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 WLE CHSE Charnpion Chemistry Class 1
(/5, AI207) Depresson of Freezing Polnt
MEQ
Flevation of Bolng Point ÀM Intthe following diagrärn point 'X feprésente

MQ hoy
The beiling peint of A0.2 msolution of a
17 Vaour
electrolyte in water is
Kkg mol ) pressure|
(K, for water 0.52 (b) 100,52 C:
(a) 100C Temperature
(d) 100.26"C
(e) 100104
(Term 1, 2021 22) (a) bolling point of solution
(b) freezing point of solvernt
8 Assertlon (A) Elevatlon in bollng
point ls # (c) boling point of solvent
collgative property. freezing point of solution. (Term, 2021-22)
Reason (R) : Elevation in boling polnt ls dlrectly
proportional to molarlty. SAI (2marks)
Ia) Both Assertion (A) and Reason (R) are correct 45. Nisha took twoaqueouS solutions - one containine
statements, and Reason (R) is the correct 75 g of urea (Molar mass = 60 g/mol)and the other
explanation of the Assertion (A). containíng 42.75 g of substance Zin 100 g of water
(b) Both Assertion (A) and Reason (R) are correct respectively. lt was observed that both the solutione
molar
statements, but Reason (R) Is not the Correct froze at the same temperature. Calculate the
kplanation of the Assertion (A). mass ofZ (2020) Ey
Assertion (A) 0scorrect, but Reason (R) is wrong 46. Calculate the freezing point of a solution containing
in 250
statement. 60g of glucose (molar mass = 180 g mol)
)
(d) Assertion (A) is wrong, but Reason (R) is correct of water. (Kof water= 1.86 Kkg mol (2018)
statement. (2020) R 47, Calculate the mass of compound (molar mass = 256
gmol) to be dissolved in 75 g of benzene to lower
VSA (1 mark) its freezing point by 0.48 K. (K= 5.12 Kkg mol).
(Delhi 2014)
39. Define the following term:
Molalelevation constant (Ks) (15,AI2014) 48.An aqueous solution of sodium chloride freezes
below 273 K. Explain the lowering in freezing point
SA! (2 marks) of water with the help of a suitable diagram.
40. Give reasons: (Delhi 2013C)
() 0.1 M KCI has higher boiling point than 0.1 M
glucose.
SA I (3 marks)
() Meat is preserved fÍr a longer time by salting 4.Calculate the mass of ascorbic acid (Molar mass =
2020) (An 176g mol) to be dissolved in 75 g of acetic acid, to
lower its freezing point by 1.5°C.
41. Why does a solution containing non-volatile solute (K= 3.9 Kkg mol) (NCERT Intext, 2020)
have higher boiling point than the pure solvent?
Why is elevation of boiling point a colligative 59 A4%% solution (w/w) of sucrose (M =342 gmol)
property? in water has a freezing point of 271.15 K. Calculate
(AI 2015) (An the freezing point of 5% glucose (M = 180g mol)
in water. (Given : Freezing point of pure water
42. 18gof glucose,CH0, (Molar mass =180 gmol) =273.15 K)
is dissolved in 1 kg of water in a sauce pan. At what (Delhi 2019) Ev
ternperature will this solution boil? 51.,A 10% solution (by mass) of sucrose in water has
(K, for water =0.52 Kkg mol", boiling polnt of pure freezing point of 269.15 K. Calculate the freezing
water 373. 15 K) (Delhi 2013) point of 10% glucOse in water, freezing point of
pure water is 273.15 K.
SA II (3 marks) (Given: Molar mass of sucrose = 342 g mol,
43. Calculate the boiling point elevation for a solution molar mass of glucose =180 g mol) (Delhi 2017) EV
prepared by adding 10 g of CaCl, to 200 gof water. 52, Calculate the freezing point of the solution when
(K, for water =0.52 Kkg mol ", molar mass of CaCi, 31 g of ethylene glycol (C,H,0,) is dissolved in 500
111 g mof) (3/5, Al2017C, Foreign 2014) gof water. (K for water =1.86 Kkg mol) (AI 2015)
Solutions 9
53. Some ethylene glycol, HOCH,CH,OH, is added to 59. Give reason for the following:
your car's cooling system along with 5 kg of water. Measurement of osmotic pressure method is
If the freezing point of water-glycol solution is
preferred for the determination of molar masses of
-15.0°C, what is the boiling point of the solution? macromolecules such as proteins and polymers.
