Structure of atom

Subject : Chemistry Paper Set : 1

Standard : 11 Structure of atom (1) Date : 25-06-2025
Total Mark : 800 Time : 0H:0M

............ Chemistry - Section A (MCQ) ............ (A) The energy is not absorbed or emitted in whole number
or multiple of quantum
(B) Radiation is associated with energy
(1) An electron in a hydrogen atom in its ground state absorbs 2 (C) Radiation energy is not emitted or absorbed conti-
times as much energy as the minimum required for it to nuously but in the form of small packets called quanta
escape from the atom. The kinetic energy of the emitted
electron is ............ eV (D) This magnitude of energy associated with a quantum is
(A) 13.6 (B) 20.4 proportional to the frequency
(C) 6.8 (D) 27.2 (10) What is the ratio of mass of an electron to the mass of a
proton
(2) What is the radius ratio for 2nd orbit of Li+2 ion 3rd orbit of (A) 1 : 2 (B) 1 : 1
Be+3 ion ? (C) 1 : 1837 (D) 1 : 3
(A) 3 : 1 (B) 16 : 27
(11) Assertion : Absorption spectrum consists of some bright
(C) 4 : 9 (D) 3 : 4 lines separated by dark spaces.
Reason : Emission spectrum consists of dark lines.
(3) The maximum energy is possessed by an electrons, when it
(A) If both Assertion and Reason are correct and the Reason
is present
is a correct explanation of the Assertion.
(A) in nucleus
(B) If both Assertion and Reason are correct but Reason is
(B) in ground energy state not a correct explanation of the Assertion.
(C) in first excited state (C) If the Assertion is correct but Reason is incorrect.
(D) at infinite distance from the nucleus (D) If both the Assertion and Reason are incorrect.
(12) According to the Bohr theory, which of the following
(4) The energy required for the ionization of excited hydrogen
transitions in the hydrogen atom will give rise to the least
atom would be (in eV )-
energetic photon ?
(A) 13.6 (B) > 13.6
(A) n = 6 to n = 1 (B) n = 5 to n = 4
(C) < 13.6 (D) None of these
(C) n = 6 to n = 5 (D) n = 5 to n = 3
(5) The isoelectronic pair is (13) The kinetic energy of an electron in the second Bohr orbit of
(A) CO, N2 (B) O2 , N O a hydrogen atom is [ a0 is Bohr radius]:
(A) 4π2hma2 (B) 16πh2 ma2
2 2

(C) (A) and (D) both (D) F2 , HCl 0 0

(C) h2
32π 2 ma20
(D) h2
64π 2 ma20
o
(6) The radius of first Bohr’s orbit for hydrogen is 0.53 A . The (14) If W is atomic weight and N is the atomic number of an
o
radius of third Bohr’s orbit would be .............. A element, then
(A) 0.79 (B) 1.59 (A) Number of e−1 = W − N (B) Number of 0 n1 = W − N
(C) 3.18 (D) 4.77 (C) Number of 1 H 1 = W − N
(D) Number of 0 n1 = N
(7) The frequency of yellow light having wavelength 600 nm is (15) The proton and neutron are collectively called as
(A) 5.0 × 1014 Hz (B) 2.5 × 107 Hz (A) Deutron (B) Positron
(C) 5.0 × 107 Hz (D) 2.5 × 1014 Hz (C) Meson (D) Nucleon
(16) The radius of which of the following orbit is same as that of
(8) The maximum wavelength of radiation that can ionise a
o the first Bohr’s orbit of hydrogen atom
sodium atom is 2414 A . The ionisation energy of sodium per
(A) He+ (n = 2) (B) Li2+ (n = 2)
mole shall be
(A) 241.4 J mol−1 (B) 497.7 J mol−1 (C) Li2+ (n = 3) (D) Be3+ (n = 2)
(C) 241.4 k J mol−1 (D) 497.7 k J mol−1 (17) Electrons are emitted with zero velocity from a metal
surface when it is exposed to radiation of wavelenght
o
(9) Which one of the following is not the characteristic of 8000 A. What should be the maximum velocity of emitted
Planck’s quantum theory of radiation electron when the same metal surface is exposed to

