Material Safety Data Sheet

FuelClear™ M15 Fuel Biocide

Safety Data Sheet according to Reg. (EU) No 2015/830 Version: 4.2
Revision Date: 18/09/23
Print Date: 18/09/23

Fuelcare Limited encourages and expects you to read and understand the entire MSDS, as there is important information throughout
the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other
appropriate methods or actions.

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier

Product name: FuelClear™ M15 Fuel Biocide

1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses: Biocidal product.

1.3 Details of the supplier of the safety data sheet

COMPANY IDENTIFICATION
Fuelcare Limited
Mercury House
Shrewsbury Business Park
Shrewsbury
SY2 6LG
UNITED KINGDOM

Customer Information Number: +44 (0)1743 360784

Customer Information Email: info@fuelcare.com

1.4 EMERGENCY TELEPHONE NUMBER

In Europe, Middle East, Africa and Asia Pacific 24 hour / 7 day emergency
response for our products is provided by the NCEC CARECHEM 24 global
network.

Country information Emergency telephone number Location

Europe, Middle East, Africa (all countries, English Language) +44 1865 407333 London, UK
Asia Pacific (all countries, English Language) +65 3165 2217 Singapore

The information contained in this document is provided free of charge and is based on technical data that Fuelcare believes to be reliable. It is intended for use by persons having technical
skill and at their own discretion and risk. Fuelcare accepts no liability for any loss, damage or expense arising from, or in connection with, the use of the information. Furthermore, none of
the contents of this publication should be taken as a license to operate under any patent, nor as a recommendation to infringe any patent. USE BIOCIDES SAFELY. ALWAYS READ THE
LABEL AND PRODUCT INFORMATION BEFORE USE. FOR PROFESSIONAL USERS ONLY.

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 Material Safety Data Sheet

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008:

Skin corrosion - Sub-category 1C - H314

Serious eye damage - Category 1 - H318
Skin sensitisation - Category 1 - H317
Short-term (acute) aquatic hazard - Category 1 - H400
Long-term (chronic) aquatic hazard - Category 1 - H410
For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008:

Hazard pictograms

Signal word: DANGER

Hazard statements
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 +P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately
call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P391 Collect spillage.

Supplemental information Corrosive to the respiratory tract.

Restricted to professional users.
EUH071
NOT FOR AVIATION FUEL.

The information contained in this document is provided free of charge and is based on technical data that Fuelcare believes to be reliable. It is intended for use by persons having technical
skill and at their own discretion and risk. Fuelcare accepts no liability for any loss, damage or expense arising from, or in connection with, the use of the information. Furthermore, none of
the contents of this publication should be taken as a license to operate under any patent, nor as a recommendation to infringe any patent. USE BIOCIDES SAFELY. ALWAYS READ THE
LABEL AND PRODUCT INFORMATION BEFORE USE. FOR PROFESSIONAL USERS ONLY.

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 Material Safety Data Sheet

Contains mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-

isothiazol-3-one [EC no. 220-239-6] (3:1)

2.3 Other hazards

Endocrine disrupting properties (human health):

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article
57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

Endocrine disrupting properties (environment):

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article
57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

PBT and vPvB assessment:

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very
persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures
This product is a mixture.

CASRN / EC-No. / REACH Registration Concentration Component Classification:

Index-No. Number REGULATION (EC) No
1272/2008

CASRN 01-2119491164-38 >= 1.0 - < 10.0 % Magnesium dinitrate Ox. Sol. 3 - H272
10377-60-3
EC-No.
233-826-7
Index-No.
–

CASRN 01-2120764691-48 >= 1.0 - < 2.5 % mixture of: 5-chloro- 2- Acute Tox. - 3 - H301
55965-84-9 methyl-4- isothiazolin-3- Acute Tox. - 2 - H330
EC-No. one [EC no. 247-500-7] Acute Tox. - 2 - H310
911-418-6 and 2-methyl-2H- Skin Corr. - 1C - H314
Index-No. isothiazol-3-one [EC no. Eye Dam. - 1 - H318
613-167-00-5 220-239-6] (3:1) Skin Sens. - 1A - H317
Aquatic Acute - 1 - H400
Aquatic Chronic - 1 -

The information contained in this document is provided free of charge and is based on technical data that Fuelcare believes to be reliable. It is intended for use by persons having technical
skill and at their own discretion and risk. Fuelcare accepts no liability for any loss, damage or expense arising from, or in connection with, the use of the information. Furthermore, none of
the contents of this publication should be taken as a license to operate under any patent, nor as a recommendation to infringe any patent. USE BIOCIDES SAFELY. ALWAYS READ THE
LABEL AND PRODUCT INFORMATION BEFORE USE. FOR PROFESSIONAL USERS ONLY.

