KENDRIYA VIDYALAYA SANGATHAN

IN SERVICE COURSE 2023-24 AHMEDABAD REGION(2023-24)

CLASS -XI SESSION ENDING EXAMINATION
CHEMISTRY THEORY (043) -GROUP -1 [ SET-1]
MM:70 Time: 3 hours
_________________________________________________________________________________________________________
BLUE PRINT- 1
TOPIC

Questions (4mark)

TOTAL MARKS
NO.

SA-II (3marks)
SA-I (2marks)

LA (5 marks)
Case based
UNIT

MCQ

1 Some basic concept of chemistry 1(1) 2(1) 4(1) 07

2 Structure of atom 1(1) 3(1) 5(1) 09

3 Classification of elements and 1(1) 2(1) 3(1) 06

periodicity in properties
4 Chemical bonding and molecular 1(2) 5(1) 07
structure
5 Thermodynamics 1(2) 3(1) 4(1) 09

6 Equilibrium 1(2) 2(1) 3(1) 07

7 Redox reaction 1(1) 3(1) 04

8 Organic chemistry: some basic 1(3) 2(1) 3(2) 11

principle and technique
9 Hydrocarbons 1(3) 2(1) 5(1) 10

TOTAL 16(16) 10(5) 21(7) 8(2) 1 15(3) 70(33)

 KENDRIYA VIDYALAYA SANGATHAN
IN SERVICE COURSE 2023-24 AHMEDABAD REGION(2023-24)
CLASS -XI SESSION ENDING EXAMINATION
CHEMISTRY THEORY (043) -GROUP -1 [ SET-1]
MM:70 Time: 3 hours
_____________________________________________________________________________________________________
General Instructions:

Read the following instructions carefully.

(a) There are 33 questions in this question paper with internal choice.

(b) SECTION A consists of 16 multiple -choice questions carrying 1 mark each.

(c) SECTION B consists of 5 short answer questions carrying 2 marks each.

(d) SECTION C consists of 7 short answer questions carrying 3 marks each.

(e) SECTION D consists of 2 case - based questions carrying 4 marks each.

(f) SECTION E consists of 3 long answer questions carrying 5 marks each.

(g) All questions are compulsory.

(h) Use of log tables and calculators is not allowed.

_________________________________________________________________________________________________

SECTION: A

1. Which of the following is not iso-electronic with Ne ?

(A) O2– (B) F- (C) Mg (D) Na+

2. The value of n and l for the last electron of the Cl atom respectively are ________ .

(A) 1 and 2 (B) 3 and 1 (C) 2 and +1 (D) 1 and –1

3. For a chemical reaction PCl3 + Cl2 ⇔PCl5 ,Which of the following factor shifted the reaction to left side?

(A) Increase of conc of PCl3 (B) Increase of conc of Cl2 (C) Increase of conc of PCl5 (D) None of the above

4. In a equilibrium chemical reaction A + B --→ C + D the concentration of any one of the reactants are doubled, then

the equilibrium constant will

(A) Also be Doubled (B) Be Halved (C) Remain the Same (D) Become One-Fourth

5. Which of the following molecules not follow the octet rule?

(A) BF3 (B) H2O (C) CH4 (D) NH3

6. Oxygen has an oxidation state of +2 in

(A) H₂O2 (B) H₂O (C) OF₂ (D) SO₂

7. The empirical formula of a compound is CH2O. The molecular formula will be

(A) C2H4O2 (B) C4H8O4 (C) C3H6O3 (D) all of these

8. Which of the following compound has polar covalent bond?

(A) LiCl (B) LiBr (C) HCl (D) None of these

9. What is the relation between But-1-ene and But-2-ene ?

(A) They are functional isomers of each other (B) They are chain isomers of each other

(C) They are tautomer’s of each other (D) They are position isomers of each other

10.Common name of the compound CH3C(CH3)2CH3 is

(A) n-pentane (B) Iso-pentane (C) Neo-pentane (D) All of the above

11. What is the change in internal energy ∆U, for a system that does 70 joules of work as it

absorbs 45 joules of heat?

(A) 115 J (B) 25 J (C) –25 J (D) –115 J

12. If the internal energy of an ideal gas decreases by the same amount as the work done by the

system, the process is:-

(A) cyclic (B) isothermal (C) adiabatic (D) isolated

ASSERTION AND REASON TYPE QUESTIONS (1 MARK)

In the following questions, a statement of Assertion (A) followed by a statement of Reason

(R) is given. Choose the correct option out of the choices are given below.

(A) Both A and R are true and R is the correct explanation of A.

(B) Both A and R are true but R is not the correct explanation of A.

(C) A is true but R is false.

(D) A is false but R is true.

13. Assertion : 30 carbocation is most stable than 20 or 10 carbocations.

Reason : Magnitude of positive charge on 30 carbocation is smaller than 20 or 10 carbocations.

14. Assertion (A): Benzene ring is stabilized by the resonance phenomena.

Reason (R): As number of resonating structures increases, stability of compound also increases.

15. Assertion (A): Free radicals are yield by heterolytic fission of covalent bond.

Reason (R) : Free radicals are highly reactive species.

16. Assertion (A): Aniline is more reactive than Nitrobenzene towards electrophilic substitution.

Reason (R) : Electron withdrawing groups are activating and ortho para directing.

SECTION B

This section contains 5 questions with internal choice in one question. The following questions are very short answer
type and carry 2 marks each.
 17. Calculate the number of atoms in each of the following

(i) 52 moles of Ar (ii) 52 u of He

18. Give any two distinguishing points between electron gain enthalpy and electronegativity?

19. Calculate the solubility of silver chloride in water at room temperature if the Ksp of AgCl is 1.6×10-10.

20. How will you prepare

(a) Methane from acetic acid ?

(b) Ethene from Ethyl alcohol ?

21. Draw the cis and trans structures of hex-2-ene. Which isomer will have higher b.p. and why?

OR

Write IUPAC names of the products obtained by the ozonolysis of Pent-2-ene

SECTION: C

This section contains 7 questions with internal choice in one question. The following questions are short answer type
and carry 3 marks each.

22. A Electron is jump from First energy level to Second energy level, Calculate energy and wavelength of Hydrogen

spectrum ?

23. (a) Out of F or Cl which element would have a more negative electron gain enthalpy? Explain.

(b) How would you explain the fact that the first ionization enthalpy of sodium is lower than that of magnesium but

its second ionization enthalpy is higher than that of magnesium?

24. Calculate the standard enthalpy of formation of CH3OH(l) from the following data:

CH3OH (l) + 3/2 O2 (g) CO2 (g) + 2H2O (l) ; ΔrH°= -726 kJ mol-1

C(g) + O2 (g) CO2 (g) ; ΔcH°= -393 kJ mol-1

H2 (g) + 1/2 O2 (g) H2O (l) ; ΔfH°= -286 kJ mol-1

25.

(a) Define Le-Chatlier principle.

(b) Describe the effect on the equilibrium of the reaction: 2H2(g) + CO (g) = CH3OH (g)

a) addition of H2 b) addition of CH3OH c) removal of CO d) removal of CH3OH

26. Write the balanced redox reaction

MnO4-(aq) + Fe2+ (aq) → Mn2+(aq)+ Fe3+ (aq) [acidic medium]

27. Explain the terms Inductive and Electrometric effects. Which electron displacement effect explains the following

correct orders of acidity of the carboxylic acids?

(a) Cl3CCOOH > Cl2CHCOOH > ClCH2COOH

 (b) CH3CH2COOH > (CH3)2CHCOOH > (CH3)3CCOOH

28. Attempt any three out of four.

(a) What are the necessary conditions for any system to be aromatic?

(b) Explain why the A is not aromatic?

(c) How would you convert the following compounds hexane into benzene?

(d) Name the electrophile attack in nitration of benzene.

SECTION D

The following questions are case -based questions. Each question has an internal choice and carries 4 (1+1+2) marks
each. Read the passage carefully and answer the questions that follow.

29.

Atoms and molecules are extremely small in size and their numbers in even a small amount of any substance is really
very large. To handle such large numbers, a unit of convenient magnitude is required. Just as we denote one dozen for
12 items, score for 20 items, gross for 144 items, we use the idea of mole to count entities at the microscopic level (i.e.,
atoms, molecules, particles, electrons, ions, etc). In SI system, mole (symbol, mol) was introduced as seventh base
quantity for the amount of a substance. The mole, symbol mol, is the SI unit of amount of substance. One mole contains
exactly 6.02214076 ×1023 elementary entities. This number is the fixed numerical value of the Avogadro constant, NA,
when expressed in the unit mol–1 and is called the Avogadro number. The amount of substance, symbol n, of a system is
a measure of the number of specified elementary entities. An elementary entity may be an atom, a molecule, an ion, an
electron, any other particle or specified group of particles. It may be emphasized that the mole of a substance always
contains the same number of entities, no matter what the substance may be. In order to determine this number
precisely, the mass of a carbon–12 atom was determined by a mass spectrometer and found to be equal to 1.992648
×10–23 g. Knowing that one mole of carbon weighs 12 g, the number of atoms in it is equal to 12 g mol-1 of 12C /1.992648
X10-23 g per 12 C atom = 6.0221367 x 10 23 atoms Mol -1 is equal to 6.0221367x 1023 atoms Mol -1

This number of entities in 1 mol is so important that it is given a separate name and symbol. It is known as ‘Avogadro
constant’, or Avogadro number denoted by NA in honour of Amedeo Avogadro. To appreciate the largeness of this
number, let us write it with all zeroes without using any powers of ten. 602213670000000000000000 Hence, so many
entities (atoms, molecules or any other particle) constitute one mole of a particular substance. We can, therefore, say
that 1 mol of hydrogen atoms = 6.022 ×1023 atoms 1 mol of water molecules = 6.022 ×1023 water molecules 1 mol of
sodium chloride = 6.022×1023 formula units of sodium chloride Having defined the mole, it is easier to know the mass of
one mole of a substance or the constituent entities. The mass of one mole of a substance in grams is called its molar
mass. The molar mass in grams is numerically equal to atomic/molecular/ formula mass in u. Molar mass of water =
18.02 g mol–1 Molar mass of sodium chloride = 58.5 g mol–1

(a) How many moles of carbon present in 120 g of 12C?

(b) Which one has more number of entities,2 g of H2 or 2 g of N2?

(c) Calculate number of molecules of H2 , atoms of H and number electron in 10 g of H2gas.

OR

(c) 0.40 g of Helium gas placed in a container, Calculate number of moles & number of atoms of He?
30. Every system is associated with a definite amount of energy, called the internal energy U or E) of the system. It is the

sum of chemical, electrical, mechanical or any other form of energy that anyone can may think of. However

gravitational energy is generally necklaces neglected. It is a state function, i. e. independent of the path followed?

lt may change when

i) heat flows in or out of the system.

ii) work is done on or by the system.

iii) matter enters or leaves the system

It is an extensive property i.e. depends upon the mass of a substance. It depends only on temperature. The absolute
value of internal energy possessed by a substance cannot be calculated because it is not possible to predict the exact
values of different forms of energy. Thus, we can just calculate the change in internal energy which is achieved by
changing the state of a system. First law of thermodynamics was proposed by Helmholtz and Robert- mayer who stated
that the energy in of an isolated system is constant. i.e. energy can neither we created nor be destroyed but can be
converted from one form to another. That's why it is also called law of conservation of energy. When a system
undergoes isothermal ΔU = zero i.e. there is no increase or decrease in the internal energy of the system then the first
law of thermodynamics reduces to 0 = q + w or q = -w.

a) neither q not w is a state function but q + w is a state function explain why?

b) Out of mass and density which is an intensive property and why?

c) Explain thermodynamically how is the heat absorbed by system is used in doing work at constant

temperature and pressure.

OR

What is the change in the energy of system if 500 Cal of heat energy are added to a system and system does 350 cal of
work on the surroundings?

SECTION E

The following questions are long answer type and carry 5 marks each. All questions have an internal choice.

31. (a) Write the electronic configurations of O2 , O2+, O2−(superoxide), O22− (peroxide)

(b) Compare the relative stability of the above species and indicate their magnetic properties;

OR

(a) Explain hybridization and its characteristics.

(b) Describe the hybridization in case of PCl5.

(c) Why are the axial bonds longer a compared to equatorial bonds?

32. Attempt any five out of seven.

(a) Write the IUPAC names of the products obtained by the ozonolysis Pent-2-ene.

(b) Arrange benzene, n-hexane and ethyne in decreasing order of acidic strength. Also give reason for this behavior.

(c) How will you convert benzene into p-chloronitrobenzene.

(d) Arrange the following sets of compounds in order of their decreasing relative reactivity with an electrophile and
assign reason. Chlorobenzene, 2, 4-dinitrochlorobenzene, p-nitro chlorobenzene.

(e) How will you convert benzene into p-nitrotoluene.

(f) Write the structural formula of 3,4,4,5- Tetramethylheptane.

(g) Draw the resonating structure of Nitrobenzene.

33. (a) The electron energy in hydrogen atom is given by En = (–2.18 x10-18)/n2J. Calculate the energy required to remove

an electron completely from the n = 2 orbit. What is the longest wavelength of light in cm that can be used to

cause this transition?

(b) Find the energy of the 3rd Bohr’s orbit of He+ ion.

(c) Calculate the number of radial nodes for 2p orbital.

OR

(a) How many electrons in an atom may have the following quantum numbers?

(i) n = 4, ms = – ½ (ii) n = 3, l = 0

(b) Show that the circumference of the Bohr orbit for the hydrogen atom is an integral multiple of the de Broglie

wavelength associated with the electron revolving around the orbit.

(c) What is the maximum number of emission lines when the excited electron of a H atom in n = 6 drops to the ground

state?
 KENDRIYA VIDYALAYA SANGATHAN
IN SERVICE COURSE 2023-24 AHMEDABAD REGION(2023-24)
CLASS -XI SESSION ENDING EXAMINATION
CHEMISTRY THEORY (043) -GROUP -1 [ SET-1]
MM:70 Time: 3 hours
_________________________________________________________________________________________________________
SECTION: A

1. (C)- Mg

2. (B)-3 &1

3. (C) -Increasing conc of PCl5

4. (B) -Halved

5. (A) – BF3

6. (C) -OF2

7. (D)- All of the above

8. (C) – HCl

9. (D)- They are position isomers of each other

10. (C) - Neopentane

11. (C) : –25 J

12. (C) Adiabatic

13. (A)

14. (B)

15. (D)

16. (C) 1

SECTION B

17. (i) 1 mole of Ar = 6.022 × 1023 atoms of Ar 1

52 mol of Ar = 52 × 6.022 × 1023 atoms of Ar

= 3.131 × 1025 atoms of Ar

(ii)1 atom of He = 4 u of He Or, 4 u of He = 1 atom of He 1

1 u of He = 1/4 atom of He
52u of He = 52/4 atom of He

= 13 atoms of He

18. Any two Distinguishing point in between Electron gain enthalpy and Electronegativity.

19. KSP = S 2 S = (KSP)1/2 S= (1.6 X 10 -10)1/2 S = 1.26 X10-5

20. ( i) By Decarboxylation CH3COOH + NaOH -----→ CH3COONa + Soda lime ------→ CH4 + Na2CO3

(ii) By Dehydration CH3CH2OH + Conc.H2SO4 -----→ CH2=CH2 + H2O

21. Geometrical isomers of hex-2-ene are:

22. E n = -2.18 x10 -18( 1/n22- 1/n22 )

Introducing correct values

Correct answer E n = 1.635 x10 -18 J Atom-1

E n = hu = h C/Lambda

Introducing correct value

Correct Answer , Lambda= 1.2 nm

23. (i) The value of the electron gain enthalpy of Cl is more negative than that of F. because of larger size

Of Cl influence less repulsion and can easily accommodate incoming electron than that of

Fluorine

(ii) The electronic configurations are as follows: 1

Na - [Ne] 3s1
 Mg - [Ne] 3s2

Sodium has one valence electron in 3s1 and by losing this electron it attains stable

configuration. Therefore the 1st ionization energy of Na is less than Mg. After removing an electron

the Na attains noble gas configuration where as Mg has one electron left. To remove an electron

from a noble gas configuration high energy is required. Therefore the second ionization enthalpy is

higher than that of magnesium.

SECTION : C

24. 1+2

25. (i) Le Chatelier's principle states that if a dynamic equilibrium is disturbed by changing the

conditions, the position of equilibrium shifts to counteract the change to reestablish an equilibrium.

