REMA TIP TOP Australia Pty Ltd.

Safety Data Sheet

According to the Model WHS Regulations and the ADG code

TIP TOP CEMENT SC-BL

Revision date: 29.11.2017 Product code: 00156-0083AUS Page 1 of 11

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
TIP TOP CEMENT SC-BL
Art.-No.
506 0160, 506 0351, 506 0352, 506 4357, 510 1155, 510 1156, 510 1165, 510 1832, 510 1833, 510 1848, 510
1849, 510 3256, 510 3257, 510 3304, 510 3407, 510 3408, 510 3438, 510 3500, 510 3501, 510 3517, 510 3603,
510 3610, 510 3710, 514 1150, 514 1591, 514 3113, 514 4740, 515 9152, 515 9303, 515 9327, 515 9328, 515
9329, 515 9334, 515 9335, 515 9336, 515 9337, 515 9341, 515 9342, 515 9358, 515 9359, 515 9365, 515 9388,
515 9389, 515 9396, 515 9397, 515 9406, 515 9407, 516 9025, 516 9033, 516 9040, 516 9087

1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
adhesive
1.3. Details of the supplier of the safety data sheet
Company name: REMA TIP TOP Australia Pty Ltd.
Street: 3 - 7 Ironbark Close
Place: Warabrook
NSW 2304 / Australia
Telephone: +61-2-4935-0200
Internet: www.rema-tiptop.com.au
Responsible Department: Responsible for the safety data sheet: sds@gbk-ingelheim.de
1.4. Emergency telephone +61-280735031, Infotrac/GBK GmbH-ID: 93591
number:

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
CLASSIFIED AS HAZARDOUS CHEMICAL ACCORDING TO SAFE WORK AUSTRALIA AND WHS CRITERIA
CLASSIFIED AS DANGEROUS GOODS ACCORDING TO THE ADG CODE
POISON SCHEDULE: S5
Classification according to WHS
Hazard categories:
Flammable liquid: Flam. Liq. 2
Serious eye damage/eye irritation: Eye Irrit. 2A
Specific target organ toxicity - single exposure: STOT SE 3
Hazardous to the aquatic environment: Aquatic Chronic 2
Hazard Statements:
Highly flammable liquid and vapour.
Causes serious eye irritation.
May cause drowsiness or dizziness.
Toxic to aquatic life with long lasting effects.

2.2. Label elements

Component(s) to be indicated on the label
Ethyl acetate 60 - < 65 %
Aliphatic Hydrocarbons 10 - < 25 %
non hazardous ingredients 10 - < 30 %
Signal word: Danger

Revision No: 3,1 AUS Print date: 29.11.2017

 REMA TIP TOP Australia Pty Ltd.
Safety Data Sheet
According to the Model WHS Regulations and the ADG code

TIP TOP CEMENT SC-BL

Revision date: 29.11.2017 Product code: 00156-0083AUS Page 2 of 11

Pictograms:

flame exclamation mark environment

Hazard statements
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements
P102 Keep out of reach of children.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash Hands thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or
shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 Call a POISON CENTER/doctor if you feel unwell.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P391 Collect spillage.
P235 Keep cool.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container to waste treatment facility in accordance with local and national
regulations .

Special labelling of certain mixtures

AUH066 Repeated exposure may cause skin dryness or cracking.
2.3. Other hazards
Vapours may form explosive mixture with air.

SECTION 3: Composition/information on ingredients

3.2. Mixtures
Chemical characterization
Preparation with ethyl acetate

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 REMA TIP TOP Australia Pty Ltd.
Safety Data Sheet
According to the Model WHS Regulations and the ADG code