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 Material Safety Data Sheet

H410

For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures

Inhalation: Move to fresh air. Give artificial respiration if breathing has stopped. If symptoms persist, call a physician.

Skin contact: IMMEDIATELY get under a safety shower. Remove contaminated clothing. Wash off with soap and water. Immediate
medical attention is required. Wash contaminated clothing before re- use. Do not take clothing home to be laundered. Discard
contaminated shoes, belts, and other articles made of leather.

Eye contact: Rinse immediately with plenty of water for at least 15 minutes. Immediate medical attention is required.

Ingestion: Drink 1 or 2 glasses of water. IMMEDIATELY see a physician. Never give anything by mouth to an unconscious person.

4.2 Most important symptoms and effects, both acute and delayed:
Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and
special treatment needed (below), any additional important symptoms and effects are described in Section 11: Toxicology Information.

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician: MATERIAL IS SEVERELY IRRITATING. It may not be advisable to induce vomiting. Possible mucosal damage
may contraindicate the use of gastric lavage.

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing media: Use extinguishing media appropriate for surrounding fire.
Unsuitable extinguishing media: No data available

5.2 Special hazards arising from the substance or mixture

Hazardous combustion products: No data available
Unusual Fire and Explosion Hazards: Combustion generates toxic fumes of the following: hydrogen chloride Nitrogen oxides (NOx)
sulphur oxides

5.3 Advice for firefighters

Fire Fighting Procedures: Cool containers/tanks with water spray. Minimize exposure. Do not breathe fumes. Contain run-off.
Special protective equipment for firefighters: Wear self-contained breathing apparatus and protective suit.

The information contained in this document is provided free of charge and is based on technical data that Fuelcare believes to be reliable. It is intended for use by persons having technical
skill and at their own discretion and risk. Fuelcare accepts no liability for any loss, damage or expense arising from, or in connection with, the use of the information. Furthermore, none of
the contents of this publication should be taken as a license to operate under any patent, nor as a recommendation to infringe any patent. USE BIOCIDES SAFELY. ALWAYS READ THE
LABEL AND PRODUCT INFORMATION BEFORE USE. FOR PROFESSIONAL USERS ONLY.

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 Material Safety Data Sheet

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures: Wear a CEN approved (or equivalent) respirator
(with organic vapor/acid gas cartridge and a dust/mist filter) during spill clean-ups and deactivation of this material. If exposed to material
during clean-up operations, IMMEDIATELY remove all contaminated clothing and wash exposed skin areas with soap and water. See
SECTION 4, First Aid Measures, for further information.

6.2 Environmental precautions: Do not allow material to contaminate ground water system. Prevent product from entering drains.

6.3 Methods and materials for containment and cleaning up: WARNING: KEEP SPILLS AND CLEAN-UP RESIDUALS OUTOF
MUNICIPAL SEWERS AND OPEN BODIES OF WATER. Adsorb the spill with spill pillows or inert solids such as clay or vermiculite,
and transfer contaminated materials to suitable containers for disposal. Deactivate spill area with freshly prepared solution of 5% sodium
bicarbonate and 5% sodium hypochlorite in water. Apply solution to the spill area at a ratio of 10 volumes deactivation solution per
estimated volume of residual spill to deac tivate any residual active ingredient. Let stand for 30 minutes. Flush the spill area with copious
amounts of water to chemical sewer (if in accordance with local procedures, permits and regulations). DO NOT add deactivation solution
to the waste pail to deactivate the adsorbed material. See Section 13, "Disposal Considerations", for information regarding the disposal
of contained materials.

6.4 Reference to other sections: References to other sections, if applicable, have been provided in the previous sub-sections.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling: This material is a severe irritant. For personal protection see section 8. Do not handle material near
food, feed or drinking water.

7.2 Conditions for safe storage, including any incompatibilities: Keep in a well-ventilated place. The product as supplied may
evolve gas (largely carbon dioxide) slowly. To prevent the buildup of pressure the product is packaged in specially vented containers,
where necessary. Keep this product in the original container when not in use. Container must be stored and transported in an upright
position to prevent spilling the contents through the vent, where fitted. Do not store this material in containers made of the following:
steel. Do not store this material near food, feed or drinking water. CONTAINERS MAY BE HAZARDOUS WHEN EMPTY. Since emptied
containers retain product residue follow all MSDS and label warnings even after container is emptied. Expiration date based only on
retention of >95% actives during storage at 20°C -25°C (68°F -77°F).
Storage stability
Storage temperature: 1 - 55 °C

7.3 Specific end use(s): See the technical data sheet on this product for further information.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

If exposure limits exist, they are listed below. If no exposure limits are displayed, then no values are applicable.

