Fergusson College (Autonomous)
Pune
Learning Outcomes-Based Curriculum
for F. Y. B. Sc. Chemistry
With effect from June 2019
1
Programme Structure
Year Course
SEM Course Title Credits
Code
F. Y. B. Sc. Chemical Mathematics & Atomic
CHE1101 2
Structure
I Basics of Organic Chemistry &
CHE1102 2
Periodicity of Elements
CHE1103 Chemistry Practical - I 2
CHE1201 Ionic Equilibrium & Chemical Bonding 2
Stereochemistry, Hydrocarbons & Mole
II CHE1202 2
Concept
CHE1203 Chemistry Practical - II 2
S. Y. B. Sc. Chemical Kinetics and Quantitative
CHE2301 3
Analysis of Organic Compounds
Reaction Mechanism and Principles of
III CHE2302 3
Metallurgy
Inorganic and Analytical Chemistry
CHE2303 2
Practicals
Thermodynamics and Volumetric
CHE2401 3
Analysis
Introduction of Biomolecules and
IV CHE2402 3
Coordination Chemistry
Physical and Organic Chemistry
CHE2403 2
Practicals
T. Y. B. Sc. CHE3501 Physical Chemistry I 3
CHE3502 Inorganic Chemistry I 3
V CHE3503 Organic Chemistry I 3
CHE3504 Analytical Chemistry I 3
CHE3505 Nuclear Chemistry I 3
OR
CHE3506 Biochemistry I 3
CHE3507 Industrial Chemistry I 3
V
CHE3511 Physical Practicals I 2
CHE3512 Inorganic Practicals I 2
CHE3513 Organic Practicals I 2
2
CHE3601 Physical Chemistry I 3
CHE3602 Inorganic Chemistry I 3
CHE3603 Organic Chemistry I 3
CHE3604 Analytical Chemistry I 3
CHE3605 Nuclear Chemistry I 3
T. Y. B. Sc. VI OR
CHE3606 Biochemistry I 3
CHE3607 Industrial Chemistry I 3
CHE3611 Physical Practicals I 2
CHE3612 Inorganic Practicals I 2
CHE3613 Organic Practicals I 2
3
Programme Learning Outcomes
PO1 Acquire coherent understanding of fundamental concepts in chemistry to integrate inter-
disciplinary science subjects.
PO2 Acquire communication skills to effectively transmit the acquired information in written
and oral formats.
PO3 Gain the sense of ethical, social and environmental awareness and responsibility.
PO4 Acquire basic computer knowledge for computation and interpretations of scientific data.
PO5 Demonstrate rational thinking to design experimental protocols to analyze and solve the
issues of agriculture, pharmaceutical, food, cosmetic, environmental monitoring industries
etc.
PO6 Acquire confidence, patience, time management, leadership and intangible skills to achieve
the goals.
PO7 Demonstrate appropriate laboratory and instrumentation skills to design, conduct and
interpret experimental outcomes with scientific, analytic reasoning.
PO8 Practice safe laboratory methods to curtail the chemical hazards.
PO9 Embrace reduce, recycle and restore chemicals (3R’s) approach.
PO10 Undertake competitive examinations for higher learning courses in chemistry to meet global
competencies.
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Class: F. Y. B. Sc.
Course code: CHE1101
Title: Chemical Mathematics & Atomic Structure
Course Outcomes Suggested Pedagogical Processes
1. Understand the significance of logarithm and 1. Problem solving sessions on logarithm,
learn and apply the plotting of graph, integration, differentiation.
derivatives and integration in chemical 2. Discussion of different types of graph using
studies. laboratory examples.
2. Understand the basic concepts of states of 3. Use of ICT tools.
matter, gas laws, kinetic gas equation, ideal 4. Use of diagram charts, models
and non- ideal gases and Van der Waals 5. Quiz and seminar
equation to study the behavior of gases. 6. Demonstration of apparatus (Viscometer,
3. Understand the factors affecting the different Stalagmometer)
physical properties of liquid such as vapour 7. Lecture method and models.
pressure, surface tension and viscosity 8. Problem solving sessions.
