Bisplas

Bisley International LLC Chemwatch Hazard Alert Code: 1

Chemwatch: 5200-44 Issue Date: 01/11/2019
Version No: 5.1.4.7 Print Date: 16/06/2021
Safety Data Sheet according to OSHA HazCom Standard (2012) requirements S.GHS.USA.EN

SECTION 1 Identification

Product Identifier
Product name Bisplas
Chemical Name Not Applicable
Synonyms NS5L; Ns05L; NS-5; NS5; D; NS 10; NS20
Chemical formula Not Applicable
Other means of identification Not Available

Recommended use of the chemical and restrictions on use

Relevant identified uses Concrete additive, superplasticiser, surfactant.

Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party
Registered company name Bisley International LLC
Address 1790 Hughes Landing Boulevard Suite 400 The Woodlands TX 77380 United States
Telephone +1 (844) 424 7539
Fax Not Available
Website www.bisley.biz
Email compliance@bisley.biz

Emergency phone number

Association / Organisation Bisley International LLC CHEMWATCH EMERGENCY RESPONSE
Emergency telephone
+1 855 237 5573 +61 2 9186 1132
numbers
Other emergency telephone
+61 2 9186 1132 +1 855-237-5573
numbers

Once connected and if the message is not in your prefered language then please dial 01

Una vez conectado y si el mensaje no está en su idioma preferido, por favor marque 02

SECTION 2 Hazard(s) identification

Classification of the substance or mixture

Considered a Hazardous Substance by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Not classified as Dangerous
Goods for transport purposes.

NFPA 704 diamond

Note: The hazard category numbers found in GHS classification in section 2

of this SDSs are NOT to be used to fill in the NFPA 704 diamond. Blue =
Health Red = Fire Yellow = Reactivity White = Special (Oxidizer or water
reactive substances)

Classification Eye Irritation Category 2B

Label elements

Hazard pictogram(s) Not Applicable

Signal word Warning

Hazard statement(s)
H320 Causes eye irritation.

Hazard(s) not otherwise classified

Not Applicable

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Precautionary statement(s) Prevention

P264 Wash all exposed external body areas thoroughly after handling.

Precautionary statement(s) Response

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.

Precautionary statement(s) Storage

Not Applicable

Precautionary statement(s) Disposal

Not Applicable

SECTION 3 Composition / information on ingredients

Substances
See section below for composition of Mixtures

Mixtures
CAS No %[weight] Name
36290-04-7 >90 2-naphthalenesulfonic acid/ formaldehyde sodium salt
7732-18-5 <10 water

SECTION 4 First-aid measures

Description of first aid measures

If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper
Eye Contact
and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Skin Contact
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
If dust is inhaled, remove from contaminated area.
Inhalation Encourage patient to blow nose to ensure clear passage of breathing.
If irritation or discomfort persists seek medical attention.
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
Observe the patient carefully.
Ingestion
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.

Most important symptoms and effects, both acute and delayed

See Section 11

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5 Fire-fighting measures

Extinguishing media
Water spray or fog.
Foam.
Dry chemical powder.
BCF (where regulations permit).

Special hazards arising from the substrate or mixture

Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Special protective equipment and precautions for fire-fighters

Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves.
Fire Fighting
Prevent, by any means available, spillage from entering drains or water courses.
Use water delivered as a fine spray to control fire and cool adjacent area.
Combustible solid which burns but propagates flame with difficulty; it is estimated that most organic dusts are combustible (circa 70%) -
according to the circumstances under which the combustion process occurs, such materials may cause fires and / or dust explosions.
Fire/Explosion Hazard Organic powders when finely divided over a range of concentrations regardless of particulate size or shape and suspended in air or some
other oxidizing medium may form explosive dust-air mixtures and result in a fire or dust explosion (including secondary explosions).
Avoid generating dust, particularly clouds of dust in a confined or unventilated space as dusts may form an explosive mixture with air, and

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any source of ignition, i.e. flame or spark, will cause fire or explosion. Dust clouds generated by the fine grinding of the solid are a particular
hazard; accumulations of fine dust (420 micron or less) may burn rapidly and fiercely if ignited - particles exceeding this limit will generally not
form flammable dust clouds; once initiated, however, larger particles up to 1400 microns diameter will contribute to the propagation of an
explosion.
Combustion products include:
carbon monoxide (CO)
carbon dioxide (CO2)
sulfur oxides (SOx)
other pyrolysis products typical of burning organic material.

