Safety Data Sheet

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SECTION 1: Identification of the substance/mixture and of the company/undertaking

Identification of the substance or mixture

Product code METHANOLSDS

Product name METHANOL
Molecular Formula CH4O

Synonyms Carbinol; Methyl Alcohol; Methyl Hydroxide; Monohydroxymethane; Wood Alcohol;

Wood Naphtha; Wood Spirits; Columbian Spirits
Product Catalog Numbers P140-40CEPPTTB; P140-40CEPPTTW; PP140-40CEPPTTB;
PP140-40CEPPTTW

Company/undertaking identification

EP Scientific Products/ThermoFisher
520 North Main Street
Miami, OK 74354
Business Phone: 1-(828)-658-2711

EMAIL ADDRESS FOR PRODUCT INFORMATION:

cservice@epscientific.com

24 hour Emergency Response for Hazardous Materials CHEMTREC: 1-800-424-9300 (U.S./Canada/Puerto Rico)
[or Dangerous Goods] Incident. Spill, Leak, Fire, [24-hours]
Exposure, or Accident. Call CHEMTREC CHEMTREC: +1-703-527-3887 (Outside North America)
[24-hours]

Country Specific Emergency Number (if available):

Product Use: Various

SECTION 2: Hazards identification

GHS - Classification

Signal Word
DANGER

Hazard pictograms

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Health hazards
Acute oral toxicity Category 3
Acute dermal toxicity Category 3
Acute inhalation toxicity - gas Category 3
Specific target organ systemic toxicity (single exposure) Category 1

Physical hazards
GHS Physical Hazard Flammable liquids
GHS Physical Hazard Category Number Category 2

Environmental hazards
Not Hazardous

Hazard Statements
H225 - Highly flammable liquid and vapor
H301 + H311 + H331 - Toxic if swallowed, in contact with skin or if inhaled
H370 - Causes damage to organs if inhaled
H370 - Causes damage to organs if swallowed
H370 - Causes damage to organs in contact with skin

Precautionary Statements

Prevention
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P240 - Ground/bond container and receiving equipment
P241 - Use explosion-proof electrical/ ventilating/ lighting/ equipment
P242 - Use non-sparking tools
P243 - Take action to prevent static discharges
P260 - Do not breathe dust/fume/gas/mist/vapors/spray
P270 - Do not eat, drink or smoke when using this product
P271 - Use only outdoors or in a well-ventilated area
P280 - Wear protective gloves/protective clothing/eye protection/face protection

Response
P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction
P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower
P330 - Rinse mouth
P362 - Take off contaminated clothing
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P311 - Call a POISON CENTER or doctor
P322 - Specific measures (see Both ethanol and fomepizole are effective antidotes for methanol poisoning, although
fomepizole is preferred. P363: Wash contaminated clothing before reuse. on this label)

Storage
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
P405 - Store locked up
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Disposal
P501 - Dispose of contents/ container to an approved waste disposal plant

Other hazards
Not Applicable

HMIS
Health 2
Flammability 3
Reactivity 0

EMERGENCY OVERVIEW: Product Description: This product is a clear, colorless liquid with a characteristic weak,
alcohol-like odor. Health Hazards: Danger! Poison! May be harmful or toxic by ingestion, skin absorption and
inhalation. May cause adverse eye effects by ingestion or skin absorption. Causes adverse central nervous system
effects. May cause irritation of the eyes, skin and respiratory system. Chronic skin exposure to low concentration
may cause defatting of the skin. If swallowed, an aspiration hazard may exist; damage to lungs can follow. Suspect
reproductive toxin, based on animal data. Flammability Hazards: Danger! Highly flammable liquid and vapor. Can
readily form explosive mixtures in air. Fumes can collect in confined spaces creating flammability and toxicity hazard.
If involved in a fire it may generate irritating fumes and toxic gases (e.g., carbon oxides and formaldehyde).
Reactivity Hazards: Methanol is not reactive, but is hygroscopic and will absorb moisture from the air. Environmental
Hazards: This product may cause harm to organisms if accidentally released. Emergency Considerations:
Emergency responders should wear appropriate protection for situation to which they respond.

SECTION 3: Composition/information on ingredients

Component CAS-No EINECS-No Weight %

Methyl alcohol 67-56-1 200-659-6 100
67-56-1 ( 100 )

We recommend handling all chemicals with caution.

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 SECTION 4: First aid measures

Description of first aid measures

RESCUERS SHOULD NOT ATTEMPT TO RETRIEVE VICTIMS OF EXPOSURE TO THIS MATERIAL WITHOUT
ADEQUATE PERSONAL PROTECTIVE EQUIPMENT, OR BY THEMSELVES. If necessary, Self-Contained
Breathing Apparatus and fire-retardant clothing should be worn. All first aid procedures should be periodically
reviewed by a doctor familiar with the material and its conditions of use in the workplace. Provide general supportive
measures (comfort, warmth, rest). Consult a doctor and/or the nearest Poison Control Centre for all exposure except
minor instances of inhalation or skin contact. Take a copy of label and SDS to physician or health professional with
the contaminated individual.

