ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM

Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

B.Sc HONOURS CHEMISTRY: MAJOR

Course structure

SEMESTER Course Title Hr/ Credits

week
Code

Essentials and applications of Mathematical, Physical and 5 4

1
Chemical sciences
I

2 Advances in Mathematical, Physical and Chemical sciences 5 4

General & Inorganic Chemistry - (T) 3 3

3
General & Inorganic Chemistry - (P) 2 1
II
Inorganic Chemistry-I - (T) 3 3
4
Inorganic Chemistry-I - (P) 2 1

Fundamentals in Organic Chemistry - (T) 3 3

5
Fundamentals in Organic Chemistry - (P) 2 1

Organic Chemistry (Halogen & Oxygen Organic Compounds) - 3 3

(T)
6
III Organic Chemistry (Halogen & Oxygen Organic Compounds - 2 1
(P)

Physical Chemistry-I ( Solutions and Electrochemistry) - (T) 3 3

7
Physical Chemistry-I ( Solutions and Electrochemistry) - (P) 2 1

8 Inorganic &Physical Chemistry - (T) 3 3

Inorganic &Physical Chemistry - (P) 2 1

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Physical Chemistry-II (States of Matter, Phase Rule & surface 3 3

9 Chemistry) - (T)

Physical Chemistry-II (States of Matter, Phase Rule & surface 2 1

Chemistry) - (P)

IV General & Physical Chemistry - (T) 3 3

10
General & Physical Chemistry - (P) 2 1

Nitrogen containing Organic Compounds & Spectroscopy. - (T) 3 3

11
Nitrogen containing Organic Compounds & Spectroscopy. - (P) 2 1

Analytical Methods in Chemistry-Quantitative analysis 3 3

12 A
Analytical Methods in Chemistry-Quantitative analysis 2 1

OR

Environmental Chemistry 3 3
12 B
Environmental Chemistry 2 1

Chromatography and Instrumental methods of Analysis 3 3

13A
Chromatography and Instrumental methods of Analysis 2 1
V
OR

Green Chemistry and Nanotechnology 3 3

13 B
Green Chemistry and Nanotechnology 2 1
3 3
Synthetic Organic Chemistry
14 A 2 1
Synthetic Organic Chemistry
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

OR
3 3
14 B Industrial Chemistry- Fertilisers and Surface coatings
2 1
Industrial Chemistry- Fertilisers and Surface coatings
3 3
Analysis of Organic Compounds
15 A 2 1
Analysis of Organic Compounds

OR
3 3
Industrial Chemistry- Polymers and water analysis
15 B 2 1
Industrial Chemistry- Polymers and water analysis

VI Internship

Inorganic Chemistry:Advance Studies in Complexes and Group 3 3

theory
16 A
Inorganic Chemistry:Advance Studies in Complexes and Group 2 1
theory

OR

Inorganic Materials of Industrial importance 3 3

16 B
Inorganic Materials of Industrial importance 2 1

VII Spectroscopy of Organic compounds 3 3

17 A
Spectroscopy of Organic compounds 2 1

OR

17 B Stereo Chemistry and Natural Products 3 3

Stereo Chemistry and Natural Products 2 1

Physical Chemistry: Thermo dynamics, Electro chemistry and 3 3

Chemical Kinetics.
18 A
Physical Chemistry: Thermo dynamics, Electro chemistry and 2 1
Chemical Kinetics.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

OR

Instrumental Methods of Chemical Analysis 3 3

18 B
Instrumental Methods of Chemical Analysis 2 1

Green Chemistry 3 3
19 A
Green Chemistry 2 1

OR
3 3
19 B Analysis of Drugs, Foods, Dairy Products& Bio Chemical
Analysis
2 1
Analysis of Drugs, Foods, DairyProducts& Bio Chemical Analysis
SEC
3 3
20 A Polymer Chemistry
2 1
Polymer Chemistry

OR
3 3
20 B Industrial Chemicals and Environment
2 1
Industrial Chemicals and Environment

Open Online trans disciplinary course

3 3
21 A Inorganic Chemistry: Metal Cluster, Electronic spectra of
Complex compounds and Bio- inorganic chemistry
VIII
2 1
Inorganic Chemistry: Metal Cluster, Electronic spectra of
Complex compounds and Bio- inorganic chemistry
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

OR
3 3
21 B Organo metallic Chemistry
2 1
Organo metallic Chemistry
3 3
22 A Modern Organic synthesis and Natural Products Modern
2 1
Modern Organic synthesis and Natural Products Modern

OR
3 3
22 B Chemistry of Natural products
2 1
Chemistry of Natural products
3 3
23 A Physical Chemistry: Quantum And Molecular Spectroscopy
2 1
Physical Chemistry: Quantum And Molecular Spectroscopy

OR
3 3
23 B Analytical Methods of Analysis
2 1
Analytical Methods of Analysis
3 3
SEC 24 A Pharmaceutical and Medicinal Chemistry
2 1
Pharmaceutical and Medicinal Chemistry

OR
3 3
24 B Pesticides and Green Chemistry
2 1
Pesticides and Green Chemistry
3 3
25A Corrosion and Its Prevention
2 1
Corrosion and Its Prevention
3 3
25 B Material & Energy Balances and Utilities in Chemical Industry
2 1
Material & Energy Balances and Utilities in Chemical Industry

Open Online trans disciplinary course

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

SEMESTER-I
COURSE 1: ESSENTIALS AND APPLICATIONS OF MATHEMATICAL, PHYSICAL
AND CHEMICAL SCIENCES
Theory Credits: 4 5 hrs/week

Course Objective:
The objective of this course is to provide students with a comprehensive understanding of the
essential concepts and applications of mathematical, physical, and chemical sciences. The
course aims to develop students' critical thinking, problem-solving, and analytical skills in
these areas, enabling them to apply scientific principles to real-world situations.
Learning outcomes:
1. Apply critical thinking skills to solve complex problems involving complex numbers,
trigonometric ratios, vectors, and statistical measures.
2. To Explain the basic principles and concepts underlying a broad range of fundamental
areas of physics and to Connect their knowledge of physics to everyday situations
3. To Explain the basic principles and concepts underlying a broad range of fundamental
areas of chemistry and to Connect their knowledge of chemistry to daily life.
4. Understand the interplay and connections between mathematics, physics, and chemistry in
various applications. Recognize how mathematical models and physical and chemical
principles can be used to explain and predict phenomena in different contexts.
5 To explore the history and evolution of the Internet and to gain an understanding of network
security concepts, including threats, vulnerabilities, and countermeasures.
UNIT I: ESSENTIALS OF MATHEMATICS:
Complex Numbers: Introduction of the new symbol i – General form of a complex number –
Modulus-Amplitude form and conversions
Trigonometric Ratios: Trigonometric Ratios and their relations – Problems on calculation of
angles Vectors: Definition of vector addition – Cartesian form – Scalar and vector product
andproblems Statistical Measures: Mean, Median, Mode of a data and problems

UNIT II: ESSENTIALS OF PHYSICS:

Definition and Scope of Physics- Measurements and Units - Motion of objects: Newtonian
Mechanics and relativistic mechanics perspective - Laws of Thermodynamics and
Significance- Acoustic waves and electromagnetic waves- Electric and Magnetic fields and
their interactions- Behaviour of atomic and nuclear particles- Wave-particle duality, the
uncertainty principle- Theories and understanding of universe
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

UNIT III: ESSENTIALS OF CHEMISTRY:

Definition and Scope of Chemistry- Importance of Chemistry in daily life -Branches of
chemistry and significance- Periodic Table- Electronic Configuration, chemical changes,
classification of matter, Biomolecules- carbohydrates, proteins, fats and vitamins.

UNIT IV: APPLICATIONS OF MATHEMATICS, PHYSICS & CHEMISTRY:

Applications of Mathematics in Physics & Chemistry: Calculus, Differential Equations &
Complex Analysis
Application of Physics in Industry and Technology: Electronics and Semiconductor
Industry, Robotics and Automation, Automotive and Aerospace Industries, Quality Control and
Instrumentation, Environmental Monitoring and Sustainable Technologies.
Application of Chemistry in Industry and Technology: Chemical Manufacturing,
Pharmaceuticals and Drug Discovery, Materials Science, Food and Beverage Industry.

UNIT V: ESSENTIALS OF COMPUTER SCIENCE:

Milestones of computer evolution - Internet, history, Internet Service Providers, Types of
Networks, IP, Domain Name Services, applications.
Ethical and social implications: Network and security concepts- Information Assurance
Fundamentals, Cryptography-Symmetric and Asymmetric, Malware, Firewalls, Fraud
Techniques- Privacy and Data Protection
Recommended books:
1. Functions of one complex variable by John.B.Conway, Springer- Verlag.
2. Elementary Trigonometry by H.S.Hall and S.R.Knight
3. Vector Algebra by A.R.Vasishtha, Krishna Prakashan Media(P)Ltd.
4. Basic Statistics by B.L.Agarwal, New age international Publishers
5. University Physics with Modern Physics by Hugh D. Young and Roger A. Freedman
6. Fundamentals of Physics by David Halliday, Robert Resnick, and Jearl Walker
7. Physics for Scientists and Engineers with Modern Physics" by Raymond A. Serway and
John W. Jewett Jr.
8. Physics for Technology and Engineering" by John Bird
9. Chemistry in daily life by Kirpal Singh
10. Chemistry of bio molecules by S. P. Bhutan
11. Fundamentals of Computers by V. Raja Raman
12. Cyber Security Essentials by James Graham, Richard Howard, Ryan Olson
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

STUDENT ACTIVITIES
UNIT I: ESSENTIALS OF MATHEMATICS:
1: Complex Number Exploration
Provide students with a set of complex numbers in both rectangular and polar forms.
They will plot the complex numbers on the complex plane and identify their properties
2: Trigonometric Ratios Problem Solving
Give students a set of problems that require the calculation of trigonometric ratios and their
relations.
Students will solve the problems using the appropriate trigonometric functions (sine, cosine,
tangent, etc.) and trigonometric identities.
3: Vector Operations and Applications
Provide students with a set of vectors in Cartesian form.
Students will perform vector addition and subtraction operations to find the resultant vectors.
They will also calculate the scalar and vector products of given vectors.
4: Statistical Measures and Data Analysis
Give students a dataset containing numerical values.
Students will calculate the mean, median, and mode of the data, as well as other statistical
measures if appropriate (e.g., range, standard deviation).
They will interpret the results and analyze the central tendencies and distribution of the data.
UNIT II: ESSENTIALS OF PHYSICS:
1. Concept Mapping
Divide students into groups and assign each group one of the topics.
Students will create a concept map illustrating the key concepts, relationships, and
applications related to their assigned topic.
Encourage students to use visual elements, arrows, and labels to represent connections and
interdependencies between concepts.
2. Laboratory Experiment
Select a laboratory experiment related to one of the topics, such as motion of objects or
electric and magnetic fields.
Provide the necessary materials, instructions, and safety guidelines for conducting the
experiment.
Students will work in small groups to carry out the experiment, collect data, and analyze the
results.
After the experiment, students will write a lab report summarizing their findings,
observations, and conclusions.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

UNIT III: ESSENTIALS OF CHEMISTRY

1: Chemistry in Daily Life Presentation
Divide students into groups and assign each group a specific aspect of daily life where
chemistry plays a significant role, such as food and nutrition, household products, medicine, or
environmental issues.
Students will research and create a presentation (e.g., PowerPoint, poster, or video) that
showcases the importance of chemistry in their assigned aspect.
2: Periodic Table Exploration
Provide students with a copy of the periodic table.
Students will explore the periodic table and its significance in organizing elements based on
their properties.
They will identify and analyze trends in atomic structure, such as electronic configuration,
atomic size, and ionization energy.
3: Chemical Changes and Classification of Matter
Provide students with various substances and chemical reactions, such as mixing acids and
bases or observing a combustion reaction.
Students will observe and describe the chemical changes that occur, including changes in
color, temperature, or the formation of new substances.
4: Biomolecules Investigation
Assign each student or group a specific biomolecule category, such as carbohydrates, proteins,
fats, or vitamins.
Students will research and gather information about their assigned biomolecule category,
including its structure, functions, sources, and importance in the human body.
They can create informative posters or presentations to present their findings to the class.
UNIT IV: APPLICATIONS OF MATHEMATICS, PHYSICS & CHEMISTRY
1: Interdisciplinary Case Studies
Divide students into small groups and provide them with interdisciplinary case studies that
involve the interdisciplinary application of mathematics, physics, and chemistry.
Each case study should present a real-world problem or scenario that requires the integration
of concepts from all three disciplines.
2: Design and Innovation Project
Challenge students to design and develop a practical solution or innovation that integrates
mathematics, physics, and chemistry principles.
Students can choose a specific problem or area of interest, such as renewable energy,
environmental conservation, or materials science.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

3: Laboratory Experiments
Assign students laboratory experiments that demonstrate the practical applications of
mathematics, physics, and chemistry.
Examples include investigating the relationship between concentration and reaction rate,
analyzing the behavior of electrical circuits, or measuring the properties of materials.
.4: Mathematical Modeling
Present students with real-world problems that require mathematical modeling and analysis.
UNIT V: ESSENTIALS OF COMPUTER SCIENCE:
1. Identifying the attributes of network (Topology, service provider, IP address and bandwidth
of
2. your college network) and prepare a report covering network architecture.
3. Identify the types of malwares and required firewalls to provide security.
4. Latest Fraud techniques used by hackers.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Course – I & II Model Paper Time:3Hrs (70 Marks)

SECTION A (Multiple Choice Questions) 30 x 1 = 30 M

30 Multiple Choice Questions (Each Unit 6 Questions)

SECTION B (Fill in the blanks) 10 x 1 = 10 M

10 Fill in the Blanks (Each Unit 2 Questions)

SECTION C (Very short answer questions) 10 x 1 = 10 M

10 Very short answer questions (Each Unit 2 Questions)

SECTION D (Matching) (From 5 Units) 2 x 5 = 10 M

1 A
B
C
D
E

2 A
B
C
D
E

SECTION E (True or False) 10 x 1 = 10 M

10 True or False (Each Unit 2 Questions)
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Single Major (w.e.f. AY 2023-24)

SEMESTER-I
COURSE – 1 ESSENTIALS AND APPLICATIONS OF MATHEMATICAL, PHYSICAL &
CHEMICAL SCIENCES
Time:3hrs MAX MARKS: 70 M
I Multiple Choice Questions 3x10=30M
1. If Arg(Z) < 0 the Arg (-Z) – arg (Z) = [ ]
−
𝜋
a) 𝜋 b) −𝜋
c) 2 d) 𝜋
4 2

2. If  1 and Arg (Z Z )  0 then [ ]

1 2

a) Z1  Z2 b) Z1 2  Z1Z 2 c) Z1Z2  1 d) None of these

3. The value of sin 50  sin 70  sin 10 is equal to [ ]
a) 1 b) 0 c) ½ d) 2
4. If a  mb  3c ,  2a  3b  5c and a  3b  5c are coplanar m= [ ]
a) 2 b) -1 c) 1 d) -9/7
5. If the vectors 2i   j  k and 4i  2 j  2k are perpendicular to each other,
then
= [ ]
a) 2 b) 5 c) 3 d) 1
6. Find the mode for the following data 0,0,1,1,2,2,2,4,5. [ ]
a) 1 b) 0 c) 4 d) 2
7. Newton – Second is the unit of [ ]
a) Velocity b) Angular Momentum c) Momentum d) Energy
8. If the force applied to a body is doubled and the mass is cut in half. What
would be the acceleration ratio? [ ]
a) 1:2 b) 2:1 c) 1:4 d) 4:1
9. Which unit is used to measure angle the S.I system? [ ]
a) Radian b) Steradian c) Degree d) Minute
10. The mass – Energy relation is given by [ ]
a) E = mc2 b) F = ma c) P = mv d) W = Fd
11. How many types of Robots are there [ ]
a) 7 b) 10 c) 6 d) 8
12. Light energy emitted by stars is due to [ ]
a) Breaking of nuclei b) Joining of nucles
c) Burning of nuclei d) Reflection of Solar Light
13. Organic chemistry is the study of . [ ]
a) Nitrogen based compoundsb) Carbon based compounds
c) Copper based compounds d) Chromium based compounds
14. Number of electrons present in outer shell of chlorine atom is [ ]
a) 5 b) 6 c) 7 d) 8
15. Which of the following is a disacchanide [ ]
a) Sucrose b) Glucose c) Fructose d) Ribose
16. The Monomers present in proteins are [ ]
a) Alcohols b) Acids c) Amino acids d) Esters
17. Lipids composed mainly of [ ]
a) C, H, N b) C, H, O c) O, N, S d) N, S, Cl
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

18. Vitamin by is also known as [ ]

a) Vitamin – H b) Vitamin – O c) Vitamin – Bd) Vitamin – L
19. Who is introduced in Calculus . [ ]
a) Isaac Newton b) Goff fried Leibniz
c) Both of the mentioned d) None of the mentioned
20. How many systems does a robot have . [ ]
a) 2 b) 6 c) 4 d) 3
21. A place where power information (or) a result leaves a system. [ ]
a) Chassis b) Output c) Sensor d) Input
22. The main electronic component used in first generation computers was [ ]
a) Transistors b) Vacuum Tubes and Valves
c) Integrated Circuits d) None of above
23. Magnetic disk is an example of [ ]
a) Secondary memory b) Primary memory
c) Main memory d) Both 1 & 2
24. http stands for [ ]
a) hypertext transfer protocol b) hypertext transmission protocol
c) high transfer transport protocol d) hyper transfer text protocol
25. What is the full form of WWW? [ ]
a) World Wide Web b) World with Web
c) Work Wide Web d) World Wide Wet
26. Which one of the following is a type of antivirus program? [ ]
a) Quick heal b) Mcafee
c) Kaspersky d) All of the above
27. Hackers usually used the computer virus for purpose. [ ]
a) To log, monitor each and every user’s stroke
b) To gain access the sensitive information like user’s Id and Passwords
c) To corrupt the user’s data stored in the computer system
d) All of the above
28. Which of the following is an example of f BDD screening technique [ ]
a) U V spectroscopy b) HPLC c) NMR spectroscopy d) None
29. Fertilizers mainly consists of [ ]
a) N, P, K b) O, N, Cl c) C, O, K d) H, P, O
30. The substance that facilitate chemical reactions without being consumed is
[ ]
a) Reactions b) Product c) Catalyst d) Inhibin

SECTION – B
II Fill in the Blanks 10x1=10M

1. Find the value of 3 cos ec20  sec 20 is
 
. 
     
2. The area of the parallelogram whose diagonals are 3 i  j 2 k and i  3 j 4 k
is .
3. is the number of cycles made by a sounding body per unit time.
4. A light year is a unit of .
5. EXPAND SAR .
6. Peptide bond formula .
7. A robot is a .
8. Differential equations that the definition of linear are nonlinear.
9. A string of 8 bits is
10. ROM stands for
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

SECTION – C

III Answer the following Short Questions 10x1=10M

1. If 3 tan A = 5 then Find Sin A and Cos A.
2. Find A.M from the following distribution.
Wages 100 120 140 160 180 200
No of
4 8 12 7 6 3
workers
3. Write any two applications of Semi – Conductor?
4. Define Zeroth law of Thermodynamics? with example.
5. Expand FBDD.
6. What are fat soluble vitamins?
7. Define Newton’s 1st Law.
8. Write any two application of Environmental monitoring?
9. What is E-mail?
10. What is a gateway?

SECTION – D
III Match the following 10x1=10M
1. A. Unit Vector in the
direction a  3i  2 j  6k ( ) a) Angular Momentum
B. Polar form 1  3i ( ) b) Glucose
C. Joule x Sec ( ) c)
1
 3i  2 j  6k
7  2   2 
D. Mass of a proton ( ) d) 2 cos  i sin 
    

  3   3 
E. Reducing Sugar ( ) e) 1.676 x 10-24 grams

2. A. Vitamin – B12 ( ) a) Newton

B. Force ( ) b) Newton second
C. Impulse ( ) c) RBC formation
D. Punch Card ( ) d) Computer games
E. Joy Stick ( ) e) Hollerith code
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

SECTION – E
IV True (or) False 10x1=10M
1. If Z is a complex number then Z Z is purely real.
2.  2
If Z is a complex number such that Z 2  Z then purely real.
3. The Mass of a body is equivalent to the ratio of the force action on it to
the acceleration it generates.
4. The region of the atmosphere above troposphere is known as
Lithosphere.
5. Essential Amino acids can be synthesized by the human body
6. Electrons fill the lowest energy levels first
7. For every action is nature here is an unequal and opposite reaction.
8. The special theory of relativity is concerned with frames of reference that
are not experiencing any acceleration.
9. A terabyte is equal to 1 million gigabytes
10. Remote browser access is used to avoid browser-based hacking.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

SEMESTER-I
COURSE 2: ADVANCES IN MATHEMATICAL, PHYSICALAND CHEMICAL
SCIENCES
Theory Credits: 4 5 hrs/week
Course Objective:
The objective of this course is to provide students with an in-depth understanding of the recent
advances and cutting-edge research in mathematical, physical, and chemical sciences. The
course aims to broaden students' knowledge beyond the foundational concepts and expose them
to the latest developments in these disciplines, fostering critical thinking, research skills, and
the ability to contribute to scientific advancements.
Learning outcomes:
1. Explore the applications of mathematics in various fields of physics and chemistry, to
understand how mathematical concepts are used to model and solve real-world problems.
2. To Explain the basic principles and concepts underlying a broad range of fundamental areas
of physics and to Connect their knowledge of physics to everyday situations.
3. Understand the different sources of renewable energy and their generation processes and
advances in nanomaterials and their properties, with a focus on quantum dots. To study the
emerging field of quantum communication and its potential applications. To gain an
understanding of the principles of biophysics in studying biological systems. Explore the
properties and applications of shape memory materials.
3. Understand the principles and techniques used in computer-aided drug design and drug
delivery systems, to understand the fabrication techniques and working principles of
nanosensors. Explore the effects of chemical pollutants on ecosystems and human health.
4. Understand the interplay and connections between mathematics, physics, and chemistry in
various advanced applications. Recognize how mathematical models and physical and
chemical principles can be used to explain and predict phenomena in different contexts.
5 Understand and convert between different number systems, such as binary, octal, decimal,
and hexadecimal. Differentiate between analog and digital signals and understand their
characteristics. Gain knowledge of different types of transmission media, such as wired (e.g.,
copper cables, fiber optics) and wireless (e.g., radio waves, microwave, satellite).

UNIT I: ADVANCES IN BASICS MATHEMATICS

Straight Lines: Different forms – Reduction of general equation into various forms –
Point of intersection of two straight lines
Limits and Differentiation: Standard limits – Derivative of a function –Problems on
product rule and quotient rule
Integration: Integration as a reverse process of differentiation – Basic methods of integration
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Matrices: Types of matrices – Scalar multiple of a matrix – Multiplication of matrices –

Transpose of a matrix and determinants
UNIT II: ADVANCES IN PHYSICS:
Renewable energy: Generation, energy storage, and energy-efficient materials and devices.
Recent advances in the field of nanotechnology: Quantum dots, Quantum Communication-
recent advances in biophysics- recent advances in medical physics- Shape Memory Materials.
UNIT III: ADVANCES IN CHEMISTRY:
Computer aided drug design and delivery, nano sensors, Chemical Biology, impact of chemical
pollutants on ecosystems and human health, Dye removal - Catalysis method
UNIT IV: ADVANCED APPLICATIONS OF MATHEMATICS, PHYSICS &
CHEMISTRY
Mathematical Modelling applications in physics and chemistry
Application of Renewable energy: Grid Integration and Smart Grids,
Application of nanotechnology: Nanomedicine,
Application of biophysics: Biophysical Imaging, Biomechanics, Neurophysics,
Application of medical physics: Radiation Therapy, Nuclear medicine
Solid waste management, Environmental remediation- Green Technology, Water treatment.
UNIT V: Advanced Applications of computer Science
Number System-Binary, Octal, decimal, and Hexadecimal, Signals-Analog, Digital, Modem,
Codec, Multiplexing, Transmission media, error detection and correction- Parity check and
CRC, Networking devices- Repeater, hub, bridge, switch, router, gateway.
Recommended books:
1. Coordinate Geometry by S.L.Lony, Arihant Publications
2. Calculus by Thomas and Finny, Pearson Publications
3. Matrices by A.R.Vasishtha and A.K.Vasishtha, Krishna Prakashan Media(P)Ltd.
4. "Renewable Energy: Power for a Sustainable Future" by Godfrey Boyle
5. "Energy Storage: A Nontechnical Guide" by Richard Baxter
6. "Nanotechnology: Principles and Applications" by Sulabha K. Kulkarni and Raghvendra A.
Bohara
7. "Biophysics: An Introduction" by Rodney Cotterill
8. "Medical Physics: Imaging" by James G. Webster
9. "Shape Memory Alloys: Properties and Applications" by Dimitris C. Lagoudas
10. Nano materials and applications by M.N.Borah
11. Environmental Chemistry by Anil.K.D.E.
12. Digital Logic Design by Morris Mano
13. Data Communication & Networking by Bahrouz Forouzan.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

STUDENT ACTIVITIES

UNIT I: ADVANCES IN BASIC MATHEMATICS

1: Straight Lines Exploration
Provide students with a set of equations representing straight lines in different forms, such
as slope-intercept form, point-slope form, or general form.
Students will explore the properties and characteristics of straight lines, including their
slopes, intercepts, and point of intersection.
2: Limits and Differentiation Problem Solving
Students will apply the concept of limits to solve various problems using standard limits.
Encourage students to interpret the results and make connections to real-world applications,
such as analyzing rates of change or optimizing functions.
3: Integration Exploration
Students will explore the concept of integration as a reverse process of differentiation and
apply basic methods of integration, such as the product rule, substitution method, or
integration by parts.
Students can discuss the significance of integration in various fields, such as physics and
chemistry
4: Matrices Manipulation
Students will perform operations on matrices, including scalar multiplication, matrix
multiplication, and matrix transpose.
Students can apply their knowledge of matrices to real-world applications, such as solving
systems of equations or representing transformations in geometry.
UNIT II: ADVANCES IN PHYSICS:
1: Case Studies
Provide students with real-world case studies related to renewable energy, nanotechnology,
biophysics, medical physics, or shape memory materials.
Students will analyze the case studies, identify the challenges or problems presented,
and propose innovative solutions based on the recent advances in the respective field.
They will consider factors such as energy generation, energy storage, efficiency,
sustainability, materials design, biomedical applications, or technological advancements.
2: Experimental Design
Assign students to design and conduct experiments related to one of the topics:
renewable energy, nanotechnology, biophysics, medical physics, or shape
memorymaterials.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)
B.Sc. Honours Course Syllabus (Single Major)
(w.e.f:2023-24A.B)

They will identify a specific research question or problem to investigate and design
an experiment accordingly.
Students will collect and analyze data, interpret the results, and draw conclusions based
on their findings.
They will discuss the implications of their experimental results in the context of recent
advances in the field.
3: Group Discussion and Debate
Organize a group discussion or debate session where students will discuss the ethical,
social, and environmental implications of the recent advances in renewable energy,
nanotechnology, biophysics, medical physics, and shape memory materials.
Assign students specific roles, such as proponent, opponent, or moderator, and provide
them with key points and arguments to support their positions.
UNIT III: ADVANCES IN CHEMISTRY:
1. Experimental Design and Simulation
In small groups, students will design experiments or simulations related to the assigned topic.
For example, in the context of computer-aided drug design, students could design a virtual
screening experiment to identify potential drug candidates for a specific disease target.
For nano sensors, students could design an experiment to demonstrate the sensitivity
and selectivity of nano sensors in detecting specific analytes.
Chemical biology-related activities could involve designing experiments to study
enzyme-substrate interactions or molecular interactions in biological systems.
Students will perform their experiments or simulations, collect data, analyze the results,and
draw conclusions based on their findings.
2. Case Studies and Discussion
Provide students with real-world case studies related to the impact of chemical pollutants
oneco systems and human health.
Students will analyze the case studies, identify the sources and effects of chemical
pollutants, and propose mitigation strategies to minimize their impact.
Encourage discussions on the ethical and environmental considerations when dealing
with chemical pollutants.
For the dye removal using the catalysis method, students can explore case studies
where catalytic processes are used to degrade or remove dyes from wastewater.
Students will discuss the principles of catalysis, the advantages and limitations of
the catalysis method, and its applications in environmental remediation.
3: Group Project
Assign students to work in groups to develop a project related to one of the topics.
The project could involve designing a computer-aided drug delivery system, developing a
nano sensor for a specific application, or proposing strategies to mitigate the impact of
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

chemical pollutants on ecosystems.

Students will develop a detailed project plan, conduct experiments or simulations,analyze
data, and present their findings and recommendations.
Encourage creativity, critical thinking, and collaboration throughout the project.
UNIT IV: ADVANCED APPLICATIONS OF MATHEMATICS, PHYSICS &
CHEMISTRY
1: Mathematical Modelling Experiment
Provide students with a mathematical modelling experiment related to one of the topics. For
example, in the context of renewable energy, students can develop a mathematical model to
optimize the placement and configuration of solar panels in a solar farm.
Students will work in teams to design and conduct the experiment, collect data, and analyze the
results using mathematical models and statistical techniques.
They will discuss the accuracy and limitations of their model, propose improvements, and interpret the
implications of their findings in the context of renewable energy or the specific application area.
2: Case Studies and Group Discussions
Assign students to analyze case studies related to the applications of mathematical
modelling in nanotechnology, biophysics, medical physics, solid waste management,
environmental remediation, or water treatment.
Students will discuss the mathematical models and computational methods used in the case
studies, analyze the outcomes, and evaluate the effectiveness of the modelling approach.
Encourage group discussions on the challenges, ethical considerations, and
potential advancements in the field.
Students will present their findings and engage in critical discussions on the advantages and
limitations of mathematical modelling in solving complex problems in these areas.
3. Group Project
Assign students to work in groups to develop a group project that integrates mathematical modelling
with one of the application areas: renewable energy, nanotechnology, biophysics,medical physics,
solid waste management, environmental remediation, or water treatment.
The project could involve developing a mathematical model to optimize the delivery of
radiation therapy in medical physics or designing a mathematical model to optimize waste
management practices.
Students will plan and execute their project, apply mathematical modelling techniques,
analyze the results, and present their findings and recommendations.Encourage
creativity, critical thinking, and collaboration throughout the project.

