Material Safety Data Sheet

DOW BRASIL INDUSTRIA E COMERCIO

DE PRODUTOS QUIMICOS LTDA.

Product name: DOWFAX™ DF 105 Defoamer Issue Date: 28.08.2023

Date of last issue: 27.08.2023
Print Date: 29.08.2023
DOW BRASIL INDUSTRIA E COMERCIO DE PRODUTOS QUIMICOS LTDA. encourages and
expects you to read and understand the entire (M)SDS, as there is important information throughout
the document. We expect you to follow the precautions identified in this document unless your use
conditions would necessitate other appropriate methods or actions.

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: DOWFAX™ DF 105 Defoamer

Relevant identified uses of the substance or mixture and uses advised against
Identified uses: For industrial use. Component(s) for the manufacture of urethane polymers. We
recommend that you use this product in a manner consistent with the listed use. If your intended use is
not consistent with the stated use, please contact your sales or technical service representative.

COMPANY IDENTIFICATION
DOW BRASIL INDUSTRIA E COMERCIO
DE PRODUTOS QUIMICOS LTDA.
AV. DAS NACOES UNIDAS 14171
EDIF DIAMOND TOWER - SANTO AMARO
04794-000 SAO PAULO - SP
BRAZIL

Customer Information Number: 0800 0474714

SDSQuestion@dow.com

EMERGENCY TELEPHONE NUMBER

24-Hour Emergency Contact: 0800-763-8422
Local Emergency Contact: 0800-763-8422

2. HAZARDS IDENTIFICATION
This product has been classified in accordance with ABNT NBR 14725-2, Chemicals - Safety, Health
and Environmental Information - Part 2: Hazard Classification System.

Hazard classification
Chemical product not classified as hazardous in accordance with ABNT NBR 14725-2.

Other hazards
No data available

3. COMPOSITION/INFORMATION ON INGREDIENTS

® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated Page 1 of 12

company of Dow
Product name: DOWFAX™ DF 105 Defoamer Issue Date: 28.08.2023

Synonyms: Alkylene glycol polymer

This product is a substance.
Component CASRN Concentration

Polyalkylene glycol 9003-11-6 >= 99,0 %

4. FIRST AID MEASURES

Description of first aid measures
General advice:
If potential for exposure exists refer to Section 8 for specific personal protective equipment.

Inhalation: Move person to fresh air and keep comfortable for breathing; consult a physician.

Skin contact: Wash off with plenty of water.

Eye contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the
initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a
physician, preferably an ophthalmologist.

Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by
medical personnel.

Most important symptoms and effects, both acute and delayed:

Aside from the information found under Description of first aid measures (above) and Indication of
immediate medical attention and special treatment needed (below), any additional important
symptoms and effects are described in Section 11: Toxicology Information.

Indication of any immediate medical attention and special treatment needed

Notes to physician: No specific antidote. Treatment of exposure should be directed at the control of
symptoms and the clinical condition of the patient.

5. FIREFIGHTING MEASURES
Extinguishing media

Suitable extinguishing media: Water fog or fine spray.. Dry chemical fire extinguishers..
Carbon dioxide fire extinguishers.. Foam.. Alcohol resistant foams (ATC type) are preferred.
General purpose synthetic foams (including AFFF) or protein foams may function, but will be
less effective..

Extinguishing Media to Avoid: Do not use direct water stream.. May spread fire..

Special hazards arising from the substance or mixture

Hazardous combustion products: During a fire, smoke may contain the original material in
addition to combustion products of varying composition which may be toxic and/or irritating. .
Combustion products may include and are not limited to:. Carbon monoxide.. Carbon dioxide..

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Product name: DOWFAX™ DF 105 Defoamer Issue Date: 28.08.2023

Unusual Fire and Explosion Hazards: Container may rupture from gas generation in a fire
situation.. Violent steam generation or eruption may occur upon application of direct water
stream to hot liquids..

Advice for firefighters

Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. .
Use water spray to cool fire exposed containers and fire affected zone until fire is out and
danger of reignition has passed.. Fight fire from protected location or safe distance. Consider
the use of unmanned hose holders or monitor nozzles.. Immediately withdraw all personnel
from the area in case of rising sound from venting safety device or discoloration of the
container.. Do not use direct water stream. May spread fire.. Move container from fire area if
this is possible without hazard.. Burning liquids may be moved by flushing with water to
protect personnel and minimize property damage.. Contain fire water run-off if possible. Fire
water run-off, if not contained, may cause environmental damage.. Review the "Accidental
Release Measures" and the "Ecological Information" sections of this (M)SDS. .