(Ks = 0.52 K kg mol and K = 1.86 K kg mol1 (1/2, 2018) (
for water) (Delhi 2014C)
54. 1.00 g of a non-electrolyte solute dissolved in 50 g 60. Define the following term:
of benzene lowered the freezing point of benzene Osmotic pressure (1/5, Al2017C, 2013) (R
by 0.40 K. The freezing point depression constant of 61. What are isotonic solutions? (Delhi 2014) (R
benzene is 5.12 Kkg mol. Find the molar mass of
the solute. (AI 2013) SAI (2 marks)
55/ A 5% solution (by mass) of cane-sugar in water has
freezing point of 271 K.Calculate the freezing point 62,, For a 5% solution of urea (Molar mass = 60 g
of 5% solution (by mass) of glucose in water if the mol), calculate the osmotic pressure at 300 K.
freezing point of pure water is 273.15 K. [R= 0.0821 Latm Kmol] (2020)
[Molecular masses: Glucose CH12O,: 180 amu; Out of 1 Mglucose and 2 M glucose, which one
Cane-sugar C12H2011:342amu] has a higher boiling point and why?
(NCERT, 3/5, Al2013C) Ey (i) What happens when the external pressure
Osmosis and Osmotic Pressure applied becomes more than the osmotíc
pressure of solution? (2/5, Delhi 2016) An
MCQ 64. BioÍd cells are isotonic with 0.9% sodium chloride
56. Assertion(A) : Araw mango placed in saline solution Solution. What happens if we place blood cells in a
loses water and shrivel into pickle. solution containing
Reason (R):Through the process of reverse osmosis (6) 1.2% sodium chloride solution?
raw mangoshrivel into pickle. (i) 0.4% sodium chloride solution?
(a) Both Assertion (A) and Reason (R) are correct (2/5, Delhi 2016) Ap
statements, and Reason (R) is the correct
explanation of the Assertion (A). SA I (3 marks)
(b) Both Assertion (A) and Reason (R) are correct
statements, but Reason (R) is not the correct 65. At 300 K, 30 g of glucose present in a litre of its
solution has an osmotic pressure of 4.98 bar. If
explanation of the Assertion (A).
the osmotic pressure of a glucose solution is 1.52
(c) Assertion (A) is correct, but Reason (R) is
incorrect statement. bar at the same temperature, what would be its
(d) Assertion (A) is incorrect, but Reason (R) is concentration? (AI 2019)
correct statement. (Term I, 2021-22) Ap 66. Asolution containing 15 g urea (molar mass = 60 g
57. Assertion (A) : Osmotic pressure is a colligative mol) per litre of solution in water has the same
property. osmotic pressure (isotonic) as a solution of glucose
Reason (R) : Osmotic pressure is directly (molar mass = 180g mol) in water. Calculate the
proportional to molarity. mass of glucose present in one litre of its solution.
(a) Both Assertion (A) and Reason (R) are correct (3/5, Al 2014)
statements, and Rea_on (R) is the correct
explanation of the Assertion (A). 67. Define the followingterms:
(b) Both Assertion (A) and Reason (R) are correct (i) Osmotic pressure
statements, but Reason (R) is not the correct (i) Colligative properties (Foreign 2014) R
explanation of the Assertion (A).
(c) Assertion (A) is correct, but Reason (R) is 2.7 Abnormal Molar Masses
incorrect statement.