1
 ( )
(27) According to Bohr’s principle, the relation between principle
o
radiation of wavelength 5000 A ? h = 6.6 × 10−34 J.s
quantum number (n) and radius of orbit is
(A) 5.74 × 106 ms−1 (B) 5.74 × 105 ms−1
(A) r ∝ n (B) r ∝ n2
(C) 5.74 × 104 ms−1 (D) 5.74 × 107 ms−1
(C) r ∝ 1
(D) r ∝ 1
(18) Which one of the following is considered as the main n n2

postulate of Bohr’s model of atom (28) The nucleus of an element contain 9 protons. Its valency
(A) Protons are present in the nucleus would be
(A) 1 (B) 3
(B) Electrons are revolving around the nucleus
(C) 2 (D) 5
(C) Centrifugal force produced due to the revolving
electrons balances the force of attraction between the (29) What is the maximum wavelength line in the lyman series of
electron and the protons He+ ion ?
(A) 3R (B) 3R
1

(D) Angular momentum of electron is an integral multiple of

h (C) 4
4R (D) None of these
2π
(30) If λL , λM and λN are the wave lengths of electron in
(19) The number of electrons in 2.1 gram-ion of Cl− is
L, M, N energy levels of H− atom respectively. What is
(A) 2.1 (B) 2.1 × 18 their decreasing order :
(C) 2.1 × 18 × 6.023 × 1023 (D) 2.1 × 18 × 6.023 × 1022 (A) λL > λM > λN (B) λL < λM < λN
(20) Rutherford’s scattering experiment is related to the size of (C) λL > λM < λN (D) λL < λM > λN
the
(A) nucleus (B) atom (31) The energy required to dislodge electron from excited
isolated H-atom, IE1 = 13.6 eV is
(C) electron (D) neutron (A) = 13.6 eV (B) > 13.6 eV
(21) For H−atom, the energy required for the removal of
(C) < 13.6and> 3.4 eV (D) ≤ 3.4 eV
electron from various sub-shells is given as under :
The order of the energies would be : (32) Which of the following statement does not form part of
Bohr’s model of the hydrogen atom
(A) Energy of the electrons in the orbit is quantized
(B) The electron in the orbit nearest to the nucleus has the
lowest energy
(C) Electrons revolve in different orbits around the nucleus
(A) E1 > E2 > E3 (B) E3 > E2 > E1
(D) The position and velocity of the electrons in the orbit
(C) E1 = E2 = E3 (D) None of these
cannot be determined simultaneously
(22) Excited hydrogen atom emits light in the ultraviolet region
at 2.47 × 1015 Hz. With this frequency, the energy of a (33) The longest wavelength line in lyman series of H−spectrum
single photon is (h = 6.63 × 10−34 Js) is : −
(A) 8.041 × 10−40 J (B) 2.680 × 10−19 J (A) 1025.8Å (B) 1215.8Å

(C) 1.640 × 10−18 J (D) 6.111 × 10−17 J (C) 972.6Å (D) 949.8Å
(23) The angular momentum of an electron in a given orbit is J (34) What will be the number of photons required to obtain 1
its kinetic energy will be Joule energy by radiation having wavelength 4000Å ?
(A) 12 mr
J2
2 (B) JV
r
(A) 3 × 1020 (B) 2 × 1018

(C) 2m
J2
(D) J2π
2
(C) 2 × 1032 (D) 2 × 1028
(24) When electromagnetic radiation of wavelength 300 nm falls (35) The nucleus of helium contains
on the surface of a metal, electrons are emitted with the (A) Four protons
kinetic energy of 1.68 × 105 J mol−1 . What is the minimum
(B) Four neutrons
(energy needed to remove an electron from the metal? )
h = 6.626 × 10−34 J s, c = 3 × 108 ms−1 NA = 6.022 × 1023 mol−1 (C) Two neutrons and two protons
(A) 2.31 × 106 J mol−1 (B) 3.84 × 104 J mol−1 (D) Four protons and two electrons
(C) 3.84 × 10−19
J mol −1
(D) 2.31 × 10 J mol
5 −1
(36) Assertion : An atom is electrically neutral
(25) The total energy of the electron of H− atom in the second Reason : Atom contains equal number of protons and
quantum state is −E2 . The total energy of the He+ atom in neutrons.
the third quantum state is (A) If both Assertion and Reason are correct and the Reason
(A) − 32 E2 (B) − 23 E2 is a correct explanation of the Assertion.
(C) − 16
9 E2 (D) − 49 E2 (B) If both Assertion and Reason are correct but Reason is
(26) Magnitude of K.E. in an orbit is equal to not a correct explanation of the Assertion.
(A) Half of the potential energy (C) If the Assertion is correct but Reason is incorrect.
(B) Twice of the potential energy (D) If both the Assertion and Reason are incorrect.
(C) One fourth of the potential energy (37) With increasing principal quantum number, the energy
(D) None of these difference between adjacent energy levels in H− atom