4. Know the classical and quantum mechanical
approach to understand the atomic structure.
UNIT I Chemical Mathematics 6 Lectures
1.1. Logarithm - Rules of logarithm, Characteristic and mantissa,
Change of sign and base, Problems based on pH and pOH.
Graphical representation of Equations-Rules for drawing graph
co-ordinates etc., Equation of straight line, slope and intercept,
plotting the graph from the data of chemical properties and
problems.
1.2. Derivative - Rules of differentiation and partial differentiation,
Algebraic, logarithmic and exponential functions and problems.
1.3. Integration- Rules of integration, Algebraic and exponential
functions and problems.
UNIT II Gaseous State 12 Lectures
2.1 Kinetic molecular model of a gas, postulates and derivation of
the kinetic gas equation, collision frequency, collision diameter;
mean free path, Maxwell distribution and its use in evaluating
molecular velocities (average, root mean square and most
probable) and average kinetic energy.
2.2 Law of equipartition of energy, degrees of freedom and
molecular basis of heat capacities, Behaviour of real gases,
Deviations from ideal gas behaviour, compressibility factor, Z,
and its variation with pressure for different gases, Causes of
deviation from ideal gas behaviour,
2.3 van der Waals equation of state, its derivation, van der Waals
equation expressed in virial form and calculation of Boyle
temperature.
2.4 Isotherms of real gases and their comparison with van der Waals
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isotherms.
UNIT III Liquid State 6 Lectures
3.1 Qualitative treatment of the structure of the liquid state, physical
properties of liquids, vapour pressure, surface tension and
coefficient of viscosity and their determination, Effect of
addition of various solutes on the surface tension and viscosity.
3.2 Explanation of cleansing action of detergents, temperature
variation of viscosity of liquids and comparison with that of
gases, qualitative discussion of structure of water.
UNIT IV Atomic Structure 12 Lectures
4.1 Rutherford atomic model, electromagnetic spectrum, Bohr’s
theory, its limitations and atomic spectrum of hydrogen atom, de
Broglie equation, Heisenberg’s Uncertainty.
4.2 Principle and its significance, Schrödinger’s wave equation
(derivation not required), significance of ψ and ψ2, quantum
numbers and their significance, normalized and orthogonal wave
functions, sign of wave functions.
4.3 Radial and angular wave functions for hydrogen atom, radial and
angular distribution curves, shapes of s, p, d and f orbitals,
Pauli’s Exclusion principle, Hund’s rule of maximum
multiplicity, Aufbau’s principle and its limitations, variation of
orbital energy with atomic number.
Learning Resources
1. Principles of PhysicalChemistry by Maron and Prutton, 1992.
2. Castellan, G. W. Physical Chemistry 4th Ed. Narosa, 2004.
3. Mortimer, R. G. Physical Chemistry 3rd Ed. Elsevier: NOIDA, UP, 200.
4. Engel, T. & Reid, P. Physical Chemistry 3rd Ed. Pearson, 2013.
5. Essentials of physical chemistry Bhal, Tuli and S. Chand, 2010.
6. J.D. Lee Concise Inorganic Chemistry: Fifth Edition, Wiley, 2008.
7. Bodie Douglas and DarlMcdanielConcepts and Models of Inorganic Chemistry Third Edition,
Wiley, 1983.
8. Duward Shriver, P. W. Atkins Inorganic Chemistry, Fifth Edition, Oxford University Press,
2002.
