Solution
Solution
1001CJA106216250183 JA
PART-1 : PHYSICS
SECTION-I (i)
1) A block lying on a smooth surface with spring connected to it is pulled by an external force as
shown. The velocity of ends A and B of the spring are 4 m/s and 2 m/s respectively. If the energy of
the spring is increasing at the rate of 20 J/sec, then the stretch in the spring is :-
(A) 1.0 cm
(B) 2.0 cm
(C) 10 cm
(D) 20 cm
2) Ignoring the gap between pulley & ceiling find the speed V of particle of mass 'm' fixed on the
(A)
(B)
(C) V = u sin (α + β)
(D) V = u cos (α + β)
3) A smooth rod is fixed at an angle α with respect to the horizontal. A little ring of mass m can slide
along the rod, to which a long thread is attached. A small sphere of mass M is attached to the
thread. Initially the ring is held motionless, and the thread hangs vertically. What is the acceleration
(A)
(B)
(C)
(D)
4) A homogeneous disk was spun around its axis to an angular velocity of ω and placed on the
boundary between two horizontal half-planes so that its center was exactly on the boundary (see
figure; top view). The coefficient of friction between the disk and one half-plane is k, and between
the disk and the other half-plane is 2k. Find the acceleration of the center of the disk immediately
(A)
(B)
(C)
(D)
SECTION-I (ii)
1) To study the variation of velocity in some motion, the velocity vectors at different times in the
given motion are drawn from the same initial point, with their lengths proportional to the
magnitude. In which of the following cases the curve joining the final ends of the velocity vectors is a
circle?
2) In a smooth ring-shaped trough located in a vertical plane there is a small ball. The ball, which is
in a position of equilibrium, is given such a horizontal velocity that after breaking away from the
trough at a certain point it falls onto the trough at the starting point (see Fig.).
(A) 0
The initial velocity v is .
(B)
The velocity at the instant the ball breaks away from the trough is .
(C)
The maximum height reached by the ball from the initial position is .
(D) The angle made by velocity vector with vertical when breaking away from the trough is 60°.
3) A weightless, inextensible thread thrown over a pulley is attached to a load of mass m located on
a smooth horizontal surface. A boy pulls the horizontal end of the thread with a constant speed u. At
some instant, the inclined section of the thread makes an angle α with the horizontal? The pulley is
at a height h, the dimensions of the block and the pulley can be neglected. The acceleration of
gravity is g. Consider only the motion of the block before it lifts off the surface. The middle point of
the string between the block and the pulley (not a fixed point on the string) is P0
(A)
'P' is moving horizontally with speed .
(B)
The tension in the string at the given instant is .
(C) The magnitude of acceleration of the block is increasing.
(D) The normal acceleration of the block is zero.
SECTION-I (iii)
1) Consider the given system in which two blocks connected by ideal string and pulley system placed
in lift, which is moving upward with an acceleration of m/s2 as shown in figure. Mass of blocks A &
B are 0.1 kg each & friction coefficient between floor & block A is . Then match the list I
2
against list II. (g = 10 m/s ). All units are in S.I. All are at rest at t = 0. (All strings and pulleys are
ideal)
List-I List-II
(5) 4
(A) P → 1;Q → 2;R → 3;S → 5
(B) P → 1;Q → 4;R → 2;S → 3
(C) P → 4;Q → 3;R → 5;S → 3
(D) P → 1;Q → 3;R → 5;S → 4
2) Assume all pulleys to be massless and smooth. Match the following. ('x' represents unknown
(Q) If x = m (2)
Tension
(S) If x = 2m (4)
Tension
3) Three masses are kept as shown in figure. Assume all surfaces to be smooth. Just after system is
List-I List-II
(5) Zero
(A) P → 2;Q → 3;R → 4;S → 1
(B) P → 2;Q → 1;R → 4;S → 3
(C) P → 1;Q → 4;R → 3;S → 2
(D) P → 1;Q → 2;R → 3;S → 5
4) P, Q, R, S are four blocks, T is a big block supporting all of the smaller blocks as shown in the
figure. Assume all pulleys to be ideal & surfaces smooth. If system is released from rest then answer
the following.
