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Answer Key AETHER Mock Test - 1

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0% found this document useful (0 votes)
69 views56 pages

Answer Key AETHER Mock Test - 1

Uploaded by

Sriram S Nambiar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Mock Test

Single Correct Questions


Which of the following is correct about phenol? Q-1

A It's more acidic than dicarbonyl compounds.

B C-OH bond length is shorter than in para nitrophenol.

C It reacts with NaHCO3 but not with Na2CO3

D It's more acidic than enol form of acetone.


Which of the following is correct about phenol? Q-1

A It's more acidic than dicarbonyl compounds.

B C-OH bond length is shorter than in para nitrophenol.

C It reacts with NaHCO3 but not with Na2CO3

D It's more acidic than enol form of acetone.


Number of sp2 hybridized atoms in Picric Acid is: Q-2

A 7

B 6

C 4

D 10
Number of sp2 hybridized atoms in Picric Acid is:

A 7

B 6

C 4

D 10
The species which is more stable than benzene is : Q-3

A B

C Both A and B D None


The species which is more stable than benzene is :

A B

C Both A and B D None


Suppose the following structures and identify the correct
order of stability : Q-4

A b=c>a

B b=c<a

C b>c>a

D a>b>c
Suppose the following structures and identify the correct
order of stability : Q-4

A b=c>a

B b=c<a

C b>c>a

D a>b>c
Which nitrogen is protonated readily in the
Guanidine? Q-5

A 1 B 2

C 3 D None of these
Which nitrogen is protonated readily in the
Guanidine?

A 1 B 2

C 3 D None of these
Which of the following has least bond length? Q-6

A O2

B HCl

C N2

D F2
Which of the following has least bond length?

A O2

B HCl

C N2

D F2
Which of the following is most stable?
Q-7

A B

C D
Which of the following is most stable?

A B

C D
The strength of backbonding is MAXIMUM among
the following compounds is ……. Q-8

A PF3 B BF3

C (SiH3)3N D (SiH3)2O
The strength of backbonding is MAXIMUM among
the following compounds is …….

A PF3 B BF3

C (SiH3)3N D (SiH3)2O
The decreasing order of bond angles in BF3, NH3,
PF3 and I3- is : Q-9

A I3- > BF3 > NH3 > PF3

B BF3 > I3- > PF3 > NH3

C BF3 > NH3 > PF3 > I3-

D BF3 > NH3 > PF3 > I3-


The decreasing order of bond angles in BF3, NH3,
PF3 and I3- is :

A I3- > BF3 > NH3 > PF3

B BF3 > I3- > PF3 > NH3

C BF3 > NH3 > PF3 > I3-

D BF3 > NH3 > PF3 > I3-


Which one of the following compounds has the smallest
bond angle? Q-10

A OH2 B SH2

C NH3 D SO2
Which one of the following compounds has the smallest
bond angle?

A OH2 B SH2

C NH3 D SO2
A 𝞼-bonded molecule MX3 is T-shaped. The
Q-11
number of lone pairs of electrons can be

A 0 B 2

C 1 D none of these
A 𝞼-bonded molecule MX3 is T-shaped. The
number of lone pairs of electrons can be

A 0 B 2

C 1 D none of these
Which of the following species contains
Q-12
minimum number of atoms in ‘XY’ plane?

A XeF5- B SF6

C IF7 D All
Which of the following species contains
minimum number of atoms in ‘XY’ plane?

A XeF5- B SF6

C IF7 D All
In PO43- ion the formal charge on the oxygen atom Q-13
of P–O bond is

A +1

B –1

C – 0.75

D + 0.75
In PO43- ion the formal charge on the oxygen atom
of P–O bond is

A +1

B –1

C – 0.75

D + 0.75
Among the following compounds, the most basic
Q-14
compound is :

A B

C D
Among the following compounds, the most basic
compound is :

A B

C D
+ –
Which of the following is NOT correct for NO2, NO2 and NO2 Q-15

A NO2 is paramagnetic in nature.

+
B NO2 is linear, NO2 is ben and bond angle is less than 120o

+
C NO2 has the strongest bonds among the given species.


D NO2 has the bond order of 1.5.
+ –
Which of the following is NOT correct for NO2, NO2 and NO2

A NO2 is paramagnetic in nature.

