28-08-2025

1902CJA101001250095 JA

PART-1 : PHYSICS

SECTION-I

1) The drawing shows a thin, uniform rod that has a length of 0.45 m and a mass of 0.09 kg. This rod
lies in the plane of the paper and is attached to the floor by a hinge at point P. A uniform magnetic
field of 0.36 T is directed perpendicularly into the plane of the paper. There is a current I = 4.0 A in
the rod, and rod does not rotate clockwise or counterclockwise. Find the angle θ.

(A) cos–1(0.36)
(B) cos–1(0.72)
(C) cos–1 (0.46)
(D) cos–1 (2/3)

2) The circuit shown has been operating for a long time. The instant after the switch in the circuit
labeled S is opened, what is the voltage across the inductor VL and which labeled point (A or B) of
the inductor is at a higher potential ? Take R1 = 4.0 Ω, R2 = 8.0 Ω, and L = 2.5 H.

(A) VL = 12 V ; Point A is at the higher potential

(B) VL = 12 V ; Point B is at the higher potential
(C) VL = 6V ; Point A is at the higher potential
(D) VL = 6V ; Point B is at the higher potential

3) In the circuit shown, the capacitor is initially charged with a 12 V battery, when switch S1 is open
and switch S2 is closed. S1 is opened. The maximum value of current in the circuit is,
(A) 10–6 A
(B) 7.2 μA
(C) 720 μA
(D) 360 μA

4) In the circuit shown below, the key K is closed at t = 0. If the current through the battery at t = 0

is I1 and t → ∞ is I2 then find

(A)

(B)

(C) 1

(D)

5) Current growth in two L-R circuits (B) and (C) as shown in figure (A). Let L1, L2, R1 and R2 be the
corresponding values in two circuits. Then

(A) (B) (C)

(A) R1 > R2
(B) R1 = R2
(C) L1 > L2
(D) L1 < L2

6) A rectangular loop has a sliding connector PQ of length ℓ and resistance RΩ and it is moving with
a speed v as shown. The set-up is placed in a uniform magnetic field going into the plane of the

paper. The three currents I1, I2 and I are :-

(A)
I1 = I2 = ,I=

(B)
I1 = – I2 = ,I=

(C)
I1 = I2 = , I=

(D)
I1 = I2 = I =

7) An infinitely long straight wire carrying current I, one side opened rectangular loop and a
conductor C with a sliding connector are located in the same plane, as shown in the figure. The
connector has length l and resistance R. It slides to the right with a velocity v. The resistance of the
conductor and the self inductance of the loop are negligible. The induced current in the loop, as a
function of separation r, between the connector and the straight wire is :

(A)

(B)

(C)

(D)

8) Consider a square loop of wire with dimension a. One side of which is parallel to another long
straight wire carrying current i0, at a distance a. The resistance of the loop is R. Neglect the self
inductance of the loop. Initially switch S was closed and at t = 0 it is opened.
 What is the net amount of charge that will flow after t = 0 through a fixed
cross-section of the wire of the loop?

(A)

(B)

(C)

(D)

9) A wooden block floating in a bucket of water has of its volume submerged. When certain
amount of an oil is poured into the bucket, it is found that the block is just under the oil surface with
half of its volume under water and half in oil. The density of oil relative to that of water is :-

(A) 0.5
(B) 0.7
(C) 0.6
(D) 0.8

10) To what height h should a cubical vessel of side a should be filled with a liquid so that total force

on the vertical face of vessel is of force on the bottom? (Neglect atmospheric pressure)

(A)

(B)

(C)

(D)

11) Pressure at the bottom of a tank of water is 3P, where P is atmospheric pressure. If the water is
drawn out till the level of water is lowered by one fifth, then the pressure at the bottom of the tank is
:

(A) 2P
(B)

(C)

(D)

12) The power emitted per unit area of a black body is R watt/m2. At what wavelength will the power
radiated by the black body be maximum. If the Stefan’s constant is and Wien’s constant is b, then:

