Worksheet
Chapter -Solutions
Class-12
Q-1 Calculate the molarity of NaOH solution obtained by dissolving
2g of NaOH in 50 mL of its solution.
Q-2 State Henry’s law. Calculate the solubility of CO2in water at
298K under 760 mm Hg. (KH for CO2 in water at 298 K is 1.25 × 106
mm Hg)
Q-3 Calculate the mass percentage of benzene (C6H6) and carbon
tetrachloride (CCl4) if 22 g of benzene is dissolved in 122 g of carbon
tetrachloride.
Q-4 8.0575 × 10–2 kg of Glaubers’s salt is dissolved in water to
obtain 1 dm3
of a solution of density 1077.2 kg m–3. Calculate the molarity,
molality
and mole fraction of Na2SO4 in the solution.
Q-5 (a) Define mole fraction.
(b) Explain the following phenomena with the help of Henry’s law:
(i) Painful condition known as bends.
(ii) Feeling of weakness and discomfort in
breathing at high altitude.
Q-6 State Raoult’s law for a solution containing volatile
components. Write two characteristics of the solution which obey
Raoult’s law at all concentrations.
Q-7 Write two differences between ideal solutions and non-ideal
solutions.
Q-8 An aqueous solution containing 20% by weight of liquid ‘A’
(Mol.wt = 140) has vapour pressure of 160 mm at 57o C. Find the
vapour pressure of pure A, if that of water is 150 mm at this
temperature.
Q-9 The vapour pressure of pure liquids A and B at 400 K are 450 and
700 mm Hg respectively. Find out the composition of liquid mixture if
total pressure at this temperature is 600 mm Hg.
Q-10 30 g of urea (M = 60 g mol–1) is dissolved in 846 g of water.
Calculate the vapour pressure of water for this solution if vapour
pressure of pure water at 298 K is 23.8 mm Hg.
Q-11 The vapour pressures of ethanol and methanol are 44.5 mm Hg
and 88.7 mm Hg respectively. An ideal solution is formed at the same
temperature by mixing 60 g of ethanol with 40 g of methanol.
Calculate the total vapour pressure of the solution
and the mole fraction of methanol in the vapour.
Q-12 What is meant by positive and negative deviations from
Raoult’s law and how is the sign of ∆mixH related to positive and
negative deviations from Raoult’s law?
Q-13 Calculate the freezing point of a solution containing 60 g of
glucose (Molar mass = 180 g mol–1) in 250 g of water. (Kf
of water = 1.86 K kg mol–1)
Q-14 Define the following terms:
(i) Colligative properties
(ii) Molality (m)
(iii)Abnormal molar mass
(iv) van’t Hoff factor
Q-15 18 g of glucose, C6H12O6 (Molar Mass = 180 g mol–1)is
dissolved in 1 kg of water in a saucepan. At what temperature will
this solution boil ?(Kb for water = 0.52 K kg mol–1, boiling point of
pure water = 373.15 K)
Q-16 45 g of ethylene glycol (C2H4O2) is mixed with 600 g of water.
Calculate
(i) the freezing point depression and
(ii) the freezing point of the solution
(Given: Kf of water = 1.86 K kg mol–1)
Q-17 A solution is prepared by dissolving 10 g of non-volatile solute
in 200 g of water. It has a vapour pressure of 31.84 mm Hg at 308 K.
Calculate the molar mass of the solute.(Vapour pressure of pure
water at 308 K = 32 mm Hg)
Q-18 3.9 g of benzoic acid dissolved in 49 g of benzene shows a
depression in freezing point of 1.62 K. Calculate the van’t Hoff
factor and predict the nature of solute (associated or
dissociated).(Given: Molar mass of benzoic acid= 122 g mol–1, Kf for
benzene = 4.9 K kg mol–1)
Q-19 (a) When 2.56 g of sulphur was dissolved in 100 g of CS2, the
freezing point lowered by 0.383 K. Calculate the formula of sulphur
(SX). (Kf for CS2 = 3.83 K kg mol–1, Atomic mass of Sulphur = 32 g
mol–1).
(b) Blood cells are isotonic with 0.9% sodium chloride solution. What
happens if we place blood cells in a solution containing;
(i) 1.2% sodium chloride solution ?
(ii) 0.4% sodium chloride solution ?
Q-20 A 10% solution (by mass) of sucrose in water has a freezing
point of 269.15 K. Calculate the freezing point of 10% glucose in
water if the freezing point of pure water is 273.15 K.
Given: (Molar mass of sucrose = 342 gmol-1)
(Molar mass of glucose = 180 g mol-1)
