Mock Test
Single Correct Questions
Which of the following is correct about phenol?                   Q-1
   A      It's more acidic than dicarbonyl compounds.
   B      C-OH bond length is shorter than in para nitrophenol.
   C      It reacts with NaHCO3 but not with Na2CO3
   D      It's more acidic than enol form of acetone.
Which of the following is correct about phenol?                   Q-1
   A      It's more acidic than dicarbonyl compounds.
   B      C-OH bond length is shorter than in para nitrophenol.
   C      It reacts with NaHCO3 but not with Na2CO3
   D      It's more acidic than enol form of acetone.
Number of sp2 hybridized atoms in Picric Acid is:   Q-2
   A      7
   B      6
   C      4
   D      10
Number of sp2 hybridized atoms in Picric Acid is:
   A      7
   B      6
   C      4
   D      10
The species which is more stable than benzene is :   Q-3
   A                              B
   C      Both A and B            D     None
The species which is more stable than benzene is :
   A                              B
   C      Both A and B            D     None
Suppose the following structures and identify the correct
order of stability :                                        Q-4
   A      b=c>a
   B      b=c<a
   C      b>c>a
   D      a>b>c
Suppose the following structures and identify the correct
order of stability :                                        Q-4
   A      b=c>a
   B      b=c<a
   C      b>c>a
   D      a>b>c
Which nitrogen is protonated readily in the
Guanidine?                                        Q-5
 A    1                     B    2
 C    3                     D     None of these
Which nitrogen is protonated readily in the
Guanidine?
 A    1                     B    2
 C    3                     D     None of these
Which of the following has least bond length?   Q-6
 A     O2
 B     HCl
 C     N2
 D     F2
Which of the following has least bond length?
 A     O2
 B     HCl
 C     N2
 D     F2
Which of the following is most stable?
                                         Q-7
 A                          B
 C                          D
Which of the following is most stable?
 A                          B
 C                          D
The strength of backbonding is MAXIMUM among
the following compounds is …….                 Q-8
 A    PF3                B    BF3
 C    (SiH3)3N           D    (SiH3)2O
The strength of backbonding is MAXIMUM among
the following compounds is …….
 A    PF3                B    BF3
 C    (SiH3)3N           D    (SiH3)2O
The decreasing order of bond angles in BF3, NH3,
PF3 and I3- is :                                   Q-9
A     I3- > BF3 > NH3 > PF3
B     BF3 > I3- > PF3 > NH3
C     BF3 > NH3 > PF3 > I3-
D     BF3 > NH3 > PF3 > I3-
The decreasing order of bond angles in BF3, NH3,
PF3 and I3- is :
A     I3- > BF3 > NH3 > PF3
B     BF3 > I3- > PF3 > NH3
C     BF3 > NH3 > PF3 > I3-
D     BF3 > NH3 > PF3 > I3-
Which one of the following compounds has the smallest
bond angle?                                             Q-10
 A      OH2             B      SH2
 C     NH3              D      SO2
Which one of the following compounds has the smallest
bond angle?
 A      OH2             B      SH2
 C     NH3              D      SO2
A 𝞼-bonded molecule MX3 is T-shaped. The
                                           Q-11
number of lone pairs of electrons can be
  A   0                B   2
  C   1                D   none of these
A 𝞼-bonded molecule MX3 is T-shaped. The
number of lone pairs of electrons can be
  A   0                B   2
  C   1                D   none of these
Which of the following species contains
                                          Q-12
minimum number of atoms in ‘XY’ plane?
  A   XeF5-            B   SF6
  C   IF7              D   All
Which of the following species contains
minimum number of atoms in ‘XY’ plane?
  A   XeF5-            B   SF6
  C   IF7              D   All
In PO43- ion the formal charge on the oxygen atom   Q-13
of P–O bond is
  A    +1
  B    –1
  C    – 0.75
  D    + 0.75
In PO43- ion the formal charge on the oxygen atom
of P–O bond is
  A    +1
  B    –1
  C    – 0.75
  D    + 0.75
Among the following compounds, the most basic
                                                Q-14
compound is :
 A                           B
 C                           D
Among the following compounds, the most basic
compound is :
 A                           B
 C                           D
                                               +       –
Which of the following is NOT correct for NO2, NO2 and NO2             Q-15
   A      NO2 is paramagnetic in nature.
          +
   B      NO2 is linear, NO2 is ben and bond angle is less than 120o
          +
   C      NO2 has the strongest bonds among the given species.
          –
   D      NO2 has the bond order of 1.5.
