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Silicone Grease Spray SDS-3

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Namee Bekele
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0% found this document useful (0 votes)
73 views8 pages

Silicone Grease Spray SDS-3

Uploaded by

Namee Bekele
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 8

According to EC-Regulation 1907/2006 (REACH)

SAFETY DATA SHEET


SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier


Trade name
SC-4 Silicone Grease Spray
Product no.
19285
REACH registration number
Not applicable
Other means of identification

1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Lubricant

Uses advised against


-
The full text of any mentioned and identified use categories are given in section 16
1.3. Details of the supplier of the safety data sheet
Company and address
ITW Spraytec Nordic
Priorsvej 36
8600 Silkeborg
Tlf.: +45 86 82 64 44
SDS info.: www.itwinfo.dk
Contact person
Kundeservice: tlf 8682 6444
E-mail
info@itw-spraytec.dk
SDS date
31-07-2015
SDS Version
1.0
1.4. Emergency telephone number
Use your national or local emergency number
See section 4 “First aid measures”

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture


Aerosol 1; H229
Aerosol 1; H222
Skin Irrit. 2; H315
Aquatic Chronic 3; H412

See full text of H-phrases in section 2.2.


2.2. Label elements
Hazard pictogram(s)

Signal word
Danger

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Hazard statement(s)
Pressurised container: May burst if heated. (H229)
Extremely flammable aerosol. (H222)
Causes skin irritation. (H315)
Harmful to aquatic life with long lasting effects. (H412)

General -
Prevention Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. (P210).
Do not spray on an open flame or other ignition source. (P211).
Safety Do not pierce or burn, even after use. (P251).
statement(s) Use only outdoors or in a well-ventilated area. (P271).
Wear protective gloves/protective clothing. (P280).
Response -
Storage Protect from sunlight. Do no expose to temperatures exceeding 50
oC/122oF. (P410+P412).
Disposal -
Identity of the substances primarily responsible for the major health hazards
-
2.3. Other hazards
This product contains an organic solvent. Repeated exposure to organic solvents can result in damage to
the nervous system and inner organs, such as the liver and kidneys.

Additional labelling
-
Additional warnings
-
VOC
-

SECTION 3: Composition/information on ingredients

3.1/3.2. Substances/Mixtures
NAME: cyclopentane
IDENTIFICATION NOS.: CAS-no: 287-92-3 EC-no: 206-016-6 Index-no: 601-030-00-2
CONTENT: 25-40%
CLP CLASSIFICATION: Flam. Liq. 2, Aquatic Chronic 3
H225, H412
NOTE: S

NAME: Petroleum gases, liquefied (<0,1 % w/w 1,3-butadiene (EINECS No. 203-450-8))
IDENTIFICATION NOS.: CAS-no: 68476-85-7 EC-no: 270-704-2 Index-no: 649-202-00-6
CONTENT: 15-25%
CLP CLASSIFICATION: Comp. Gas, Flam. Gas 1
H220, H280

NAME: Naphtha (petroleum), hydrotreated light (<0,1 % w/w benzene (EINECS No 200-753-7)).
IDENTIFICATION NOS.: CAS-no: 64742-49-0 EC-no: 265-151-9 Index-no: 649-328-00-1
CONTENT: 15-25%
CLP CLASSIFICATION: Flam. Liq. 2, STOT SE 3, Skin Irrit. 2, Asp. Tox. 1, Aquatic Chronic 2
H225, H304, H315, H336, H411

(*) See full text of H-phrases in chapter 16. Occupational exposure limits are listed in section 8, if these are available.
S = Organic solvent
Other informations
Skin Cat. 2 Sum = Sum(Ci/S(G)CLi) = 1,5176 - 2,2764
N chronic (CAT 3) Sum = Sum(Ci/M(chronic)i*25*0.1*10^CATi) = 7,19744 - 10,79616

SECTION 4: First aid measures

4.1. Description of first aid measures


General information
In the case of accident: Contact a doctor or casualty department – take the label or this safety data sheet.
Contact a doctor, if in doubt about the injured person’s condition or if the symptoms continue. Never give

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According to EC-Regulation 1907/2006 (REACH)

an unconscious person water or similar.