9. Donald A. Tarr, Gary Miessler Inorganic Chemistry Third Edition, Pearson, 2013.
10. A. Bahl, B. S. Bahl, and G.D. Tuli, Essentials of Physical Chemistry, S. Chand and Co Pvt Ltd
2014. (pages 1-96 for Atomic Structure)
6
Course code: CHE1102
Title: Basics of Organic Chemistry & Periodicity of Elements
Course Learning Outcome Suggested Pedagogical Processes
1. Understand the basic concepts of the organic 1. Lecture method and 3D models.
chemistry including covalent bonding and 2. Use of ICT tools.
properties, organic acid-base and factors 3. Quiz and seminar.
affecting strength of acids and bases. 4. Mind mapping techniques and concept
2. Understand the mechanism of reactions with charts.
alkanes, alkenes and alkynes. 5. Problem solvingsessions.
3. Understand the trend in the periodic table
with reference to atomic and ionic size,
electron gain enthalpy, ionization enthalpy.
4. Understand the effect of nuclear charge on
shielding and screening effect in atoms.
UNIT I Basics of Organic Chemistry 13 Lectures
1.1 Organic Compounds: Covalent bond, hybridization, shapes of
molecules, influence of hybridization on bond properties, inter and
intra molecular hydrogen bonding.
1.2 Electronic Displacements: Inductive, resonance and mesomeric
effects, hyper conjugation, tautomerism and their applications,
dipole moment, organic acids and bases, their relative strength,
strength of acids and bases, pKa and pKb values of common organic
acids and bases.
1.3 Homolytic and heterolytic fission with suitable examples, curly
arrow rules, formal charges; electrophiles and nucleophiles
nucleophlicity and basicity, types, shape and their relative stability
of carbocations, carbanions, free radicals and carbenes. Introduction
to types of organic reactions and their mechanism, addition,
elimination, substitution and rearrangement reactions.
UNIT II Chemistry of Hydrocarbons 9 Lectures
2.1 Introduction to Hydrocarbons, Classification of hydrocarbons (up to
aromatic hydrocarbons).
2.2 Alkanes: IUPAC nomenclature, formation of alkanes, Wurtz
reaction, Wurtz-Fittig reactions, free radical substitutions:
Halogenation-relative reactivity and selectivity.
2.3 Alkenes: IUPAC nomenclature, formation of alkenes by elimination
reactions, mechanism of E1, E2, E1cb reactions, Saytzeff and
Hofmann eliminations, Reactions of alkenes: Electrophilic additions
their mechanisms (Markownikoff/Anti Markownikoff addition),
mechanism of oxymercuration-demercuration,
hydroborationoxidation, ozonolysis, reduction (catalytic and
chemical), syn and anti-hydroxylation (oxidation), 1, 2 and 1, 4
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addition reactions in conjugated dienes, Diels-Alder reaction, allylic
and benzylic bromination and mechanism, e.g. propene, 1-butene,
toluene, ethylbenzene and their industrial application of
hydrocarbons.
2.4 Alkynes: IUPAC nomenclature, acidity, electrophilic and
nucleophilic additions, hydration to form carbonyl compounds,
alkylation of terminal alkynes.
UNIT III Research in India in the field of Chemistry 2 Lectures
3.1 Introduction to Premier Indian Research Institutes in Chemistry,
ShantiswaroopBhatnagar awardees in last 5 years in Chemistry.
UNIT IV Periodicity of Elements 12 Lectures
4.1 Long form of periodic table, s, p, d, f block elements, Classification
of elements, electronic configuration, detailed discussion of the
following properties of the elements with reference to s and p-block.
4.2 Effective nuclear charge, shielding or screening effect, Slater rules,
variation of effective nuclear charge in periodic table.
4.3 Atomic and ionic radii.
4.4 Ionization enthalpy, Successive ionization enthalpies and factors
affecting ionization enthalpy and trends in groups and periods.
Applications of ionization enthalpy.
4.5 Electron gain enthalpy (Electron affinity) and trends in groups and
periods.
4.6 Electro-negativity, Pauling’s scale. Variation of electro-negativity
with bond order and hybridization.
Learning resources
1. Clayden, J., Greeves, N., & Warren, S. G. Organic chemistry. Oxford: Oxford University
Press, 2012.