If a chemical reaction is at equilibrium and experiences a change in pressure, temperature, or

concentration of products or reactants, the equilibrium shifts in the opposite direction to offset the

change. 1

(ii) (a) According to Le Chatelier’s principle, on the addition of H2, the equilibrium of the given

reaction will shift the forward direction. 2

26. Method of Balancing 1

MnO4- + 5 Fe 2++ 8 H+ -----------→ Mn 2+ +5 Fe3++ 4H20 2

 11/2 +11/2

28. (a) A compound is said to be aromatic if it satisfies the following three conditions: 2

(i) It should have a planar structure.

(ii) The π–electrons of the compound are completely delocalized in the ring.

(iii) The total number of π–electrons present in the ring should be equal to (4n + 2),

where n= 0, 1, 2 … etc. This is known as Huckel’s rule.

(b) A is not aromatic because 1

(i) It is not planar

(ii) A does not follow Huckel’s rule. (4n+2) = 8 => n = 1.5 ( non integer)

(c) By cyclisation &aromatization correct reaction 1

(d) NO2+ -Nitronium ion 1

29. Number of of H2 Molecules = 10/2 X 6.022 X 10 23 = 3.011x10 24 ½ +½

Number of of H Atoms = 10/2 X2x2 6.022 X 10 23 =6.022x10 24 ½ +½

Number of of Electrons = 10/2 X2x2 6.022 X 10 23 =6.022x10 24 ½ +½

OR
 Number of of moles of He = 0.10

Number of of He Atoms = 0.10 x 6.022 X 10 23 =6.022x10 23 ½ +½

30. (i) From first law of thermodynamics ΔU = q + w as q + w is equal to ΔU which is a state function it

does not depends upon path of reaction and only depends upon initial and final state. 1

(ii) Density is an intensive property as it characteristics of a material and does not change with amount
where as mass does change. 1

(iii) ΔU=q +w (from first law of thermodynamics) 2 0 = q +w. (ΔU=0 at constant Temp.) 0 = q – p ΔV

q = – w Therefore heat absorbed is used to do work by the system. OR According to the first law of

thermodynamics. 2 ΔU = q + w = 500 +( – 350) = +150 cal

SECTION: E

31. (i). The electronic configuration of O2 molecule can be written as:

Total electrons = 8+8= 16 1 [σ(1s)]2 [σ∗(1s)]2 [σ(2s)]2 [σ∗(2s)]2 [σ(2pz)]2 [π(2px)]2 [π(2py)]2 [π∗(2px)]1
[π∗(2py)] 1

Nb=10 , Na= 6

(i) Bond order= (Nb−Na)/ 2 = (10−6)/ 2 = 2

(ii) Paramagnetic ( 2 unpaired electrons) The electronic configuration of O2 + can be written as: Total
electrons = 8+8-1= 15 1 [σ(1s)]2 [σ∗(1s)]2 [σ(2s)]2 [σ∗(2s)]2 [σ(2pz)]2 [π(2px)]2 [π(2py)]2 [π∗(2px)] 1
[π∗(2py)]0 Nb=10 , Na= 5

(i) Bond order= (Nb−Na) 2 = (10−5) 2 = 2.5

(ii) Paramagnetic ( 1 unpaired electron) Electronic configuration of O2− ion will be: Total
electrons = 8+8+1= 17 1
[σ(1s)]2 [σ∗(1s)]2 [σ(2s)]2 [σ∗(2s)]2 [σ(2pz)]2 [π(2px)]2 [π(2py)]2 [π∗(2px)]2 [π∗(2py)]1
Nb=10 , Na= 7 (i) Bond order= (Nb−Na) 2 = (10−7)/ 2 = 1.5 (ii) Paramagnetic ( 1 unpaired
electron)

Electronic configuration of O2 2− ion will be: Total electrons = 8+8+2= 18 1

[σ(1s)]2 [σ∗(1s)]2 [σ(2s)]2 [σ∗(2s)]2 [σ(2pz)]2 [π(2px)]2 [π(2py)]2 [π∗(2px)]2 [π∗(2py)]2

Nb=10 , Na= 8 (i) Bond order= (Nb−Na) /2 (10−8) 2 = 1 (ii) Diamagnetic ( All paired electron)

(ii) Bond dissociation energy is directly proportional to bond order. Thus, the higher the bond order, the
greater will be the stability. On this basis, the order of stability is

O2+ > O2 > O2 − > O2 2− 1

OR
 (a) Hybridization: It is the process of inter mixing atomic orbitals having slightly different
energies to form new orbitals having equivalent energy and identical shape. The new
orbitals formed are called hybrid orbitals. 1

Characteristics of hybridization 1.

1.The number of hybrid orbitals formed is equal to the number of atomic orbitals undergo
hybridization.
2. The hybrid orbitals are always equivalent in energy and in identical shape.
3. The hybrid orbitals are more effective in forming stable bonds than the pure atomic
orbitals.
4. The hybrid orbitals are directed to some fixed positions in space. So the type of
hybridization gives the shape of the molecule.

(b) The ground state (a) and excited state (b) outer electronic configurations of phosphorus

(Z=15) are:

Phosphorus atom is sp3d hybridized fig. (c) in the excited state. These 5 half-filled orbitals are filled by
the electron donated by 5 Cl atoms.

(C) 1

There are 5 P–Cl sigma bonds in PCl5. 3 P–Cl bonds lie in one plane and make an angle of 120°

with each other. These bonds are called equatorial bonds. The remaining 2 P–Cl bonds lie above

and below the equatorial plane and make an angle of 90° with the plane. These bonds are called

axial bonds. As the axial bond pairs suffer more repulsion from the 3 equatorial bond pairs, axial
bonds are slightly longer than equatorial bonds.

32. (a) Ethanal and Propanal 1

(b) Ethyne > n-hexane > Benzene 1

(c) Correct reaction for nitration of benzene by nitrating mixture 1

(d) Chlorobenzene >p-nitro chloro benzene> 2,4-dinitro chloro benzene. 1

(e) correct conversion using least steps. 1

(f) CH3CH2C(CH3)C(CH3)2 C(CH3)CH2CH3

(g) Correct resonating structures. 1

OR

(a) Functional isomerism: It is the type of isomers formed by compounds that have the same

molecular formula but different functional groups. For example, propanone and propanal are

functional isomers as they both have the same molecular formula but different functional groups. 1

(b) Electrophiles are electron deficient species and can accept an electron pair from electron

rich species. Examples include carbocations and carbonyl compounds. 1

 1+1+1

1+1+1
 KENDRIYA VIDYALAYA SANGATHAN
IN SERVICE COURSE 2023-24 AHMEDABAD REGION(2023-24)
CLASS -XI SESSION ENDING EXAMINATION
CHEMISTRY THEORY (043) -GROUP -1 [ SET-2]
MM:70 Time: 3 hours
_____________________________________________________________________________________________________

BLUE PRINT
SR. CHAPTER MCQ ASSERTION – SA LA CBT VERY TOTAL
NO REASON LONG
1 SOME BASIC OF CHEMISTRY 2(2) 2(1) 3(1) 7(4)
2 STRUCTURE OF ATOM 2(2) 2(1) 5(1) 9(4)
3 CLASSIFICATION OF ELEMENTS 1(1) 1(1) 4(1) 6(3)
4 CHEMICAL AND MOLECULAR 3(3) 2(1) 7(5)
BONDING 2(1)
5 THERMODYNAMICS 1(1) 2(1) 3(1) 9(4)
3(1)
6 EQUILIBRIUM 3(1) 4(1) 7(2)
7 REDOX REACTON 1(1) 3(1) 4(2)
8 ORGANIC CHEMISTRY 3(3) 3(1) 5(1) 11(5)
9 HYDROCARBON 1(1) 1(1) 3(1) 5(1) 10(4)
TOTAL 12 4 10 21 8 15 70
 KENDRIYA VIDYALAYA SANGATHAN
IN SERVICE COURSE 2023-24 AHMEDABAD REGION(2023-24)
CLASS -XI SESSION ENDING EXAMINATION
CHEMISTRY THEORY (043) -GROUP -1 [ SET-2]
MM:70 Time: 3 hours
_____________________________________________________________________________________________________

General Instructions:

Read the following instructions carefully.

a) There are 33 questions in this question paper with internal choice.
b) SECTION A consists of 16 multiple-choice questions carrying 1 mark each.
c) SECTION B consists of 5 very short answer questions carrying 2 marks each.
d) SECTION C consists of 7 short answer questions carrying 3 marks each.
e) SECTION D consists of 2 case- based questions carrying 4 marks each.
f) SECTION E consists of 3 long answer questions carrying 5 marks each.
g) All questions are compulsory.
h) Use of log tables and calculators is not allowed

SECTION A

Q.1 Number of the required angular nodes for 4d orbital is __________.

(a)4 (b)3 (c)2 (d)1
Q.2 Which among the following is responsible for ruling out the existence of definite paths
or trajectories of the electrons?

(a)Pauli’s exclusion principle. (b)Heisenberg’s uncertainty principle.

(c)Hund’s rule of maximum multiplicity. (d)Aufbau principle.
Q.3 Which of the following angles corresponds to sp2 hybridisation?
(a) 90° (b) 120° (c) 180° (d) 109°
Q.4 Shape of PCl5 is :
(a) Octahedral (b) Square pyramidal
(c) Trigonal Planar (d) Trigonal bipyramidal
Q.5 The correct thermodynamics condition for the spontaneous reaction at all
temperature is :
(a) ∆𝐻 < 0 𝑎𝑛𝑑 ∆𝑆 > 0 (b) ∆𝐻 < 0 𝑎𝑛𝑑 ∆𝑆 < 0
(c) ∆𝐻 < 0 𝑎𝑛𝑑 ∆𝑆 > 0 (𝑑)∆𝐻 > 0 𝑎𝑛𝑑 ∆𝑆 < 0
Q.6 Which one of the following bond is the weakest?

(a) Ionic bond (b) Covalent bond.

(c) Metallic Bond (d) van der Waals force

Q.7 Using the standard electrode potential, find out which of the pair between redox
reaction is not feasible. E0values are: E0 (Fe3+/Fe2+ ) = +0.77V, ( E0 (I2/I– )= +0.54V,
(E0 Cu2+/Cu) = +0.34V, ( E0Ag+/Ag )= +0.80 V
(A) Fe3+ and I– (B) Ag+ and Cu
(C) Fe3+ and Cu (D) Ag and Fe3+
Q.8 The IUPAC name for the compound is:

(A) 1 -Chloro-2-nitro-4-methylbenzene
(B) l-Chloro-4-methyl-2-nitrobenzene
(C) 2-Chloro-1 -nitro-5-methylbenzene
(D) m-Nitro-p-chlorotoluene
Q.9 Covalent bonds can undergo fission in two different ways. The correct representation
involving the heterolytic fission of CH3 – Br is:

Q.10 Which of the following compounds will exhibit geometrical isomerism?

(a) 1 – Phenyl but-2-ene (b) 3 – Phenyl but-1-ene
(c) 2 – Phenyl but-1-ene (d) 1,1–Diphenyl-1-propene
Q.11 Principal, azimuthal and magnetic quantum numbers are respectively related to :
(a) size, orientation and shape (b)size, shape and orientation
(c)shape, size and orientation (d)None of the above
Q.12 The principle involved in paper chromatography is :
(A) adsorption (B) partition (C) solubility (D) volatility
Assertion-Reason Type Question:
The following questions given below consist of an "Assertion" (A) and "Reason" (R)
Type questions. Use the following Key to choose the appropriate answer.

(A)If both (A) and (R) are true, and (R) is the correct explanation of (A).
(B)If both (A) and (R) are true but (R) is not the correct explanation of (A).
(C) If (A) is true but (R) is false.
(D) If (A) is false but (R) is true.
Q.13 Assertion : 1.231 has three significant figures.
Reason : All numbers right to the decimal point are significant.
Q.14 Assertion : The empirical mass of ethene is half of its molecular mass.
Reason : The empirical formula represents the simplest whole number ratio of
various atoms present in a compound.
Q.15 Assertion : Second period consists of 8 elements.
Reason : Number of elements in each period is four times the number of atomic
orbitals available in the energy level that is being filled.

Q.16 Assertion : Trans-pent-2-ene is polar but trans-but-2-ene is non-polar.

Reason : The polarity of cis-isomer is more than trans which are either non-
polar or less polar.

SECTION B
Q.17 (a) Can a catalyst change the position of equilibrium in a reaction? 2

(b) What is the effect of reducing the volume on the system described below?

2C(s) + O2(g) 2CO(g)

Q.18 Calculate the molarity of NaOH in the solution prepared by dissolving its 4 g in
enough water to form 250 mL of the solution. 2
OR

Calculate the atomic mass (average) of chlorine using the following data:
Isotopes % Natural Abundance Molar Mass
35Cl 75.77 34.9689
37Cl 24.23 36.9659

Q.19 Which is correct electronic configuration of valence shell of Cu : 3d104s1 or 3d94s2.

Explain with proper reason? 2
OR
Use the molecular orbital energy level diagram to show that Ne2 has no bond.

Q.20 Predict hybridization of central atom in the following species:

(i) water (ii) 𝑃𝐶𝑙5 2

Q.21 Draw structure of the following molecules (according to VSEPR Theory):

(a) Water (b) Ammonia 2

SECTION C

Q.22 The density of 3 M solution of NaCl is 1.25 g mL–1. Calculate the molality of the
solution. 3

Q.23 Enthalpies of formation of CO(g), CO2(g), N2O(g) and N2O4(g) are –110, – 393,
81 and 9.7 kJ mol–1 respectively. Find the value of ∆rH for the reaction: 3

OR

The reaction of cyanamide, NH2CN (s), with dioxygen was carried out in a bomb
calorimeter, and ΔU was found to be –742.7 kJ mol–1 at 298 K.
Calculate enthalpy change for the reaction at 298 K.
NH2CN(s) +3/2O2(g)--------------->N2(g) + CO2(g) + H2O(l)

Q.24 Balance the following equations by 3

Fe2+ + H+ + Cr2O72------------>Cr3+ + Fe3+ + H2O (the oxidation number method)

OR

MnO2 + C2O42----------------->Mn2+ + CO2 ( by ion electron method)

Q.25Write the mechanism for electrophilic addition reaction of HBr on ethene. 3

Q.26 (a) Define pH. 3
(b) The concentration of hydrogen ion in a sample of soft drink is 3.8 × 10–3M. what is
its pH ?
Q.27 Expansion of a gas in vacuum is called free expansion. Calculate the work done and the
change in internal energy when 1 litre of ideal gas expands isothermally into vacuum until is
total volume is 5 litre? 3
Q.28 Write the structure of the following IUPAC Name :
(1) 2- chloro 2-phenyl butane 3
(2) 1,2 – dibromo ethane
(3) propan-1,2,3- carboxylic acid
 SECTION D

Q.29 Modern periodic table arranges the elements in the increasing order of atomic
number. It has 18 groups and 7 periods. Atomic numbers are consecutive in a period and
increases in group in a pattern. Elements are divided into four blocks, s-block,p-block, d-
block andf-block based on their electronic configuration. 78% of elements are metals, about
20 elements are non-metals and few elements like B, Si, Ge, As are metalloids. Metallic
character increases down the group but decreases along the period from left to right. The
physical and chemical properties vary periodically with their atomic numbers.

Periodic trends are observed in atomic size, ionisation enthalpies, electron gain enthalpies,
electronegativity and valence. Oxides of metals are basic, some are amphoteric. Non-metals
form acidic oxides, some form neutral oxides. s-block elements are soft, highly reactive, do
not show variable oxidation states. p-block elements are metals, non-metals as well as
metalloids, show variable oxidation states, exist as solids, liquids and gases. d-block
elements are metals, form coloured ions, show variable oxidation states, have high melting
and boiling points. Lanthanoids and actinoids are f-block elements, form coloured ions. All
actinoids are radioactive.

Answer the following questions:

(i) Considering the atomic number and position in the periodic table, arrange the following
elements in the increasing order of metallic character : Si, Be, Mg, Na, P 1

(ii) Write the general outer electronic configuration of p & d block elements 1

(iii) On the basis of quantum numbers, justify that the 6th period of the periodic table
should have 32 elements 2

Q.30
Equilibrium constant, Kc is independent of initial concentrations. But if a system at
equilibrium is subjected to a change in the concentration of one or more of the reacting
substances, then the system is no longer at equilibrium; and net reaction takes place in
some direction until the system returns to equilibrium once again. Similarly, a change in
temperature or pressure of the system may also alter the equilibrium.
In order to decide what course the reaction adopts and make a qualitative prediction
about the effect of a change in conditions on equilibrium we use Le Chatelier’s principle.

It states that a change in any of the factors that determine the equilibrium conditions of
a system will cause the system to change in such a manner so as to reduce or to
counteract the effect of the change. This is applicable to all physical and chemical
equilibria.