2
 (A) decreases absorbed
(A) 2.15 × 10−11 erg (B) 0.1911 × 10−10 erg
(B) increases
(C) 2.389 × 10−12 erg (D) 0.239 × 10−10 erg
(C) remains constant
(50) The average distance of an electron in an atom from its
(D) decreases for high value of z and increases for low value nucleus is of the order of
of z (A) 106 m (B) 10−6 m
(38) The expression for Bohr’s radius of an atom is
(C) 10−10 m (D) 10−15 m
(A) r = 4π2nme (B) r = 4πn2 me
2 2 2 2
h h
(51) Which of the following is correct regarding Bohr’s theory
4 z2 2z

(C) r = n2 h 2
4π 2 me2 z 2 (D) r = n2 h 2
4π 2 m2 e2 z 2 (A) On doubling the mass of elelctron (hypothetically)
rd
(39) If the radius of the 3 Bohr’s orbit of hydrogen atom is r3 moving in stationary orbit its velocity increases
and the radius of 4th Bohr’s orbit is r4 . Then .... (B) On doubling the mass of elelctron (hypothetically)
(A) r4 = 169
r3 (B) r4 = 16 9 r3 moving in stationary orbit its velocity decreases
(C) r4 = 34 r3 (D) r4 = 43 r3 (C) On doubling the mass of elelctron (hypothetically)
(40) The number of neutron in tritium is moving in stationary orbit its kinetic energy will
(A) 1 (B) 2 increases

(C) 3 (D) 0 (D) On doubling the mass of elelctron (hypothetically)

moving in stationary orbit its kinetic energy will
(41) A metal surface emits photo electrons, when the incident decreasese
radiation possesses minimum.....
(A) Frequency (B) Intensity (52) An isostere is
(A) N O2− and O3 (B) N O2− and P O43−
(C) Velocity (D) Wave-length
(C) CO2 , N2 O, N O3− (D) ClO4− and OCN −
(42) The positive charge of an atom is
(A) Spread all over the atom (53) Cathode rays have
(A) Mass only
(B) Distributed around the nucleus
(B) Charge only
(C) Concentrated at the nucleus
(C) Neither mass nor charge
(D) All of these
(D) Mass and charge both
(43) In Bohr series of lines of hydrogen spectrum, the third line
from the red end corresponds to which one of the following (54) Which transition in the hydrogen atomic spectrum will have
inter-orbit in an atom of hydrogen the same wavelength as the transition, n = 4 to n = 2 of
(A) 4 → 1 (B) 2 → 5 He+ spectrum?
(A) n = 4 to n = 3 (B) n = 3 to n = 2
(C) 3 → 2 (D) 5 → 2
o (C) n = 4 to n = 2 (D) n = 2 to n = 1
(44) Ratio of energy of photon of wavelength 3000 A and
o (55) What is the maximum wavelength line in the Lyman series
6000 A is
of He+ ion ?
(A) 3 : 1 (B) 2 : 1
(A) 3R (B) 1/3R
(C) 1 : 2 (D) 1 : 3
(C) 4/4R (D) None of these
(45) Electromagnetic radiation with maximum wavelength is
(56) The ratio of minimum wavelengths of Lyman & Balmer series
(A) Ultraviolet (B) Radio wave
will be : −
(C) X ray (D) Infra red (A) 1.25 (B) 0.25
(46) Wave number of a spectral line for a given transition is (C) 5 (D) 10
y cm−1 for He+ , then its value for Li2+ for the same
transition is (57) An electron in an atom jumps in such a way that its kinetic
(A) 4y cm−1 (B) y cm−1 energy changes from x to x4 . The change in potential energy
will be
(C) 3y
4 cm−1 (D) 9y
4 cm−1 (A) + 23 x (B) − 38 x
(47) The frequency of a wave of light is 12 × 1014 s−1 . The wave (C) + 43 x (D) − 34 x
number associated with this light is
(58) An electron instially present in an excited state of H atom is
(A) 5 × 10−7 m (B) 4 × 10−8 cm−1
further excited to another energy level by an incident
(C) 2 × 10−7 m−1 (D) 4 × 104 cm−1 photon. It releases 10 photons while coming back to ground
(48) The energy of the electron in the first orbit of He+ is state out of which 7 have higher energy than incident
−871.6 × 10−20 J. The energy of the electron in the first photon. The electron was instially present in
orbit of hydrogen would be (A) I st excited state (B) 2nd excited state
(A) − 871.6 × 10−20 J (B) − 435.8 × 10−20 J (C) 3rd excited state (D) 4th excited state
(C) − 271.9 × 10−20 J (D) − 108.9 × 10−20 J (59) A sodium cation has a different number of electrons from
(49) In a Bohr’s model of atom when an electron jumps from (A) O2− (B) F −
n = 1 to n = 3, how much energy will be emitted or (C) Li− (D) Al3+