Inhalation
Get the person into fresh air and stay with them.
Skin contact
Remove contaminated clothing and shoes at once. Skin that has come in contact with the material must be
washed thoroughly with water and soap. Skin cleanser can be used. DO NOT use solvents or thinners.
Eye contact
Remove contact lenses. Flush eyes immediately with plenty of water (20-30°C) for at least 15 minutes and
continue until irritation stops. Make sure you flush under the upper and lower eyelids. If irritation
continues, contact a doctor.
Ingestion
Give the person plenty to drink and stay with the person. If the person feels unwell, contact a doctor
immediately and take this safety data sheet or the label from the product with you. Do not induce vomiting
unless recommended by the doctor. Hold head facing down so that no vomit runs back into the mouth and
throat.
Burns
Rinse with water until the pain stops and continue for 30 minutes.
4.2. Most important symptoms and effects, both acute and delayed
Neurotoxic effect: This product contains organic solvents, which can have an effect on the nervous
system. Symptoms of neurotoxicity can be: loss of appetite, headache, dizziness, whistling in the ears,
tingling sensations in the skin, sensitivity to the cold, cramps, difficulty in concentrating, tiredness, etc.
Repeated exposure to solvents can result in the breaking down of the skin's natural fat layer. The skin will
then be more prone to absorb dangerous substances, e.g. allergens.
Irritation effects: This product contains substances which cause irritation to skin and eyes, or when
inhaled. Contact with locally irritative substances can cause the area of contact to be more prone to absorb
damaging substances such as allergens.
4.3. Indication of any immediate medical attention and special treatment needed
No special
Information to medics
Bring this safety data sheet.

SECTION 5: Firefighting measures

5.1. Extinguishing media


Recommended: alcohol-resistant foam, carbonic acid, powder, water mist. Water jets should not be used,
since they can spread the fire.
5.2. Special hazards arising from the substance or mixture
If the product is exposed to high temperatures, as in the case of fire, dangerous catabolic substances are
produced. These are: Carbon oxides. Fire will result in thick black smoke. Exposure to catabolic products
can damage your health. Fire fighters should use proper protection gear. Closed containers, which are
exposed to fire, should be cooled with water. Do not let fire-extinguishing water run into sewers and other
water courses.

Aerosols may explode if heated / fire.


5.3. Advice for firefighters
Wear self-contained breathing apparatus and protective clothing to prevent contact.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


Stores that have not ignited must be cooled by water mist. Where possible, remove flammable materials.
Make sure there is sufficient ventilation.
6.2. Environmental precautions
Avoid discharge to lakes, streams, sewers, etc. In the event of a leakage to the surroundings, contact the
local environmental authorities. Consider putting up waste collecting trays/basins to prevent leakage to the
surroundings.
6.3. Methods and material for containment and cleaning up
Use sand, sawdust, earth, vermiculite, diatomaceous earth to contain and collect non-combustible
absorbent materials and place in container for disposal, according to local regulations. Cleaning should be
done as far as possible using normal cleaning agents. Solvents should be avoided.
6.4. Reference to other sections
See section on “Disposal considerations ” with regard to the handling of waste. See section on 'Exposure
controls/personal protection' for protective measures.