TIP TOP CEMENT SC-BL

Revision date: 29.11.2017 Product code: 00156-0083AUS Page 3 of 11

Hazardous components
CAS No Chemical name Quantity
EC No Classification according to WHS criteria
141-78-6 Ethyl acetate 60 - < 65 %
205-500-4 Flam. Liq. 2, Eye Irrit. 2A, STOT SE 3; H225 H319 H336 AUH066
64742-49-0 Hydrocarbons, C7-C9, n-alkanes, isoalkanes, cyclics 10 - < 25 %
920-750-0 Flam. Liq. 2, STOT SE 3, Asp. Tox. 1, Aquatic Chronic 2; H225 H336 H304 H411 AUH066
14634-93-6 Zinc-bis (N-ethyl-N-phenyldithiocarbamate) <5%
238-677-1 Eye Irrit. 2A, Aquatic Chronic 4; H319 H413
5459-93-8 N-Cyclohexyl-N-ethylamine <1%
226-733-8 Flam. Liq. 3, Acute Tox. 3, Acute Tox. 4, Acute Tox. 4, Skin Corr. 1B, Aquatic Chronic 3; H226 H311
H332 H302 H314 H412
1314-13-2 Zinc oxide <1%
215-222-5 Aquatic Acute 1, Aquatic Chronic 1; H400 H410
non hazardous ingredients 10 - < 30 %

Full text of H and AUH phrases: see section 16.

Further Information
According to note P to labelling (Australian Hazardous Chemical Information System (HCIS)), "Solvent naphta
(petroleum)" is not to be classified as "carcinogenic" or "mutagen" ingredient because a benzene content (EINECS
No. 200-753-7) is below 0.1 % by weight.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information
Remove contaminated soaked clothing immediately.
If you feel unwell, seek medical advice.
Take away from danger area and lay down affected person.
After inhalation
Move to fresh air in case of accidental inhalation of vapours or decomposition products.
In the event of symptoms refer for medical treatment.
After contact with skin
Wash off with soap and plenty of water.
Consult a doctor if skin irritation persists.
After contact with eyes
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Seek medical treatment by eye specialist.
After ingestion
Do not induce vomiting.
Summon a doctor immediately.
Induce vomiting only upon the advice of a physician.
4.2. Most important symptoms and effects, both acute and delayed
Causes serious eye irritation.
May cause drowsiness or dizziness.
Repeated exposure may cause skin dryness or cracking.
Attention. Beware, danger of aspiration.
4.3. Indication of any immediate medical attention and special treatment needed

Revision No: 3,1 AUS Print date: 29.11.2017

 REMA TIP TOP Australia Pty Ltd.
Safety Data Sheet
According to the Model WHS Regulations and the ADG code

TIP TOP CEMENT SC-BL

Revision date: 29.11.2017 Product code: 00156-0083AUS Page 4 of 11
Treat symptoms.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media
Foam, carbon dioxide (CO2), dry chemical, water-spray.
Unsuitable extinguishing media
Full water jet.
5.2. Special hazards arising from the substance or mixture
Fire may produce:
carbon monoxide and carbon dioxide.
5.3. Advice for firefighters
Use breathing apparatus with independent air supply.
Protective suit.
HAZCHEM: 3Y
Additional information
Vapours are heavier than air and spread along ground.
The vapour/air mixture is explosive, even in empty, uncleaned receptacles.
Cool containers at risk with water spray jet.
Fire residues and contaminated firefighting water must be disposed of in accordance with the local regulations.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

In case of vapour formation use respirator.
Use only explosion-proof equipment.
Ensure adequate ventilation.
Use personal protective clothing.
Keep away sources of ignition.
6.2. Environmental precautions
Do not discharge into the drains/surface waters/ground water.
6.3. Methods and material for containment and cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder).
Shovel into suitable container for disposal.
6.4. Reference to other sections
Observe protective instructions (see Sections 7 and 8).
Information for disposal see section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
Keep container tightly closed.
Vapours are heavier than air and spread along ground.
Keep a good ventilation and air-exhaust at the place of work.
Avoid contact with skin, eyes and clothing.
Advice on protection against fire and explosion
Keep away from heat and sources of ignition.
Do not smoke.
Take precautionary measures against static discharges.
Use only explosion-proof equipment.
7.2. Conditions for safe storage, including any incompatibilities
Revision No: 3,1 AUS Print date: 29.11.2017
 REMA TIP TOP Australia Pty Ltd.
Safety Data Sheet
According to the Model WHS Regulations and the ADG code