SECTION 6 Accidental release measures

Personal precautions, protective equipment and emergency procedures

See section 8

Environmental precautions
See section 12

Methods and material for containment and cleaning up

Remove all ignition sources.
Clean up all spills immediately.
Minor Spills
Avoid contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Remove all ignition sources.
Clear area of personnel and move upwind.
Major Spills Alert Fire Brigade and tell them location and nature of hazard.
Control personal contact with the substance, by using protective equipment and dust respirator.
Prevent spillage from entering drains, sewers or water courses.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 Handling and storage

Precautions for safe handling

Remove all ignition sources.
Limit all unnecessary personal contact.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
When handling DO NOT eat, drink or smoke.
Safe handling
Organic powders when finely divided over a range of concentrations regardless of particulate size or shape and suspended in air or some
other oxidizing medium may form explosive dust-air mixtures and result in a fire or dust explosion (including secondary explosions)
Minimise airborne dust and eliminate all ignition sources. Keep away from heat, hot surfaces, sparks, and flame.
Establish good housekeeping practices.
Remove dust accumulations on a regular basis by vacuuming or gentle sweeping to avoid creating dust clouds.
Store in original containers.
Keep containers securely sealed.
Other information
No smoking, naked lights or ignition sources.
Store in a cool, dry, well-ventilated area.

Conditions for safe storage, including any incompatibilities

Polyethylene or polypropylene container.
Suitable container
Check all containers are clearly labelled and free from leaks.
Storage incompatibility Avoid reaction with oxidising agents

+ x + o + + +

X — Must not be stored together

0 — May be stored together with specific preventions
+ — May be stored together

Note: Depending on other risk factors, compatibility assessment based on the table above may not be relevant to storage situations, particularly where large volumes of dangerous goods
are stored and handled. Reference should be made to the Safety Data Sheets for each substance or article and risks assessed accordingly.

SECTION 8 Exposure controls / personal protection

Control parameters

Occupational Exposure Limits (OEL)

INGREDIENT DATA
Not Available
Emergency Limits
Ingredient TEEL-1 TEEL-2 TEEL-3
Bisplas Not Available Not Available Not Available

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Ingredient Original IDLH Revised IDLH

2-naphthalenesulfonic acid/
Not Available Not Available
formaldehyde sodium salt
water Not Available Not Available

Occupational Exposure Banding

Ingredient Occupational Exposure Band Rating Occupational Exposure Band Limit
2-naphthalenesulfonic acid/
E ≤ 0.01 mg/m³
formaldehyde sodium salt
Notes: Occupational exposure banding is a process of assigning chemicals into specific categories or bands based on a chemical's potency and the
adverse health outcomes associated with exposure. The output of this process is an occupational exposure band (OEB), which corresponds to a
range of exposure concentrations that are expected to protect worker health.

Exposure controls
Appropriate engineering Use in a well-ventilated area
controls General exhaust is adequate under normal operating conditions.

Personal protection

Safety glasses with side shields.

Chemical goggles.
Eye and face protection
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing
the wearing of lenses or restrictions on use, should be created for each workplace or task.
Skin protection See Hand protection below
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to
manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance
and has therefore to be checked prior to the application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be observed when
making a final choice.
Hands/feet protection Personal hygiene is a key element of effective hand care.
Experience indicates that the following polymers are suitable as glove materials for protection against undissolved, dry solids, where abrasive
particles are not present.
polychloroprene.
nitrile rubber.
butyl rubber.
Body protection See Other protection below
Overalls.
P.V.C apron.
Other protection
Barrier cream.
Skin cleansing cream.

Respiratory protection
Particulate. (AS/NZS 1716 & 1715, EN 143:2000 & 149:001, ANSI Z88 or national equivalent)

· Respirators may be necessary when engineering and administrative controls do not adequately prevent exposures.
· The decision to use respiratory protection should be based on professional judgment that takes into account toxicity information, exposure measurement data, and frequency
and likelihood of the worker's exposure - ensure users are not subject to high thermal loads which may result in heat stress or distress due to personal protective equipment (powered,
positive flow, full face apparatus may be an option).
· Published occupational exposure limits, where they exist, will assist in determining the adequacy of the selected respiratory protection. These may be government mandated or
vendor recommended.
· Certified respirators will be useful for protecting workers from inhalation of particulates when properly selected and fit tested as part of a complete respiratory protection
program.
· Where protection from nuisance levels of dusts are desired, use type N95 (US) or type P1 (EN143) dust masks. Use respirators and components tested and approved under
appropriate government standards such as NIOSH (US) or CEN (EU)
· Use approved positive flow mask if significant quantities of dust becomes airborne.
· Try to avoid creating dust conditions.

SECTION 9 Physical and chemical properties

Information on basic physical and chemical properties

Appearance Brownish powder with slight odour; mixes with water.