Answer the following questions:

a) Using Le – Chatelier principle, predict the effect of Increasing the temperature
in each of the following equilibrium systems: 2
Exothermic
i) N2(g)+3H2(g) ⇌ 2NH3(g)

Endothermic
ii) N2(g)+O2(g)+Δ ⇌ 2NO(g)
iii)
b)Describe the effect of partial pressures of the given reactants on the equilibrium
of the reaction: 2H2(g) + CO (g) ⇌ CH3OH (g) 2
i) addition of H2 ii) removal of CO

SECTION E

Q.31 (a) A 100 watt bulb emits monochromatic light of wavelength 400 nm. Calculate
the number of photons emitted per second by the bulb. 2
(b) What are the frequency and wavelength of a photon emitted during a transition
From n = 5 state to the n = 2 state in the hydrogen atom? 3
OR
An atom of an element has two electrons in the outermost M-shell. State its (1 x5)

(a) Electronic configuration

(b) Number of protons
(c) Atomic number
(d) Nature whether metal or non-metal
(e) Name of the element

Q.32 (i) Arrange the following halogens in increasing order of reactivity towards
alkanes : F2, Cl2, Br2, I2

(ii) Arrange the following in increasing order of energy released during their
combustion:

(iii)Arrange the following in the increasing order of C—C bond length : C2H6, C2H4, C2H2.
(iv) Give a brief account for the following statements :
(a) n-Pentane has greater boiling point than iso-pentane.
(b) CH4 cannot be synthesized by Wurtz reaction.
Or

(a)An alkyne (X) has molecular formula C5H8. It reacts neither with sodamide nor with
ammoniacal cuprous chloride. Identify X (2+3)
 .
(b)A hydrocarbon ‘Y’ decolourises bromine water. On ozonolysis it gives 3-methylbutanal
and formaldehyde. Give the name and structure of the compound.

(c) A hydrocarbon (Z) has molecular formula, C8H10. It does not decolourise bromine
water and is oxidised to benzoic acid on heating with K2Cr2O7. It can also have three other
isomers A, B and C. Write the structures of Z, A, B and C.

Q.33 Consider structures I to VII and answer the questions a to e (1x5=5)

I. CH3-CH2-CH2-CH2-OH

II. CH3-CH2-CH(OH)-CH3

III.

IV. CH3-CH(CH3)-CH2-OH

V. CH3-CH2-O-CH2-CH3

VI. CH3-O-CH2-CH2-CH3

VII. CH3-O-CH(CH3)-CH3

(a) Which of the above compounds form pairs of metamers?

(b) Identify the pairs of compounds which are functional group isomers.
(c) Identify the pairs of compounds that represents position isomerism.
(d) Identify the pairs of compounds that represents chain isomerism.
(e) Define Geometrical isomerism with example.
Or

(a) Benzoic acid is a organic compound. Its crude sample can be purified by
crystallisation from hot water. What characteristic differences in the properties
of benzoic acid and the impurity make this process of purification suitable? (2)
(b) i) In which C–C bond of CH3CH2CH2Br, the inductive effect is expected to be the
least? (3)
ii)Identify Electrophile & nucleophile from the following & Give definition of each:
CH3 COOH + OH-→ CH3 COO- + H2O
C6H6 + CH3CO+ → C6H5(COCH3)

------------------------------------------------------------------------------------------------------------
 KENDRIYA VIDYALAYA SANGATHAN
IN SERVICE COURSE 2023-24 AHMEDABAD REGION(2023-24)
CLASS -XI SESSION ENDING EXAMINATION
CHEMISTRY THEORY (043) -GROUP -1 [ SET-2]
Marking scheme

Marking scheme of chemistry question paper Set - A

1. (c ) 1
2. (b) 1
3. (b) 1
4. (d) 1
5. (a) 1
6. (d) 1
7. (d) 1
8. (b) 1
9. (b) 1
10. (a) 1
11. (b) 1
12. (b) 1
13. (d) 1
14. (a) 1
15. (C ) 1
16. (b ) 1
17 (a) Ans .No, a catalyst cannot change the position of equilibrium in a 1+1
chemical reaction. Aatalyst, however, affects the rate of reaction.
(b) Ans. The forward reaction is accompanied by increase in volume.
Hence according to Chatelier’s principle, reducing the volume will shift
the equilibrium in the forward direction.

18. M=no. of moles of solute/volume of solution in litre ½

M=(4g/40g)/0.250L ½
M=0.4 M ½(CORRECT
Or ANS.)+
Correct formula ½(CORRECT
Correct substitution UNIT)
Correct ans & unit

½
½
½ +1/2

19. 3d104s1 1+1

Completely filled and half filled orbitals have extra stability. In 3d104s1, d orbital
is completely filled and s is half filled. So it is more stable
configuration.
Or
 KENDRIYA VIDYALAYA SANGATHAN
IN SERVICE COURSE 2023-24 AHMEDABAD REGION(2023-24)
CLASS -XI SESSION ENDING EXAMINATION
CHEMISTRY THEORY (043) -GROUP -1 [ SET-2]
Marking scheme

Correct diagram and bond order

20. (a)sp3 (b)sp3d 1+1

21. 1+1

Bond angles are also expected

22. M = 3 mol L–1
Mass of NaCl
in 1 L solution = 3 × 58.5 = 175.5 g 1
Mass of
1L solution = 1000 × 1.25 = 1250 g
(since density = 1.25 g mL–1) 1
Mass of water in solution = 1250 –75.5
= 1074.5 g
Molality=No. of moles of solute/Mass of solvent in kg 1
m =3 mol/1.0745kg = 2.79 m
23. Correct formula 1
Correct substitution 1
Correct Ans with unit ½+½

24 Correct Balancing 3
25. 3

26. (a) Correct definition 1+1+1

(b) pH = – log[3.8 × 10–3] = – {log[3.8] + log[10–3]} = – {(0.58) + (– 3.0)}
= – { – 2.42} = 2.42
Therefore, the pH of the soft drink is 2.42 and it can be inferred that it is acidic.
27 1
(–w) = pext (V2 – V1) = 0 × (5 –1) = 0

2
 KENDRIYA VIDYALAYA SANGATHAN
IN SERVICE COURSE 2023-24 AHMEDABAD REGION(2023-24)
CLASS -XI SESSION ENDING EXAMINATION
CHEMISTRY THEORY (043) -GROUP -1 [ SET-2]
Marking scheme

For isothermal expansion q = 0

By first law of thermodynamics-

q = ΔU + (–w)

0 = ΔU + 0

so, ΔU = 0

28 (1)CH3- (Cl)C(C6H5)-CH2-CH3 1+1+1

(2) Br-CH2-CH2-Br
(3) HOOC-CH2-CH(COOH)-CH2-COOH
29. (i) Metallic character increases down a group and decreases along a 1+1+1+1
period as we move from left to right. Hence the order of increasing
metallic character is: P < Si < Be < Mg < Na

(ii) the general outer electronic configuration of p block is: ns2np1-6 and
d block is : (n-1)d1-10 ns0-2 except for Pd where its electronic configuration is
4d105s0.
(iii) In 6th period The total number of orbitals available are 16. The maximum
number of electrons that can be accommodated is 32; and therefore 32
elements are there in the 6th period

30. (a) i)In an exothermic reaction increase in temperature shifts the equilibrium 1
to the left hand side

ii) For an endothermic reaction increase in temperature shifts the equilibrium 1

to the right
1
b) i)Equilibrium will shift towards forward direction
(ii) Equilibrium will shift towards backward direction 1

31. (a) Power of the bulb = 100 watt==100 J s–1 1

Energy of one photon E = hc/λ
=6.626 x10 34 J s x 3 x108 m s -1/400 10 9m
=4.969 x 10-19 J 1
No. of photons=100Js-1/4.969 x 10-19 J
=2.012 x 1020

(b) Since ni = 5 and nf = 2, this transition gives 1

rise to a spectral line in the visible region
of the Balmer series
 KENDRIYA VIDYALAYA SANGATHAN
IN SERVICE COURSE 2023-24 AHMEDABAD REGION(2023-24)
CLASS -XI SESSION ENDING EXAMINATION
CHEMISTRY THEORY (043) -GROUP -1 [ SET-2]
Marking scheme

1 1
ΔE =2.18 x 10-18J ⌊25 − 4⌋

=-4.18 x 10-19J
It is an emission energy 1
The frequency of the photon (taking
energy in terms of magnitude) is given by

ν=ΔΕ / h
= 4.18 x 10-19J/ 6.626 x10 -34
=6.91×1014 Hz 1

λ=c/ν= 3 x108 m s -1/6.91×1014 Hz

=434 nm
OR
(a) Since the atom has two electrons in the outermost M-shell, the K and L
shells are already filled. As a result, the electronic configuration is 2, 8, 2. This
means that the number of electrons of the atom is 12.

(b) The number of protons equals the number of electrons. Therefore, the
number of protons will be 12.

(c) The atomic number equals the number of protons, which is 12.

(d) A metal. This is due to the fact that metallic elements have valence
electrons less than 3.

(e) Mg

32. . (i) I2 < Br2 < Cl2 < F2 1+1+1+2

(ii) As branching increases, the ∆H°comb decreases (becomes less
negative). Thus, the increasing order of heat of combustion is
(II) < (I) < (IV) < (III).
(iii) C2H2 (120 pm) < C2H4 (134 pm) < C2H6 (154 pm)
(iv)(a) As n-pentane is linear and iso-pentane is not so, n-pentane has
higher surface area than iso-pentane. Hence, the magnitude of van der
Waals’ force is higher in n-pentane. erefore, it has higher boiling point. (b)
Wurtz reaction occurs between two alkyl halides to yield alkane. Methane
has only one carbon atom, hence cannot be prepared using Wurtz
reaction.
Or
 KENDRIYA VIDYALAYA SANGATHAN
IN SERVICE COURSE 2023-24 AHMEDABAD REGION(2023-24)
CLASS -XI SESSION ENDING EXAMINATION
CHEMISTRY THEORY (043) -GROUP -1 [ SET-2]
Marking scheme

(a) Alkyne X is C5H8. Since it does not react with sodamide or ammoniacal
cuprous chloride, the triple bond cannot be terminal. ? X is CH3CH2C CCH3
Pent-2-yne
(b) Hydrocarbon ‘Y’ is alkene because it decolourises bromine water. From
the products of ozonolysis, the structure of alkene can be predicted.
1+1+2

(c) Since, it does not decolourise bromine water, it is arene. Thus,

33. (a) V , VI & VII 1*5 = 5

(b) I/II/III/IV & V/VI/VII
(c) I & II, III & IV
(d) I/II & III/IV
(e) correct definition
Or
2
(a) Benzoic acid can purified by hot water because of following characteristics.
(i) Benzoic acid is more soluble in hot water and less soluble in cold water.
(ii) Impurities present in benzoic acid are either insoluble in water or more
soluble in water to such an extent that they remain in solution as the mother
liquor upon crystallisation.
3
(b) Magnitude of inductive effect diminishes as the number of intervening
bonds increases. Hence, the effect is least in the bond between carbons-C2 &
C3 .
c) Electrophile: CH3CO+ Nucleophile: OH-
 KENDRIYA VIDYALAYA SANGATHAN
IN SERVICE COURSE 2023-24 AHMEDABAD REGION(2023-24)
CLASS -XI SESSION ENDING EXAMINATION
CHEMISTRY THEORY (043) -GROUP -1 [ SET-2]
Marking scheme
 KENDRIYA VIDYALAYA SANGATHAN
(IN-SERVICE COURSE 2023-24, AHMEDABAD REGION)
CLASS XI- SESSION ENDING EXAMINATION (SEE)
CHEMISTRY THEORY (043)
Max. Marks:70 Time: 3:00 hours

BLUE PRINT- SAMPLE PAPER - 03

Questions (4mark)
No

MCQs1 marks)

TOTAL MARKS
SA-II (3marks)
SA-I (2marks)

LA (5 marks)
Case based
UNIT

1 Some basic concept of 1(2) - - - 5(1) 07

chemistry

2 Structure of atom 1(2) 2(2) 3(1) - - 09

3 Classification of elements and 1(1) 2(1) 3(1) - - 06

periodicity in properties

4 Chemical bonding and 1(3) - - 4(1) - 07

molecular structure

5 Thermodynamics 1(1) - 3(1) - 5(1) 09

6 Equilibrium 1(1) 2(1) - 4(1) - 07

7 Redox reaction 1(1) - 3(1) - - 04

8 Organic chemistry: some basic 1(3) - 3(1) - 5(1) 11

principle and technique

9 Hydrocarbons 1(2) 2(1) 3(2) - - 10

TOTAL 16(16) 10(5) 21(7) 8(2) 1 15(3) 70(33)

 KENDRIYA VIDYALAYA SANGATHAN
(IN-SERVICE COURSE 2023-24, AHMEDABAD REGION)
CLASS XI- SESSION ENDING EXAMINATION (SEE)
SAMPLE PAPER - 03
CHEMISTRY THEORY (043)
Max. Marks:70 Time: 3:00 hours
General Instructions:
Read the following instructions carefully.
(a) There are 33 questions in this question paper with internal choice.
(b) SECTION A consists of 16 multiple -choice questions carrying 1 mark each.
(c) SECTION B consists of 5 short answer questions carrying 2 marks each.
(d) SECTION C consists of 7 short answer questions carrying 3 marks each.
(e) SECTION D consists of 2 case - based questions carrying 4 marks each.
(f) SECTION E consists of 3 long answer questions carrying 5 marks each.
(g) All questions are compulsory.
(h) Use of log tables and calculators is not allowed.
SECTION A
The following questions are multiple -choice questions with one correct answer. Each question
carries 1 mark. There is no internal choice in this section.

1. Which of the following is correct?

(A) The sum of mole fractions of all the components in a solution is always unity
(B) Mole fraction depends upon temperature
(C) Mole fraction is always negative
(D) Mole fraction is independent of content of solute in solution
2. The set of four numbers used to describe the position and energy of the electron in an
atom are called quantum numbers. There are four quantum numbers, namely, principal(n),
azimuthal(l), magnetic(m) and spin(s) quantum numbers. Which of the following is not
permissible arrangement of quantum numbers for electron in an atom?

(A) n = 5, l = 3, m = 0, s = + ½ (B) n = 3, l = 2, m = – 3, s = – ½
(C) n = 3, l = 2, m = – 2, s = – ½ (D) n = 4, l = 0, m = 0, s = – ½
3. Atomic size depends upon several factors such as nuclear charge, no of shells, number of
electrons, screening effect etc. Which one of the following is correct order of increase of size
(A) Mg < Na+ < F- < Al (B) Na+ < Al < Mg < F-
(C) Na+ < F- < Al < Mg (D) Na+ < F- < Mg < Al
4. According to Fajan’s rule, covalent bond is favoured by
(A) Large cation and small anion (B) Large cation and large anion
(C) Small cation and large anion (D) Small cation and small anion
5. Shape of the molecule depends on the number of bonded and non-bonded pair of electrons,
Incorrect for NH4+ ion_
(A) Four N–H bonds are present (B) Tetrahedral in shape
(C) Two type of N–H bond lengths are present (D) Bond angle is 109.50
6. Randomization of a system measured by entropy, which of the following demonstrates a
decrease in entropy?
(A) Dissolving a solid into solution (B) An expanding universe
(C) Burning a log in a fire place (D) water condensation
7. Redox reactions are those in which oxidation and reduction takes place simultaneously,
which of the following is not an example of redox reaction?
(A) CuO + H2 → Cu + H2O
(B) Fe2O3 + 3CO → 2Fe + 3CO2
(C) 2K + F2→ 2KF
(D) BaCl2 + H2SO4 → BaSO4 + 2HCl
8. The compounds, which have same molecular mass but having different physical and chemical
properties are called as isomers, select pair of isomers?
(A) ethyl alcohol and dimethyl ether (B) acetone and acetaldehyde
(C) propionic acid and propanone (D) methyl alcohol and dimethyl ether
9. The hybridisation of carbon atom in C — C single bond of H2C = CH — CH = CH2 is
(A) sp3 — sp (B) sp2 — sp
(C) sp2 — sp2 (D) sp3 — sp3
10. The percentage of s- character of the hybrid orbitals in ethane, ethene and ethyne are
respectively.
(A) 50, 75, 100 (B) 10, 20, 40
(C) 25, 33, 50 (D) 25, 50, 75
11. When an alkene on ozonolysis gives formaldehyde and acetaldehyde, the alkene is:
(A) ethene (B) propene
(C) but-1-ene (D) but-2-ene
12. Solubility of a gas in liquid increases on…
(A) Addition of a catalyst (B) Decreasing of pressure
(C) Increasing of pressure (D) Increasing of temperature

Q 13-16.
Given below are two statements labelled as Assertion (A) and Reason (R)

Select the most appropriate answer from the options given below:
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correct explanation of A.
(c) A is true but R is false.
(d) A is false but R is true.