Skin contact If skin contact causes irritation, flush with running water. Under running water,
remove contaminated clothing, shoes, and leather goods (e.g., watchbands,
belts). Transport victim to an emergency care facility immediately. Discard
contaminated clothing, shoes and leather goods. DO NOT reuse. Seek medical
attention if adverse effects occur after flushing.
Eye contact Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for
at least 30 minutes, by the clock, while holding the eyelid(s) open. DO NOT
INTERRUPT FLUSHING. Do NOT allow victim to rub eyes or keep eyes closed.
Have victim "roll" eyes. Neutral saline solution may be used as soon as it is
available. If necessary, keep emergency vehicle waiting. Take care not to rinse
contaminated water into the non-affected eye or onto the face. Quickly transport
victim to an emergency care facility.
Ingestion If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER
FOR MOST CURRENT INFORMATION. NEVER give anything by mouth if victim
is rapidly losing consciousness, is unconscious or is convulsing. Have victim rinse
mouth thoroughly with water. DO NOT INDUCE VOMITING. Have victim drink 240
to 300 mL (8 to 10 oz.) of water to dilute material in stomach. If milk is available, it
may be administered AFTER the water has been given. If vomiting occurs
naturally, rinse mouth and repeat administration of water. Quickly transport victim
to an emergency care facility.
Inhalation If aerosols from of this product are inhaled, remove victim to fresh air. If
necessary, use artificial respiration to support vital functions. If breathing is
difficult, give oxygen. Seek medical attention if adverse effect occurs after
removal to fresh air.
Notes to Physician Treat symptomatically.

Most important symptoms and effects, both acute and delayed

H225 - Highly flammable liquid and vapor H301 + H311 + H331 - Toxic if swallowed, in contact with skin or if inhaled
H370 - Causes damage to organs if inhaled H370 - Causes damage to organs if swallowed H370 - Causes damage to
organs in contact with skin

Indication of any immediate medical attention and special treatment needed

Treat symptoms and eliminate exposure. The following information is for specific treatment for Methanol.The severity
of outcome following methanol ingestion may be more related to the time between ingestion and treatment, rather
than the amount ingested. Therefore, there is a need for rapid treatment of any ingestion exposure. Both ethanol and
fomepizole are effective antidotes for methanol poisoning, although fomepizole is preferred.

Medical conditions aggravated by exposure

Pre-existing skin and respiratory disorders or severe hepatic dysfunction may be aggravated by exposure to this
product.
PROTECTION OF FIRST AID RESPONDERS: See Sections 6 (Accidental Release Measures) and 8 (Exposure
Controls-Personal Protection).

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 SECTION 5: Firefighting measures

Extinguishing media

Suitable extinguishing media For small fires, use dry chemical, carbon dioxide, or water
spray. For large fires, use dry chemical, carbon dioxide,
alcohol-resistant foam, or water spray. Water may not be
effective as it may not cool burning Methanol below its
flashpoint. Cool containers with flooding quantities of
water until well after fire is out. Water sprays may be used
to direct or block flammable vapors. Consideration for
surrounding materials must be taken into account. .
Unsuitable extinguishing media No information available.

Special hazards arising from the substance or mixture

Methanol is highly flammable and can ignite if exposed to ignition source or temperature at or above its flash point.
Containers may explode when heated. Methanol burns with a clear, almost invisible, or non-luminous light-blue
flame. Mixtures of Methanol and water at concentrations greater than 20% methanol can burn. If involved in a fire,
this product may decompose and produce irritating vapors and toxic gases (e.g., carbon oxides and formaldehyde).
Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the
ground and collect in low or confined areas creating a toxicity and flammability hazard.

Advice for fire-fighters

Do not direct steady stream of water at burning product, which can spread material and fire. In the event of fire, cool
containers of this material with water to prevent failure. Water fog or spray can also be used by trained fire-fighters to
disperse vapors of this product and to protect personnel. Move containers from fire area if it can be done without risk
to firefighters. For small releases, if it is not possible to stop the leak, and it does not endanger personnel, let the fire
burn itself out. Structural firefighters must wear Self-Contained Breathing Apparatus (SCBA) and full protective
equipment. If protective equipment is contaminated by this product, it should be thoroughly washed with soapy water
prior to removal of SCBA respiratory protection. Firefighters whose protective equipment becomes contaminated
should thoroughly shower with warm, soapy water and should receive medical evaluation if they experience any
adverse effects.

Explosion Sensitivity to Mechanical Impact/ Explosion Sensitivity to Static Discharge

Explosion Sensitivity to Mechanical Impact: Not sensitive.
Explosion Sensitivity to Static Discharge: Static discharge may cause this product to ignite.

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 SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Trained personnel using pre-planned procedures should respond to uncontrolled releases. Proper protective
equipment should be used. In case of a spill, clear the affected area and protect people. An accidental release can
result in a fire. Uncontrolled releases should be responded to by trained personnel using pre-planned procedures.
Proper protective equipment should be used. In case of a spill, clear the affected area and protect people. Use
non-sparking tools. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Avoid
allowing water runoff to contact spilled material. Call CHEMTREC (1-800-424-9300) for emergency assistance. Or if
in Canada, call CANUTEC (613-996-6666). The level of vapors must be below 10% of the LEL (see Section 5,
Fire-Fighting Measures), if applicable, before personnel are allowed into the spill area. The atmosphere must have
levels of components lower than those listed in Section 8, (Exposure Controls and Personal Protective Equipment), if
applicable, and have at least 19.5 percent oxygen before personnel can be allowed into the area without
Self-Contained Breathing Apparatus.
EQUIPMENT:
Small Spills: Wear double-gloves (rubber over latex gloves), rubber apron, and splash goggles or safety glasses.
Protective goggles should be cleaned with an alcohol wipe after the cleanup.
Large Spills: Trained personnel following pre-planned procedures should handle non-incidental releases. Minimum
Personal Protective Equipment should be rubber gloves, rubber boots, face shield, and Tyvek suit. The minimum
level of personal protective equipment for all releases must be Level B: triple-gloves (fire-retardant gloves and nitrile
gloves over latex gloves), chemical resistant suit and boots, hard hat, and Self-Contained Breathing Apparatus. A fire
retardant suit must be worn over the chemical resistant suit.