Physical state Divided Solid Relative density (Water = 1) 0.6-0.8

Partition coefficient n-octanol
Odour Not Available Not Available
/ water
Odour threshold Not Available Auto-ignition temperature (°C) Not Available
pH (as supplied) Not Applicable Decomposition temperature Not Available
Melting point / freezing point
Not Available Viscosity (cSt) Not Applicable
(°C)
Initial boiling point and boiling
Not Available Molecular weight (g/mol) Not Applicable
range (°C)
Flash point (°C) Not Available Taste Not Available

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Evaporation rate Not Applicable Explosive properties Not Available

Flammability Not Available Oxidising properties Not Available
Surface Tension (dyn/cm or
Upper Explosive Limit (%) Not Available Not Applicable
mN/m)
Lower Explosive Limit (%) Not Available Volatile Component (%vol) Negligible
Vapour pressure (kPa) Negligible Gas group Not Available
Solubility in water Miscible pH as a solution (%) 7-9
Vapour density (Air = 1) Not Applicable VOC g/L Not Available

SECTION 10 Stability and reactivity

Reactivity See section 7

Unstable in the presence of incompatible materials.
Chemical stability Product is considered stable.
Hazardous polymerisation will not occur.
Possibility of hazardous
See section 7
reactions
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decomposition
See section 5
products

SECTION 11 Toxicological information

Information on toxicological effects

Inhaled Generated dust may be discomforting
Accidental ingestion of the material may be damaging to the health of the individual.
Ingestion
Ingestion of anionic surfactants may produce diarrhoea, bloated stomach, and occasional vomiting.
Skin Contact There is some evidence to suggest that this material can cause inflammation of the skin on contact in some persons.
There is some evidence to suggest that this material can cause eye irritation and damage in some persons.
Eye Direct eye contact with some anionic surfactants in high concentration can cause severe damage to the cornea. Low concentrations can cause
discomfort, excess blood flow, and corneal clouding and swelling. Recovery may take several days.
Long term exposure to high dust concentrations may cause changes in lung function i.e. pneumoconiosis, caused by particles less than 0.5
Chronic
micron penetrating and remaining in the lung.

TOXICITY IRRITATION
Bisplas
Not Available Not Available

TOXICITY IRRITATION

Dermal (rabbit) LD50: >2000 mg/kg[2] Eye (rabbit): non-irritant *

2-naphthalenesulfonic acid/
formaldehyde sodium salt Inhalation(Rat) LC50; 17.4 mg/L4h[2] Skin (rabbit): non-irritant *

Oral(Rat) LD50; 3800 mg/kg[2] Skin (rabbit): slight

TOXICITY IRRITATION
water
Oral(Rat) LD50; >90000 mg/kg[2] Not Available

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise
specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

2-NAPHTHALENESULFONIC
ACID/ FORMALDEHYDE * BASF
SODIUM SALT
2-NAPHTHALENESULFONIC
ACID/ FORMALDEHYDE No significant acute toxicological data identified in literature search.
SODIUM SALT & WATER

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity
Serious Eye Damage/Irritation STOT - Single Exposure
Respiratory or Skin
STOT - Repeated Exposure
sensitisation
Mutagenicity Aspiration Hazard
Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification

SECTION 12 Ecological information

Toxicity
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Endpoint Test Duration (hr) Species Value Source

Bisplas Not Not Not
Not Available Not Available
Available Available Available

Endpoint Test Duration (hr) Species Value Source

2-naphthalenesulfonic acid/
formaldehyde sodium salt Not Not Not
Not Available Not Available
Available Available Available

Endpoint Test Duration (hr) Species Value Source

water Not Not Not
Not Available Not Available
Available Available Available

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite
V3.12 (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment
Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air
water LOW LOW

Bioaccumulative potential
Ingredient Bioaccumulation
No Data available for all ingredients

Mobility in soil
Ingredient Mobility
No Data available for all ingredients

SECTION 13 Disposal considerations

Waste treatment methods

Recycle wherever possible or consult manufacturer for recycling options.
Consult State Land Waste Management Authority for disposal.
Product / Packaging disposal
Bury residue in an authorised landfill.
Recycle containers if possible, or dispose of in an authorised landfill.

SECTION 14 Transport information

Labels Required
Marine Pollutant NO

Land transport (DOT): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Transport in bulk according to Annex II of MARPOL and the IBC code

Not Applicable

Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
Product name Group
2-naphthalenesulfonic acid/
Not Available
formaldehyde sodium salt
water Not Available

Transport in bulk in accordance with the ICG Code

Product name Ship Type
2-naphthalenesulfonic acid/
Not Available
formaldehyde sodium salt
water Not Available

SECTION 15 Regulatory information

Safety, health and environmental regulations / legislation specific for the substance or mixture

2-naphthalenesulfonic acid/ formaldehyde sodium salt is found on the following regulatory lists
US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory US TSCA Chemical Substance Inventory - Interim List of Active Substances

