SAFETY DATA SHEET

Guard Style E T
Section 1. Identification
Product name : Guard Style E T
Product code : 44765
Product type : Powder coating.
Other means of : Not available.
identification

Supplier's details : JOTUN INDIA PRIVATE LIMITED

Fulcrum, A wing – 601(II) / 602,
Next to Hyatt Regency,
Sahar Road, Andheri – East, Mumbai – 99
India

SDSJotun@jotun.com

Emergency telephone : Jotun India Pvt Ltd +91 2138 671300

number
44765 3 44765
^(ValidationDate) 1

Section 2. Hazards identification

Classification of the : ACUTE TOXICITY (oral) - Category 5
substance or mixture SERIOUS EYE DAMAGE/EYE IRRITATION - Category 1
SKIN SENSITISATION - Category 1
GERM CELL MUTAGENICITY - Category 1B
SHORT-TERM (ACUTE) AQUATIC HAZARD - Category 3
LONG-TERM (CHRONIC) AQUATIC HAZARD - Category 3

GHS label elements

Hazard pictograms :

Signal word : Danger.

Hazard statements : H303 - May be harmful if swallowed.
H318 - Causes serious eye damage.
H317 - May cause an allergic skin reaction.
H340 - May cause genetic defects.
H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements
Prevention : P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P280 - Wear protective gloves. Wear eye or face protection. Wear protective
clothing.
P273 - Avoid release to the environment.

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Section 2. Hazards identification

Response : P308 + P313 - IF exposed or concerned: Get medical attention.
P301 + P312 - IF SWALLOWED: Call a POISON CENTER or physician if you feel
unwell.
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water.
P333 + P313 - If skin irritation or rash occurs: Get medical attention.
P305 + P351 + P338 + P310 - IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or physician.
Storage : P405 - Store locked up.
Disposal : P501 - Dispose of contents and container in accordance with all local, regional,
national and international regulations.

Other hazards which do not : None known.

result in classification

Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Other means of : Not available.
identification

CAS number/other identifiers

CAS number : Not applicable.
EC number : Mixture.
Product code : 44765
Ingredient name % CAS number
1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1h,3h,5h)-trione <5 2451-62-9
zinc di(benzothiazol-2-yl) disulphide <1 155-04-4
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately
flush eyes with plenty of water, occasionally lifting the upper and lower eyelids.
Check for and remove any contact lenses. Continue to rinse for at least 10 minutes.
Chemical burns must be treated promptly by a physician.
Inhalation : Get medical attention immediately. Call a poison center or physician. Remove
victim to fresh air and keep at rest in a position comfortable for breathing. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
It may be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie,
belt or waistband. In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
Skin contact : Get medical attention immediately. Call a poison center or physician. Wash with
plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly
by a physician. In the event of any complaints or symptoms, avoid further exposure.
Wash clothing before reuse. Clean shoes thoroughly before reuse.

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Section 4. First aid measures

Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out
mouth with water. Remove dentures if any. Remove victim to fresh air and keep at
rest in a position comfortable for breathing. If material has been swallowed and the
exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Chemical burns must be treated
promptly by a physician. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or
waistband.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : No known significant effects or critical hazards.
Skin contact : May cause an allergic skin reaction.
Ingestion : May be harmful if swallowed.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Firefighting measures

Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : This material is harmful to aquatic life with long lasting effects. Fire water
from the chemical contaminated with this material must be contained and prevented from being
discharged to any waterway, sewer or drain.
Fine dust clouds may form explosive mixtures with air.

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Section 5. Firefighting measures

Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides
sulfur oxides
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Provide adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate
personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful
to the environment if released in large quantities.