13. Assertion(A): In Fahrenheit scale (0F) temperature is represented in between 32o to 2120.
Reason(R): Absolute zero temperature means 0o Fahrenheit.

14. Assertion(R): The charge to mass ratio of particles (electrons) of Cathode rays do not depends
upon the material of electrodes and the nature of the gas present in the cathode ray tube.
Reason(R) : Electrons are basic constituents of all the atoms.
15. Assertion(A) : Shape of NH3 molecule is tetrahedral.
Reason(R): In NH3 nitrogen is sp3 hybridized.

16. Assertion(A): Addition of HBr to propene in presence of benzoyl peroxide produces 1-

bromopropane as the major product.
Reason(R): Addition of HBr to propene in the presence of peroxide follows free radical chain
mechanism.
SECTION B
This section contains 5 questions with internal choice in one question. The following questions
are very short answer type and carry 2 marks each.

17. (a) What is the value for the principal quantum no. for a spherical orbital which has one nodal
plane?
(b) An element with atomic number 7 has following given configurations:
(a) 1s2 2s2 2px2, 2py1, 2pz0 or (b) 1s2 2s2 2px1, 2py1, 2pz1
Which one of the two is correct and why? (State the rule involved)

18. State and explain Heisenberg’s uncertainty principle and its significance. Using this principle,
calculate the uncertainty in the position of an electron if the uncertainty in its velocity is 5.7 X 105
m/sec [ h= 6.6 X 10-34Js (Kg m2 S-1), mass of electron=9.1 X 10-31 Kg]

19. (a) An element is symbolized as ‘Unq’, what is the atomic no and of the element?
(b) Justify the presence of 18 elements in the 5th period of the Periodic Table?

20. (a) Write down the formula for the conjugate acid and conjugate base of NH 3.
(b) Define (i) Common ion effect (ii) Buffer solution

21. (a) Sodium salt of which acid is needed for the preparation of methane? Write chemical
equation involved.
(b) How will you distinguish between Propane and propene?

OR

One isomer of butene gives similar product of hydro halogenations in presence of or absence of
peroxide. Draw the structure and IUPAC name of this isomer with chemical reaction.

SECTION C
This section contains 7 questions with internal choice in one question. The following questions
are short answer type and carry 3 marks each.

22. (a) Write the electronic configuration of chromium and copper (At no. Cr=24, Cu = 29).
(b) How wavelength (λ) of a moving particle associated with its momentum (p), state the rule
related.
(c) Calculate the effective mass of a photon with wavelength 3.6 Å.
[h=6.626 10 -34 Js, velocity of light =3 x108 ms-1]
23. Give reason
(a) H2O is liquid while H2S is gas.
(b) Electron gain enthalpy of chlorine is more than that of fluorine.
(c) Lithium and beryllium show similarities in their physical and chemical properties.

24. (a) During a process no exchange of heat between system and surrounding, name the process.
(b) Neither q nor w is a state function but (q+w) is a state function, why?
(c) In a process, 701 J of heat is absorbed by a system and 394 J of work is done by the system.
What is the change in internal energy of the process?

25. (a) Why is benzene extra ordinarily stable though it contains three double bonds?
(b)How would you convert the following compounds into benzene? (any two)
(a) Ethyne (b) Ethene (c) Hexane
Write chemical equation in each.

26. Why is Wurtz reaction not preferred for the preparation of alkanes containing odd number of
carbon atoms? Illustrate your answer by taking one example.
(b) Write chemical equations for the following hydrocarbons:
(i) Phenol heated with Zn-dust.
(ii) Addition of HBr on Propene in the presence of Peroxide

27. (a) Name the method/technique used to purify liquids having very high boiling points and
those, which decompose at or below their boiling points.
(b) In Carius method of estimation of halogens 0.15 g of an organic compound gave 0.12 g of AgBr.
Find out the % of Br in the compound. (Atomic mass of Ag = 108, Br= 80).

28. (SELECT ANY THREE)

(a) Name the U-shaped apparatus which is used to connect two half cells in Daniell cell, what is its
role?
(b) Balance the following redox reaction by ion electron (reaction half) method showing all the
steps:
Cr2O72– + + Fe2+ →Cr3+ + +Fe3+ [Acidic medium]
(c) Calculate the oxidation state of underlined atom the following compounds
(i) K2Cr2O7 (ii) H2O2
(d) Given the standard electrode potential: K+/K = -2.93 V : Ag+/Ag = 0.80 V Hg2+/Hg = +0.79 V :
Mg2+/Mg = -2.37 V Cr3+/Cr = -0.74 V Arrange these in increasing reducing power with reason.

SECTION D
The following questions are case -based questions. Each question has an internal choice and
carries 4 (1+1+2) marks each. Read the passage carefully and answer the questions that follow.

29. Dipole moment is property which arises due to the difference between electro negativities of
atoms in a molecule which are bonded covalently. Both lone pair and bond pairs present in a
molecule plays a major role in finding the dipole moment and shape of a molecule. Dipole moment
is measurable. Dipole moment can create polarity in molecules. Some covalent molecule shows
some ionic character also. The covalent character of a molecule is directly linked to Fajans rule.
The shape of a molecule depends upon the number of valence shell electron pairs (bonded or
nonbonded) around the central atom. Pairs of electrons in the valence shell repel one another
since their electron clouds are negatively charged. These pairs of electrons tend to occupy such
positions in space that minimise repulsion and thus maximise distance between them. The valence
shell is taken as a sphere with the electron pairs localising on the spherical surface at maximum
distance from one another.

Read the above passage and answer the following questions.

(a) Water is a V-shaped molecule but CH4 has a tetrahedral shape even though both have
same hybridization
(b) Therma-col is insoluble in water but it is readily dissolves in petrol or kerosene, why?
(c) It is known that SiCl4 is more covalent than AlCl3, based on Fajan’s rule support your
observation
OR
(d) Draw the structures of the following molecules using the VSEPR model:
(i) ClF3 (ii) SF4

30. Read the given passage and answer the questions that follow:
Equilibrium can be established for both physical and chemical processes and at equilibrium rate
of forward and reverse processes are equal. Equilibrium constant (KC) is expressed as the
concentration of products divided by reactants, each raised to Stoichiometric Coefficient. K C has
fixed value of constant temperature and at this stage concentration, pressure etc. become
constant. KP is equilibrium constant in terms of partial pressure of gases or vapours. The direction
of reaction can be predicted by reaction quotient QC and QP. QC = KC at equilibrium and QP = KP. Le
Chatelier's principle states 'Equilibrium' will shift in the direction so as to counter balance the
effect of change in T, P and conc. The equilibrium between ions and unionised molecules in weak
electrolyte is called ionic equilibrium.

(a) In the equilibrium H2(g) + I2(g) ⇌ 2HI(g), if at a given temperature, the concentration of the
reactants is decreased, what will be the value of equilibrium constant Kc.
(b) If the value of an equilibrium constant for a particular reaction is 1.6 × 10-5, what will be present
in the system at equilibrium.
(c) The value of Kc for the reaction 2A ⇌ B + C is 2 × 103.
At a given time, the composition of reaction mixture is [A] = [B] = [C] = 4× 10 –5 M. In
which direction the reaction will proceed?
Or
(c) Equilibrium constant, Kc for the reaction P (g) + 3Q (g) ⇌ 2C (g) at 500 K is 0.061. At a
particular time, the analysis shows that composition of the reaction mixture is 3.0 mol L –1 N2 , 2.0
mol L–1 H2 and 0.5 mol L–1 C . Is the reaction at equilibrium? If not in which direction does the
reaction tend to proceed to reach equilibrium
SECTION E
The following questions are long answer type and carry 5 marks each. All questions have an
internal choice.

31. SELECT ANY FIVE

(a) What is the value for the temperature 40oC in Fahrenheit scale?
(b) Write two ways how concentration terms molarity is differed from molality. Will they remain
same on increasing temperature, explain it.
(c) Calculate the molarity of NaOH in the solution prepared by dissolving its 4 g in enough water
to form 250 ml of the solution.
(d) The following data is obtained when N2 and O2 react together to form different compounds:

Mass of Mass of
S No Nitrogen
Nitrogen Oxygen
oxide
(a) N 2O 28 g 16 g
(b) NO 14 g 16 g
(c) N 2O 3 28 g 48 g
(d) NO2 14 g 32 g
(e) N 2O 5 28 g 80 g
Which law of chemical combination is obeyed by the above experimental data? Give its statement
(e) What is the relation between empirical and molecular masses?
(f) A compound contains Na = 43.4% , C= 11.3% and O= 45.3%. Its molar mass is 106 gmol -1. What
are its empirical and molecular formulas?

32. (a) State the second law of thermodynamics.

(b) For the reaction 𝐻2 (𝑔) → 2𝐻(𝑔), what are the signs of Δ𝐻 and Δ𝑆 ?
(c) Discuss the effect of temperature on the spontaneity of a reaction, when both Δ𝐻 0 and Δ𝑆 0
have positive signs.
(d) Calculate the free energy change (∆H) and spontaneity for the given reaction:
2C(s) + O2(g) ⎯⎯→ 2CO2(g)
Given: ∆H = – 300 kJ mol-1, R= ∆S = 3 kJK-1 mol-1 R=8.314 J mol−1K−1 at 300 K

OR
(a) Name the law which states that entropy of universe is continuously increasing due to
spontaneous process taking place in it.
(b) State Hess’s law of constant heat summation.
(c) The combustion of one mole of benzene takes place at 298 K and 1 atm. After combustion,
CO2(g) and H2O(l) are produced and 3267.0 kJ of heat is liberated. Calculate the standard enthalpy
of formation, ∆f H0 of benzene. Standard enthalpies of formation of CO2 (g) and H2O(l) are –393
kJ mol–1 and – 286 kJ mol–1 respectively.
 ➢ C6H6(l) + 15/2 O2(g) ⎯⎯→ 6CO2(g) + 3H2O(l); Δr Ho = – 3267 KJ.mol-1
➢ C(s) + O2 (g) ⎯⎯→ CO2 (g); Δc Ho = – 393 KJ.mol-1
➢ H2(g) + ½ O2 ⎯⎯→ H2O (l); Δf Ho = – 286 KJmol-1

33. (a) Draw the cis and trans structures of but-2-ene. Which isomer will have higher b.p. & why?
(b) What is the structure of carbanion? Write the order of stability of following Carbanion:
H3C −, (CH3)3C −, (CH3)2CH –
(c) Write IUPAC nomenclature of

(i) (ii)

(iii) (iv)

OR
(a) Draw cis and trans isomers of but-2-ene. Which isomer will have higher melting point?
(b) What is the structure of carbocation? Write the order of stability of following Carbocation:
H3C+, (CH3)3C+, (CH3)2C+H
(c) Write IUPAC names of the following:

(i) (ii)

(iii) (iv)

************* THE END************

 KENDRIYA VIDYALAYA SANGATHAN
(IN-SERVICE COURSE 2023-24, AHMEDABAD REGION)
CLASS XI- SESSION ENDING EXAMINATION (SEE)
MARKING SCHEME SAMPLE PAPER - 03
CHEMISTRY THEORY (043)
Q No Answer Marks
1. A 1
2. B 1
3. B 1
4. C 1
5. C 1
6. D 1
7. D 1
8. A 1
9. C 1
10. C 1
11. B 1
12. C 1
13. C 1
14. A 1
15. D 1
16. A 1
17. (i) 2s 1
(ii) (b) is the correct ½
Hund's rule states that pairing of electrons in the orbitals of a subshell (orbitals of ½
equal energy) starts when each of them is singly filled.
18. (a) Heisenberg's uncertainty principle states that for particles exhibiting both 1
particle and wave nature, it will not be possible to accurately determine both the
position and velocity at the same time.
(b)

19. (a) The atomic number of element Unq is 104. Its name is Unnilquadium ½
(b) This period has 4d, 5s and5p available orbitals. The total number of available ½
orbitals are 9 and therefore the maximum number of electrons that can be
accommodated is 18. Thus, 5th period contains 18 elements. 1
20. (a) (i) conjugate acid of NH3 = NH4+ ½
(ii) conjugate base of NH3= NH2- ½
(b) (i) common ion effect: The common ion effect is an effect that suppresses the
ionization of an electrolyte when another electrolyte (which contains an ion which ½
is also present in the first electrolyte, i.e. a common ion) is added
(ii) buffer solution: The solutions which resist a change in pH upon dilution or upon
the addition of small amounts of acid/alkali to them. ½

21. (a) Decarboxylation is a method used to prepare Methane using sodium salt ½
of Ethanoic acid (Sodium ethanoate) ½

(b) propane has a single bond whilst propene has a double bond. This gives
1
propene a combustion advantage, so it burns hotter. Propene fuel gas is extremely
flammable but non-toxic.
OR
But-2-ene is the isomer of butene gives similar product of hydro halogenations in
½ +½
presence of or absence of peroxide.
½ +½
Name, structure and both correct reactions
22. (a) 29Cu = 1s2 2s2 2p6 3s2 3p6 3d10 4s1 ½ +½
2 2 6 2 6 5 1
24Cr =1s 2s 2p 3s 3p 3d 4s
(b) De Broglie relation:
De Broglie relation says that an electron's wavelength and momentum have a ½ +½
relationship, which is given by p = h/mv.
(c)

½ +½

23. (a) Intermolecular hydrogen bonding 1

(b) due to small size of fluorine atom. As a result, there are strong interelectronic
repulsions in the relatively small 2p orbitals of fluorine and thus, the incoming 1
electron does not experience much attraction. 1
(c) Diagonal relationship
24. (a) A diabetic process . 1
(b) q and w both are path function. q stands for heat which depend on the path or
the chemical reaction w stands for work done which also depend on the path or
the chemical reaction Now from first law of thermodynamics, 1
ΔU=q+w
Since ΔU is a state function, thus we can say that q+w is a state function.
(c) According to the first law of thermodynamics, ΔU=q+W
Where, ΔU = change in internal energy for a process q= heat
W = work Given, q = + 701 J (Since heat is absorbed)
W = –394 J (Since work is done by the system) ½ +½
Substituting the values in expression, we get
 ΔU= 701 J + (-394 J) ΔU = 307 J
Hence, the change in internal energy for the given process is 307 J.