3
(60) The radium of an atom is about to visible region for H−atom.
(A) the same as the volume of its nucleus (A) Both Assertion & Reason are True & the Reason is a
correct explanation of the Assertion.
(B) four times the radius of its nucleus
(B) Both Assertion & Reason are True but Reason is not a
(C) 10, 000 times the radius its nucleus
correct explanation of the Assertion.
(D) 1012 times the radius of its nucleus
(C) Assertion is True but Reason is False.
(61) The increasing order (lowest first) for the values of e/m (D) Both Assertion & Reason are False.
(charge/mass) for
(A) e, p, n, α (B) n, p, e, α (70) The distance between 4th and 3rd Bohr orbits of He+ is : −
(A) 2.645 × 10−10 m (B) 1.322 × 10−10 m
(C) n, p, α, e (D) n, α, p, e
(C) 1.851 × 10−10 m (D) 4.761 × 10−10 m
(62) The ratio of the wavelengths of the light absorbed by a
Hydrogen atom when it undergoes n = 2 → n = 3 and (71) The number of electrons in the atom which has 20 protons in
n = 4 → n = 6 transitions, respectively, is the nucleus
(A) 36
1
(B) 16
1 (A) 20 (B) 10

(C) 1
(D) 1 (C) 30 (D) 40
9 4
(72) The difference in wavelength of first and second spectral
(63) Given below are two statements: o
Statement I : According to Bohr’s model of hydrogen atom, lines of lyman series in Li+2 ion spectrum is ................ A
the angular momentum of an electron in a given stationary (A) 190 (B) 182.1
state is quantised. (C) 27 (D) 21.1
Statement II : The concept of electron in Bohr’s orbit,
violates the Heisenberg uncertainty principle. (73) Bohr model of atom is contradicted by
In the light of the above statements, choose the most (A) Pauli’s exclusion principle
appropriate answer from the options given below: (B) Planck quantum theory
(A) Both Statement I and Statement II are correct.
(C) Heisenberg uncertainty principle
(B) Statement I is correct but Statement II is incorrect.
(D) All of these
(C) Statement I is incorrect but Statement II is correct
(74) When alpha particle are sent through a thin metal foil, most
(D) Both Statement I and Statement II are incorrect. of them go straight through the foil because
(64) The number of protons, neutrons and electrons in 175 (A) α− particles are much heavier than electrons
71 Lu,
respectively, are : (B) α− particles are positively charged
(A) 175, 104 and 71 (B) 71, 104 and 71
(C) most part of the atom is empty space
(C) 104, 71 and 71 (D) 71, 71 and 104
(D) α− particle move with high velocity
(65) The space between proton and electron in hydrogen atom is
(75) Among the following groupings which represents the
:
collection of isoelectronic species?
(A) Absolutely empty
(A) N O+ , C22− , O2− , CO (B) N2 , C22− , CO, N O
(B) Full of electromagnetic radiation
(C) CO, N O+ , CN − , C22− (D) N O, CN − , N2 , O2−
(C) Full of air (76) An electronic transition from 1s orbital of an atom causes
(D) Full of Ether (A) Absorption of energy
(66) The greater the energy of a photon, the (B) Release of energy
(A) longer the wavelength and the higher the frequency (C) Both release or absorption of energy
(B) longer the wavelength and the lower the frequency (D) Unpredictable
(C) shorter the wavelength and the higher the frequency (77) A metal is irradiated with light of wavelength 660 nm. Given
(D) shorter the wavelength and the lower the frequency that the work function of the metal is 1.0 eV , the de Broglie
wavelength of the ejected electron is close to
(67) First and second excitation potentials of hydrogen atom (in (A) 6.6 × 10−7 m (B) 8.9 × 10−11 m
eV ) would be respectively
(C) 1.3 × 10−9 m (D) 6.6 × 1013 m
(A) 10.2, 12.1 (B) 12.1, 10.2
(78) In photoelectric effect, the photocurrent
(C) 13.6, 3.4 (D) 3.4, 13.6
(A) Increases with increasing frequency of incident photon.
(68) For which of the following, the radius will same as for
hydrogen atom having n = 1 (B) Decreases with increasing frequency of incident photon
(A) He+ , n = 2 (B) Li+2 , n = 2 (C) Does not depend on the frequency of photon
(C) Be +3
,n = 2 (D) Li +2
,n = 3 (D) Depends both on intensity and frequency of the
incident photon
(69) Assertion : − Emitted radiation will fall in visible region
when an electron jump from n = 4 to n = 2 in H−atom. (79) If the electron jumps from 7.00 eV energy level to 5.0 eV
Reason : − Frequency of radiation of Lyman series belongs energy level, it :