List-I List-II
(5)
SECTION-II
1) In a rectangular box, a ball bounces elasticity back and forth along the same trajectory, hitting
the left wall and the bottom at points a and b from the bottom corner of the box. The distance of a
from the common corner is 3m and that of b is 4m. What is the time (in sec) between successive
2) The ball rotates with a frequency ν = 0.7 s−1 around a vertical axis passing through its centre. A
thread with a small body is attached to the top point of the ball (see figure). The length of the thread
is equal to a quarter of the circumference of the large circle of the ball. 2/3 of the length of the
thread is in contact with the surface of the ball. The radius of the ball is . Find N.
(g = 10 m/s2, π = )
4) At the left edge of a cart of length L = 0.25 m and mass M = 1 kg lies a cube of mass m = 0.25 kg
(see fig.). The cube is given a horizontal velocity v0 = 1 m/s to the right by pushing it, while the cart
is initially stationary. Determine at what distance from the left edge of the cart the cube will be after
it stops sliding relative to the cart. The coefficient of friction of the cube on the bottom of the cart is
μ = 0.1. The impacts of the cube on the walls are considered to be absolutely elastic. The cart moves
5) A long wire is wound into a spiral of radius R with a pitch h (Fig.). The axis of the spiral is located
vertically. A bead slides along the spiral; the coefficient of friction between the wire and the bead is
µ. Find the square of steady-state speed v2 of the bead. (Given h/R = 5π/2 and µ = 3/4. Also, square
of radius R is (9/164) m2, g = 10m/s2)
6) If a spring block system is kept on a rough horizontal surface with one end of spring fixed. The
block could stay in equilibrium up to a maximum elongation of e. If the block is pulled by 5.5e and
released, the total work done by friction till the block eventually stops is 5Nke2, where k is the spring
constant. Find the nearest value of integer N.
PART-2 : CHEMISTRY
SECTION-I (i)
(A)
(B) ClO2 , NO2
(C) S2 , O2
(D) ClO2 , O2
Except one , all the salt have –ve oxidation state of nitrogen in cation and +ve oxidation state of
(A)
nitrogen in anion.
(B) All the salts have at least one Nitrogen in tetrahedral geometry.
(C) All the salts have at least one nitrogen in triangular planar geometry.
(D) Average oxidation number of nitrogen is lowest in (R) & highest in (U)
SECTION-I (ii)
1) For second period homonuclear diatomic molecules, both 2s and 2p orbitals are used in the
formation of molecular orbitals. The shape of the molecular orbitals are identified by linear
combination of atomic orbitals, followed by normalisation of wavefunction and then taking the
square of the wavefunction.
Select the CORRECT statement(s) about homonuclear diatomic molecules of 2nd period.
Six 2p atomic orbitals form a σb and σ* pair and two doubly degenerated πb & π* molecular
(A)
orbitals are present.
σ bonding molecular orbitals are characterised by the absence of nodal plane perpendicular
(B)
to internuclear axis between the two nuclei.
π-bonding molecular orbital have a nodal plane along bond axis and another nodal plane
(C)
perpendicular to the nodal plane between the two nuclei.
(D) The order of bond length & bond strength is just reverse in N2, C2 and F2
2) When halogen reacts with hydrogen they produces hydrogen halide, hydrogen halide dissolve in
water to produce hydrohalic acid.
Select which is/are CORRECT for hydrogen halides / hydrohalic acid.
Hydrogen halides are colorless diatomic gases at room temperature but HF is hydrogen bonded
(A)
oligomer low boiling colorless liquid (293 K).
HCl gas have lowest melting point & boiling point, and reaction of HClaq. with iron proceeds to
(B)
FeCl3 & H2
(C) The of gaseous HX diminish rapidly with increasing molecular weight and for HI it is
endothermic
(D) The thermal stability and boiling point change regularly on moving from Fluorine to Iodine.