Special protective equipment for firefighters: Wear positive-pressure self-contained

breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet,
coat, trousers, boots, and gloves).. Avoid contact with this material during fire fighting
operations. If contact is likely, change to full chemical resistant fire fighting clothing with self-
contained breathing apparatus. If this is not available, wear full chemical resistant clothing
with self-contained breathing apparatus and fight fire from a remote location. . For protective
equipment in post-fire or non-fire clean-up situations, see Section 8 of the safety data sheet..

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures: Spilled material may
cause a slipping hazard. Use appropriate safety equipment. For additional information, refer to
Section 8, Exposure Controls and Personal Protection.

Removal of ignition sources: Keep away from sources of ignition - No smoking.

Dust Control: Not applicable

Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information.

Methods and materials for containment and cleaning up: Contain spilled material if possible.
Absorb with materials such as: Sand. Dirt. Collect in suitable and properly labeled containers. Do
not use water for cleanup. See Section 13, Disposal Considerations, for additional information.

7. HANDLING AND STORAGE

Precautions for safe handling: Keep container closed. This material is hygroscopic in nature. See
Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION.
Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition
temperatures possibly resulting in spontaneous combustion.

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Product name: DOWFAX™ DF 105 Defoamer Issue Date: 28.08.2023

Conditions for safe storage: Keep container tightly closed when not in use. Store in the following
material(s): Stainless steel. Polypropylene. Polyethylene-lined container. Teflon. Glass-lined
container. Aluminum. Plasite 3066 lined container. Plasite 3070 lined container. 316 stainless steel.

Storage stability
Storage temperature: Storage Period:
15 - 35 °C 24 Month

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
If exposure limits exist, they are listed below. If no exposure limits are displayed, then no values are
applicable.

Exposure controls
Engineering controls: Use local exhaust ventilation, or other engineering controls to maintain
airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure
limit requirements or guidelines, general ventilation should be sufficient for most operations. Local
exhaust ventilation may be necessary for some operations.

Individual protection measures

Eye/face protection: Use safety glasses (with side shields).
Skin protection
Hand protection: Chemical protective gloves should not be needed when handling
this material. Consistent with general hygienic practice for any material, skin contact
should be minimized.
Other protection: No precautions other than clean body-covering clothing should be
needed.
Respiratory protection: Under intended handling conditions, no respiratory protection should
be needed.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance
Physical state Liquid.
Color Clear
Odor Mild
Odor Threshold No test data available
pH 7,5 - 9,3 DOWM 101495
Melting point/range Not applicable to liquids
Freezing point Not reported See Pour Point
Boiling point (760 mmHg) Decomposes before boiling
Flash point closed cup 216 °C ASTM D 93
Evaporation Rate (Butyl Acetate No test data available
= 1)
Flammability (solid, gas) Not Applicable

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Product name: DOWFAX™ DF 105 Defoamer Issue Date: 28.08.2023

Flammability (liquids) Not expected to be a static-accumulating flammable liquid.

Lower explosion limit No test data available
Upper explosion limit No test data available
Vapor Pressure No test data available
Relative Vapor Density (air = 1) >1 Calculated.
Relative Density (water = 1) 1,015 at 25 °C / 25 °C Calculated.
Water solubility Calculated. partly soluble
Partition coefficient: n- No data available
octanol/water
Auto-ignition temperature No test data available
Decomposition temperature No test data available
Kinematic Viscosity 155 - 180 cSt at 38 °C ASTM D 445
Explosive properties Not explosive
Oxidizing properties No
Molecular weight 2.000 g/mol Calculated.
Pour point -32 °C Calculated.

NOTE: The physical data presented above are typical values and should not be construed as a
specification.

10. STABILITY AND REACTIVITY

Reactivity: No data available

Chemical stability: Stable under recommended storage conditions. See Storage, Section 7.

Possibility of hazardous reactions: Will not occur by itself.

Conditions to avoid: Product can oxidize at elevated temperatures. Generation of gas during
decomposition can cause pressure in closed systems.

Incompatible materials: Avoid contact with oxidizing materials. Avoid contact with: Strong acids.
Strong bases. Avoid unintended contact with isocyanates. The reaction of polyols and isocyanates
generates heat.

Hazardous decomposition products: Decomposition products depend upon temperature, air supply
and the presence of other materials.. Decomposition products can include and are not limited to:.
Carbon dioxide.. Alcohols.. Ethers.. Hydrocarbons.. Ketones.. Polymer fragments..