4
 (A) Absorbs 2.0 eV kinetic energy energy
(A) Increases (B) Decreases
(B) Absorbs 2.0 eV potential energy
(C) Remains the same (D) None of these
(C) Emits 2.0 eV electrical energy
(D) Emits 2.0 eV photon (91) The radius of the second Bohr orbit for hydrogen atom is
o
(80) A particular station of All India Radio, New Delhi, broadcasts .......... A
on a frequency of 1, 368 kHz (kilohertz). The wavelength of (Plank’s const. h = 6. × 10−34 Js ; mass of electron
the electromagnetic radiation emitted = 9.1091 × 10−31 kg ; charge of electron
] by the transmitter is : e = 1.60210 × 10−19 C ; permittivity of vaccum
[speed of light c = 3.0 × 108 ms−1
ϵ0 = 8.854185 × 10−12 kg −1 m−3 A2 )
(A) 219.3 m (B) 219.2 m
(A) 1.65 (B) 4.76
(C) 2192 m (D) 21.92 cm
(C) 0.529 (D) 2.12
(81) The minimum energy that must be possessed by photons in
order to produce the photoelectric effect with platinum (92) Assertion : For Balmer series of hydrogen spectrum, the
metal is .... × 10−19 J value n1 = 2 and n2 = 3, 4, 5.
[Given: The threshold frequency of platinum is 1.3 ×1015 s−1 Reason : The value of n for a line in Balmer series of
and h = 6.6 × 10−34 J s.] hydrogen spectrum having the highest wave length is 4 and
(A) 32.1 (B) 0.624 6.
(A) If both Assertion and Reason are correct and the Reason
(C) 8.58 (D) 976
is a correct explanation of the Assertion.
(82) The ratio of charge and mass would be greater for
(B) If both Assertion and Reason are correct but Reason is
(A) Proton (B) Electron
not a correct explanation of the Assertion.
(C) Neutron (D) Alpha
(C) If the Assertion is correct but Reason is incorrect.
(83) The minimum real charge on any particle which can exist is
(D) If both the Assertion and Reason are incorrect.
(A) 1.6 × 10−19 Coulomb (B) 1.6 × 10−10 Coulomb
(C) 4.8 × 10−10 Coulomb (D) Zero (93) When an electron drops from a higher energy level to a low
(84) The emission spectrum of hydrogen is found to satisfy the energy level, then
expression for the ( energy change.
) ∆E (in joules) such that (A) Energy is emitted
∆E = 2.18 × 10 n2 − n2 J where n1 = 1, 2, 3. . . .. and n2
1 1
(B) Energy is absorbed
1 2
= 2, 3, 4....... The spectral lines correspond to Paschen series
(C) Atomic number increases
to
(A) n1 = 1 and n2 = 2, 3, 4 (D) Atomic number decreases
(B) n1 = 3 and n2 = 4, 5, 6
(94) The atomic number of an element represents
(C) n1 = 1 and n2 = 3, 4, 5 (A) Number of neutrons in the nucleus
(D) n1 = 2 and n2 = 3, 3, 5 (B) Number of protons in the nucleus
(85) Positive ions are formed from the neutral atom by the (C) Atomic weight of element
(A) Increase of nuclear charge(B) Gain of protons
(D) Valency of element
(C) Loss of electrons (D) Loss of protons
(86) Photoelectric effect can be caused by (95) Wavelength of spectral line emitted is inversely proportional
to
(A) visible light but not X− rays
(A) Radius (B) Energy
(B) Gamma rays but not by X− rays
(C) Velocity (D) Quantum number
(C) U.V. light only
(96) Which is correct graph ?
(D) Visible light, U.V. rays and Gamma rays also
(A) (B)
(87) The ionzation potential of hydrogen atom is 13.6 eV. The
energy required to remove an electron from the n = 2 state
of hydrogen atom is : ............ eV
(A) 27.2 (B) 13.6
(C) 6.8 (D) 3.4
(88) The ratio of the radius of the first three Bohr orbits is (D)
(C)
(A) 1 : 12 : 13 (B) 1 : 2 : 3
(C) 1 : 4 : 9 (D) 1 : 8 : 27
(89) Normally, the time taken in the transition is :
(A) Zero (B) 1
(C) 10−5 sec (D) 10−8 sec
(90) When an electron jumps from lower to higher orbit, its (97) The nature of anode rays depends upon