Component Regulation Type of Listing Value/Notation

The information contained in this document is provided free of charge and is based on technical data that Fuelcare believes to be reliable. It is intended for use by persons having technical
skill and at their own discretion and risk. Fuelcare accepts no liability for any loss, damage or expense arising from, or in connection with, the use of the information. Furthermore, none of
the contents of this publication should be taken as a license to operate under any patent, nor as a recommendation to infringe any patent. USE BIOCIDES SAFELY. ALWAYS READ THE
LABEL AND PRODUCT INFORMATION BEFORE USE. FOR PROFESSIONAL USERS ONLY.

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 Material Safety Data Sheet

mixture of: 5-chloro-2- - TWA 0.075 mg/m3, as 5- chloro-2-methyl-2H- isothiazol-3-one

methyl-4-isothiazolin-3-
one [EC no. 247-500-7]
STEL 0.23 mg/m3, as 5- chloro-2-methyl-2H- isothiazol-3-one
and 2- methyl-2H -
isothiazol-3-one [EC no.
220-239-6] (3:1) TWA 1.5 mg/m3, as 2- methyl-2H-isothiazol-3- one

STEL 4.5 mg/m3, as 2- methyl-2H-isothiazol-3- one

Derived No Effect Level

Magnesium dinitrate
Workers

Acute systemic effects Acute local effects Long-term systemic effects Long-term local effects

Dermal Inhalation Dermal Inhalation Dermal Inhalation Dermal Inhalation

n.a. n.a. n.a. n.a. 20.8 mg/kg 147 mg/m3 n.a. n.a.
bw/day

Consumers

Acute systemic effects Acute local effects Long-term systemic effects Long-term local effects

Dermal Inhalation Dermal Inhalation Dermal Inhalation Dermal Inhalation

n.a. n.a. n.a. n.a. 12.5 mg/kg 43.5 mg/m3 n.a. n.a.
bw/day

Predicted No Effect Concentration

Magnesium dinitrate

Compartment PNEC

Fresh water 0.045 mg/l

Marine water 0.045 mg/l

Intermittent 4.5 mg/l

use/release

Sewage treatment 18 mg/l

The information contained in this document is provided free of charge and is based on technical data that Fuelcare believes to be reliable. It is intended for use by persons having technical
skill and at their own discretion and risk. Fuelcare accepts no liability for any loss, damage or expense arising from, or in connection with, the use of the information. Furthermore, none of
the contents of this publication should be taken as a license to operate under any patent, nor as a recommendation to infringe any patent. USE BIOCIDES SAFELY. ALWAYS READ THE
LABEL AND PRODUCT INFORMATION BEFORE USE. FOR PROFESSIONAL USERS ONLY.

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 Material Safety Data Sheet

8.2 Exposure controls

Engineering controls: Use local exhaust ventilation with a minimum capture velocity of 150 ft/min. (0.75 m/sec.) at the point of dust
or mist evolution. Refer to the current edition of "Industrial Ventilation: A Manual of Recommended Practice" published by the
American Conference of Governmental Industrial Hygienists for information on the design, installation, use, and maintenance of
exhaust systems.

Protective measures: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.

Individual protection measures

Eye/face protection: Eye protection: Use chemical splash goggles and face shield (EN166). Eye protection worn must be compatible
with respiratory protection system employed. Use chemical splash goggles and face shield (EN166).

Skin protection
Hand protection: Use chemical resistant gloves classified under Standard EN374: Protective gloves against chemicals and
micro-organisms. Examples of preferred glove barrier materials include: Butyl rubber. Ethyl vinyl alcohol laminate ("EVAL").
Examples of acceptable glove barrier materials include: Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Polyvinyl
chloride ("PVC" or "vinyl"). When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or
higher (breakthrough time greater than 240 minutes according to EN 374) is recommended. When only brief contact is
expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to EN 374) is
recommended. Glove thickness alone is not a good indicator of the level of protection a glove provides against a chemical
substance as this level of protection is also highly dependent on the specific composition of the material that the glove is
fabricated from. The thickness of the glove must, depending on model and type of material, generally be more than 0.35 mm
to offer sufficient protection for prolonged and frequent contact with the substance. As an exception to this general rule it is
known that multilayer laminate gloves may offer prolonged protection at thicknesses less than 0.35 mm. Other glove
materials with a thickness of less than 0.35 mm may offer sufficient protection when only brief contact is expected. NOTICE:
The selection of a specific glove for a particular application and duration of use in a workplace should also take into account
all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements
(cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the
instructions/specifications provided by the glove supplier.