SECTION-I (iii)
List-II
List-I
(Surface tension in J/m2 and Dominant
(Liquid)
intermolecular forces)
2) Following question is based on inorganic reactions (List-I) and the result(s) of reactions (List-II)
Find the correct code of your answer.
List-I List-II
(Reaction) (Results)
(Q) H3PO3 + PCl3 (2) Yellowish white powder which is moist in air
(R) Pt with aqua regia (3) Deep red fumes with clear solution
3) Use given information to solve given matching type question and find correct code of your
answer.
The vigorous fluorinating activity of an interhalogen compound [X] i.e. BrF5 is demonstrated by
reaction with silicate [K] i.e. KAlSi3O8
KAlSi3O8 + BrF5 [L] + [M] + [N] + [O] + O2 ↑
If [L] , [M] , [N] and [O] all are binary fluoride compounds and atomic number of atom in fluorides
is changed as L > M > N > O
List-I
List-II
(Binary
(Characteristics / Specification of Binary
fluoride
fluoride)
compound)
List-I
List-II
(Substance)
SECTION-II
Identify all the gases (1 to 6) and calculate the sum of bond order(s) in (Gas-1) + (Gas-2) + (Gas-3)
+ (Gas-4) + (Gas-5) + (Gas-6)
2) Given silicone molecule (where n = 25) is prepared by hydrolysis & condensation of methyl
substituted chlorosilanes.
Let :-
P = Number of molecules of dimethyl chlorosilanes required
Q = Number of molecules of trimethyl chlorosilanes required
R = Total number of HCl molecules formed during reaction.
S = Total number of Si–O–Si bonds in given molecule.
Find the value of P + Q + R + S ?
4) An impure white solid sample which contain Calcium chloride , Calcium hypochlorite, Calcium
hydroxide & some water of crystalization. That impure solid is widely used as an oxidizing agent in
Textile mills, Looms , Hosiery laundry and Organic synthesis.
Find the number of CORRECT statement(s) for the given impure solid sample.
1. Have chlorine with oxidation number = +1
2. Have chlorine with oxidation number = –1
3. Produce red color on Bunsen burner flame
4. The oxo anion of given salt produces & Cl– on disproportionation
5. Produces I2 when react with KI in acidic solution
6. In Moist air produces pungent smelling gas
7. It can decolorize moist litmus paper
8. It is used to disinfects water
9. ClO2 is the anhydride of that oxyacid whose anion present in given salt
6) If the reaction sequence given below is carried out with 80 gm of Rhombic sulphur, the amount of
white solid formed finally (in gm) is.
(Ignore all the values after decimal place in final answer) :-
The % yield of [X] , [Y] , [Z] and the final product white solid is given in parentheses
[Atomic mass of H = 1 , C = 12 , O = 16 , Cl = 35.5 , S = 32 , Ba = 137 , N = 14]
PART-3 : MATHEMATICS
SECTION-I (i)
(A) 0
(B) 1
(C) 2
(D) 4
2) Let a relation R on the interval is defined as x R y if and only if sec2x – tan2y = 1. Then R is :
(A)
(B)
(C)
(D)
(A)
(B)
(C)
(D)
SECTION-I (ii)
1) Let f(x) = sin(cos–1(tan(cos–1x))). If α be a real solutions of the equation f(f(x)) = f(x), then the value
of can be -
(where [.] is greatest integer function)