Environmental precautions
Prevent material from entering sewer or confined spaces, waterways, soil or public waters. Do not flush to sewer.

Methods and material for containment and cleaning up

Small Spills: Absorb spilled liquid with activated carbon, polypads, or other suitable inert absorbent materials. Place
spilled material in appropriate container for disposal, sealing tightly. Remove all residue before decontamination of
spill area.
Spills in Hoods: Decontamination of all interior hood surfaces may be required after the above procedures for small
spills have been followed. If the HEPA filter of a hood is contaminated, the unit must be labeled "Do not
use-contaminated" and the filter must be changed and disposed of properly as soon as possible.
Large Spills: Trained personnel following pre-planned procedures should handle all releases of this material. Cover
spilled material with activated carbon or other non-reactive material. Prevent material from entering sewer or confined
spaces, waterways, soil or public waters. Monitor area and confirm levels are bellow exposure limits given in Section
8 (Exposure Controls-Personal Protection), if applicable, before non-response personnel are allowed into the spill
area.

Reference to other sections

See Section 13, Disposal Considerations for more information.

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 SECTION 7: Handling and storage

Precautions for safe handling

As with all chemicals, avoid getting this product ON YOU or IN YOU. Do not eat, drink, smoke, or apply cosmetics
while handling this product. Wash hands thoroughly after handling this product or equipment and containers of this
compound. Follow SPECIFIC USE INSTRUCTIONS supplied with product. Use in a well-ventilated location,
segregated from other materials and operations. Keep away from heat, sparks, and other sources of ignition. Use
non-sparking tools. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames. Bond and ground containers during transfers of material. Containers of this product must be
properly labeled. Keep container tightly closed when not in use. .

Conditions for safe storage, including any incompatibilities

Store away from direct sunlight or sources of intense heat. Material should be stored in secondary containers or in a
diked area, as appropriate. Store containers away from incompatible chemicals (see Section 10, Stability and
Reactivity). Containers should be separated from oxidizing materials by a minimum distance of 20 ft. or by a barrier
of non-combustible material at least 5 ft. high having a fire-resistance rating of at least 0.5 hours. Storage areas
should be made of fire resistant materials. Local Fire Departments should be notified of the storage of this product on
site. Storage and processing areas of this product should be identified with a NFPA 704 placard (diamond) large
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appropriate. Have appropriate extinguishing equipment in the storage area (such as sprinkler systems or portable fire
extinguishers). Inspect all incoming containers before storage to ensure containers are properly labeled and not
damaged. Refer to NFPA 30, Flammable and Combustible Liquids Code, for additional information on storage. .

Specific end use(s)

This product has various uses in different industries. Follow all industry standards for use of this product.

PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT

When cleaning non-disposable equipment, wear latex or butyl rubber (double gloving is recommended), goggles, and
lab coat. Wash equipment with soap and water. Wipe equipment down with damp sponge or polypad. Collect all
rinsates and dispose of according to applicable Federal, State, and local procedures standards. .

SECTION 8: Exposure controls/personal protection

Control parameters

Chemical Name ACGIH-TLVs (TWA) ACGIH-TLVs (STEL) OSHA-PELs (TWA) OSHA-PELs (STEL)
Methyl alcohol 200 mg/m3 (skin) 250 mg/m3(skin) 200 mg/m3 Not Established

Chemical Name NIOSH-RELs (TWA) NIOSH-RELs (STEL) NIOSH (IDLH) Other

Methyl alcohol 200 mg/m3(skin) 250 mg/m3 (skin) 3000 mg/m3 DFG MAKs:TWA = 200
(skin)PEAK/CEILING:
4•MAK15mi n.aver age
value, 1-hr interval, 4 per
shiftDFG MAK Pregnancy
Risk Classification: C

International Exposure LimitsCurrently, the following international exposure limits are in place for Methanol.
This may not be a complete list and exposure limits change and should be
checked for currency.
METHANOL:
ARAB Republic of Egypt: TWA = 200 ppm (260 mg/m3), Skin, JAN 1993
Australia: TWA = 200 ppm (262 mg/m3), STEL = 250 ppm (328 mg/m3), JUL 2008
Austria: MAK-TMW = 200 ppm (260 mg/m3); KZW = 800 ppm (1040 mg/m3), skin,
2007
Belgium: TWA = 200 ppm (266 mg/m3), MAR 2002
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 Belgium: STEL = 250 ppm (333 mg/m3), Skin, MAR 2002
Denmark: TWA = 200 ppm (260 mg/m3), skin, MAY 2011
EC: TWA = 260 mg/m3 (200 ppm), skin, FEB 2006
Finland: TWA = 200 ppm (270 mg/m3), STEL = 250 ppm (330 mg/m3), skin, NOV
2011
France: VME = 200 ppm (260 mg/m3), VLE = 1000 ppm (1300 mg/m3), FEB 2006
Germany: MAK = 200 ppm (270 mg/m3), 2011
Hungary: TWA = 260 mg/m3, STEL 1040 mg/m3, Skin, SEP 2000
Iceland: TWA = 200 ppm (260 mg/m3), skin, NOV 2011
Japan: OEL = 200 ppm (260 mg/m3), skin, MAY 2012
Korea: TWA = 200 ppm (260 mg/m3), STEL = 250 ppm (310 mg/m3), skin, 2006
Mexico: TWA = 200 ppm (260 mg/m3); STEL = 310 mg/m3 (250 ppm), 2004
The Netherlands: MAC-TGG = 260 mg/m3, Skin, 2003
New Zealand: TWA = 200 ppm (262 mg/m3); STEL = 250 ppm (328 mg/m3), skin,
JAN 2002
Norway: TWA = 100 ppm (130 mg/m3), JAN 1999
Peru: TWA = 200 ppm (262 mg/m3); STEL = 250 ppm (328 mg/m3), JUL 2005
The Philippines: TWA = 200 ppm (260 mg/m3), JAN 1993
Poland: MAC(TWA) = 100 mg/m3, MAC(STEL) = 300 mg/m3, JAN 1999
Russia: TWA = 5 mg/m3, STEL 15 mg/m3, Skin, JUN 2003
Sweden: TWA = 200 ppm (250 mg/m3); STEL = 250 ppm (350 mg/m3), Skin, JUN
2005
Switzerland: MAK-W = 200 ppm (260 mg/m3), KZG-W = 800 ppm (1040 mg/m3),
skin, JAN 2011
Thailand: TWA = 200 ppm (260 mg/m3), JAN 1993
Turkey: TWA = 200 ppm (260 mg/m3), JAN 1993
United Kingdom: TWA = 200 ppm (266 mg/m3); STEL = 250 ppm (333 mg/m3),
skin, OCT 2007
In Argentina, Bulgaria, Colombia, Jordan, Singapore, Vietnam, check ACGIH TLV