UNIT V: Advanced Applications of computer Science

Students must be able to convert numbers from other number system to binary number
systems
1. Identify the networking media used for your college network
2. Identify all the networking devices used in your college premises.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Course – I & II Model Paper Time: 3Hrs (70 Marks)

SECTION A (Multiple Choice Questions) 30 x 1 = 30 M

30 Multiple Choice Questions (Each Unit 6 Questions)

SECTION B (Fill in the blanks) 10 x 1 = 10 M

10 Fill in the Blanks (Each Unit 2 Questions)

SECTION C (Very short answer questions) 10 x 1 = 10 M

10 Very short answer questions (Each Unit 2 Questions)

SECTION D (Matching) (From 5 Units) 2 x 5 = 10 M

1 A
B
C
D
E

2 A
B
C
D
E

SECTION E (True or False) 10 x 1 = 10 M

10 True or False (Each Unit 2 Questions)
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Single Major (w.e.f. AY 2023-24)

SEMESTER-I
Model Paper
COURSE -2 ADVANCES OF MATHEMATICAL, PHYSICAL & CHEMICAL SCIENCES
Time: 3Hrs MAX MARKS: 70 M

I Multiple Choice Questions 3x10=30M

SECTION – A
1. The equation of the line passing through the point (1, 2) and perpendicular to the line x+y+1=0 is
[ ]
a) y-x+1=0 b) y-x-1=0 c) y-x+2=0 d) y-x-2=0
Lt
1  cos 2x
x
2. 0 is equal to [ ]
x2
a) 0 b) 1 c) 2 d) 4
3. The derivative of cos12x2 1 w.r.to cos1x is [ ]
1 c)
2
d) 1- x2
a) 2 b)
2 1  x2 x
4.  etan x sec2 x dx = [ ]
a) etan x b) esin x c) tan x d) sin x
 1 0  3 4
5. If 2x  y   and 2x  y   then X is equal to [ ]
 3   1 
 2   2 
 4 4  1 1 1  2
a)   c) 1  d) None of these
 b)  1 1 0 
 4 4  
6. If A  aijmxn such that aij = 0 for i  j then A is [ ]
a) a row matrix b) a column matrix
c) a diagonal matrix d) a scalar matrix
7. Which of the following is an renewable energy source [ ]
a) Coal b) Natural gas c) Solar d) Nuclear
8. What is the main purpose of Photovoltaic cells in solar panels [ ]
a) Heat generation b) Electricity generation c) Water purification d) Carbon captune
9. Which renewable energy source is harnessed from the earth’s
Internal heat? [ ]
a) Solar b) Wind c) Geothermal d) Hydro
10. What is the fundamental principle behind quantum mechanics [ ]
a) Classical Mechanics b) Quantum Superposition c) Newton law of motion d) Maxwell’s equation
11. What is the primary application of proton therapy in medical physics? [ ]
a) Diagnostic Imaging b) Radiation therapy c) Magnetic resonance Imaging
d) Computed Tomography (C.T)
12. What is the primary advantage of using quantum dob in solar cells? [ ]

a) Low cost b) High efficiency

c) Fast charging d) Large size
13. The Binding capacity between the drug and target is known as [ ]
a) Virtual Screening b) Docking Score c) ADMET d) None
14. The Increased sensitivity of Nanosensors is due to [ ]
a) High Surface-to-volume ratio b) Low surface-to-volume ratio
15. The green pigment chlorophyll is affected by [ ]
a) Co2 b) No2 c) So2 d) CH4
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

16. What is the Photo catalyst used in the dye renoval catalysis method [ ]

a) Oxygen b) Hydrogen c) Titanium Oxide d) Zinc

17. Which phase of Shape memory alloy occurs at higher temperature & has a needle – like structure
[ ]
a) Martensite b) Austenite c) Hysterisis d) None
18. The Pollutant causing Global warming [ ]
a) Co2 b) So2 c) No2 d) O3
19. In Quantum mechanics, the Schrodinger Equation is a fundamental Equation, used to model the
behavior of particles. What does the Schrodinger Equation describe [ ]
a) Stability b) Wave-Particle duality
c) Degidity d) Massive
20. What is the term used to describe the process of using nano particles to enhance imaging techniques
for medical diagnostics [ ]
a) Nano Scopy b) Nano Therapy c) Nano Diagnose d) None of these
21. How can nano medicine contribute to personalized medicine? [ ]
a) By increasing the cost of medical treatment.
b) By using a one-size –fits all approach.
c) By tailoring based on an individual’s genetic make-up.
d) By avoiding the use of advanced technologies.
22. In radiation therapy, What does the term “brancy therapy” refer to [ ]
a) External beam radiation therapy
b) Radiation therapy using photons
c) Internal radiation therapy involving the placement of radio active sources directly within or
close to the tumor.
d) Radiation therapy without the use of imaging.
23. What is the purpose of coagulation in the water treatment process? [ ]
a) Removing dissolved minerals
b) Disinteching water
c) Settling suspended particals
d) Adjusting PH levels
24. What is the purpose of green building design and construction? [ ]
a) maximizing energy consumption
b) minimizing the use of sustainable materials
c) Reducing the environmental impact of buildings
d) Ignoring energy – efficient technologies
25. Hybrid system combine which two types of signals? [ ]
a) Analog and Analog b) Digital and Digital c) Analog and Digital d) Continuous and Finite
26. Which error detection technique can detect a wide range of errors including burst errors and most
multiple bits.
a) Hamming code b) Read- Solomon code c) Parity check d) CRC
27. Which layer of the OSI model does a router operate at [ ]
a) Transport layer b) Network layer c) Transport layer d) Data link layer
28. What technology allows DSL modems to separate voice and data signals.
a) Dail-up modem b) DSL modem c) Wireless modem d) Cable modem
Ans b) DSL modem
29. What protocol do bridges use to prevent network loops? [ ]
a) Internet Protocol b) Transmission Control Protocol (TCP)
c) Simple Network Management Protocol (SNMP) d) Spanning Tree Protocol (STP)
30. The…………. between two words is the number of difference between corresponding bits
a) Hamming code b) Hamming distance [ ]
c) Hamming rule d) Hamming data
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

SECTION – B
III Fill in the Blanks 10x1=10M
1. Tidal energy is an Example for energy.
2. are the particles used in quantum dots.
3. Expand CADD
4. First step in the purification of water
5. is an application for Medical Physics.
6. MRI stands for
7.  ex sin x cos xdx  .
8. Equation of the lines through the point (3, 2) and making an angle of 45° with the line x-2y = 3 are
.
9. A computer understands only ...................... code
10. ................................ converts audio and video into digital information

SECTION – C
III Answer the following Questions 10x1=10M
1. Give some Examples for renewable sources?
2. Information stored in quantum computer in the form of?
3. What is the difference between MRI and C.T. Scan?
4. Name two applications of Nanotechnology?
5. Solid waste Management? (SWM)
6. Expand ADMET
Lt
ax  x cos x
7. x0 ; Evaluate
b sin x
Evaluate  xlog x dx
2
8.
9. What are the key design issues of the computer networks?
10. What is multiplexing?

SECTION – D
III Match the following 10x1=10M
1. A. Wind energy ( ) a) Orthodontic applications
B. Solar energy ( ) b) Non invasile imaging
C. Minamata ( ) c) Harness the kinetic energy of
wind to produce electricity
D. Ni-Ti wire ( ) d) Convert sunlight into electricity
E. Magnetic Resonance Imaging ( ) e) Mercury
2. A. Fluoroscene microscopy ( ) a) 3
 3  4
B.   3 then m value is ( ) b) Moniterity cellular

m 5 
d
C. log sec x  tan x ( ) c) F1
dx
D. 1111000l ( ) d) Guided media
E. Ethernet cable ( ) e) (secx)
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

SECTION – E
IV True (or) False 10x1=10M
1. Quantum dots are the nano particles, are primarily used for structural
Reintor cement in medical implants?

2. Quantum mechanics is a branch of physics Extensively used mathematical

Models, to describe the behavior of particles at atomic and subatomic level.

3. The Mass of a body is equivalent to the ratio of the force action on it to the
acceleration it generates.

4. The region of the atmosphere above troposphere is known as Lithosphere.

5. Essential Amino acids can be synthesized by the human body

6. Electrons fill the lowest energy levels first

7. The equation of a line with slope m and making an intercept c on y axis is y=mx

8. Intercept form of a line which cuts a and b respectively on the x and y axis
x y
Then  1
a b
9. A university would use a CAN to converts its composes in two cities.

10. Gateway device is operate at transport layer.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

II - SEMESTER

Course Code 3: GENERAL AND INORGANIC CHEMISTRY

Credits: 03

Course Outcomes: At the end of the course the student will be able to-

1. Understand the structure of atom and the arrangement of elements in the

periodic table.

2. Understand the nature and properties of ionic compounds.

3. Identify the structure of a given inorganic compound.

4. Explain the existence of special types of compounds through weak chemical forces.

5. Define acids and bases and predict the nature of salts.

Syllabus:

Unit I: Atomic Structure and Periodic table (9 h)

Electronic configuration: Bohr theory, duel nature of electrons, Heisenberg

uncertainty principle, the Schrodinger equation, significance of wave functions,
normalization of wave function, radial and angular wave functions, Pauli’s exclusion
principle, Hund’s rule, sequence of energy levels (Aufbau principle).

Periodicity: periodic law and arrangement of elements in the periodic table, IUPAC
nomenclature and group number, horizontal, vertical, and diagonal relationships in
the periodic table. 1.3 General properties of atoms: size of atoms and ions-atomic
radii, ionic radii, covalent radii; trend in ionic radii, ionization potential, electron
affinity; electronegativity - Pauling, Mulliken-Jaffe, Allred-Rochow definitions;
oxidation states and variable valency; isoelectronic relationship; inert-pair effect;
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

UNIT 2: Ionic bond (9 h)

Properties of ionic compounds, factors favouring the formation of ionic compounds-

ionization potential, electron affinity, and electronegativity. Lattice energy:
definition, factors affecting lattice energy, Born-Haber cycle-enthalpy of formation

of ionic compound and stability. Stability of ionic compounds in terms of ∆Hfand Uo.
Solubility and thermal stability of ionic compounds. Covalent character in ionic
compounds-polarization and Fajan’s rules; effects of polarization-solubility, melting
points, and thermal stability of typical ionic compounds.

UNIT 3: The Covalent Bond (9 h)

Valance Bond theory-arrangement of electrons in molecules, hybridization of atomic

orbitals and geometry of molecules-BeCl2, BF3, CH4, PCl5, SF6– VSEPR model-
effect of bonding and nonbonding electrons on the structure of molecules, effect of
electronegativity,
isoelectronic principle, illustration of structures by VESPR model-NH3, H2O, SF4, 𝐼𝐶𝑙− ,4
2
𝐼𝐶𝑙− , XeF4, XeF6
Molecular orbital theory -LCAO method, construction of M.O. diagrams for homo-
nuclear and hetero-nuclear diatomic molecules (N2, O2, CO and NO)

UNIT 4: Metallic and Weak Bonds (9 h)

The Metallic bond: metallic properties, free electron theory, Valence Bond Theory,
band theory of metals. Explanation of conductors, semiconductors and insulators.

Weak bonds: hydrogen bonding-intra- and intermolecular hydrogen bonding,

influence on the physical properties of molecules, comparison of hydrogen bond
strength and properties of hydrogen bonded N, O and F compounds; associated
molecules-ethanol and acetic acid; Vanderwaals forces, ion dipole-dipole
interactions.
UNIT 5: Acids and Bases (9 h)

Theories of acids and bases: Arrhenius theory, Bronsted-Lowry theory, Lewis theory,
the solvent system, Nonaqueous solvents: classification-protonic and aprotic
solvents, liquid ammonia as solvent-solutions of alkali and alkaline earth metals in
ammonia.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Types of chemical reactions: acid-base, oxidation-reduction, calculation of oxidation

number. Definition of pH, pKa, pKb. Types of salts, Salt hydrolysis. Pearson’s
concept, HSAB principle & its importance, bonding in Hard-Hard andSoft-Soft
combinations.

List of Reference Books:

1. J. D. Lee, Concise Inorganic Chemistry, 5th ed., Blackwell Science, London, 1996.

2. . B. R. Puri, L. R. Sharma, K. C. Kalia, Principles of Inorganic Chemistry,

Shoban Lal Nagin Chand and Co., 1996.

3. D. F. Shriver and P. W. Atkins, Inorganic Chemistry, 3rd ed., W. H. Freeman

and Co, London,
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

II - SEMESTER

Course Code 3: GENERAL AND INORGANIC CHEMISTRY

Credits: 01

Practical- I Qualitative Analysis of SIMPLE SALT

Qualitative inorganic analysis (Minimum of Six simple salts should be analysed) 50 M

Course outcomes:

At the end of the course, the student will be able to;

1. Understand the basic concepts of qualitative analysis of inorganic simple salt.

2. Use glassware, equipment and chemicals and follow experimental procedures in

the laboratory

3. Apply the concepts of common ion effect, solubility product and concepts related
to qualitative analysis

Laboratory course syllabus:

Analysis of SIMPLESALT 50 M

Analysis of simple salt containing ONE anion and ONE cation from the following:
Anions: Carbonate, Sulphate, Chloride, Bromide, Acetate, Nitrate, Borate,
Phosphate. Cations: Lead, Copper, Iron, Aluminium, Zinc, Nickel, Manganese,
Calcium, Strontium, Barium, Magnesium and Ammonium.

Co-curricular activities and Assessment Methods

1. Continuous Evaluation: Monitoring the progress of student’s learning.

2. Class Tests, Work sheets and Quizzes

3. Presentations, Projects and Assignments and Group Discussions:

Enhances critical thinking skills and personality

4. SEMESTER -End Examination: critical indicator of student’s learning

and teaching methods adopted by teachers throughout the SEMESTER

Reference books:

1. Vogel's Quanlitative Inorganic Analysis, Seventh edition, Pearson.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

II - SEMESTER

Course Code 4: INORGANIC CHEMISTRY- I

Credits: 03

Course outcomes:

At the end of the course, the student will be able to:

1. Understand the basic concepts of p-block elements.

2. Explain the concepts of d-block elements

3. Distinguish lanthanides and actinides.

4. Describe the importance of radioactivity.

Syllabus:

UNIT –I Chemistry of p-block elements – I 9 h

Group 13: Preparation & structure of Diborane, Borazine and

(BN)x Group14: Preparation, classification and uses of silicones
and Silanes. Group 15: Preparation & structure of Phosphonitrilic
Chloride P3N3Cl6

Unit II Chemistry of p-block elements – II 9 h

Group 16: Classification of Oxides, structures of oxides and Oxoacids of

Sulphur Group 17: Preparation and Structures of Interhalogen compounds.
Pseudohalogens,

UNIT-III Chemistry of d-block elements: 9 h

Characteristics of d-block elements with special reference to electronic configuration,

variable valence, colour, magnetic properties, catalytic properties and ability to form
complexes. Stability of various oxidation states of 3d series-Latimer diagrams.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

UNIT-IV Chemistry of f-block elements: 9 h

Chemistry of lanthanides - electronic configuration, oxidation states, lanthanide

contraction, consequences of lanthanide contraction, colour, magnetic properties.

Separation of lathanides by ion exchange method.

Chemistry of actinides - electronic configuration, oxidation states, actinide

contraction, comparison of lanthanides and actinides.

Unit – V Radioactivity 9 h

Definition, Isotopes, n/p ratio, binding energy, types of radioactivity, Soddy-Fajan’s

displacement law,Law of Radioactivity, Radioactive decay series, Nuclear Reactions-
fission and fusion, Applications of radioactivity.

List of Reference books:

1. Basic Inorganic Chemistry by Cotton and Wilkinson

2. Advance Inorganic chemistry vol-I by Satya Prakash

3. Inorganic chemistry by Puri and Sharma

4. Concise Inorganic Chemistry by J D Lee

5. Nuclear Chemistry by Maheshwar Sharon, 2009

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

II -SEMESTER

Course Code 4: INORGANIC CHEMISTRY- I

Credits: 01

Course outcomes:

At the end of the course, the student will be able to:

1. Understand the basic concepts of inorganic preparations.

2. Use glassware, equipment and chemicals and follow experimental

procedures in the laboratory

3. Apply the properties of various elements for the preparation of inorganic

compounds.
Syllabus:
Preparation of Inorganic compounds:

4. Crystallization of compounds and determination of melting point.

5. Preparation of Cuprous chloride.

6. Preparation of Potash Alum.

7. Preparation of Chrome Alum.

8. Preparation of Ferrous oxalate

9. Preparation of Ferrous ammonium sulphate.

Co-curricular activities and Assessment Methods

10. Continuous Evaluation: Monitoring the progress of student’s learning

11. Class Tests, Worksheets and Quizzes
12. Presentations, Projects and Assignments and Group Discussions:
Enhances critical thinking skills and personality
13. SEMESTER -End Examination: critical indicator of student’s learning
and teaching methods adopted by teachers throughout the
Reference books:

1. Vogel's Quanlitative Inorganic Analysis, Seventh edition, Pearson.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Single Major
Model Question Paper
SEMESTER-II
B.Sc Chemistry
Paper: 4- General & Inorganic Chemistry
Time:3hrs MAX MARKS: 70 M

SECTION-A
Answer any 5 questions. Each question carries 4 marks 5 x 4 = 20M
1. Explain Heisenberg uncertainty principle and Hund’s rule.
2. Write a note on stability of ionic compounds.
3. Explain structures of SF4, NH3 using VSEPR theory.
4. Write about inter and intra molecular hydrogen bond.
5. Write about protic and aprotic solvents.
6. Explain geometry of CH4 & SF6 using Valence Bond theory.
7. Explain significance of wave functions.
8. Define pH, pKa, pKb.

SECTION-B
Answer all the questions, Each question carries 10 marks. 5 x 10 = 50M
9. a. Write about (i) Bohr Theory. (ii) Paulis exclusion principle.
(or)
b. Explain general properties of atoms (i) atomic radii & ionic radii
(ii) ionization potential (iii) electronegativity.

10. a. What are properties of ionic compounds. Explain any three factors favouring the formation
of ionic compounds.
(or)
b. Write about (i) Born –Haber Cycle (ii) Fajan’s rules
11. a. Write advantage of MO theory over VBT. Construct the MO diagrams for O2 and CO
molecules.
(or)
b. Explain Valence bond theory and concept of hybridization by taking any two examples.
12. a. Write about Band theory of metals. Explain about conductors, semiconductors and insulators.
(or)
b. Explain free electron theory. Explain metallic properties.
13. a. Explain Bronsted Lowry theory and Lewis acid base theory.
(or)
b. Define Pearson’s concept. Explain HSAB Principle and its importance in bonding.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Single Major
Model Question Paper
SEMESTER-II
B.Sc Chemistry
Paper: 4- Inorganic Chemistry-I
Time:3hrs MAX MARKS: 70 M
SECTION-A
Answer any 5 questions. Each question carries 4 marks 5 x 4 = 20M
1. What are silicones. Write their classification.
2. What are Pseudohalogens. Give examples.
3. Write about variable valence of d-block elements
4. Write about magnetic properties of lanthanides.
5. Write note on isotopes and n/p ratio.
6. Explain the structure of borazine.
7. Compare Lanthanides and Actinides.
8. Write a note on oxoacids of sulphur.

SECTION-B
Answer ALL the questions, Each question carries 10 marks. 5 x 10 = 50M
9. a. Explain the preparation and Structure of diborane.
(or)
b. Explain the preparation and structure of phosphonitrilic chloride.

10. a. Explain classification of oxides. Draw structures of any two oxides of sulphur.
(or)
b. What are interhalogen compounds. Write their preparation. Explain structure of AX5 & AX7
interhalogen compounds.
11. a. Write the electronic configuration of 3d – series elements.
(or)
b. Explain Colour & catalytic properties of d-block elements.
12. a. What is Lanthanide Contraction. Explain the consequences of Lanthanide Contraction.
(or)
b. (i) Write about separation of lanthanides by ion exchange method.
(ii) Write about oxidation states exhibited by actinides.
13.a. Write an essay on Nuclear Fission and Nuclear Fusion reactions.
(or)
b. Write about (i) Soddy- Fajans law (ii) Applications of radioactivity.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

III -SEMESTER
Course Code 5: FUNDAMENTALS IN ORGANIC CHEMISTRY
Credits: 03

Course outcomes:

At the end of SEMESTER, the student will be able to

1. Understand and explain the differential behaviour of organic compounds based on

fundamental concepts learnt.

2. Formulate the mechanism of organic reactions by recalling and correlating the

fundamental properties of the reactants involved.

3. Learn and identify many organic reaction mechanisms .

4. Correlate and describe the stereo-chemical properties of organic compounds and

reactions.

Syllabus:

Unit 1. Structural theory in Organic Chemistry (9 h)

Types of bond fission and organic reagents (Electrophilic, Nucleophilic, and free radical
reagents). Reaction intermediates – Carbocations, carbanions & free radicals. Bond
polarization: Factors influencing the polarization of covalent bonds, inductive effect -
Application of inductive effect (a) Basicity of amines (b) Acidity of carboxylic acids (c)
Stability of carbonium ions. Resonance or Mesomeric effect, application to (a) acidity of
phenol, and (b) acidity of carboxylic acids. Hyper conjugation and its application to stability
of carbonium ions, Free radicals and alkenes.

Unit II Saturated Hydrocarbons (Alkanes and Cycloalkanes) 9 h

General methods of preparation of alkanes- Wurtz and Wurtz Fittig reaction, Corey House
synthesis, physical and chemical properties of alkanes, Conformational analysis of alkanes
(Conformations, relative stability and energy diagrams of Ethane, Propane and butane).

General molecular formulae of cycloalkanes and relative stability, Baeyer strain theory,
Cyclohexane conformations with energy diagram, Conformations of monosubstituted
cyclohexane.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

UNIT-III Unsaturated Hydrocarbons (Alkenes and Alkynes) 9 h

General methods of preparation, physical and chemical properties, Saytzeff and Hoffmann
eliminations (with mechanism), Electrophilic Additions, (H2, HX) mechanism
(Markownikoff/ Antimarkownikoff addition) with suitable examples-syn and anti-addition;
addition of X2, HX. Oxymercuration demercuration, ozonolysis, hydroxylation, Diels Alder
reaction, 1,2- and1,4-addition reactions in conjugated dienes. Reactions of alkynes; acidity,
electrophilic and nucleophilic additions, hydration to form carbonyl compounds, Alkylation
of terminal alkynes.

UNIT-IV Benzene and its reactivity (9 h )

Structure of Benzene – Preparation - polymerisation of acetylene and decarboxylation-
Properties -mechanism of electrophilic aromatic substitution of Friedel- Craft's alkylation and
acylation. halogenation and nitration,

UNIT-V Orientation of aromatic substitution (9 h )

Concept of aromaticity, Huckel's rule - application to Benzenoid (Benzene, Naphthalene) and

Non - Benzenoid compounds (cyclopropenylcation, cyclopentadienyl anion and tropylium
cation) Orientation of aromatic substitution - ortho, para and meta directing groups. Ring
activating and deactivating groups with examples (Electronic interpretation of various groups
like NO2 and Phenolic). Orientation of (i) Amino, methoxy and methyl groups (ii) Carboxy,
nitro, nitrile, carbonyl and sulphonic acid groups (iii) Halogens.

List of Reference Books

1. Morrison, R. N. & Boyd, R. N. Organic Chemistry, Dorling Kindersley (India) Pvt. Ltd.

(PearsonEducation).

2. Finar, I. L. Organic Chemistry (Volume 1), Dorling Kindersley (India) Pvt. Ltd. (Pearson

Education).

3. Guide book to Mechanism in Organic Chemistry by Peter Sykes 6th edition,1985.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

III -SEMESTER
Course Code 5: Fundamentals in Organic Chemistry - Organic Qualitative Analysis

Credits: 01

Organic Qualitative analysis

Course outcomes:

At the end of the course, the student will be able to;

1. Use glassware, equipment and chemicals and follow experimental procedures in the
laboratory

2. Determine melting and boiling points of organic compounds

3. Understand the application of concepts of different organic reactions studied in theory part
of organic chemistry

Syllabus:

Analysis of an organic compound through systematic qualitative procedure for functional

group identification including the determination of melting point and boiling point with
suitable derivatives. Alcohols, Phenols, Aldehydes, Ketones, Carboxylic acids, Aromatic
primary amines, amides and simple sugars.

Co-curricular activities and Assessment Methods

1. Continuous Evaluation: Monitoring the progress of student’s learning

2. Class Tests, Worksheets and Quizzes

3. Presentations, Projects and Assignments and Group Discussions:

Enhances critical thinking skills and personality

4. SEMESTER -End Examination: critical indicator of student’s learning and

teaching methods adopted by teachers throughout the SEMESTER .
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Reference books:

1) Vogel A.I .Practical Organic Chemistry, Longman Group Ltd.

2) Bansal R.K. Laboratory Manual of Organic Chemistry, Wiley-Eastern.

3) Ahluwalia V. K. and Agarwal R. Comprehensive Practical Organic Chemistry,

University press.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

III -SEMESTER

Course Code 6: ORGANIC CHEMISTRY

(Halogen and Oxygen containing organic compounds)

Credits: 03

Course outcomes:

At the end of the course, the student will be able to:

1. Understand the concept of SN1and SN2and SNi mechanisms.

2. Describe the reactivity of alcohols and phenols.

3. Achieve the skills required to propose various mechanisms

4. Apply the concepts for synthesising various oxygen containing organic

compounds

5. Interconvert the monosaccharides.

Syllabus:

Unit – I Halogen compounds ( 9 h)

Alkyl halides: Preparation of alkyl halides from i) alkanes, ii) alkenes and iii) alcohols.
Properties - nucleophilic substitution reactions–SN1and SN2 and SNi mechanisms with energy
profile diagrams, stereo chemical aspects and effect of solvent. Williamson’s synthesis.

Aryl halides: Preparation i) from phenols ii) Sandmeyer’s reaction, nucleophilic aromatic
substitution (Benzyne mechanism);relative reactivity of alkyl, allyl, vinyl and benzyl, aryl
halides towards nucleophilic substitution reactions.

Unit II Alcohols and Phenols (9h)

Alcohols: Preparation of 10,20,30alcohols from Grignard’s reagent, Bouveault–Blanc

Reduction; Chemical properties – substitution of –OH by using PCl5, PCl3, PBr3, SOCl2 and
with HX / ZnCl2, Oxidation of alcohols with PCC, PDC; Oxidation of diols by HIO4 and
Pb(OAc)4, Pinacol Pinacolone arrangement with mechanism, relative reactivity of 1°, 2°,
3°alcohols.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Phenols :Preparation from diazonium salt and Cumene. Reactions and mechanism–Reimer–
Tiemann,Kolbe–Schmitt Reactions, Fries and Claisen rearrangements.

Unit III Carbonyl Compounds (9h)

Preparation from-Acid chlorides,1,3-dithiane and nitriles; Structure and reactivity of carbonyl

group, Nucleophilic addition reactions with HCN, NaHSO 3 and alcohols. addition-

elimination reactions with hydroxylamine, hydrazine, phenyl hydrazine, 2,4DNP,

semicarbazide. Oxidations and reductions (Clemmensen’s, Wolf–Kishner’s, withLiAlH4 &
NaBH4).

Reaction & Mechanism- Aldol condensation, Cannizzaro reaction, Perkin reaction, Benzoin
condensation, Claisen-Schmidt reaction, Haloform reaction

Unit-IV Carboxylic acid and Active methylene Compounds (9h )

Carboxylic Acids: Preparation from Grignard reagent and hydrolysis of nitriles, Reactions of
monocarboxylic acids- Reactions involving -H, -OH and-COOHgroups, formation of salts,
esters, acidchlorides, amides and anhydrides. Degradation of carboxylic acids by Huns-
Diecker’s reaction, decarboxylation by Schmidt reaction, Arndt-Eistert synthesis,
halogenation by Hell- Volhard- Zelinsky reaction. Mechanisms of acidic and alkaline
hydrolysis of esters, Reformatsky reactions, Curtius rearrangement.
Active methylene compounds: Ketoenol tautomerism, preparation of Aceto Acetic
Ester(AAE) by Claisen condensation with mechanism,synthetic applications of AAE in the
preparation of mono carboxylic acids, di carboxylic acids, α,β-unsaturated acids and
heterocyclic compounds.
Unit V : Carbohydrates ( 9 h )

Classification and their biological importance, Monosaccharides: Structural elucidation of

glucose and fructose, epimers and anomers, mutarotation, determination of ring size of
glucose and fructose, Haworth projections and conformational structures; Interconversions of
aldoses and ketoses; Killiani-Fischer synthesis and Ruff degradation; Disaccharides–
Haworth structure of maltose, lactose and sucrose.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

II. List of Reference Books

1) 1.Morrison, R. N. & Boyd, R. N. Organic Chemistry, Dorling Kindersley (India) Pvt.

Ltd. (PearsonEducation).

2) 2.Finar, I. L. Organic Chemistry (Volume 1), Dorling Kindersley (India) Pvt. Ltd.
(Pearson Education).

3) Guide book to Mechanism in Organic Chemistry by Peter Sykes 6th edition,1985.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

III - SEMESTER

Course Code 6: Organic Chemistry - Organic Preparations (P)

Credits: 01

Course outcomes:

On the completion of the course, the student will b eable to do the following:

1. How to use glassware, equipment and chemicals and follow

experimental procedures in the laboratory.

2. How to calculate limiting reagent, theoretical yield, and percent yield.

3. How to perform common laboratory techniques including reflux, distillation,

recrystallization, vacuum filtration.

4. How to critically evaluate data collected to determine the identity, purity and
percent yield of products and to summarize findings in writing in a clear and
concise manner.

Syllabus - Organic preparations (50M)

i. Acetylation of β-naphthol, vanillin and salicylic acid by:

a) Using conventional method.

b) Using green approach

ii. Preparation of Nerolin

Co-curricular activities and Assessment Methods;

1. Continuous Evaluation: Monitoring the progress of student’s learning

2. Class Tests, Worksheets and Quizzes

3. Presentations, Projects and Assignments and Group Discussions:

Enhances critical thinking skills and personality

4. SEMESTER -End Examination: critical indicator of student’s learning and

teaching methods adopted by teachers throughout the SEMESTER .
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Reference books:

1. Vogel A.I .Practical Organic Chemistry, Longman Group Ltd.

2. Bansal R.K. Laboratory Manual of Organic Chemistry, Wiley-Eastern.

3. Ahluwalia V. K. and Agarwal R. Comprehensive Practical Organic Chemistry,

University press.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

III - SEMESTER

Course Code 7: PHYSICAL CHEMISTRY - I

(Solutions & Electro Chemistry)

Credits: 03

Course outcomes:

At the end of the SEMESTER the student will be able to

1. Understand the ideal and non ideal behaviour of solutions.

2. Determine the molecular mass of non-volatile solutes.

3. Discuss the basic concepts of Photochemistry.

4. Apply the principles of electrical conductivity.

5. Explain the importance of emf and its applications.

Syllabus:

Unit I Solutions ( 9h)

Classification - Miscible, Partially miscible and Immiscible - Raoult’s Law - Azeotropes-

HCl-H2O system and ethanol-water system. Partially miscible liquids-phenol- water system.
Critical solution temperature (CST), Effect of impurity on consulate temperature. Immiscible
liquids and steam distillation. Nernst distribution law. Calculation of the partition coefficient.
Applications of distribution law.

Unit II Colligative Properties (9h)

Relative lowering of Vapour Pressure, Elevation in boing point depression in freezing point
and Osmotic pressure. Determination of molecular mass of non-volatile solute by Ostwald-
Walker method, Cottrell’s method, Rast method and Barkeley-Hartley method.

Abnormal colligative properties. Van't Hoff factor.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit III – Photochemistry ( 9h )

Difference between thermal and photochemical processes, Laws of photochemistry-

Grothus- Draper's law and Stark-Einstein's law of photochemical equivalence, Quantum

yield- Photochemical reaction mechanism- hydrogen- chlorine and hydrogen- bromine

reaction. Qualitative description of fluorescence, phosphorescence, Jablonski diagram,
chemiluminescence - Photosensitized reactions- energy transfer processes (simple example),
quenching, Photo stationary state.

Unit IV Electrochemistry-I ( 9 h )

Conductance, Specific conductance, equivalent conductance and molar conductance - effect

of dilution. Cell constant. Strong and weak electrolytes, Kohlrausch's law and its applications,

Definition of transport number, determination of transport number by Hittorf’s method.

Debye-Huckel - Onsagar's equation for strong electrolytes (derivation excluded), Application
of conductivity measurements- conductometric titrations.