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According to EC-Regulation 1907/2006 (REACH)

SECTION 7: Handling and storage

7.1. Precautions for safe handling


Consider putting up waste collecting trays/basins to prevent leakage to the surroundings. See section on
'Exposure controls/personal protection' for information on personal protection.
7.2. Conditions for safe storage, including any incompatibilities
Always store in containers of the same material as the original. Must be stored in a cool and ventilated
area, away from possible sources of combustion.
Storage temperature
< 50°C
7.3. Specific end use(s)
This product should only be used for applications described in Section 1.2

SECTION 8: Exposure controls/personal protection

8.1. Control parameters


OEL
Petroleum gases, liquefied (<0,1 % w/w 1,3-butadiene (EINECS... (EH40, 2005)
Long-term exposure limit (8-hour TWA reference period): 1000 ppm | 1750 mg/m3
Short-term exposure limit (15-minute reference period): 1250 ppm | 2180 mg/m3
Comments: Carc (> 0,1%butadien) (Carc = Capable of causing cancer. )

DNEL / PNEC
DNEL (Naphtha (petroleum), hydrotreated light (<0,1 % w/w benzene (EINECS No 200-753-7)).): 447 mg/m3 - Exposure: Inhalation -
Duration: Long term – Systemic effects - General population
DNEL (Naphtha (petroleum), hydrotreated light (<0,1 % w/w benzene (EINECS No 200-753-7)).): 2085 mg/m3 - Exposure: Inhalation -
Duration: Long term – Systemic effects - Workers

8.2. Exposure controls


Compliance with the stated exposure limits values should be checked on a regular basis.
General recommendations
Observe general occupational hygiene.
Exposure scenarios
If there is an appendix to this safety data sheet, the indicated exposure scenarios must be complied.
Exposure limits
Trade users are covered by the rules of the working environment legislation on maximum concentrations
for exposure. See work hygiene threshold values below.
Appropriate technical measures
Airborne gas and dust concentrations must be kept as low as possible and below the current threshold
values (see below). Use for example an exhaust system if the normal air flow in the work room is not
sufficient. Make sure that eyewash and emergency showers are clearly marked.
Hygiene measures
Whenever you take a break in using this product and when you have finished using it, all exposed areas of
the body must be washed. Always wash hands, forearms and face.
Measures to avoid environmental exposure
No specific requirements.
Individual protection measures, such as personal protective equipment

Generally
Use only CE marked protective equipment.
Respiratory Equipment

Respiratory protection is not normally required in well-ventilated areas. In case of inadequate ventilation a
respirator with filter A2 is recommended.
Skin protection

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According to EC-Regulation 1907/2006 (REACH)

Special work clothing should be used.


Hand protection
Recommended: Nitrile rubber. . See the manufacturer's instructions
Eye protection
Use face shield. Use safety glasses with a side shield as an alternative.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties


Form Colour Odour pH Viscosity Density (g/cm3)
Aerosol Clear None - - -
Phase changes
Melting point (°C) Boiling point (°C) Vapour pressure (mm Hg)
- - -
Data on fire and explosion hazards
Flashpoint (°C) Ignition (°C) Self ignition (°C)
<0 - -
Explosion limits (Vol %) Oxidizing properties
- -
Solubility
Solubility in water n-octanol/water coefficient
Insoluble -
9.2. Other information
Solubility in fat Additional information
- N/A

SECTION 10: Stability and reactivity

10.1. Reactivity
No data available
10.2. Chemical stability
The product is stable under the conditions, noted in the section on “Handling and storage”.
10.3. Possibility of hazardous reactions
No special
10.4. Conditions to avoid
Avoid static electricity.
10.5. Incompatible materials
Strong acids, strong bases, strong oxidizing agents, and strong reductants agents.
10.6. Hazardous decomposition products
The product is not degraded when used as specified in section 1.

SECTION 11: Toxicological information

11.1. Information on toxicological effects


Acute toxicity
Substance Species Test Route of exposure Result
Naphtha (petroleum), hydrotrea... Rabbit LD50 Dermal > 2000 mg/kg
Naphtha (petroleum), hydrotrea... Rat LD50 Oral > 5000 mg/kg
Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/irritation
No data available.
Respiratory or skin sensitisation
No data available.
Germ cell mutagenicity
No data available.
Carcinogenicity
No data available.
Reproductive toxicity
No data available.
STOT-single exposure
No data available.

