Bisflow R100M1

Bisley International LLC Chemwatch Hazard Alert Code: 1

Chemwatch: 5373-06 Issue Date: 01/11/2019
Version No: 4.1.4.7 Print Date: 17/06/2021
Safety Data Sheet according to OSHA HazCom Standard (2012) requirements S.GHS.USA.EN

SECTION 1 Identification

Product Identifier
Product name Bisflow R100M1
Chemical Name Not Applicable
Synonyms Not Available
Chemical formula Not Applicable
Other means of identification Not Available

Recommended use of the chemical and restrictions on use

Relevant identified uses Concrete admixture, superplasticiser for cement concrete.

Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party
Registered company name Bisley International LLC
Address 1790 Hughes Landing Boulevard Suite 400 The Woodlands TX 77380 United States
Telephone +1 (844) 424 7539
Fax Not Available
Website www.bisley.biz
Email compliance@bisley.biz

Emergency phone number

Association / Organisation Bisley International LLC CHEMWATCH EMERGENCY RESPONSE
Emergency telephone
+1 855 237 5573 +61 2 9186 1132
numbers
Other emergency telephone
+61 2 9186 1132 +1 855-237-5573
numbers

Once connected and if the message is not in your prefered language then please dial 01

Una vez conectado y si el mensaje no está en su idioma preferido, por favor marque 02

SECTION 2 Hazard(s) identification

Classification of the substance or mixture

Considered a Hazardous Substance by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Not classified as Dangerous
Goods for transport purposes.

NFPA 704 diamond

Note: The hazard category numbers found in GHS classification in section 2

of this SDSs are NOT to be used to fill in the NFPA 704 diamond. Blue =
Health Red = Fire Yellow = Reactivity White = Special (Oxidizer or water
reactive substances)

Classification Eye Irritation Category 2B

Label elements

Hazard pictogram(s) Not Applicable

Signal word Warning

Hazard statement(s)
H320 Causes eye irritation.

Hazard(s) not otherwise classified

Not Applicable

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Precautionary statement(s) Prevention

P264 Wash all exposed external body areas thoroughly after handling.

Precautionary statement(s) Response

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.

Precautionary statement(s) Storage

Not Applicable

Precautionary statement(s) Disposal

Not Applicable

SECTION 3 Composition / information on ingredients

Substances
See section below for composition of Mixtures

Mixtures
CAS No %[weight] Name
31497-33-3 >50 methylallyl alcohol ethoxylated
7732-18-5 <50 water

SECTION 4 First-aid measures

Description of first aid measures

If this product comes in contact with eyes:
Wash out immediately with water.
Eye Contact
If irritation continues, seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Skin Contact
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Inhalation
Other measures are usually unnecessary.
Immediately give a glass of water.
Ingestion
First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

Most important symptoms and effects, both acute and delayed

See Section 11

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5 Fire-fighting measures

Extinguishing media
The product contains a substantial proportion of water, therefore there are no restrictions on the type of extinguishing media which may be used. Choice of extinguishing media should
take into account surrounding areas.
Though the material is non-combustible, evaporation of water from the mixture, caused by the heat of nearby fire, may produce floating layers of combustible substances.
In such an event consider:
foam.

Special hazards arising from the substrate or mixture

Fire Incompatibility None known.

Special protective equipment and precautions for fire-fighters

Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves in the event of a fire.
Fire Fighting
Prevent, by any means available, spillage from entering drains or water courses.
Use fire fighting procedures suitable for surrounding area.
The material is not readily combustible under normal conditions.
However, it will break down under fire conditions and the organic component may burn.
Not considered to be a significant fire risk.
Heat may cause expansion or decomposition with violent rupture of containers.
Fire/Explosion Hazard
Decomposes on heating and produces toxic fumes of:
carbon dioxide (CO2)
sulfur oxides (SOx)
other pyrolysis products typical of burning organic material.

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Bisflow R100M1

SECTION 6 Accidental release measures

Personal precautions, protective equipment and emergency procedures

See section 8

Environmental precautions
See section 12

Methods and material for containment and cleaning up

Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Minor Spills
Control personal contact with the substance, by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Minor hazard.
Clear area of personnel.
Major Spills
Alert Fire Brigade and tell them location and nature of hazard.
Control personal contact with the substance, by using protective equipment as required.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 Handling and storage

Precautions for safe handling

Limit all unnecessary personal contact.
Wear protective clothing when risk of exposure occurs.
Safe handling
Use in a well-ventilated area.
When handling DO NOT eat, drink or smoke.
Store in original containers.
Keep containers securely sealed.
Other information
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.

Conditions for safe storage, including any incompatibilities

Polyethylene or polypropylene container.
Suitable container Packing as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Storage incompatibility None known

+ x + o + + +

X — Must not be stored together

0 — May be stored together with specific preventions
+ — May be stored together

Note: Depending on other risk factors, compatibility assessment based on the table above may not be relevant to storage situations, particularly where large volumes of dangerous goods
are stored and handled. Reference should be made to the Safety Data Sheets for each substance or article and risks assessed accordingly.