Unit V Electrochemistry-II ( 9 h )

Electrochemical Cells- Single electrode potential, Types of electrodes with examples: Metal-
metal ion, Gas electrode, Inert electrode, Redox electrode, Metal-metal insoluble salt- salt
anion. Determination of EMF of a cell, Nernst equation, Applications of EMF measurements

-Potentiometric titrations. Fuelcells – Basic concepts, examples and applications.

List of Reference books:

1) Principles of physical chemistry by Prutton and Marron

2) Solid State Chemistry and its applications by Anthony R. West

3) Text book of physical chemistry by K L Kapoor

4) Text book of physical chemistry by S Glasstone

5) Advanced physical chemistry by Bahl and Tuli

6) Advanced physical chemistry by Gurudeep Raj

7) Principles of physical chemistry by Puri, Sharma and Pathania.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

III - SEMESTER

Course Code 7: PHYSICAL CHEMISTRY -I

Credits: 01

Course outcomes:
At the end of the course, the student will be able to:
1. Use of glassware, equipment and chemicals and follow experimental procedures in the
laboratory.

2. Understand and apply the concepts of solutions practically.

3. Apply concepts of electrochemistry in experiments.

Syllabus:
CST, Conductometric and Potentiometric Titrimetry 50 M
1. Determination of CST for Phenol-water system.

2. Effect of electrolyte on CST.

3. Conductometric titration - Determination of concentration of HCl solution using

standard NaOH solution.

4. Conductometric titration – Determination of concentration of CH3COOH

Solution using standard NaOH solution.

5. Potentiometric titration-Determination of concentration of HCl using standard

NaOH solution.

II. Co-curricular activities and Assessment Methods;

1) Continuous Evaluation: Monitoring the progress of student’s learning

2) Class Tests, Worksheets and Quizzes

3) Presentations, Projects and Assignments and Group Discussions: Enhances

critical thinking skills and personality

4) SEMESTER -End Examination: critical indicator of student’s learning and teaching

methods adopted by teachers throughout the SEMESTER .

III. List of reference books:

1) A Text Book of Quantitative Inorganic Analysis(3rdEdition) –A.I.Vogel

2) Web related references suggested by teacher.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

III - SEMESTER

COURSE CODE 8: INORGANIC AND PHYSICAL CHEMISTRY

Credits: 03

I. Course outcomes:

At the end of the SEMESTER the student will be able to:

1) Apply IUPAC nomenclature for Coordination compounds

2) Understand the various theories, structure and stereo chemistry of coordination

compounds.

3) Explain the reaction mechanism in complexes.

4) Apply the 18 electron rule.

5) Discuss the basic concepts of thermodynamics.

Syllabus;

Unit I Coordination Chemistry-I ( 9 h )

IUPAC nomenclature of Coordination compounds, structural and stereo isomerism in

complexes with coordination numbers 4 and 6. Valence Bond Theory(VBT):Postulates-
magnetic properties- Inner and outer orbital complexes. Limitations of VBT, CFT- Postulates

- Splitting in Octahedral, tetrahedral, tetragonal and square planar fields. Crystal field
stabilization energy(CFSE), Crystal field effects for weak and strong fields. Factors affecting
the magnitude of crystal field splitting energy, Spectro chemical series, Tetragonal distortion
of octahedral geometry, Jahn-Teller distortion.

UNIT–II Coordination Chemistry II ( 9 h )

1. Inorganic molecular Reaction Mechanism: ( 6 h)

Introduction to inorganic reaction mechanisms. Concept of reaction pathways, transition

state, intermediate and activated complex. Labile and inert complexes, ligand substitution
reactions – SN1 and SN2,Substitution reactions in square planar complexes, Trans-effect,
theories of trans effect and its applications
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

2. Stability of metal complexes: ( 3 h)

Thermodynamic stability and kinetic stability, factors affecting the stability of metal
complexes, chelate effect, determination of composition of complex by Job's method and
mole ratio method.
Unit III Organo metallic compounds ( 9 h)

Definition and classification of organo metallic Compounds on the basis of bond type,
Metalcarbonyls:18electron rule, electron count of mononuclear, poly nuclear and substituted
metal carbonyls of 3d series. General methods of preparation of mono and binuclear
carbonyls of 3d series. π-acceptor behaviour of CO (MO diagram of CO to be discussed),
synergic effect and use of IR data to explain extent of back bonding.

Unit IV Thermodynamics- I ( 9 h )

Concept of heat(q), work(w), internal energy(U), State function and Path function- statement
of first law; enthalpy(H), relation between heat capacities, calculations of q, w, U and H for
reversible, irreversible processes, Joule-Thomson effect- coefficient, Calculation of work for
the expansion of perfect gas under isothermal and adiabatic conditions for reversible
processes. Temperature dependence of enthalpy of formation- Kirchoff’s equation.

Unit V Thermodynamics II (9h)

Second law of thermodynamics Different Statements of the law, Carnot cycle and its
efficiency, Carnot theorem, Concept of entropy, entropy as a state function, entropy changes
in reversible and irreversible processes. Entropy changes in spontaneous and equilibrium
processes. Third law of thermodynamics, Nernst heat theorem, Spontaneous and non-
spontaneous processes, Helmholtz and Gibbs equation - Criteria for spontaneity.

II. List of Reference Books:

1) Concise coordination chemistry by Gopalan and Ramalingam

2) Coordination Chemistry by Basalo and Johnson
3) Text book of physical chemistry by S Glasstone
4) Concise Inorganic Chemistry by J.D.Lee
5) Advanced Inorganic Chemistry Vol-I by Satyaprakash, Tuli, Basu and Madan
6) A Text Book of Physical Chemistry by K.L.Kapoor Vol 2, 6th edition, 2019.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

III - SEMESTER

COURSE CODE 8: INORGANIC AND PHYSICAL CHEMISTRY - QUALITATIVE

INORGANIC ANALYSIS

Credits: 01

( Minimum of Six mixtures should be analyzed)

Course outcomes:

At the end of the course, the student will be able to:

1) Understand the basic concepts of qualitative analysis of inorganic mixture.

2) Use glassware, equipment and chemicals and follow experimental procedures in the
laboratory.

3) Apply the concepts of common ion effect, solubility product and concepts related to
qualitative analysis.

Analysis of Mixture 50M

Analysis of mixture salt containing two anions and two cations (From two different groups)
from the following:

Anions: Carbonate, Sulphate, Chloride, Bromide, Acetate, Nitrate, Borate, Phosphate.

Cations: Lead, Copper, Iron, Aluminium, Zinc, Nickel, Manganese, Calcium, Strontium,
Barium, magnesium and Ammonium.

Minimum of Six mixtures should be analyzed.

Co-curricular activities and Assessment Methods

1) Continuous Evaluation: Monitoring the progress of student’s learning

2) Class Tests, Worksheets and Quizzes

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

3) Presentations, Projects and Assignments and Group Discussions: Enhances

critical thinking skills and personality

4) SEMESTER - End Examination: critical indicator of student’s learning and teaching

methods adopted by teachers throughout the SEMESTER.

List of Text books:

1. A textbook of qualitative inorganic analysis by A.I. Vogel.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

IV - SEMESTER

COURSE CODE 9: PHYSICAL CHEMISTRY -II

(States of Matter, Phase Rule & Surface Chemistry)

Credits: 03

I. Course outcomes:

At the end of the SEMESTER the student will be able to:

1. Explain the difference between solids liquids and gases in terms of intermolecular
interactions.

2. Differentiate ideal and real gases.

3. Discuss the basic concepts of two component systems

4. Apply the concepts of adsorption.

5. Understand the basic concepts of crystallography.

II. Syllabus:

Unit I - Gaseous state (9 h )

Postulates of Kinetic theory of Gases (exclude derivation) – deduction of gas laws from
kinetic gas equation-Vander Waal’s equation of state. Andrew’s isotherms of carbon dioxide,
continuity of state. Critical phenomena. Relationship between critical constants and vander
Waal’s constants. Law of corresponding states. Joule- Thomson effect. Inversion
temperature.

Unit II – Liquid State ( 9 h )

Physical properties of liquids; vapour pressure, surface tension and coefficient of viscosity,
and their determination. Effect of addition of various solutes on surface tension and viscosity.
Temperature variation of viscosity of liquids and comparison with that of gases. Qualitative
discussion of structure of water.

Liquid crystals, mesomorphic state. Differences between liquid crystal and solid/liquid.
Classification of liquid crystals into Smectic and Nematic. Application of liquid crystals as
LCD devices
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

UNIT-III - Solid state ( 9h )

Symmetry in crystals. Law of constancy of interfacial angles. The law of rationality of

indices. Miller indices, Definition of lattice point, space lattice, unit cell. Bravais lattices and
crystal systems. X-ray diffraction and crystal structure. Bragg’s law and its derivation.
Powder method. Defects in crystals. Stoichiometric and non-stoichiometric defects.

Unit IV - Phase Rule ( 9 h )

The Concept of phase, components, degrees of freedom. Gibbs phase rule. Phase diagram of
one component system – water system, Study of Phase diagrams of Simple eutectic systems

i) Pb-Ag system, desilverisation of lead ii) NaCl-Water system, Congruent and incongruent
melting point- Definition and examples for systems having congruent and incongruent
melting point, freezing mixtures

Unit V Surface Chemistry ( 9 h )

Definition and classification of Colloids- Coagulation of colloids- Hardy-Schulze rule.

Stability of colloids, Protection of Colloids, Gold number.

Adsorption - Physical and chemical adsorption, Freundlich and Langmuir adsorption

isotherm, applications of adsorption.

III. List of Reference Books:

1) Solid State Chemistry and its applications by Anthony R. West

2) Text book of physical chemistry by K L Kapoor Vol.1

3) Text book of physical chemistry by S Glasstone

4) Advanced physical chemistry by Bahl and Tuli.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

IV - SEMESTER

Course Code 9: Organic Preparations

Credits: 01

Course outcomes:

At the end of the course, the student will be able to:

1) Use glassware, equipment and chemicals and follow experimental procedures in the
laboratory

2) Apply concepts of surface chemistry in experiments.

3) Be familiar with the concepts & practical applications of Surface tension and viscosity
of liquids.

Physical Chemistry Practical Syllabus:

1. Determination of surface tension of liquid by drop count method

2. Determination of surface tension of liquid by drop weight method

3. Determination of surface tension of mixture (liquid + detergent) using stalagmometer.

4. Determination of coefficient of viscosity of an organic liquid.

5. Determination of composition of a glycerol in glycerol + water mixture using

viscometer.

6. Adsorption of acetic acid on animal charcoal, verification of Freundlich isotherm.

Co-curricular activities and Assessment Methods:

1) Continuous Evaluation: Monitoring the progress of student’s learning

2) Class Tests, Worksheets and Quizzes

3) Presentations, Projects and Assignments and Group Discussions: Enhances

critical thinking skills and personality

4) SEMESTER -End Examination: critical indicator of student’s learning and teaching

methods adopted by teachers throughout the SEMESTER .
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

List of reference books:

1) A Text Book of Quantitative Inorganic Analysis(3rdEdition) –A.I.Vogel

2) Web related references suggested by teacher.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

IV - SEMESTER

Course Code 10: GENERAL AND PHYSICAL CHEMISTRY

Credits: 03

I. Course outcomes:

At the end of the SEMESTER the student will be able to:

1. Correlate and describe the stereochemical properties of organic compounds.

2. Explain the biological significance of various elements present in the human body.

3. Apply the concepts of ionic equilibrium for the qualitative and quantitative analysis.

4. Determine the order of a chemical reaction.

5. Describe the basic concepts of enzyme catalysis.

II. Syllabus:

UNIT-I Stereo chemistry of carbon compounds ( 9 h )

Molecular representations - Wedge, Fischer, Newman and Saw-Horse formulae.

Optical isomerism: Optical activity- wave nature of light, plane polarised light, optical
rotation and specific rotation. Chiral molecules- definition and criteria (Symmetry elements)-
Definition of enantiomers and diastereomers – Explanation of optical isomerism with
examples- Glyceraldehyde, Lactic acid, Alanine, Tartaric acid, 2,3-dibromopentane.

Unit II Bioinorganic Chemistry ( 9 h )

Metal ions present in biological systems, classification of elements according to their action
in biological system. Geochemical effect on the distribution of metals, Na / K- pump,
carbonic anhydrase and carboxy peptidase. Excess and deficiency of some trace metals.
Toxicity of metal ions (Hg, Pb, Cd and As), reasons for toxicity, Use of chelating agents in
medicine, Cisplatin as an anti-cancer drug. Iron and its application in bio-systems,
Haemoglobin-transfer of oxygen, Myoglobin-Storage and transfer of iron
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit III Ionic equilibrium ( 9 h )

Strong, moderate and weak electrolytes, degree of ionization, factors affecting degree of
ionization, ionization constant and ionic product of water. Ionization of weak acids and
bases, pH scale, Buffer solutions-Henderson’s equation. Indicators-theories of acid – base
Indicators, selection of Indicators,

Common ion effect Solubility and solubility product of sparingly soluble salts – applications
of solubility product principle.

Unit IV Chemical Kinetics-I: ( 9 h )

The concept of reaction rates. Effect of temperature, pressure, catalyst and other factors on
reaction rates. Order and molecularity of a reaction, Derivation of integrated rate equations
for zero, first and second order reactions (similar and different reactants). Half–life of a
reaction. General methods for determination of order of a reaction.

Unit V Chemical Kinetics-II: ( 9 h 0

Concept of activation energy and its calculation from Arrhenius equation. Theories of
Reaction Rates: Collision theory and Activated Complex theory of bimolecular reactions.
Comparison of the two theories (qualitative treatment only).

Enzyme catalysis- Specificity, factors affecting enzyme catalysis, Inhibitors and Lock & key
model. Michaels- Menten equation- derivation, significance of Michaelis-Menten constant.

III. Reference books

1) Text book of physical chemistry by S Glasstone

2) Concise Inorganic Chemistry by J.D.Lee

3) Advanced physical chemistry by Gurudeep Raj

4) Advanced physical chemistry by Bahl and Tuli

5) Inorganic Chemistry by J.E.Huheey

6) Basic Inorganic Chemistry by Cotton and Wilkinson.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

IV - SEMESTER

Course Code 10: Physical Chemistry - Volumetric Analysis

Credits: 01

Physical Chemistry - Volumetric Analysis

IV. Course outcomes:

At the end of the course, the student will be able to;

1. Use glassware, equipment and chemicals and follow experimental procedures in the
laboratory

2. Understand and explain the volumetric analysis based on fundamental concepts learnt in
ionic equilibria

3. Learn and identify the concepts of a standard solutions, primary and secondary standards

4. Facilitate the learner to make solutions of various molar concentrations.

V. Syllabus:
Volumetric analysis:

1. Estimation of sodium hydroxide using standardised HCl solution.

2. Estimation of sodium carbonate and sodium hydroxide present in a mixture.

3. Determination of Fe (II) using KMnO4 with oxalic acid as primary standard. (internal
indicator method)

4. Determination of Fe (II) using KmnO4 with oxalic acid as primary standard. (external
indicator method)

5. Estimation of water of crystallization in Mohr’s salt by titrating with KmnO4

VI. Co-curricular activities and assessment methods :

1. Continuous Evaluation: Monitoring the progress of student’s learning

2. Class Tests, Worksheets and Quizzes

3. Presentations, Projects and Assignments and Group Discussions:

Enhances critical thinking skills and personality

4. SEMESTER -End Examination: critical indicator of student’s learning and

teaching methods adopted by teachers throughout the SEMESTER .
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VII. List of reference books:

1. A Text Book of Quantitative Inorganic Analysis(3rdEdition) –A.I.Vogel

2. Web related references suggested by teacher.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

IV - SEMESTER

Course Code 11: Nitrogen containing Organic Compounds & Spectroscopy

Credits: 03

Nitrogen containing Organic Compounds & Spectroscopy

I. Course outcomes:

At the end of the SEMESTER the student will be able to:

1. Distinguish primary secondary and teritiary amines and their properties.

2. Describe the preparation and properties of amino acids.

3. Explain the reactivity of nitro hydrocarbons.

4. Discuss heterocyclic compounds with N, O and S.

5. Apply the concepts of UV and IR to ascertain the functional group in an organic

compound.

II. Syllabus:
Unit I Amines: ( 9 h )
Classification, chirality in amines (pyramidal inversion), preparations – Gabriel synthesis,
Hoffmann- Bromamide reaction ( with mechanism), reduction of amides and Schmidt
reaction. Distinction between Primary, secondary and tertiary amines using Hinsberg’s
method and nitrous acid. Discussion of the following reactions with emphasis on the
mechanistic pathway: Carbylamine reaction, Hoffmann’s exhaustive methylation, Hofmann
and Cope elimination.
Diazonium Salts: Preparation and synthetic applications of diazonium salts including
preparation of arenes, haloarenes, phenols, cyano and nitro compounds. Coupling reactions of
diazonium salts (preparation of azo dyes).

UNIT- II Amino acids ( 9 h )

Definition and classification of Amino acids into alpha, beta, and gamma amino acids.
Natural and essential amino acids - definition and examples, classification of alpha amino
acids into acidic, basic and neutral amino acids with examples. Methods of synthesis: a) from
halogenated carboxylic acid, b) Gabriel Phthalimide synthesis c) Strecker's synthesis.
Physical properties: Zwitter ion structure - salt like character - solubility, melting points,
amphoteric character, definition of isoelectric point. Chemical properties: General reactions
due to amino and carboxyl groups - lactams from gamma and delta amino acids by heating-
peptide bond (amide linkage). Structure and nomenclature of peptides and proteins.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

UNIT- III Nitro hydrocarbons ( 9h )

Nomenclature and classification, structure -Tautomerism of nitroalkanes leading to acid and

keto form, Preparation of Nitroalkanes, reactivity - halogenation, reaction with HONO
(Nitrous acid), Nef reaction and Mannich reaction leading to Micheal addition and reduction.

Unit IV Heterocyclic Compounds ( 9 h )

Introduction and definition: Simple five membered ring compounds with one hetero atom Ex.
Furan, Thiophene and Pyrrole - Aromatic character – Preparation from 1, 4, -dicarbonyl
compounds, Paul-Knorr synthesis. Properties: Acidic character of pyrrole - electrophillic
substitution at 2 or 5 position, Halogenation, Nitration and Sulphonation - Diels Alder
reaction in furan. Pyridine – synthesis - Aromaticity -Basicity - Comparison with pyrrole- one
method of preparation and properties - Reactivity towards Nucleophilic substitution reaction.

Unit V UV-Visible & IR Spectroscopy ( 9 h )

Selection rules for electronic spectra, types of electronic transitions in molecules, concept of
chromophore and auxochrome, effect of conjugation- Woodward Fischer rules for calculating

max of conjugated dienes and , unsaturated compounds. Infrared spectroscopy and types
of molecular vibrations and fingerprint region. IR spectra of alkanes, alkenes and simple
alcohols (inter and intra molecular hydrogen bonding), aldehydes, ketones, carboxylic acids
and their derivatives (effect of substitution on >C=O stretching absorptions).

III. List of Reference Books

1) A Text Book of Organic Chemistry by Bahl and Arunbahl

2) A Text Book of Organic chemistry by I L FinarVol I
3) Organic chemistry by Bruice
4) Organic chemistry by Clayden
5) Spectroscopy by William Kemp
6) Spectroscopy by Pavia
7) Organic Spectroscopy by J. R. Dyer
8) Elementary organic spectroscopy by Y.R. Sharma
9) Spectroscopy by P.S.Kalsi
10) Spectrometric Identification of Organic Compounds by Robert M
Silverstein, Francis X Webster
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

IV - SEMESTER

Course Code 11: Organic preparations and IR Spectral Analysis

Credits: 01

Organic preparations and IR Spectral Analysis

Course outcomes:

On completion of the course, the student will be able to:

11) Use glassware, equipment and chemicals and follow experimental procedures in the
laboratory

12) Calculate limiting reagent, theoretical yield, and percent yield

13) Engage in safe laboratory practices by handling laboratory glassware, equipment, and
chemical reagents appropriately

14) Dispose of chemicals in a safe and responsible manner

15) Perform common laboratory techniques including reflux, distillation, recrystallization,

vacuum filtration.

16) Create and carry out work up and separation procedures.

Syllabus:

A. Organic preparations: 40M

1) Acetylation of one of the following compounds: amines (aniline, o-, m-, ptoluidines
and o-, m-, p-anisidine)

a. Using conventional method.

b. Using green approach

2) Benzoylation of one of the following amines (aniline, o-, m-, p- toluidines and o-, m-,
p-anisidine)

3) Nitration of any one of the following:

Acetanilide/nitrobenzene by conventional method

B. IR Spectral Analysis 10M

IR Spectral Analysis of the following functional groups with examples a) Hydroxyl groups b)
Carbonyl groups c) Amino groups d) Aromatic groups
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Co-curricular activities and assessment methods:

1. Continuous Evaluation: Monitoring the progress of student’s learning

2. Class Tests, Worksheets and Quizzes

3. Presentations, Projects and Assignments and Group Discussions:

Enhances critical thinking skills and personality

4. SEMESTER -End Examination: critical indicator of student’s learning and

teaching methods adopted by teachers throughout the SEMESTER .

List of reference books:

1. Vogel A.I .Practical Organic Chemistry, Longman Group Ltd.

2. Bansal R.K. Laboratory Manual of Organic Chemistry, Wiley-Eastern.

3. Ahluwalia V. K. and Agarwal R. Comprehensive Practical Organic Chemistry,

University press.

4. Web related references suggested by teacher.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V- SEMESTER

Course Code 12 A: ANALYTICAL METHODS IN CHEMISTRY-

QUANTITATIVE ANALYSIS

Credits: 03

ANALYTICAL METHODS IN CHEMISTRY- QUANTITATIVE ANALYSIS

SKILL ENHANCEMENT COURSE (ELECTIVE)

I. Learning Outcomes:

Students after successful completion of the course will be able to:

1) Identify the importance of solvent extraction and ion exchange method.

2) Acquire knowledge on the basic principles of volumetric analysis and gravimetric

analysis.

3) Demonstrate the usage of common laboratory apparatus used in quantitative analysis.

4) Understand the theories of different types of titrations.

5) Gain knowledge on different types of errors and the minimization methods.

II. Syllabus:

Unit-1: Quantitative analysis-1 (9 hours)

A brief introduction to analytical methods in chemistry. Principles of volumetric analysis,

concentration terms- Molarity, Molality, Normality,v/v, w/v, ppm and ppb, preparing
solutions- Standard solution, primary standards and secondary standards.. Description and
use of common laboratory apparatus- volumetric flask, burette, pipette, beakers, measuring
cylinders.

Unit-2: Quantitative analysis-2 (9 hours)

Principles of volumetric analysis: Theories of acid-base (including study of acid-base titration

curves), redox, complex metric, iodometric and precipitation titrations-choice of indicators
for the saturations. Principles of gravimetric analysis: precipitation, coagulation, peptization,
coprecipitation, post precipitation, digestion, filtration, and washing of precipitate, drying and
ignition.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit-3: Treatment of analytical data (9 hours)

Types of errors- Relative and absolute, significant figures and its importance, accuracy -
methods of expressing accuracy, errors- Determinate and indeterminate and minimization of
errors, precision-methods of expressing precision, standard deviation and confidence interval.

Unit-4: Separation techniques (9hours)

Solvent Extraction: Introduction, principle, techniques, factors affecting solvent extraction,

Batch extraction, Continuous extraction and counter current extraction. Synergism.

Application-Determination of Iron(III). Ion Exchange method: Introduction, action of ion

exchange resins, applications.

UNIT-5: Analysis of water ( 9 hours)

Determination of dissolved solids, total hardness of water, turbidity, alkalinity, Dissolved

oxygen, COD, determination of chloride using Mohr’s method.

III. Suggested Co-Curricular Activities:

1) Training of students by related industrial experts.

2) Assignments, Seminars and Quiz(on related topics).

3) Visits to laboratories, firms, research organizations etc.

4) Invited lectures and presentations on related topics by field/industrial experts.

IV. List of Reference Books:

1) Fundamentals of Analytical Chemistry by F.James Holler, Stanley R Crouch,

DonaldM.West and Douglas A. Skoog, Ninth edition, Cengage.

2) Analytical Chemistry by Gary D.Christian, Purnendu K.Dasgupta and KevinA.

Schug, Seventh edition, Wiley.

3) Quantitative analysis by R.A.DayJr.and A.L.Underwood, Sixth edition, Pearson.

4) Text book of Vogel's Quantitative Chemical Analysis,Sixth edition, Pearson.

5) Text book of Environmental Chemistry and Pollution Control by S.S.Dara and

D.D.Mishra, Revised edition, S Chand & Co Ltd.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V- SEMESTER

Course Code 12 A: Analytical Methods in Chemistry – Quantitative analysis:

Credits: 01

Analytical Methods in Chemistry – Quantitative analysis:

V. Learning Outcomes:

On successful completion of this practical course, student shall be able to:

1) Estimate Iron(II )using standard Potassium dichromate solution

2) Learn the procedure for the estimation of total hardness of water

3) Demonstrate the determination of chloride using Mohr’s method

4) Acquire skills in the operation and calibration of pH meter

5) Perform the strong acid vs strong base titration using pH meter

VI. Laboratory course Syllabus:

1) Estimation of Iron(II)using standard Potassium dichromate solution (using DPA

indicator)

2) Estimation of total hardness of water using EDTA

3) Determination of chloride ion by Mohr’s method

4) Study the effect on pH of addition of HCl/NaOH to solutions of acetic acid, sodium

acetate and their mixtures.

5) Preparation of buffer solutions of different pH (i) Sodium acetate-acetic acid, (ii)

Ammonium chloride-ammonium hydroxide.

6) pH metric titration of (i) strong acid vs strong base,(ii)weak acid vs. Strong base.

7) Determination of dissociation constant of a weak acid.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VII. Co-Curricular Activities:

Mandatory:(Lab /field training of students by teacher:(lab:10+field:05):

1) For Teacher: Training of students by the teacher in laboratory and field for not less
than 15 hours on the field techniques / skills of calibration of pH meter, Strong acid vs
strong base titration using pH meter, determination of chloride ion, estimation of
water quality parameters and estimation of Iron(II).

2) For Student: Student shall visit a related industry / chemistry laboratory in

universities / research organizations/private sector facility and observe various
methods used for the analysis of water. Write their observations and submit a hand
written fieldwork /project work report not exceeding10pages in the given format to
the teacher.

3) Max marks for Field work / projectwork Report:05.

4) Suggested Format for Fieldwork/project work: Title page, student details, index page,
details of place visited, observations, findings and acknowledgements.

5) Unit tests (IE).

VIII. List of Reference books:

Text book of Vogel's Quantitative Chemical Analysis, Sixth edition, Pearson.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V- SEMESTER

Course 12 B : Environmental Chemistry

Credits: 03

Learning Outcomes:

Students after successful completion of the course will be able to:

1) Understand the environment functions and how it is affected by human activities.

2) Acquire chemical knowledge to ensure sustainable use of the world's resources and

3) ecosystems services.

4) Engage in simple and advanced analytical tools used to measure the different types of
pollution.

5) Explain the energy crisis and different aspects of sustainability.

6) Analyze key ethical challenges concerning biodiversity and understand the moral
principles, goals

7) and virtues important for guiding decisions that affect Earth’s plant and animal life.

II Syllabus

UNIT-I Environmental chemistry 9h

Definition – Concept of Environmental chemistry-Scope and importance of environment in

now a days – Nomenclature of environmental chemistry – Segments of environment–Effects
of human activities on environment – Natural resources–Renewable Resources–Solar and
Biomass Energy and Nonrenewable resources – Thermal power and atomic energy –
Reactions of atmospheric oxygen and Hydrological cycle.

UNIT-II Air Pollution 9h

Definition – Sources of air pollution – Classification of air pollution – Ambient air quality
standards- Climate change – Global warming – Pollution from combustion systems- Acid
rain –Photochemical smog – Green house effect – Formation and depletion of ozone –
Bhopal gas disaster–Instrumental techniques to monitor pollution – Controlling methods of
air pollution.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

UNIT-III

Water pollution 9h

Unique physical and chemical properties of water – Water quality standards and parameters –
Turbidity- pH Dissolved oxygen – BOD, COD, Suspended solids, total
dissolvedsolids,alkalinity–Hardnessofwater–Methodstoconverttemporaryhardwaterintosoft
water – Methods to convert permanent hard water into soft water – eutrophication and its
effects –Industrial waste water treatment.

UNIT-IV

Chemical Toxicology 9h

Toxic chemicals in the environment – effects of toxic chemicals – cyanide and its toxic
effects – pesticides and its biochemical effects – toxicity of lead, mercury, arsenic and
cadmium- Solid waste management.

UNIT-V

Ecosystem and biodiversity 9h

Ecosystem : Concepts–structure–Functionsandtypesofecosystem–
Abioticandbioticcomponents – Energy flow and Energy dynamics of ecosystem– Food
chains – Food web– Tropic levels– Biogeochemical cycles (carbon, nitrogen and
phosphorus)

Bio diversity:

Definition – level and types of biodiversity – concept- significance – magnitude and

distribution of biodiversity–trends-biogeographical classification of india – biodiversity at
national, global and regional level.

Suggested Co-Curricular Activities:

1) Training of students by related industrial experts.

2) Assignments, Seminars, Group discussions, Debates and Quiz(on related topics).
3) Visits to laboratories, firms, research organizations etc.
4) Invited lectures and presentations on related topics by field/industrial experts.
5) Preparation of videos on tools, techniques on selected topics.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

I. List of Reference books:

1. Fundamentals of ecology by M.C.Dash

2. A Text book of Environmental chemistry byW. Moore and F.A. Moore

3. Environmental Chemistry by Samir k.Banerji

4. Water pollution, Lalude, MC Graw Hill

5. Environmental Chemistry, Anil Kumar De, Wiley Eastern ltd.

6. Environmental analysis, SM Khopkar ( IIT Bombay )

7. Environmental Chemistry by BK Sharma & H Kaur, Goel publishing house.

8. Fundamentals of Environmental Chemistry, Manahan, Stanley. E

9. Applications of Environmental Chemistry, Eugene R. Wiener

10. Web related references suggested by teacher.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V - SEMESTER

Course 12 B Environmental Chemistry

Credits: 01

Environmental Chemistry

Learning Outcomes:

On successful completion of this practical course, student shall be able to:

1. List out, Identify and handle various equipment in Chemistry lab.

2. Learn the procedures of preparation of standard solutions.

3. Demonstrate skills in operating instruments.

4. Acquire skills in handling spectrophotometer.

5. Analyze water and soil samples.

Laboratory course Syllabus:

1. Identification of various equipment in the laboratory.

2. Determination of carbonate and bicarbonate in water samples by double titration
method.

3. Determination of hardness of water using EDTA

a) Permanent hardness b) Temporary hardness

4. Determination of Chlorides in water samples by Mohr’s method.

5. Determination of pH, turbidity and total solids in water sample.

6. Determination of Ca +2 and Mg +2 in soil sample by flame photometry.

7. Determination of pH in soil samples using pHmetry.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Suggested Co-Curricular Activities:

Mandatory:(Lab /field training of students by teacher:(lab:10+field:05):

1) For Teacher: Skills training of students by the teacher in classroom, lab and field for
not less than15 hours on field related quantitative techniques for the water quality
parameters, soil pollution and air pollution.

2) For Student: Individual visit to any one of the local field agencies/research
laboratories in universities/research organizations/private sector culminating writing
and submission of a handwritten fieldwork/project work Report not exceeding 10
pages in the given format.

3) Max marks for Field work / project work Report:05.

4) Suggested Format for Fieldwork/project work: Title page, student details, index page,
details of place visited, observations, findings and acknowledgements.

5) Unit tests (IE).