5
 (A) Nature of electrode of x is ..... .
(Nearest
( integer) )
(B) Nature of residual gas h = 6.63 × 10−34 Js, c = 3.00 × 108 ms−1
(C) Nature of discharge tube (110) Consider an imaginary ion 48 3−
. The nucleus contains ’a’%
22 X
(D) All the above more neutrons than the number of electrons in the ion. The
value of ’a’ is ..... [nearest integer]
(98) A bulb of 40 W is producing a light of wavelength 620 nm
with 80% of efficiency then the number of photons emitted (111) The number of electrons and neutrons of an element is 18
by the bulb in 20 seconds are and 20 respectively. Its mass number is
o
(1eV = 1.6 × 10−19 J, hc = 12400 eV A) (112) A 50 watt bulb emits monochromatic red light of
(A) 2 × 1018 (B) 1018 wavelength of 795 nm. The number of photons emitted per
(C) 1021 (D) 2 × 1021 second by the bulb is x × 1020 . The value of x is ...... . ]
[ Given : h = 6.63 × 10−34 Js and c = 3.0 × 108 ms−1
(99) The expression Ze gives :
(A) The charge of α− particle (113) The kinetic energy of an electron in the second Bohr orbit of
h2
a hydrogen atom is equal to xma 2 . The value of 10x is ........ .
(B) The charge on an atom 0
(a0 is radius of Bohr’s orbit) (Nearest integer) [Given :
(C) The charge on the nucleus of atomic number Z π = 3.14]
(D) The kinetic energy of an α− particle (114) A bulb emits monochromatic yellow light of the wavelength
0.57 micron. If the rate of emission of quanta per second of
(100) Be2+ is isoelectronic with which of the following ions?
the bulb is 14.33 × 1019 , the power of the bulb (in W att) is
(A) H + (B) Li+ .....
(C) N a+ (D) M g 2+ (115) The series limit for Balmer series of H− spectra is