25. (a) because of the three double bonds that are actually delocalized pi-electrons 1
that are found to be in resonance. ½ +½
(b) Correct equation ½ +½
26. (a) Wurtz reaction is not preferred for the preparation of alkanes containing odd 1
number of carbon atoms due to the formation of side products. Or suitable answer
(b) chemical equations for the following hydrocarbons:
(i) Phenol heated with Zn-dust to form benzene. ½ +½
(ii) Addition of HBr on Propene in the presence of Peroxide to form 1-bromo
propane ½ +½
27. (a) Distillation under reduced pressure 1
(b) % of Br in the compound = 34.04% (correct formula and correct calculation). 1+1
28. (a) salt bridge, correct function of salt bridge ½ +½
(b) Balance the following redox reaction by ion electron (reaction half) method
showing all the steps: 1

Cr2O72– + + Fe2+ →Cr3+ + +Fe3+ [Acidic medium]

(c) (i) K2Cr2O7 = +6 (ii) H2O2= -1 ½ +½
(d) Ag<Hg<Cr<Mg<K correct reason
29. (a) presence and absence of lone pair 1
(b) Like dissolve like or Any other correct reason 1
(c) Correct explanation on the basis of size of cation or charge on cation 1+1
(d) Correct structures (i) ClF3 : T-shape (ii) SF4: see-saw or distorted tetrahedral
30. (a) Kc remains unchanged 1
(b) Correct answer 1
(c) Correct answer Or
1
1
(c) Correct answer
31. (a) correct calculation, Fahrenheit scale = 40oF? ½ +½
(b) Any two differences about molarity and molarity, temperature dependence
and mass/mass and mass/volume ½ +½
(c) formula and calculation, molarity of NaOH = 0.4 M ½ +½
(d) Law of multiple proportion and correct statement ½ +½
(e) correct formula n= Molecular mass/ Empirical mass 1
(f) correct calculation : Na2CO3 1
32. (a) Second law of thermodynamics: The Second Law of Thermodynamics states
that the state of entropy of the entire universe, as an isolated system, will always 1
increase over time. It also states that the changes in the entropy in the universe 1
can never be negative.
(b) Δ𝐻 = +ve and Δ𝑆 = +ve 1
(c) if both Δ𝐻 0 and Δ𝑆 0 are positive then reaction will be spontaneous at high
temperature. 1+1
(d) correct formula ΔH=ΔU + Δng RT and ΔG=ΔH - TΔS
and correct calculation
 OR 1
(a) Second law of thermodynamics.
(b) The change in enthalpy for a reaction is the same whether the reaction takes 1
place in one or a series of steps. ∆H = ∆H1 + ∆H2 + ∆H3…….
(c)

33. (a) correct structure of cis and trans but-2-ene. 1

Cis but-2-ene will have higher b.p. because of dipole moment in not equal to zero. 1
(b) Trigonal pyramidal
1
order of stability of following Carbanion: H3C −> (CH3)2CH – > (CH3)3C −
(c) IUPAC nomenclature ½ +½
(i) 2, 3 dimethyl butane (ii) 3,3 diethyl pentane ½ +½
(iii) 3-keto pentanoic acid (iv) Butene-3-yne
OR
(a) correct structure of cis and trans but-2-ene. 1
Trans- but-2-ene will have higher m.p. because of symmetrical/ close packing 1
efficiency.
(b) trigonal planer 1
order of stability of following Carbocation: (CH3)3C +> (CH3)2CH + > H3C + ½ +½
½ +½
(c) IUPAC nomenclature
(i) Isopropyl-benzene or methyl ethyl benzene (ii) Hex 4-en-1yne.
(iii) 2,2 dimethyl propane (iv) 3, 3- dimethylpentane
 KENDRIYA VIDYALAYA SANGATHAN
(IN-SERVICE COURSE 2023-24, AHMEDABAD REGION)
CLASS XI- SESSION ENDING EXAMINATION (SEE)
CHEMISTRY THEORY (043)
Max. Marks:70 Time: 3:00 hours

BLUE PRINT- SAMPLE PAPER - 04

Questions (4mark)
MCQs1 marks)

TOTAL MARKS
SA-II (3marks)
No

SA-I (2marks)

LA (5 marks)
Case based
UNIT

1 Some basic concept of 1(1) 2(1) - 4(1) - 07

chemistry

2 Structure of atom 1(1) - 3(1) - 5(1) 09

3 Classification of elements and 1(1) 2(1) 3(1) - - 06

periodicity in properties

4 Chemical bonding and 1(2) - - - 5(1) 07

molecular structure

5 Thermodynamics 1(2) 3(1) 4(1) - 09

6 Equilibrium 1(2) 2(1) 3(1) - - 07

7 Redox reaction 1(1) 3(1) - - 04

8 Organic chemistry: some basic 1(3) 2(1) 3(2) - - 11

principle and technique

9 Hydrocarbons 1(3) 2(1) - - 5(1) 10

TOTAL 16(16) 10(5) 21(7) 8(2) 1 15(3) 70(33)

 KENDRIYA VIDYALAYA SANGATHAN
(IN-SERVICE COURSE 2023-24, AHMEDABAD REGION)
CLASS XI- SESSION ENDING EXAMINATION (SEE)
SAMPLE PAPER - 04
CHEMISTRY THEORY (043)
Max. Marks:70 Time: 3:00 hours

General Instructions:
Read the following instructions carefully.
(a) There are 33 questions in this question paper with internal choice.
(b) SECTION A consists of 16 multiple -choice questions carrying 1 mark each.
(c) SECTION B consists of 5 short answer questions carrying 2 marks each.
(d) SECTION C consists of 7 short answer questions carrying 3 marks each.
(e) SECTION D consists of 2 case - based questions carrying 4 marks each.
(f) SECTION E consists of 3 long answer questions carrying 5 marks each.
(g) All questions are compulsory.
(h) Use of log tables and calculators is not allowed.
SECTION A
The following questions are multiple choice questions with one correct answer. Each
question carries 1 mark. There is no internal choice in this section.

1. Atomic mass of chlorine is 35.5. It has two isotopes of atomic mass 35 and 37. The
percentage of heavier isotope is:
(A) 10 (B) 75
(C) 20 (D) 25

2. An element has atomic number 11 and mass number 24. What does the nucleus contain?
(A) 11 protons, 13 neutrons (B) 11 protons, 24 neutrons
(C) 13 protons, 11 neutrons (D) 13 protons, 11 electrons

3. An atom with high electronegativity generally has_

(A) tendency to form positive ions. (B) More negative electron gain enthalpy
(C) large atomic size (D) high ionization enthalpy

4. Dipole moment is a measurement of the separation of two opposite electrical charges.

Identify the pair with permanent dipole moment.
(A) NO2 and CO2 (B) NO2 and O3
(C) SiF4 and CO2 (D) SiF4 and NO2

5. The standard Gibbs free energy change, ΔG°, indicates the thermodynamic favorability of
a physical or chemical process. which of the following is not correct?
(A) at equilibrium, ∆G is zero for a reversible reaction
(B) ∆G is positive for a spontaneous reaction
(C) ∆G is negative for a spontaneous reaction
(D) ∆G is positive for a non-spontaneous reaction
6. Identify the correct statements with reference to the given reaction
P4 + 3OH– + 3H2O → PH3 + 3H2PO2 –
(A) Phosphorus is undergoing reduction only.
(B) Phosphorus is undergoing oxidation only.
(C) Phosphorus is undergoing oxidation as well as reduction.
(D) None of the above

7. In quantitative analysis of carbon and hydrogen, the mass of water produced is determined
by passing the mixture through a weighed U – tube containing ‘X’ and carbon dioxide is
absorbed in concentrated solution of ‘Y’.
(A) X = CaCl2 , Y = NaOH (B) X = Ca(OH)2 , Y = CuSO4
(C) X = CuSO4 , Y = Ca(OH)2 (D) X = CaCl2 , Y = KOH

8. The number of primary (10), secondary (20) and tertiary(30) carbons in 3, 4-dimethylheptane
are respectively_
(A) 4, 3 and 2 (B) 2, 3 and 4
(C) 4, 2 and 3 (D) 3, 4 and 2

9. The equilibrium constant of the following reactions

SO2(g) + ½O2(g) ⇌ SO3(g) and
2SO2(g) +O2(g) ⇌ 2SO3(g)
are K1 and K2 respectively. The relationship between K1 & K2 is

(A)K1 = K2 (B) K22 = K1

(C) K12 = K2 (D) K2 = √K1

10. The reaction quotient (Q) for the reaction

N2 (g) + 3H2 (g) ⇌ 2NH3 (g) is given by Q = [NH3]²/[N2][H2]³

The reaction will proceed from right to left if

(A) Q = Kc. (B) Q < Kc
(C) Q > Kc. (D) Q = 0

11. Which of the following cannot be prepared by Wurtz reaction?

(A) Ethane (B) Methane
(C) Butane (D) Hexane

12. The reaction of benzene with an acetyl chloride or acetic anhydride in the presence of
Lewis acids yields
(A) Acetophenone (B) Nitrobenzene
(C) n-propyl benzene (D) Ethylbenzene
Q. 13 – 16 Given below are two statements labelled as Assertion (A) and Reason (R)
Select the most appropriate answer from the options given below:
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correct explanation of A.
(c) A is true but R is false.
(d) A is false but R is true.

13. Assertion (A): pi bonds are weaker than σ bonds.

Reason(R): pi bonds are formed by the sidewise overlapping of p-orbital.

14. Assertion (A): Combustion of all organic compounds is exothermic process.

Reason (R): The enthalpies of all elements in their standard state are zero

15. Assertion(A): Different number of electron pairs are present in resonance structures.
Reason(R): Resonance structures differ in the location of electrons around the
constituent atoms.

16. Assertion(A): Pentane and 2-Methylbutane are non-polar in nature.

Reason(R): Boiling point of Pentane is higher than that of 2-Methylbutane

SECTION B
This section contains 5 questions with internal choice in one question. The following
questions are very short answer type and carry 2 marks each.

17. (a)Which orbital is partially filled in actinoids, write general electronic configuration of
f-block elements.
(b)Write electronic configuration of second element of chalcogen family.

18. Name the isomerism shown by 2-methyl propene and butene and draw all the possible
isomers having double bond, the compound having molecular formula C4H8

19. (a) Among propene and propyne which one is more acidic and why?
(b) Write chemical reaction when ethyne gas is allowed to pass over red-hot iron tube.

20. For the endothermic reaction

PCl5 ⇌ PCl3 + Cl2 at 473K the value of equilibrium constant Kc is 8.3 x10-3 .
(a) Write an expression for Kc.
(b) What is the value of Kc for reverse reaction at same temperature.
(c) What would be effect on Kc if pressure is increased.
(d) What will be the direction of shifting equilibrium on increasing temperature?

21. (a) Hydrogen and oxygen combine to form two products water (H2O) and hydrogen
peroxide (H2O2), Which law of chemical combination is obeyed here state the law.
(b) How many moles of helium is present in 8g of helium? Support your answer?
OR
A compound made up of two elements A and B has A= 70 %, B = 30 %. Their relative number
of moles in the compound are 1.25 and 1.88. calculate_
(a) Atomic masses of the elements A and B
(b) Molecular formula of the compound, if its molecular mass is found to be 160

SECTION C
This section contains 7 questions with internal choice in one question. The following
questions are short answer type and carry 3 marks each.

22. (a) What is Aufbau’s principle? What is the significance of this principle?
(b) Calculate (i)wavenumber & (ii) frequency of yellow radiation having wavelength 5800 A0.
[h= 6.6 X 10-34Js (Kg m2 S-1), c = 3 X 108 ms-1, 1 A0 = 10-10 m]

23. (a) Name the quantum number used to determine orientation of an atomic orbital.
(b) State Heisenberg’s uncertainty principle and Pauli’s rule.
(c) The outer electronic configurations of some elements are:
(i) 3d4 4s1 (ii) 3d10 4s2 : Identify the element.

24. Give reason

(a) O has lower ionization enthalpy than nitrogen?
(b) Cations are smaller and anions larger in radii than their parent atom.
(c) Noble gases have positive electron gain enthalpy values. Explain.

25. (a) Name the such property which does not depends on the amount of the matter.
(extensive/intensive) and choose such properties from the following
Temperature, density, Pressure, Molar heat capacity and enthalpy
(b) write a relationship between Gibbs Energy Change and Equilibrium Constant
(c) Derive the relationship between Cp and Cv.
OR
(a) State first law of thermodynamics.
(b) Define Hess’s Law of constant heat summation
(c) The equilibrium constant for a reaction is 10. What will be the value of ∆G?
R=8.314 JK-1mol-1, T=300K
26. (a) Differentiate between the principle of estimation of nitrogen by Duma’s method and
Kjeldahl’s method
(b) In the estimation of Sulphur by Carius method, 0.468 g of an organic Sulphur compound
gives 0.668 g of barium sulphate. Find the percentage of Sulphur in the given compound.
[At. mass; Ba = 137 u, S = 32 u, O =16 u]
OR
(a) Explain the reason for the fusion of an organic compound with metallic sodium for testing
nitrogen, sulphur and halogens.
(b)Explain why alkyl groups act as electron donors when attached to a π system.
(c) Name the technique used to separate (any two)
(i) the mixture of o-nitro phenol and p- nitro phenol.
(ii) aniline – water mixture
(iii) separation of Glycerol from spent-lye in soap industry.
27. (a)Write conjugate base for H2O and NH4+ species.
(b)Calculate the pH of the following solution:
(i) 10-3 molar HCl aq solution
(ii) 10-4 molar NaOH aq solution
28. SELECT ANY THREE
(a) Identify the oxidizing and reducing agent for the reaction
N2H4(l) + 2H2O2(l) → N2(g) + 4H2O(l)
(b) In a reaction an element in one oxidation state is simultaneously oxidized and reduced,
name the reaction with proper example.
(c) Balance the following redox reaction by ion electron (reaction half) method showing all
the steps: 𝑀𝑛𝑂4− + 𝐶2 𝑂42− + 𝐻 + → 𝑀𝑛2+ + 𝐶𝑂2 + 𝐻2 𝑂
(d) Balance the following redox reaction by ion electron (reaction half) method showing all
the steps:
MnO4–(aq) + Br–(aq) → MnO2(s)+ BrO3– (aq) [Basic medium]

SECTION D
The following questions are case -based questions. Each question has an internal choice and
carries 4 (1+1+2) marks each. Read the passage carefully and answer the questions that
follow.

29. Mr Pinakin, a primary school teacher and highly expert in data handling attended several
chemistry-based workshops as a data operator or as computer expert. As his curious nature
he learnt somewhat basic concept of chemistry, like concentration terms mass percentage,
molality, molarity and mole fraction etc. He heard that one mole of nitrogen and three moles
of hydrogen react together to form two moles of ammonia. He also heard that combustions
of hydrocarbon are exothermic in nature to produce carbon di-oxide and water. The limiting
reactant (or limiting reagent) is the reactant that gets consumed first in a chemical reaction
and therefore limits how much product can be formed. He also learned that one mole of every
substance have equal no of particles i.e 6.022×1023. The volume occupied by one gram-mole
of gas is about 22.4 litres at standard temperature and pressure (0°C, 1 atmosphere) and is
the same for all gases, according to Avogadro’s law. At evening he thought if I burnt whole
coal (charcoal) available at my home (01 kg) in the free supply of air what amount of carbon
di-oxide produced during course of chemical reaction? He was confused that water will be
produced or not during this reaction. He also knows atomic mass of carbon i.e. 12 u.
Read the above passage assuming coal is pure carbon and undergoing complete
combustion, answer the following questions.
 (a) In above situation, what amount of CO2 produced?
(b) Identify the limiting reagent in the above situation when Mr Pinakin burned total
coke available at his home, if any.
(c) What amount of coal (coke) needed Mr Pinakin to produce 44.8 L of CO2 in free
supply of air (O2)?
(d) Calculate the number of moles of coal that Mr Pinakin had at home.
OR
Calculate the number of carbon atoms that Mr Pinakin had at home.

30. We can measure the transfer of heat from one system to another which cause change in
temperature. The magnitude of change in temperature depends upon heat capacity of the
substance. The enthalpy change of reaction remains the same irrespective of number of steps
is Hess's law. It helps to calculate enthalpy of formation, combustion and other enthalpy
changes. Enthalpy change can also be calculated by using bond enthalpies. First law gives law
of conservation of energy but does not give direction of reaction. Second law states, entropy
of universe is continuously increasing due to spontaneous processes taking place in it. ΔH and
ΔS (entropy change) cannot decide spontaneity of process. We need ΔG (free energy change)
which is -ve for spontaneous, +ve for non-spontaneous. ΔG = 0 for process in equilibrium. ΔG
is related to equilibrium constant. If ΔG = -ve, 'K' is +ve and vice versa. Third law of
thermodynamics states the entropy of perfectly crystalline substance is zero at zero kelvin.

(a) We can determine ΔH lattice with the help of cycle. Name the law of constant heat
summation and name the cycle.
(b) ΔH0f of O3, CaO, NH3 and HI are +142.2, - 643.9, -46, +25.95 kJ mol-1. Arrange these in
increasing order of stability.
(c) Under what conditions the following reactions will be spontaneous:
(i) Reaction with both ∆H and ∆S positive
(ii) reaction with both ∆H and ∆S negative.
OR
(c) Predict in which of the following, entropy increases/decreases:
(i) A liquid crystallizes into a solid.
(ii) Temperature of a crystalline solid is raised from 0 K to 115 K.

SECTION E
The following questions are long answer type and carry 5 marks each. All questions have an
internal choice.

31. (a) Which orbital is non-directional?

(b) Draw the shapes of px & dx2-y2 orbitals.
(c) Write de Broglie relation
(d)Write any two limitations of Bohrs model of an atom.
(e) What is the maximum number of emission lines when the excited electron of a H
atom in n = 6 drops to the ground state?
(f) What are the frequency and wavelength of a photon emitted during a transition from
 n = 5 state to n = 2 state in the hydrogen atom?
(g) Calculate the wave number for the longest wavelength transition in the Balmer series of
atomic hydrogen.

32. (a) Give Reason:

(i) All P-Cl bonds in PCl5 molecule are not equal.
(ii) N2 is less reactive than O2
(iii) BF3 is non polar while NH3 is a polar molecule.
(b) On the basis of VSEPR theory draw the structure of the following:
(i) BrF3 (ii) XeO3
OR
(a) Distinguish sigma (  ) and a pi (  ) bond. (Any two)
(b) Which out of NH3 and NF3 has higher dipole moment and why?
(c) write any two limitations of octet rule.
(d) What is meant by the term bond order? Calculate the bond order of O2+ with help of
molecular orbital diagram.

33. (a) Explain giving suitable reactions:

(a) Markovnikov’s rule (b) Wurtz reaction. (c) β – elimination.
(b) An alkene ‘A’ on ozonolysis gives a mixture of ethanal and pentan-3-one.
(a) Write structure and IUPAC name of ‘A’.
(b) Give the reaction involved.
OR
(a) What are the necessary conditions for a compound to be an aromatic?
(b) How will you convert:
(i) Benzene to p-nitro bromobenzene (ii) Ethyl chloride to ethene.
(c) What happens when addition of HBr to propene takes place in the presence of peroxide.
Give mechanism.