Engineering measures This product should be used areas with adequate ventilation. Use process
enclosures, local exhaust ventilation, or other engineering controls to maintain
airborne levels below recommended exposure limits provided in this section, if
applicable. Use a non-sparking, grounded, explosion-proof ventilation system
separate from other exhaust ventilation systems. Exhaust directly to the outside,
taking necessary precautions for environmental protection. An eyewash and
safety shower should be readily accessible.

Exposure controls

Personal Protective Equipment

The following information on appropriate Personal Protective Equipment is provided to assist employers in
complying with OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132, including U.S. Federal
OSHA Respiratory Protection (29 CFR 1910.134), OSHA Eye Protection 29 CFR 1910.133, OSHA Hard
Protection 29 CFR 1910.138, OSHA Foot Protection 29 CFR 1910.136 and OSHA Body Protection 29
CFR1910.132), equivalent standards of Canada (including CSA Respiratory Standard Z94.4-02, Z94.3-M1982,
Industrial Eye and Face Protectors and CSA Standard Z195-02, Protective Footwear), or standards of EU member
states (including EN 529:2005 for respiratory PPE, CEN/TR 15419:2006 for hand protection, and CR 13464:1999
for face/eye protection). Please reference applicable regulations and standards for relevant details.

Respiratory protection
Maintain airborne contaminant concentrations below limits listed above, if applicable. In instances where inhalable
aerosols may be generated and respiratory protection is necessary, use only respiratory protection authorized
under appropriate regulations. In the U.S., oxygen levels below 19.5% are considered IDLH by OSHA.
In such atmospheres, use of a full-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator
withaux il
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 (1910.134-1998).
The following are NIOSH respiratory protection equipment guidelines for Methanol and are provided for additional
information on the selection of respiratory protection equipment.
METHANOL
CONCENTRATION RESPIRATORY PROTECTION
Up to 2000 ppm: Any Supplied-Air Respirator (SAR).
Up to 5000 ppm: Any SAR operated in a continuous-flow mode.
Up to 6000 ppm: Any SAR that has a tight-fitting facepiece and is operated in a continuous-flow
mode, or any Self-Contained Breathing Apparatus (SCBA) with a full facepiece, or any SAR with a full facepiece.
Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions: Any SCBA that has a full
facepiece and is operated in a pressure-demand or other positive-pressure mode, or any SAR that has a full
facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary
SCBA operated in pressure-demand or other positive-pressure mode.
Escape: Any appropriate escape-type, SCBA.

Hand protection Use butyl rubber, Teflon, Viton, Saranex, or Responder gloves for routine
industrial use. Use triple gloves for spill response, as stated in Section 6
(Accidental Release Measures) of this SDS. If necessary, refer to applicable
regulations.

Eye protection Splash goggles or safety glasses. Splash goggles and faceshield should be
considered when handling solutions made from this product. If necessary, refer to
appropriate country regulations and standards for further information.

Skin and Body Protection Use body protection appropriate for task. Full-body chemical protective clothing is
recommended for emergency response procedures. If a hazard of injury to the
feet exists due to falling objects, rolling objects, where objects may pierce the
solesoft hef eetorwher eempl oyee’ sfeetmaybeex posedt oelectr
icalhazar ds,
use foot protection. Refer to appropriate country regulations and standards for
further information.

Hygiene measures Handle in accordance with good industrial hygiene and safety practice

Environmental exposure controls

Prevent material from entering sewer or confined spaces, waterways, soil or public waters. Do not flush to sewer.