II. List of Reference books:

1. A Text Book of Quantitative Inorganic Analysis(3rdEdition) –A.I.Vogel

2. Water pollution, Lalude, MC Graw Hill

3. Environmental analysis, SM Khopkar ( IIT Bombay )

4. Web related references suggested by teacher.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V - SEMESTER

Course 13A :Chromatography and Instrumental methods of Analysis

Credits: 03

Learning Outcomes:

1) Students after successful completion of the course will be able to:

2) Identify the importance of chromatography in the separation and identification of

compounds in a mixture

3) Acquire a critical knowledge on various chromatographic techniques.

4) Demonstrate skills related to analysis of water using different techniques.

5) Understand the principles of spectrochemistry in the determination of metal ions.

6) Comprehend the applications of atomic spectroscopy.

Syllabus:

Unit-1: Chromatography-Introduction and classification (9 hours)

Principle, Classification of chromatographic methods, Nature of adsorbents, eluents,

Rfvalues, factors affecting Rfvalues.

UNIT-2: TLC and paper chromatography ( 9hours)

Thin layer chromatography: Principle, Experimental procedure, preparation of plates,

adsorbents and solvents, development of chromatogram, detection of spots, applications and
advantages.

Paper Chromatography: Principle, Experimental procedure, choice of paper and solvents,

various modes of development- ascending, descending, radial and two dimensional,
applications.

UNIT-3: Column chromatography ( 9 hours)

Column chromatography: Principle, classification, Experimental procedure, stationary and

mobile phases, development of the Chromatogram, applications.

HPLC: Basic principles, instrumentation–block diagram and applications.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

UNIT-4: Spectrophotometry ( 9 hours )

Principle, Instrumentation : Single beam and double beam spectrometer, Beer-Lambert’s law-
Derivation and deviations from Beer-Lambert’s law, applications of Beer-Lambert’s law-
Quantitative determination of Fe+2, Mn+2and Pb+2.

UNIT-5: Polarimetry and Refractometry ( 9 hours )

Polarimetry and Refractometry: Polarimetry: Nature of polarized light, polarimeter, sample

cells, operation of the polarimeter, optical purity. Refractometry; The refractive index,
Refractometer.

Suggested Co-Curricular Activities:

1) Training of students by related industrial experts.

2) Assignments, Seminars and Quiz(on related topics).

3) Visits to laboratories, firms, research organizations etc.

4) Invited lectures and presentations on related topics by field/industrial experts

List of Reference books:

1) Fundamental so Analytical Chemistry by F.James Holler, Stanley R Crouch, Donald

M.West and Douglas A.Skoog, Ninth edition, Cengage.

2) Analytical Chemistry by Gary D.Christian, Purnendu K.Dasgupta and Kevin

A.Schug, Seventh edition, Wiley.

3) Quantitative analysis byR.A.DayJr .and A.L.Underwood,Sixth edition,Pearson.

4) Text book of Vogel's Quantitative Chemical Analysis, Sixth edition/Pearson.

5) Instrumental methods of Chemical Analysis by Dr.B.K.Sharma 1981

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V - SEMESTER

Course 13 A: Chromatography and Instrumental methods of Analysis

Credits: 01

Learning Outcomes:

On successful completion of this practical course, student shall be able to:

1) Perform the separation of a given dye mixture using TLC

2) Learn the preparation of TLC plates

3) Demonstrate the separation of mixture of amino acids using paper chromatography

4) Acquire skills in using column chromatography for the separation of dye mixture.

Laboratory course Syllabus:

1) Separation of a given dye mixture (methyl orange and methylene blue) using TLC
(using alumina as adsorbent).

2) Separation of mixture of methyl orange and methylene blue by column

chromatography.

3) Separation of given mixture of amino acids (glycine and phenyl alanine) using
ascending paper chromatography.

4) Separation of food dyes using Column Chromatography

5) Separation of triglycerides using TLC

6) Verification of Beer lambert’s law. (Using potassium permanganate solution) using

colorimeter / spectrophotometer.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Co-Curricular Activities:

Mandatory: (Lab /field training of students by teacher:(lab:10+field:05):

1) For Teacher:Training of students by the teacher in laboratory and field for not
lessthan15 hours on the field techniques/skills of determination of hardness of water,
using the calorimeter and or Spectrophotometer, preparation of TLC plate,
identification of spots in TLC and Paper chromatographic techniques, loading of
column, selection of solvent system, separation of amino acids and dyes mixture using
chromatographic techniques.

2) For Student: Student shall visit a related industry/chemistry laboratory in

universities/research organizations/private sector facility and observe the
chromatographic techniques used for the separation of compounds. Write their
observations and submit a hand written fieldwork/project work report not exceeding
10 pages in the given format to the teacher.

3) Max marks for Fieldwork/project work Report: 05Max marks for Field work /
project work Report:05.

4) Suggested Format for Fieldwork/project work: Title page, student details, index page,
details of place visited, observations, findings and acknowledgements.

5) Unit tests (IE).

List of Reference books:

1) Text book of Vogel's Quantitative Chemical Analysis, Sixth edition, Pearson.

2) VogelA.I .Practical Organic Chemistry, Longman Group Ltd.

3) Bansal R.K. Laboratory Manual of Organic Chemistry, Wiley-Eastern.

4) Ahluwalia V. K. and Agarwal R. Comprehensive Practical Organic Chemistry,

University press.

5) MannF.Gand Saunders B.C, Practical Organic Chemistry, Pearson Education.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V - SEMESTER

Course 13 B Green Chemistry and Nanotechnology.

Credits: 03

I. Learning Outcomes:

Students after successful completion of the course will be able to:

1. Understand the importance of Green chemistry and Green synthesis.

2. Engage in Microwave assisted organic synthesis.

3. Demonstrate skills using the alternative green solvents in synthesis.

4. Demonstrate and explain enzymatic catalysis .

5. Analyse alternative sources of energy and carry out green synthesis.

6. Carry out the chemical method of nanomaterial synthesis.

II. Syllabus

UNIT-I Green Chemistry: I 9hrs

Introduction-Definition of green Chemistry,Need for green chemistry, Goals of Green

chemistry Basic principles of green chemistry. Green synthesis- Evaluation of the type of the
reaction i) Rearrangements (100% atom economic),ii)Addition reaction(100% atom
economic). Organic reactions by Sonication method: apparatus required and examples of
sono chemical reactions (Heck, Hundsdiecker and Wittig reactions).

UNIT- II Green Chemistry : Part- II 9hrs

A) Selection of solvent:
i) Aqueous phase reactions
ii) Reactions in ionic liquids, Heck reaction, Suzuki reactions,epoxidation.
iii) Solid supported synthesis

B) Supercritical CO2:Preparation, properties and applications,(decaffeination, drycleaning)

C) Green energy and sustainability.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

UNIT-III Microwave and Ultrasound assisted green synthesis: 9hrs

Apparatus required, examples of MAOS (synthesis of fused anthroquinones, Leukart

reductive amination of ketones)-Advantages and disadvantages of MAOS. Aldol
condensation –Cannizzaro reaction - Diels-Alder reactions- Strecker's synthesis

UNIT-IV Green catalysis and Green synthesis 9hrs

Heterogeneous catalysis, use of zeolites, silica, alumina, supported catalysis-biocatalysis:

Enzymes, microbes Phase transfer catalysis (micellar/surfactant)

1. Green synthesis of the following compounds : adipic acid, catechol, disodium imino

diacetate (alternative Strecker’s synthesis)

2. Microwave assisted reaction in water –Hoffmann elimination – methyl benzoate to benzoic

acid – oxidation of toluene and alcohols–microwave assisted reactions in organic solvents.

Diels-Alder reactions and decarboxylation reaction.

3. Ultrasound assisted reactions–sonochemical Simmons–Smith reaction(ultrasonic alternative

to iodine)

UNIT – V Nanotechnology in Green chemistry 9hrs

Basic concepts of Nanoscience and Nanotechnology – Bottom-up approach and Top down
approaches with examples – Synthesis of Nano materials – Classification of Nanomaterials –
Properties and Application of Nanomaterials. Chemical and Physical properties of
Nanoparticles – Physical synthesis of nanoparticles – Inert gas condensation - aerosol method

- Chemical Synthesis of nanoparticles – precipitation and co-precipitation method, sol-gel

method.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

III. Suggested Co-Curricular Activities:

1) Training of students by related industrial experts.

2) Assignments, Seminars, Group discussions, Debates and Quiz(on related topics).

3) Visits to laboratories, firms, research organizations etc.

4) Invited lectures and presentations on related topics by field/industrial experts.

5) Preparation of videos on tools, techniques and applications of Green chemistry and

Nanosynthesis.

IV. List of Reference books:

1. Green Chemistry Theory and Practical. P.T.Anatas and J.C. Warner

2. Green Chemistry V.K. Ahluwalia Narosa, New Delhi.

3. Real world cases in Green Chemistry M.C. Cann and M.E. Connelly

4. Green Chemistry: Introductory Text M.Lancaster: Royal Society of Chemistry

(London)

5. Principles and practice of heterogeneous catalysis, Thomas J.M.,Thomas M.J., John

Wiley

6. Green Chemistry: Environmental friendly alternatives R S Sanghli and M.M

Srivastava, Narosa Publications

7. Nanotechnology: Health and Environmental Risks, Jo Anne Shatkin, CRC Press

(2008).

8. Green Processes for Nanotechnology: From Inorganic to Bioinspired Nanomaterials,

Vladimir A. Basiuk, Elena V. Basiuk Springer (2015)

9. Web related references suggested by teacher.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V- SEMESTER

Course 13 B Green Chemistry and Nanotechnology

Credits: 01

V. Learning Outcomes:

On successful completion of this practical course, student shall be able to:

1. List out, identify and handle various equipment in the laboratory.

2. Learn the procedures of green synthesis.

3. Demonstrate skills in the preparation of Nanomaterials.

4. Acquire skills in Microwave assisted organic synthesis.

5. Perform some applications of Nanomaterials.

VI. Laboratory course Syllabus:

1. Identification of various equipment in the laboratory.

2. Acetylation of 10 amine by green method: Preparation of acetanilide

3. Rearrangement reaction in green conditions: Benzil - Benzilic acid rearrangement

4. Radical coupling reaction: Preparation of 1,1-bis -2-naphthol

5. Green oxidation reaction: Synthesis of adipic acid

6. Preparation and characterization of biodiesel from vegetable oil/ waste cooking oil

7. Preparation and characterization of Nanoparticles of gold using tea leaves.

8. Benzoin condensation using Thiamine Hydrochloride as a catalyst instead of cyanide.

9. Photoreduction of Benzophenone to Benzopinacol in the presence of sunlight.

VII. Suggested Co-Curricular Activities:

Mandatory:(Lab /field training of students by teacher:(lab:10+field:05):

1) For Teacher: Training of students by the teacher in the classroom or in the

laboratory for not less than 15 hours on field related quantitative techniques for
Enzymatic catalysis, Microwave assisted organic synthesis, Biodiesel preparation
etc
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

2) For Student: Student shall visit a related industry / chemistry laboratory in

universities / research organizations/private sector facility and observe various
methods used for the analysis of water. Write their observations and submit ahand
written fieldwork /project work report not exceeding10pages in the given format
to the teacher.

3) Max marks for Field work / project work Report:05.

4) Suggested Format for Fieldwork/project work: Title page, student details, index
page, details of place visited, observations, findings and acknowledgements.

5) Unit tests (IE).

VIII. List of Reference books:

1) Green Chemistry Theory and Practical. P.T.Anatas and J.C. Warner

2) Green Chemistry V.K. Ahluwalia Narosa, New Delhi.

3) Real world cases in Green Chemistry M.C. Cann and M.E. Connelly

4) Green Chemistry: Introductory Text M.Lancaster: Royal Society of Chemistry

(London)

5) Web related references suggested by teacher.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V - SEMESTER

Course 14A: Synthetic Organic Chemistry.

Credits: 03

I. Learning Outcomes:

Students after successful completion of the course will be able to:

1) Identify the importance of reagents used in the synthesis of organic compounds.

2) Acquire knowledge on basic concepts in different types of pericyclic reactions.

3) Understand the importance of retro synthesis inorganic chemistry.

4) Comprehend the applications of different reactions in synthetic organic chemistry.

II. Syllabus:

Unit-1:Pericyclic reactions 9 hours

Definition and classification of pericyclic reactions: Phases, nodes and symmetry properties
of molecular orbital’s in ethylene,1,3-butadiene,1,3,5-hexatriene,alkylationandallylradical.
Thermal and photochemical reactions. Electro cyclic reactions: Definition and examples,
definitions of con and disrotation,Woodward-Hoffmann selection rules.(Correlation diagrams
excluded) Cyclo addition reactions: Definition and examples, definitions of supra facial and
antar facial addition, Woodward- Hoffmann selection rules. (Correlation diagrams excluded)

Unit-2 : Organic photochemistry 9hours

Jablonski diagram-singlet and triplet States Photochemistry of Carbonyl compounds 𝑛−𝜋*

and 𝜋−𝜋*transitions, Norrish type-1and type-2reactions Paterno–Buchi reaction.

Unit-3 : Retrosynthesis 9 hours

Important terms in Retro synthesis with examples-Disconnection, Target molecule, FGI,

Synthon, Retrosynthetic analysis, chemo selectivity, region selectivity. Importance of Order
of events in organic synthesis. Retrosynthetic analysis of the compounds: a)
cyclohexene b)4-Nitro toluene c) Paracetamol.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit-4 : Synthetic Reactions 9 hours

Shapiro reaction, Stork - enamine reaction(only alkylation),Wittig reaction, Robinson

annulation, Bailys-Hillman reaction, Heck reaction, Suzuki coupling. Synthesis of aldehydes
and ketones using1, 3-Dithiane.

Unit-5 : Reagents in Organic Chemistry 9 hours

Oxidizing agents:PCC,PDC,SeO2 (Riley oxidation), NBS.

Reducing agents : LiAlH4(with mechanism), LTBA, Metal-solvent reduction (Birch

reduction), Catalytic reduction.

III. Suggested Co-Curricular Activities:

1) Training of students by related industrial experts.

2) Assignments, Seminars and Quiz (on related topics), collection of relevant videos
and material.

3) Visits to laboratories, firms, research organizations etc.

4) Invited lectures and presentations on related topics by field / industrial experts.

IV. List of Reference books:

1) Pericyclic reactions by Ian Fleming, Second edition,Oxford University press.

2) Pericyclic Reactions- A Text book: Reactions, Applications and Theory by

S.Sankararaman, WILEY-VCH.

3) Reaction Mechanism in Organic Chemistry by S.M. Mukherji and S.P.Singh, Revised

edition, Trinity Press.

4) Pericyclic reactions – A Mechanistic study by S.M.Mukherji, Macmillan India.

5) Organic synthesis :The disconnection approach by Stuart Warren, John Wiley&Sons.

6) Organic chemistry by Jonathan Clayden, Nick Greeves and Stuart Warren, Second
edition, Oxford university press.

7) Reactions, Reagents and Rearrangements by S.N. Sanyal, Bharati Bhawan Publishers

&Distributors
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V - SEMESTER

Course - 14-A Synthetic Organic Chemistry

Credits: 01

V. Learning Outcomes:

On successful completion of this practical course, student shall be able to:

1) Perform the organic qualitative analysis for the detection of N, S and halogens using
the green procedure.

2) Learn the procedure for the separation of mixture famine acids using paper
Chromatography.

3) Prepare the TLC plates for TL chromatography.

4) Acquire skills in conducting column chromatography for the separation of dyes in the
given mixture.
VI. Laboratory course syllabus:

1) Green procedure for organic qualitative analysis: Detection of N,S and halogens

2) Separation of given mixture of amino acids (glycine and phenyl alanine) using
ascending paper chromatography.

3) Separation of a given dye mixture (methyl orange and methylene blue) using TLC
(using alumina as adsorbent).

4) Separation of mixture of methyl orange and methylene blue by column

chromatography

5) Separation of food dyes using Column Chromatography

6) Separation of triglycerides using TLC

VII. Suggested Co-Curricular Activities

1) Mandatory:(Lab/field training of students by teacher:(lab:10+field:05):

2) For Teacher: Training of students by the teacher in laboratory and field for not
lessthan15 hours on the field techniques/skills of detection of N, Sand halogens using
thegreen procedure, preparation of TLC plates, detection of organic compounds using
Rf values in TLC / paper chromatography, loading of column, selection of solvent

system for column chromatography, separation of amino acids and dye mixture using
chromatographic techniques.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

3) For Students : Student shall visit a related industry/chemistry laboratory in

universities/research organizations/private sector facility and observes the synthetic
reactions. Write their observations and submit a hand written fieldwork/project
workreportnotexceeding10 pages in the given format to the teacher.

4) Max marks for Fieldwork/project work Report:05.

5) Suggested Format for Fieldwork/project work: Title page, student details, index page,
details of place visited, observations, findings, and acknowledgements.

6) Unit tests(IE).

VIII. List of Reference books :

1) VogelA.I.Practical Organic Chemistry, Longman Group Ltd.

2) Bansal R.K. Laboratory Manual of Organic Chemistry, Wiley-Eastern.

3) Ahluwalia V. K. and Aggarwal R. Comprehensive Practical Organic Chemistry,

University press.

4) MannF.G and Saunders B.C, Practical Organic Chemistry, Pearson Education.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V - SEMESTER

- Course 14 B:Industrial Chemistry- Fertilisers and Surface coatings

Credits: 03

I. Learning Outcomes:

Students after successful completion of the course will be able to:

1) Identify the importance of different surface coatings.

2) Acquire a critical knowledge on manufacture of ceramics and cement.

3) Understand various steps in the manufacture of cane sugar.

4) Explain the manufacture of pulp and paper.

II. Syllabus:

Unit-1: Fertilizers 9 hours

A brief introduction to industrial chemistry. Different types of fertilizers. Manufacture of the

following fertilizers :Urea, Ammonium nitrate, Calcium ammonium nitrate, Ammonium
phosphates; Polyphosphate, Superphosphate, Compound and mixed fertilizers.

Unit-2: Silicates 9 hours

Ceramics: Important clays and Feldspar. Ceramics - types, uses and manufacture. High
technology ceramics and their applications.

Cements: Classification of cement, ingredients and their role, Manufacture of cement and the
setting process, quick setting cements.

Unit-3 : Surface Coatings 9 hours

Objectives of coatings surfaces, preliminary treatment of surface, classification of surface

coatings. Paints and pigments - formulation, composition and related properties. Oil paint

,modified oils, Pigments, toners and lake pigments, fillers, thinners, enamels, emulsifying
agents. Special paints (Heat retardant, Fire retardant, Eco-friendly paint, Plastic paint), Water
and Oil paints.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit-4: Sugar Chemistry 9hours

Introduction – Manufacture and recovery of cane sugar from molasses, manufacture of

sucrose from beet root, testing and estimation of sucrose.

Unit-5: Paper Industry 9 hours

Pulp and Paper-Introduction, Manufacture of pulp, sulphate or Kraft pulp, soda pulp, sulphite
pulp, rag pulp, beating, refining, filling, sizing and colouring of pulp, manufacture of paper.

III. Suggested Co – Curricular Activities:

1) Training of students by related industrial experts.

2) Assignments, Seminars, debates , discussions and Quiz(on related topics).

3) Visits to industries, firms, research organizations etc.

4) Invited lectures and presentations on related topics by field/industrial experts.

5) Preparation of PPTS and videos.

IV. List of Reference books:

1) J.A.Kent : Riegel’s Hand book of Industrial Chemistry, CBS Publishers, New Delhi.

2) P.C.Jain, M.Jain : Engineering Chemistry, Dhanpat Rai & Sons, Delhi.

3) R. Gopalan, D. Venkappayya, S. Nagarajan: Engineering Chemistry, Vikas

Publications, New Delhi.

4) B.K.Sharma: Engineering Chemistry,Goel Publishing House,Meerut

5) O. P. Vermani, A. K. Narula: Industrial Chemistry, Galgotia Publications Pvt. Ltd.,

New Delhi.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V - SEMESTER

Course - 14-B Industrial Chemistry- Fertilizers and Surface coatings

Credits: 01
V. Learning Outcomes:

On successful completion of this practical course, student shall be able to:

1) Determine free acidity in ammonium sulphate fertilizer.

2) Learn the procedure for the Estimation of Calcium in Calcium ammonium nitrate
fertilizer.

3) Demonstrate skills on Estimation of phosphoric acid in superphosphate fertilizer.

4) Acquire skills in using colorimeter for the estimation of sucrose.

VI. Laboratory course Syllabus:

1) etermination of free acidity in ammonium sulphate fertilizer.

2) Estimation of Calcium in Calcium ammonium nitrate fertilizer.

3) Estimation of phosphoric acid in superphosphate fertilizer.

4) Estimation of sucrose by colorimetry.

VII. Suggested Co-Curricular Activities:

Mandatory:(Lab / field training of students by teacher :(lab:10+field:05):

1) For Teacher: Training of students by the teacher in laboratory and field for not less
than 15hours on field related skills in determination of free acidity, estimation of
calcium and phosphoric acid in a fertilizer, use of colorimeter to estimate sucrose.

2) For Student :Student shall visit a related industry /chemistry laboratory in

universities/research organizations/private sector facility and observe the surface
coatings of surfaces used to prevent the corrosion. Write their observations and
submit a hand written fieldwork/project work report notexceeding10pagesinthe given
format to the teacher.

3) Max marks for Field work/ project work Report:05.

4) Suggested Format for Fieldwork/project work: Title page, student details, index page,
details of place visited, observations, findings and acknowledgements.

5) Unit tests(IE).
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VIII. List of Reference books:

1) Text book of Vogel's Quantitative Chemical Analysis, Sixth edition, Pearson.

2) Text book on Experiments and Calculations in Engineering Chemistry, S.S.Dara,

S.Chand.

3) R.Gopalan, D.Venkappayya, S.Nagarajan: Engineering Chemistry,Vikas Publications.

4) B.K.Sharma: Engineering Chemistry, Goel Publishing House, Meerut

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V - SEMESTER

Course 15 A Analysis of Organic Compounds

Credits: 03

I. Learning Outcomes:

Students after successful completion of the course will be able to:

1) Identify the importance of mass spectrometry in the structural elucidation of organic

compounds.

2) Acquire the knowledge on structural elucidation of organic compounds.

3) Understand various chromatography methods in the separation and identification of

organic compounds.

4) Demonstrate the knowledge gained in solvent extraction for the separate the organic
compounds.

II. Syllabus:

Unit-I: Nuclear Magnetic Resonance (NMR) spectroscopy 9 h

Principles of nuclear magnetic resonance, equivalent and non-equivalent protons, position of

signals. Chemical shift, NMR splitting of signals - spin-spin coupling, coupling constants.
Applications of NMR with suitable examples - ethyl bromide, ethanol, acetaldehyde, 1,1,2-
tribromo ethane, ethyl acetate, toluene and acetophenone.

Unit II Mass Spectrometry 9hrs

A brief introduction to analysis of organic compounds

Basic principles, Instrumentation - Mass spectrometer, electron Ionization (Electron

Impactionization, EI), Molecular ions, metastable ions, Isotope abundance. Basic
fragmentation types. Fragmentation patterns in Toluene, 2-Butanol, Butaldehyde,
Propionicacid.

Unit-III : Structural elucidation of organic ompounds using IR,NMR & mass spectral
data- 9 hours

2,2,3,3-Tetramethyl butane,Butane-2,3-dione,Propionicacid and methyl propionate.

Phenyl acetylene, acetophenone, cinnamic acid and p-nitroaniline.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit-IV: Separation techniques-1 9 hours

Solvent extraction-Principle and theory, Batch extraction technique, application of batch

extraction in the separation of organic compounds from mixture- acid & neutral, base &
neutral.

Chromatography – Principle and theory, classification, types of adsorbents, eluents, R fvalues

and factors affecting Rfvalues. Thin layer chromatography - principle, experimental
procedure, advantages and applications.

Unit-5: Separation techniques - 2 9 hours

Paper chromatography- Principle, experimental procedure, ascending, descending, radial and

two dimensional, applications.

Column chromatography - Principle, classification, experimental procedure and applications.

HPLC-Principle, Instrumentation – block diagram and applications.

III. Suggested Co-Curricular Activities:

1) Training of students by related industrial experts.

2) Assignments, Seminars and Quiz (on related topics), collection of relevant videos
and material.

3) Visits to laboratories, firms, research organizations etc.

4) Invited lectures and presentations on related topics by field / industrial experts.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

IV. List of Reference books:

1) Organic Spectroscopy by William Kemp,Third Edition, Palgrave USA.
2) Introduction to Spectroscopy by Pavia, Lamp man, Kriz and Vyvyan, Fifth edition,
Cengage.
3) Organic Spectroscopy: Principles and Applications by Jag Mohan, Second edition,
Alpha Science.
4) Spectroscopy of Organic Compounds by P.S.Kalsi, Seventh edition, New Age
International.

5) Spectroscopic Methods in Organic Chemistry by Ian Fleming and Dudley Williams,

Seventh edition, Springer.

6) Fundamentals of Analytical Chemistry by F.James Holler, Stanley R Crouch, Donald

M.West and Douglas A.Skoog, Ninth edition, Cengage.

7) Analytical Chemistry by Gary D.Christian, Purnendu K.Dasgupta and KevinA.Schug,

Seventh edition, Wiley.

8) Quantitative analysis by R.A.DayJr.andA.L.Underwood, Sixth edition, Pearson.

9) Text book of Vogel's Quantitative Chemical Analysis, Sixth edition, Pearson.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V - SEMESTER

Course – 15 A Analysis of Organic Compounds

Credits: 01

V. Learning Outcomes:

On successful completion of this practical course, student shall be able to:

1) Prepare acetanilide using the green synthesis.

2) Demonstrate the preparation of an azo dye.

3) Acquire skills in the separation of organic compounds in the given mixture using
solvent extraction

VI. Laboratory course Syllabus:

1) Identification of various equipment in the laboratory.

2) Acetylating of 10amine by green method : Preparation of acetanilide

3) Rearrangement reaction in green conditions : Benzil-Benzilic acid rearrangement

4) Radical coupling reaction : Preparation of 1,1-bis-2-naphthol

5) Green oxidation reaction: Synthesis of adipic acid

6) Preparation and characterization of biodiesel from vegetable oil/waste cooking oil.

7) Photo reduction of Benzophenone to Benzopinacol in the presence of sunlight.

8) Separation of organic compounds in a mixture(acidic compound + neutral compound)

using solvent extraction.

9) Separation of organic compounds in a mixture (basic compound+ neutral compound)

using solvent extraction.

VII. Suggested Co-Curricular Activities:

Mandatory: (Lab / field training of students by teacher:(lab:10+field:05):

1) For Teacher: Training of students by teacher in laboratory and field for not lessthan15
hours on the field techniques/skills of preparation of acetanilide, preparation of azo
dye, use of separating funnel for solvent extraction, separation of organic compounds
in a mixture.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

2) For Student : Student shall visit a related industry/chemistry laboratory in

universities/research organizations/private sector facility and observe the techniques
used for the separation of organic compounds. Write their observations and submit a
hand written fieldwork/project work report not exceeding10 pages in the given format
to the teacher.

3) Max marks for Fieldwork / project work Report:05.

4) Suggested Format for Fieldwork/project work: Title page, student details, index page,
details of place visited, observations, findings, and acknowledgements.

5) Unit tests(IE).

VIII. List of Reference books :

1) Vogel A.I.Practical Organic Chemistry, Longman Group Ltd.

2) Bansal R.K. Laboratory Manual of Organic Chemistry, Wiley-Eastern.

3) Ahluwalia V. K. and Aggarwal R. Comprehensive Practical Organic Chemistry,

University press.

4) MannF.G and Saunders B.C, Practical Organic Chemistry, Pearson Education.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V - SEMESTER

Course 15 B : Industrial Chemistry- Polymers and water analysis

Credits: 03

I. Learning Outcomes:

Students after successful completion of the course will be able to:

1) Understand the basic concepts of polymers

2) Acquire a critical knowledge on the preparation and applications of organic polymers.

3) Explain the sources of air pollution.

4) Demonstrate the analysis of water quality parameters.

5) Identify the importance of industrial waste management.

II. Syllabus:

Unit-1: Organic Polymers-1 9 hours

Basic definitions, degree of polymerization, classification of polymers-Natural and Synthetic

polymers, Organic and Inorganic polymers, Thermo plastic and Thermosetting polymers,
Plastics, Elastomers, Fibers and Resins, Linear, Branched and Cross-Linked polymers.

Unit-2: Organic Polymers-2 9 hours

Addition polymers and Condensation polymers, mechanism of polymerization- Free radical,

ionic and Zeigler-Natta polymerization. Industrial manufacturing and applications of following
polymers, Polystyrene, Poly acrylo nitrile, Poly methacrylate, Polymethyl- methacrylate.

Unit-3: Air Pollution 9 hours

Sources of air pollution, acid rain, photochemical smog, Greenhouse effect, Formation and
depletion of ozone, sources and effects of various gaseous pollutants: NOx, SOx, SPM, CO,
hydrocarbons, controlling methods of air pollution.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit-4 Analysis of water 9hours

Determination of total hardness of water, Dissolved oxygen, BOD, COD, total dissolved solids,
turbidity, alkalinity, determination of chloride using Mohr’s method.

Unit-5 : Industrial Waste Management 9 hours

Waste water treatment - primary, secondary & tertiary treatment. (All treatment methods in
detail). Characteristics of solid wastes, methods of solid waste treatment and disposal,
microbiology involved in solid waste disposal, methods of solid waste disposal-composting,
sanitary and filling - economic, aesthetic and environmental problems.

III. Suggested Co- Curricular Activities

1) Training of students by related industrial experts.

2) Assignments, Seminars, discussions and Quiz(on related topics).

3) Visits to laboratories, firms, research organizations etc.

4) Invited lectures and presentations on related topics by field / industrial experts.

IV. List of Reference books :

1) E.Stocchi: Industrial Chemistry,Vol-I,Ellis Horwood Ltd. UK

2) J.A.Kent : Riegel’s Handbook of Industrial Chemistry, CBS Publishers, New Delhi.

3) P.C.Jain, M.Jain : Engineering Chemistry, Dhanpat Rai & Sons, Delhi.

4) R. Gopalan, D. Venkappayya, S. Nagarajan: Engineering Chemistry, Vikas

Publications, New Delhi.

5) B.K.Sharma : Engineering Chemistry, Goel Publishing House, Meerut

6) O.P.Vermani, A.K.Narula: Industrial Chemistry, Galgotia Publications Pvt. Ltd., New

Delhi.

7) A.K.De, Environmental Chemistry : NewAgeInternational Pvt, Ltd, NewDelhi.

8) C.k.Varshney:Water Pollution and Management,Wiley Eastern Limited, Chennai.

9) S.S. Dara and D.D. Mishra: Text book of Environmental Chemistry and Pollution
Control, Revised edition, S.C.Hand & CoLtd.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V -SEMESTER
Course – 15- B Industrial Chemistry- Polymers and water analysis

Credits: 01

V. Learning Outcomes:

On successful completion of this practical course, student shall be able to:

1) Learn the procedures for the determination of BOD and COD.

2) Demonstrate skills in the determination of chloride in the given water sample.

3) Acquire skills in determining the hardness of water.

4) Analyse the soil samples

5) Handle pHmeter.

VI. Laboratory course Syllabus:

1) Determination of Hardness of water by EDTAtitration.

2) Determination of Chemical Oxygen Demand(COD)

3) Determination of Biological Oxygen Demand(BOD)

4) Determination of chloride using Mohr’s method.