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STOT-repeated exposure
No data available.
Aspiration hazard
No data available.
Long term effects
Neurotoxic effect: This product contains organic solvents, which can have an effect on the nervous system.
Symptoms of neurotoxicity can be: loss of appetite, headache, dizziness, whistling in the ears, tingling
sensations in the skin, sensitivity to the cold, cramps, difficulty in concentrating, tiredness, etc. Repeated
exposure to solvents can result in the breaking down of the skin's natural fat layer. The skin will then be more
prone to absorb dangerous substances, e.g. allergens.
Irritation effects: This product contains substances which cause irritation to skin and eyes, or when inhaled.
Contact with locally irritative substances can cause the area of contact to be more prone to absorb damaging
substances such as allergens.

SECTION 12: Ecological information

12.1. Toxicity
Substance Species Test Test duration Result
cyclopentane Fish LC50 96 h 100000 ug/L

12.2. Persistence and degradability


Substance Biodegradability Test Result
No data available.
12.3. Bioaccumulative potential
Substance Potential bioaccumulation LogPow BFC
No data available.
12.4. Mobility in soil
No data available
12.5. Results of PBT and vPvB assessment
No data available
12.6. Other adverse effects
This product contains ecotoxic substances which can have damaging effects on water-organisms. This product
contains substances which can cause undesirable long-term effects in the water environment, due to its poor
biodegradability.

SECTION 13: Disposal considerations

13.1. Waste treatment methods


The product is covered by the regulations on dangerous waste.
Waste
EWC code
160504
Specific labelling
-
Contaminated packing
Packaging which contains leftovers from the product must be disposed of in the same way as the product.

SECTION 14: Transport information

This product is covered by the conventions on dangerous goods.


14.1 – 14.4
ADR/RID
14.1. UN number 1950
14.2. UN proper shipping name AEROSOLS, FLAMMABLE
14.3. Transport hazard
2.1
class(es)
14.4. Packing group II
Notes -
Tunnel restriction code D

IMDG
UN-no. 1950
Proper Shipping Name AEROSOLS, FLAMMABLE

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According to EC-Regulation 1907/2006 (REACH)

Class 2.1
PG* II
EmS F-D, S-U
MP** -
Hazardous constituent Cyclopentane, Heptane, Petroleum gas; liquefied

IATA/ICAO
UN-no.
Proper Shipping Name
Class
PG*

14.5. Environmental hazards


-
14.6. Special precautions for user
-
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
No data available
(*) Packing group
(**) Marine pollutant

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Restrictions for application
People under the age of 18 must not be exposed to this product cf. Council Directive 94/33/EC.
Demands for specific education
-
Additional information

Sources
EC regulation 1907/2006 (REACH)
Directive 2000/532/EC
EC Regulation 1272/2008 (CLP)
15.2. Chemical safety assessment
No
2830322911, ITW Chemical Products Scandinavia ApS
SECTION 16: Other information

Full text of H-phrases as mentioned in section 3


H220 - Extremely flammable gas.
H225 - Highly flammable liquid and vapour.
H280 - Contains gas under pressure; may explode if heated.
H304 - May be fatal if swallowed and enters airways.
H315 - Causes skin irritation.
H336 - May cause drowsiness or dizziness.
H411 - Toxic to aquatic life with long lasting effects.
H412 - Harmful to aquatic life with long lasting effects.

The full text of identified uses as mentioned in section 1


-
Other symbols mentioned in section 2

Other
It is recommended to hand over this safety data sheet to the actual user of the product. Information in this
safety data sheet cannot be used as a product specification.
The information in this safety data sheet applies only to this specific product (mentioned in section 1) and is
not necessarily correct for use with other chemicals/products.

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According to EC-Regulation 1907/2006 (REACH)

A change (in proportion to the last essential change (first cipher in SDS version)) is marked with a blue
triangle.
The safety data sheet is validated by
MJH
Date of last essential change
(First cipher in SDS version)
-
Date of last minor change
(Last cipher in SDS version)
-

ALPHAOMEGA. Licens nr.:2830322911, ITW Chemical Products Scandinavia ApS


www.chymeia.com

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