(A)

(B)

(C)

(D)

13) A small circular loop of conducting wire has radius a and carries current I. It is placed in a
uniform magnetic field B perpendicular to its plane such that when rotated slightly about its
diameter and released, it starts performing simple harmonic motion of time period T. If the mass of
the loop is m then:

(A)

(B)

(C)

(D)

14) A cylindrical vessel of cross-section A contains water to a height h. There is a hole in the bottom
of radius 'a'. The time in which it will be emptied is:

(A)

(B)

(C)

(D)
15)
The region between y = 0 and y = d contains a magnetic field . A particle of mass m and

charge q enters the region with a velocity and from y = d. If d = , the acceleration of the
charged particle at the point of its emergence at the other side is:

(A)

(B)

(C)

(D)

16) An electron is moving along the positive x-axis. If the uniform magnetic field is applied parallel
to the negative z-axis. Then
(a) The electron will experience magnetic force along positive y-axis
(b) The electron will experience magnetic force along negative y-axis
(c) The electron will not experience any force in magnetic field
(d) The electron will continue to move along the positive y-axis
(e) The electron will move along circular path in magnetic field. Choose the correct answer from the
options given below:

(A) (b) and (e) only

(B) (a) to (e) only
(C) (c) and (d) only
(D) (b) and (d) only

17) A velocity selector consists of electric field and magnetic field with B = 12 mT.
The value E required for an electron of energy 728 eV moving along the positive x-axis to pass
undeflected is: [Given, mass of electron = 9.1 × 10−31 kg]

(A) 192 kVm−1

(B) 192 m Vm−1
(C) 9600 kVm−1
(D) 16 kVm−1

18) A straight wire along the z-axis carries a current i in the negative z-direction. The magnetic
vector field at point having coordinate (x, y) on the z = 0 plane is:

(A)
(B)

(C)

(D)

19) There are two identical small holes on the opposite sides of a tank containing a liquid. The tank
is open at the top. The difference in height between the two holes is h. As the liquid comes out of the
two holes, the tank will experience a net horizontal force proportional to :

(A)
(B) h
(C) h3/2
(D) h2

20) A long solenoid has 200 turns per cm and carries i. The magnetic field at its centre is 6.28 x 10−2
weber/m2. Another long solenoid has 100 turns per cm and it carries a current i/3. The value of the
magnetic field at its centre is :

(A) 1.05 x 10−2 weber/m2

(B) 1.05 x 10−5 weber/m2
(C) 1.05 x 10−3 weber/m2
(D) 1.05 x 10−4 weber/m2

SECTION-II

1) Two coils, 1 and 2 have a mutual inductance = M and resistance R each. A current flows in coil 1,
which varies with time as : i1 = kt2, where k is a constant and ‘t’ is time. The total charge that has

flown through coil 2, between t=0 at t=T is Find

2) A time varying magnetic field B = B0r2t is existing in a cylindrical region as shown in figure. If the

induced electric field r = is E1, and at r = 2R is E2. Then ratio of is n × 10–2 Find n.
3) An ideal fluid of density 800 k gm−3, flows smoothly through a bent pipe (as shown in figure) that

tapers in cross-sectional area from a to . The pressure difference between the wide and narrow

sections of pipe is 4100 Pa. At wider section, the velocity of fluid is ms−1 for x =________

[Given: g = 10 ms−2]

4) A charge particle of 2 μC accelerated by a potential difference of 100 V enters a region of uniform

magnetic field of magnitude 4 mT at right angle to the direction of field. The charge particle
completes semicircle of radius 3 cm inside magnetic field. The mass of the charge particle is
_________× 10−18 kg.