TIP TOP CEMENT SC-BL

Revision date: 29.11.2017 Product code: 00156-0083AUS Page 5 of 11

Requirements for storage rooms and vessels

Keep container tightly closed in a dry, cool and well-ventilated place.
Pay attention to anti-explosion rules.
Advice on storage compatibility
Incompatible with:
Oxidizing agents.
Nitrous acid and other nitrosating agents.
Further information on storage conditions
Keep away from food, drink and animal feeding stuffs.
7.3. Specific end use(s)
adhesive
SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational Exposure Limits (OEL) - Australia
CAS No Substance ppm mg/m3 Category
141-78-6 Ethyl acetate 200 720 TWA
141-78-6 Ethyl acetate 400 1440 STEL
1314-13-2 Zinc oxide (dust) - 10 TWA
1314-13-2 Zinc oxide (dust) - - STEL
1314-13-2 Zinc oxice (fume) - 5 TWA
1314-13-2 Zinc oxice (fume) - 10 STEL

Exposure limits (EH40)

CAS No Substance ppm mg/m³ fibres/ml Category Origin

141-78-6 Ethyl acetate 200 - TWA (8 h) WEL

400 - STEL (15 min) WEL

8.2. Exposure controls

Appropriate engineering controls
Ensure adequate ventilation, especially in confined areas.
Protective and hygiene measures
Do not inhale vapours.
Wash hands before breaks and immediately after handling the product.
When using do not eat, drink or smoke.
Treat subsequently with skin cream.
Remove and wash contaminated clothes before re-use.
Eye/face protection
Tightly fitting goggles.
Eye wash bottle with pure water.
Hand protection
Splash protection:
Protective gloves resistant to chemicals made off natural-rubber latex, minimum coat thickness 0.6 mm, permeation
resistance (wear duration) approx. 10 minutes, i.e. protective glove <Lapren 706> made by www.kcl.de.
Protective gloves resistant to chemicals made off butyl, minimum coat thickness 0.7 mm, permeation resistance
(wear duration) > 60 minutes, i.e. protective glove <Butoject 898> made by www.kcl.de.
This recommendation refers exclusively to the chemical compatibility and the lab test conforming to EN 374 carried
out under lab conditions.
Requirements can vary as a function of the use. Therefore it is necessary to adhere additionally to the

Revision No: 3,1 AUS Print date: 29.11.2017

 REMA TIP TOP Australia Pty Ltd.
Safety Data Sheet
According to the Model WHS Regulations and the ADG code

TIP TOP CEMENT SC-BL

Revision date: 29.11.2017 Product code: 00156-0083AUS Page 6 of 11
recommendations given by the manufacturer of protective gloves.
Skin protection
Solvent-resistant apron.
Respiratory protection
In case of insufficient ventilation wear suitable respiratory equipment (gas filter type A).

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state: Viscous liquid
Colour: Blue
Odour: Ester-like
Test method
pH-Value: No information available.
Changes in the physical state
Melting point: No information available.
Initial boiling point and boiling range: > 35 °C
Flash point: - 20 °C DIN EN ISO 3679
Flammability
Solid: No information available.
Explosive properties
No information available.
Lower explosion limits: 2.1 vol. %
Upper explosion limits: 11.5 vol. %
Ignition temperature: 460 °C
Auto-ignition temperature
Solid: No information available.
Decomposition temperature: No information available.
Oxidizing properties
No information available.
Vapour pressure: 100 hPa
(at 20 °C)
Density (at 20 °C): 0.88 g/cm³
Water solubility: Immiscible
(at 20 °C)
Solubility in other solvents
No information available.
Partition coefficient: No information available.
Viscosity / dynamic: 4500 - 6500 mPa·s
(at 20 °C)
Viscosity / kinematic: 3740 - 3820 mm²/s
(at 40 °C)
Flow time: 385 s 6 DIN EN ISO 2431
(at 23 °C)
Vapour density: No information available.
Evaporation rate: No information available.
Solvent separation test: < 3%

Revision No: 3,1 AUS Print date: 29.11.2017

 REMA TIP TOP Australia Pty Ltd.
Safety Data Sheet
According to the Model WHS Regulations and the ADG code