.......... Chemistry - Section B (NUMERIC) .......... (116) The total number of isoelectronic species from the given set
is .......
O2− , F − , Al, M g 2+ , N a+ , O+ , M g, Al3+ , F
(101) A metal surface is exposed to 500 nm radiation. The
threshold frequency of the metal for photoelectric current is (117) Wavenumber for a radiation having 5800Å wavelength is
4.3 × 1014 Hz. The velocity of ejected electron is x × 10 cm−1 . The value of x is. . . . . . . .
....... × 105 ms−1 (Nearest integer) ]
[Use : h = 6.63 × 10−34 Js, me = 9.0 × 10−31 kg (118) A photon of 300 nm is absorbed by a gas and then re-emits
two photons. One re-emitted photon has wavelength
(102) The wave no. of the first line of Balmer series of H atom is 496 nm , the wavelength of second re-emitted photon is
15200 cm−1 . What is wave number of the first line of Lyman
series of Li2+ ................ cm−1 (119) Photon having wavelength 310 nm is used to break the
bond of A2 molecule having bond energy 288 kJ mol−1
(103) The electronic configuration of a dipositive ion M 2+ is then % of energy of photon converted to the K.E. is
2, 8, 14 and its atomic mass is 56. The number of neutrons in
o
[hc = 12400 ev A , 1 eV /atom = 96 kJ/mol]
the nucleus would be :
(120) How many spectral line of Balmer series present in visible
(104) Find the value of wave number of (v̄) in terms of Rydberg’s region :
constant, when transition of electron takes place between
two levels of He+ ion whose sum is 4 and difference is 2 (121) For hydrogen atom, energy of an electron in first excited
state is −3.4eV, KE. of the same electron of hydrogen atom
(105) Which orbit of Be+3 has the same orbit radius as that of the is xeV. Value of x is. . . . . . .×10−1 eV. (Nearest integer)
ground state of hydrogen atom
(122) A hypothetical electromagnetic wave is show below.
(106) The number of following statement/s which is/are incorrect (Image)
is
(A) Line emission spectra are used to study the electronic The frequency of the wave is x × 1019 Hz. x = . . . . (nearest
structure integer)
(B) The emission spectra of atoms in the gas phase show a
continuous spread of wavelength from red to violet
(C) An absorption spectrum is like the photographic
negative of an emission spectrum
(D) The element helium was discovered in the sun by
spectroscopic method
(107) If the radius of the hydrogen atom is 53 pm, the radius of the (123) The work function for a metal is 4 eV. To emit a photo
He+ ion is closest to ...... pm electron of zero velocity from the surface of the metal, the
o
wavelength of incident light should be : ................ A
(108) A certain transition in the hydrogen spectrum from an
excited state in one or more steps gives rise to a total of ten (124) Nitrogen atom has an atomic number of 7 and oxygen has
lines. Number of lines lying in visible spectrum is an atomic number 8. The total number of electrons in a
nitrate ion will be
(109) The number of photons emitted by a monochromatic (single
frequency) infrared range finder of power 1 mW and (125) The orbital angular momentum of an electron in 3s orbital is
wavelength of 1000 nm, in 0.1 second is x × 1013 . The value 2π . The value of.x is ...........
xh

6
(126) The number of electrons plus neutrons in 40
19 K is .....
+

(127) The frequency of one of the lines in Paschen series of

hydrogen atom is 2.340 × 1011 Hz. The quantum number n2
which produces this transition is

(128) The longest wavelength of light that can be used for the
ionisation of lithium atom (Li) in its ground state is (141) A certain atomic transition from an excited state to the
x × 10−8 m. The value of x is ..... (Nearest Integer) ground state of the hydrogen atom in one or more steps
(Given : Energy of the electron in the first shell of the give rise to four line in the ultraviolet region of the
hydrogen atom is −2.2 × 10−18 J; h = 6.63 × 10−34 Js and spectrum. How many lines does this transition produce in
c = 3 × 108 ms−1 ) the infrared region of the spectrum

(129) The electronic configuration of a dipositive metal M 2+ is (142) If molecular mass and atomic mass of sulphur are 256 and 32
2, 8, 14 and its atomic weight is 56 a.m.u. The number of respectively, its atomicity is
neutrons in its nuclei would be (143) The value of Rydberg constant (RH ) is 2.18 × 10−18 J. The
velocity of electron having mass 9.1 × 10−31 kg in Bohr’s
(130) Electromagnetic radiation of wavelength 663 nm is just
first orbit of hydrogen atom = . . . . . . . . . × 105 ms−1
sufficient to ionise the atom of metal A. The ionization
(nearest integer)
energy of metal A in kJ mol−1 is ...... .
(Rounded-off
[ to the nearest integer) (144) If the work function of a metal is 6.63 × 10−19 J, the
h = 6.63 × 10−34 Js, c =] 3.00 × 108 ms−1 , maximum wavelength of the photon required to remove a
NA = 6.02 × 1023 mol−1 photoelectron from the metal is .... nm. (Nearest integer)
[Given : h = 6.63 × 10−34 J s, and c = 3 × 108 m s−1 ]
(131) The energy of one mole of photons of radiation of frequency
2 × 1012 Hz in Jmol−1 is .....(Nearest integer) (Given: (145) A gas absorbs a photon of 355 nm and emits at two
−34 −1
) wavelengths. If one of the emissions is at 680 nm, the other
h = 6.626 × 10 JS NA = 6.022 × 10 mol23
is at : ................. nm
(132) The energy of one mole of photons of radiation of (146) The wavelength of the radiation emitted, when in a
wavelength 300nm is ...... kJ mol−1 . hydrogen atom electron falls from infinity to stationary state
(Given : h = 6.63 × 10−34 Js, NA = 6.02 × 1023 mol−1 , 1, would be ............... nm (Rydberg constant
c = 3 × 108 ms−1 ) = 1.097 × 107 m−1 )
(133) Assume that the radius of the first Bohr orbit of hydrogen (147) 4s2 is the configuration of the outermost orbit of an
atom is 0.6Å. The radius of the third Bohr orbit of He+ is element. Its atomic number would be : −
.................. picometer. (Nearest Integer)
(148) The energy of an electron in first Bohr orbit of H−atom is
(134) Supposing the energy (in arbitrary units) of the energy levels −13.6 eV . The magnitude of energy value of electron in the
in the hydrogen atom is given as under: first excited state of Be3+ is ..........eV.(nearest integer
value)
Energy K L M N
level (149) A certain electronic transition from an excited state to
n=1 n=2 n=3 n =
ground state of the H atom in one or more step gives rise to
4.....n = three lines in the ultra violet region of the spectrum. How
∞ many lines does this transition produce in the infrared
region of the spectrum : −
Energy −864 a.u. Zero
the excitation energy needed to raise the electron from M
level to n = ∞ would be :