(A) 1
(B) 0
(C) –1
(D) 2
SECTION-I (iii)
1)
List-I List-II
2)
List-I List-II
(Q) (2) 2
is
(Where [.] is greatest integer function)
3)
List-I List-II
(P) (1) 2
is equal to
(Q) (2) 4
Value of where θ = 18° is equal to
(S) (4) 6
The absolute value of is
(5) 3
(A) P → 1;Q → 3;R → 5;S → 2
(B) P → 5;Q → 3;R → 4;S → 2
(C) P → 4;Q → 1;R → 2;S → 3
(D) P → 3;Q → 4;R → 1;S → 5
4)
List-I List-II
1) Given that f(x) is a function defined on (–∞,∞) satisfying f(1) = 5 and for any x ∈ (–∞,∞), f(x + 5) >
f(x) + 5
and f(x + 1) ≤ f(x) + 1. If g(x) = 2f(x) + 9 – 2x, then g(2025) is
5) If range of the function ƒ(x) = tan–1(3x2 + (k – 1)x + 3) is for x ∈ R, then the sum of all
possible real value(s) of k, is
PART-1 : PHYSICS
SECTION-I (i)
Q. 1 2 3 4
A. C A B A
SECTION-I (ii)
Q. 5 6 7
A. B,C,D A,B A,C,D
SECTION-I (iii)
Q. 8 9 10 11
A. B A A A
SECTION-II
Q. 12 13 14 15 16 17
A. 1 3 2 2 5 3
PART-2 : CHEMISTRY
SECTION-I (i)
Q. 18 19 20 21
A. A D C C
SECTION-I (ii)
Q. 22 23 24
A. A,B,D A,C A,B
SECTION-I (iii)
Q. 25 26 27 28
A. D D D B
SECTION-II
Q. 29 30 31 32 33 34
A. 11 205 7 8 23 419
PART-3 : MATHEMATICS
SECTION-I (i)
Q. 35 36 37 38
A. C A B B
SECTION-I (ii)
Q. 39 40 41
A. B,C A,B,C A,B,C,D
SECTION-I (iii)
Q. 42 43 44 45
A. A B B A
SECTION-II
Q. 46 47 48 49 50 51
A. 17 16 0 4 2 59
SOLUTIONS
PART-1 : PHYSICS
1)
= kx·vrel
20 = Fℓp × 2
⇒ Fℓp = 10 N
2) V cos θ = u
α + β + 90° + θ = 180°
3)
Mg – T = Ma sin α ...(1)
Ring along the Rod
mg sin α + T sin α = ma ...(2)
a1 = a sin α
4)
df = µdN
(down)
(up)
So, (up)
5)
(b) Circle
6)
As 3α = 180°
α = 60°
Angle of v with horizontal is 60°
maximum height
7)
x2 + h2 = ℓ2
xv = ℓv ⇒ v = usec α.
xa + v2 = u2
8)
In frame of lift
f = 0.5 N
1.5 – f = 2 mar along the string
⇒ ar = 5 m/s2
⇒ T = 1N
aAy = 0
SAy = 0
WA = 0 WB = 2N
9)
4m = 3m + 3x
3x = m
T – xg = x × 2a – (1) × 2
mg – 2T = ma...(2)
mg – 2xg = (4x + m)a
Case-I : ,a=0
Case-II : x = m,
Case-III : ,
Case-IV : x = 2m
10)
2ax = 3ax ...(1)
ay = ax + ax
...(2)
For (m + 2m)
⇒ 3 mg – N cos θ = 3 may ....(3)
For 3m
N sin θ = 3 max ...(4)
6 mg – 2N cos θ = 5N sin θ
...(2)
For 2m, 2mg + 2ma = 4ma2
...(3)
19a = g
a12 = a1 + a2 = g
12)
= 1 sec
13)
T sin 60° = mg
T cos 60° = mω2r
where
14)
mgsinα·x – µmgcosα·x = k
= – 2J
15)
16)
Then
So,
17)
The block oscillates with shifted mean position.
Total distance = (5.5e + 3.5e) + (3.5e + 1.5e) + (1.5e – 0.5 e)
= 15 e
So, Wf = –(15e) · (ek)
PART-2 : CHEMISTRY
18) (I)
(II)
(III)
(IV)
19)
20)
21)
22)
24)
25)
26)
27)
28)
30) P = 50
Q=2
R = 102
S = 51
2(CH3)3SiCl + m(CH3)2SiCl2 + (2m+2)H2O
→ (2m+2)HCl + m(CH3)2Si(OH)2 + 2(CH3)3SiOH
31)
32)
34)
PART-3 : MATHEMATICS
35)
36) sec2x – tan2x = 1 (on replacing y with x)
⇒ Reflexive
sec2x – tan2y = 1
⇒ 1 + tan2x + 1 – sec2y = 1
⇒ sec2y – tan2x = 1
⇒ symmetric
sec2x – tan2y = 1,
sec2y – tan2z = 1
Adding both
⇒ sec2x – tan2y + sec2y – tan2 z = 1 + 1
sec2x + 1 – tan2z = 2
sec2x – tan2z = 1
⇒ Transitive
hence equivalence relation
37) Note that sin(α + β) = sinα cosβ + cosα sinβ = + cosα sinβ.