TIP TOP CEMENT SC-BL

Revision date: 29.11.2017 Product code: 00156-0083AUS Page 7 of 11

Solvent content: < 85 %

9.2. Other information
No data available.

SECTION 10: Stability and reactivity

10.1. Reactivity
No decomposition if stored and applied as directed.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
Reactions with oxidizing agents.
10.4. Conditions to avoid
To avoid thermal decomposition, do not overheat.
Vapour/air mixtures are explosive at intensive warming.
Heating can release vapours which can be ignited.
10.5. Incompatible materials
Nitrous acid and other nitrosating agents.
oxidizing agents.
10.6. Hazardous decomposition products
Carbon monoxide and carbon dioxide
An inappropriate handling, for instance major amounts of product combined with strong heat and nitrosating agents,
renders possible a cleavage of nitrosamines in traces.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity
Based on available data, the classification criteria are not met.
No toxicological data available.
Irritation and corrosivity
Causes serious eye irritation.
Skin corrosion/irritation: Based on available data, the classification criteria are not met.
Sensitising effects
Based on available data, the classification criteria are not met.
Carcinogenic/mutagenic/toxic effects for reproduction
Based on available data, the classification criteria are not met.
STOT-single exposure
May cause drowsiness or dizziness. (Ethyl acetate ; Hydrocarbons, C7-C9, n-alkanes, isoalkanes, cyclics)
STOT-repeated exposure
Repeated exposure may cause skin dryness or cracking.
Aspiration hazard
Based on available data, the classification criteria are not met.
Practical experience
Other observations
Effects of breathing high concentrations of vapour may include: Headache, dizziness, weakness, unconsciousness.
Repeated or prolonged exposure may cause skin irritation and dermatitis, due to degreasing properties of the
product.

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 REMA TIP TOP Australia Pty Ltd.
Safety Data Sheet
According to the Model WHS Regulations and the ADG code

TIP TOP CEMENT SC-BL

Revision date: 29.11.2017 Product code: 00156-0083AUS Page 8 of 11

Further information
An inappropriate handling, for instance major amounts of product combined with strong heat and nitrosating agents,
renders possible a cleavage of nitrosamines in traces.

SECTION 12: Ecological information

12.1. Toxicity
Ecological data are not available.
Toxic to aquatic life with long lasting effects.
Hydrocarbons, C6-C7, n-alkanes, iso-alkanes, cyclic compounds, < 3% n-hexane
LC50/EC50/EC50 : 1 - 10 mg/l
Zinc oxide
EC50/Ceriodaphnia dubia/48 h = 0.01 - 0.1 mg/l
EC50/Selenastrum capricornutum/72 h = 0.01 - 0.1 mg/l
N-Cyclohexyl-N-ethylamine
EC50/Daphnia magna/48 h = 10 - 100 mg/l
ErC50/Desmodesmus subspicatus/72 h = 10 - 100 mg/l
N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine
Ethyl acetate
LC50/EC50/EC50 : > 100 mg/l
12.2. Persistence and degradability
No data available.
12.3. Bioaccumulative potential
No data available.
12.4. Mobility in soil
No data available.
12.5. Results of PBT and vPvB assessment
According to Regulation (EC) No 1907/2006 (REACH) none of the substances, contained in this product are a PBT /
vPvB substance.
12.6. Other adverse effects
Hazardous water pollutant
Further information
Do not flush into surface water or sanitary sewer system.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Advice on disposal
Where possible recycling is preferred to disposal.
Can be incinerated, when in compliance with local regulations.
The waste code number must be agreed with the disposer / manufacturer / competent authority.
Contaminated packaging
Empty containers should be taken for local recycling, recovery or waste disposal.
Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken for
reuse.
Packaging that cannot be cleaned should be disposed of like the product.

SECTION 14: Transport information

FLAMMABLE
LIQUID
3

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 REMA TIP TOP Australia Pty Ltd.
Safety Data Sheet
According to the Model WHS Regulations and the ADG code

TIP TOP CEMENT SC-BL

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Land transport (ADG)