(d) Assertion (A) is incorrect, but Reason (R) is van't Hoff and Abnormal Molar Mass
Correct statement. (2020)
VSA (1 mark)
VSA (1 mark)
68. Define the following term:
58What happens when a pressure greater than (Deihi 2017)
osmotic pressure is applied on the solution side van't Hoff factor
separated from solvent by a semi-permeable 69. Define the following term:
membrane? (1/2, 2020) Ap Abnormal molar mass (Delhi 2017)
 WtG CBSE Chanpion Chemistry Class 12
10
association
solution?
of benzoic acid if it forms a dimer in
SAI (2 marks)
factor? What types of
values (K, for benzene = 4.9 Kkg mol 1)
70. What is van't Hoff the solution the solute (2020) An
can it have if in forming 76. A 0,01 maqueous solution of AlCIa
molecules undergo -0.068 °C. Calculate the percentage of freezes at
(Given: K, for water =1.86 Kkg mol 1 di(2020)
ssociatioEvn,
() dissociation
(ii) association? (2/5, Al 2014C)( U]
77. Calculate the freezing point of solution
whenin 1.950
van't Hoff and Elevation in Boiling Point g of MgCI, (M = 95 g mol-l) was dissolved
g of water, assuming MgCl, undergoes
VSA (1 mark) ionization.
complete
kg mol)
71. Give reason for thefollowing: (K, for water = 1.86 K (Delhi 2016)
is
Elevation of boiling point of 1 M KCI solution 78. When 2.56 g of sulphur was dissolved in 100 g
nearly double than that of 1 Msugar solution.
of CSo, the freezing point lowered by 0.383 k
(1/2, 2018)(U1 Calculate the formula of sulphur (S,).
(K the CS, =3.83 Kkg mol ", atomic mass of sulphur
SA II (3 mark) =32 g mol-) (3/5 Delhi 2016)C
72. Calculate the boiling point of solution when 4 g of 79. 3.9 g of benzoic acid dissolved in 49 g of benzene
MgSO, (M = 120 g mol) was dissolved in 100 g shows a depression in freezing point of 1.62 K
of water, assuming MgSO undergoes complete Calculate the van't Hoff factor and predict the
ionization.
(K, for water =0.52 Kkg mol-) (AI 2016) nature of solute (associated or dissociated).
(Given: Molar mass of benzoic acid =122 g mol-1
van't Hoff and Depression in Freezing Point K for benzene =4.9K kg mol") (Delhi 2015) Ev
80. Calculate the mass of NaCl (molar mass = 58.5 g
SAI (2 marks) mol-) to be dissolved in 37.2 g of water to lower the
73. Assuming complete dissociation, calculate the freezing point by 2°C, assuming that NaCl undergoes
expected freezing point of a solution prepared by complete dissociation. (K, for water = 1.86 Kkg mol)
dissolving 6.00 gof Glauber's salt, Na,SO4 10H,0 in (Foreign 2015)
0.100kg of water.
(K for water = 1.86 K kg mol, atomic masses: van't Hoff and Osmotic Pressure
Na =23, S=32,O =16, H= 1) (2/5, Al 2014C) (Ap
SAII (3 marks)
SA I| (3 marks)
81. A solution contains 5.85 g NaCl (Molar mass
74. When 19.5 g of F-CH,-COOH (molar mass 58.5 g mol) per litreof solution. It has an osmotic
= 78 g mol) is dissolved in 500g of water, the pressure of 4.75 atm at 27°C. Calculate the degree
depression in freezing point is observed to be of dissociation of NaCl in this solution.
1°C. Calculate the degree of dissociation of (Given:R= 0.082 LatmKmol) (3/5, 2020)
F-CH,-COOH.
82. Determine the osmotic pressure of a solution
(Given: Kfor water =1.86 Kkg mol]
(3/5, 2020) Ev prepared by dissolving 2.5 x 10 g of K,SO, in 2
L of water at 25°C, assuming that it is completely
75. The freezing point of a solution containing 5 g of dissociated.
benzoic acid (M = 122 g mol) in 35 g of benzene (R = 0.0821 Latm K mol molar mass of K,SO4
is depressed by 2.94 K. What is the percentage
=174g mol) (Delhi 2013)

CBSE Sample Questions

2.2 Expressing Concentrationof Reason (R): Molarity isa colligative property.
Solutions Select the most appropriate answer from the options
given below:
MCO (a) Both A and R are true and R is the correct
1, Given below are two statements labelled as explanation of A.
assertion (A) and Reason (R). (b) Both A and R are true but R is not the correct
Assertion (A): Molarity of a solution changes with explanation of A.