Other protection: Wear as appropriate:

Chemical resistant apron
Complete suit protecting against chemicals

Respiratory protection: Typical use of this material does not result in workplace exposures that exceed the exposure limits listed in
the Exposure Limit Information Section. For those special workplace conditions where the listed exposure limits are exceeded, a
respiratory protection program meeting OSHA 1910.134 and ANSI Z88.2 requirements must be followed. For concentrations up to 10
times the exposure limit, wear a properly fitted NIOSH approved (or equivalent) half-mask or full facepiece air purifying respirator
equipped with organic vapor cartridges and N95 filters. If oil mist is present, use R95 or P95 filters. For those unlikely situations where
exposure may greatly exceed the listed exposure limits (i.e. greater than 10-fold), or in any emergency situation, wear a properly fitted
NIOSH approved (or equivalent) self-contained breathing apparatus in the pressure demand mode or a full facepiece airline respirator

The information contained in this document is provided free of charge and is based on technical data that Fuelcare believes to be reliable. It is intended for use by persons having technical
skill and at their own discretion and risk. Fuelcare accepts no liability for any loss, damage or expense arising from, or in connection with, the use of the information. Furthermore, none of
the contents of this publication should be taken as a license to operate under any patent, nor as a recommendation to infringe any patent. USE BIOCIDES SAFELY. ALWAYS READ THE
LABEL AND PRODUCT INFORMATION BEFORE USE. FOR PROFESSIONAL USERS ONLY.

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 Material Safety Data Sheet

in the pressure demand mode with emergency escape provision. See SECTION 6, Accidental Release Measures, for respirator and
protective clothing requirements for spill clean-up and decontamination of this material.

Environmental exposure controls

See SECTION 7: Handling and storage and SECTION 13: Disposal considerations for measures to prevent excessive environmental
exposure during use and waste disposal.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Appearance
Physical state Liquid
Colour Colourless to pale yellow clear
Odour aromatic
Odour Threshold No data available
pH 4.4
Melting point/range No data available
Freezing point <-20°C
Boiling point (760 mmHg) 229.00 °C Solvent
Flash point 138.00 °C PENSKY MARTENS CLOSED CUP
Evaporation Rate (Butyl Acetate = 1) <1.00 Water
Flammability (solid, gas) Not Applicable
Lower explosion limit No data available
Upper explosion limit No data available
Vapor Pressure 0.08 hPa solvent-like
Relative Vapor Density (air = 1) 0.6500
Relative Density (water = 1) 1.0440 at 25 °C
Water solubility completely soluble
Partition coefficient: n- octanol/water log Pow: 0.401 Measured log Pow: -0.486 Measured
Auto-ignition temperature No data available
Decomposition temperature No data available
Dynamic Viscosity 97.800 mPa.s at 25 °C
Kinematic Viscosity No data available
Explosive properties No data available
Oxidizing properties No data available

9.2 Other information

Molecular weight No data available
Percent volatility < 97.00 %

The information contained in this document is provided free of charge and is based on technical data that Fuelcare believes to be reliable. It is intended for use by persons having technical
skill and at their own discretion and risk. Fuelcare accepts no liability for any loss, damage or expense arising from, or in connection with, the use of the information. Furthermore, none of
the contents of this publication should be taken as a license to operate under any patent, nor as a recommendation to infringe any patent. USE BIOCIDES SAFELY. ALWAYS READ THE
LABEL AND PRODUCT INFORMATION BEFORE USE. FOR PROFESSIONAL USERS ONLY.

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 Material Safety Data Sheet

NOTE: The physical data presented above are typical values and should not be construed as a specification.

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity: No data available

10.2 Chemical stability: No data available

10.3 Possibility of hazardous reactions: Stable under recommended storage conditions. Product will not undergo polymerization.

10.4 Conditions to avoid: No data available

10.5 Incompatible materials: Avoid contact with the following: Oxidizing agents Amines Reducing
agents Mercaptans.

10.6 Hazardous decomposition products: Nitrogen oxides (NOx) Sulphur oxides hydrogen chloride

SECTION 11: TOXICOLOGICAL INFORMATION

Toxicological information appears in this section when such data is available.

11.1 Information on toxicological effects

Acute toxicity
Acute oral toxicity
LD50, Rat, female, 3,723 mg/kg
LD50, Rat, male, 3,600 mg/kg

Acute dermal toxicity

LD50, Rabbit, female, > 3,600 mg/kg
LD50, Rabbit, male, 3,500 mg/kg

Acute inhalation toxicity

Product test data not available. Refer to component data.

Skin corrosion/irritation
For similar material(s):
In skin corrosion/irritation test conducted in compliance with GLP standards is considered as causing severe skin irritation.

