ots 6a: ox. oy: (a) (b) @ (Gi) (iii) (ii) (iii) At the same temperature, CO» gas is more soluble in water than Oy gas. Which one of them will have higher value of Ky and why ? How does the size of blood cells change when placed in an aqueous solution containing more than 0-9% (mass/volume) sodium chloride ? 1 molal aqueous solution of an electrolyte AyBg is 60% ionized. Calculate the boiling point of the solution. 14143=5 (Given : Ky for H20 = 0:52 K kg mol!) OR ‘The vapour pressures of A and B at 25°C are 75 mm Hg and 25 mm Hg, respectively. If A and B are mixed such that the mole fraction of A in the mixture is 0-4, then calculate the mole fraction of B in vapour phase. Define colligative property. Which colligative property is preferred for the molar mass determination of macromolecules ? Why are equimolar solutions of sodium chloride and glucose not isotonic ? 2424125 A 6% solution of glucose (molar mass = 180 g mol) is isotonic with 2:5% solution of an unknown organic substance. Calculate the molecular weight of the unknown organic substance. A 4% solution of urea (molar mass = 60 g mol”) is isotonic with 5.2% solution of an unknown organic substance. Calculate the molecular weight of the unknown organic substance. A 3% solution of glucose (molar mass = 180 g mol”) is isotonic with 2.5% solution of an unknown organic substance. Calculate the molecular weight of the unknown organic substance. 2x1=2os: OG: oy ae le. The vapour pressure of a solvent at 283 K is 100 mm Hg. Calculate the vapour pressure of a dilute solution containing 1 mole of a strong electrolyte AB in 50 moles of the solvent at 283 K (assuming complete dissociation of solute AB). (a) Define molal depression constant. How is it related to enthalpy of fusion ? OR (b) What type of deviation is shown by ethanol and acetone mixture ? Give reason. What type of azeotropic mixture is formed by that deviation ? A solution is prepared by dissolving 5 g of a non-volatile solute in 200 g of water. It has a vapour pressure of 31-84 mm Hg at 300 K. Calculate the molar mass of the solute. (Vapour pressure of pure water at 300 K = 32 mm Hg) A solution containing 60 g of a non-volatile solute in 250 g of water freezes at 270.67 K. Calculate the molar mass of the solute. (K; of water = 1.86 K kg mol}. 18 g of a non-volatile solute is dissolved in 200 g of H,O freezes at 272.07 K. Calculate the molecular mass of solute (K, for water = 1.86 K kg mol!) Calculate the molar mass of a compound when 6.3 g of it is dissolved in 27 g of chloroform to form a solution that has a boiling point of 68.04 °C. ‘The boiling point of pure chloroform is 61.04 °C and K,, for chloroform is 3.63 °C kg mol!21: (@) (i) Define reverse osmosis. (ii) Why are aquatic species more comfortable in cold water in comparison to warm water ? Gii) A solution containing 2 g of glucose (M = 180 g mol") in 100 g of water is prepared at 308 K. If the vapour pressure of pure water at 303 K is 32.8 mm Hg, what would be the vapour pressure of the solution ? 1+14+3 oR (b) (@) Predict whether Van't Hoff factor will be less or greater than one, when Ethanoic acid is dissolved in benzene. (ii) Define ideal solution. (ii) Calculate the mass of CaCl, (molar mass = 111 g mol!) to be dissolved in 500 g of water to lower its freezing point by 2K, assuming that CaCl, undergoes complete dissociation. 1+1+3 (K; for water = 1.86 K kg mol!) 4Q: (@) (i) Ishan’s automobile radiator is filled with 1.0 kg of water. How many grams of ethylene glycol (Molar mass = 62 g mol~!) must Ishan add to get the freezing point of the solution lowered to — 2.8 °C. K, for water is 1.86 K kg - mol}. 3 (ii) What type of deviation from Raoult’s law is shown by ethanol and acetone mixture ? Give reason. 2 OR (>) @ Boiling point of water at 750 mm Hg pressure is 99.68 °C. How much sucrose (Molar mass = 342 g mol~!) is to be added to 500 g of water such that it boils at 100 °C ? (K, for water = 0.52 K kg mol!) (ii) State Henry's law and write its any one application. B+2 13% Calculate elevation of the boiling point of the solution when 4 of MgSOq (molar mass = 120 g/mol) was dissolved in 100 g of water, assuming MgSO4 undergoes complete ionisation. (Ky, for water = 0.52 K kg mol!) 3'4: Calculate elevation of the boiling point of solution when 2 g of MgSOg (molar mass = 120 g/mol) was dissolved in 100 g of water, assuming MgSO4 undergoes complete dissociation. [Ky for water = 0.52 K kg mol! 3 IS: (a) Pure ethanol cannot be prepared by fractional distillation of ethanol — water mixture. Comment. I (b) — Why does a mixture of chloroform and acetone show deviation from ideal behaviour ? 1 (©) (i) The vapour pressure of pure benzene at a certain temperature is 1.25 atm. When 1.2 g of non-volatile, non-electrolyte solute is added to 60 g of benzene (M = 78 g mol"), the vapour pressure of the solution becomes 1.237 atm. Calculate the molar mass of the non-volatile solute. 