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 SECTION 9: Physical and chemical properties

Information on basic physical and chemical properties

Appearance liquid
Color Clear, colorless. APHA: 10 max
Odor Characteristic weak, alcohol-like odor
Odor Threshold 160 ppm (detection, geometric mean); 690 ppm (recognition, geometric mean)
Molecular Weight 32.04
pH No data available
Freezing point -98°C (-143.9°F)
Melting point / melting range °C -98 °F -143.9
Boiling point / boiling range °C @ 760 mmHg: 64.7 °F 148.46
Flash point °C (closed cup): 12°C °F (closed cup): 53.6°F
Autoignition Temperature °C 455°C °F 851°F
Decomposition temperature °C Mixture has not been tested °F Mixture has not been tested
Evaporation rate (ether = 1): 5.2
Flammability (solid, gas) (in air by volume, %): LEL: 6.0% UEL: 31.0%
Upper explosion limit Mixture has not been tested
Lower explosion limit Mixture has not been tested
Vapor Pressure (air = 1) @ 20°C: 128 mmHg
Vapor density (air= 1) 1.11
Relative density Mixture has not been tested
Specific gravity @ 20°C: 0.7910 g/cm3
Solubility (Water) miscible
Partition coefficient: Log P(oct) = -0.77
n-octanol/water
Viscosity @ 20°C: 0.55 cPs
Explosive properties Mixture has not been tested
Oxidizing properties No oxidizing properties

Other information
SOLUBILITIES IN OTHER LIQUIDS: Soluble in all proportions in ethanol, other alcohols, benzene, chloroform, diethyl
ether, other ethers, esters, ketones, and most other organic solvents.

HOW TO DETECT THIS SUBSTANCE (identification properties): The odor of Methanol is not a good method to
identify Methanol in event of accidental release, as the geometric mean odor threshold is of the same order as the
TLV.

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 SECTION 10: Stability and reactivity

Chemical stability Methanol is stable when properly stored (see Section 7, Handling and Storage) at
normal temperature. Methanol absorbs moisture from the air.

Possibility of hazardous will not occur.

reactions

Conditions to avoid Avoid extreme temperatures, sources of ignition, confined spaces and contact with
incompatible chemicals. Contact with water should be controlled.

Incompatible materials Methanol is incompatible with strong oxidizing agents (e.g. bromine, chlorine,
chromium trioxide, nitric acid, perchlorates or sodium hypochlorite), hydrogen
peroxide, metals (e.g. powdered aluminum or magnesium), carbon tetrachloride
and metals (e.g. aluminum, magnesium or zinc), alkali metals (e.g. sodium or
potassium), acetyl bromide, dichloromethane, perchloric acid or metal
perchlorates (e.g. barium perchlorate or lead perchlorate), potassium
tert-butoxide, alkylaluminum solutions, beryllium hydride, cyanuric chloride,
isocyanates or phosphorus (III) oxide, diethyl zinc, mineral acids (e.g. sulfuric
acid), organic acids, acid anhydrides, acid chlorides or sodium hydroxide and
chloroform. Methanol is corrosive to type 12L14 carbon steel at room temperature
and type 3003 aluminum, copper (10-100% methanol solution) and admiralty
brass, at 93°C (199.4°F). Methanol attacks plastics such as nylon 66, nylon 610,
acrylonitrile-butadiene-styrene, styrene-acrylonitrile, rigid polyurethane, thermoset
isophthalic polyester and polystyrene; elastomers, such as polyacrylate,
polyurethane, hard rubber, soft rubber, Viton A; and general purpose epoxy
coating.

Hazardous decomposition Combustion: If exposed to extremely high temperatures, thermal decomposition

products may generate irritating fumes and toxic gases (e.g., carbon oxides and
formaldehyde). Hydrolysis: None. .

SECTION 11: Toxicological information

Information on toxicological effects

SYMPTOMS OF EXPOSURE BY ROUTE OF EXPOSURE: The health hazard information provided below is pertinent
to employees using this product in an occupational setting. The following paragraphs describe the symptoms of
exposure by route of exposure.
Inhalation: Symptoms of inhalation may include breathing difficulty, irritation of the mucus membranes, coughing,
nasal congestion, and a sore throat. Inhalation may cause adverse central nervous system effects including initial
symptoms of dizziness, incoordination, nausea and headache, vomiting. A time period with no obvious symptoms
follows (typically 8-24 hrs). This latent period is followed by metabolic acidosis and severe visual effects which may
include reduced reactivity and/or increased sensitivity to light, blurred, double and/or snowy vision, and blindness.
Depending on the severity of exposure and the promptness of treatment, victims of exposure may recover completely
or may have permanent blindness, vision disturbances and/or nervous system effects.
Contact with Skin or Eyes: Contact with the eyes will cause moderate irritation, pain, reddening and watering.
Depending on the duration of skin contact, skin exposure may cause reddening, discomfort, and mild irritation.
Repeated skin-exposure to low concentrations can result in dermatitis (inflammation and reddening of the skin).
Skin Absorption: Methanol can be absorbed through intact skin and can cause systemic toxicity by this route of
exposure. Skin absorption of Methanol can cause significant disturbances in vision, including blindness. Other
sympt omscani ncl udethoseasdescr ibedunder‘ I ngest
ion’.
Ingestion: Methanol is toxic by ingestion and cannot be made non-poisonous. May be harmful, fatal or cause
blindness if swallowed. Aspiration hazard; ingestion may result in aspiration into lungs and cause potential fatal
chemical pneumonitis or pulmonary edema. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
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May cause systemic toxicity with acidosis. May cause central nervous system depression, characterized by
excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse,
unconsciousness, coma and possible death due to respiratory failure. May cause adverse cardiopulmonary system
effects.
Injection: Though not anticipated to be a significant route of exposure for this product, injection (via punctures or
lacerations by contaminated objects) may cause redness at the site of injection.

OTHER HEALTH EFFECTS/INFORMATION: Methanol is significantly less toxic to most experimental animals than
humans, because most animal species metabolize Methanol differently. Non-primate species do not ordinarily show
symptoms of metabolic acidosis or the visual effects which have been observed in primates and humans.

HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. Exposure to this product may
cause the following health effects:
Acute: Methanol can cause adverse central nervous system effects by all routes of exposure. Inhalation and
ingestion may cause damage to the optic nerve and blindness. Ingestion may be harmful or fatal.
Chronic: Symptoms of chronic exposure may be the same as acute symptoms. Repeated, low concentration skin
contact of this product may cause dermatitis. Methanol is only very slowly eliminated from the body. Because of this
slow elimination, methanol should be regarded as a cumulative poison. Though a single exposure may cause no
effect, daily exposure may result in the accumulation of a harmful amount.

TARGET ORGANS:
Acute: Eyes, central nervous system, skin.
Chronic: Eyes, skin, cardiovascular system. Currently, the following toxicity data are available for Methanol.
Standard Draize Test (Skin-Rabbit, adult) 20 mg/24hours Moderate irritation effects
Standard Draize Test (Eye-Rabbit, adult) 100 mg/24 hours Moderate irritation effects
DNA Inhibition (Human-lymphocyte) 300 mmol/L
Microsomal Mutagenicity Assay (Mouse-lymphocyte) 7900 mg/L
LC50 (Inhalation-Rat) 64,000 ppm/4 hours
LD50 (Oral-Rat) 5628 mg/kg
LD50 (Oral-Mouse) 7300 mg/kg
LD50 (Intraperitoneal-Rat) 7529 mg/kg
LD50 (Intraperitoneal-Mouse) 10,765 mg/kg
LD50 (Intravenous-Rat) 2131 mg/kg
LD50 (Subcutaneous-Mouse) 9800 mg/kg
LD50 (Intravenous-Mouse) 4710 mg/kg
TCLo (Inhalation-Rat) 10,000 ppm/7 hours (7-15 days preg): Teratogenic effects
TCLo (Inhalation-Human) 86,000 mg/m3: Eye effects, Pulmonary system effects
TCLo (Inhalation-Human) 300 ppm: Eye effects, Central nervous system effects, Pulmonary system effects
LDLo (Oral-Man) 6422 mg/kg: Central nervous system effects, Pulmonary system effects, Gastrointestinal tract
effects
LDLo (Oral-Human) 428 mg/kg: Central nervous system effects, Pulmonary system effects
LDLo (Oral-Human) 143 mg/kg: Eye effects, Pulmonary system effects, Gastrointestinal tract effects
TDLo (Oral-Woman) 4 g/kg: Eye effects, Pulmonary system effects, Gastrointestinal tract effects
TDLo (Oral-Woman) 4 g/kg
TDLo (Oral-Man) 3429 mg/kg: Eye effects
TDLo (Oral-Rat) 7500 mg/kg (17-19 days preg): Reproductive effects
LDLo (Oral-Monkey) 1000 mg/kg
LDLo (Skin-Monkey) 393 mg/kg
LCLo (Inhalation-Monkey) 1000 ppm.

Principal Routes of Exposure

Irritation This product may cause moderate irritation to the eyes and mild irritation of the
skin and respiratory system.

Corrosivity Conclusive but not sufficient for classification

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 Sensitization This product is not known to cause human skin or respiratory sensitization.

STOT - Single Exposure Conclusive but not sufficient for classification

STOT - Repeated Exposure Conclusive but not sufficient for classification

Carcinogenicity This material is not found on the following lists: U.S. EPA, U.S. NTP, U.S. OSHA,
U.S. NIOSH, GERMAN MAK, IARC, and ACGIH, and therefore are not considered
to be, nor suspected to be cancer-causing agents by these agencies.

Mutagenicity Methanol is not reported to cause human mutagenic effects. There is insufficient
information available to conclude that methanol is mutagenic. A positive result was
obtained in a limited oral study in mice, however other oral and inhalation studies
in live rats and mice have given negative results. Mostly negative results have
been obtained in cultured mammalian cells, bacteria and fruit flies (Drosophila).

Reproductive toxicity Listed below is information concerning the effects of Methanol on human and
animal reproductive systems.
/Teratogenicity: Methanol is not reported to cause human embryotoxic or
teratogenic effects. Methanol has produced fetotoxicity in rats and teratogenicity
in mice exposed by inhalation to high concentrations that did not produce
significant maternal toxicity.
Toxicity: Methanol is not reported to cause human reproductive effects.

Aspiration hazard Conclusive but not sufficient for classification

SYNERGISTIC MATERIALS
No synergistic materials are known.

ACGIH BIOLOGICAL EXPOSURE INDICES (BEIs)

Currently, ACGIH Biological Exposure Indices (BEIs) have not been determined for the components of this product.

SECTION 12: Ecological information

Toxicity
Methanol may cause harm to organisms if released to the environment. The following aquatic toxicity data are
available. Due to the large volume of data available, only select data are provided in this SDS. Contact EP Scientific
for information on additional data.
EC50 (Daphnia magna Water flea; immobilization) 24 hours = > 10,000 mg/L
LC50 (Pimephales promelas fathead minnows) 96 hours = 29.4 g/L
LC50 (Oncorhynchus mykiss Rainbow trout, 0.8 g) 96 hours = 19,000 mg/L
LC50 (Lepomis macrochirus Bluegill) 96 hours = 15,400 mg/L; flow-through
LC50 (Alburnus alburnus Bleak, 8 cm) 96 hours = 28,000 mg/L; static
LC50 (Nitocra spinipes Harpacticoid copepod, adult) 96 hours = 12,000 mg/L LC50 (Helisoma trivolvis aquatic
mollusk) 96 hours = > 100 mg/L
LC50 (Dugesia tigrina aquatic worm) 96 hours = > 100 mg/L
LC50 (Lumbriculus variegatus aquatic worm) 96 hours = > 100 mg/L
LC50 (Crangon crangon Brown shrimp, adult) 96 hours = 1340 mg/L
LC50 (Mytilus edulis Mussel, 5-7 cm) 96 hours = 15,900 mg/L
LC50 (Agonus cataphractus Armed bullhead, adult) 96 hours = 7900-26,070 mg/L.