SECTION 8 Exposure controls / personal protection

Control parameters

Occupational Exposure Limits (OEL)

INGREDIENT DATA
Not Available
Emergency Limits
Ingredient TEEL-1 TEEL-2 TEEL-3
Bisflow R100M1 Not Available Not Available Not Available

Ingredient Original IDLH Revised IDLH

methylallyl alcohol ethoxylated Not Available Not Available
water Not Available Not Available

Exposure controls
Appropriate engineering
General exhaust is adequate under normal operating conditions.
controls

Personal protection

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Bisflow R100M1

Safety glasses with side shields; or as required,

Chemical goggles.
Eye and face protection Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing
the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption
and adsorption for the class of chemicals in use and an account of injury experience.
Skin protection See Hand protection below
Hands/feet protection Wear general protective gloves, eg. light weight rubber gloves.
Body protection See Other protection below
Overalls.
Other protection
Eyewash unit.

Respiratory protection
Particulate. (AS/NZS 1716 & 1715, EN 143:2000 & 149:001, ANSI Z88 or national equivalent)

SECTION 9 Physical and chemical properties

Information on basic physical and chemical properties

Appearance Clear yellow iquid with mild organic compound odour; mixes with water.

Physical state Liquid Relative density (Water = 1) 1.05-1.15

Partition coefficient n-octanol
Odour Not Available Not Available
/ water
Odour threshold Not Available Auto-ignition temperature (°C) Not Applicable
pH (as supplied) 4-6 Decomposition temperature Not Available
Melting point / freezing point
Not Available Viscosity (cSt) 330-660 @ 25C
(°C)
Initial boiling point and boiling
Not Available Molecular weight (g/mol) Not Applicable
range (°C)
Flash point (°C) Not Applicable Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Applicable Oxidising properties Not Available
Surface Tension (dyn/cm or
Upper Explosive Limit (%) Not Applicable Not Available
mN/m)
Lower Explosive Limit (%) Not Applicable Volatile Component (%vol) 50 water
Vapour pressure (kPa) 2.3 @ 20C Gas group Not Available
Solubility in water Miscible pH as a solution (%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available

SECTION 10 Stability and reactivity

Reactivity See section 7

Chemical stability Product is considered stable and hazardous polymerisation will not occur.
Possibility of hazardous
See section 7
reactions
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decomposition
See section 5
products

SECTION 11 Toxicological information

Information on toxicological effects

Inhaled Not normally a hazard due to non-volatile nature of product
The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because of the lack of
Ingestion
corroborating animal or human evidence.
The material is not thought to produce adverse health effects or skin irritation following contact (as classified by EC Directives using animal
Skin Contact models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational
setting.
Although the liquid is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce transient discomfort
Eye
characterised by tearing or conjunctival redness (as with windburn).
Long-term exposure to the product is not thought to produce chronic effects adverse to the health (as classified by EC Directives using animal
Chronic
models); nevertheless exposure by all routes should be minimised as a matter of course.

TOXICITY IRRITATION
Bisflow R100M1
Not Available Not Available

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Bisflow R100M1

methylallyl alcohol TOXICITY IRRITATION

ethoxylated Not Available Not Available

TOXICITY IRRITATION
water
Oral(Rat) LD50; >90000 mg/kg[2] Not Available

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise
specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

Polyethers (such as ethoxylated surfactants and polyethylene glycols) are highly susceptible to being oxidized in the air. They then form complex
METHYLALLYL ALCOHOL mixtures of oxidation products.
ETHOXYLATED Animal testing reveals that whole the pure, non-oxidised surfactant is non-sensitizing, many of the oxidation products are sensitisers. The
oxidization products also cause irritation.
METHYLALLYL ALCOHOL
No significant acute toxicological data identified in literature search.
ETHOXYLATED & WATER

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity
Serious Eye Damage/Irritation STOT - Single Exposure
Respiratory or Skin
STOT - Repeated Exposure
sensitisation
Mutagenicity Aspiration Hazard
Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification

SECTION 12 Ecological information

Toxicity

Endpoint Test Duration (hr) Species Value Source

Bisflow R100M1 Not Not Not
Not Available Not Available
Available Available Available

Endpoint Test Duration (hr) Species Value Source

methylallyl alcohol
ethoxylated Not Not Not
Not Available Not Available
Available Available Available

Endpoint Test Duration (hr) Species Value Source

water Not Not Not
Not Available Not Available
Available Available Available

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite
V3.12 (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment
Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air
water LOW LOW

Bioaccumulative potential
Ingredient Bioaccumulation
No Data available for all ingredients

Mobility in soil
Ingredient Mobility
No Data available for all ingredients

SECTION 13 Disposal considerations

Waste treatment methods

Recycle wherever possible or consult manufacturer for recycling options.
Consult State Land Waste Management Authority for disposal.
Product / Packaging disposal
Bury residue in an authorised landfill.
Recycle containers if possible, or dispose of in an authorised landfill.