Serious eye damage/eye irritation

In eye damage/eye irritation tests conducted in compliance with GLP standards the product caused effects which were not reversible
within 21 days. Based on these observations the product is considered as causing serious damage to eyes.

Sensitization

The information contained in this document is provided free of charge and is based on technical data that Fuelcare believes to be reliable. It is intended for use by persons having technical
skill and at their own discretion and risk. Fuelcare accepts no liability for any loss, damage or expense arising from, or in connection with, the use of the information. Furthermore, none of
the contents of this publication should be taken as a license to operate under any patent, nor as a recommendation to infringe any patent. USE BIOCIDES SAFELY. ALWAYS READ THE
LABEL AND PRODUCT INFORMATION BEFORE USE. FOR PROFESSIONAL USERS ONLY.

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 Material Safety Data Sheet

Causes sensitisation.

For respiratory sensitization:

No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Product test data not available. Refer to component data.

Specific Target Organ Systemic Toxicity (Repeated Exposure)

Product test data not available. Refer to component data.

Carcinogenicity
Product test data not available. Refer to component data.

Teratogenicity
Product test data not available. Refer to component data.

Reproductive toxicity
Product test data not available. Refer to component data.

Mutagenicity
Product test data not available. Refer to component data.

Aspiration Hazard
Product test data not available. Refer to component data.

COMPONENTS INFLUENCING TOXICOLOGY:

Magnesium Dinitrate

Acute inhalation toxicity

The LC50 has not been determined.

Specific Target Organ Systemic Toxicity (Single Exposure)

Evaluation of available data suggests that this material is not an STOT-SE toxicant.

Specific Target Organ Systemic Toxicity (Repeated Exposure)

For similar material(s):
Based on available data, repeated exposures are not anticipated to cause significant adverse effects.

Carcinogenicity
No relevant data found.

The information contained in this document is provided free of charge and is based on technical data that Fuelcare believes to be reliable. It is intended for use by persons having technical
skill and at their own discretion and risk. Fuelcare accepts no liability for any loss, damage or expense arising from, or in connection with, the use of the information. Furthermore, none of
the contents of this publication should be taken as a license to operate under any patent, nor as a recommendation to infringe any patent. USE BIOCIDES SAFELY. ALWAYS READ THE
LABEL AND PRODUCT INFORMATION BEFORE USE. FOR PROFESSIONAL USERS ONLY.

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 Material Safety Data Sheet

Teratogenicity
For similar material(s):
Did not cause birth defects or other effects in the fetus even at doses which caused toxic effects in the mother.

Reproductive toxicity
For similar material(s):
In animal studies, did not interfere with reproduction.

Mutagenicity
In vitro tests did not show mutagenic effects In vivo tests did not show mutagenic effects

Aspiration Hazard
No aspiration toxicity classification

mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H - isothiazol-3-one [EC no. 220-239-6]
(3:1)
Acute inhalation toxicity
LC50, Rat, 4 Hour, dust/mist, 0.33 mg/l

Specific Target Organ Systemic Toxicity (Single Exposure)

Evaluation of available data suggests that this material is not an STOT-SE toxicant.

Specific Target Organ Systemic Toxicity (Repeated Exposure)

Excessive exposure may cause irritation to upper respiratory tract (nose and throat). Based on available data, repeated
exposures are not anticipated to cause additional significant adverse effects.

Carcinogenicity
Did not cause cancer in laboratory animals.

Teratogenicity
Did not cause birth defects or other effects in the fetus even at doses which caused toxic effects in the mother.

Reproductive toxicity
In animal studies, did not interfere with reproduction.

Mutagenicity
In vitro tests did not show mutagenic effects In vivo tests did not show mutagenic effects

Aspiration Hazard
No aspiration toxicity classification

The information contained in this document is provided free of charge and is based on technical data that Fuelcare believes to be reliable. It is intended for use by persons having technical
skill and at their own discretion and risk. Fuelcare accepts no liability for any loss, damage or expense arising from, or in connection with, the use of the information. Furthermore, none of
the contents of this publication should be taken as a license to operate under any patent, nor as a recommendation to infringe any patent. USE BIOCIDES SAFELY. ALWAYS READ THE
LABEL AND PRODUCT INFORMATION BEFORE USE. FOR PROFESSIONAL USERS ONLY.

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 Material Safety Data Sheet

11.2. Information on other hazards

Endocrine disrupting properties

The substance/mixture does not contain components considered to have endocrine disrupting properties according to
REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at
levels of 0.1% or higher.

Further information
No data available

SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicological information appears in this section when such data is available.