5) a water heater of power 2000 W is used to heat water. The specific heat capacity of water is 4200
J kg−1 K−1. The efficiency of heater is 70%. Time required to heat 2 kg of water from 10°C to 60°C
is______s.
(Assume that the specific heat capacity of water remains constant over the temperature range of the
water)

PART-2 : CHEMISTRY

SECTION-I

1) Liquid A and B form an ideal solution. The vapour pressures of pure liquids A and B are 350
and 750 mm Hg respectively at the same temperature. If xA and xB are the mole fraction of A and B
in solution while yA and yB are the mole fraction of A and B in vapour phase then,

(A)

(B) (xA − yA) < (xB − yB)

(C)

(D)

2) Concentrated nitric acid is labelled as 75% by mass. The volume in mL of the solution which
contains 30g of nitric acid is____________
(Given, density of nitric acid solution is 1.25 g/mL.)

(A) 32
(B) 55
(C) 45
(D) 40

3)
The freezing point depression of a 0.1 in aqueous solution of a monobasic weak acid HA is 0.20 oC.
The dissociation constant for the acid is :
Given, Kf(H2O) = 1.8 K kg mol−1, molality ≡ molarity

(A) 1.90 x 10−3

(B) 1.89 x 10−1
(C) 1.1 x 10−2
(D) 1.38 x 10−3

4) CrCℓ3 ∙ xNH3 can exist as a complex. 0.1 molal aqueous solution of this complex shows a
depression in freezing point of 0.558°C. Assuming 100% ionisation of this complex and coordination
number of Cr is 6, the complex will be (Given, K = 1.86 K kg mol−1)

(A) [Cr(NH3)3 Cℓ3]

(B) [Cr(NH3)4 Cℓ2] Cℓ
(C) [Cr(NH3)6] Cℓ3
(D) [Cr(NH3)5 Cℓ] Cℓ2

5) A conductivity cell with two electrodes (dark side) are half-filled with infinitely dilute aqueous
solution of a weak electrolyte. If volume is doubled by adding more water at constant temperature,
the molar conductivity of the cell will

(A) depend upon type of electrolyte

(B) decrease sharply
(C) increase sharply
(D) remain same or can not be measured accurately

6) One of the commonly used electrode is calomel electrode. Under which of the following
categories, calomel electrode comes?

(A) Gas- ion electrodes

(B) Oxidation-reduction electrodes
(C) Metal- insoluble salt-anion electrodes
(D) Metal ion-metal electrodes

7) The standard cell potential of a fuel cell based on the oxidation of methanol in air that has
been used to power television relay station is measured as 1.21 V. The standard half cell reduction

potential for O2 is 1.229 V.

Choose the correct statement.

(A)
The standard half cell reduction potential for the reduction of is 19 mV.
(B) Oxygen is formed at the anode
(C) Reactants are fed at one go to each electrode
(D) Reduction of methanol takes place at the cathode

8) Match List-I with List-II.

List-I(Cell) List-II(Use/Property/Reaction)

A. Laclanche cell I. Converts energy of combustion into electrical energy

B. Ni − Cd cell II. Does not involve any ion in solution and is sued in hearing aids

C. Fuel cell III. Rechargeable

D. Mercury cell IV. Reaction at anode Zn → Zn2+ + 2e−

Choose the correct answer from the options given below
(A) A-III, B-I, C-IV, D-II
(B) A-I, B-II, C-III, D-IV
(C) A-II, B-III, C-IV, D-I
(D) A-IV, B-III, C-I, D-II

9) The major product of the following reaction is

(A)

(B)

(C)

(D)

10) Given below are two statements.

Statement I Vanillin will react with NaOH and also with Tollen's reagent.

Statement II Vanillin will undergo self aldol condensation very easily.

In the light of the above statements, choose the most appropriate answer from the options given
below

(A) Statement I is correct but Statement II is incorrect.