2. Morrison, R. N. & Boyd, R. N. Organic Chemistry, 6th Edition, (Pearson Education), 1992.
3. Finar, I. L. Organic Chemistry (Volume 1), Dorling Kindersley (India) Pvt. Ltd. (Pearson
Education), 1964.
4. McMurry, J.E. Fundamentals of Organic Chemistry, 7th Ed. Cengage Learning India
Edition, 2013.
5. J. D. Lee Concise Inorganic Chemistry: Fifth Edition, Wiley, 2007.
6. Bodie Douglas and DarlMcdaniel Concepts and Models of Inorganic Chemistry Third
Edition, Wiley,1994.
7. Duward Shriver, P. W. Atkins Inorganic Chemistry, Fifth Edition, Oxford University Press,
2002.
8. Donald A. Tarr, Gary Messler Inorganic Chemistry Third Edition, Pearson, 2013.
9. F. Albert Cotton and Geoffrey Wilkinson Advanced Inorganic Chemistry, Sixth Edition,
2013.
8
Course code: CHE1103
Title: Chemistry Practical - I
Course Learning Outcome Suggested Pedagogical Processes
1. Acquire the skills for qualitative analysis of 1. Demonstration of experiments.
organic, inorganic compounds and the 2. Use of ICT tools.
purification techniques. 3. Quiz and seminar.
2. Apply safe laboratory practices, skillfulness 4. Practice sessions.
and self-confidence in the lab.
UNIT I Laboratory Safety 1 Practical
UNIT II Organic Chemistry Practicals 5 Practicals
1.1 Purification of Organic Compound by
1.1.1 Crystallization Method by using different solvents
(two compounds)
1.1.2 Distillation (Demonstration)
1.1.3 Sublimation Method (one compound)
1.2 Qualitative analysis / characterization of organic compound
containing C, H, (O), N, S elements (no element test)
1.3 Separation of a mixture of ortho and para nitrophenol OR
ortho and para nitroaniline by thin layer chromatography
(TLC).
1.4 Use of ChemDraw Software
UNIT III Inorganic Chemistry Practicals [Any FIVE Mixtures without 5 Practicals
Phosphate & Borate]
2.1 Semi-micro inorganic qualitative analysis of binary mixture
containing two cations and two anions.
Learning Resources:
1. Khosla, B.D.; Garg, V. C. and Gulati Senior practical physical chemistry, R. Chand & Co.:
New Delhi, 2011.
2. Garland, C. W.; Nibler, J.W. and shoemaker, D. P Experiments in physical chemistry 8th
Ed. McGraw-Hill: New work, 2003.
3. Mendham, J., A. I. Vogel’s Qualitative Organic Chemical Analysis 6th Ed., Pearson, 2009.
4. Mann, F.G. & Saunders, B.C. Practical Organic Chemistry, Pearson Education, 2009.
5. Furniss, B.S.; Hannaford, A.J.; Smith, P.W.G.; Tatchell, A.R. Practical Organic Chemistry,
5th Ed., Pearson, 2012.
6. Vogel’s Qualitative Inorganic Analysis 7th Edn, Revised by G Svehla, Pearson 2009.
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Course code: CHE1201
Title: Ionic Equilibrium & Chemical Bonding
Course Learning Outcome Suggested Pedagogical Processes
1. Understand the crystal structures with the 1. Discussion of different types of graph using
help of various parameters. laboratory examples.
2. Understand the theories of strong 2. Lecture method and models.
eletrolytes, factors influencing degree of 3. Use of ICT tools.
dissociation and application of solubility 4. Use of diagram charts, models.
product and ionic product in qualitative 5. Quiz and seminar.
analysis. 6. Demonstration of apparatus (Landsberger’s
3. Apply the colligative properties: lowering apparatus).
of vapour pressure, elevation of boiling 7. Problem solving sessions.
point and depression in freezing pointto
determine the molecular mass.
4. Understand the fundamental concepts and
theories of bondingand their application to
justify the shape and geometry of inorganic
molecules.