5) Determination of pH, turbidity and total solids in water sample.

6) Determination of Ca+2 and Mg+2 in soil sample by flame photometry.

7) Determination of pHin soil samples using pHmetry.

VII. Suggested Co-curricular activities

Mandatory:(Student training by teacher in field related skills:inlab:15,in field:05hours):

1) For Teacher: Training of students by the teacher in laboratory and field for not
lessthan15hours on the field related skills in the determination of hardness of water,
estimation of COD and BOD in water sample, determination of chloride ion in water
sample.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

2) For Student: Student shall visit a related industry /chemistry laboratory in

universities/research organizations /private sector facility and observe the measurement
of water quality parameters. Write their observations and submit a hand written field
work / project work report not exceeding10pages in the given format to the teacher.

3) Max marks for Fieldwork/project work Report:05.

4) Suggested Format for Fieldwork/project work: Title page, student details, index page,
details of place visited, observations ,findings, and acknowledgements.

5) Unit tests(IE).

VIII. List of Reference books :

1) Text book of Vogel's Quantitative Chemical Analysis, Sixth edition, Pearson.

2) Text book on Experiments and Calculations in Engineering Chemistry, S.S.Dara,

S.Chand.

Note-1: For SEMESTER –VII &VIII, for the domain subject Chemistry, Three Core
courses and Two Skill Enhanced Courses shall be chosen course A or B from the list of
Courses in each SEMESTER. Three pairs of Core Courses are 16A&16B, 17A&17B,
18A&18B for Sem- VII and 21A &21 B, 22 A& 22 B and 23 A& 23 B in Sem-VIII.

Two Pairs of Skill Enhanced Courses are 19A&19B, 20A&20 B for Sem-VII and 24A &
24 B, 25A&25 B from Sem- VIII

One Online Course chosen from Swayam/NPTEL/Any other courses recognized by

universities per SEMESTER -VII and VIII.

Note-2: One of the main objectives of Skill Enhancement Courses (SEC) is to inculcate skills
related to the domain subject in students. The syllabus of SEC will be partially skill oriented.
Hence, teachers shall also impart practical training to students on the skills embedded in
syllabus citing related real field situations.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VII - SEMESTER

Course 16A: Inorganic Chemistry-I: Advance Studies in Complexes and

Group theory

I. Course Learning Outcomes:

On successful completion of this course, student shall be able to:

1) The student will understand the VSPER theory, symmetric and unsymmetric
Hydrogen bonds ininorganic molecules.

2) Understanding the Crystal field theory and Jahn Teller Effects.

3) The Students will be able to understand the basics of molecular orbital theory and
energetic ofhybridization.

4) The Students are able to understand the Jobs method, hard and soft acids and bases.

5) The students will acquire the knowledge of symmetry

II. Syllabus:

Unit-I: Chemistry of non- transition elements: 9 Hours

Inter halogen compounds, Halogen oxides and oxyfluorides, Clathrate compounds, Spectral
and Magnetic properties of Lanthanides and Actinides. Analytical applications of
Lanthanides and Actinides. Synthesis, properties and structure of B-N, S-N,P-N cyclic
compounds. Intercalation compounds.

Metal π- complexes: preparation, structure and bonding in Nitrosyl, Dinitrogen and

Dioxygen complexes.

Unit-II: Structure and Bonding: 9 Hours

pπ-dπ bonding, Bent’s rule, Non-valence cohesive forces, VSEPR theory. Molecular Orbital
theory, Symmetry of Molecularorbitals, Molecularorbitals in triatomic(BeH2) moleculesand

ions (NO2-) and energy level diagrams. Application of MO theory to square planar

(PtCl42-) and octahedral complexes(CoF 63-,Co(NH3 )63+). Walsh diagrams for linear
(BeH2 ) and bent(H2O)molecules.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit-III: Metal–ligand bonding: 9 Hours

Crystal Field Theory of bonding in transition metal complexes-Splitting of d-orbitals in

octahedral, tetrahedral, square planar and Trigonal bipyramidal and Square pyramidal fields.
Tetragonal distortions - Jahn-Teller effect. Applications and limitations of CFT. Experimental
evidences for covalence in complexes. Molecular Orbital Theory of bonding for Octahedral,
tetrahedral and square planar complexes. π-bonding and MOT - Effect of π - donor and π –
acceptor ligands on Δo. Experimental evidence for π-bonding in complexes.

Unit-IV: Metal–ligand Equilibriain solutions: 9 Hours

Step wise and over all formation constants. Trends in stepwise constant(statistical effect and
statistical ratio). Determination of formation constants by Spectrophotometric method (Job’s
method) and pHmetric method (Bjerrum’s). Stability correlations-Irwing-William’s series.
Hard and soft acids and bases (HSAB),Acid-base strengths.

Unit- V: Group theory 9 Hours

Basic concepts of Symmetry and Group theory- Symmetry elements, symmetry

operations and point groups. Schoenflies symbols-Classification of
molecules into point groups–Axioms of Group theory– Group multiplication
tables for C2V and C3V point groups–Similarity. Transformation and classes
Representations–reducible and irreducible representations. Mulliken symbols,
Orthogonality theorem and its implications,character table and it’s anatomy.

III. Suggested Co-Curricular Activities

1) Training of students by related industrial experts.

2) Assignments, Seminars and Quiz (on related topics), collection of relevant videos and
material.

3) Visits to industries, firms, research organizations etc.

4) Invited lectures and presentations on related topics by field/ industrial experts.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

IV. List of Textbooks :

1) Inorganic Chemistry Huheey, Harper and Row.

2) Physical methods in inorganic chemistry,R.S.Drago.AffliatedEast-WestPvt.Ltd.

3) Concise inorganic chemistry, J.D.Lee, ELBS.

4) Modern Inorganic Chemistry, W.L.Jolly, McGrawHill.

5) Inorganic Chemistry,K.F.Purcell and J.C.KotzHolt Saunders international.

6) Concepts and method Of inorganic chemistry, B.E.Douglas and D.H.M.C. Daniel,

oxford Press.

7) Introductory quantum Mechanics, A.K.Chandra.

8) Quantum Chemistry, R.K.Prasad.

V. Reference books:

1) Inorganic Chemistry, Atkins,ELBS.

2) Advanced Inorganic Chemistry,Cottonand Wilkinson,Wiley Eastern.

3) Text book of Coordination chemistry, K.Soma Sekhara Rao and K.N.K.Vani, Kalyani
Publishers.

4) GroupTheory and its Applications to Chemistry, K.V.Raman,

TataMcGraw– Hill Publishing Company Ltd., New Delhi.

5) Chemical Applications of Group Theory, F.A.Cotton Wiley Eastern

Limited NewDelhi.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Course 16A: Inorganic Chemistry-I: Advance Studies in Complexes and Group theory
practical Syllabus:

VI. Learning Outcomes:

On successful completion of this practical course, student shall be able to:

1) List out, identify and handle various equipment in Chemistry lab.

2) Understand the basic concepts of qualitative analysis of inorganic mixture.

3) Apply the concepts of common ion effect, solubility product and concepts related to
qualitativeanalysis..

4) Acquire skills in elimination interfering anion..

5) Identification of less familiar cation.

Syllabus:

1) Synthesis of Inorganic Metal Complexes:

2) Synthesis of 3d transition metal complexes of tetrahedral, square planar

andoctahedral geometries.

3) Tetra ammine copper (II) sulphate monohydrate

4) Potassium tris (oxalato) ferrate(III) trihydrate

5) Tris (thiourea) copper(I) sulphate

Systematic Semi micro Qualitative Analysis of Inorganic six radical

mixtures: In systematic Semi micro qualitative inorganic analysis, inorganic
mixture contains three cations and three anions. The analysis involves
identification and conformation ofcations and anions containing one
less familiar cation (Tungsten, Molybdenum, Zirconium, Thorium, Titanium,
Uranium, Cerium, Vanadium, Lithium, Berkelium etc.,) and one interfering
anion.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Anions:

CO32-,S2-,SO32-,Cl-,Br-,I-,NO3-,SO42-,CH3COO-, C2O42-, C4H4O62-

,PO43-,CrO42-,AsO43-,F-,BO33-

Cations :
Ammonium (NH4+)

1st group: Hg, Ag, Pb, Tl, W

2nd group: Hg, Pb, Bi, Cu, Cd, As, Sb, Sn, Mo 3rd group: Fe, Al, Cr, Ce, Th, Ti, Zr, V, U, Be
4th group: Zn, Mn, Co, Ni

5th group: Ca, Ba, Sr

6th group: Mg, K, Li

Note: A minimum of 4 inorganic mixtures must be analysed in this SEMESTER .

VII. Sugggested Co-Curricular Activities

Mandatory:(Lab/field training of students by teacher:(lab:10+field:05):

1) For Teacher: Training of students by the teacher in laboratory and field for not
lessthan15 hours on the field techniques/skills of involves identification and
conformation of cations and anions containing one less familiar cation and
one interfering anion.

2) For Students: Student shall visit a related industry/chemistry laboratory in

universities / research organizations / private sector facility and observes the
synthetic reactions. Write their observations and submit a hand written
fieldwork/project work report not exceeding10 pages in the given format to the
teacher.

3) Max marks for Fieldwork/project work Report :05.

4) Suggested Format for Fieldwork/project work: Title page, student details, index page,
details of place visited, observations, findings and acknowledgements.

5) Unittests(IE).
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VIII. Reference Books:

1) Practical Inorganic Chemistry,G.Marr and B.W.Rockett.

2) Practical Inorganic Chemistry by G.PassH. Sutchiffe, 2 nd edn JohnWiley &

Sons.

3) Experimental Inorganic / Physical Chemistry, M.A.Malati, Horwood

Publishing ,Chichester,UK(1999)

4) Vogel’s text book of semi micro qualitative analysis, 5th Edition by G. Svehla.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VII - SEMESTER

Course 16B:Inorganic Materials of Industrial Importance

I. Course learning Outcomes:

By the end of the course, the students will be able to:

1. Learn the composition and applications of the different kinds of glass.

2· Understand glazing of ceramics and the factors affecting their porosity.

3· Give the composition of cement and discuss the mechanism of setting of cement.
4· Explain the suitability of fertilizers for different kinds of crops and soil.

5· Explain the process of formulation of paints and the basic principle behind the protection
offered by the surface coatings.

6· Explain the principle, working and applications of different batteries.

7· List and explain the properties of engineering materials for mechanical construction used
in day today life.

8· Explain the synthesis and properties of nano-dimensional materials, various semiconductor

And superconductor oxides

II. Syllabus

Unit 1:Silicate Industries: [9 hours]

Glass: Glassy state and its properties, classification (silicate and non-silicate glasses).
Manufacture andprocessing of glass. Composition and properties of the following types of
glasses: Soda lime glass, leadglass, armoured glass, different types of safety glass,
borosilicate glass, fluorosilicate glass, colouredglass, photosensitive glass, photochromic
glass, glass wool and optical fibre.

Ceramics: Brief introduction to types of ceramics. glazing of ceramics.

Unit 2:Fertilizers: [9 hours]

Different types of fertilizers (N, P and K). Importance of fertilizers, chemistry involved in the
manufactureof the following fertilizers: urea, ammonium nitrate, calcium ammonium nitrate,

ammonium phosphates,superphosphate of lime, potassium chloride and potassium nitrate.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit 3: Batteries:[9 hours]

Primary and secondary batteries, characteristics of an Ideal Battery, principle, working,

applications andcomparison of the following batteries: Pb- acid battery, Li-metal batteries, Li

-ion batteries, Li-polymerbatteries, solid state electrolyte batteries, fuel cells, solar cells and
polymer cells.

Unit 4:Synthesis of inorganic solids: [9 hours]

Conventional heat and beat method, Co-precipitation method, Sol-gel method, Hydrothermal
method, Chemical vapor deposition (CVD), Ion-exchange and Intercalation method.

Unit 5:Nanomaterials: [9 hours]

Overview of nanostructures and nanomaterial’s, classification, preparation and optical

properties of gold and silver metallic nanoparticles, concept of surface Plasmon resonance,
carbon nanotubes, inorganic nanowires, Bioinorganic nanomaterial’s natural and artificial
nanomaterial’s, self-assembled nanostructures, control of Nano architecture, one dimensional
control.

III. Suggested Co-Curricular Activities

1. Training of students by related industrial experts.

2. Assignments, Seminars and Quiz (on related topics), collection ofrelevant

videos and material.

3. Visits of abilities, firms, research organizations etc.

4. Invited lectures and presentations on related topics by field/industrial experts

IV. Suggested Text Books:

1. Poole Jr.; Charles P.; Owens, Frank J. (2003), Introduction to Nanotechnology, John
Wileyand Sons
2. West, A. R. (2014),Solid State Chemistry and Its Application, Wiley
3. Smart, L. E.; Moore, E. A. (2012),Solid State Chemistry An Introduction, CRC
PresTaylor &Francis.
4. Atkins, P.W.; Overton, T.L.; Rourke, J.P.; Weller, M.T.; Armstrong, F.A.(2010),Shriver
andAtkins Inorganic Chemistry, W. H. Freeman and Company.
5. Kent, J. A. (ed) (1997),Riegel’s Handbook of Industrial Chemistry, CBS Publishers,
NewDelhi.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V. References:

1. Svehla, G.(1996),Vogel’s Qualitative Inorganic Analysis, Prentice Hall.

2. Banewicz, J. J.; Kenner, C.T. Determination of Calcium and Magnesium in Limestones

and Dolomites, Anal. Chem., 1952, 24 (7), 1186–1187.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VII: SEMESTER

Course 16B: Inorganic Materials of Industrial importance-

VI. Learning outcomes:

By the end of the course students will be able to:

1. Identify sulphate and ammonium ion present in ammonium sulphate fertilizer

2. Estimate the amount of calcium present in a fertilizer

3. Synthesize nanoparticles by chemical method

4. Synthesize metal doped metal oxide nanoparticles

5. Prepare and characterize silver nanoparticles.

VII. Practical Syllabus:

1. Detection of constituents of Ammonium Sulphate fertilizer (Ammonium and Sulphate

ions) byqualitative analysis and determine its free acidity.

2. Detection of constituents of CAN fertilizer (Calcium, Ammonium and Nitrate ions)

fertilizer andestimation of Calcium content.

3. Synthesis of ZnO nanoparticles by chemical method and its characterization using UV-
visible Spectrophotometer.4. Cu doped ZnO nanoparticles

5. Synthesis of silver nanoparticles by green methods and its characterizationusing UV-

visible Spectrophotometer.

6. Detection of constituents of Dolomite (Calcium, Magnesium and carbonate ions) and

Determination of composition of Dolomite (Complexometric titration).

VIII. Co-Curricular Activities:

Mandatory:(Lab/field training of students by teacher :(lab:10+field:05):

1. For Teacher: Training of students by the teacher in laboratory and field for not
less than15 hours on the field techniques/skills of synthesis of nanoparticles and its
characterization using various techniques.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

2. For Students: Student shall visit a related industry/chemistry laboratory in

universities/research organizations/private sector facility and observes the stages in
cement preparation. Write their observations and submit a hand written
fieldwork/project work report not exceeding 10 pages in the given format to the
teacher.

3. Max. Marks for Fieldwork/project work Report:05.

4. Suggested Format for Fieldwork/project work: Title page, student details,

index page, details of place visited, observations, findings, and

acknowledgements.

5. Unittests(IE).

IX. References:

1. Ghorbani, H. R.; Mehr, F.P.; Pazoki, H.; Rahmani B. M. Synthesis ofZnO Nanoparticles
byPrecipitation Method.Orient J Chem. 2015;31(2).

2. Orbaek, W.; McHale, M.M.; Barron, A.R. Synthesis and characterization of silver
nanoparticles for an undergraduate laboratory, J. Chem. Educ. 2015, 92, 339−344.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VII -SEMESTER

Course 17A:Spectroscopy of Organic compounds

I. Learning Outcomes:

By the end of the course, the students will be able to:

1) Gain insight into the basic fundamental principles of IR and UV-Visspectroscopic

techniques.

2) Use basic theoretical principles underlying UV-visible and IR spectroscopy as a tool for
functional group identification in organic molecules

3) Interpret of IR, UV-visible spectra and their applications

4) Interpret of NMR, Mass spectra and their applications

5) Interpret the spectra in identifying the organic compounds

II. Syllabus

Unit-I [9 hours]

UV-Vis Spectroscopy

Energy transitions – Simple chromophores – UV absorption of Alkenes –polyenes

unsaturated cyclic systems – Carbonyl compounds, α,β-unsaturated carbonylsystems -
Woodward Fieser rules – aromatic systems – solvent effects – geometricalisomerism – acid

and base effects – typical examples – calculation of λmax values usingWoodward - Fieser
rules.

b) ORD: Theory of optical rotatory dispersion, α-Axial haloketone rule and octant rule –

Application of these rules in the determination of absolute configuration of cyclohexanones,

decalones and cholestanones.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit-II [9 hours]

Infrared Spectroscopy (FT-IR): Fundamental modes of vibrations – Stretching and bending

vibrations – overtones, combination bands and Fermi resonance, factors influencing
vibrational frequencies, hydrogen bonding – fingerprint region and its importance – Study of

typical group frequencies for – CH, -OH, -NH, -CO-NH2, -CC, -CHO, -CO and aromatic
systems. Application in structural determination –Simple problems

Unit-III [9 hours]

1
H NMR spectroscopy:

a) Magnetic properties of Nuclei, Nuclear resonance, Fourier Transformation and its

importance in NMR. Equivalent and non-equivalent protons, The chemical shift and it’s
importance, calculation of chemical shift, factors affecting the chemical shifts such as
electronegativity and anisotropy, effect of deuteration, Signal integration, Spin-spin coupling:
vicinal (Karplus relationships), germinal and long range. Coupling constants (J) and factors
affecting coupling constants. –Shielding and deshielding mechanisms in acetylene carbonyl
and Benzene, anisotropy –Spin-Spin Interactions related to first order and higher order spectra
(AB, A2; AB2, ABX, ABC, AMX) –temperature dependence spectra, Hydrogen bonding.

Unit-IV [9 hours]

Electron Spin Resonance Spectroscopy (ESR):

Basic Principles, Comparison of NMR &ESR.Determination of ‘g’ value, Factors

affectingthe ‘g’ value.Isotropic and Anisotropic constants.Splitting, hyperfine splitting
couplingconstants. Line width, Zero field splitting, and Kramer degeneracy. Crystal field
splitting,Crystal field effects.

Applications: Detection of free radicals; ESR spectra of(a) Methyl radical (CH3∙), (b)
Benzene anion (C6H6-).
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

UNIT-V

MASS SPECTROMETRY [9 hours]

Introduction, ion production, type of ionization, EI, CI, FD, and FAB-factors affecting
fragmentation, ion analysis, ion abundance. Mass spectral fragmentation of organic
compounds, common functional groups, molecular-ion peak, metastable peak, Mac Lafferty
rearrangement. Nitrogen rule, isotope labeling. High resolution mass spectrometry, Examples
of mass spectral fragmentation of organic compounds with respect to their structure
determination.

III. Suggested Co-Curricular Activities

1. Training of students by related industrial experts.

2. Assignments, Seminars and Quiz (on related topics), collection ofrelevant

videos and material.

3. Visits of abilities, firms, research organizations etc.

4. Invited lectures and presentations on related topics by field/industrial experts.

IV. Suggested Text Books:

1. Organic spectroscopy, W. Kemp 5th Ed, ELBS

2. Spectroscopy of organic compounds, RM Silversteen and others, 5th Ed,John Wiley

3. Spectroscopy of organic compounds, P.S. Kalsi, Wiley, 1993.

V. References:

1. NMR in chemistry-A multi nuclear introduction, William Kemp, McMillan, 1986.

2. Spectroscopic methods in Organic chemistry, DH Williams & I Flemmi

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Course 17A: Spectroscopy of Organic Compounds- Practical Syllabus

VI. Learning outcomes:

By the end of the course students will be able to

1. Identify the functional groups present in the molecules

2. Apply data to in identification of the molecule

3. Describe principles involved in Spectroscopic methods

4. Predict number of signals, splitting patterns in the proton NMR of a compound

5. Develop ability in the combined use of mass spectrometry and spectroscopic techniques for
structure elucidation

VII. Practical Syllabus

a) Problems involving individual spectral methods – UV, IR, PMRand Mass

b) Problems involving combined any two of UV, IR, PMRand Mass

c) Problems involving combined any three of UV, IR, PMRand Mass

c) Problems involving all four UV, IR, PMR and Mass spectral data.

VIII. Co-Curricular Activities:

Mandatory:(Lab/field training of students by teacher:(lab:10+field:05):

1. For Teacher: Training of students by the teacher in laboratory and field for not less
than15 hours on the field techniques/skills of detection of organic compounds
using spectroscopic data.

2. For Students: Student shall visit a related industry/chemistry laboratory in

universities/research organizations/private sector facility and observes the
synthetic reaction and obtaining spectral data and analyzing the organic
compounds. Write their observations and submit a hand written fieldwork/project
work report not exceeding
10 pages in the given format to the teacher.
3. Max. Marks for Fieldwork/project work Report:05.
4. Suggested Format for Fieldwork/project work: Title page, student details,
index page, details of place visited, observations, findings, and
acknowledgements.

5. Unit tests(IE).
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

IX. References:

1. NMR in chemistry-A multi nuclear introduction, William Kemp, McMillan, 1986.

2. Spectroscopic methods in Organic chemistry, DH Williams & I Flemmi

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VII - SEMESTER

Course 17 B: Organic Chemistry: Stereo Chemistry and Natural Products

I. Course Learning outcomes:

On successful completion of this course, student shall be able to:

1) Understand and apply the substitution and elimination reaction mechanisms at

aliphaticand aromatic substrates for various reactions leading to research

2) Write the stereo chemical forms for different organic molecules.

3) Understand the conformations of acyclic, monocyclic and fused ring systems and
applying it toorganic compounds.

4) Explain formation of various heterocyclic compounds and their synthesis and

importance.

5) Describe the importance of natural products in medicinal chemistry

II. Syllabus:

Unit – I Reaction Mechanism 9 Hours

Aliphatic Nucleophilic Substitution and Nucleophilic Aromatic substitution:

Stereo chemistry of SN2and SN1 mechanisms, Neighboring Group Participation

(Anchimeric assistance), NGP by O, S, N : Aromatic Nucleophilic substitution SN2 (Ar)
(Addition – Elimination), SN1(Ar) and benzyne mechanisms (Elimination - Addition);
evidence for the structure of benzyne. Von Richter Sommelet-Hauser rearrangements.

Elimination Reactions:

Type of elimination reactions, mechanisms, Stereochemistry and Orientation, Hofmann

and Saytzeff rules, Syn elimination versus anti-elimination,competition between
elimination and substitution, dehydration, dehydrogenation, dehalogenation,
decarboxylative eliminations and pyrolytic eliminations
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit-II: Stereo Chemistry-I: 9 Hours

Concept and Recognition of Molecular Symmetry and Chirality. Definition and

classification of Stereoisomers, Enantiomer, Diastereomer, Homomer, Epimer, Anomer,
Configuration and Conformation, Configurational nomenclature: D,L and R,S
nomenclature. Molecular representation of organic molecules: Fischer,Newman and
Sawhorse projections and their inter-conversions. Geometrical Isomerism. Cis-trans, E, Z-
and Syn and anti nomenclature, Methods of determining configuration of Geometrical
isomers using physical, spectral and chemical methods, Stability, Cis-trans interconversion.

Unit-III: Stereo Chemistry-II: 9 Hours

Conformation and factors influencing on stability of Conformations; Conformational

analysis of cyclic molecules - cyclobutane, cyclohexane – mono and disubstituted
cyclohexanes and carbon heteroatom bonds having C–O&C–N. Prochirality and

Prostereoisomerism:-Homotopic ligands and faces; enantiotopic ligands and faces;

diastereotopic ligands and faces; nomenclature of enantiotopic ligands and faces(Pro-R,
Pro- S, Re, Si carbonyl compounds and Alkenes)

Stereoisomerism in molecules without chiral Center Axial chiralityAllenes, Alkylidene

cycloalkanes, spiranes. Atropisomerism: Biphenyl derivatives, nomenclature. Planar
chirality: Ansa compounds, paracyclophanes, trans-cyclooctene and Helicity.

UNIT–IV Heterocyclic compounds 9 Hours

Importance of heterocyclic compounds as drugs. Nomenclature of heterocyclic systems

based on ring size, number and nature of hetero atoms. Chemistry of heterocyclic
compounds, synthesis and reactivity of the following systems: Quinoline, Isoquinoline,
Indole, Pyrazole, Imidazole, Oxazole, Isoxazole, Pyridazine, pyrimidine and Pyrazine.

UNIT- V Chemistry of some typical natural products 9Hours

Isolation, classification, structure elucidation, synthesis of:

Alkaloids: Atropine, Nicotine, and Quinine.

Terpenoids: α-Terpeneol, α-Pinene and Camphor.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

III. Suggested Co- Curricular Activities

1) Training of students by related industrial experts.

2) Assignments, Seminars and Quiz (on related topics), collection ofrelevant videos
and material.

3) Visits to laboratories, firms, research organizations etc.

4) Invited lectures and presentations on related topics by field/industrial experts.

IV. List of Textbooks:

1) Advanced organic chemistry-Reaction, mechanism and structure, Jerry March,

John Wiley.

2) Advanced organic chemistry, F.A.Carey and R.J.Sundberg, Springer, NewYork.

3) A guide book to Mechanism in organic chemistry, Peter Sykes, Longman.

4) Organic chemistry, I.L.Finar, Vol.I, Fifth edi . ELBS.

5) Organic chemistry, Hendrickson,Cram and Hammond (McGraw–Hill).

V. Reference books:

1) Structure and mechanism in organic chemistry, C.K.Ingold, Cornell University Press.

2) Principles of organic synthesis, R.O.C.Norman and J.M.Coxon, Blakie Academic

& Professional.

3) ReactionMechanisminOrganicChemistry,S.M.MukherjiandS.P.Singh,Macmillan.

4) Basic Principles of Organic Chemistry by J.B.Roberts and M. Caserio.

5) Stereochemistry of Organic compounds by Ernest L.Eliel, Samuel H.Wilen

6) Chemistry of natural products byS.V.Bhat ,B.A.Nagasampangi.

7) Stereochemistry of Organic compounds by D.Nasipuri.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Course No 17 B : ORGANIC CHEMISTRY PRACTICALS

VI. Learning Outcomes:

On successful completion of this practical course, student shall be able to:

1) List out, identify and handle various equipment in Chemistry lab.

2) Acquire skills in the separation of organic compounds in the given mixture using
solvent extraction.

3) Determine the Melting and Boiling points of Organic compounds.

4) Understand the application of concepts of different organic reactions studied in the

theory partof Organic chemistry.

VII. Syllabus.
Systematic qualitative analysis of an organic mixture containing two compounds; Identification
of method of separation and the functional group(s) present in each of them and preparation of
one solid derivative for the conformation of each of the functional group(s).Purification of
derivatives- The student has to do Recrystallization to final derivatives(s) and submit the sample.
If the sample is impure liquid must carry out distillation process.

VIII. Suggested Co-Curricular Activities

Mandatory:( Lab/field training of students by teacher:(lab:10+field:05):

1) For Teacher: Training of students by the teacher in laboratory and field for
not lessthan15 hours on the field techniques/skills of separation of the given
organic mixture, identifying and confirming the functional group followed
by the preparation of recrystallized solid derivative.

2) For Students: Student shall visit a related industry/chemistry laboratory in

universities/research organizations/private sector facility and observesthe synthetic
reactions. Write their observations and submit a hand written fieldwork/project
work report not exceeding10 pages in the given format to the teacher.
3) Max marks for Fieldwork/project work Report:05.
4) Suggested Format for Fieldwork/project work: Title page, student details, index
page, details of place visited, observations, findings and acknowledgements.

5) Unit tests(IE).
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

IX. Reference Books:

1) Vogel’s Text Book of Quantitative Chemical Analysis, J. Mendham, R. C.

Denney, J. D.Barnes and M. J. Thomas, 4th& 6th Ed. (Pearson Education Asia).

2) Vogel’s Text Book of Practical Organic Chemistry, B.S. Furniss, A.J. Hannaford,
P.W.G.Smith, A.R. Tatchell, 5 Ed.(Longman Scientific & Technical).
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VII - SEMESTER

Course 18A:Physical Chemistry – I :Thermodynamics, Electrochemistry andChemical

Kinetics

I. Course Learning outcomes:

On successful completion of this course, student shall be able to:

1) Understand the classical thermo dynamics, fugacity.

2) Describe the Electrochemical cells, Liquid junction potential.

3) Derive the Butler - Volmer equation and Ilkovic equation

4) Understand the complex reactions, chain reactions.

5) Demonstrate the Branching Chain Reactions, Enzyme catalysis and Photochemical

equilibrium.

II. Syllabus

Unit-I: Thermodynamics: 9 Hours

Classical thermodynamics - Entropy change in reversible and irreversible processes - Entropy

of mixing of ideal gases - Entropy and disorder – Free energy functions - Gibbs-Helmholtz
equation – Maxwell partial relations. Conditions of equilibrium and spontaneity - Free energy
changes in chemical reactions, Van't Hoff reaction isotherm - Van't Hoff equation – Classiuss

- Clapeyron equation -partial molar quantities - Chemical potential - Gibbs- Duhem equation

- partial molar volume -determination of partial molar quantities - Fugacity - Determination

of fugacity – Thermodynamic derivation of Raoult'slaw.

Unit-II: Electrochemistry-1: 9 Hours

Electrochemical cells - Measurement of EMF - Nernst equation –Equilibrium constant from

EMF Data - pH and EMF data - Determination of solubility product from EMF
measurements. Concentration cells with and without transference – Liquid junction potential
and its determination -Activity and activity coefficients - Debye Huckel limiting law and its

verification. Effect of dilution on equivalent conductance of electrolytes - Anomalous

behavior of strong electrolytes. Debye Huckel – Onsagar equation-verification andlimitations-
Bjerrum treatment of electrolytes.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit-III: Electro Chemistry-II: 9 Hours

Reference electrode - Standard hydrogen electrode. Calomel electrode-Indicator electrodes:

Metal- metal ion electrodes – Inert electrodes-Membrane electrodes - theory of glass
membrane potential, potentiometric titrations, Conductometric titrations. Electrode potentials

- Double layer at the interface - rate of charge transfer - Decomposition potential – Over

potential - Tafel plots - Derivation of Butler- Volmer equation for one electron transfer –
electro chemical potential.

Unit-IV :Chemical kinetics and Photochemistry: 9 Hours

Branching Chain Reactions- Hydrogen-oxygen reaction - lower and upper explosion limits -
Fast reactions - Study of kinetics by flow methods -Relaxation methods - Flash photolysis.
Acid base catalysis –protolytic and prototropic mechanism. Enzyme catalysis-Michelis-
Menten kinetics.

Photochemistry:Quantum yield and its determination, Actinometry, Reactions with low and
high quantum yields, Photo sensitization, Exciplexes and Excimers,Kinetics of collisional
quenching- Stern-Volmer equation.

Unit-V: Chemical kinetics - II: 9Hours

Methods of deriving rate laws - complex reactions - Rate expressions for opposing, parallel
and consecutive reactions involving unimolecular steps. Theories of reaction rates -
collision theory-Steric factor-Activated complex theory -Thermo dynamic aspects–
Unimolecular reactions- Lindemann's theory -Lindemann Hinshelwood theory. Primary and
secondary salt effects. Elementary account of linear free energy relationships - Hammet-
Taftequation - Chain reactions - Rate laws of H2-Br2, photochemical reaction of H2 - Cl2.
Decomposition of acetaldehyde and ethane- Rice-Hertzfeld mechanism.