Similarly, because sin(α – β) = sinα cosβ – cosα sinβ, we conclude that ≤ cosα sinβ < .
38)
sin(1 – x) = cosx
cosx – cos
(negative), x = (rejected)
(least positive)
39) &
∴
given f(f(x)) = f(x)
∴
Let x2 = t ⇒ 2t – 1 =
⇒ t = 1 or –1 (reject)
∴ x2 = 1
⇒ x = 1 or –1
40)
∵ g(α+1, β) = g(α, β) + α
∴ g(x, y) = g(x–1, y) + (x – 1)
= g(x–2, y) + (x – 2) + (x – 1)
= g(x–3, y) + (x – 3) + (x – 2) + (x – 1)
...(1)
Now, ∵ g(α, β+1) = g(α, β) – β
g(1, y) = g(1, y–1) – (y – 1)
= g(1, y–2) – {(y – 2) + (y – 1)}
...(2)
from (1) and (2)
⇒ (x – y)(x + y – 1) = 2 × 1999
⇒ (x, y) ≡ (1001, 999)
or
≡ (2000, 1999)
42)
(P)
function is periodic but fundamental period can't be determined
(Q)
(R)
⇒
∴ f(x) is periodic with period π
43)
(P) [cos2x] = 0
⇒ 0 ≤ cos2x < 1
so, f(x) = sin2x
Range ≡ (0, 1]
(Q) sin–1[x] is defined if
–1 ≤ x < 2
but
Domain ≡ [–1, 0)
(R) 4 – |x| = (2π)–|x|
(S) if x ∈ I
|log3|x + 1|| = 8
⇒ |x + 1| = 38 or |x + 1| = 3–8
↓ ↓
Two integral sol. Two non integral sol. (rejected)
if x ∉ I
|log3|x + 1|| = 7
⇒ |x + 1| = 37 or |x + 1| = 3–7
↓ ↓
Two integral sol. Two non integral sol.
(rejected)
Number of solutions = 4
44)
(P)
=4–1=3
(Q) 2α + 3α = 90°
⇒ cos(2.3r–1α) = cos(90.3r–1 – 3rα)
if r is odd then cos(2.3r–1α) = sin(3rα)
if r is even then cos(2.3r–1α) = –sin(3rα)
⇒
(R) A = B = C = 60°
(S) Let
Now
The value of the product is 4
45)
(P)
ƒ(x) is many one, is neither odd nor even in [–2,2]
(Q)
range contains at least one integer but not more than 3 integers.
ƒ(x) is many one, bounded and neither odd nor even.
(R)
(S) ƒ(x) = |x| + [x]2
is many one and neither odd nor even
46)
f(x + 1) ≤ f(x) + 1
⇒ f(x + 5) ≤ f(x + 4) + 1
≤ f(x + 3) + 2
≤ f(x + 2) + 3
≤ f(x + 1) + 4
⇒ f(x + 5) ≤ f(x) + 5 ...(1)
and given
f(x + 5) ≥ f(x) + 5 ...(2)
equality must be held everywhere
f(1), f(2), f(3), . . . A.P.
⇒ 5, 6, 7, . . .
f(2025) = 2029
g(2025) = 2f(2025) + 9 – 2(2025)
g(2025) = 2017
47)
⇒ ⇒
48) 2x2 + (3x – 2)2 + 8 + 12cot2(πx) + 13sec2 + 9 tan2
x∈ϕ
49)
Let
⇒Q=4
p=2
51) f(x) =
f(x) =
f(x) =
f(4 – x) =
f(x) + f(4 – x) =
Aliter :
⇒ f(x) + f(4 – x) =
Now
= 58 + 1 = 59