11. TOXICOLOGICAL INFORMATION

Toxicological information appears in this section when such data are available.

Information on likely routes of exposure

Ingestion, Inhalation, Skin contact, Eye contact.

Acute toxicity (represents short term exposures with immediate effects - no chronic/delayed
effects known unless otherwise noted)

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Product name: DOWFAX™ DF 105 Defoamer Issue Date: 28.08.2023

Acute Toxicity Endpoints:

Not classified based on available information.

Acute oral toxicity

Information for the Product:

Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal

handling operations are not likely to cause injury; however, swallowing larger amounts may
cause injury.

Typical for this family of materials.

LD50, Rat, > 4.000 mg/kg Estimated. No deaths occurred at this concentration.

Information for components:

Polyalkylene glycol
Typical for this family of materials. LD50, Rat, > 4.000 mg/kg Estimated. No deaths
occurred at this concentration.

Acute dermal toxicity

Information for the Product:

Prolonged skin contact is unlikely to result in absorption of harmful amounts.

Typical for this family of materials.

LD50, Rabbit, > 10.000 mg/kg

Information for components:

Polyalkylene glycol
Typical for this family of materials. LD50, Rabbit, > 10.000 mg/kg

Acute inhalation toxicity

Information for the Product:

At room temperature, exposure to vapor is minimal due to low volatility; single exposure is
not likely to be hazardous.

As product: The LC50 has not been determined.

Information for components:

Polyalkylene glycol
The LC50 has not been determined.

Skin corrosion/irritation

Not classified based on available information.

Information for the Product:

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Product name: DOWFAX™ DF 105 Defoamer Issue Date: 28.08.2023

Based on testing for product(s) in this family of materials:

Prolonged exposure not likely to cause significant skin irritation.

Information for components:

Polyalkylene glycol
Prolonged exposure not likely to cause significant skin irritation.
Material may be handled at elevated temperatures; contact with heated material may cause
thermal burns.

Serious eye damage/eye irritation

Not classified based on available information.

Information for the Product:

Based on testing for product(s) in this family of materials:

May cause slight temporary eye irritation.
Corneal injury is unlikely.

Information for components:

Polyalkylene glycol
May cause slight temporary eye irritation.
Corneal injury is unlikely.

Sensitization

For skin sensitization:

Not classified based on available information.

For respiratory sensitization:

Not classified based on available information.

Information for the Product:

For skin sensitization:

No relevant data found.

For respiratory sensitization:

No relevant data found.

Information for components:

Polyalkylene glycol
For skin sensitization:
No relevant data found.

For respiratory sensitization:

No relevant data found.

Specific Target Organ Systemic Toxicity (Single Exposure)

Not classified based on available information.

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Product name: DOWFAX™ DF 105 Defoamer Issue Date: 28.08.2023

Information for the Product:

Evaluation of available data suggests that this material is not an STOT-SE toxicant.

Information for components:

Polyalkylene glycol
Evaluation of available data suggests that this material is not an STOT-SE toxicant.

Aspiration Hazard

Not classified based on available information.

Information for the Product:

Based on physical properties, not likely to be an aspiration hazard.

Information for components:

Polyalkylene glycol
Based on physical properties, not likely to be an aspiration hazard.

Chronic toxicity (represents longer term exposures with repeated dose resulting in
chronic/delayed effects - no immediate effects known unless otherwise noted)

Specific Target Organ Systemic Toxicity (Repeated Exposure)

Not classified based on available information.

Information for the Product:

For similar material(s):

In animals, effects have been reported on the following organs after exposure to aerosols:
Lung.

Information for components:

Polyalkylene glycol
For similar material(s):
In animals, effects have been reported on the following organs after exposure to aerosols:
Lung.

Carcinogenicity

Not classified based on available information.

Information for the Product:

Product test data not available.

Information for components:

Polyalkylene glycol
No relevant data found.

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Product name: DOWFAX™ DF 105 Defoamer Issue Date: 28.08.2023

Teratogenicity

Not classified based on available information.

Information for the Product:

Product test data not available.

Information for components:

Polyalkylene glycol
No relevant data found.

Reproductive toxicity

Not classified based on available information.

Information for the Product:

Product test data not available.

Information for components:

Polyalkylene glycol
No relevant data found.

Mutagenicity

Not classified based on available information.

Information for the Product:

For this family of materials: In vitro genetic toxicity studies were negative. Animal genetic
toxicity studies were negative.