III. Suggested Co- Curricular Activities:

1) Training of students by related industrial experts.

2) Assignments, Seminars, discussions and debates and Quiz (on related topics),
collection of relevant videos and material.

3) Visits to laboratories, firms, research organizations etc.

4) Invited lectures and presentations on related topics by field / industrial experts.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

IV. List of Textbooks:

1) Physical Chemistry P.W.Atkins, ELBS.

2) Chemical Kinetics -K.J.Laidler,McGraw Hill Pub.

3) Text Book of Physical Chemistry. Samuel Glasstone, Mcmillan Pub.

4) Physical Chemistry, G.W.Castellan.Narosa Publishing House

V. Reference books:

1) Thermodynamics for Chemists.Samuel Glasstone.

2) Electro chemistry,Samuel Glasstone,Affiliated East West

3) Physical Chemistry, W.J.Moore, Prentice Hall

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Course 18A : PHYSICAL CHEMSITRY PRACTICALS –I

Learning Outcomes:

On successful completion of this practical course, student shall be able to:

1) List out, identify and handle various equipment in Chemistry lab.

2) Learn and apply the concepts of electro chemistry in experiments.

3) Be familiar with electro analytical methods and techniques which study an analyte by
measuring the potential ( volts) and / or current ( amperes) in an electro chemical cell
containing the analyte..

4) Learn the procedures of preparation of standard solutions.

5) Acquire skills in operation and calibration of instruments..

Syllabus:

1) Conductometric titration of Strong acid versus Strong base

2) Dissociation constant of weak acid (CH3COOH) by conductometric method.

3) Conductometric titration of Weak acid vs Strong base.

4) Determination of cell constant

5) Acid-catalyzed hydrolysis of methyl acetate

6) Determination of partial molar volume of solute –H2O system by apparent molar

volume method.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Suggested Co-CurricularActivities
Mandatory:(Lab/fieldtrainingofstudentsbyteacher:(lab:10+field:05):

1) For Teacher: Training of students by the teacher in laboratory and field for not
lessthan15 hours on the field techniques/skills of handling conductometric
titrations.

2) For Students: Student shall visit a related industry / chemistry laboratory in

universities/research organizations/private sector facility and observes the
synthetic reactions. Write their observations and submit a hand written field
work/project work report not exceeding10 pagesin the given format to the teacher.

3) Max marks for Field work /project work Report : 05.

4) Suggested Format for Field work/project work: Title page, student details, index
page,details of place visited, observations, findings and acknowledgements.

5) Unit tests(IE).

VI. Reference book:

1) Vogel’s Text Book of Quantitative Chemical Analysis, J. Mendham, R. C. Denney, J.

D. Barnesand M. J. Thomas, 4th& 6th Ed. (Pearson Education Asia).

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VII - SEMESTER

Course 18 B: Instrumental Methods of Chemical Analysis

I. Learning Outcomes

By the end of the course, the students will be able to:

1) Handle analytical data

2) Understand basic components of IR, FTIR, UV-Visible and Mass spectrometer.

3) Interpret of IR, FTIR, UV-visible spectra and their applications.

4) Understand the use of single and double beam instruments.

5) Learn elemental analysis, Electro analytical Methods, Radiochemical Methods, X-ray

analysis and electron spectroscopy

II. Syllabus:
Unit-I: Introduction to analytical methods of data analysis and Electroanalytical
Methods: [9 hours]

Treatment of analytical data, including error analysis. Classification of analytical methods

and the types of instrumental methods. Consideration of electromagnetic radiations.

Potentiometry & Voltammetry.

Unit –II: Molecular spectroscopy [9 hours]

Infrared spectroscopy: Interaction of radiations with molecules: absorption and scattering.

Means of excitation (light sources), separation of spectrum (wavelength dispersion, time
resolution), detection of the signal (heat, differential detection), interpretation of spectrum
(qualitative, mixtures, resolution),and advantages of Fourier-Transform Infrared (FTIR)
spectroscopy.
Applications: Issues of quality assurance and quality control, special problems for portable
instrumentation and rapid detection.

Unit- III:UV-Visible/ Near IR Spectroscopy [9hours]

Emission, absorption, fluorescence and photoacoustic. Excitation sources (lasers, time
resolution),wavelength dispersion (gratings, prisms, interference filters, laser, placement of
sample relative to dispersion, resolution), Detection of signal (photocells, photomultipliers,

diode arrays, sensitivity and S/N),Single and double beam instruments, Interpretation
(quantification, mixtures, absorption vs. fluorescence and the use of time).
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit–IV: Mass spectroscopy [ 9 hours]

Making the gaseous molecule into an ion (electron impact, chemical ionization), Making
liquids and solids into ions (electrospray, electrical discharge, laser desorption, fast atom
bombardment), Separation of ionson basis of mass to charge ratio, Magnetic, Time of flight,
Electric quadrapole. Resolution, time and multiple separations, detection and interpretation.

Unit –V: Elemental analysis [9 hours]

Atomic spectroscopy: Atomic absorption, atomic emission, and atomic fluorescence.

Excitation and getting sample into gas phase (flames, electrical discharges, plasmas),

wavelength separation and resolution (dependence on technique), detection of radiation

(simultaneous/scanning, signal noise),interpretation (errors due to molecular and ionic
species, matrix effects, other interferences).

III. Suggested Co-Curricular Activities

1. Training of students by related industrial experts.

2. Assignments, Seminars and Quiz (on related topics), collection of

relevant videos and material.

3. Visits of abilities, firms, research organizations etc.

4. Invited lectures and presentations on related topics by field/industrial experts.

IV. Suggested Text Books:

1. Willard, H.H.; Merritt, L.L. Jr.; Dean, J.A.; Settle, F.A. Jr.(2004), Instrumentalmethods
of analysis, 7th edition, CBS Publishers.

2. Skoog, D.A.; Holler, F. J.; Crouch, S.(2006),Principles of Instrumental Analysis,

Thomson Brooks/Cole.

3. Banwell, C.N. (2006),Fundamentals of Molecular Spectroscopy,Tata McGraw-Hill

Education
V. Reference Books:

1. Skoog, D. A.; Holler, F. J.; Crouch, S.(2006),Principles of Instrumental Analysis,

Cengage Learning.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

2. Christian, G.D.(2004),Analytical Chemistry, 6th Edition, John Wiley & Sons, New York.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Course 18 B: Instrumental Methods of Chemical Analysis-Practical Syllabus

VI: Course learning outcomes

By the end of the course students will be able to

1) Determine the isoelectric pH of a protein

2) Identify the functional groups present in organic compounds

3) Estimate the amount of chloride and iodide present in the solution

4) Recognize the quality of water

VII. Practical-Syllabus

1. Determination of the isoelectric pH of a protein.

2. Titration curve of an amino acid

3. IR absorption spectra (study of aldehydes and ketones)

4. Potentiometric titration of a chloride-iodide mixture

5. Potentiometric Titration of Metal Ions in Ethanol

6. Estimation of Alkalinity, BOD and COD

VIII. Co-Curricular Activities:

a) Mandatory:(Lab/fieldtrainingofstudentsbyteacher:(lab:10+field:05):
1. For Teacher: Training of students by the teacher in laboratory and field
for not lessthan15 hours on the field techniques/skills of detection of
organic compounds using spectroscopic data.

2. ForStudents:Student shall visit a related industry/ chemistry laboratory

in universities/research organizations/private sector facility and
observes the synthetic reactions and obtain spectral data for
interpretation of the synthetic compounds. Write their observations and
submit a hand written fieldwork/project work report not exceeding10
3. pages in the given format to the teacher.

4. Max. marks for Fieldwork/project work Report:05.

5. Suggested Format for Fieldwork/project work: Title page, student

details, index page, details of place visited, observations, findings,
and acknowledgements.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

6. Unittests(IE).

IX. References:

1. Skoog, D. A.; Holler, F. J.; Crouch, S.(2006),Principles of Instrumental Analysis,

Cengage Learning.

2. Christian, G.D.(2004),Analytical Chemistry, 6th Edition, John Wiley & Sons, New York.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VII - SEMESTER

Skill Enhancement Course

Course 19 A: Green Chemistry

I. Learning Outcomes:

By the end of the course Students will be able to:

1. Understand the twelve principles of green chemistry and will build the basic understanding
of toxicity, hazard and risk of chemical substances·

2. Understand stoichiometric calculations and relate themto green chemistry metrics.

3. They will learn about atom economy and how it is different from percentage yield.

4. Learn to design safer chemical, products and processes that are less toxic, than current
alternatives. Hence, they will understand the meaning of inherently safer design for accident
prevention and the principle "what you don't have can't harm you"

5. Understand benefits of use of catalyst and bio catalyst,use of renewable feed stock which
helps in energy efficiency and protection of the environment, renewable energy sources, and
importance led reactions in various green solvents.

6. Appreciate the use of green chemistry in problem solving skills, critical thinking and
valuable skills to innovate and find out solution to environmental problems. Thus the students
are able to realize that chemistry can be used to solve rather than cause environmental
problems.

7. Green chemistry is a way to boost profits, increase productivity and ensure sustainability
with absolute zero waste. Success stories and real world cases also motivate them to practice
green chemistry.

II. Syllabus:

Unit 1:Introduction to Green Chemistry [9 hours]

What is Green Chemistry? Some important environmental laws, pollution prevention Act of
1990, emergence of green chemistry, Need for Green Chemistry. Goals of Green Chemistry.
Limitations/ Obstacles in the pursuit of the goals of Green Chemistry.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit 2:Principles of Green Chemistry and Designing a Chemical synthesis [9 hours]

Twelve principles of Green Chemistry and their explanation with examples

Special emphasis on the following:

Prevention of Waste/ by products; maximum incorporation of the materials used in the

process into the final products, Environmental impact factor, waste or pollution prevention
hierarchy. Green metrics to assess greenness of a reaction, e.g. Atom Economy, calculation of
atom economy of the rearrangement, addition, substitution and elimination reactions.
Prevention/ minimization of hazardous/ toxic products reducing toxicity. Risk = (function)
hazard x exposure. Designing safer chemicals with minimum toxicity yet has the ability to
perform the desired functions. Green solvents: super critical fluids with special reference to
carbon dioxide, water as a solvent for organic reactions, ionic liquids, fluorous biphasic
solvent, PEG, solventless processes, solvents obtained from renewable resources and how to
compare greenness of solvents. Energy requirements for reactions – alternative sources of
energy: use of microwaves,

Ultrasonic energy and photochemical energy. Selection of starting materials; should be

renewable rather than depleting, Illustrate with few example such as biodiesel and polymers
from renewable resources (such as green plastic). Avoidance of unnecessary derivatization –
careful use of blocking/protecting groups. Use of catalytic reagents (wherever possible) in
preference to stoichiometric reagents; catalysis andgreen chemistry, comparison of
heterogeneous and homogeneous catalysis, biocatalysis, asymmetric catalysis and
photocatalysis.

Unit 3:Examples of Green Synthesis/ Reactions [9 hours]

Green Synthesis of the following compounds: adipic acid, catechol, disodium iminodiacetate
(alternative toStrecker synthesis).Green Reagents: Non-phosgene Isocyanate Synthesis,
Selective Methylation using Dimethylcarbonate. Microwave assisted solvent free synthesis of
copper phthalocyanine. Microwave assisted reactions in water: Hofmann Elimination, methyl
benzoate to benzoic acid. AndDecarboxylation reactionUltrasound assisted reactions:
sonochemical Simmons-Smith Reaction (Ultrasonic alternative to Iodine)
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit 4: [9 hours]
Real world case studies based on the Presidential green chemistry awards of EPA
Surfactants for Carbon Dioxide – replacing smog producing and ozone depleting solvents
with CO2 for precision cleaning and dry cleaning of garments. A new generation of
environmentally advanced wood preservatives: Getting the chromium and Arsenic out of
pressure treated wood. An efficient, green synthesis of a compostable and widely applicable

plastic (polylactic acid) made from corn. Healthier Fats and oils by Green Chemistry:
Enzymatic Inter esterification for production of No Trans-Fats and Oils.

Unit 5:Future Trends in Green Chemistry [9 hours]

Oxidation reagents and catalysts; Biomimcry and green chemistry, Biomimetic,
Multifunctional Reagents; mechanochemical and solvent free synthesis of inorganic
complexes; co crystal controlled solid state synthesis(C2S3); Green chemistry in sustainable
development.

III. Suggested Co-Curricular Activities

1. Training of students by related industrial experts.

2. Assignments, Seminars and Quiz (on related topics), collection ofrelevant

videos and material.

3. Visits of abilities, firms, research organizations etc.

4. Invited lectures and presentations on related topics by field/industrial experts.

IV. Suggested Text Books:

1. Anastas, P.T.; Warner, J.C.(1998),Green Chemistry, Theory and Practice, Oxford
University Press.
2. Lancaster, M.(2016),Green Chemistry An Introductory Text.2nd Edition, RSC
Publishing.
3. Cann , M. C. ;Connely,M. E.(2000), Real-World cases in Green Chemistry, American
Chemical Society,Washington.

4. Matlack, A.S.(2001),Introduction to Green Chemistry, Marcel Dekker.

5. Alhuwalia,V. K.; Kidwai, M.R.(2005),New Trends in Green chemistry,

Anamalaya Publishers
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V. References:

1. Kirchoff, M.; Ryan, M.A. (2002), Greener approaches to undergraduate chemistry

experiment. AmericanChemical Society, Washington DC.

2. Sharma, R.K.; Sidhwani, I.T.; Chaudhari, M.K.(2013), Green Chemistry Experiments: A

monograph, I.K.International Publishing House Pvt Ltd. New Delhi.

3. Pavia,D.L.; Lamponam, G.H.; Kriz, G.S.W. B.(2006),Introduction to organic

Laboratory Technique-A Micro-scale approach,4th Edition, Brooks-Cole Laboratory
Series for Organic chemistry.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VII - SEMESTER

Skill Enhancement Course

Course 19 A: Green Chemistry practical

Learning Outcomes:

By the end of the course students will be able to

1. Synthesize nanoparticles using green methods

2. Prepare biodiesel form waste cooking oil

3. Synthesize inorganic complexes using green methods

4. Synthesize benzopinacol in the presence of sunlight

VI. Practical Syllabus

1. Preparation and characterization of nanoparticles of CuO/ ZnO nanoparticles usingplant

extracts.

2. Preparation of biodiesel fromwaste cooking oiland characterization (TLC, pH, Solubility,

Combustion Test,Density, Viscosity.

3. Benzoin condensation using Thiamine Hydrochloride as a catalyst instead of cyanide.

4. Solvent free, microwave assisted one pot synthesis of phthalocyanine complex of

copper(II).

5. Photoreduction of benzophenone to benzopinacol in the presence of sunlight.

6. Spot tests for qualitative inorganic analysis for cations and anions, and qualitativeorganic
analysis for preliminary test and functional group analysis.

VII. Co-Curricular Activities:

Mandatory:(Lab/field training of students by teacher :(lab:10+field:05):

1. For Teacher: Training of students by the teacher in laboratory and field for not
less than15 hours on the field techniques/skills of green methodologies in place of

polluting solvents/chemicals
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

2. For Students: Student shall visit a related industry/chemistry laboratory in

universities/research organizations/private sector facility and observes the green
synthetic methods adopted in the industry. Write their observations and submit a
hand written fieldwork/project work report not exceeding 10 pages in the given
format to the teacher.

3. Max. Marks for Fieldwork/project work Report:05.

4. Suggested Format for Fieldwork/project work: Title page, student details,

index page, details of place visited, observations, findings, and
acknowledgements.

5. Unittests(IE).

VIII. References:

1. Wealth from Waste: A green method to produce biodiesel from waste cooking oil and
generation of usefulproducts from waste further generated. Indu Tucker Sidhwaniet al.
University of Delhi, Journal ofUndergraduate Research and Innovation, Volume 1, Issue
1,February 2015, ISSN: 2395-2334.

2. Sidhwani, Tucker I.; Chowdhury, S. Greener alternatives to Qualitative Analysis for

Cations withoutH2S and other sulfur containing compounds, J. Chem. Educ. 2008, 85, 1099.

3. Sidhwani, Tucker I.; Chowdhury, S. et al., DU Journal of Undergraduate Research and

Innovation,2016, Volume 2, Issue 2, 70-79.

4. Dhingra, S., ;Angrish, C. Qualitative organic analysis: An efficient, safer, and economical
approach to preliminary tests and functional group analysis. Journal of ChemicalEducation,
2011, 88(5), 649-651.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VII - SEMESTER

Skill Enhancement Course

Course 19 B: Analysis of Drugs,Foods,DairyProducts&Bio-Chemical Analysis

I. Learning Outcomes:

Students after successful completion of the course will be able to:

1. Explain the principles of formulation and application of Drugs.

2. Acquire a critical knowledge on synthetic techniques of drugs.

3. Demonstrate the skills in analysis of Foods,DairyProducts.

4. Comprehended the applications of Bio-ChemicalAnalysis.

5. Acquire a critical knowledge on analysis of Foods,DairyProducts.

II. Syllabus)

UNIT- I 9 hours
Analysis of the following drugs and pharmaceuticals preparations: (Knowledge of molecular
formula, structure and analysis): Analysis of analgesics and antipyretics like aspirin and
paracetamol ,Analysis of antimalerials like choloroquine, Analysis of drugs in the treatment of
infections and infestations: Amoxycillin, chloramphenicol, penicillin, tetracycline.

UNIT- II 9 hours
Analysis of the following drugs and pharmaceuticals preparations :(Knowledge of molecular
formula, structure and analysis):

Analysis of antihistamine drugs and sedatives like: allegra, zyrtec (citirizine), alprazolam,
trazodone, lorazepem, ambien(zolpidem).

UNIT- III 9 hours

Analysis of anti epileptic and anti convulsant drugs like phenobarbital and
phenacemide.Analysis of drugs used in case of cardiovascular
drugs:atenolol,norvasc(amlodipine),Analysis of lipitor(atorvastatin) a drug for the prevention
of production of cholesterol.

Analysis of diuretics like: furosemide (Lasix), triamterene

Analysis of prevacid(lansoprazole)a drug used for the prevention of production of acids in

stomach.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

UNIT- IV 10 hours

Analysis of Milk and milk products:Acidity,total solids,fat,total nitrogen,protenines, lactose,

phosphate activity, casein, choride. Analysis of food materials-Preservatives :Sodium
carbonate, sodium benzoate sorbicacid. Coloring matters –Briliant blue FCF, fastgreenFCF,
tertrazine, erytrhosine, sunset yellowFCF.

Flavoring agents - Vanilla , diacetyl, isoamyl acetate, limonene, ethyl propionate , allyl

hexanoate and Adulterants in rice and wheat, wheat floor, sago, coconut oil, coffee powder,
tea powder, milk.

UNIT-V 8 hours

Clinical analysis of blood: Composition of blood,clinical analysis, trace elements in the body.
Estimation of blood chlolesterol, glucose,enzymes, RBC&WBC,Blood gas analyser.

III. Suggested Co-Curricular Activities

1) Training of students by related industrial experts.

2) Assignments, Seminars and Quiz (on related topics), collection of relevant videosand
material.

3) Visits of related Industries/firms,research organizations etc.

4) Invited lectures and presentations on related topics by field/industrial experts.

IV. Text Books:

1. Wilson and Giswold’s Organic medicinal and Pharmaceutical Chemistry.

2. Foye’s Principles of Medicinal Chemistry.

3. Burger’s Medicinal Chemistry, Vol I to IV.

4. Introduction to principles of drug design- Smith and Williams.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V. References Books:

1. Wilson and Giswold’s Organic medicinal and Pharmaceutical Chemistry.

2. Foye’s Principles of Medicinal Chemistry.

3. Burger’s Medicinal Chemistry, Vol I to IV.

4. Introduction to principles of drug design- Smith and Williams.

5. Remington’s Pharmaceutical Sciences.

6. Martindale’s extra pharmacopoeia.

7. Organic Chemistry by I.L. Finar, Vol. II.

8. The Organic Chemistry of Drug Synthesis by Lednicer, Vol. 1-5.

9. Text book of practical organic chemistry- A.I.Vogel.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Course 19B. AnalysisofDrugs,Foods,DairyProducts&Bio-ChemicalAnalysis-PracticalSyllabus

VI. Learning Outcomes:

On successful completion of this practical course, student shall be able to:

1. Develop comprehensive product development programs to meet new product criteria

and timing.

2. Acquire skills in the Analysis of Drugs,foods and Dairy Products.

3. Demonstrate proficiency in the experimental techniques of biomedical chemical

4. Carry out food testing with the knowledge of foods.

5. Learn the procedure of synthesis of drugs.

6. Critically develop, apply, report, interpret and reflect on strategies for collectingdata
in the lab and field.

VII. Practical (Laboratory) Syllabus:

1. Preparation of Aspirin

2. Preparation of Paracetamol

3. Preparation of Acetanilide

4. Preparation of BarbutiricAcid

5. Preparation of Phenyl Azo β-naphthol

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VIII. References Books:

1. Introduction to principles of drug design- Smith and Williams.

2. Remington’s Pharmaceutical Sciences.

3. Martindale’s extra pharmacopoeia.

4. Organic Chemistry by I.L. Finar, Vol. II.

5. The Organic Chemistry of Drug Synthesis by Lednicer, Vol. 1-5.

6. Text book of practical organic chemistry- A.I.Vogel.

IX. Co-CurricularActivities

Mandatory:(Lab/fieldtrainingofstudentsbyteacher:(lab:10+field:05):

1. For Teacher: Training of students by the teacher in laboratory and field for not
lessthan15 hours on the field techniques/skills of comprehensive product development
programs to meet new product criteria and timing. Acquire skills in the preparation of
Drugs, foods and Dairy Products, carry out food testing with the knowledge of testing
food adultrationand learn the procedure of synthesis of drugs.

2. ForStudents:Studentshallvisitarelatedindustry/chemistrylaboratoryinuniversities/rese
arch organizations/private sector facility and observes the preparation of
Cosmeceuticals and Pharmaceutical. Write their observations and submit a hand
written fieldwork/project workreportnotexceeding10 pages in the given
format to the teacher.

a). MaxmarksforFieldwork/projectworkReport:05.

b). Suggested Format for Fieldwork/project work: Title page, student

details,indexpage,detailsofplacevisited,
observations,findings,andacknowledgements.

c).Unit tests(IE).
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

SEMESTER – VII

Skill Enhancement course

Course 20A: Polymer Chemistry

I. Course Learning Outcomes

By the end of this course, students will be able to:

1. Know about history of polymeric materials and their classification

2· Learn about different mechanisms of polymerization and polymerization techniques

3· Evaluate kinetic chain length of polymers based on their mechanism

4· Differentiate between polymers and copolymers

5· Learn about different methods of finding out average molecular weight of polymers

6· Differentiate between glass transition temperature (Tg) and crystalline melting point (Tm)
7· Determine Tg and Tm

8· Know about solid and solution properties of polymers

9· Learn properties and applications of various useful polymers in our daily life.

II. Syllabus:

Unit-1

History of polymeric materials and functionality and its importance [9 hours]

Different schemes of classification of polymers, Polymer nomenclature, Molecular forces and

chemical bonding in polymers, Texture of Polymers.Criteria for synthetic polymer formation,
classification of polymerization processes, Relationships between functionality, extent of
reaction and degree of polymerization. Bi-functional systems, Poly-functional systems.

Unit-II

Kinetics of Polymerization [9 hours]

Mechanism and kinetics of step growth, radical chain growth, ionic chain (both cationic and
anionic) and coordination polymerizations, Mechanism and kinetics of copolymerization,
polymerization techniques.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit-III

Determination of molecular weight of polymers and crystallinity [9 hours]

(Mn,Mw, etc) by end group analysis, viscometry, light scattering and osmotic pressure
methods. Molecular weight distribution and its significance. Poly dispersity index.
Determination of crystalline melting point and degree of crystallinity, Morphology of
crystalline polymers, Factors affecting crystalline melting point.

Unit-IV

Glass transition temperature (Tg) and Polymer Solution [9 hours]

Free volume theory, WLF equation, Factors affecting glass transition temperature (Tg).
Criteria for polymer solubility, Solubility parameter, Thermodynamics of polymersolutions,
entropy, enthalpy, and free energy change of mixing of polymers solutions, Flory- Huggins
theory, Lower and Upper critical solution temperatures.

Unit-V

Properties of Polymers [9 hours]

(Physical, thermal, Flow &Mechanical Properties).

Brief introduction to preparation, structure, properties and application of the following

polymers: poly olefins, polystyrene and styrene copolymers, poly (vinyl chloride) and related
polymers, poly(vinyl acetate) and related polymers, acrylic polymers, fluoro polymers,
polyamides and related polymers. Phenol formaldehyde resins (Bakelite, Novalac),
polyurethanes, silicone polymers, polydienes, Polycarbonates, Conducting Polymers, [poly
acetylene, poly aniline, poly(p-phenylene sulphide poly pyrrole, poly thiophene)].

III. Suggested Co-Curricular Activities

1. Training of students by related industrial experts.

2. Assignments, Seminars and Quiz (on related topics), collection ofrelevant

videos and material.

3. Visits of abilities, firms, research organizations etc.

4. Invited lectures and presentations on related topics by field/industrial experts.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

IV. Suggested Text Books:

1. R.B. Seymour & C.E. Carraher: Polymer Chemistry: An Introduction, Marcel Dekker, Inc.
New York, 1981.

2. G. Odian: Principles of Polymerization, 4th Ed. Wiley, 2004.

3. F.W. Billmeyer: Textbook of Polymer Science, 2nd Ed. Wiley Interscience, 1971.

4. P. Ghosh: Polymer Science & Technology, Tata McGraw-Hill Education, 1991.

5. R.W. Lenz: Organic Chemistry of Synthetic High Polymers. Interscience Publishers, New
York, 1967.

V. Refernces:

1. Allcock, H.R.; ; Lampe, F. W.; Mark, J. E.(2003),Contemporary Polymer Chemistry,

Prentice-Hall.

2. Fried, J.R. (2003), Polymer Science and Technology, Prentice-Hall.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Course 20A:Polymer Chemistry- Practical Syllabus

VI. Learning Outcomes:

By the end of the course students will be able to

1. Determine the molecular weight of a polymer by viscometric studies

2. Prepare urea formaldehyde polymer

3. Determine the molecular weight by end group analysis

VII. Practical Syllabus

1. Estimation of the amount of HCHO in the given solution by sodium sulphite method

2. Determination of molecular weight by viscometry: Poly vinyl proplylidine (PVP) in water

3. Determination of molecular weight by end group analysis

4. Preparation of urea-formaldehyde resin

5. Precipitation polymerization of acrylonitrile

6. Redox polymerization of acrylamide

VIII. Co-Curricular Activities:

Mandatory:(Lab/field training of students by teacher :(lab:10+field:05):

1. For Teacher: Training of students by the teacher in laboratory and field for not
less than15 hours on the field techniques/skills of preparation of polymers.

2. For Students: Student shall visit a related industry/chemistry laboratory in

universities/research organizations/private sector facility and observes the
preparation steps of polymers and quality polymer formed using various
techniques. Write their observations and submit a hand written fieldwork/project
work report not exceeding

10 pages in the given format to the teacher.

3. Max. Marks for Fieldwork/project work Report:05.

4. Suggested Format for Fieldwork/project work: Title page, student details,
index page, details of place visited, observations, findings, and
acknowledgements.

5. Unittests(IE).
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

IX. References:

1. Munk, P.; Aminabhavi, T. M. (2002), Introduction to Macromolecular Science, John

Wiley &Sons.

2. Sperling, L.H.(2005),Introduction to Physical Polymer Science, John Wiley & Sons

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

SEMESTER – VII

Skill Enhancement Course

Course 20B.Industrial Chemicals and Environment

I. LearningOutcomes:

Students after successful completion of the course will be able to:

1. Identify the importance of Manufacture of Inorganic Chemicals

2. Acquire knowledge on production, uses, storage and hazards of Industrial Gases.

3. Understand the importance of Environment.

4. Understanding about water pollution and its effects.

5. Acquire knowledge on Energy and its effects on Environment

Syllabus

Unit-I 9 Hours

Inorganic Chemicals: Manufacture, application, analysis and hazards in handling the

following chemicals: hydrochloric acid, nitricacid, sulphuricacid, causticsoda, common salt,
borax, bleaching powder, sodium thiosulphate, hydrogen peroxide, potash alum,chrome alum,
potassium dichromate and potassium permanganate.

Unit-II 9 Hours

Industrial Gases: Large scale production, uses, storage and hazards in handling of the following
gases: oxygen, nitrogen, argon, neon, helium, hydrogen, acetylene, carbon monoxide,
chlorine,fluorine,sulphur dioxide and phosgene

IndustrialMetallurgy:

Preparationofmetals(ferrousandnonferrous)andultrapuremetalsforsemiconductortechnology.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit-III 9 hours

Air pollution

Air Pollution: Major regions of atmosphere. Chemical and photochemical reactions in

atmosphere. Air pollutants :types, sources, particle size and chemical nature; Photochemical
smog: its constituents and photochemistry. Environmental effects of ozone, Major sources of

air pollution. Pollution bySO2, CO2, CO, NOx, H2S and other foul smelling gases. Methods of
estimation of CO, NOx, Sox and control procedures. Effects of air pollution on living
organisms and vegetation. Greenhouse effect and Global warming, Ozone depletion by oxides
of nitrogen, chloro fluoro carbons and Halogens, removal of sulphur from coal. Control of
particulates.

Unit-IV 9hours

Water Pollution: Hydrological cycle, water resources, aquatic ecosystems, Sources and
nature of water pollutants, Techniques for measuring water pollution, Impacts of water
pollution on hydrological and ecosystems. Water purification methods. Effluent treatment
plants (primary, secondary and tertiary treatment). Industrial effluents from the following
industries and their treatment: electroplating, textile, tannery, dairy, petroleum and
petrochemicals, agro, fertilizer,etc.

Unit-V

Energy&Environment 9 hours

Sources of energy: Coal, petrol and

naturalgas.NuclearFusion/Fission,Solarenergy,Hydrogen,geothermal, Tidal and Hydel, etc.
Nuclear Pollution: Disposal of nuclear waste, nuclear disaster and its management.

Biocatalysis:Introduction to biocatalysis :Importance in ―Green Chemistry and Chemical

Industry.

II. Suggested Co-Curricular Activities

1. Training of students by related industrial experts.
2. Assignments, Seminars and Quiz (on related topics), collection of relevant videosand
material.
3. Visits of related Industries/firms, research organizations etc.
4. Invited lectures and presentations on related topics by field/industrial experts.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

III. Text Books:

1. J.A.Kent:Riegel’s Hand book of Industrial Chemistry,CBSPublishers,NewDelhi.

2. S.S.Dara: AText book of Engineering Chemistry, S.Chand&CompanyLtd.NewDelhi.

3. K.De,Environmental Chemistry:NewAge InternationalPvt., Ltd,New Delhi.

4. E.Stocchi: Industrial Chemistry,Vol-I,EllisHorwood Ltd.UK.

IV. References Books:

1. E.Stocchi: Industrial Chemistry,Vol-I,EllisHorwood Ltd.UK.

2. R.M. Felder, R.W. Rousseau: Elementary Principles of Chemical Processes,

WileyPublishers,New Delhi.