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water is found on the following regulatory lists

US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory US TSCA Chemical Substance Inventory - Interim List of Active Substances

Federal Regulations

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Section 311/312 hazard categories

Flammable (Gases, Aerosols, Liquids, or Solids) No
Gas under pressure No
Explosive No
Self-heating No
Pyrophoric (Liquid or Solid) No
Pyrophoric Gas No
Corrosive to metal No
Oxidizer (Liquid, Solid or Gas) No
Organic Peroxide No
Self-reactive No
In contact with water emits flammable gas No
Combustible Dust No
Carcinogenicity No
Acute toxicity (any route of exposure) No
Reproductive toxicity No
Skin Corrosion or Irritation No
Respiratory or Skin Sensitization No
Serious eye damage or eye irritation No
Specific target organ toxicity (single or repeated exposure) No
Aspiration Hazard No
Germ cell mutagenicity No
Simple Asphyxiant No
Hazards Not Otherwise Classified No

US. EPA CERCLA Hazardous Substances and Reportable Quantities (40 CFR 302.4)
None Reported

State Regulations

US. California Proposition 65

None Reported

National Inventory Status

National Inventory Status
Australia - AIIC / Australia
Yes
Non-Industrial Use
Canada - DSL Yes
Canada - NDSL No (2-naphthalenesulfonic acid/ formaldehyde sodium salt; water)
China - IECSC Yes
Europe - EINEC / ELINCS / NLP No (2-naphthalenesulfonic acid/ formaldehyde sodium salt)
Japan - ENCS Yes
Korea - KECI Yes
New Zealand - NZIoC Yes
Philippines - PICCS Yes
USA - TSCA Yes
Taiwan - TCSI Yes
Mexico - INSQ No (2-naphthalenesulfonic acid/ formaldehyde sodium salt)
Vietnam - NCI Yes
Russia - FBEPH Yes
Yes = All CAS declared ingredients are on the inventory
Legend:
No = One or more of the CAS listed ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)

SECTION 16 Other information

Revision Date 01/11/2019

Initial Date 31/12/2015

SDS Version Summary

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Date of
Version Sections Updated
Update
Acute Health (inhaled), Acute Health (skin), Appearance, Chronic Health, Classification, Disposal, Engineering Control,
3.1.2.1 16/02/2016 Environmental, Fire Fighter (fire/explosion hazard), Handling Procedure, Ingredients, Personal Protection (hands/feet), Physical
Properties, Spills (major), Storage (storage requirement), Synonyms, Use
5.1.2.1 01/11/2019 One-off system update. NOTE: This may or may not change the GHS classification
5.1.3.1 10/05/2021 Regulation Change
5.1.4.1 24/05/2021 Regulation Change
5.1.4.2 30/05/2021 Template Change
5.1.4.3 04/06/2021 Template Change
5.1.4.4 05/06/2021 Template Change
5.1.4.5 09/06/2021 Template Change
5.1.4.6 11/06/2021 Template Change
5.1.4.7 15/06/2021 Template Change

Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or
other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

Definitions and abbreviations

PC－TWA: Permissible Concentration-Time Weighted Average
PC－STEL: Permissible Concentration-Short Term Exposure Limit
IARC: International Agency for Research on Cancer
ACGIH: American Conference of Governmental Industrial Hygienists
STEL: Short Term Exposure Limit
TEEL: Temporary Emergency Exposure Limit。
IDLH: Immediately Dangerous to Life or Health Concentrations
ES: Exposure Standard
OSF: Odour Safety Factor
NOAEL :No Observed Adverse Effect Level
LOAEL: Lowest Observed Adverse Effect Level
TLV: Threshold Limit Value
LOD: Limit Of Detection
OTV: Odour Threshold Value
BCF: BioConcentration Factors
BEI: Biological Exposure Index
AIIC: Australian Inventory of Industrial Chemicals
DSL: Domestic Substances List
NDSL: Non-Domestic Substances List
IECSC: Inventory of Existing Chemical Substance in China
EINECS: European INventory of Existing Commercial chemical Substances
ELINCS: European List of Notified Chemical Substances
NLP: No-Longer Polymers
ENCS: Existing and New Chemical Substances Inventory
KECI: Korea Existing Chemicals Inventory
NZIoC: New Zealand Inventory of Chemicals
PICCS: Philippine Inventory of Chemicals and Chemical Substances
TSCA: Toxic Substances Control Act
TCSI: Taiwan Chemical Substance Inventory
INSQ: Inventario Nacional de Sustancias Químicas
NCI: National Chemical Inventory
FBEPH: Russian Register of Potentially Hazardous Chemical and Biological Substances

This document is copyright.

Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without
written permission from CHEMWATCH.
TEL (+61 3) 9572 4700.

end of SDS