12.1 Toxicity

Magnesium dinitrate

Acute toxicity to fish

Not expected to be acutely toxic to aquatic organisms. For similar material(s):
LC50, Poecilia reticulata (guppy), 96 Hour, > 100 mg/l

Acute toxicity to aquatic invertebrates

For similar material(s):
EC50, Daphnia magna, 48 Hour, > 100 mg/l

Acute toxicity to algae/aquatic plants

For similar material(s):
ErC50, Algae, 72 Hour, Growth rate, > 100 mg/l

Toxicity to bacteria
Based on data from similar materials
EC50, 3 Hour, > 1,000 mg/l, OECD Test Guideline 209

mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H - isothiazol-3-one [EC no. 220-239-6]
(3:1)
Acute toxicity to fish
Material is very toxic to aquatic organisms (LC50/EC50/IC50 below 1 mg/L in the most sensitive species).
LC50, Oncorhynchus mykiss (rainbow trout), flow-through test, 96 Hour, 0.19 mg/l, OECD Test Guideline 203 or Equivalent

Acute toxicity to aquatic invertebrates

LC50, Daphnia magna (Water flea), flow-through test, 48 Hour, 0.16 mg/l, OECD Test Guideline 202 or Equivalent
EC50, Acartia tonsa, static test, 48 Hour, 0.007 mg/l

The information contained in this document is provided free of charge and is based on technical data that Fuelcare believes to be reliable. It is intended for use by persons having technical
skill and at their own discretion and risk. Fuelcare accepts no liability for any loss, damage or expense arising from, or in connection with, the use of the information. Furthermore, none of
the contents of this publication should be taken as a license to operate under any patent, nor as a recommendation to infringe any patent. USE BIOCIDES SAFELY. ALWAYS READ THE
LABEL AND PRODUCT INFORMATION BEFORE USE. FOR PROFESSIONAL USERS ONLY.

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 Material Safety Data Sheet

Acute toxicity to algae/aquatic plants

EC50, Pseudokirchneriella subcapitata (green algae), 72 Hour, 0.027 mg/l, OECD Test Guideline 201 or Equivalent
NOEC, Skeletonema costatum (marine diatom), static test, 72 Hour, Growth rate, 0.0014 mg/l
EC50, Skeletonema costatum (marine diatom), 72 Hour, 0.0063 mg/l, OECD Test Guideline 201

Chronic toxicity to fish

NOEC, Rainbow trout (Oncorhynchus mykiss), flow-through, 14 d, 0.05 mg/l NOEC, Pimephales promelas (fathead
minnow), flow-through test, 36 d, 0.02 mg/l

Chronic toxicity to aquatic invertebrates

NOEC, Daphnia magna, flow-through test, 21 d, 0.1 mg/l

12.2 Persistence and degradability

Magnesium dinitrate

Biodegradability: No relevant data found.

mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H - isothiazol-3-one [EC no. 220-239-6]
(3:1)
Biodegradability: Considered to be rapidly degradable.

Biodegradation: < 50 %
Exposure time: 10 d

Biodegradation: 62 %
Exposure time: 28 d
Method: OECD Test Guideline 301B
Photodegradation
Atmospheric half-life: 0.38 - 1.3 d

12.3 Bioaccumulative potential

Bioaccumulation: 5-Chloro-2-methyl-4-isothiazolin-3-one (CMIT): 5-Chloro-2-methyl-4- isothiazolin-3-one (MIT):

Partition coefficient: n-octanol/water(log Pow): 0.401 Measured Partition coefficient: n- octanol/water(log Pow): -
0.486 Measured

12.4 Mobility in soil

Magnesium dinitrate

The information contained in this document is provided free of charge and is based on technical data that Fuelcare believes to be reliable. It is intended for use by persons having technical
skill and at their own discretion and risk. Fuelcare accepts no liability for any loss, damage or expense arising from, or in connection with, the use of the information. Furthermore, none of
the contents of this publication should be taken as a license to operate under any patent, nor as a recommendation to infringe any patent. USE BIOCIDES SAFELY. ALWAYS READ THE
LABEL AND PRODUCT INFORMATION BEFORE USE. FOR PROFESSIONAL USERS ONLY.

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 Material Safety Data Sheet

Potential for mobility in soil is very high (Koc between 0 and 50).
Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected to be an important
fate process.
Partition coefficient (Koc): 24

mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H - isothiazol-3-one [EC no. 220-239-6]
(3:1)
Potential for mobility in soil is very high (Koc between 0 and 50).
Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected to be an important
fate process.
Partition coefficient (Koc): 28 Estimated.

12.5 Results of PBT and vPvB assessment

mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H - isothiazol-3-one [EC no. 220-239-6]
(3:1)
This substance is not considered to be persistent, bioaccumulating and toxic (PBT). This substance is not considered to be
very persistent and very bioaccumulating (vPvB).