(B) Statement I is incorrect but Statement II is correct.
(C) Both Statement I and Statement II are correct.
(D) Both Statement I and Statement II are incorrect.
11) The major product(P) in the following reaction is :

(A)

(B)

(C)

(D)

12) An organic compound (X) with molecular formula C3H6O is not readily oxidised. On reduction it
given C3H8O(Y) which reacts with HBr to give a bromide (Z) which is converted to Grignard reagent.
This Grignard reagent on reaction with (X) followed by hydrolysis give 2,3-dimethylbutan-2-ol.
Compounds (X), (Y) and (Z) respectively are :

(A) CH3COCH3, CH3CH2CH2OH, CH3CH(Br)CH3

(B) CH3COCH3, CH3CH(OH)CH3, CH3CH(Br)CH3
(C) CH3CH2CHO, CH3CH = CH2, CH3CH(Br)CH3
(D) CH3CH2CHO, CH3CH2CH2OH, CH3CH2CH2Br

13) The correct sequence of acidic strength of the following aliphatic acids in their decreasing order
is:
CH3CH2COOH, CH3COOH, CH3CH2CH2COOH, HCOOH

(A) CH3COOH > CH3CH2COOH > CH3CH2CH2COOH > HCOOH

(B) HCOOH > CH3COOH > CH3CH2COOH > CH3CH2CH2COOH
(C) HCOOH > CH3CH2CH2COOH > CH3CH2COOH > CH3COOH
(D) CH3CH2CH2COOH > CH3CH2COOH > CH3COOH > HCOOH

14) The major product 'P' formed in the given reaction is :

(A)

(B)

(C)

(D)

15) The compounds that produce CO2 with aqueous NaHCO3 solution are:
Choose the correct answer from the options given below:

(A) A and B only

(B) A, B and E only
(C) A, C and D only
(D) A and C only

16) The major product 'P' formed in the following sequence of reaction is :

(A)

(B)

(C)
(D)

17) A(g) ⇌ B(g) + , the correct relationship between KP,α and equilibrium pressure p is:

(A)

(B)

(C)

(D)

18) For a reaction

N2O5(g) → 2NO2(g) + O2(g) in a constant volume container, no products were present initially.
The final pressure of the system when 50% of reaction gets completed is

(A) 7/2 times of initial pressure

(B) 7/4 times of initial pressure
(C) 5/2 times of initial pressure
(D) 5 times of initial pressure

19) At temperature T, compound AB2(g) dissociates as AB2(g) ⇌ AB(g) + B2(g) having degree of
dissociation x (small compared to unity). The correct expression for x in terms of KP and P is

(A)

(B)

(C)

(D)

20) Which of the following lines correctly show the temperature dependence of equilibrium constant,
K, for an exothermic reaction ?

(A) A and B
(B) B and C
(C) C and D
(D) A and D

SECTION-II

1) Consider the following electrochemical cell at standard condition.

Au(s) | QH2, Q | NH4 X (0.01 M) | | Ag+ (1 M) | Ag(s) Ecell = +0.4 V
The couple QH2/Q represents quinhydrone electrode, the half cell reaction is given below :

(Given : )
The pKb value of the ammonium halide salt (NH4X) used here is _______(Nearest integer)

2)

The observed and normal molar masses of compound MX2 are 65.6 and 164 respectively. The
percent degree of ionisation of MX2 is _____%. (Nearest integer).

3) Identify the structure of the final product (D) in the following sequence of the reactions :

Total number of sp2 hybridised carbon atoms in product D is_____________

4) Number of compounds from the following which will not dissolve in cold NaHCO3 and NaOH
solutions but will dissolve in hot NaOH solution is_______

5) PCl5 dissociates as
PCl5(g) ⇌ PCl3(g) + Cl2(g)
5 moles of PCl5 are placed in a 200 L vessel which contains 2 moles of N2 and is maintained at 600 K.
The equilibrium pressure is 2.46 atm. The equilibrium constant KP for the dissociation of PCl5 is
_________x 10−3. (Nearest integer)
(Given, R = 0.082 L atm K−1 mol−1; assume ideal gas behaviour).