Methods and material for containment and cleaning up

Small spill : Move containers from spill area. Avoid dust generation. Do not dry sweep.
Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled
waste container. Place spilled material in a designated, labeled waste container.
Dispose of via a licensed waste disposal contractor.
Large spill : Move containers from spill area. Approach the release from upwind. Prevent entry
into sewers, water courses, basements or confined areas. Avoid dust generation.
Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place
in a closed, labeled waste container. Dispose of via a licensed waste disposal
contractor. Note: see Section 1 for emergency contact information and Section 13
for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in
which this product is used. Avoid exposure - obtain special instructions before use.
Do not handle until all safety precautions have been read and understood. Do not
get in eyes or on skin or clothing. Do not ingest. Avoid release to the environment.
If during normal use the material presents a respiratory hazard, use only with
adequate ventilation or wear appropriate respirator. Keep in the original container or
an approved alternative made from a compatible material, kept tightly closed when
not in use. Empty containers retain product residue and can be hazardous. Do not
reuse container.

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Section 7. Handling and storage

Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected
including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible
incompatibilities materials (see Section 10) and food and drink. Store locked up. Keep container
tightly closed and sealed until ready for use. Containers that have been opened
must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabelled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1h,3h,5h)-trione ACGIH TLV (United States, 3/2018).
TWA: 0.05 mg/m³ 8 hours.
Dust Limit : 10 mg/m³ (TWA of total inhalable dust) and 4 mg/m³ (TWA of respirable)

Appropriate engineering : If user operations generate dust, fumes, gas, vapour or mist, use process
controls enclosures, local exhaust ventilation or other engineering controls to keep worker
exposure to airborne contaminants below any recommended or statutory limits.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying to EN 166 should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or
dusts. If contact is possible, the following protection should be worn, unless the
assessment indicates a higher degree of protection: chemical splash goggles and/
or face shield. If inhalation hazards exist, a full-face respirator may be required
instead.
Skin protection
Hand protection : There is no one glove material or combination of materials that will give unlimited
resistance to any individual or combination of chemicals.
The breakthrough time must be greater than the end use time of the product.
The instructions and information provided by the glove manufacturer on use,
storage, maintenance and replacement must be followed.
Gloves should be replaced regularly and if there is any sign of damage to the glove
material.
Always ensure that gloves are free from defects and that they are stored and used
correctly.
The performance or effectiveness of the glove may be reduced by physical/chemical
damage and poor maintenance.
Barrier creams may help to protect the exposed areas of the skin but should not be
applied once exposure has occurred.

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Section 8. Exposure controls/personal protection

Wear suitable gloves tested to EN374.
May be used, gloves(breakthrough time) 4 - 8 hours: neoprene, polyvinyl alcohol
(PVA)
Recommended, gloves(breakthrough time) > 8 hours: nitrile rubber, PVC

Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : If workers are exposed to concentrations above the exposure limit, they must use a
respirator according to EN 140. If dust is generated and ventilation is inadequate,
use respirator that will protect against dust/mist. (FFP2 / N95).

Section 9. Physical and chemical properties

Appearance
Physical state : Solid. Powder.
Colour : Various
Odour : Odourless.
Odour threshold : Not applicable.
pH : Not applicable.
Melting point (dust) : 85 - 115 °C
Boiling point : Not applicable.
Flash point : Not applicable.
Evaporation rate : Not applicable.
Flammability (solid, gas) : Fine dust clouds may form explosive mixtures with air.
Lower explosion limit (dust) : 30 g/m³ (EN 14034-3)
Minimum ignition energy : 10 - 30 (EN 13821)
(mJ)
Vapour pressure : Not applicable.
Vapour density : Not applicable.
Density : 1.2 to 1.9 g/cm³
Solubility : Insoluble in the following materials: cold water and hot water
Partition coefficient: n- : Not applicable.
octanol/water
Auto-ignition temperature : > 400°C
Decomposition temperature : >250°C (>482°F)
Viscosity : Not applicable.