12.6 Endocrine disrupting properties

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH
Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or
higher.

12.7 Other adverse effects

Magnesium dinitrate
This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-
239-6] (3:1)
This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods

Incinerate liquid and contaminated solids in accordance with local, state, and federal regulations.

The definitive assignment of this material to the appropriate EWC group and thus its proper EWC code will depend on the use that is
made of this material. Contact the authorized waste disposal services.

Contaminated packaging: Empty containers retain product residues. Follow label warnings even after container is emptied. Improper
disposal or reuse of this container may be dangerous and illegal. Refer to applicable federal, state and local regulations.

The information contained in this document is provided free of charge and is based on technical data that Fuelcare believes to be reliable. It is intended for use by persons having technical
skill and at their own discretion and risk. Fuelcare accepts no liability for any loss, damage or expense arising from, or in connection with, the use of the information. Furthermore, none of
the contents of this publication should be taken as a license to operate under any patent, nor as a recommendation to infringe any patent. USE BIOCIDES SAFELY. ALWAYS READ THE
LABEL AND PRODUCT INFORMATION BEFORE USE. FOR PROFESSIONAL USERS ONLY.

Registered in England No. 02385625 www.fuelcare.com VAT GB 551 5102 80 Page 14 of 15

 Material Safety Data Sheet

SECTION 14: TRANSPORT INFORMATION

Classification for ROAD and Rail transport (ADR/RID):

14.1 UN number UN 3265
14.2 UN proper shipping name CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.(Mixture of: 5-chloro-2-methyl-
2H-isothiazol-3-one and 2-methyl-2H- isothiazol-3-one (3:1))
14.3 Transport hazard class(es) 8
14.4 Packing group |||
14.5 Environmental group Mixture of: 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H- isothiazol-3-one
(3:1))
14.6 Special precautions for user Hazard Identification Number: 80

Classification for SEA transport (IMO-IMDG):

14.1 UN number UN 3265
14.2 UN proper shipping name CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.(Mixture of: 5-chloro-2-methyl-
2H-isothiazol-3-one and 2-methyl-2H- isothiazol-3-one (3:1))
14.3 Transport hazard class(es) 8
14.4 Packing group |||
14.5 Environmental group Mixture of: 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H- isothiazol-3-one
(3:1))
14.6 Special precautions for user EmS: F-A, S-B
14.7 Transport in bulk according to Consult IMO regulations before transporting ocean bulk
Annex I or II of MARPOL 73/78 and
the IBC or IGC Code

Classification for AIR transport (IATA/ICAO):

14.1 UN number UN 3265
14.2 UN proper shipping name CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.(Mixture of: 5-chloro-2-methyl-
2H-isothiazol-3-one and 2-methyl-2H- isothiazol-3-one (3:1))
14.3 Transport hazard class(es) 8
14.4 Packing group |||
14.5 Environmental group Not applicable
14.6 Special precautions for user No data available

This information is not intended to convey all specific regulatory or operational requirements/information relating to this product.
Transportation classifications may vary by container volume and may be influenced by regional or country variations in regulations.
Additional transportation system information can be obtained through an authorized sales or customer service representative. It is the
responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the
material.

The information contained in this document is provided free of charge and is based on technical data that Fuelcare believes to be reliable. It is intended for use by persons having technical
skill and at their own discretion and risk. Fuelcare accepts no liability for any loss, damage or expense arising from, or in connection with, the use of the information. Furthermore, none of
the contents of this publication should be taken as a license to operate under any patent, nor as a recommendation to infringe any patent. USE BIOCIDES SAFELY. ALWAYS READ THE
LABEL AND PRODUCT INFORMATION BEFORE USE. FOR PROFESSIONAL USERS ONLY.

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 Material Safety Data Sheet

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

REACh Regulation (EC) No 1907/2006

This product contains only components that have been either pre-registered, registered, are exempt from registration, are regarded as
registered or are not subject to registration according to Regulation (EC) No. 1907/2006 (REACH).,The aforementioned indications of
the REACH registration status are provided in good faith and believed to be accurate as of the effective date shown above. However,
no warranty, express or implied, is given. It is the buyer ś /user ś responsibility to ensure that his/her understanding of the regulatory
status of this product is correct.

Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards
involving dangerous substances.
Listed in Regulation: ENVIRONMENTAL HAZARDS
Number in Regulation: E1
100 t
200 t

Further information
Take note of Directive 94/33/EC on the protection of young people at work or stricter national regulations, where applicable.

15.2 Chemical safety assessment

No Chemical Safety Assessment has been carried out for this substance/mixture.