************* THE END************

 KENDRIYA VIDYALAYA SANGATHAN
(IN-SERVICE COURSE 2023-24, AHMEDABAD REGION)
CLASS XI- SESSION ENDING EXAMINATION (SEE)
MARKING SCHEME SAMPLE PAPER - 04
CHEMISTRY THEORY (043)

Q Answer Marks
No
1. D 1
2. A 1
3. B 1
4. B 1
5. B 1
6. C 1
7. D 1
8. A 1
9. C 1
10. C 1
11. B 1
12. A 1
13. A 1
14. B 1
15. D 1
16. B 1
17. (a) 5f-orbital, (n−2)f1-14(n−1)d0-1ns2 ½+ ½
(b) The second element of the chalcogen family is Sulphur. Electronic +1
configuration of Sulphur is: 1s2 2s2 2p6 3s2 3p4 OR 2,8,6.
18. Chain isomerism ½×4=
Correct structure of all possible 03 isomers: 2
(i) CH3-CH2-CH=CH2 (ii) CH3-CH=CH-CH3 (iii) CH3-CH(CH3)=CH2
19. (a) propyne is more acidic because of sp hybridisation (more % of s- characters, 1
high electronegativity etc)
(b) Ethyne gas is allowed to pass over red-hot iron tube to form benzene 1
(correct equation).
20. (a) expression for Kc. ½
(b) Kc for reverse reaction ½
(c) Equilibrium shifted towards backwords direction to intact same value of Kc. ½
(d) Equilibrium shifted towards forewords direction ½
21. (a) Law of multiple proportions ½
law of multiple proportions states that if two elements form more than ½
one compound, then the ratios of the masses of the second element which
combine with a fixed mass of the first element will always be ratios of small
whole numbers.
(b) moles of helium present in 8g of helium = 8/4 = 2 moles
1
OR
 Atomic mass of elements A =
% Percentage of element A/ relative number of moles of A
= 70/1.25 = 56 u
Atomic mass of elements B = ½
% Percentage of element B/ relative number of moles of B
= 30/1.88 = 16 u

Simplest molar Ratio Simplest whole number ratio A =

= 1.25/1.25 = 1 ½

Simplest molar Ratio Simplest whole number ratio B = = 1.88/1.25= 1.5

A: B :: 1:1.5 :: 2:3
∴ Empirical formula of compound = A2B3
Molecular mass = 160
Empirical formula mass = 2(56) + 3(16) = 112 + 48 = 160
n = Molecular mass/ empirical mass = 160/160 = 1
∴ Molecular formula = n x Empirical formula = 1 x A2B3 = A2B3 1

22. (a) The Aufbau principle states that electrons fill lower-energy atomic orbitals
before filling higher-energy ones, by following this rule, we can predict the ½+½
electron configurations for atoms or ions.
(b) Wavelength of light =5800×10-10 m
Frequency = c/ wavelength
= 3×108 ms-1 / 5800×10-10 m 1
= 0.05 ×1016 s-1
wave no.is reciprocal of wavelength
wave no. = 1/ 5800×10-10 m
= 0.017 ×10-8 m-1 1
23. (a) Magnetic quantum number 1
(b) Statement of Heisenberg’s principle and Pauli’s rule ½+½
(c) The outer electronic configurations of some elements are:
½+½
(i) Chromium (Cr) (ii) Zinc (Zn)

24. (a) Oxygen has lower ionisation enthalpy than nitrogen because by removing 1
one electron from 2p - orbital oxygen acquires stable configuration, i.e.,2p3
On the other hand, in case of nitrogen it is not easy to remove one of the three
2p - electrons due to its stable configuration.
(half-filled electronic configuration)

(b) Cation are smaller & anions larger in radii than their parent atoms because
there is a loss of electrons from valence shell in the case of cation, so decreases
the shell number and in the case of anion there is addition of electrons. which 1
cause decreases in size of cation and increases the size of anion.

(c) they have stable electronic configuration and thus have no tendency to take 1
additional electron
25. (a) Extensive property 1
Temperature, density, Pressure, Molar heat capacity
 (ii) ΔG=RT ln Q OR ΔG=2.303 RTlog Kc
If ΔG = 0, then K = Q, and the reaction is at equilibrium. ½
(iii) we know that q = n C ∆T
At constant pressure P, qP = n CP ∆T = ∆H
Similarly, at constant volume V, 1½
qV = n CV ∆T = ∆U
For one mole of an ideal gas (n=1), we know that
∆H = ∆U + ∆(pV) = ∆U + ∆(RT) = ∆U + R ∆T.
So, we can say that ∆H = ∆U + R ∆T.
Substituting the above values for ∆H and ∆U into the equation, we get:
CP ∆T = CV ∆T + R ∆T
CP = CV + R
CP – CV = R
OR 1
(a) Energy cannot be created or destroyed; it can only be converted from one form
to another. 1
(b) The change in enthalpy for a reaction is the same whether the reaction takes
place in one or a series of steps. ∆H = ∆H1 + ∆H2 + ∆H3……. ½+½
(c) ΔG0=−2.303RTlogK=−2.303×8.314×300log10=−5.744kJ/mol
26. (a) In Dumas method, a known quantity of nitrogen containing organic compound is
heated strongly with excess of copper oxide in an atmosphere of carbon dioxide to
produce free nitrogen in addition to carbon dioxide and water. nitrogen evolved from
the organic compound is measured and then estimated.

On the other hand, in Kjeldahl’s method, a known quantity of nitrogen containing

organic compound is heated with concentrated sulphuric acid. The nitrogen present
in the compound is quantitatively converted into ammonium sulphate. ammonia
which then is estimated volumetrically.

(b)

OR

(a) The elements such as halogens, nitrogen and sulphur are covalently bonded to the
organic compounds. For their detection, we need to convert them to their ionic form
for performing respective tests for their detection. As per principle, on fusion Na
converts all elements present in an organic compound in ionic form

(b) When an alkyl group is attached to a π system it acts as an electron-donor group

by the process of hyperconjugation. This type of overlap leads to a delocalisation also
 known as no-bond resonance of the π electrons making the molecule more stable. Or
by taking any example.

(c) (i) fractional distillation (ii) steam distillation (iii) distillation under reduced
pressure

27. (a) NH2- is the conjugate acid of NH3.

OH- is the conjugate base of H2O.
(b) (i) [H+] = 10-3 M, pH = −log[10-3], pH = 3
(ii) [OH–] = [NaOH] = 0.0001 M = 10-4 M
pOH = –log [OH–] = –log(10-4)= 4
pH = 14 – pOH = 14 - 4 = 10
28. (a) H2O2 is an oxidizing agent and N2H4 is a reducing agent 1
(b) disproportionation reaction with example ½+½
(c) stepwise balancing the reaction to get
2MnO-4+16H+ + 5C2O2-2→2Mn2++10CO2+8H2O. 2
(d) stepwise balancing the reaction to get
2MnO4- +Br- + H2O → 2MnO2+BrO3-+2OH- 2
29. (a) 12 g of C can produce = 44 g of CO2 1
1000 g of carbon can produce CO2 = 44 × 1000/12 = 3667 g CO2
(b) Carbon is the limiting reagent 1
(c) number of moles of coal that Mr Pinakin had at home= 1000/12 =83.3
OR 2
(c) number of carbon atoms that Mr Pinakin had at home = 1000/12*NA
or correct calculation
30. (a) Born Haber cycle. Hess law of Heat summation. ½+½
(b) O3< HI < NH3< CaO ; increasing order of stability.
(c) For a reaction to occur spontaneously, ΔG must be negative so,
1
(i) When both ∆H and ∆S positive then it will be spontaneous at very high
temperature only. 2
(ii) When both ∆H and ∆S negative the it will be spontaneous at low
temperature only.
OR
(c) (i) A liquid crystallizes into a solid. entropy decreases:
(ii) Temperature of a crystalline solid is raised from 0 K to 115 K: entropy
increases.
31. (a) s-orbital is non-directional? 1
(a) Correct structure / shapes of px & dx2-y2 orbitals. 1
(c) De Broglie relation says that an electron's wavelength and momentum
½+½
have a relationship, which is given by p = h/mv.
(d) Any two limitations of Bohrs model of an atom. 1
(e) 15 lines 1
(f) Correct answer (λ = 434 nm) 1
1
 (g)

32. (a) Since two axial P-Cl bonds are repelled by three bond pairs each while three 1
equatorial P-Cl bonds are repelled by two bond pairs each, therefore axial
bonds are longer and hence weaker as compared to more stable equatorial
bonds. Thus, all the five P-Cl bonds in PCl5 are not equivalent.

(b) Bond order of N2=3, bond order of O2=2. Higher the bond order, higher is
the bond dissociation energy i.e., higher stability or less reactivity. Thus, N2 is
1
less reactive than O2

(c) Though the B−F bond in BF3 is polar, but they arrange themselves in trigonal
planar geometry and hence cancel out each other due to symmetry. Therefore,
there is no net dipole moment. Whereas in NH3, the shape of molecule is 1
trigonal pyramidal with no symmetry, hence there is a net dipole moment

(b) the structure (i) BrF3 ; bent-T 1

1
(ii) XeO3 : Trigonal pyramidal

OR
(a) Any two correct differences between a sigma (  ) and a pi (  ) bond ½+½
(b) NH3 and NF3 both have a geometry that is pyramidal in nature. For each 1
molecule, N denotes an atom that has only one pair. On the other hand, F
represents electronegative molecules. Hence, the H & N- F bond has higher
 polarity than bonds denoting N-H. It is estimated that the dipole of NH3 will be
1.46 D, while NF3 will be measured as 0.24D at the same time.
Thereby NH3 will have a high dipole when compared to NF3. all bonds denote
that N-H proceeds in the same direction, adding the number of lone pairs. On
the other hand, bonds with the denotation of N-F move in the opposite
direction, which cuts down the sole pair moment.

(c) Any two limitations of octet rule.

(d) Bond order is the number of chemical bonds between a pair of atoms and ½ + ½
indicates the stability of a bond. For example, in diatomic nitrogen, N≡N, the
1
bond order is 3; in acetylene, H−C≡C−H, the carbon-carbon bond order is also
3, and the C−H bond order is 1.
OR explanation on the basis of MOT.
Calculation of the bond order of O2+ with help of M O diagram. = 2.5
1
33. (i) Markovnikov’s rule
According to Markovnikov's rule, during addition reaction on unsymmetrical
alkene the negative part of addendum (adding molecule) gets attached to that
doubly bonded C which possess lower number of hydrogen atoms. ½ +½
Any reaction related to Markovnikov’s rule
(ii) Wurtz reaction.
Wurtz’s reaction is an organic chemical coupling reaction wherein sodium
metal is reacted with two alkyl halides in the environment provided by a
solution of dry ether in order to form a higher alkane along with a compound
containing sodium and the halogen.
Any example related to Wurtz reaction
(iii) β – elimination. ½ +½
A beta-elimination reaction generally involves the cleavage of a sigma (σ) bond
at the position beta (β) to a pair of electrons that departs a molecule via a
nucleophilic leaving group, subsequently leading to the formation of a new pi
(π) bond.
Any example related to β – elimination

(b) An alkene ‘A’ on ozonolysis gives a mixture of ethanal and pentan-3-one. ½ +½

(i) IUPAC name : 3-Ethylpent-2-ene.

(ii) correct reaction involved.
OR ½ +½
(a) A compound is said to be aromatic if it satisfies the following three
conditions:
1
(i) It should have a planar structure.
(ii) The π–electrons of the compound are completely delocalized in the ring.
(iii) The total number of π–electrons present in the ring should be equal to (4n
+ 2), where n= 0, 1, 2 … etc. This is known as Huckel’s rule.

(b) (i) Benzene to p-nitro bromobenzene

Electrophilic aromatic substitution of benzene with bromine in presence of
ferric bromide gives bromobenzene. Nitration with conc. nitric acid and
concentric sulphuric acid give a mixture of ortho-bromonitrobenzene and
para-bromo nitrobenzene which are separated by fractional distillation. 1

(ii) Ethyl chloride to ethene.The conversion of Ethyl chloride to Ethene is a

dehydrohalogenation reaction as in this reaction removal of hydrogen and a
halogen takes place. When alcoholic KOH will be treated with an alkyl halide,
1
an elimination reaction will take place.

CH3CH2Cl+KOH→C2H4+KCl+H2O

(c) mechanism of addition of HBr to propene in the presence of peroxide.

In presence of peroxide, HBr adds on alkenes in anti-markovnikov's way, thus
H3C−CH=CH2Propene+HBrPeroxide→H3C−CH2−CH2Brn−propyl bromide
1+1
Kharasch observed that the addition of HBr to unsymmetrical alkene in the
presence of organic peroxide follows an opposite course to that suggested by
Markovnikov. This is termed anti-Markovnikov or peroxide effect.
Step by step.
 KENDRIYA VIDYALAYA SANGATHAN
(IN-SERVICE COURSE 2023-24, AHMEDABAD REGION)
CLASS XI- SESSION ENDING EXAMINATION (SEE)
CHEMISTRY THEORY (043)
Max. Marks:70 Time: 3:00 hours

SAMPLE PAPER NO- 5

BLUE PRINT
SN Name of chapter MCQ (1M) SA I SA II CBQ LA (5M) TOTAL
(2M) (3M) (4M)
1 Some basic concepts of chemistry 2(2) 1(2) 1(3) 4Q (7M)
2 Structure of atom 2(2) 1(3) 1(5) 4Q (9M)
3 Classification of elements and periodicity in 2(2) 1(3) 4Q (6M)
properties
4 Chemical bonding and molecular structure 2(2) 1(2) 1(3) 4Q (7M)
5 chemical thermodynamics 2(2) 1(2) 1(5) 4Q (9M)
6 equlibrium 1(1) 1(2) 1(4) 3Q (7M)
7 Redox reactions 1(1) 1(3) 2Q (4M)
8 Organic chemistry- some basic principles and 3(3) 1(2) 2(6) 6Q (11M)
techniques
9 hydrocarbons 1(1) 1(4) 1(5) 3Q (10M)
TOTAL 16Q(16M) 5Q(10M) 7Q(21M) 2Q(8M) 3Q(15M) 33Q(70M)

Note: No overall choice. However internal choice one question in 2M, one Q in 3M, two Q in 5M and in both CBQ –sub
division c (2M -Q)
 KENDRIYA VIDYALAYA SANGATHAN
(IN-SERVICE COURSE 2023-24, AHMEDABAD REGION)
CLASS XI- SESSION ENDING EXAMINATION (SEE)
CHEMISTRY THEORY (043)
Max. Marks:70 Time: 3:00 hours

SAMPLE PAPER NO- 5

General Instructions:
Read the following instructions carefully.
(a) There are 33 questions in this question paper with internal choice.
(b) SECTION A consists of 16 multiple -choice questions carrying 1 mark each.
(c) SECTION B consists of 5 short answer questions carrying 2 marks each.
(d) SECTION C consists of 7 short answer questions carrying 3 marks each.
(e) SECTION D consists of 2 case - based questions carrying 4 marks each.
(f) SECTION E consists of 3 long answer questions carrying 5 marks each.
(g) All questions are compulsory.
(h) Use of log tables and calculators is not allowed.
SECTION A
1 For which of the following set of quantum numbers, an 1
electron will have the highest energy?
(a) 3, 2, +1, +1/2 (b) 4, 2, -1, +1/2
(c) 4, 1, 0, -1/2 (d) 5, 0, 0, +1/2.