PART-3 : MATHEMATICS

SECTION-I

1) Let 1 ≤ x ≤ 5. If the range of f is [α, β], then 4 (α + β) equals:

(A) 157
(B) 253
(C) 125
(D) 154

2) The value of is

(A) loge2
(B) 2
(C) 1
(D) e2

3) If the line 3x – 2y + 12 = 0 intersects the parabola 4y = 3x2 at the points A and B, then at the
vertex of the parabola, the line segment AB subtends an angle equal to
(A)

(B)

(C)

(D)

4) Let the parabola y = x2 + px – 3, meet the coordinate axes at the points P, Q and R. If the circle C
with centre at (–1, –1) passes through the points P, Q and R, then the area of ΔPQR is :

(A) 4
(B) 6
(C) 7
(D) 5

5) Let for ƒ(x) = 7tan8x + 7tan6x – 3tan4x – 3tan2x, and . Then 7I1 + 12I2
is equal to :

(A) 2π
(B) π
(C) 1
(D) 2

6) Let be a point on the parabola y2 = 4ax and PQ be a focal chord of the parabola. If M
and N are the foot of perpendiculars drawn from P and Q respectively on the directrix of the
parabola, then the area of the quadrilateral PQMN is equal
to:

(A)

(B)

(C)

(D)

7) If where C is the constant of integration,

then equals:
(A)

(B)

(C)

(D)

8)

Let , where C is the constant of integration.

If , Then α + β − γ equals :

(A) 55
(B) 47
(C) 48
(D) 62

9) Let the shortest distance from (a, 0), a > 0, to the parabola y2 = 4x be 4. Then the equation of
the circle passing through the point (a, 0) and the focus of the parabola, and having its centre on the
axis of the parabola is:

(A) x2 + y2 − 6x + 5 = 0
(B) x2 + y2 − 4x + 3 = 0
(C) x2 + y2 − 10x + 9 = 0
(D) x2 + y2 − 8x + 7 = 0

10) In I(m, n) = then I(9, 14) + I(10, 13) is

(A) I(9, 1)
(B) I(19, 27)
(C) I(1, 13)
(D) I(9, 13)

11) If , then f(1) is equal to:

(A) loge2 + 2
(B) 4(loge2 – 2)
(C) 2 – loge2
(D) 4(loge2 + 2)
12) Let f : R → R be a twice differentiable function such that f(2) = 1. If F(x) = xƒ(x) for all x ∈ R,

and , then is equal to:

(A) 11
(B) 15
(C) 9
(D) 13

13) Let f(x) be a positive function and and . Then the

value of is equal to____________

(A) 9
(B) 6
(C) 12
(D) 4

14) The integral is equal to:

(A) 3 + 2π
(B) 4 + π
(C) 1 + 3π
(D) 2 + 3π

15) Let P be the parabola, whose focus is (–2, 1) and directrix is 2x + y + 2 = 0. Then the sum of
the ordinates of the points on P, whose abscissa is –2, is

(A)

(B)

(C)

(D)

16) The integral is equal to:

(A)

(B)

(C)

(D)

17)

The length of the latus rectum of the parabola 169 {(x + 1)2 + (y − 3)2} = (5x − 12y + 17)2 is :

(A)

(B)

(C)

(D)

18) The value of is:

(A)

(B)

(C)
(D) e

19)

If then is :

(A)

(B)

(C)

(D)
20) The value of is equal to

(A)

(B) π

(C)

(D)

SECTION-II

1) Evaluate

2) If = (α, β, γ ∈
Z), where C is the constant of integration, then α + β + γ is equal to ___________.

3) If where C is
the constant of integration, then α + 2β is equal to ______________

4) Let r be the radius of the circle, which touches x-axis at point (a, 0), a < 0 and the parabola y2 =
9x at the point (4, 6). Then r is equal to __________.

5) If where C is the constant

of integration and m, n ∈ N, then m + n is equal to
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B D C B B C B C C C B D B B B A A A B A

SECTION-II

Q. 21 22 23 24 25
A. 2 25 363.00 144.00 300.00

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C A D D D C A D A A D B B A C C A B C A

SECTION-II

Q. 46 47 48 49 50
A. 6.00 75.00 7.00 3.00 1107.00

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A C D B C C C A A D B A D C A C D C C A

SECTION-II

Q. 71 72 73 74 75
A. 10.5 19.00 16.00 30.00 379.00
 SOLUTIONS

PART-1 : PHYSICS

1)

2)

When switch was is closed

Just after switch is opened we know current in inductor does not change instantaneously.