3. J.A.Kent:Riegel’s Hand book of Industrial Chemistry,CBSPublishers,NewDelhi.

4. S.S.Dara: A Text book of Engineering Chemistry, S.Chand&CompanyLtd.NewDelhi.

5. K.De,Environmental Chemistry:NewAge InternationalPvt., Ltd,New Delhi.

6. S.M.Khopkar,Environmental Pollution Analysis: WileyEasternLtd,NewDelhi.

7. S.E.Manahan,Environmental Chemistry,CRCPress(2005).

8. G.T.Miller,Environmental Science11thedition.Brooks/Cole(2006).

9. A.Mishra,Environmental Studies.Selectiveand ScientificBooks,NewDelhi(2005).

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Course 20B: Industrial Chemicals &Environment- PracticalSyllabus

V. LearningOutcomes:

Onsuccessfulcompletion ofthispractical course, studentshall beableto:

1. Perform DeterminationofDO, COD and BOD

2. Learn the procedure for

measurementofchloride,sulphateandsalinityofwater

3. Estimationof total alkalinityof water

4. Acquire skills in determination of dissolved gases like O2, CO2,SPMetc.

Practical(Laboratory)Syllabus:

1. Determination of Dissolved Oxygen (DO)in water.

2. Determination of Chemical Oxygen Demand(COD)

3. Determination of Biological Oxygen Demand(BOD)

4. Percentage of available chlorine in bleaching powder.

5. Measurement of chloride, sulphate and salinity of water samples by simpletitration

method (AgNO3 and potassium chromate).

6. Estimation of total alkalinity ofwater samples (CO 32-,HCO3-) using double titration
method.

7. Measurement of dissolvedCO2.

8. Study of some of the common bio-indicators of pollution.

9. Estimation of SP Minair samples.

10. Preparation of borax/boricacid.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VI. Lab References:

1. E.Stocchi: Industrial Chemistry,Vol-I,EllisHorwoodLtd.UK.

2. R.M. Felder, R.W. Rousseau: Elementary Principles of Chemical Processes,

WileyPublishers,New Delhi.

3. J.A.Kent:Riegel’s Hand book of Industrial Chemistry,CBSPublishers,NewDelhi.

4. S.S.Dara: AText book of EngineeringChemistry,S.Chand&CompanyLtd.NewDelhi.

5. K.De,Environmental Chemistry:NewAgeInternationalPvt., Ltd,NewDelhi.

6. S.M.Khopkar,Environmental Pollution Analysis: WileyEasternLtd,NewDelhi.

VII. Co-CurricularActivities

Mandatory:(Lab/fieldtrainingofstudentsbyteacher:(lab:10+field:05):

5. For Teacher: Training of students by the teacher in laboratory and

field for not lessthan15 hours on the field techniques/skills in
determinationofDO, COD,BOD, CO2,SPM etc. Learn the procedure
for measurementofchloride,sulphateandsalinityofwater, total
alkalinityof water

6. ForStudents:Studentshallvisitarelatedindustry/chemistrylaboratoryinun
iversities/research organizations/private sector facility and observes the
determinationofDO, COD,BOD, CO2,SPM etc. Write their
observations and submit a hand written fieldwork/project
workreportnotexceeding10 pages inthegivenformat totheteacher.

a. MaxmarksforFieldwork/projectworkReport:05.

b. Suggested Format for Fieldwork/project work: Title page, student

details, indexpage,detailsofplacevisited,
observations,findings,andacknowledgements.

c. Unittests(IE).
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VIII - SEMESTER

Course 21A: Inorganic Chemistry-II: Metal clusters, Electronic spectra ofComplex

compounds and Bio-inorganic chemistry

I. Course Learning outcomes:

On successful completion of this course, student shall be able to:

1) Understand the study of age compounds of oxygen, phosphorous andsulphur..

2) Explain the various metal clusters and metal π complexes.

3) Describe the reactions of organo metallic compounds and its applications.

4) Understand the reaction mechanism in transition metal complexes.

5) Demonstrate the orgel diagrams and electronic spectra of transition metalcomplexes.

6) Discuss structure and functions of hemoglobin, myoglobin and vitamin B12,

photochemical laws.

II. Syllabus

Unit-I:Non-metal cages and metal clusters: 9Hours

Structure and bonding in phosphorous- oxygen, phosphorous -Sulphur cages; structure and
bonding in higher boranes with (special referencetoB12 icosahedra). Carboranes,
metalloboranes, metallocarboranes. Classification- LNCs and HNCs, Isoelectronic and Isolobal
relationships, electron counting rules: Wade’s and Lauher’s rules. M-Mmultiple bonding;
preparation ,structure and bonding in dinuclear[Re2Cl8]2- ion, trinuclear[Re3Cl9], tetranuclear
W4(OR)16, hexanuclear[Mo6Cl8]4+ and [Nb6Cl12]2-.

Unit-II: Organo metallic chemistry of transition metals: 9Hours

Classification and electron counting rules,hapticity, synthesis, structure and bonding of

Ferrocene,dibenzene chromium, cycloheptatriene and tropylium complexes of transition
metals.Reactions of organo metallic compounds- oxidative addition, reductive elimination,

insertion and elimination. Applications of organo metallic comp ounds-Catalytic hydrogenation,

Hydro formylation.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit-III: Reaction mechanism of transition metal complexes: 9Hours

Kinetics of octahedral substitution, acid hydrolysis, base hydrolysis - conjugate base (CB)
mechanism. Direct and indirect evidences in favour of CB mechanism. Anation reactions.

Reactions without metal-ligand bond cleavage. Factors affecting the substitution reactions in
octahedral complexes. Trans effect on substitution reactions in square planar complexes.
Mechanism of redox reactions, outer sphere mechanism, cross reactions and Marcus – Hush
equation, inner sphere mechanism.

Unit-IV: Term symbols and Electronic spectra: 9Hours

Term symbols and their derivation. Microstates, Hunds rules to predict ground terms and ground

states.List of ground energy and higher energy terms from d 1 to d9 configurations;

Electronic spectra of transition metal complexes:Spectroscopic terms.Selection rules,Slator–

Condon parameters, Racah parameters,Term separation energies for d n configurations.
Correlationdiagrams and Orgel diagrams. Tanabe- Sugano diagrams for d1tod9
configurations.Calculations of Dq, B and β parameters. Charge transfer spectra.

nit-V:Bio-inorganic chemistry and Magnetic properties of complexes: 9Hours

Bio-inorganic chemistry:

Storage and transport of dioxygen by Hemoglobin and Myoglobin, Chlorophyll, Vitamin B12 and
its importance.

Magnetic properties of transition metal complexes:

Orbital and spin contribution, spin-orbit coupling and magnetic moments. Types of magnetism,
factors affecting on Paramagnetism, Dia, ferro and Antimagnetism.

III. suggested Co- Curricular Activities

1) Training of students by related industrial experts.

2) Assignments, Seminars, discussions, debates and Quiz (on related topics), collectionof
relevant videos and material.

3) Visits to laboratories, firms, research organizations etc.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

4) Invited lectures and presentations on related topics by field/industrial experts

IV. List of Textbooks:

1) Inorganic Chemistry by Huheey.Harper and Row.

2) Concise inorganic chemistry by J.D. Lee ,ELBS.

3) Inorganic chemistry, K.F.Purcell and J.C.Kotz, Holt Saunders international

4) Organo metallic chemistry by R.C.Mehrotra and A.Singh.NewAge International.

5) Advanced Inorganic Chemistry by Cotton and Wilkinson, Wiley Eastern

V. Reference books:

1) Inorganic reaction mechanism by Basolo and Pearson, Wiley Eastern

2) Bioinorganic Chemistry by K.Hussan Reddy

3) Biological Aspects of inorganic chemistry by A.W. Addiso, W.R.Cullen, D.Dorphin and

G.J.James. Weliey Interscience.

4) Photo chemistry of coordination compounds by V.Balzani and V. Carassiti. Academic

Press.

5) Text book of Coordination chemistry by K.Soma Sekhara Rao and K.N.K.Vani, Kalyani
Publishers.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Course 21A: INORGANIC CHEMISTRY PRACTICALS –II

VI. Learning Outcomes:

On successful completion of this practical course, student shall be able to:

1) List out, identify and handle various equipment in Chemistry lab.

2) Learn the concepts and procedures of preparation of standard solutions, primary and
secondary standards.

3) Demonstrate skills in Volumetric and gravimetric determinations.

4) Acquire skills in standardizing and determination of different metal ions.

5) Understand and explain the volumetric analysis based on fundamental concepts learnt in
ionic equillibria.

VII. Practical Syllabus:

Quantitative analysis -

Volumetric:

1) Determination of Ferric iron by photochemical reduction

2) Determination of Nickel by EDTA

3) Determination of Calcium and Magnesium in a mixture by EDTA

4) Determination of Ferrocyanide by Ceric sulphate

5) Determination of Copper(II) in presence of iron(III)

Gravimetric:

1) Determination of Zinc as Zinc pyrophosphate

2) Determination of Nickel from a mixture of Copper and Nickel.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VIII. SuggestedCo-Curricular Activities

Mandatory:(Lab/fieldtrainingofstudentsbyteacher:(lab:10+field:05):

1) For Teacher: Training of students by the teacher in laboratory and field for not
lessthan15 hours on the field techniques/skills of determination of cations
by volumetric and gravimetric determinations.

2) For Students: Student shall visit a related industry/ chemistry laboratory in

universities/ research organizations/private sector facility and observes the
synthetic reactions. Write their observations and submit a hand written field
work/project work report not exceeding10 pages in the given format to the teacher.

3) Max marks for Field work / project work Report:05.

4) Suggested Format for Fieldwork/project work: Title page, student details, index
page,details of place visited, observations, findings, and acknowledgements.

5) Unit tests(IE).

IX. Reference books:

1) Vogel’s text book of quantitative chemical analysis, 5th edition by G.H. Jeffery et al.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VIII - SEMESTER

Course 21B: Organo Metallic Chemistry

I. Learning Outcomes:

By the end of this course, students will be able to

1. Apply 18-electron rule to rationalize the stability of metal carbonyls and relatedspecies

2. Understand the nature of Zeise’s salt and compare its synergic effect with that ofcarbonyls.

3. Identify important structural features of the various hapto metal complexes

4. Get a general idea of catalysis and describe in detail the mechanism of Wilkinson’s
catalyst,

5. Zeigler- Natta catalyst and synthetic gasoline manufacture by Fischer-Tropsch process

6. Understand the importance of organometallic compounds in the synthesis oforganic

compounds

II. Syllabus:

Unit-I Mono, Di, hapto Complexes [9 hours]

Nomenclature and Classification based on the number of Coordinated Carbons (hapticity) and
number of electrons donated by the Ligand. 16 and 18 electron rules.Electron counting covalent and
ionic models. 1Complexes : General methods of Preparation –Bonding of Ligand to Metal :α and β
Interaction and agostic interaction– Stability and decomposition pathways – 1 Complexes –
Tertiary Phosphine – Transition Metal Alkyl and Aryl Complexes of Pt – Ortho-effect – Bonding in
Metal – Carbene and Carbyne Complexes. 2 –Complexes: General methods of preparation of
Metal –Alkene Complexes – Structure and Bonding in 2 Complexes.

Unit-II Tri, tetra and pentahapto Complexes [9 hours]

3 - Complexes: Metal-Allyl Complexes – General Preparative Routes – Structure andBonding in

3 Allyl Complexes – Fluxionality. 4 Complexes: Structure and Bonding in

4 Complexes –Butadiene and Cyclo butadiene Complexes. 5 – Complexes: General methods of

Preparation – Bis ( 5-cyclopentadienyl) metal complexes (Metallocenes) – Ferrocene: Structure
and Bonding –Reactions of Ferrocene – Mechanism of Electroplilic substitution – Friedel Crafts
acylation, alkylation, nitration.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit-III Hexa, Hepta and Octahapto Complexes [9 hours]

6Complexes : Metal –Arene Complexes – Dibenzenechromium – Preparation, Structure and

Bonding inBis(arene)-Metal Complexes – Reactions. 7 Complexes: Preparation , Structure and
Reactions of 7C7H7 Complexes. 8 Complexes: C8H8 as a Ligand – Cyclooctatetraene
Complexes – Preparation,Structure and Bonding in Uranocene

Unit-IV Catalysis by Organometallic Compounds [9 hours]

General principles of catalysis, properties of catalysts, homogeneous and heterogeneous catalysis

(Catalytic steps, examples and industrial applications), deactivation and regeneration of catalysts,
catalyticpoison, promoter.

Study of the following industrial processes and their mechanism:

1. Alkene hydrogenation (Wilkinson’s Catalyst)

2. Synthetic gasoline (Fischer Tropsch reaction)

3. Polymerisation of ethene using Ziegler-Natta catalyst

Unit-V Organometallic Reagents in Organic synthesis [9 hours]

Preparation and application of the following in organicsynthesis: 1) Organolithium 2) Organo

copper reagents 3) Organoboranes in C-C bondformation 4) Organo silicon reagents: reactions
involving β-carbocations and α-carbanions,utility of trimethylsilyl halides, cyanides and triflates.

Suggested Co-Curricular Activities

1. Training of students by related industrial experts.
2. Assignments, Seminars and Quiz (on related topics), collection ofrelevant
videos and material.
3. Visits of abilities, firms, research organizations etc.
4. Invited lectures and presentations on related topics by field/industrial experts.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

III. Suggested Text Books:

1. Shriver, D.D.; Atkins, P.; Langford, C.H. (1994),Inorganic Chemistry 2nd Ed., Oxford
UniversityPress.

2. Atkins, P.W.; Overton, T.L.; Rourke, J.P.; Weller, M.T.; Armstrong, F.A. (2010),Shriver
andAtkins Inorganic Chemistry, 5th Edition, W. H. Freeman and Company.

3. Cotton, F.A.; Wilkinson, G.; Gaus, P.L. Basic Inorganic Chemistry, 3rd Edition,Wiley
India.

4. Powell, P.(1988), Principles of Organometallic Chemistry, Chapman and Hall.

IV. References:

1. Organometallics-A Concise Introduction, Ch.Eischeinbroich and Salzer-VCH

2. Organotransition Metal Chemistry Fundamental Concepts and Applications, John
AkioYamamato,Wiley & Sons.

3. Basic organometallic Chemistry, B.D. Gupta / A. J. Elias

4. Greenwood, N.N.; Earnshaw, A.(1997), Chemistry of the Elements, 2nd Edition,

Elsevier(Ziegler Natta Catalyst and Equilibria in Grignard Solution)

Course 21B: Organo Metallic Chemistry-Practical Syllabus

V. Learning Outcomes
By the end of the course students will be able to
1. Synthesize inorganic complexes using monodentate ligands
2. Prepare Cis complexes using bi dentate ligands
3. Prepare Trans Complexes using bi dentate ligands
4. Distinguish Cis and Trans compounds

VI. Practical Syllabus:

1. TetraammineCoppe (II) Sulphate monohydrate

2. Potassium tris oxalate Ferrate (III) Tri hydrate

3. Hexaammine Nickel (II) Chloride

4. Preparation of Cis bis (glycenato) Copper (II) monohydrate

5. Preparation of Transbis (glycenato) Copper (II) monohydrate
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

6. Synthesis of tris (acetyl acetonato) Manganese (III)

VII. Co-Curricular Activities:

Mandatory:(Lab/field training of students by teacher :(lab:10+field:05):

1. For Teacher: Training of students by the teacher in laboratory and field for not
less than15 hours on the field techniques/skills of preparation and identification of
complexes

2. For Students: Student shall visit a related industry/chemistry laboratory in

universities/research organizations/private sector facility and observes the
synthesis of inorganic metal complexes and analyzing it using IR spectral data.
Write their observations and submit a hand written fieldwork/project work report
not exceeding 10 pages in the given format to the teacher.

3. Max. Marks for Fieldwork/project work Report:05.

4. Suggested Format for Fieldwork/project work: Title page, student details,
index page, details of place visited, observations, findings, and
acknowledgements.

5. Unit tests(IE).

VIII. References:

1. Advanced Practical Chemistry, J. Singh, R.K.P.,Singh, etc. Pragati Edition

2. R.G. Charles, Inorg. Symth. 7 (1963) 183

3. F. Basolo and R.g. Pearson, Mechanisms of Inorganic reactions, 2 nd Edition. Pearson

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VIII- SEMESTER

Course 22A: Organic Chemistry: Modern Organic synthesis and Natural products

I. Course Learning outcomes:

On successful completion of this course, student shall be able to:

1) Understand various types of reaction intermediates and the bonding present in various
organic compounds.

2) Explain how to protect various functional groups in organic synthesis.

3) Describe the mode of addition reactions by electrophile and nucleophiles.

4) Discuss mechanisms of named reactions and their applications in organic synthesis.

5) Know about the importance of flavones, flavonoids and harmones.

II. Syllabus:

UNIT – I Reactive intermediates, Reactive Species and Protecting groups: 9 hours

Reactive intermediates : Generation, Structure, Stability, Detection and Reactivity of

Carbocations,Carbanions, Free radicals, Carbenes, Nitrenes and Arynes.

Reactive Species: Generation and reactivity of Electrophiles, Nucleophiles, Dienophiles,

Ylids, Enophiles.

Protecting groups: Protection of carbonyl, Hydroxyl, carboxylic acid and amine groups.

UNIT-II Addition Reactions 9 Hours

Addition to Carbon – Carbon Multiple Bonds: Mechanistic and stereo chemical

aspects of addition reactions involving electrophiles, nucleophiles and free radicals, region
and chemo selectivity,orientation and reactivity, Hydrogenation of double and
triple bonds, hydrogenation of aromatic rings, Hydroboration.

Addition to Carbon - Hetero Multiple Bonds: Steric course of addition reactions to

C=O and C=N, , Knoevenagel, Claisen- Schmidt, Dieckman and Stobbe condensations,
Wittig, Grignard, Mannich and Michael reaction.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

UNIT-III Molecular Rearrangements 9 Hours

Types of molecular rearrangements, migratory aptitude;

Rearrangements to electron deficient carbon: Wagner-Meerwein, Dienone–Phenol, Arndt-

Eistert synthesis;

Rearrangements to electron deficient nitrogen: Beckmann, Hofmann, Schmidt

rearrangements;

Rearrangements to electron deficient oxygen: Baeyer-villiger, Benzil-Benzilic acid and

Favorskii rearrangements.

UNIT–IV: Steroid harmones 9Hours

Nomenclature, basic skeleton, Diel’s hydrocarbon and it’s stereochemistry. Isolation,
structure determination and synthesis of androsterone, testosterone, oestrone and
progesterone.

UNIT–V: Flavonoids and Isoflavonoids: 9 Hours

Nomenclature and general methods of structure determination, Isolation, structure
elucidation and synthesis of Kaempferol, Quercetin, Cyanidin, Genestein, Butein and
Daidzein. Biosynthesis of flavonoids and Isoflavonoids.

III. Suggested Co- curricular activities

1) Training of students by related industrial experts.

2) Assignments, Seminars, discussions and Quiz (on related topics), collection of

relevant videos and material.

3) Visits to laboratories, firms, research organizations etc.

4) Invited lectures and presentations on related topics by field/industrial experts

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

IV. List of Text books :

1) Advanced Organic Chemistry: Reactions Mechanisms and Structure by

JerryMarch, Mc.GrawHill and Kogakush.

2) Organic Chemistry Vol.I(SixthEd )andVol.II(Fifth Ed.) by ILFinar

ELBS.

3) Organic Chemistry (fifthEd) by Morrison and Boyd, PHI, India.

4) Organic Chemistry (fifthedition) by Francis A.Carey Tata Mc Graw Hill

publishing Company Limited, New Delhi.

5) Chemistry of natural products by S.V.Bhat, B.A.Nagasampangi

V. Reference Books:

1) Reaction Mechanism in Organic Chemistry by Mukherjee Singh.

2) A guide book to mechanism in Organic Chemistry by Peter Sykes,

ELBS.

3) Chemistry of Natural products by R.S.Kalsi, Kalyani Publishers.1983.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Course 22A : ORGANIC CHEMISTRY PRACTICALS –II

VI. Learning Outcomes:

On successful completion of this practical course, student shall be able to:

1) List out, identify and handle various equipment in Chemistry lab.

2) Learn the concepts and procedures of handling chemical reagents appropriately.

3) Demonstrate skills to perform reflux, distillation, recrystallisation and vacuum

filtration.

4) Calculate theoretical yield and percent yield. .

5) Dispose chemicals in a safe and responsible manner.

VII. Syllabus:

Preparation, recrystallization, and determination of melting point & yield of the

following compounds:

1) Aspirin

2) Nerolin

3) Chalcone

4) p-Nitro acetanilide

5) 2,4,6- Tribromoaniline

6) m-Dinitrobenzene

7) Phthalimide

8) Diels-Alder adduct.

VIII. Suggested Co-Curricular Activities

Mandatory:(Lab/field training of student by teacher:(lab:10+field:05):

1) For Teacher: Training of students by the teacher in laboratory and field for not
lessthan15 hours on the field techniques/skills of organic synthesis and
recrystallization of the organic compound
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

2) For Students: Student shall visit a related industry/chemistry laboratory in

universities/research organizations/private sector facility and observes the
synthetic reactions. Write their observations and submit a hand written
fieldwork/project work report not exceeding10 pages in the given format to the
teacher.

3) Max marks for Fieldwork /project work Report:05.

4) Suggested Format for Fieldwork/project work: Title page, student details, index
page, details of place visited, observations, findings and acknowledgements.

5) Unit tests(IE).

IX. Reference Books:

1) Vogel’s Textbook of Quantitative Chemical Analysis, J. Mendham, R. C. Denney,

J. D. Barnes and M. J. Thomas, 4th& 6th Ed. (Pearson Education Asia).

2) Vogel’s Textbook of Practical Organic Chemistry, B.S. Furniss, A.J. Hannaford,

P.W.G.Smith, A.R. Tatchell, 5 Ed.(Longman Scientific & Technical)
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VIII - SEMESTER
Course 22B:Chemistry of Natural Products

I. Course learning Outcomes

By the end of the course students will be able to:

Understand isolation, purification and characterization of simple chemical constituents from

the natural source

1. Learn the different types of alkaloids and their chemistry

2. To know the classification of terpenoids, isoprene rule, structures and their naturalsources.

3. Learn advanced methods of structural elucidation of compounds of natural origin

4. Understand isolation, purification, chemical constituents from the natural source

5. To know the structure characterization and synthesis of steroids

II. Syllabus:

Unit I: Alkaloids [9 hours]

Introduction, general methods for the elucidation of the structure, breaking into small
fragments,determination of structure of fragments.Type of linkage, functional nature of
oxygen,zwitter ion method to know number of –OH groups,C=O group,-COOH group –
OCH (Ziesel’s method).Detection of N atom,Detection of –N-CH group. Herzig–Meyer
3 3

method to recognize heterogeneous system.Hofmann exhaustive methylation.

Emde’sdegradation,Von-Braundegradation,reductivedegradation,Alkali
fusion,oxidation,dehydrogenation.

Unit - II:Structure and synthesis [9 hours]

1. Phenyl ethyl amine group alkaloids (adrenaline)

2. Piperedine group alkaloids(piperine)

3. Pyridine group alkaloids(coniine)

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit- III

Terpenoids [9 hours]
Isoprene rule, special isoprene rule, classification.General methods of the determination of
structure. Nature of Oxygen, number of alkyl groups (Kuhn-roth method). Unsaturation
detection, reduction (NOCl), dehydrogenation , oxidative degradation,ozonolysis, H 2O2,
Baeyer’s reagent, NaOX, HNO3, dehydration–ZnCl2, H2SO4 . Catalytic
hydrogenation,Grignard reaction, Reformatsky reaction.

Unit-IV Structure and synthesis [9 hours]

Mono terpenoids (acyclic)-Citral–structure and synthesis.Monocyclic mono terpenoids:

α -Terpeniol, Menthol, Limonine –Structure and Synthesis

Unit-V

Steroids [9 hours]
Occurrence, nomenclature, basic skeleton, Diel's hydrocarbon and stereochemistry. Isolation,
structure determination and synthesis of Cholesterol (Synthesis not required), Bio Synthesis
of Steroids. Chemistry and synthesis of oestrone, progesterone, androsterone, testosterone.

III. Suggested Co-Curricular Activities

1. Training of students by related industrial experts.

2. Assignments, Seminars and Quiz (on related topics), collection ofrelevant

videos and material.

3. Visits of abilities, firms, research organizations etc.

4. Invited lectures and presentations on related topics by field/industrial experts.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

IV. Suggested Text Books:

1. Some Modern methods of Organic Synthesis W. Carithers, Cambridge University Press,

Cambridge.

2. Organic Chemistry: Stereochemistry and the Chemistry ofNatural Products.-I.L. Finar,

Pearson Education, Asia
3. Organic Chemistry, Morrison and Boyd, Pearson, 7th Edition
4. Organic Chemistry, Solmons and Fryhle, Willy Student Edition
5. Organic Chemistry a Lab Manual, Piva, Lampman, Engel. Cengage Learning India

V. References:

1. The terpenoids by Simonsen

2) The steroids by Shoppee

3) Chemistry of Carbon compounds by Rodd

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Course 22B:Chemistry of Natural Products- Practical Syllabus

VI. Learning outcomes:

By the end of the course students will be able to:

1. Separate the natural products using chromatographic techniques

2. Identify the alkaloids present in extracted natural products

3. Identify the terpenes present in plant extracts

4. Identify the steroids present in plant extracts

5. Identify the phenolic groups present in natural products

VII. Practical Syllabus

1. Separation of natural products using column chromatography

2. Identification of alkaloids in any three plant extracts

3. Identification of terpenes in any three plant extracts

4. Identification of diterpinoids in any three plant extracts

5. Identification of Steroids in any three plant extracts

6. Identification of phenolic groups in three plant extracts

VIII. Co-Curricular Activities:

Mandatory:(Lab/field training of students by teacher :(lab:10+field:05):

1. For Teacher: Training of students by the teacher in laboratory and field for not less than15
hours on the field techniques/skills of analyzingorganic compounds using spectroscopic data.

2. For Students: Student shall visit a related industry/chemistry laboratory in

universities/research organizations/private sector facility and observes the
separation of natural products obtaining spectral data and analyzing the functional

groups and type of natural product. Write their observations and submit a hand
written fieldwork/project work report not exceeding10 pages in the given format
to the teacher.
3. Max. Marks for Fieldwork/project work Report:05.
4. uggested Format for Fieldwork/project work: Title page, student details,
index page, details of place visited, observations, findings, and
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

acknowledgements.

5. Unittests(IE).

IX. References:

1) The terpenoids by Simonsen

2) The steroids by Shoppee

3) Chemistry of Carbon compounds by Rodd

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VIII - SEMESTER
Course 23A: Physical Chemistry: Quantum and Molecular Spectroscopy

I. Course Learning outcomes:

On successful completion of this course, student shall be able to:

1) Learn the basic non-relativistic quantum mechanics.

2) Understand the time-dependent and time-independent Schrödinger equation.
3) Describe the principles and theories of rotational, vibrational and vibrational
spectroscopy methods.
4) Interpret the molecular spectra and find molecular properties from molecular
spectra.

Syllabus:

Unit – I Basic Quantum Chemistry-I- : 9 Hours

Wave equation - interpretation of wave function-properties of wave function-

normalization and orthogonalisation, Operators- linear and non-linear- commutators of
operators. Postulates of quantum mechanics; setting up of operators to observables;
Hermitian operator- Eigen values and Eigen functions of Hermitian operator; Expansion
theorems. Eigen functions of commuting operators-significance. Simultaneous
measurement of properties and the uncertainty principle.

UNIT-II Basic Quantum Chemistry-II- : 9 Hours

Wave mechanics of simple systems with constant potential energy, particle in one
dimensional box- factors influencing color transition- dipole integral, Symmetry
arguments in deriving the selection rules, the concept of tunneling- particle in three -
dimensional box. Calculations using wave functions of the particle in a box-
Orthogonality, measurability of energy, position and momentum, average values and
probabilities. Rigid rotor, Wave mechanics of systems with variable potential energy-
simple harmonic oscillator- solution of wave equation- selection rules.

UNIT-III Fundamentals of Molecular Spectroscopy-I: 9 Hours

Microwave and IR- Spectroscopy- Rotational spectra of diatomic molecules - Rigid rotor
- Selection rules- Calculations of bond length- Isotopic effect, Second order stark effect
and its applications. Infrared spectra of diatomic molecules- harmonic and anharmonic
oscillators - Selection rules- Overtones- Combination bands- Calculation of force
constant, anharmonicity constant and zero point energy. Fermi resonance,
simultaneous vibrational - rotational spectra ofdiatomic molecules.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

UNIT- IV. Fundamentals of Molecular Spectroscopy - II : 9Hours

Raman and Electronic Spectra- Classical and quantum mechanical explanations-

Rotational Ramanand Vibrational Raman spectra. Electronic spectra of
diatomicmolecules- Vibrational Coarse structure- intensities of spectral lines- Franck-
Condon principle- applications, Rotational Fine structure- band headand band shading.
Charge transfer spectra.

UNIT- V Introduction to computer programming- FORTRAN 77: 9 Hours

Basic structures and functioning of computer with P.C. as an illustrative example- Main
memory- Secondary storage memory- input/output devices- computer languages-
operating systems- principles of algorithms-and flow charts-constants and variables-
Arithmetic expressions- Arithmetic statements-Replacement statement- IF statement-
logical IF and BLOCK IF statements- GOTO statements-subscripted variable and
DIMENSION statement. DO statement- Rules for DO statement- Functions and
subroutines- Development of FORTRAN statements for simple formulae in chemistry
such as Vander Waals equation- pH of a solution- First order rate equation- Cell constant-
Electrode potential. Flow charts and computer programs for Program for the calculation of
Cell Constant, Specific Conductance and Equivalence. Rate Constant of First order
reaction or Beer’s law by linear least square method. Hydrogen ion concentration of a
strong acid solution/Quadratic equation. Solution for Vander Waals equation or Hydrogen
ion concentration of a monoprotic weak acid Standard deviation and Variance of
univariant data.

II. Suggested Co – curricular activities :

1) Training of students by related industrial experts.
2) Assignments, Seminars and Quiz (on related topics), collection of relevant videos
and material.

3) Visits to laboratories, firms, research organizations etc.

4) Invited lectures and presentations on related topics by field/industrial experts

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

III. List of Text books:

1) Fundamentals of Molecular spectroscopy: by C.N. Banwell

2) Molecular spectroscopy: by B.K.Sharma

3) Molecular spectroscopy: by Aruldas

4) Introductory quantum mechanics: by A.K. Chandra

IV. Reference books:

1) Quantum chemistry: by R.K. Prasad

2) Principles of computer programming(FORTRAN 77 IBM PC): by V.Rajaraman

3) Basics of computers for chemists: by P.C. Jurs

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Course 23A: PHYSICAL CHEMISTRY PRACTICALS –II

V. Learning Outcomes:

On successful completion of this practical course, student shall be able to:

1) List out, identify and handle various equipment in Chemistry lab.
2) Learn and apply the concepts of electro chemistry in experiments.
3) Be familiar with electro analytical methods and techniques which study an analyte
by measuring the potential (volts) and / or current (amperes) in an electro chemical
cell containing the analyte.
4) Learn the procedures of preparation of standard solutions.
5) Acquire skills in operation and calibration of instruments.

VI. Syllabus:

1) Titration of mixture Strong acid and weak acid versus Strong base by
conductometry.

2) Titration of Strong acid Vs Strong Base – pH – metry.

3) Titration of mixture of (NaHCO3 + Na2CO3) Vs HCl – pH- metry.

4) Titration of Strong acid Vs Strong Base using Quinhydrone electrode.

5) Titration of Fe+2Vs K2Cr2O7 – potentiometry

6) Verification of Beer-Lambert’s law by Iron- thiocyanate system –colorimetry.