2
The maximum number of electrons in a sub shell with, l=3 and 1
n=4 is;
(a) 16 (b) 10 (c) 12 (d) 14

3 What will be the molarity of a solution, which contains 5.85 g 1

of NaCl(s) per 500 mL? (Atomic mass of Na=23u,Cl=35.5u)
(a) 4 mol L–1 (b) 20 mol L–1 (c) 0.2 mol L–1 (d) 2 mol L–1

4 The atomic number of the element which belongs to 7th period

and has the IUPAC name as unnilennium is: 1
a) 102 b) 109
c) 119 d) 108
5 The enthalpy of formation of a compound is: 1
a) Always positive c) Either negative or positive
b) Always negative d) Is never negative
6 The displacement of electrons in a multiple bond in the
presence of attacking reagent is called? 1
a) Inductive effect b) Electrometric effect
c) Resonance effect d) Hyper conjugation
Correct IUPAC name for the following compound is
7

(a) 2- ethyl-3-methylpentane
(b) 3,4- dimethylhexane
(c) 2-sec-butylbutane
(d) 2, 3-dimethylbutane
8 When 1-bromopropane reacts with Na metal in presence of 1
dry ether, it gives ……………………… and named as ………..
(a) 2, 3-dimethyl butane, Friedel Craft’s reaction.
(b) iso-propane, Wurtz reaction
(c) n-hexane, Wurtz reaction
(d) n-hexane, Fittig reaction
9 The elements in which electrons are progressively filled in 4f-
orbital are called
(a) actinoids 1
(b) transition elements
(c) lanthanoids
(d) halogens
10 When 1 mol of gas is heated at constant volume and
temperature is raised from 298K to 308K. Heat supplied to the 1
gas is 500 J. Choose the correct statement for the given
process:
a) q =W=500 J, ∆U>0
b) q = ∆U=500 J, W=0
c) q =W=500 J, ∆U=0
d) ∆U=0, q=W = - 500 J
11 Identify the disproportionation reaction 1
(a) CH4 + 2O2 → CO2 + 2H2O
(b) CH4 + 4Cl2 → CCl4 + 4HCl
(c) 2F2 + 2OH– → 2F– + OF2 + H2O
(d) 2NO2 + 2OH– → NO2– + NO3 – + H2O
12 The molecular formula of diphenyl methane is C13H12. 1
How many structural isomers are possible when one of
the hydrogen is replaced by a chlorine atom?
(a) 8 (b)7 (c) 4 (d) 9

In the following questions (Q. No. 13 - 16) a statement of

assertion followed by a statement of reason is given. Choose
the correct answer out of the following choices.
A) Assertion and reason both are correct statements and
reason is correct explanation for assertion.
B) Assertion and reason both are correct statements but
reason is not correct explanation for assertion.
C) Assertion is correct statement but reason is wrong
statement.
D) Assertion is wrong statement but reason is correct
statement.
13 Assertion (A): Energy of resonance hybrid is equal to the
average of energies of all canonical forms.
Reason (R): Resonance hybrid cannot be represented by a 1
single structure.
14 Assertion(A): van der Waals radius is considered to be largest
while covalent radius of an atom is the smallest. 1
Reason(R): van der Waals radius is one-half the distance
between the nuclei of two non-bonded isolated atoms.
15 Assertion (A) : The bond order of helium is always zero
Reason (R) : The number of electrons in bonding molecular 1
orbital and antibonding molecular orbital are equal.
16 Assertion (A) : For any chemical reaction at a particular 1
temperature, the equilibrium constant is fixed and is a
characteristic property.
Reason (R) : Equilibrium constant is independent of
temperature.
SECTION B
17 (a)If two elements can combine to form more than one
compound, the masses of one element that combine with a (1+1)
fixed mass of the other element, are in the whole-number
ratio. Is this statement true? If yes, according to which law?
(b) Calculate the number of molecules in 2.2 g of CO2
18. Mention the state of hybridization and geometry of 2
i) methyl carbocation and
 ii) methyl carbonanion.

19 Two different bond lengths are observed in PCl5 molecules but 2

only one bond length is observed in SF6. Explain.
20 The solubility product of A2B is 32 X 10-9 mol3L-1. Calculate its 2
solubility.
21 (i)The molar enthalpy of vapourisation of acetone is 2
less than that of water. Why?
(ii) At absolute zero the atoms or molecules do not
move at all in the perfectly crystalline state. Find out
the entropy of the above substance.
OR
For the reaction; 2Cl(g) ———-> Cl2(g); what will
be the signs of ∆H and ∆S? Explain with reason.

SECTION C
22. A compound on analysis is found to contain following 3
percentage composition:
Na= 43.4%, C=11.4%, O= 45.3%. Determine the empirical and
molecular formula of the compound, given molecular mass of
the compound is 106.
(Atomic Mass: C=12, O=16, Na=23)
23. Answer any three (1 x 3 )
(a) Arrange the following species in increasing order of their
ionic size: N3–, Na+, F–, O2–
(b) Out of P and S , which element has higher ionization
enthalpy, give reason.
c) ) Out of O and S , which element has lower -ve electron
gain enthalpy, give reason
d) Noble gases have positive electron gain enthalpy. Give
reason
24 (a)Write electronic configuration of N2 molecule as per MOT (2+1)
and calculate its bond order and predict its magnetic
properties.
b) H2O is a liquid whereas H2S is a gas at room temperature.
Justify.
25 If the uncertainty in the velocities of two particles A and B with 3
masses of 1.0 × 10-27 kg and 1.0 × 10-31 kg, respectively, are
same, what will be the ratio of uncertainty in their positions?
 OR
What is the de Broglie’s wavelength that is associated with
motion of earth orbiting around the sun at a speed of
3x106m/s?
(mass of earth = 6x1024kg; Planck constant= 6.6 X 10-34 J s)

26 Balance the following ionic equation by ion electron method 3

I-+ MnO4-+ --→ I2 + Mn2+ (in acidic medium)
27. (a) From the resonating structures of aniline justify that NH2 (1+2)
group is ortho , para directing group..
(b) In Carius method of estimation of halogen, 0.15 g of an
organic compound gave 0.12 g of AgBr. Find out the
percentage of Br in the compound. (At. mass of Ag = 108, Br
= 80)
28. Write all the isomers of C4H10O and give examples with any 3
pair of the same, as chain, position, functional isomers and
metamers.
SECTION D
29. Aromatic compound, any of a large class of (1+1+2)
unsaturated chemical compounds characterized by one or
more planar rings of atoms joined by covalent bonds of two
different kinds. The unique stability of these compounds is
referred to as aromaticity. Although the
term aromatic originally concerned odour, today its use
in chemistry is restricted to compounds that have particular
electronic, structural, or chemical properties. Aromaticity
results from particular bonding arrangements that cause
certain π (pi) electrons within a molecule to be strongly held.
Aromaticity is often reflected in smaller than expected heats
of combustion and hydrogenation and is associated with low
reactivity.
Chemical bonding in benzene:
Benzene (C6H6) is the best-known aromatic compound and the
parent to which numerous other aromatic compounds are
related. The six carbons of benzene are joined in a ring, having
the planar geometry of a regular hexagon in which all of the
C—C bond distances are equal. The six π electrons circulate in
a region above and below the plane of the ring,
each electron being shared by all six carbons, which maximizes
the force of attraction between the nuclei (positive) and the
 electrons (negative). Equally important is the number of π
electrons, which, according to molecular orbital theory, must
be equal to 4n + 2, in which n = 1, 2, 3, etc. For benzene with
six π electrons, n = 1.
(a)Identify whether the following system is aromatic or non-
aromatic.

( b) Why does benzene show electrophilic substitution

reactions more commonly than addition reactions?
(c )Mention all necessary conditions to be satisfied for a
molecule to be aromatic.
OR
( c) Explain the effect of activating and deactivating group on
benzene with example.
30. Equilibrium is possible only in a closed system at a given (1+1+2)
temperature. Equilibrium can be established for both physical
and chemical reactions. The reaction may be fast or slow
depending upon the experimental conditions and the nature of
the reactants. When the reactants in a closed vessel at a
particular temperature react to give the products keep on
increasing for sometimes after which there is no change in the
concentrations of either of the reactants or products. This
stage of the system is the dynamic equilibrium. At equilibrium
the ratio of concentration of product to concentration of
reactant is constant and this statement is known as law of
equilibrium. Equilibrium state may be disturbed by changing
external factors like pressure, temperature, concentration etc.
a) Chemical equilibrium is dynamic in nature. Write yes or
no and justify your answer.
b) When water is heated in an open vessel, it does not
attain the equilibrium state. Why?
c) (i) Predict the condition for equilibrium state.
(ii) H2O(l) H2O(g) Which characteristic property can
be defined?

OR
 c)Write any two favourable conditions to obtain maximum
yield in Haber’s process.
N2+ 3H2  2NH3 + heat

SECTION E
31 How will you convert the following (any five) (1 x 5)
(i) benzene to acetophenone
(ii) Phenol to benzene.
(iii) Chlorocyclohexane to cyclohexene
(iv) ethyne to benzene
(v) Ethyne to ethanal
(vi) Propene to 2-Bromoprpane
(vii) benzene to nitrobenzene
32. (a)Calculate w, q & ΔU when 0.75mole of an ideal gas expands (3+2)
isothermally & reversibly at 27∘C from volume 15L to 25L.
(log 5 = 0.6990, log 3 = 0.4771)
( b)For the reaction 2 A(g) + B(g) → 2D(g) ,∆U° = –10.5 kJ.
Calculate ∆H° for the reaction.
OR
(a) Standard molar enthalpy of formation, ∆f H0 is just a (2+3)
0 0
special case of enthalpy of reaction, Δr H . Is the Δr H for
the following reaction same as Δf H0?
CaO(s) + CO2(g) → CaCO3(s); Δf H0 = –178.3 kJ mol–1.
Give reason for your answer.
(b) Calculate the standard enthalpy of formation of CH3OH
from the following data:
(i) CH3OH(l) + 3/2 02 (g) ———-> CO2 (g) + 2H20 (l);
∆rHϴ = – 726 kJmol-1
(ii) C(s) + 02(g) —————>CO2 (g);∆cH ϴ = -393 kJmol-1
(iii) H2(g) + 1/2O2(g) —————->H20 (l);
∆fH ϴ = -286 kJ mol-1
33. (a) A mono positive ion of 3d transition element has no (2+3)
unpaired electron. Identify the element and write its electronic
configuration in ground state.
(b) An electromagnetic radiation of wavelength 242 nm is just
sufficient to ionize a sodium atom. Calculate ionization enthalpy
of sodium in kJmol−1
 OR
(a) Write electronic configuration of Co3+. (Z=27) (1+1+1+2)
(b) Find out the number of unpaired electrons in Fe3+ (Z=26)
(c) Electronic energy in a particular orbit is expressed with a
negative sign. Why?
(d) Calculate the number of radial and angular nodes in
i) 5p
ii) 4d

****************************************************************
 KENDRIYA VIDYALAYA SANGATHAN
(IN-SERVICE COURSE 2023-24, AHMEDABAD REGION)
CLASS XI- SESSION ENDING EXAMINATION (SEE)
CHEMISTRY THEORY (043)
Max. Marks:70 Time: 3:00 hours

SAMPLE PAPER NO-5

MARKING SCHEME
1 b 2 d 3 c 4 b 5 c 6 b
7 b 8 c 9 c 10 b 11 c 12 c
13 D 14 A 15 A 16 C

17 (a) YES, Law of multiple proportion 1

(b) 3.0101 X1022 `1
18. Carbonanion: sp3, tetrahedral ½ each
Carbocation : sp2, planar
19 - Two types of bonds in trigonal bipyramidal i.e PCl5 2
- One type of bond in octahedral in SF6
20.
1/2

1 mole of gives 2 moles of and 1 mole of B ½

Thus if solubility of is s moles/litre, solubility of A is 2s
moles/litre and solubility of B is s moles/litre 1/2

Therefore,
,
,
½
Hence, the solubility of is

21 (i) Acetone- dipole -dipole interaction and water – H bond 1

1
(ii) Zero

OR

Negative, negative and proper reason 1+1

22 Element % Atomic No of Simplest ratio ½

converted Mass moles
to mass
(g)
𝟒𝟑.𝟒 𝟐𝟑 𝟏.𝟖𝟖 𝟎.𝟗𝟓 = 𝟏.97 ~𝟐
Na 43.4g 23
=1.88
½
C 11.4g 12 𝟏𝟏.𝟒 𝟏𝟐 𝟎. 𝟗𝟓 𝟎. 𝟗𝟓 = 𝟏
=0.95 ½
 O 45.3 g 16 𝟒𝟓. 𝟑 𝟏𝟔 𝟐. 𝟖𝟑 𝟎. 𝟗𝟓 = 𝟐.
= 𝟐. 𝟖𝟑 𝟗𝟕~𝟑
Emp Formula = Na2CO3
½
EF mass= 106
Mol mass = 106 1
Molecular formula Na2CO3
23 Na+<F-,O2-<N3- 1
P, reason(extra stability due to half filled conifiguration) 1+1
O, compact and e-e repulsion
Noble gases have stable completely filled electronic configuration
24 a) Configuration: (σ1s2 σ∗1s2 σ2s2 σ∗2s2 π2px2 π2py2 σ2pz2) 1
Bond order =3 ½
Magnetic property= diamagnetic ½
b) H- bonding 1
25 De Broglie wavelength = h/mv 1
λ=6×10-34/ 6X1024 x 3x106 1
λ=3.68×10−65 m 1

OR
ΔxAmAΔvA = ΔxBmBΔvB
Given, ΔvA = ΔvB
1
Therefore, ΔxAmA = ΔxBmB 1
ΔxA1.0 × 10-27 kg = ΔxB1.0 × 10-31 kg 1

ΔxA / ΔxB = 1.0 × 10-31 kg/1.0 × 10-27 kg = 1/10000.

26 The balanced oxidation half-reaction is given as:

½
2I−(aq)→I2(s)+2e−
The balanced reduction half-reaction is given as:
MnO−4(aq)+8H+(aq)+5e−→Mn2+(aq)+4H2O(l)
Now we balance the number of elctrons being exchanged ½
between the two half-reactions and then add the resulting
equations together:
{5×Equation−(1)5×Equation−(1)} + 1
{2×Equation−(2)2×Equation−(2)}:
10I−(aq)+2MnO−4(aq)+16H+(aq)
→5I2(s)+2Mn2+(aq)+8H2O(l) 1

27. a) proper reason 1

b) Molar mass of AgBr = 108 + 80 = 188 g mol-1
½
188 g AgBr contains 80 g bromine
½
0.12 g AgBr contains= 80 X 0.12/188 g bromine ½
Percentage of bromine=80 X0.12 X100/188 X 0.15= 34.04% 1/2
28 Total 7 isomers, 4 of alcohols and 3 of ethers 3
29 a) aromatic 1
b) highly conjugated structure and stable 1
c ) – cyclic 2
-planar
- conjugated
Huckle’s rule
OR
Comparison of rate of reaction with respect to ESR 2
30 a)Yes proper reason 1
b) proper reason 1
c) Rate of forward reaction = Rate of Backward reaction, Vapour 2
Pressure.