UNIT I Solid State 10 Lectures
1.1 Nature of the solid state, law of constancy of interfacial angles,
law of rational indices, Miller indices, elementary ideas of
symmetry, symmetry elements and symmetry operations.
1.2 Qualitative idea of point and space groups, seven crystal systems
and Bravais lattices, X-ray diffraction, Bragg’s law, a simple
account of rotating crystal method and powder pattern method.
1.3 Analysis of powder diffraction patterns of NaCl, CsCl and KCl.
Relation between radius and edge, packing fraction and density of
crystal.
UNIT II Ionic Equilibrium 6 Lectures
2.1 Ostwald dilution law, verification, limitations. Theory of strong
electrolyte, Debye-Huckel theory, degree of dissociation,
common ion effect, factors which influence degree of
dissociation.
2.2 Solubility equilibria, solubility product and ionic product and its
application in qualitative analysis.
UNIT III Theory of dilute solutions: Colligative Properties 8 Lectures
3.1 Colligative properties, lowering of vapour pressure,
measurement of lowering of Vapour pressure, boiling point
elevation, measurement of elevation of boiling point by
Landsberger ‘s method, depression in freezing point method,
Beckmann’s method, Osmotic Pressure.
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3.2 Application of colligative properties to determine molecular
weight of non-electrolyte, abnormal molecular weight, Relation
between Vant Hoff’s factor and degree of dissociation of
electrolyte by colligative property and numerical.
UNIT IV Chemical Bonding 12 Lectures
4.1 Electronic theory of valence, attainment of stable configuration,
Types of bonds – ionic, covalent, coordinate, metallic bonds -
qualitative idea. Types of overlaps: s-s, s-p, p-p, p-d, d-d and
their examples.
4.2 Ionic bond: General characteristics, types of ions, size effects,
radius ratio rule and its limitations. Packing of ions in crystals.
Born-Landé equation with derivation. Born-Haber cycle and its
application, solvation energy.
4.3 Covalent bond: Lewis structure, Valence Bond Theory (Heitler-
London approach). Pauling-Slater Theory. Concept of
hybridization, equivalent and non-equivalent hybrid orbitals.
Types of hybridization involving s, p, & d orbitals, hybridization
geometries in the molecules like i) BeF2 ii) BF3 iii) [MnCl4]2- iv)
[Ni(CN)4]2-v) Fe(CO)5 vi) [Cr(H2O)6]2+, vii) IF7.
4.4 Formal charge, Valence shell electron pair repulsion theory
(VSEPR), shapes of simple molecules and ions containing lone
pairs and bond pairs of electrons: H2O, NH3, PCl5, PCl6-, SF6,
SO42-, ClF3, Cl2O, BrF5, I3-, BrF2+, TeCl4, XeO3.
Learning Resources
1. Principles of Physical Chemistry by Maron and Prutto, 1992.
2. Castellan, G. W. Physical Chemistry 4th Ed. Narosa, 2004.
3. Mortimer, R. G. Physical Chemistry 3rd Ed. Elsevier: NOIDA, UP, 2000.
4. Engel, T. & Reid, P. Physical Chemistry 3rd Ed. Pearson, 2013.
5. Essentials of physical chemistry Bhal, Tuli and S. Chand, 2010
6. Fundamentals of Analytical Chemistry, Skoog, West and Haller, 1963.
7. J. D. Lee Concise Inorganic Chemistry: Fifth Edition, Wiley, 2008.
8. Bodie Douglas and DarlMcdaniel Concepts and Models of Inorganic Chemistry Third
Edition, Wiley, 1983.
9. Duward Shriver, P. W. Atkins Inorganic Chemistry, Fifth Edition, Oxford University Press
2002.
10. Donald A. Tarr, Gary Miessler Inorganic Chemistry Third Edition, Pearson, 2013.
11. F. Albert Cotton and Geoffrey Wilkinson Advanced Inorganic Chemistry, Sixth
Edition2013.