2 OR (c) (ii) The boiling point of benzene is 353.23 K. When 1.80 g of a non-volatile solute was dissolved in 90 g of benzene, the boiling point is raised to 354.11 K. Calculate the molar mass of the solute. Ky for benzene is 2.53 K kg mol”, 2 16: — What is Henry’s law ? Give one application of it. 2 1%: (a) Differentiate between Ideal solution and Non-ideal solution. (b) 30g of urea is dissolved in 846 g of water. Calculate the vapour pressure of water for this solution if vapour pressure of pure water at 298 K is 23-8 mm Hg. 3 18- A solution is prepared by dissolving 10 g of non-volatile solute in 200 g of water. It has a vapour pressure of 31-84 mm Hg at 308 K. Calculate the molar mass of the solute. (Vapour pressure of pure water at 308 K = 32 mm Hg) 2 "9. Give reason : 3x1=3 (a) Measurement of osmotic pressure method is preferred for the determination of molar masses of macromolecules such as proteins and polymers. (b) Aquatic animals are more comfortable in cold water than in warm water. (©) Elevation of boiling point of 1 M KCI solution is nearly double than that of 1 M sugar solution.Der a1: 22: 23: 2a: ois 2a ‘The vapour pressure of pure liquid X and pure liquid Y at 25 °C are 120 mm Hg and 160 mm Hg respectively. If equal moles of X and Y are mixed to form an ideal solution, calculate the vapour pressure of the solution. 2 When 19.5 g of F - CH, ~ COOH (Molar mass = 78 g mol~"), is dissolved in 500 g of water, the depression in freezing point is observed to be 1°C. Calculate the degree of dissociation of F - CH, ~ COOH. [Given : K; for water = 1.86 K kg mol-] 3 Give reasons for the following : (a) Aquatic animals are more comfortable in cold water in comparison to warm water. (>) Sprinkling of salt helps in clearing the snow-covered roads in hilly areas. On mixing liquid X and liquid Y, volume of the resulting solution decreases. What type of deviation from Raoult’s law is shown by the resulting solution ? What change in temperature would you observe after mixing liquids X and Y? 0.3 g of acetic acid (M = 60 g mol”) dissolved in 30 g of benzene shows a depression in freezing point equal to 0-45°C. Calculate the percentage association of acid if it forms a dimer in the solution. (Given : Ky for benzene = 5-12 K kg mol?) What type of deviation from Raoult’s law is shown by a mixture of ethanol and acetone ? Give reason. (a) What type of deviation from Raoult’s law is shown by a mixture of ethanol and acetone ? Give reason. OR (b) Define Azeotrope. What type of azeotrope is formed by negative deviation from Raoult’s law ? Give an example. If benzoic acid (M = 122 g mol) is associated into a dimer when dissolved in benzene and the osmotic pressure of a solution of 61 g of benzoic acid in 100 mL benzene is 6-5 atm at 27°C, then what is the percentage association of benzoic acid ? = 0.0821 L atm K™! mol”) (Given :ag lg eS Me: 82 (a) b) (a) () (a) (b) (a) () (Why is boiling point of 1M NaC! solution more than that of 1M glucose solution ? 1424255 (i) A non-volatile solute *X’ (molar mass = 50 g mol) when dissolved in 78g of benzene reduced its vapour pressure to 90%. Calculate the mass of X dissolved in the solution. ii) Calculate the boiling point elevation for a solution prepared by adding 10g of MgCl, to 200g of water assuming MgCl, is completely dissociated. (K, for Water = 0.512 K kg mol“, Molar mass MgCl, OR 95g mol!) @ Why is the value of Van't Hoff factor for ethanoic acid in benzene close to 0.5? 1424255 (ii) Determine the osmotic pressure of a solution prepared by dissolving 2.32 x 10g of K,SO, in 2L of solution at 25 °C, assuming that K,SO, is completely dissociated. (R = 0.082 L atm K* mol“, Molar mass K,SO, = 174g mol“) (ii) When 25.6g of Sulphur was dissolved in 100g of benzene, the freezing point lowered by 0.512 K. Calculate the formula of Sulphur (S,). (K, for benzene = 5.12 K kg mol, Atomic mass of Sulphur = 32g mol) Find the value of van't Hoff factor for acetie acid in benzene as per the given equation : 2CH,COOH = (CH;COOH),, assuming its complete association, Osmotic pressure of a solution containing 3-5 g of dissolved protein in 0-05 L of a solution is 0-035 atm at 310 K. Calculate the molar mass of the protein. (R = 0-0821 L atm K~! mol™}) 142 Find the van't Hoff factor for aqueous KCl, assuming complete dissociation. A solution of an organic compound is prepared by dissolving 68:4 g in 1000 g of water. Calculate the molar mass of the compound when elevation in boiling point is 0-104 K and Ky, for water is 0-52 K kg mol™}. 3 What will be the van’t Hoff factor for a dilute solution of KySO,, assuming complete dissociation ? 1-00 g of non-electrolyte solute dissolved in 50 g of benzene lowered the freezing point of benzene by 0:40 K. Find the molar mass of the solute. (Ky for benzene = 5:12 K kg mol~) 3 Answer the following questions (a) 20 mL of a liquid A was mixed with 20 mL of liquid B. The volume of resulting solution was found to be less than 40 mL. What do you conclude from the above data ?(b) © ) Which of the following show positive deviation from Raoult’s law ? Carbon disulphide and Acetone; Phenol and Aniline; Ethanol and Acetone The vapour pressure of a solution of glucose in water is 750 mm Hg at 100°C. Calculate the mole fraction of solute. (Vapour pressure of water at 373 K = 760 mm Hg) OR The boiling point of solution increases when 1 mol of NaCl is added to 1 litre of water while addition of 1 mol of methanol to one litre of water decreases its boiling point. Explain the above observations. 1+1+2