OR
Increase in temperature – backward.
Increase in pressure- forward

2
31 c-i)

1 each

ii) with zinc dust

(iii)aq.KOH
(iv)Fe metal at 873K
(v) Hg2+,H+
(vi) HBr
(vii) Conc.HNO3 and Conc. H2SO4
32.
½
a ½
½
½
½
½

b) For the given reaction, 2 A(g) + B(g) → 2D(g)

∆ng = 2 – (3) = –1 mole ½
Substituting the value of ∆Uθ in the expression of ∆H: ½
∆Hθ = ∆Uθ + ∆ngRT ½
= (–10.5 kJ) – (–1) (8.314 × 10–3 kJ K–1 mol–1 ) (298 K) ½
= –10.5 kJ – 2.48 kJ
∆Hθ = –12.98 kJ
OR
(a) no, as compound is not formed from its constituent 1+1
element in their standard state.
(b) The equation we aim at; 1
C(s) + 2H2(g) + l/202(g) ———> CH3OH (l);∆fH– = ±? … (iv) 1
Multiply eqn. (iii) by 2 and add to eqn. (ii)
∆fH = – 239 kJ mol-1 1

33. a) Cu, Electronic configuration 2

b)
½

½
1
1
OR
a) 1s2 2s2 2p6 3s2 3p63d6 b)5 1
c)Because approaching from infinity has maximum energy 1
considered as zero 1
a) 5p- radial- 3, angular-1, 4d-radial-1, angular-2 2
 KENDRIYA VIDYALAYA SANGATHAN
(IN-SERVICE COURSE 2023-24, AHMEDABAD REGION)
CLASS XI- SESSION ENDING EXAMINATION (SEE)
CHEMISTRY THEORY (043)
Max. Marks:70 Time: 3:00 hours

SAMPLE PAPER NO- 6

BLUE PRINT
SN Name of chapter MCQ (1M) SA I SA II CBQ LA (5M) TOTAL
(2M) (3M) (4M)
1 Some basic concepts of chemistry 2(2) 1(2) 1(3) 4Q(7M)
2 Structure of atom 1(1) 1(3) 1(5) 3Q (9M)
3 Classification of elements and periodicity in 3(3) 1(3) 4Q(6M)
properties
4 Chemical bonding and molecular structure 2(2) 1(2) 1(3) 4Q(7M)
5 chemical thermodynamics 2(2) 1(2) 1(5) 4Q(9M)
6 equlibrium 1(1) 1(2) 1(4) 3Q(7M)
7 Redox reactions 1(1) 1(3) 2Q (4M)
8 Organic chemistry- some basic principles and 3(3) 1(2) 2(6) 6Q (11M)
techniques
9 hydrocarbons 1(1) 1(4) 1(5) 3Q (10M)
TOTAL 16Q(16M) 5Q(10M) 7Q(21M) 2Q(8M) 3Q(15M) 33Q(70M)

Note: No overall choice. However internal choice-two questions in 2M, one Q in 3M, two Q in 5M and in both CBQ –sub
division c (2M -Q)
 KENDRIYA VIDYALAYA SANGATHAN
(IN-SERVICE COURSE 2023-24, AHMEDABAD REGION)
CLASS XI- SESSION ENDING EXAMINATION (SEE)
CHEMISTRY (O43)
SET 6

MAX MARKS: 70 TIME: 3.00 HOURS

General Instructions
There are 33 questions in this question paper with internal choice,
Section A consists of 16multiple choice questions carrying 1 mark each.
Section B consists of 5very short answer questions carrying 2 marks each.
Section C consists of 7.short answer questions carrying 3 marks each.
Section D consists of 2 case – based questions carrying 4 marks each.
Section E consists of 3 long answer questions carrying 5 marks each.
All questions are compulsory.
Use of log tables and calculators is not allowed.
SECTION A
1 What is the mass percent of carbon in CO2 1
(a) 0.034% (b) 27.27% (c)3.4% (d)28.7%
2 The number of atoms present in one mole of an element is equal to Avogadro 1
number. Which of the following element contains the greatest number of
atoms?
(a) 4g He (b) 46g Na (c) 0.40g Ca (d) 12g He
3 Arrange the following species in order of increasing ionic radii. 1
Mg2+ ,F– O2– , Al3+ , Na+
(a) Al3+< Mg2+< Na+< O2–< F–
(b) Mg2+< Al3+< Na+< F–< O2–
(c) Al3+< Mg2+< Na+< F–< O2–
(d) Al3+< Na+< Mg2+< F–< O2–
4 The General electronic configuration (n-2) f 1-14(n - 1) d0-1 ns0-2 refers to which 1
of the following elements?
(a)s block elements (b)p block elements
(c)d block elements (d)f block elements
5 The IUPAC name of the given compound is 1

(a)2- Bromopropane (b)2- Bromobutane

(c)3-Bromopropane (d)1-Bromobutane
6 The shape of BrF3 molecule is 1
(a)Trigonal pyramidal (b)Triagonal planar
 (c)T shape (d)V shape
7 In which of the following compounds, hydrogen bonding does not exist? 1
(a)Water (b)Hydrogen fluoride (c)Ammonia (d)Hydrogen iodide
8 Which of the following is an extensive property? 1
(a) Temperature (b) Density (c)Volume (d)Pressure
9 One mole of which of the following has the highest entropy? 1
(a) Liquid nitrogen (b) Hydrogen gas (c) Mercury (d) Diamond
10 For a reaction QC<KC. The overall reaction __________________ 1
(a)proceeds from left to right (b) proceeds from right to left
(c) is at equilibrium (d) stops completely
11 The oxidation number of Cr in K2Cr2O7 is 1
(a)+3 (b) +4 (c) +5 (d)+6
12 Which of the following orbitals is characterised by n=2, l=0 ? 1
(a)1s orbital (b)2s orbital (c) 2p orbital (d)3d orbital
13 Assertion (A) : Noble gases have positive electron gain enthalpies. 1
Reason (R): Noble Gases are very reactive elements.
(a)Both A and R are true and R is the correct explanation of A.
(b) Both A and R are true but R is not the correct explanation of A.
(c)A is true but R is false.
(d) A is false but R is true.
14 Assertion (A) : The boiling points of the branched chain alkanes are greater 1
than that of the straight chain isomers
Reason (R) : Branching of carbon chain makes the molecule more compact
and decreases the surface area & van der Waals’ forces .
(a) Both A and R are true and R is the correct explanation of A.
(b) Both A and R are true but R is not the correct explanation of A.
(c)A is true but R is false.
(d) A is false but R is true.
15 Assertion (A) : Among carbocations, teritiary carbocation is most stable. 1
Reason (R) : There are more number of hyperconjugative structures for
tertiary carbocation.
(a)Both A and R are true and R is the correct explanation of A.
(b) Both A and R are true but R is not the correct explanation of A.
(c)A is true but R is false.
(d) A is false but R is true.
16 Assertion (A) : A mixture of ethyl alcohol and water can be separated by 1
simple distillation.
Reason (R) : Ethyl alcohol and water are immiscible liquids .
(a)Both A and R are true and R is the correct explanation of A.
(b) Both A and R are true but R is not the correct explanation of A.
(c)A is true but R is false.
(d) A is false but R is true.
SECTION B
17 Calculate the mole fraction of NaCl if 2 moles of NaCl are dissolved in 1000 2
 grams of water.(At mass of Na= 23 u & Cl = 35.5 u)
18 According to VSEPR theory, draw and write the shape of the following 2
molecules. (a) SF4 (b) H2O
19 a) Explain Born-Haber cycle for NaCl. 2
OR
a) State the second Law of Thermodynamics.
b) Compute the internal energy change involving 1 mole of a gas if 1500 J of
heat are added to the gas and no work is done.
20 a) State common ion effect with an example. 2
b)What is the pH of 0.1 M HCl?
OR
a) Which of the following are acidic salts? CH3COOK, NH4Cl, Na2CO3, NH4SO4
b) Write the expression of equilibrium constant Kp for the reaction
CaCO3(s)⇌CaO (s) + CO2 (g)
21 (a)Define Inductive effect. (b)In which C–C bond of CH3CH2CH2Br, the 2
inductive effect is expected to be the least?
SECTION C
22 a) Out of Molality and Molarity which is better to express concentration and 3
why?
b) When 4.00 moles of H2 is mixed with 2.00 moles of Cl2 how many grams of
HCl can form? Also identify the limiting reagent. (At mass of Cl = 35.5u)
H2(g) + Cl2(g)→2 HCl(g)
23 Give reason 3
(i) Sulphur has more negative electron gain enthalpy than Oxygen.
(ii) Boron has less ionization enthalpy than Beryllium.
(iii)1st Ionization enthalpy of Sodium is lower that Magnesium.
24 According to Molecular orbital theory, write the electronic configuration of 3
N2 and N2- molecule. Find the bond order and magnetic property of the
molecule.
25 Attempt any three : 3
(a) Explain ortho and para directing influence of Toluene.
(b) Draw the structure of 3,3 –Dimethylpent-1-ene.
(c) Sodium salt of which acid will be needed for the preparation of propane ?
Write chemical equation for the reaction
(d) Draw Newman’s projection of ethane.
26 In the estimation of sulphur by Carius method, 0.200 g of an organic 3
sulphur compound afforded 0.466 g of barium sulphate. Calculate the percentage
of sulphur in the given compound. (Molar mass of BaSO4 is 233 g/mol.)
27 Permanganate(VII) ion, MnO4– in basic solution oxidises iodide ion, I– to 3
produce molecular iodine (I2) and manganese (IV) oxide (MnO2). Write a
balanced ionic equation to represent this redox reaction
28 Electrons are emitted with zero velocity from a metal surface when it is 3
 exposed to radiation of wavelength 6800 Å. Calculate threshold frequency
(ν0 ) and work function (W0 ) of the metal.
SECTION D

29 Read the following passage and answer the questions that follow. 4
According to Arrhenius theory, acids are substances that dissociates in water to
give hydrogen ions H+ (aq) and bases are substances that produce hydroxyl ions
OH – (aq). According to Brönsted-Lowry theory, acid is a substance that is capable
of donating a hydrogen ion H+ and bases are substances capable of accepting a
hydrogen ion, H+ . In short, acids are proton donors and bases are proton
acceptors. G.N. Lewis in 1923 defined an acid as a species which accepts electron
pair and base which donates an electron pair. As far as bases are concerned, there
is not much difference between Brönsted-Lowry and Lewis concepts, as the base
provides a lone pair in both the cases. However, in Lewis concept many acids do
not have proton. Answer the following questions on the basis of above passage:
a) What will be the conjugate bases for the following Brönsted acids:
HF, H2SO4
b) Classify the following species into Lewis acids and Lewis bases BH3 , NH3
c)All Bronsted acids are Arrhenius acids but Bronsted bases are not Arrhenius
bases . Explain.
OR
NaOH is not basic according to Lewis concept. Explain

30 Alkanes are hydrocarbons in which the carbon atoms are held together by single 4
bonds. Their general formula is CnH2n+2 for molecules which do not contain ring
structures. With their repeated – CH 2 units, the alkanes constitute a homologous
series of organic compounds in which the members differ in molecular mass by
multiples of 14.03 u (the total mass of each such methylene-bridge unit, which
comprises a single carbon atom of mass 12.01 u and two hydrogen atoms of mass
~1.01 u each).
Melting point and boiling point, both the factors depend on the surface area and
branching. As the branching is done in an alkane its surface area decreases, this
results in decrease of boiling point and increase in melting point
Starting with the simplest branched compound, as you increase branching, you
will increase the melting point, but decrease the boiling point. Why? Going from
“branched” to “highly branched” makes a molecule more compact and sphere-like
 Variation of boiling points and melting point in alkanes

On the basis of above data , answer the following questions:

(a) Why boiling point of alkanes increases as the molecular mass increases ?
(b) Arrange in increasing order of boiling point of But-1-ene , Pent-1-ene and
propene.
(c) It has been found saturated hydrocarbons having 5 or more carbon exists in
the liquid or solid form whereas lower members upto 4 carbon atoms exist
in the gaseous form. Give plausible reason for this.
OR
c) 2,2-Dimethyl propane and Pentane are having same molecular mass , they have
different melting points. Explain

SECTION E
31 Answer any five : 5
(a) An electron is in one of the 3d orbitals. Give the possible values of n,l and
m for this electron
(b) Using s, p, d, f notations, describe the orbital with the following quantum
numbers.
(i) n=1, l=0 (ii) n=3, l=1
(iii) n=4,n=2 (iv) n=4, l=3
(c) How many electrons in an atom may have the following quantum
numbers? n=3 , l=0
(d) if uncertainty in the position of an electron is zero, what will the
uncertainty in its momentum. State the law . Write its mathematical
expression.
(e) Draw the boundary surface diagram of dx2 -y2 , dz2 orbital
(f) How many sub-shells are associated with n=4? How many electrons will be
 present in the sub-shell having m=-1/2, n=4
(g) write the electronic configuration of Cr+ ion (Z=24).
32 (a) if one or more modes bring about a chemical change in one or more steps, 5
then the amount of heat absorbed or evolved during the entire reaction is
the same , whichever way was observed. Identify and state the law involved.
(b) What is the relation between Cp and CV for one mole of an ideal gas?
(c)The standard enthalpy of formation of CO2(g), CO(g) and H2O(g) are –
393.5, – 110.5 and –241.8 kJ/mol respectively, Calculate the standard
enthalpy change (in kJ) for the reaction given below.
CO2(g) + H2(g) →CO(g) + H2O(g)
OR
(a) No heat is absorbed by the system from the surroundings, but work (w) is
done on the system. What type of wall does the system have?
(b) Write the sign of ∆H and ∆S for the change Cl2(g) → 2Cl (g).
(c)For the reaction 2A + B →C at 298 K,H = 400 kJ mol–1 and S = 0.2 kJ K–1
mol–1, at what temperature will the reaction become spontaneous
considering H and S to be constant over the temperature range?
33 (a)How will you convert benzene into 5
(i) nitrobenzene (ii) Toluene (iii) m- nitro chlorobenzene
(b) Write IUPAC names of the products obtained by addition reactions of HBr
to hex-1-ene (i) in the absence of peroxide and (ii) in the presence of
peroxide.
OR
(a) Wurtz reaction is not preferred for the preparation of alkanes containing
odd number of carbon atoms? Illustrate your answer by suitable reactions.
(b) Draw the cis- and trans-structures for hex-2-ene. Which isomer will have
higher b.p. and why?
(c) Write IUPAC names of the products obtained by the ozonolysis of Pent-2-
ene
 KENDRIYA VIDYALAYA SANGATHAN
(IN-SERVICE COURSE 2023-24, AHMEDABAD REGION)
CLASS XI- SESSION ENDING EXAMINATION (SEE)
CHEMISTRY THEORY (043)
Max. Marks:70 Time: 3:00 hours
SAMPLE PAPER NO- 6
MARKING SCHEME
SECTION A
1 (b) 27.27 1
2 (d) 12 g of He 1
3 (c) Al3+< Mg2+< Na+< F–< O2– 1
4 (d) f block elements 1
5 (b)2- bromo butane 1
6 (c) T shape 1
7 (d)Hydrogen iodide 1
8 (c)Volume 1
9 b) Hydrogen Gas 1
10 (a) proceeds from left to right 1
11 (d)+6 1
12 (b) 2s orbital 1
13 (b)A is true but R is false. 1
14 (d) A is false but R is true. 1
15 (a)Both A and R are true and R is the correct explanation of A 1
16 (b)A is true but R is false 1
SECTION B
17 No of moles of water = 1000/18 = 55.55 ½
Mole fraction of NaCl = No of moles of NaCl/No of moles of solution ½
= 2/57.55 1
=0.035
18 (i)See-saw shape &correct structure (ii) V or Bent shape & correct structure 1+1
19 Correct explanation of Born-Haber cycle 1+1
OR
a) Statement of second Law of Thermodynamics.
b) ΔU=q+w = 1500 J
20 (a)correct statement (b) b)pH = -log [H+] = -log 0.1 =1 1+1
OR
a) Acidic salts- NH4Cl, NH4SO4
b)Kp = [CO2(g)]
21 (a) polarisation of σ-bond caused by the polarisation of adjacent σ-bond is 1+1
referred to as the inductive effect. (b) Magnitude of inductive effect
diminishes as the number of intervening bonds increases. Hence, the effect
is least in the bond between carbon-3 and hydrogen.
 SECTION C
22 a) Molality is better to express as its independent of temperature. 2+1
b) 4x 36.5 = 146 g of HCl can form
Limiting reagent – H2

23 (i)Due to small size of oxygen, there will be greater interelectronic repulsion 1

when an electron is added. 1
(ii)the 2s orbital is fully filled in beryllium and is closer to the nucleus 1
whereas boron has one electron in a 2p orbital.So more energy is required
to remove an electron from Beryllium.
(iii) To attain noble gas configuration.
24 1
1
1

Diamagnetic
N2- ; B.O =2.5 , Paramagnetic
25 (a)correct reason 1
(b)Correct structure of 3,3,-dimethylpent-1-ene 1
(c)Butanoic acid and correct reaction 1
(d)correct structures
26 233 g of BaSO4 has 32 g of sulphur.
2
0.466 g of BaSO4 will contain (32 × 0.466) / 233 = 0.064 g of sulphur.
1
The percentage of sulphur in the given compound is 0.064 ×100/0.200=32%.
27 6I – (aq) + 2MnO4 – (aq) + 4H2O(l) → 3I2(s) + 2MnO2(s) +8 OH– (aq) 3
28 1
1
1
SECTION D
29 a) F- ,HSO4 - 1/2+1/2
b) BH3 =Lewis acid NH3 =Lewis base 1/2+ ½
c) Arrhenius acids and Bronsted acids both are proton donor whereas 1+1
Arrhenius bases are OH- donor and Bronsted bases are proton acceptor.
OR NaOH cannot accept lone pair of electrons but only release OH- ion.
30 . (a) due to increase in vander waal’s forces of attraction 1
(b) Propene, But-1-ene, Pent-1-ene 1
(c)Vander waal force of attraction increases with increase in molecular
mass 1+1
OR
(c)2,2-Diethyl propane has branched structure and fits in crystal lattice 2
 SECTION E
31 (a)n=3, l=2, m=+1/2 or -1/2 1
(b)i)1s (ii) 3p (iii) 4d (iv) 4f 1
(c) 2 1
(d) state Heisenberg’s uncertainity principle and its mathematical expression 1
(e) correct structures 1
(f) 4, 16 1
(g) [Ar] 3d5 1
(any five )

32 (a) Statement of Hess’s Law of constant heat summation 1

b) Cp - CV = R 1
c)
1
2
OR
1
a) ∆ U = w ad, wall is adiabatic
1
b) ∆ H = +ve, ∆ S = -ve
c)
½
½
1
1

33 (a)correct steps of conversion ½

½
½
½
1
1
1
(b)

OR
(a)due to formation of mixture of hydrocarbons which are difficult to separate 1+1
and suitable reaction
(b)correct structures , cis form has higher b.p due to dipole –dipole interaction 1+1
1/2+
(c)Ethanal and Propanal 1/2