SECTION 14 Transport information

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Labels Required
Marine Pollutant NO

Land transport (DOT): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Transport in bulk according to Annex II of MARPOL and the IBC code

Not Applicable

Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
Product name Group
methylallyl alcohol ethoxylated Not Available
water Not Available

Transport in bulk in accordance with the ICG Code

Product name Ship Type
methylallyl alcohol ethoxylated Not Available
water Not Available

SECTION 15 Regulatory information

Safety, health and environmental regulations / legislation specific for the substance or mixture

methylallyl alcohol ethoxylated is found on the following regulatory lists

US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory US TSCA Section 12(b) - List of Chemical Substances Subject to Export Notification
Requirements

water is found on the following regulatory lists

US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory US TSCA Chemical Substance Inventory - Interim List of Active Substances

Federal Regulations

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Section 311/312 hazard categories

Flammable (Gases, Aerosols, Liquids, or Solids) No
Gas under pressure No
Explosive No
Self-heating No
Pyrophoric (Liquid or Solid) No
Pyrophoric Gas No
Corrosive to metal No
Oxidizer (Liquid, Solid or Gas) No
Organic Peroxide No
Self-reactive No
In contact with water emits flammable gas No
Combustible Dust No
Carcinogenicity No
Acute toxicity (any route of exposure) No
Reproductive toxicity No
Skin Corrosion or Irritation No
Respiratory or Skin Sensitization No
Serious eye damage or eye irritation No
Specific target organ toxicity (single or repeated exposure) No
Aspiration Hazard No
Germ cell mutagenicity No
Simple Asphyxiant No
Hazards Not Otherwise Classified No

US. EPA CERCLA Hazardous Substances and Reportable Quantities (40 CFR 302.4)
None Reported

State Regulations

US. California Proposition 65

None Reported

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National Inventory Status

National Inventory Status
Australia - AIIC / Australia
No (methylallyl alcohol ethoxylated)
Non-Industrial Use
Canada - DSL No (methylallyl alcohol ethoxylated)
Canada - NDSL No (methylallyl alcohol ethoxylated; water)
China - IECSC No (methylallyl alcohol ethoxylated)
Europe - EINEC / ELINCS / NLP No (methylallyl alcohol ethoxylated)
Japan - ENCS No (methylallyl alcohol ethoxylated)
Korea - KECI No (methylallyl alcohol ethoxylated)
New Zealand - NZIoC No (methylallyl alcohol ethoxylated)
Philippines - PICCS No (methylallyl alcohol ethoxylated)
USA - TSCA Yes
Taiwan - TCSI No (methylallyl alcohol ethoxylated)
Mexico - INSQ No (methylallyl alcohol ethoxylated)
Vietnam - NCI No (methylallyl alcohol ethoxylated)
Russia - FBEPH Yes
Yes = All CAS declared ingredients are on the inventory
Legend:
No = One or more of the CAS listed ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)

SECTION 16 Other information

Revision Date 01/11/2019

Initial Date 03/10/2019

SDS Version Summary

Version Date of Update Sections Updated
3.1.2.1 07/10/2019 Ingredients
4.1.2.1 01/11/2019 One-off system update. NOTE: This may or may not change the GHS classification
4.1.3.1 10/05/2021 Regulation Change
4.1.4.1 24/05/2021 Regulation Change
4.1.4.2 30/05/2021 Template Change
4.1.4.3 04/06/2021 Template Change
4.1.4.4 05/06/2021 Template Change
4.1.4.5 09/06/2021 Template Change
4.1.4.6 11/06/2021 Template Change
4.1.4.7 15/06/2021 Template Change

Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or
other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

Definitions and abbreviations

PC－TWA: Permissible Concentration-Time Weighted Average
PC－STEL: Permissible Concentration-Short Term Exposure Limit
IARC: International Agency for Research on Cancer
ACGIH: American Conference of Governmental Industrial Hygienists
STEL: Short Term Exposure Limit
TEEL: Temporary Emergency Exposure Limit。
IDLH: Immediately Dangerous to Life or Health Concentrations
ES: Exposure Standard
OSF: Odour Safety Factor
NOAEL :No Observed Adverse Effect Level
LOAEL: Lowest Observed Adverse Effect Level
TLV: Threshold Limit Value
LOD: Limit Of Detection
OTV: Odour Threshold Value
BCF: BioConcentration Factors
BEI: Biological Exposure Index
AIIC: Australian Inventory of Industrial Chemicals
DSL: Domestic Substances List
NDSL: Non-Domestic Substances List
IECSC: Inventory of Existing Chemical Substance in China
EINECS: European INventory of Existing Commercial chemical Substances
ELINCS: European List of Notified Chemical Substances
NLP: No-Longer Polymers
ENCS: Existing and New Chemical Substances Inventory

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KECI: Korea Existing Chemicals Inventory

NZIoC: New Zealand Inventory of Chemicals
PICCS: Philippine Inventory of Chemicals and Chemical Substances
TSCA: Toxic Substances Control Act
TCSI: Taiwan Chemical Substance Inventory
INSQ: Inventario Nacional de Sustancias Químicas
NCI: National Chemical Inventory
FBEPH: Russian Register of Potentially Hazardous Chemical and Biological Substances

This document is copyright.

Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without
written permission from CHEMWATCH.
TEL (+61 3) 9572 4700.

end of SDS