                                               +       –
Which of the following is NOT correct for NO2, NO2 and NO2
   A      NO2 is paramagnetic in nature.
          +
   B      NO2 is linear, NO2 is ben and bond angle is less than 120o
          +
   C      NO2 has the strongest bonds among the given species.
          –
   D      NO2 has the bond order of 1.5.
Which of the following species are hypervalent?
(I) ClO4– (II) BF3           (III) SO4-2       (IV)   Q-16
     -2
CO3
  A    I, II, III          B    I, III
  C    III, IV             D    I, III, IV
Which of the following species are hypervalent?
(I) ClO4– (II) BF3           (III) SO4-2       (IV)
     -2
CO3
  A    I, II, III          B    I, III
  C    III, IV             D    I, III, IV
Choose the correct statement for O2 molecule.
As per M.O.T both the unpaired electrons of O2 molecule are :      Q-17
 A   in degenerated molecular orbitals
 B   in molecular orbitals which have given shape :
 C   in molecular orbitals which are perpendicular to each other
 D   all are correct
Choose the correct statement for O2 molecule.
As per M.O.T both the unpaired electrons of O2 molecule are :
 A   in degenerated molecular orbitals
 B   in molecular orbitals which have given shape :
 C   in molecular orbitals which are perpendicular to each other
 D   all are correct
Arrange the hydrogens in increasing order of
their acidic strengths.                        Q-18
A   A- Hc < Ha < Hb ; B- Hd < Hc < Hb < Ha
B   A- Hc < Ha < Hb ; B- Hd < Hc < Ha < Hb
C   A- Ha < Hc < Hb ; B- Hd < Hc < Hb < Ha
D   A- Hc < Ha < Hb ; B- Hd < Hb < Hc < Ha
Arrange the hydrogens in increasing order of
their acidic strengths.
A   A- Hc < Ha < Hb ; B- Hd < Hc < Hb < Ha
B   A- Hc < Ha < Hb ; B- Hd < Hc < Ha < Hb
C   A- Ha < Hc < Hb ; B- Hd < Hc < Hb < Ha
D   A- Hc < Ha < Hb ; B- Hd < Hb < Hc < Ha
Assuming the bond direction to the z-axis, which of the
overlapping of atomic orbitals of two atom (A) and (B)    Q-19
will result in bonding?
(i) s-orbital of A and px–orbital of B
(ii) s-orbital of A and pz–orbital of B
(iii) py-orbital of A and pz–orbital of B
(iv) s-orbital of both (A) and (B)
 A     I and IV           B     I and II
 C     III and IV         D     II and IV
Assuming the bond direction to the z-axis, which of the
overlapping of atomic orbitals of two atom (A) and (B)
will result in bonding?
(i) s-orbital of A and px–orbital of B
(ii) s-orbital of A and pz–orbital of B
(iii) py-orbital of A and pz–orbital of B
(iv) s-orbital of both (A) and (B)
 A     I and IV           B     I and II
 C     III and IV         D     II and IV
Select incorrect statement.
                                                                     Q-20
  A    O3 and O2- both are diamagnetic
  B    Out of O2, O2+, O3, least O-O bond length is in O2+
  C    Out of O2, O2+, O2-, only O2 is paramagnetic
  D    Out of O2 , O2+, O2–, maximum spin magnetic moment have O2.
Select incorrect statement.
  A    O3 and O2- both are diamagnetic
  B    Out of O2, O2+, O3, least O-O bond length is in O2+
  C    Out of O2, O2+, O2-, only O2 is paramagnetic
  D    Out of O2 , O2+, O2–, maximum spin magnetic moment have O2.
Integer Type Questions
How many groups among the following show -I effect?
                                                      Q-21
How many groups among the following show -I effect?
Ans. 6
Number of species having dipole
                                  Q-22
moment less than 1 is :
HBr, HI, H2S, NF3, HCl
Number of species having dipole
moment less than 1 is :
HBr, HI, H2S, NF3, HCl
Ans. 4
Total number of molecules which are antiaromatic?
                                                    Q-23
Total number of molecules which are antiaromatic?
  Ans. 3
The positive charge of the following carbocation can be
delocalized over how many oxygen atoms in the             Q-24
resonating structure?
The positive charge of the following carbocation can be
delocalized over how many oxygen atoms in the
resonating structure?
  Ans. 2
The number of bent-shaped molecule/s
                                       Q-25
from the following is_______
N3-, NO2-, I3-, O3, SO2
The number of bent-shaped molecule/s
from the following is_______
N3-, NO2-, I3-, O3, SO2
 Ans : 3