14.1. UN number: UN 1133
14.2. UN proper shipping name: Adhesives
14.3. Transport hazard class(es): 3
14.4. Packing group: III
Hazard label: 3
Special Provisions: 223
Limited quantity: 5 L / 30 kg
Other applicable information (land transport)
HAZCHEM: 3Y
Marine transport (IMDG)
14.1. UN number: UN 1133
14.2. UN proper shipping name: Adhesives
14.3. Transport hazard class(es): 3
14.4. Packing group: III
Hazard label: 3
Marine pollutant: YES
Limited quantity: 5 L / 30 kg
Excepted quantity: E1
EmS: F-E, S-D
Other applicable information (marine transport)
Receptacle max. 30 L, IMDG Code subsection 2.3.2.2
Segregation group: -
Air transport (ICAO-TI/IATA-DGR)
14.1. UN number: UN 1133
14.2. UN proper shipping name: Adhesives
14.3. Transport hazard class(es): 3
14.4. Packing group: III
Hazard label: 3
Limited quantity Passenger: 10 L
Passenger LQ: Y344
Excepted quantity: E1
IATA-packing instructions - Passenger: 355
IATA-max. quantity - Passenger: 30 L (*)
IATA-packing instructions - Cargo: 366
IATA-max. quantity - Cargo: 100 L (*)
Other applicable information (air transport)
*) [3.3.3.1 IATA DGR]
14.5. Environmental hazards
ENVIRONMENTALLY HAZARDOUS: yes

Danger releasing substance: Hydrocarbons, C7-C9, n-alkanes, isoalkanes, cyclics

14.6. Special precautions for user
Handle in accordance with good industrial hygiene and safety practice.
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
The transport takes place only in approved and appropriate packaging.

Revision No: 3,1 AUS Print date: 29.11.2017

 REMA TIP TOP Australia Pty Ltd.
Safety Data Sheet
According to the Model WHS Regulations and the ADG code

TIP TOP CEMENT SC-BL

Revision date: 29.11.2017 Product code: 00156-0083AUS Page 10 of 11

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
Restrictions on use (REACH, annex XVII):
Entry 28: Hydrocarbons, C7-C9, n-alkanes, isoalkanes, cyclics
2004/42/EC (VOC): 80 - 85 %
National regulatory information
Water contaminating class (D): 2 - clearly water contaminating
Additional information
Poison Schedule: S5
All components of this mixture are listed on or exempted from AICS.
15.2. Chemical safety assessment
Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information

Changes
Changes in chapter: 5, 9, 14.

Abbreviations and acronyms

ADG = Australian Code for the Transport of Dangerous Goods by Road & Rail
IMDG = International Maritime Code for Dangerous Goods
IATA/ICAO = International Air Transport Association / International Civil Aviation Organization
MARPOL = International Convention for the Prevention of Pollution from Ships
IBC-Code = International Code for the Construction and Equipment of Ships Carrying Dangerous Chemicals in Bulk
HAZCHEM = HAZardous CHEMicals
WHS = Work Health and Safety
NOHSC = National Occupational Health and Safety Commission (Australia)
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
REACH = Registration, Evaluation, Authorization and Restriction of Chemicals
CAS = Chemical Abstract Service
EN = European norm
ISO = International Organization for Standardization
DIN = Deutsche Industrie Norm
PBT = Persistent Bioaccumulative and Toxic
vPvB = Very Persistent and very Bio-accumulative
LD = Lethal dose
LC = Lethal concentration
EC = Effect concentration
IC = Median immobilisation concentration or median inhibitory concentration

Relevant H and AUH phrases (number and full text)

H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H336 May cause drowsiness or dizziness.
H400 Very toxic to aquatic life.

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 REMA TIP TOP Australia Pty Ltd.
Safety Data Sheet
According to the Model WHS Regulations and the ADG code

TIP TOP CEMENT SC-BL

Revision date: 29.11.2017 Product code: 00156-0083AUS Page 11 of 11
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
H413 May cause long lasting harmful effects to aquatic life.
AUH066 Repeated exposure may cause skin dryness or cracking.
Further Information
Data of items 4 to 8, as well as 10 to 12, do partly not refer to the use and the regular employing of the product (in
this sense consult information on use and on product), but to liberation of major amounts in case of accidents and
irregularities.
The information describes exclusively the safety requirements for the product(s) and is based on the present level of
our knowledge.
The delivery specifications are contained in the corresponding product sheet.
This data does not constitute a guarantee for the characteristics of the product(s) as defined by the legal warranty
regulations.
(n.a. = not applicable; n.d. = not determined)

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data
sheet.)

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