(135) Ratio of radius of second and first Bohr orbits of H atom

(136) The wavelngth of radiation emitted when electron falls from

4th Bohr orbit to 2nd in H atom is .............. nm

(137) The core charge on oxygen is equal to -

(138) To obtain a diff raction peak, for a crystalline solid with

interplane distance equal to the wavelength of incident
X-ray radiation. The angle of incidence should be .... ◦

(139) When the excited electron of a H atom from n = 5 drops to

the ground state, the maximum number of emission lines
observed are.......

(140) The electron in the nth orbit of Li2+ is excited to (n + 1)

orbit using the radiation of energy 1.47 × 10−17 J (as shown
in the diagram). The value of n is .....Given
RH = 2.18 × 10−18 J

7
 Structure of atom
Subject : Chemistry Paper Set : 1
Structure of atom (1) Date : 25-06-2025
Standard : 11
Total Mark : 800 (Answer Key) Time : 0H:0M

Chemistry - Section A (MCQ)

1-A 2-B 3-D 4-C 5-C 6-D 7-A 8-D 9-A 10 - C

11 - D 12 - C 13 - C 14 - B 15 - D 16 - D 17 - B 18 - D 19 - C 20 - A
21 - C 22 - C 23 - A 24 - D 25 - D 26 - A 27 - B 28 - A 29 - B 30 - B
31 - D 32 - D 33 - B 34 - B 35 - C 36 - C 37 - A 38 - B 39 - B 40 - B
41 - A 42 - C 43 - D 44 - B 45 - B 46 - D 47 - D 48 - C 49 - B 50 - C
51 - C 52 - A 53 - D 54 - D 55 - B 56 - B 57 - A 58 - B 59 - C 60 - C
61 - D 62 - D 63 - A 64 - B 65 - A 66 - C 67 - A 68 - C 69 - C 70 - C
71 - A 72 - D 73 - C 74 - C 75 - C 76 - A 77 - C 78 - C 79 - D 80 - A
81 - C 82 - B 83 - A 84 - B 85 - C 86 - D 87 - D 88 - C 89 - D 90 - A
91 - D 92 - C 93 - A 94 - B 95 - B 96 - C 97 - B 98 - D 99 - C 100 - B

Chemistry - Section B (NUMERIC)

101 - 5 102 - 738720 103 - 30 104 - 32R

9
105 - 2 106 - 1 107 - 27 108 - 3 109 - 50 110 - 4
111 - 38 112 - 2 113 - 3155 114 - 50 115 - 3646 116 - 5 117 - 1724 118 - 759 119 - 25 120 - 4
121 - 34 122 - 5 123 - 3100 124 - 32 125 - 0 126 - 39 127 - 5 128 - 4 129 - 30 130 - 180
131 - 798 132 - 399 133 - 270 134 - 96 135 - 4 136 - 486 137 - +6 138 - 30 139 - 10 140 - 1
141 - 3 142 - 8 143 - 22 144 - 300 145 - 743 146 - 91 147 - 30 148 - 54 149 - 1