12. A. Bahl, B. S. Bahl, and G.D. Tuli, Essentials of Physical Chemistry, S. Chand and Co Pvt
Ltd 2014. (pages 172-207 for Chemical Bonding).
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Course code: CHE1202
Title: Stereochemistry, Hydrocarbons & Mole Concept
Course Learning Outcome Suggested Pedagogical Processes
1. Understand the 3D structure of organic 1. Lecture method and 3D models.
molecules, chirality,optical isomerism,R/S 2. Use of ICT tools.
and E/Z configuration. 3. Quiz and seminar.
2. Understand the mechanism of aromatic 4. Mind mapping techniques and concept chart
electrophilic substitution reactions. 5. Problem solving sessions
3. Understand the concept of mole, molarity,
normality, equivalent weight, standard
solutions including standardization and its
applications in quantitative analysis.
4. Learn the balancing of redox reaction by ion
electron method.
UNIT I Stereochemistry 12 Lectures
1.1 Introduction to isomerism and its classification. Fischer Projection,
Newmann and Sawhorse Projection formulae and their inter
conversions. Conformational isomerism in alkanes (Ethane,
propane and n-butane) with energy profile diagrams, Geometrical
isomerism Geometrical isomerism: cis–trans and, syn-anti
isomerism E/Z notations with C.I.P rules.
1.2 Optical isomerism: Optical activity, specific rotation,
chirality/asymmetry, enantiomers, molecules with two or more
chiral-centres, distereoisomers, meso structures, racemic mixture
and resolution, relative and absolute configuration, D/L, R/S and
E/Z designations.
UNIT II Aromatic Hydrocarbons (10 L) 10 Lectures
2.1 Aromaticity: Hückel’s rule, aromatic character of arenes,
homocyclic and polycyclic aromatic hydrocarbons (benzene,
naphthalene, anthracene), cyclic carbocations/carbanions and
heterocyclic compounds with suitable examples (Pyrrole, furan,
thiophene, pyridine and its basicity) with their relevance to industry.
2.2 Electrophilic aromatic substitution: Reactions of benzene,
naphthalene and anthracene sulphonation, nitration, halogenation,
Friedle Craft alkylation/acylation reactions, with their mechanis.
2.3 Directing effects of the groups. Industrial application of aromatic
hydrocarbons.
UNIT III Recent Trends in Chemistry 2 Lectures
3.1 Introduction to research journals in chemistry, search Engine like
Sci-Finder, Google Scholar, C on CD, Reaxis, Nobel Prize winners in
Chemistry in last five years.
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UNIT IV Mole Concept (12 L) 12 Lectures
1.1 Mole concept – GMV relationship, problems based on mole
concept, methods of expressing concentrations, strength,
normality, molarity, molality, %w/v, %v/v, ppm, standardization
of solutions, primary and secondary standard substances,
preparation of standard solution of acids and bases, problems
related to acid base titration. Principles involved in volumetric
analysis (from practical experiments) to be carried out.
1.2 Oxidation and Reduction – Definitions of related terms, oxidizing
and Reducing agents, Oxidation number, Rules to assign oxidation
number. Balancing redox reactions by ion-electron method (both
acidic and alkaline medium), Problem based on equivalent weight
of oxidants and reductants. Standard Electrode Potential and its
application to redox reactions.
Learning Resources
1. Clayden, J., Greeves, N., & Warren, S. G. (2012). Organic chemistry. Oxford: Oxford
University Press, 2012.
2. Morrison, R. N. & Boyd, R. N. Organic Chemistry, 6th Edition, (Pearson Education), 1992.
3. Eliel, E. L. &Wilen, S. H. Stereochemistry of Organic Compounds, Wiley: London, 1994.
4. Kalsi, P. S. Stereochemistry Conformation and Mechanism, New Age International, 2005.
5. Mc Murry, J.E. Fundamentals of Organic Chemistry, 7th Ed. Cengage Learning India
Edition, 2013.