(c) Ais true but Ris false.
temperature.
(d) Ais false but Ris true. (Term 1, 2021-22) R
Solutions 11

2.3 Solubility 6. Assertion : Nitric acid and water form maximum

MCQ boiling azeotrope.
Reason: Azeotropes are binary mixtures having the
Solubilityof gases in liquids decreases with rise in same composition in liquid and vapour phase.
temperature because dissolution is an (2020-21)
(a) endothermic and reversible process
(b) exothermic and reversible process 2.6 Colligative Properties and
(c) endothermic and irreversible process Determination of Molar Mass
(d) exothermic and irreversible process.
In the
(Term 1, 2021-22) MCQ
following question a statement of assertion
followed by a statement of reason is given. Choose the In which of the following cases blood cells will
correct answer out of the following. shrink?
(a) Both Aand Rare true and Ris the (a) When placed in water containing more than
of A.
correct explanation 0.9% (mass/ volume) NaCl solution.
(b) Both A and R are true but R is
not the correct (b) When placed in water containing less than O.9%
explanation of A. (mass /volume) NaCl solution.
(c) Ais true but R is false.
(d) A is false but Ris true. (c) When placed in water containing 0.9% (mass/
volume) NaCl solution.
Assertion: Aquaticspecies are (d) When placed in distilled water.
cold waters rather than in warm more comfortable in
waters. (Term I,2021-22) An
Reason : Different gases have different Ku Values at
the same temperature. 8. How much ethyl alcohol must be added to 1 litre
(2020-21) of water so that the solution will freeze at- 14°C?
2.4 Vapour Pressure of Liquid (Kfor water = 1.86°C/mol)
(b) 8.5 mol
(a) 7.5 mol
Solutions (c) 9.5 mol (d) 10.5 mol
(Term I, 2021-22)
MCQ
9 Water retention or puffiness due to high salt intake
4 ldentify the law which is stated as
OCcurs due to
"For any solution, the partial vapour pressure of
each volatile component in the solution is directly (a) diffusion
proportional to its mole fraction." (b) vapour pressure difference
(a) Henry's law (b) Raoult's law (c) osmosis
(c) Dalton's law (d) Gay-Lussac's Law (d) reverse osmosis. (Term I,2021-22)
(Term I, 2021-22) Ap
10. ) Given below are two statements labelled as
5. When 1 mole of benzene is mixed with 1 mole of
assertion (A) and Reason (R).
toluene the vapour will contain
Assertion (A) : Cryoscopic constant depends on
(Given: Vapour pressure of benzene = 12.8 kPa and nature of solvent.
vapour pressure of toluene = 3.85 kPa).
(a) equal amount of benzene and toluene as it Reason (R) : Cryoscopic constant is a universal
constant.
forms an ideal solution
(b) unequal amount of benzene and toluene as it Select the most appropriate answer from the options
forms a non-ideal solution given below:
(c) higher percentage of benzene (a) Both Aand R are true and R is the correct
(d) higher percentage of toluene. (2020-21) (U explanation of A.
(b) Both A andR are true but R is not the correct
2.5 ldeal and Non-idealSolutions explanation of A.
(c) Aistrue but Ris false.
MCQ (d) Ais false but Ris true. (2020-21)
In the following question a statement of assertion
followed by a statement of reason is given. Choose the SAI (2 marks)
correct answer out of the following. 11. Aglucose solution boils at 101.04°C at 1 atm. What
(a) BothA and Rare true and Risthe correct explanation will be relative lowering of vapour pressure of an
of A.
(b) Both A and R are true but R is not the correct aqueous solution of urea which is equimolal to given
explanation of A. glucose solution?,
(c) A is true but Ris false. (Given: K, for water is 0.52 Kkg mol)
(d) A is false but Ris true. (2020-21) Ev
 12. 12
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Give true what

13.
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g g marks) (3
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mass CBSE
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