7) Determination of single electrode potential of Cu2+/Cu and estimate the given

unknown concentration.

VII. Suggested Co- Curricular Activities

Mandatory:(Lab/fieldtrainingofstudentsbyteacher:(lab:10+field:05):
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

1. For Teacher: Training of students by the teacher in laboratory and field for not
lessthan15 hours on the field techniques/skills of handling the pHmetry,
potentiometry and colorimetry. .

2. For Students: Student shall visit a related industry/chemistry laboratory in

universities/research organizations/private sector facility and observes the
synthetic reactions. Write their observations and submit a hand written field work

/project work report not exceeding10 pages in the given format to the teacher.

3. Max marks for Field work/project work Report:05.

4. Suggested Format for Fieldwork/project work: Title page, student details, index
page, details of place visited, observations, findings and acknowledgements.

5. Unit tests(IE).

VIII. Reference books:

1. Vogel’s Text Book of Quantitative Chemical Analysis, J. Mendham, R. C.

Denney, J. D. Barnes and M. J. Thomas, 4th& 6th Ed. (Pearson Education Asia).
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VIII - SEMESTER

Course 23B: Analytical Methods of Analysis

I. Learning Outcomes:

By the end of this course, students will be able to:

1· Perform experiment with accuracy and precision.

2· Develop methods of analysis for different samples independently.

3· Test contaminated water samples.

4· Understand basic principle of instrument like Flame Photometer, UV-vis

spectrophotometer.

5· Learn separation of analytes by chromatography.

6· Apply knowledge of geometrical isomers and keto-enoltautomers to analysis.

7· Determine composition of soil.

8· Estimate macronutrients using Flame photometry.

II. Syllabus:

Unit 1:Qualitative and quantitative aspects of analysis:9h

Sampling, evaluation of analytical data, errors, accuracy and precision, methods of their
expression.Normal law of distribution of indeterminate errors, statistical test of data; F, Q
and t test, rejection of data,and confidence intervals.

Unit 2:Optical methods of analysis 9h

Origin of spectra, interaction of radiation with matter, fundamental laws of spectroscopy

and selectionRules.

UV-Visible Spectrometry: Basic principles of instrumentation (choice of source,

monochromator and detector) for single and double beam instrument; Transmittance.
Absorbance and Beer-Lambert lawBasic principles of quantitative analysis: estimation of
metal ions from aqueous solution, geometricalisomers, keto-enoltautomers. Flame Atomic
Absorption and Emission Spectrometry: Basic principles of instrumentation (choice of
source, monochromator, detector, choice of flame and Burner designs). Techniques of
atomization and sample introduction; Method of background correction, sources of
chemical interferences and their method of removal, Techniques for the quantitative
estimation of trace level of metal ions fromwater samples.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit 3:Thermal methods of analysis: 9 h

Theory of thermogravimetry (TG) and basic principle of instrumentation of thermal

analyser.Techniquesfor quantitative estimation of Ca and Mg from their mixture.

Unit 4:Electroanalyticalmethods 9 h

Classification of electro-analytical methods, basic principle of pH metric, potentiometric

andconductometric titrations.Techniques used for the determination of equivalence points.
Techniques usedfor the determination of pKa values.

Unit5:Separation techniques9 h

Solvent extraction: Classification, principle and efficiency of the technique. Mechanism of

extraction: extraction by salvation and chelation, Technique of extraction:
batch,continuous and counter current extractions, Qualitative and quantitative aspects of
solvent extraction:extraction of metal ions from aqueous solution, extraction of organic
species from the aqueous and non aqueous media.

Chromatography: Classification, principle and efficiency of the technique, Mechanism of

separation:adsorption, partition & ion-exchange.

III. Suggested Co-Curricular Activities

1. Training of students by related industrial experts.

2. Assignments, Seminars and Quiz (on related topics), collection of

relevant videos and material.

3. Visits of abilities, firms, research organizations etc.

4. Invited lectures and presentations on related topics by field/industrial experts.

IV. Suggested Text Books:

1. Willard, H.H.(1988),Instrumental Methods of Analysis, 7th Edition, Wardsworth

Publishing Company.

2. Christian, G.D.(2004),Analytical Chemistry, 6th Edition, John Wiley & Sons, New
York.

3. Harris, D. C.(2007),Quantitative Chemical Analysis,6th Edition, Freeman.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V. References:

1. Khopkar, S.M. (2008), Basic Concepts of Analytical Chemistry, New Age

International Publisher.

2. Skoog, D.A.; Holler F.J.; Nieman, T.A. (2005), Principles of Instrumental Analysis,

Thomson Asia Pvt. Ltd.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Course 23B: Analytical Methods of Analysis- Practical Syllabus

VI. Learning Outcomes

By the end of the course students will be able to

1. Separate ions using chromatography

2. Identify the ion by comparing Rf values with the literature

3. Analyze soil parameters

4. Verify Beer Lamberts law

5. Determine the carbonate and bicarbonate using pH

VII. Practical Syllabus

1. Separation of mixtures by paper chromatography and reporting the Rf values of Co 2+

and Ni2+.

2. Separation of mixtures by paper chromatography and reporting the Rf values of Amino

acids present in the given mixture

3. To separate a mixture of Ni2+& Fe2+ by complexation with DMG and extracting the
Ni2+ DMG complex in chloroform, and determine its concentration by spectrophotometry

4. Analysis of soil:

(i) Determination of pH of soil.

(ii) Estimation of calcium and magnesium

(iii) Qualitative detection of nitrate and phosphate

5. Verification of Lambert-Beer’s law and determination of concentration of a coloured
species (CuSO4, KMnO4)

6. Determination of carbonate- and bicarbonate in a mixture using pHmetry

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VIII. Co-Curricular Activities:

Mandatory:(Lab/field training of students by teacher :(lab:10+field:05):

1. For Teacher: Training of students by the teacher in laboratory and field for
not less than15 hours on the field techniques/skills of estimating the quality of
soil.

2. For Students: Student shall visit a related industry/chemistry laboratory in

universities/research organizations/private sector facility and observes various
measured parameters of soil analysis. Write their observations and submit a
hand written fieldwork/project work report not exceeding 10 pages in the given
format to the teacher.

3. Max. Marks for Fieldwork/project work Report:05.

4. Suggested Format for Fieldwork/project work: Title page, student

details, index page, details of place visited, observations, findings, and
acknowledgements.

5. Unittests(IE).

IX. References:

1. Jeffery, G.H.; Bassett, J.; Mendham, J.; Denney, R.C.(1989),Vogel’s Textbook of

QuantitativeChemical Analysis,John Wiley and Sons.

2. Analytical Chemistry by Gary D. Christian 6th Edition John Wiley &Sons Inc New
York 1994.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VIII - SEMESTER

Skill Enhancement courses

Course 24A: Pharmaceutical and Medicinal Chemistry

I. Learning Outcomes:

n successful completion of this practical course, student shall be able to:

1) Know the Terminology in Pharmaceutical chemistry.

2) Describe the classification of Pharmaceutical chemistry

3) Learn the procedure for Synthesis and therapeutic activity of thecompounds.

4) Acquire knowledge on Pharmacodynamics and Anesthetics Drugs

5) Gain knowledge on HIV-AIDS and Drugs.

II. Syllabus:

UNIT-I Pharmaceutical chemistry 9 hours

Terminology: Pharmacy, Pharmacology, Pharmacophore, Pharmacodynamics,

Pharmacokinetics (ADME, Receptors - brief treatment), Metabolites and Anti
metabolites. Nomenclature: Chemical name, Generic name and trade names with
examples.

UNIT-II Classification of Drugs 9 hours

Classification based on structures and therapeutic activity with one example each,
Administration of drugs. Absorption of drugs - factors affecting absorption of drugs,

routes of administration - local, enema, oral and external, parental routes - advantages and
disadvantages.

UNIT-III Synthesis and therapeutic activity of the compounds: 9hours

a. Chemo theraputic Drugs : l.Sulpha drugs (Sulpha methoxazole) 2.Antibiotics - β-

Lactam Antibiotics, MacrolideAntibiotics, 3. Anti malarial Drugs(chloroquine)

b. Psychotherapeutic Drugs: 1.Anti pyrectics (Paracetamol) 2.Hypnotics, 3.Tranquilizers

(Diazepam) 4.Levodopa
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

UNIT-IV Pharmacodynamics and Anesthetics Drugs: 9hours

1) Antiasthma Drugs (Salbutamol)

2) Antianginals (Glyceryl trinitrate)

3) Diuretics (Furosemide)

4) Anesthetics - general - ether, chloroform, ethyl chloride, halothane, nitrousoxide,

local -esters - cocaine, benzococaine.

UNIT-V HIV-AIDS: 9 hours

Immunity - CD-4cells, CD-8cells, Retro virus, Replication in human body, Investigation

available, prevention of AIDS, Drugs available - examples with structures: PIS: Indinavir
(crixivan), Nelfinavir (Viracept), AZT- Zidovudine.

III. Suggested Co-Curricular Activities:

1) Training of students by related industrial experts.

2) Assignments, Seminars and Quiz (on related topics), collection of relevantvideos

andmaterial.

3) Visits of related Industries/firms, research organizations etc.

4) Invited lectures and presentations on related topics by field/industrial experts.

IV. List of text Books:

1) Synthetic Drugs by O.D.Tyagi & M.Yadav3.Medicinal Chemistry by Ashutoshkar

2) Medicinal Chemistry by P.Parimoo

3) Pharmacology& Pharmacotherapeutics R.S Satoshkar & S.D.Bhandenkar

4) Reference Books:

5) Medicinal Chemistry by Dr. B.V.Ramana

6) Synthetic Drugs by O.D.Tyagi & M.Yadav3.Medicinal Chemistry by Ashutoshkar

7) Medicinal Chemistry by P.Parimoo

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V.
1) Pharmacology& Pharmacotherapeutics R.S Satoshkar & S.D.Bhandenkar

2) Medicinal Chemistry by Kadametal P-I &P.II

3) European Pharmacopoeia.

Course 24A. Pharmaceutical and Medicinal Chemistry- Practical Syllabus

Skill Enhancement course

VI. Learning Outcomes:

On successful completion of this practical course, student shall be able to:

1) Learn the procedure for the synthesis of drugs.

2) Synthesis of Drugs Assisted by Microwave Oven

3) Acquire skills in Drawing structure and Reaction using Chemdraw

4) Know the reactions and mechanisms involved in synthesis of Drugs.

VII. Laboratory course Syllabus

1) Synthesis of Sulphanilamide

2) Synthesis of 7- Hydroxy -4- methyl coumarin

3) Synthesis of Chlorobutanol

4) Synthesis of Tolbutamide 07

5) Assay of Chlorpheniramine Maleate

6) Assay of Benzyl Penicillin 2
7) Synthesis of Aspirin Assisted by Microwave Oven
8) Drawing structure and Reaction using Chemdraw
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VIII. List of Reference books:

1) Wilson and Giswold’s Organic medicinal and Pharmaceutical Chemistry.

2) Foye’s Principles of Medicinal Chemistry.

3) Burger’s Medicinal Chemistry, Vol I to IV.

4) Introduction to principles of drug design- Smith and Williams.

5) Remington’s Pharmaceutical Sciences.

6) Martindale’s extra pharmacopoeia.

7) Organic Chemistry by I.L. Finar, Vol. II.

8) The Organic Chemistry of Drug Synthesis by Lednicer, Vol. 1-5.

9) Text book of practical organic chemistry- A.I.Vogel.

IX. Suggested Co-Curricular Activities

Mandatory:(Lab /field training of students by teacher:(lab: 10+field:05):

1) For Teacher: Training of students by the teacher in laboratory and field for not less
than15 hours on the field techniques/skills of comprehensive product development
programs to meet new product criteria and timing. Acquire skills in the preparation of
drugs and pharmaceuticals, learn the procedure of synthesis of drugs with good yield.

2) For Students: Student shall visit a related industry/chemistry laboratory in

universities/research organizations/private sector facility and observes the preparation
of Cosmeceuticals and Pharmaceutical. Write their observations and submit a hand
written fieldwork/project work report notexceeding10 pages in the given format to the

teacher.
3) Max marks for Fieldwork/project work Report: 05.
4) Suggested Format for Fieldwork/project work: Title page, student details, index page,
details of place visited, observations, findings, and acknowledgements.

5) Unit tests (IE).

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

X. Reference books:

1) The Organic Chemistry of Drug Synthesis by Lednicer, Vol. 1-5.

2) Text book of practical organic chemistry- A.I.Vogel.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VIII – SEMESTER
Skill Enhancement course

Course-24B. Pesticides and Green Chemistry

I. LearningOutcomes:

On completion of this course,the student will be able to

1. Understand the basic knowledge of pesticides and their classification.

2. Explain the synthetic methods of pesticides.

3. Acquire knowledge about the different types of pesticide formulations and their use.

4. Explain conceptsin green chemistry.

5. State and explain the principles of green chemistry.

6. Identify the need of green chemistry and green synthesis.

7. Think to design and develop materials and processes that reduce the use and generation
of hazardous substances in industry.

II. Syllabus

Unit-I Pesticides 9h

Introduction to pesticides, advantages and disadvantages of pesticides, types of

pesticides–Insecticides, Fungicides, Herbicides, Weedicides, Rodenticides plant growth
regulators, Pheromones and Hormones. Brief discussion with examples, Structure and
uses.

Unit-II Pesticides Synthesis 9h

Synthesis and uses of representative pesticides in the following classes: Organochlorines

(DDT,Gammexene); Organophosphates (Malathion, Parathion); Carbamates (Carbofuran
and carbaryl);Quinones(Chloranil); Anilides (Alachlor andButachlor).

Unit-III PesticideFormulations 9h

Dust and Granules, Wettable powders, seed disinfectant, Surfactants, Emulsifiable

concentrates, Aerosols, Sprays, and Controlled ReleaseFormulations.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit-IV GreenChemistry 9h

Introduction: Definition of green Chemistry, need of green chemistry, twelve principles

of GreenChemistry with their explanations and examples; Green Synthesis-Maximum
utilization ofreactantsandreagents(atomeconomy).Selection
ofsolvent:Aqueousphasereactions,Reactionsin ionic liquids, Solid supported synthesis,
Solvent free reactions (solid phase reactions), andGreencatalysts:Phasetransfer
catalysts(PTC) and Biocatalysts.

Unit-V Green Synthesis 9h

Green Synthesis of the following compounds: Styrene, Adipic Acid,Catechol, BHT,

Methyl Methacrylate, Urethane,4-amino dipheny lamine, benzyl bromide,
Acetaldehyde, Furfural, Ibuprofen,Paracetamol,Citral.

III. Suggested Co-Curricular Activities

1. Training of students by related industrial experts.

2. Assignments, Seminars and Quiz (on related topics), collection of relevant videosand
material.

3. Visits of related Industries/firms, research organizations etc.

4. Invited lectures and presentations on related topics byfield/industrial experts.

IV. TEXT BOOKS

1. Industrial chemistry byB.K.Sharma. GoelPublishingHouse,Meerut.

2. E.Stocchi:Industrial Chemistry,Vol-I,EllisHorwoodLtd.UK.

3. Chemistry of pesticidesbyN.K.Roy

4. R.Cremlyn:Pesticides,JohnWiley.

5. V.K.Ahluwalia&M.R.Kidwai:NewTrendsinGreenChemistry,AnamalayaPublishers(200

6. P.T. Anastes& J.K. Warmer: Oxford Green Chemistry- Theory and Practical,
UniversityPress(1998).

7. A.S.Matlack: IntroductiontoGreenChemistry,MarcelDeckkar(2001).
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V. References Books:

1. Fundamentals of industrial chemistry–pharmaceuticals, polymers and business by

JohnA.Tyrell.

2. Riegel's Hand book of Industrial Chemistry ninth edition Edited byJamesA.Kent.

3. E.Stocchi:Industrial Chemistry,Vol-I,EllisHorwoodLtd.UK.

4. Chemistry of pesticides byN.K.Roy

5. R.Cremlyn:Pesticides,JohnWiley.

6. PesticidesFormulations–VanWade.Velkenburg,1973.

7. PesticidesSynthesis–Mavy,Kohn,Menn,1979.

8. Kirchoff,M.&Ryan,M.A.Greenerapproachestoundergraduatechemistryexperiment.Amer
icanChemical Society, Washington DC (2002).
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Course-24B: Pesticides and Green Chemistry-Practical Syllabus:

Skill Enhancement course

VI. Laboratory-Skills Outcomes:

On successful completion of this practical course, student shall be able to:

1. List out, identify and handle various equipment in the laboratory.

2. Learn the procedures of green synthesis.

3. Acquire skills in Microwave assisted organic synthesis.

4. Perform some applications of green synthesis.

VI. Practical Laboratory)Syllabus

The list of suggestive experiments is given below. However, depending upon available
resources, any three experiments may be conducted)

1. Benzoin condensation using Thiamine Hydrochloride as acatalyst(instead of cyanide).

2. Formation of Chalcones–A Greener Alternative.

3. Preparation of Salicylic Acid(Aspirin)by Microwave Assisted Method.

4. Green Synthetic Process for Acetanilide.

5. Green Synthetic Process for Dibenzal Propanone.

6. Green Synthetic Process for trans esterification of vegetable oil to crude bio-diesel.

VII. Recommended Books / References:

1. Anastas,P.T&Warner,J.C.GreenChemistry:TheoryandPractice,OxfordUniversityPress(1
998).

2. Kirchoff,M.&Ryan,M.A.Greenerapproachestoundergraduatechemistryexperiment.Ame
rican Chemical Society, Washington DC (2002).
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

3. Ryan,M.A.IntroductiontoGreenChemistry,Tinnesand;(Ed),AmericanChemicalSociety,
Washington DC (2002).

4. Sharma,R.K.;Sidhwani,I.T.andChaudhari,M.K.I.K.GreenChemistryExperiment:Amono
graph,International Publishing ISBN 978-93-81141-55-7 (2013).

5. Cann,M.C.andConnelly,M.E.RealworldcasesinGreenChemistry,AmericanChemicalSoci
ety (2008). UGC DOCUMENT ON LOCFCHEMISTRY 83

6. Cann,M.C.andThomas,P.RealworldcasesinGreenChemistry,AmericanChemicalSociety

(2008).

7. Lancaster,M.GreenChemistry:AnIntroductoryTextRSCPublishing,SecondEdition,2010.

8. Pavia,D.L.,Lampman,G.M.,Kriz,G.S.&Engel,R.G.IntroductiontoOrganicLaboratoryTec
hniques: AMicroscale and Macro Scale Approach, W. B. Saunders, 1995.

IX. Co-CurricularActivities

a. Mandatory:(Lab/fieldtrainingofstudentsbyteacher:(lab:10+field:05):

1. For Teacher: Training of students by the teacher in laboratory and field for not
lessthan15 hours on the field techniques/skills of comprehensive product development
programs to meet new product criteria and timing. Acquire skills in the preparation of
Cosmeceuticals and Pharmaceutical drugs, Carry out perfume testing with the
knowledge of perfumes and learn the procedure of synthesis of drugs.

2. ForStudents:Studentshallvisitarelatedindustry/chemistrylaboratoryinuniversities/resear
ch organizations/private sector facility and observes the preparation of Cosmeceuticals
and Pharmaceutical. Write their observations and submit a hand written
fieldwork/project workreportnotexceeding10 pages in the given format to the teacher.

a) Max marks for Field work/project work Report:05.

b) Suggested Format for Fieldwork/project work: Title page, student details,

index page, details of place visited, observations, findings and
acknowledgements.

c) Unit tests(IE).
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VIII - SEMESTER
Skill Enhancement course

Course-25A:Corrosion and Its Prevention

I. Learning Outcomes:

1. This course will create awareness of corrosion and its control process

2. It focuses on protective metallic coatings for prevention of corrosion

3. It focuses on protective coatings of materials.

4. It covers about the insulating materials in electric industries and also aware about
semiconductors.

II. Syllabus:

Unit-I: Corrosion 9h

Introduction - Economic aspects of corrosion - Dry or Chemical Corrosion - Wet or

electrochemical corrosion - Mechanism of Electrochemical Corrosion. Galvanic Corrosion -
Concentration Cell Corrosion - Differential aeration corrosion – Pitting Corrosion-
Underground or soil corrosion-Passivity.

Unit-II: CorrosionandItsControl 9h

Factors Influencing Corrosion - Microbiological Corrosion, Atmospheric corrosion –

Corrosion Control-Proper designing –Using pure metal-Using metal alloys.

Chemical conversion – Coating - Phosphating - Chromising - Treatment of metal surfaces hot

dipping-Use of inhibitors.

Unit-III: ProtectiveCoatings 9h

Introduction-Metallic Coatings-Various methods of cleaning articles before electrod eposition

– Electroplate and -Electroplating methods.

Pre-treatment of the surface–Metallic Coatings-Hot Dipping-Cementation or Impregnated

Coatings-Sprayed Metal Coatings-Cladding–Vapour Deposition.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit-IV Paints 9h

Paints-ingredients and their functions, required properties of aPaint-Paint Constituents and

their Functions-Manufacture of Paint.

Types of Pigments-Characteristics of pigment-Oils-Uses in Paint Emulsion Paints–Special

Paints-Paint Remover Varnishes.

Unit-V: Insulators and Semiconductor 9h

Electrical Insulating Materials-Dielectric properties-Requirements of an Electrical Insulating

Material-Classification of insulating material-Electrical Rigid Insulations.

Semiconductors-Introduction-Classification–Degenerate semiconductors–Superconductors.

III. Suggested Co-Curricular Activities

1. Training of students by related industrial experts.

2. Assignments, Seminars and Quiz (on related topics), collection of relevant videos and
material.

3. Visits of related Industries/firms, research organizations etc.

4. Invited lectures and presentations on related topics by field/industrial experts.

IV. Text Books

1. M.G.Fontana:Corrosion Engineering, McGrawHillInternationalBookCo. London.

2. L.L. Shreir: Corrosion, Vol I and Vol II, Newness Butterworths, EdwardArnoldLtd,
London.

3. J.C.Scully:Fundamental of Corrosion,PergamonPressInc.NewYork, USA.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

V. References Books:

1. M.G.Fontana:Corrosion Engineering,McGraw Hill InternationalBookCo. London.

2. L.L. Shreir: Corrosion, Vol I and Vol II, Newness Butterworths, EdwardArnoldLtd,
London.

3. J.C.Scully:Fundamental of Corrosion,PergamonPressInc.NewYork, USA.

4. V.S.Sastry:Corrosion Inhibitors,Principles&Applications,JohnWiley&Sons.

5. C.C.Nathan:Corrosion Inhibitors,NACE,Houston,Texas.

6. Corrosion-Causes and Prevention:Speller.F. N.

7. Material Science mini refresher byH.S.Bawa, TatapublisherIndia.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Course 25A:Corrosion and its Prevention-Practical Syllabus:

Skill Enhancement course

VI. Learning Outcomes:

On successful completion of this practical course, student shall be able

to:

1. Chalk out a plan to decrease the rate of corrosion.

2. Preparation of pigment.

3. To study about the Rate of corrosion with respect to Aluminium and Iron
plates

4. To determine the effect of Temperature on rate of corrosion

Practical(Laboratory)Syllabus:

5. Electroless metallic coatings on ceramic and plastic material.

6. Preparation of pigment (zincoxide)

7. To determine the rate of corrosionon different metallic plates

(Iron,Aluminium) in various Concentrations of HCl.

8. To determine the effect of temperature on rate of corrosion in acidic medium.

9. To determine the rate of corrosion on a metallic plate in acidic medium.

10. To determine the rate of corrosion on an Aluminium plate in basicmedium.

VII. LabReferences:

1. Analytical ChemistrybyGaryD.Christian 6th edition Wileypublication.

2. Senior Practical Physical Chemistry, B.D.Khosla, V.C.Garg, Adarsh

Gulati, RChandandCo.

3. Applied Chemistry Theory and Practice, O.P.Virani, A.K.Nebula.

NewAge InternationalPublishers,2nd Edition.

4. S.W.Rajbhoj andT.K.Chondhekar,SystematicExperimentalPhysical
Chemistry,Anjali Publication,Second Edition 2000.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

5. SunitaRattan,ExperimentsinAppliedChemistry,S.K.Kataria&Sons,Secondedition,
2008

6. Khosla,B.D.;Garg,V.C.&Gulati,A.SeniorPracticalPhysicalChemistry,R.C
hand &Co.:NewDelhi (2011).

7. UGC practical manual for experimental analysis.

VIII. Cocurricular Activities:

a) Mandatory:(Lab/fieldtrainingofstudentsbyteacher:(lab:10+fields:05):

1. ForTeacher: Training of students byt he teacher in laboratory and field for

not less than15hours on the field techniques/skills of corrosion formation
observations in nature.

2. For Students: Student shall visit a related industry/chemistry laboratory in

universities/research organizations/private sector facility and observes
corrosion process and its prevention. Write their observations and submit a

hand written fieldwork/project work report notexceeding10 pages in the given

format to the teacher. And also observe the semiconductors, insulators used in
industry.

a. Max marks for Fieldwork/projectworkReport:05.

b. Suggested FormatforFieldwork/projectwork: Title page,

student details, index page,details of place visited,
observations, findings and acknowledgements.

C. Unit tests(IE).
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

VIII - SEMESTER
Skill Enhancement course

Course 25B: Material & Energy Balances and Utilities in Chemical Industry

I. Learning Outcomes:

At the end of the course student will be able to

1. Describe the distinction between Atomic weight, Molecular weight and Equivalent
Weight.

2. Write down the flow diagrams for chemical engineering operations.CO3

3. Describe the capacities of gases and gaseous mixtures.

4. Write down water treatment procedures for industrial use.

5. Describe the types of boilers.

6. Demonstrate knowledge acquired in steam generation.

7. Write down compressors and blowers.

8. Classify pumps based on their function.

II. Syllabus:

Unit-I 9h

Dimensions and units: Basic Chemical Calculations -Atomic weight, molecular weight,
equivalent weight, Mole, composition of(i) Liquid mixtures and (ii)gaseous mixtures. Ideal
gas law, vapor pressure, Humidity and Saturation.

Unit-II 9h

Material Balance without Chemical Reactions: Flow diagram for material balance, simple
material balance with or without recycle or by-pass for chemical engineering operations such
as distillation, absorption, crystallization, evaporation and extraction.

Material Balance involving chemical reactions: concept of limiting reactant, conversion,

yield, selectivity and liquid phase reaction, gas phase reaction with o rwith out recycleor by
pass.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Unit-III 9h

Energy Balance:Heat capacity of pure gases and gaseous mixtures at constant pressures,
sensible heat changes in liquids, Enthalpy changes during phase transformation: Enthalpy of

fusion, Enthalpy of vaporization,

Enthalpy of condensation, Enthalpy of sublimation, Hess’s law of constant, Heat Summation

and its applications

Unit-IV 9h

Utilities in Chemical Industry

a) Boilers:Types of boilers and their functioning

b) Water: Specifications of industrial use,various water treatments.

c) Steam:Generation and use.

d) Air:Specification of industrial use,process ingofair

Unit-V 9h

Fluid flow and Pumps

Fluid flow: Fans, blowers, compressors, vacuum pump, ejectors.

Pumps: Reciprocating pumps, Gear pumps, centrifugal pumps.

III. Suggested Co-Curricular Activities

1. Training of students by related industrial experts.

2. Assignments, Seminars and Quiz (on related topics), collection of relevant videosand
material.

3. Visits of related Industries/firms, research organizations etc.

4. Invited lectures and presentations on related topics by field/industrial experts.

 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

IV. Text Books:

1. E.Stocchi:IndustrialChemistry,Vol-I,EllisHorwoodLtd.UK

2. R. M. Felder, R. W. Rousseau: Elementary Principles of Chemical Processes,

WileyPublishers,NewDelhi.

3. P.C.Jain,M.Jain:EngineeringChemistry,DhanpatRai&Sons,Delhi.

4. B.K.Sharma:EngineeringChemistry,GoelPublishingHouse,Meerut

V. ReferenceBooks:

1. B.I. Bhatt and S.M. Vora: Stoichiometry, Tata McGraw-Hill publishing Company
Ltd,NewDelhi.

2. E.Stocchi:IndustrialChemistry,Vol-I,EllisHorwoodLtd.UK

3. R. M. Felder, R. W. Rousseau: Elementary Principles of Chemical Processes,

WileyPublishers,NewDelhi.

4. J.A.Kent:Riegel’sHandbookofIndustrialChemistry,CBSPublishers,NewDelhi.

5. P.C.Jain,M.Jain:EngineeringChemistry,DhanpatRai&Sons,Delhi.

6. R. Gopalan, D. Venkappayya, S. Nagarajan: Engineering Chemistry, Vikas

Publications,NewDelhi.

7. B.K.Sharma:EngineeringChemistry,GoelPublishingHouse,Meerut

8. S.C.Bhatia: ChemicalProcessIndustries,Vol.I&II,CBSPublishers,NewDelhi.

9. W. L. McCabe and J. C.Smith: Unit Operations in Chemical Engineering, Mc-Graw

HillBook Company,NewYork.

10. O. P. Vermani, A. K. Narula: Industrial Chemistry, GalgotiaPublicationsPvt. Ltd.,

NewDelhi.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

Course 25B: Material & Energy Balances and Utilities in Chemical Industry-
Practical Syllabus

Skill Enhancement course

VI. Learning Outcomes

At the end of the course student will be able to

1. Carry out the Quantitative analysis of calcium in lime stone.

2. Determine the hardness of given water sample using EDTA.
3. DetermineCODand BODofagiven watersample.

4. FindoutthePercentageofavailablechlorinepresentin thebleachingpowder.

VII. PracticalSyllabus

1. Quantitative analysis of calcium in limestone by complexometric titration.

2. Hardness of water by EDTA titration.

3. Determination of Chemical Oxygen Demand(COD)

4. Determination of Biological Oxygen Demand(BOD)

5. Percentage of available chlorine in bleaching powder

VIII. Reference Books:

1. 4.J.A.Kent:Riegel’sHandbookofIndustrialChemistry,CBSPublishers,NewDelhi.

2. 5.P.C.Jain,M.Jain:EngineeringChemistry,DhanpatRai&Sons,Delhi.

3. 6.R. Gopalan, D. Venkappayya, S. Nagarajan: Engineering Chemistry, Vikas

Publications,NewDelhi.

4. 7.B.K.Sharma:EngineeringChemistry,GoelPublishingHouse,Meerut

5. 8.S.C.Bhatia: ChemicalProcessIndustries,Vol.I&II,CBSPublishers,NewDelhi.
 ADIKAVI NANNAYA UNIVERSITY: RAJMAHENDRAVARAM
Single Major B.Sc Chemistry (w.e.f:2023-24A.B)

IX. Co-CurricularActivities:

a). Mandatory:

1. For Teacher: Training of students by the teacher in laboratory and field for
not lessthan15 hours on the field techniques/skills of detection of N, S and
halogens using thegreen procedure, preparation of TLC plates, detection of
organic compounds using
RfvaluesinTLC/paperchromatography,loadingofcolumn,selectionofsolvents
ystem for column chromatography, separation of amino acids and dye
mixture using chromatographic techniques.

2. For Students: Student shall visit a related industry/ chemistry laboratory in

universities/research organizations/private sector facility and observes the

synthetic reactions. Write their observations and submit a hand written

fieldwork/project workreportnotexceeding10 pages in the given format to
the teacher.

a. Max marks for Field work/projectworkReport:05.

b. Suggested Format for Fieldwork/project work: Title page,

student details, index page,details of place visited, observations,
findings and acknowledgements.

c. Unit tests(IE).