Information for components:

Polyalkylene glycol
No relevant data found.

12. ECOLOGICAL INFORMATION

Ecotoxicological information appears in this section when such data are available.

Ecotoxicity
Acute toxicity to fish
For this family of materials:
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).

For this family of materials:

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Product name: DOWFAX™ DF 105 Defoamer Issue Date: 28.08.2023

LC50, Cyprinus carpio (Carp), 96 Hour, > 100 mg/l

Acute toxicity to aquatic invertebrates

For this family of materials:
EC50, Daphnia magna, 48 Hour, > 100 mg/l

Persistence and degradability

Biodegradability: For this family of materials: Material is readily biodegradable. Passes
OECD test(s) for ready biodegradability.
For this family of materials: 10-day Window: Not applicable
Biodegradation: > 60 %
Exposure time: 28 d
Method: OECD Test Guideline 301F or Equivalent

Bioaccumulative potential
Bioaccumulation: No bioconcentration is expected because of the relatively high molecular
weight (MW greater than 1000).

Mobility in Soil
No relevant data found.

Results of PBT and vPvB assessment

This substance has not been assessed for persistence, bioaccumulation and toxicity (PBT).

Other adverse effects

This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

13. DISPOSAL CONSIDERATIONS

Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY
OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local
laws and regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility of the waste generator. AS YOUR SUPPLIER,
WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING
PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION
PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED
CONDITION AS DESCRIBED IN SDS SECTION 1: Identified Uses. FOR UNUSED &
UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed, permitted:
Recycler. Reclaimer. Incinerator or other thermal destruction device. For additional information, refer
to: Handling & Storage Information, MSDS Section 7 Stability & Reactivity Information, MSDS
Section 10 Regulatory Information, MSDS Section 15

Treatment and disposal methods of used packaging: Empty containers should be recycled or
otherwise disposed of by an approved waste management facility. Waste characterizations and
compliance with applicable laws are the responsibility of the waste generator. Do not re-use
containers for any purpose.

14. TRANSPORT INFORMATION

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Product name: DOWFAX™ DF 105 Defoamer Issue Date: 28.08.2023

ANTT
Not regulated for transport

Classification for SEA transport (IMO-IMDG):

Not regulated for transport
Transport in bulk Consult IMO regulations before transporting ocean bulk
according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code

Classification for AIR transport (IATA/ICAO):

Not regulated for transport

This information is not intended to convey all specific regulatory or operational

requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.

15. REGULATORY INFORMATION

It is recommended the customer to check in the location of use of this product whether it is specifically
regulated for human perusal or veterinary applications, as food and pharmaceuticals additives or
packaging, domissanitary, and cosmetics, or even as controlled agent recognized as precursor to
drug, chemical weapons, and ammunition manufacture.
The communication of the hazards of this product is in accordance with local and international
legislations, observing always the most restrictive requirement.

16. OTHER INFORMATION

Hazard Rating System

NFPA
Health Flammability Instability
1 1 0

Revision
Identification Number: 129756 / A125 / Issue Date: 28.08.2023 / Version: 6.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.

Full text of other abbreviations

AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by Land of
Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR - Carcinogen,
Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DSL -

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Product name: DOWFAX™ DF 105 Defoamer Issue Date: 28.08.2023

Domestic Substances List (Canada); ECx - Concentration associated with x% response; ELx -
Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New
Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG -
Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice;
IARC - International Agency for Research on Cancer; IATA - International Air Transport Association;
IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals
in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization;
IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime
Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law
(Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals
Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a
test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of
Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed
(Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No
Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program;
NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and
Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent,
Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical
Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No
1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition Temperature;
SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Transportation of
Dangerous Goods; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Control
Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the
Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative; WHMIS -
Workplace Hazardous Materials Information System

DOW BRASIL INDUSTRIA E COMERCIO DE PRODUTOS QUIMICOS LTDA. urges each customer
or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or
appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards
associated with the product. The information herein is provided in good faith and believed to be
accurate as of the effective date shown above. However, no warranty, express or implied, is given.
Regulatory requirements are subject to change and may differ between various locations. It is the
buyer's/user's responsibility to ensure that his activities comply with all federal, state, provincial or local
laws. The information presented here pertains only to the product as shipped. Since conditions for use
of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine
the conditions necessary for the safe use of this product. Due to the proliferation of sources for
information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for
(M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from
another source or if you are not sure that the (M)SDS you have is current, please contact us for the
most current version.
BR

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