+
B NO2 is linear, NO2 is ben and bond angle is less than 120o

+
C NO2 has the strongest bonds among the given species.


D NO2 has the bond order of 1.5.
Which of the following species are hypervalent?
(I) ClO4– (II) BF3 (III) SO4-2 (IV) Q-16
-2
CO3

A I, II, III B I, III

C III, IV D I, III, IV
Which of the following species are hypervalent?
(I) ClO4– (II) BF3 (III) SO4-2 (IV)
-2
CO3

A I, II, III B I, III

C III, IV D I, III, IV
Choose the correct statement for O2 molecule.
As per M.O.T both the unpaired electrons of O2 molecule are : Q-17

A in degenerated molecular orbitals

B in molecular orbitals which have given shape :

C in molecular orbitals which are perpendicular to each other

D all are correct


Choose the correct statement for O2 molecule.
As per M.O.T both the unpaired electrons of O2 molecule are :

A in degenerated molecular orbitals

B in molecular orbitals which have given shape :

C in molecular orbitals which are perpendicular to each other

D all are correct


Arrange the hydrogens in increasing order of
their acidic strengths. Q-18

A A- Hc < Ha < Hb ; B- Hd < Hc < Hb < Ha

B A- Hc < Ha < Hb ; B- Hd < Hc < Ha < Hb

C A- Ha < Hc < Hb ; B- Hd < Hc < Hb < Ha

D A- Hc < Ha < Hb ; B- Hd < Hb < Hc < Ha


Arrange the hydrogens in increasing order of
their acidic strengths.

A A- Hc < Ha < Hb ; B- Hd < Hc < Hb < Ha

B A- Hc < Ha < Hb ; B- Hd < Hc < Ha < Hb

C A- Ha < Hc < Hb ; B- Hd < Hc < Hb < Ha

D A- Hc < Ha < Hb ; B- Hd < Hb < Hc < Ha


Assuming the bond direction to the z-axis, which of the
overlapping of atomic orbitals of two atom (A) and (B) Q-19
will result in bonding?
(i) s-orbital of A and px–orbital of B
(ii) s-orbital of A and pz–orbital of B
(iii) py-orbital of A and pz–orbital of B
(iv) s-orbital of both (A) and (B)

A I and IV B I and II

C III and IV D II and IV


Assuming the bond direction to the z-axis, which of the
overlapping of atomic orbitals of two atom (A) and (B)
will result in bonding?
(i) s-orbital of A and px–orbital of B
(ii) s-orbital of A and pz–orbital of B
(iii) py-orbital of A and pz–orbital of B
(iv) s-orbital of both (A) and (B)

A I and IV B I and II

C III and IV D II and IV


Select incorrect statement.
Q-20

A O3 and O2- both are diamagnetic

B Out of O2, O2+, O3, least O-O bond length is in O2+

C Out of O2, O2+, O2-, only O2 is paramagnetic

D Out of O2 , O2+, O2–, maximum spin magnetic moment have O2.


Select incorrect statement.

A O3 and O2- both are diamagnetic

B Out of O2, O2+, O3, least O-O bond length is in O2+

C Out of O2, O2+, O2-, only O2 is paramagnetic

D Out of O2 , O2+, O2–, maximum spin magnetic moment have O2.


Integer Type Questions
How many groups among the following show -I effect?
Q-21
How many groups among the following show -I effect?

Ans. 6
Number of species having dipole
Q-22
moment less than 1 is :
HBr, HI, H2S, NF3, HCl
Number of species having dipole
moment less than 1 is :
HBr, HI, H2S, NF3, HCl

Ans. 4
Total number of molecules which are antiaromatic?
Q-23
Total number of molecules which are antiaromatic?

Ans. 3
The positive charge of the following carbocation can be
delocalized over how many oxygen atoms in the Q-24
resonating structure?
The positive charge of the following carbocation can be
delocalized over how many oxygen atoms in the
resonating structure?

Ans. 2
The number of bent-shaped molecule/s
Q-25
from the following is_______
N3-, NO2-, I3-, O3, SO2
The number of bent-shaped molecule/s
from the following is_______
N3-, NO2-, I3-, O3, SO2

Ans : 3

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