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Assignment 2 (05.03.2024) Solution

The document consists of a series of questions related to the solubility of gases, intermolecular forces, and laws governing solutions such as Henry's and Raoult's laws. It covers topics like the effects of temperature on gas solubility, calculations involving gas constants, and assertions related to solution properties. Additionally, it includes practical problems requiring calculations of solubility, molarity, and molality in various scenarios.

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54 views2 pages

Assignment 2 (05.03.2024) Solution

The document consists of a series of questions related to the solubility of gases, intermolecular forces, and laws governing solutions such as Henry's and Raoult's laws. It covers topics like the effects of temperature on gas solubility, calculations involving gas constants, and assertions related to solution properties. Additionally, it includes practical problems requiring calculations of solubility, molarity, and molality in various scenarios.

Uploaded by

k4nbwhwptd
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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1.

Why are the aquatic species more comfortable in cold water in comparison
to warm water?

2.What is the similarity between Raoult's law and Henry's law?

3. Explain the solubility rule "like dissolves like" in terms of intermolecular


forces that exist in solutions.

4. State Henry's law. Write its one application. What is the effect of
temperature on solubility of gases in liquid?

5. Henry's law constant (K) for the solution of methane in benzene at 298 K is
4.27 x10 to the power 5 mm Hg. Calculate the solubility of methane in
benzene at 298 K under 760 mm Hg.

6. State Raoult's law for the solution containing volatile components

. What is the similarity between Raoult's law and Henry's law.

7. Gas (A) is more soluble in water than Gas (B) at the same temperature.
Which one of the two gases will have the higher value of K (Henry's constant)
and why?

8. The vapour pressure of pure liquid X and pure liquid Y at 25°C are 120 mm
Hg and 160 mm Hg. respectively. If equal moles of X and Y are mixed to form
an ideal solution, calculate the vapour pressure of the solution.

9. Henry's law constant for CO, in water is 1.67 x 10 to the power 5 Pa at 298
K. Calculate the number of molesof CO₂ in 500 ml. of soda water when
packed under 2.53 x 10 Pa at the same temperature.

10. Calculate the molarity of 9.8% (w/w) solution of H₂SO₄ if the density of
the solution is 1.02 g ml. (Molar mass of H₂SO₄ = 98 g/mol.

11. At higher altitudes, people suffer from a disease called anoxia. In this
disease, they become weak and cannot think clearly.why?

12. An unknown gas 'X' is dissolved in water at 2.5 bar pressure and has
mole fraction 0.04 in solution. The mole fraction of 'X' gas when the pressure
of gas is doubled at the same temperature is

(a) 0.08

(c) 0.02

(b) 0.04

(d) 0.92
In the following questions, two statements are given one labeled Assertion
(A) and the other labeled Reason (R). Select the correct answer to these
questions from the codes (a), (b), (c) and (d) as given below:

(a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R)
is the correct explanation of the Assertion

(b) Both Assertion (A) and Reason (R) are correct statements, but Reason (R)
is not the correct explanation of the Assertion (A).

(c) Assertion (A) is correct, but Reason (R) is incorrect statement. (d)
Assertion (A) is incorrect, but Reason (R) is correct statement.

13.Assertion (A): Molarity of a solution in liquid state changes with


temperature.

Reason (R): The volume of a solution changes with change in temperature.

14. Assertion (A): If more volatile liquid is added to another liquid, vapour
pressure of solution will be greater than that of pure solvent.

Reason (R): Vapour pressure of solution is entirely due to solvent molecules.

15. Henry's law constant for the molality of methane in benzene at 298 K is
4.27 x 10 to the power 5 mm Hg. Calculate the solubility of methane in
benzene at 298 K under 760 mm Hg.

16. Calculate the molality of a sulphuric acid solution in which the mole
fraction of water is 0.85.

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