride
4.1 Chemical Energy and ATP
                  ATP-ADP Cycle
  • Proteins
    – Proteins are least likely to be broken down to make ATP.
       – amino acids not usually needed for energy
       – about the same amount of energy as a carbohydrate
4.1 Chemical Energy and ATP
             ATP-ADP Cycle
4.1 Chemical Energy and ATP
        Chemical Structure of ATP
                        Adenine Base
     3 Phosphates        Ribose Sugar
4.1 Chemical Energy and ATP
    How Do We Get Energy From ATP?
4.1 Chemical Energy and ATP
               ADP-ATP Cycle
  • Cells break phosphate bonds between the last
    two phosphate groups in a molecule of ATP as
    needed to supply energy for most cellular
    functions, when this happens a molecule of
    ADP (adenosine diphosphate) and a
    phosphate become available for reuse.
4.1 Chemical Energy and ATP
               ADP-ATP Cycle
  When any of the phosphate bonds are broken or
    formed, energy is involved.
  • Energy is released each time a phosphate is
    removed from the molecule.
  • Energy is stored each time a phosphate
    attaches to the molecule.
4.1 Chemical Energy and ATP
                ADP-ATP Cycle
  • To constantly supply the cell with energy, the
    ADP is recycled, creating more ATP which
    carries much more energy than ADP.
4.1 Chemical Energy and ATP
        Steps in the ADP-ATP Cycle
  • To supply cells with energy, a “high energy”
    bond in ATP is broken. ADP is formed and a
    phosphate is released back into the
    cytoplasm.
  ATP      ADP + phosphate + energy
4.1 Chemical Energy and ATP
        Steps in the ADP-ATP Cycle
   • As the cell requires more energy, ADP
     becomes ATP when a free phosphate
     attaches to the ADP molecule. Then energy
     needed to create an ATP molecule is much
     less than the amount of energy produced
     when the bond is broken.
    ADP + phosphate + energy          ATP
4.1 Chemical Energy and ATP
        How is the bond broken?
          HYDROLYSIS (Adding H2O)
       Assisted by the enzyme ATPase.
H 2O
4.1 Chemical Energy and ATP
       How Does That Happen?
 An
 Enzyme!
4.1 Chemical Energy and ATP
           The ADP-ATP Cycle
                              ATP
 ATP-ase                      Synthetase
4.1 Chemical Energy and ATP
          How is ATP Re-Made?
   The reverse of the previous process
    occurs.
    Another Enzyme is
    used!
    ATP Synthase
4.1 Chemical Energy and ATP
   APPLICATION: EXPLAIN THE DIAGRAM
                              phosphate removed