Voltage across R1 is R1 = 18 volt.

So voltage across inductor = 6 volt & B is at higher potential.

3)

Correct option answer is C

4) At t = 0, current does not flow through inductor.

∴
At t = ∞ ⇒

5)

Correct option answer is B

6)

7) B =

⇒e=

i=

8)

9) In 1st situation
Vbρbg = Vsρwg

...(i)
here Vb is volume of block
Vs is submerged volume of block
ρb is density of block
ρw is density of water
& Let ρo is density of oil
finally in equilibrium condition

Vbρbg =
2ρb = ρ0 + ρw

10) Let h be the length of liquid column

11) 3P = P + hρwg ⇒ hρwg = 2P

when water is drawn out, the pressure at bottom.

12)

13)

Correct option answer is B

14)

Correct option answer is B

15)

Correct option answer is B

16)

Correct option answer is A

17)

Correct option answer is A

18)

19)

20)
 21)

22)

ϕB = B0r2t(2πrdr)

23)

Correct option answer is 363.00

24)

Correct option answer is 144.00

25)

Correct option answer is 300.00

PART-2 : CHEMISTRY

26) Given,
27) %w/w of HNO3 = 75%
Means that 100 g , of solution contains 75g of HNO3

and

∵ 75g of HNO3 present in mL solution.

∴ 30 g of HNO3 present in

solution

28) Depression in freezing point is given by

ΔTf = iKfm
0.2 = i x 1.8 x 0.1

For,
t=01
t = teq 1 − α α α
i=1+α

Keq = 1.38 x 10−3

29) Given, Kf = 1.86 K kg mol−1

ΔTf = 0.558 oC
Molality = 0.1 molal
Using formula,
ΔTf = iKfm
0.558 = i x 1.86 x 0.1
On solving, we get
i=3
So, among the given options,
compound given in option (d) have the value of i = 3. So, the complex is [Cr(NH3)5 Cℓ] Cℓ2

30) As the given solution is already infinitely dilute hence no change in molar conductivity is
observed upon addition of water.

31)
Calomel electrodes comes in the category of metal-insoluble salt-anion electrodes.

32) Among the given statements only (a) is correct

cell potential is given by

= 19 mV
∴ Fuel cell involves oxidation of methanol which will occur at anode and reduction of O2 will
occur at cathode.

33) The correct match is

A-IV, B-III, C-I, D-II

34)

Complete reaction sequence is as follows :

So, the major product obtained is given in option (a).

35) Statement I is correct, whereas statement II is incorrect.

The correct from of statement II is,
Vanillin does not give self aldol reaction due to lack of acidic H for condesation.

36)

The complete reaction is as follows,

37)

Complete reaction sequence is as follows:

38) The correct sequence of acidic strength of given aliphatic acids in their decreasing order is
:
HCOOH > CH3COOH > CH3CH2COOH > CH3CH2CH2COOH

39)
In the above reaction KMnO4 oxidises benzylic carbon containing at least one α-hydrogen atom
to −COOH.

40)

Correct option answer is C

41)
 Correct option answer is C

42)

Correct option answer is A

43)

Correct option answer is B

44)

Correct option answer is C

45)

Correct option answer is A

46)

Correct option answer is 6.00

47)

Correct option answer is 75.00

48)

Correct option answer is 7.00

49)

Correct option answer is 3.00

50)

Correct option answer is 1107.00

PART-3 : MATHEMATICS
51)

52)
53)

54)
55)
56)
57)
58)
59)
60)
61)
62)
63)
64)
65)
66)

67)

Correct option answer is D

68)
69)

70)

71)

Correct option answer is 10.5

72)
73)
74)
75)