SECTION 16: OTHER INFORMATION

Full text of H-Statements referred to under sections 2 and 3.

H301 Toxic if swallowed.
H310 Fatal in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H330 Fatal if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

Classification and procedure used to derive the classification for mixtures according to Regulation (EC) No 1272/2008
Skin Corr. - 1C - H314 - Calculation method
Eye Dam. - 1 - H318 - Based on product data or assessment
Skin Sens. - 1 - H317 - Calculation method
Aquatic Acute - 1 - H400 - Calculation method
Aquatic Chronic - 1 - H410 - Calculation method

The information contained in this document is provided free of charge and is based on technical data that Fuelcare believes to be reliable. It is intended for use by persons having technical
skill and at their own discretion and risk. Fuelcare accepts no liability for any loss, damage or expense arising from, or in connection with, the use of the information. Furthermore, none of
the contents of this publication should be taken as a license to operate under any patent, nor as a recommendation to infringe any patent. USE BIOCIDES SAFELY. ALWAYS READ THE
LABEL AND PRODUCT INFORMATION BEFORE USE. FOR PROFESSIONAL USERS ONLY.

Registered in England No. 02385625 www.fuelcare.com VAT GB 551 5102 80 Page 16 of 15

 Material Safety Data Sheet

Revision
Identification Number: FM15 / A002 / Issue Date: 18.09.2023 / Version: 4.2

Legend
STEL Short term exposure limit
TWA Time weighted average
Acute Tox. Acute toxicity
Aquatic Acute Short-term (acute) aquatic hazard
Aquatic Chronic Long-term (chronic) aquatic hazard
Eye Dam. Serious eye damage
Skin Corr. Skin corrosion
Skin Sens. Skin sensitisation

Full text of other abbreviations

ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways; ADR - European
Agreement concerning the International Carriage of Dangerous Goods by Road; AICS - Australian Inventory of Chemical Substances;
ASTM - American Society for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regulation; Regulation
(EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation;
DSL - Domestic Substances List (Canada); ECHA - European Chemicals Agency; EC-Number - European Community number; ECx -
Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS -
Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; GHS - Globally
Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - International Air
Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk;
IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical
Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial
Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50
- Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL -
International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed (Adverse)
Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical
Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals
and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the
European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RID -
Regulations concerning the International Carriage of Dangerous Goods by Rail; SADT - Self-Accelerating Decomposition Temperature;
SDS - Safety Data Sheet; SVHC - Substance of Very High Concern; TCSI - Taiwan Chemical Substance Inventory; TRGS - Technical
Rule for Hazardous Substances; TSCA - Toxic Substances Control Act (United States); UN - United Nations; vPvB - Very Persistent
and Very Bioaccumulative

Information Source and References

This MSDS is prepared by Product Regulatory Services and Hazard Communications Groups from information supplied by internal
references within our company. Fuelcare Limited urges each customer or recipient of this MSDS to study it carefully and consult

The information contained in this document is provided free of charge and is based on technical data that Fuelcare believes to be reliable. It is intended for use by persons having technical
skill and at their own discretion and risk. Fuelcare accepts no liability for any loss, damage or expense arising from, or in connection with, the use of the information. Furthermore, none of
the contents of this publication should be taken as a license to operate under any patent, nor as a recommendation to infringe any patent. USE BIOCIDES SAFELY. ALWAYS READ THE
LABEL AND PRODUCT INFORMATION BEFORE USE. FOR PROFESSIONAL USERS ONLY.

Registered in England No. 02385625 www.fuelcare.com VAT GB 551 5102 80 Page 17 of 15

 Material Safety Data Sheet

appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this MSDS and any
hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date
shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ
between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with all federal, state, provincial or
local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under
the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due
to the proliferation of sources for information such as manufacturer-specific MSDS’s, we are not and cannot be responsible for MSDS’s
obtained from any source other than ourselves. If you have obtained an MSDS from another source or if you are not sure that the MSDS
you have is current, please contact us for the most current version.

The information contained in this document is provided free of charge and is based on technical data that Fuelcare believes to be reliable. It is intended for use by persons having technical
skill and at their own discretion and risk. Fuelcare accepts no liability for any loss, damage or expense arising from, or in connection with, the use of the information. Furthermore, none of
the contents of this publication should be taken as a license to operate under any patent, nor as a recommendation to infringe any patent. USE BIOCIDES SAFELY. ALWAYS READ THE
LABEL AND PRODUCT INFORMATION BEFORE USE. FOR PROFESSIONAL USERS ONLY.

Registered in England No. 02385625 www.fuelcare.com VAT GB 551 5102 80 Page 18 of 15