Mobility Using a structure estimation method based on molecular connectivity indices, the
Koc for Methanol can be estimated to be 1. According to a classification scheme,
this estimated Koc value suggests that Methanol is expected to have very high
mobility in soil.

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Persistence and degradability If released to the atmosphere, a vapor pressure of 127 mm Hg at 25°C indicates
that Methanol will exist solely in the vapor phase. Vapor phase Methanol is
degraded in the atmosphere by reaction with photochemically-produced hydroxyl
radicals; the half-life for this reaction in air is estimated to be 17 days. If released
to soil, Methanol is expected to have very high mobility based upon an estimated
Koc of 1. Volatilization from moist soil surfaces is expected to be an important fate
process based upon a Henry's Law constant of 4.55X10-6 atm-cu m/mole.
Methanol may also volatilize from dry soils based upon it vapor pressure.
Biodegradation of methanol in soils is expected to occur rapidly based on
half-lives in a sandy silt loam from Texas and a sandy loam from Mississippi of 1
and 3.2 days, respectively. If released into water, Methanol is not expected to
adsorb to suspended solids and sediment based upon the estimated Koc.
Volatilization from water surfaces is expected to be an important fate process
based upon this compound's Henry's Law constant. Estimated volatilization
half-lives for a model river and model lake are 3 and 35 days, respectively.
Biodegradation is expected to occur in natural waters since methanol is degraded
quickly in soils and was biodegraded rapidly in various aqueous screening tests
using sewage seed or activated sludge. Hydrolysis of Methanol and photolysis in
sunlit surface waters are not expected since methanol lacks functional groups that
are susceptible to hydrolysis or photolysis under environmental conditions.

Bioaccumulative potential Fish (golden ide) exposed to 0.05 mg/L of Methanol for three days in an aquatic
tank had measured BCF values of less than 10. Based on a classification
scheme, this BCF value suggests that bioconcentration in aquatic organisms is
low.

Results of PBT and vPvB assessment

No information available.
EXPOSURE CONTROLS: Controls should be engineered to prevent release to the environment, including
procedures to prevent spills, atmospheric release and release to waterways.

Other adverse effects Components of this product are not listed or expected to have having ozone
depletion potential.

SECTION 13: Disposal considerations

Waste treatment methods

It is the responsibility of the generator to determine at the time of disposal whether the product meets the criteria of a
hazardous waste per regulations of the area in which the waste is generated and/or disposed of. Waste disposal must
be in accordance with appropriate Federal, State, and local regulations. This product, if unaltered by use, may be
disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority.
Shipment of wastes must be done with appropriately permitted and registered transporters.

DISPOSAL CONTAINERS: Waste materials must be placed in and shipped in appropriate 5-gallon or 55-gallon poly
or metal waste pails or drums. Permeable cardboard containers are not appropriate and should not be used. Ensure
that any required marking or labeling of the containers be done to all applicable regulations.

PRECAUTIONS TO BE FOLLOWED DURING WASTE HANDLING: Wear proper protective equipment when
handling waste materials. Dispose of in accordance with applicable Federal, State, and local procedures and
standards.

EPA Waste number

Wastes from this product should be tested to see if they meet D001 (Waste Characteristic-Ignitability). RCRA U
Series Wastes: CAS# 67-56-1: waste number U154 (Ignitable waste).
WASTE CODES: 16 05 08: Discarded Organic Chemicals Consisting of or Containing Dangerous Substances.

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 SECTION 14: Transport information

INTERNATIONAL AIR TRANSPORT ASSOCIATION SHIPPING INFORMATION (IATA)

This product is classified as dangerous goods, per the International Air Transport Association.
UN number UN 1230
UN proper shipping name Methanol
Transport hazard class(es) 3 (Flammable), 6.1 (Toxic)
Packing group II
Excepted Quantities E2
Passenger and Cargo Aircraft Packing Instruction 352
Passenger and Cargo Aircraft Maximum Net 1L
Quantity per Pkg.
Passenger and Cargo Aircraft Limited Quantity Y341
Packing Instruction
Passenger and Cargo Aircraft Limited Quantity 1L
Maximum Net Quantity per Pkg
Cargo Aircraft Only Packing Instruction 364
Cargo Aircraft Only Maximum Net Quantity per 60 L
Pkg.
Special Provisions A104, A113
ERG Code 3P

U.S. DEPARTMENT OF TRANSPORTATION REGULATIONS

This product is classified as dangerous goods, per U.S. DOT regulations, under 49 CFR 172.101.
UN number UN 1230
UN proper shipping name Methanol
Transport hazard class(es) 3 (Flammable), 6.1 (Toxic)
Packing group II
DOT Label(s) Required Class 3 (Flammable), 6.1 (Toxic)
Emergency Response Guidebook Number, 2012 128
Marine Pollutant Methanol does not meet the criteria of the DOT as Marine
Pollutant (as defined by 49 CFR 172.101, Appendix B).
NOTE: Shipments of this product may be shipped under
small quantity and limited quantity exceptions as indicated
under 49 CFR §173.4 and 49 CFR §173.154, if all
requirements are met.
Quantity Exception
Small Quantity Exception (49 CFR 173.4): Small quantities of Class 3 material are not subjected to other
requirements of the Hazardous Materials Regulations (Subchapter C) when the maximum quantity per inner
receptacle is limited to 30 mL (1 oz). Refer to 49 CFR 173.4 for specific information in packaging small quantity
materials.
Limited Quantity Exceptions [49 CFR 173.150(b)]: Limited quantities for Class 3, Packing Group II materials have
inner packagings not over 1.0 L net capacity each, packed in strong outer packaging.
.

TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS

This product is classified as Dangerous Goods, per regulations of Transport Canada.
UN number UN 1230
UN proper shipping name Methanol
Transport hazard class(es) 3 (Flammable), 6.1 (Toxic)
Packing group II
Hazard Label(s) Required Class 3 (Flammable), Class 6.1 (Toxic)
Special Provisions 43
Explosive Limit and Limited Quantity Index 1
ERAP Index None.
Passenger Carrying Ship Index None
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 Passenger Carrying Road or Rail Vehicle Index 1
Marine Pollutant This product does not meet the criteria to be a Marine
Pollutant.

INTERNATIONAL MARITIME ORGANIZATION SHIPPING INFORMATION (IMO)

This product is classified as dangerous goods, per the International Maritime Organization.
UN number UN 1230
UN proper shipping name Methanol
Transport hazard class(es) 3 (Flammable), 6.1 (Toxic)
Packing group II
Hazard Label(s) Required Class 3 (Flammable), Class 6.1 (Toxic)
Special Provisions 279
Excepted Quantities E2
Limited Quantities 1L
IBCs Instructions: IBC02; Provisions: None
EmS F-E, S-D
Stowage and Segregation Category B. Clear of living quarters.
Marine Pollutant This product does not meet the criteria to be a Marine
Pollutant.

EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY

ROAD (ADR)
This product is classified by the Economic Commission for Europe to be dangerous goods.
UN number UN 1230
UN proper shipping name Methanol
Transport hazard class(es) 3 (Flammable), 6.1 (Toxic)
Packing group II
Classification Code FT1
Label 3 + 6.1
Special Provisions 279
Limited Quantities 1L
Excepted Quantities E2
Packing Instructions P001, IBC02
Packing Special Provisions None
Mixed Packing Provisions MP19
Portable Tank & Bulk Container Packing T7
Instructions
Portable Tank & Bulk Container Special Provisions TP2
Hazard Identification No. 336

Environmental hazards
This material does not meet the criteria of environmentally hazardous according to the criteria of the UN Model
Regulations (as reflected in the IMDG Code, ADR, RID, and ADN); components are not specifically listed in Annex III
under MARPOL 73/78

Special precautions for user

Not Applicable

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
See the information under the individual jurisdiction listings for IBC information.

SECTION 15: Regulatory information

United States regulations

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U.S. SARA Threshold Planning Quantity (TPQ): There are no specific Threshold Planning Quantities for this material.
The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lb (4,540 kg) may apply,
per 40 CFR 370.20.
U.S. CERCLA Reportable Quantity (RQ): 5000 lb (2270 kg)
U.S. TSCA INVENTORY STATUS: Methanol is listed on the TSCA Inventory.
Other U.S. Federal Regulations: Methanol is listed as a hazardous air pollutant (HAP) generallyknown or suspected
to cause serious health problems. The Clean Air Act, as amended in 1990, directs EPA to set standards requiring
major sources to sharply reduce routine emissions of toxic pollutants. EPA is required to establish and phase in
specific performance based standards for all air emission sources that emit one or more of the listed pollutants.
Methanol is included on this list.

Chemical CAS-No Weight % SARA 302(40 CFR SARA 304(40 CFR SARA 313(40 CFR
Name 355, Appendix A) Table 302.4) 372.65)
Methyl alcohol 67-56-1 100 No No Yes

California Proposition 65
Methanol is on the California Proposition 65 Lists. WARNING! This compound is known to the State of California to
cause developmental harm.
Chemical Name CAS-No Weight % Category
Methyl alcohol 67-56-1 100 Developmental

Canadian regulations

Canadian DSL/NDSL Status: Methanol is listed on the DSL inventory.

Canadian Environmental Protection Agency (CEPA) Priorities Substances List: Methanol is a Substance with
Greatest Potential For Human Exposure Substance on Environment Canada/Health Canada Pilot Project List (CEPA
1999, Section 73). Meets categorization criteria: *may present, to individuals in Canada, the greatest potential for
exposure; or *are persistent or bio-accumulative in accordance with the regulations, and inherently toxic to human
beings or to non-human organisms, as determined by laboratory or other studies..

WHMIS Hazard Class

B2 - Flammable liquid
D1B - Toxic materials
D2A - Very toxic materials
D2B - Toxic materials

SECTION 16: Other information

Reason for revision SDS sections updated.

Revision number 1
Revision date 29-Dec-2017

Product Use: Various.

References
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•LOLIdatabase:ht tps:
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-dat
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"The above information was acquired by diligent search and/or investigation and the recommendations are based on
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prudent application of professional judgment. The information shall not be taken as being all inclusive and is to be
used only as a guide. All materials and mixtures may present unknown hazards and should be used with caution.
Since the Company cannot control the actual methods, volumes, or conditions of use, the Company shall not be held
liable for any damages or losses resulting from the handling or from contact with the product as described herein.
THE INFORMATION IN THIS SDS DOES NOT CONSTITUTE A WARRANTY, EXPRESSED OR
IMPLIED,INCLUDING ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR ANY PARTICULAR
PURPOSE"

End of Safety Data Sheet

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