6. J. D. Lee Concise Inorganic Chemistry: Fifth Edition, Wiley, 2007.
7. Bodie Douglas and DarlMcdaniel Concepts and Models of Inorganic Chemistry Third
Edition, Wiley, 1994.
8. Duward Shriver, P. W. Atkins Inorganic Chemistry, Fifth Edition, Oxford University Press,
2002.
9. Donald A. Tarr, Gary Miessler Inorganic Chemistry Third Edition, Pearson, 2013.
10. F. Albert Cotton and Geoffrey Wilkinson Advanced Inorganic Chemistry, Sixth Edition,
1962.
11. Sarin and Sarin Numerical problems in Chemistry, 1980.
13
Course code: CHE1203
Title: Chemistry Practical - II
Course Learning Outcome Suggested Pedagogical Processes
1. Understand the concepts andcalculations of heat of 1. Demonstration of experiments.
solution of KNO3, universal gas constant ‘R’ by 2. Use of ICT tools.
Eudiometric method, 3. Quiz and seminar.
2. Learn to calculate the dissociation constant of weak 4. Practice sessions.
acid by pH metry and apply the data to study the
least square fitting method.
3. Understand the relative viscosity of given organic
liquids by Ostwald viscometer.
4. Able to visualize the shapes of s and p orbitals,
using polar plots.
5. Understand the quantitative estimations by
volumetric and gravimetric methods.
UNIT I Physical Chemistry Practicals (Any FIVE): 5 Practicals
1.1 Polar plots of s, pzorbitals
1.2 Relative viscosity of given organic liquids by viscometer
1.3 Molar gas constants (R)in different units by eudiometric method.
1.4 Interpretation of powder diffraction pattern of 1:1 salts.
1.5 Dissociation constant of a weak acid by pH metry.
1.6 To determine molecular weight of solute by depression in
freezing point method. Naphthalene – Sulphur.
1.7 To determine molecular weight of given electrolyte (KCl) and
on-electrolyte (Urea) by Landberger’s method and to study
abnormal molecular weight of electrolyte.
1.8 Scientific graphing of following functions using MS-Excel
1.8.1 exponential
1.8.2 logarithmic
1.8.3 linear
1.9 Determination of rate constant of acid catalyzed ester hydrolysis.
1.10 Heat of solution of potassium nitrate in water.
UNIT II Analytical Chemistry Practicals (Any FIVE) 5 Practicals
2.1 Cleaning and Maintenance of apparatus and instruments.
Calibration of apparatus:
1.1.1 Burette
1.1.2 Pipette
1.1.3 Volumetric flask
1.1.4 Thermometers (1/10th, 1100C and 3600C)
2.2 Preparation standard solution of 0.05N oxalic acid(exact) and
standardization and determination of strength of given 0.05N
(approx) KMnO4 solution using two burette method.
2.3 Determination of acetic acid in vinegar by titrimetric method.
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2.4 Determination of percentage composition of ZnO and ZnCO3 in
the given mixture gravimetrically.
2.5 Estimation of hydroxide/sulphate and carbonate present together
in mixture.
2.6 Estimation of Fe(II) by using standardized 0.05N (approx)
KMnO4 solution.
Estimation of the amount of Mg (II) present in the given solution
complexometrically.
Learning Resources
1. Khosla, B.D., Garg, V. C. and Gulati Senior Practical Physical Chemistry, R. Chand & Co.:
New Delhi, 2011.
2. Garland, C. W. Nibler, J.W. and Shoemaker, D. P. Experiments in Physical Chemistry, 8th
Ed. McGrawHill, New York, 2003.
3. Mendham, J., Vogel’s Quantitative Chemical Analysis 6th Ed., Pearson, 2008.
4. Mann, F.G. & Saunders, B.C. Practical Organic Chemistry, Pearson Education,2009.
5. Furniss, B.S.; Hannaford, A.J.; Smith, P.W.G.; Tatchell, A.R. Practical Organic Chemistry,
5th Ed., Pearson, 2012.
15