Section 10. Stability and reactivity

Reactivity : Fine dust clouds may form explosive mixtures with air.
Chemical stability : The product is stable.
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Conditions to avoid : Avoid the creation of dust when handling and avoid all possible sources of ignition
(spark or flame).
Take precautionary measures against electrostatic discharges.
To avoid fire or explosion, dissipate static electricity during transfer by earthing and
bonding containers and equipment before transferring material.
Prevent dust accumulation.
Incompatible materials : No specific data.

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Section 10. Stability and reactivity

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
1,3,5-tris(oxiranylmethyl) LD50 Oral Rat 138 mg/kg -
-1,3,5-triazine-2,4,6(1h,3h,
5h)-trione
zinc di(benzothiazol-2-yl) LD50 Oral Rat 540 mg/kg -
disulphide
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
1,3,5-tris(oxiranylmethyl) Eyes - Severe irritant Rabbit - 100 -
-1,3,5-triazine-2,4,6(1h,3h, milligrams
5h)-trione
Eyes - Irritant Mammal - - - -
species
unspecified
Sensitisation
Product/ingredient name Route of Species Result
exposure
1,3,5-tris(oxiranylmethyl) skin Mammal - species Sensitising
-1,3,5-triazine-2,4,6(1h,3h, unspecified
5h)-trione
zinc di(benzothiazol-2-yl) skin Mammal - species Sensitising
disulphide unspecified
Mutagenicity
Not available.
Carcinogenicity
Not available.
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1h,3h,5h)- Category 2 Not determined Not determined
trione
Aspiration hazard
Not available.

Information on likely routes : Not available.

of exposure
Potential acute health effects

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Section 11. Toxicological information

Eye contact : Causes serious eye damage.
Inhalation : No known significant effects or critical hazards.
Skin contact : May cause an allergic skin reaction.
Ingestion : May be harmful if swallowed.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains

Delayed and immediate effects as well as chronic effects from short and long-term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : Once sensitized, a severe allergic reaction may occur when subsequently exposed
to very low levels.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : May cause genetic defects.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Route ATE value
Oral 2450.68 mg/kg
Inhalation (vapours) 73.52 mg/l

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Section 12. Ecological information

Toxicity
Not available.

Persistence and degradability

Not available.

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
1,3,5-tris(oxiranylmethyl) -0.8 - low
-1,3,5-triazine-2,4,6(1h,3h,
5h)-trione
zinc di(benzothiazol-2-yl) 5.02 <8 low
disulphide

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible. This material and
its container must be disposed of in a safe way. Care should be taken when
handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Avoid dispersal of spilt
material and runoff and contact with soil, waterways, drains and sewers.

Section 14. Transport information

ADR/RID IMDG IATA
UN number Not regulated. Not regulated. Not regulated.

UN proper - - -
shipping name
Transport hazard - - -
class(es)

Packing group - - -
Environmental No. No. No.
hazards
Additional - - -
information

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Section 14. Transport information

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Transport in bulk according : Not available.

to Annex II of Marpol and
the IBC Code

Section 15. Regulatory information

Safety, health and : No known specific national and/or regional regulations applicable to this product
environmental regulations (including its ingredients).
specific for the product
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.

Montreal Protocol (Annexes A, B, C, E)

Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.

UNECE Aarhus Protocol on POPs and Heavy Metals

Not listed.

Section 16. Other information

History
Date of printing : 01.10.2020
Date of issue/Date of : 01.10.2020
revision
Date of previous issue : 17.04.2020
Version : 1.01
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader
The information in this document is given to the best of Jotun's knowledge, based on laboratory testing and
practical experience. Jotun's products are considered as semi-finished goods and as such, products are
often used under conditions beyond Jotun's control. Jotun cannot guarantee anything but the quality of the
product itself. Minor product variations may be implemented in order to comply with local requirements.
Jotun reserves the right to change the given data without further notice.

Users should always consult Jotun for specific guidance on the general suitability of this product for their
needs and specific application practices.

If there is any inconsistency between different language issues of this document, the English (United
Kingdom) version will prevail.

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