Page 1/18
Safety data sheet
                                                  according to 1907/2006/EC, Article 31
              Printing date 14.11.2023           Version number 1.11 (replaces version 1.10)          Revision: 14.11.2023
          *       SECTION 1: Identification of the substance/mixture and of the company/undertaking
                · 1.1 Product identifier
                · Trade name: Release agent f. double density Polyester-PU Concentrate of 1502/272
                · Article number: 1502/222
                · 1.2 Relevant identified uses of the substance or mixture and uses advised against
                  Not suitable for use in homeworker (DIY) applications.
                · Application of the substance / the mixture
                  Release Agent
                  Intermediate
                  Restricted to professional users.
                · Uses advised against cosmetic products
                · 1.3 Details of the supplier of the safety data sheet
                · Manufacturer/Supplier:
                  Jakob Keck Chemie GmbH
                  Zweibrücker Str.189 - 193
                  66954 Pirmasens
                  Tel.: 06331 537-0
                  Fax.: 06331 537-211
                · Informing department:
                  Product safety department.
                  e-mail: sdb@keck-chemie.de
                · 1.4 Emergency telephone number:
                  Monday - Thursday: 9 a.m. - 4 p.m.,
                  Friday: 7 - 2 p.m.
                  Mr. Eric Zimmer Tel.: +49 6331 537 170
          *       SECTION 2: Hazards identification
                · 2.1 Classification of the substance or mixture
                · Classification according to Regulation (EC) No 1272/2008
                            health hazard
                  Asp. Tox. 1        H304 May be fatal if swallowed and enters airways.
                  Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
                · 2.2 Label elements
                · Labelling according to Regulation (EC) No 1272/2008
                  The product is classified and labelled according to the GB CLP regulation.
                · Hazard pictograms GHS08
                · Signal word Danger
                · Hazard-determining components of labelling:
                  hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics
                · Hazard statements
                  H304 May be fatal if swallowed and enters airways.
                  H412 Harmful to aquatic life with long lasting effects.
                · Precautionary statements
                  P273         Avoid release to the environment.
                  P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
                  P331         Do NOT induce vomiting.
                  P405         Store locked up.
                  P501         Dispose of contents/container in accordance with local/regional/national/international
                               regulations.
                · Additional information:
                  EUH066 Repeated exposure may cause skin dryness or cracking.
                                                                                                           (Contd. on page 2)
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                                                                                                                        Page 2/18
                                                           Safety data sheet
                                                 according to 1907/2006/EC, Article 31
              Printing date 14.11.2023          Version number 1.11 (replaces version 1.10)                  Revision: 14.11.2023
              Trade name: Release agent f. double density Polyester-PU Concentrate of 1502/272
                                                                                                                   (Contd. of page 1)
                · Information pertaining to particular dangers for man and environment
                  At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the solvent.
                  May be fatal if swallowed and enters airways.
                · 2.3 Other hazards Inhalation of aerosol spray may damage health.
                · Results of PBT and vPvB assessment
                · PBT: Not applicable.
                · vPvB: Not applicable.
                · Determination of endocrine-disrupting properties
                  The product does not contain substances with endocrine disrupting properties.
                  For information on endocrine disrupting properties see section 11.
          *       SECTION 3: Composition/information on ingredients
                · 3.2 Mixtures
                  EC number: 927-285-2         hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% 50 – 100%
                  Reg.nr.: 01-2119480162-45 aromatics
                                                  Asp. Tox. 1, H304, EUH066
                                               polydimethylsiloxane                                              10 – 25%
                  CAS: 8042-47-5               White mineral oil, petroleum                                     2.5 – 10%
                  EINECS: 232-455-8            substance with a Community workplace exposure limit
                  Reg.nr.: 01-2119487078-27
                · Description: Mixture of the substances listed below with harmless additions.
                · Dangerous components:
                  EC number: 927-285-2          hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, <    50 – 100%
                  Reg.nr.: 01-2119480162-45 2% aromatics
                                                   Asp. Tox. 1, H304, EUH066
                  CAS: 8042-47-5                White mineral oil, petroleum                                 2.5 – 10%
                  EINECS: 232-455-8             substance with a Community workplace exposure limit
                  Reg.nr.: 01-2119487078-27
                  CAS: 8002-74-2                Paraffin waxes and Hydrocarbon waxes                          < 2.5%
                  EINECS: 232-315-6             substance with a Community workplace exposure limit
                  Reg.nr.: 01-2119488076-30
                           01-2119913039-42
                  CAS: 541-02-6                 decamethylcyclopentasiloxane                                  < 0.1%
                  EINECS: 208-764-9             Non-classified vPvB substance.
                  Reg.nr.: 01-2119511367-43 Non-classified PBT substance.
                                                Substance with a Community workplace exposure limit.
                                                Substance identified as having endocrine disrupting
                                                properties (II).
                  CAS: 556-67-2                 octamethylcyclotetrasiloxane                               0.025 – < 0.1%
                  EINECS: 209-136-7                Flam. Liq. 3, H226;      Repr. 2, H361f;    Aquatic
                  Index number: 014-018-00-1 Chronic 1, H410 (M=10)
                  Reg.nr.: 01-2119529238-36 Non-classified vPvB substance.
                                                Non-classified PBT substance.
                                                Substance with a Community workplace exposure limit.
                                                Substance identified as having endocrine disrupting
                                                properties (II; III).
                  CAS: 100-41-4                 ethylbenzene                                                  < 0.1%
                  EINECS: 202-849-4                Flam. Liq. 2, H225;      STOT RE 2, H373; Asp. Tox. 1,
                  Index number: 601-023-00-4 H304;         Acute Tox. 4, H332; Aquatic Chronic 3, H412
                  Reg.nr.: 01-2119489370-35 substance with a Community workplace exposure limit
                · Additional information For the wording of the listed hazard phrases refer to section 16.
                                                                                                                   (Contd. on page 3)
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                                                                                                                    Page 3/18
                                                          Safety data sheet
                                                according to 1907/2006/EC, Article 31
              Printing date 14.11.2023          Version number 1.11 (replaces version 1.10)             Revision: 14.11.2023
              Trade name: Release agent f. double density Polyester-PU Concentrate of 1502/272
                                                                                                               (Contd. of page 2)
          *       SECTION 4: First aid measures
                · 4.1 Description of first aid measures
                · General information
                  Instantly remove any clothing soiled by the product.
                  Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
                  hours after the accident.
                  Take off contaminated clothing and wash it before reuse.
                  Call a doctor immediately.
                · After inhalation
                  In case of unconsciousness bring patient into stable side position for transport.
                  Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms
                  persist.
                · After skin contact
                  Instantly wash with water and soap and rinse thoroughly.
                  Consult a doctor in the event of a skin reaction.
                · After eye contact
                  Rinse cautiously with water for several minutes.
                  If eye irritation persists: Get medical advice/attention.
                · After swallowing
                  If swallowed, rinse mouth with water (only if the person is conscious).
                  Instantly call for doctor.
                  Do NOT induce vomiting.
                  If swallowed or in case of vomiting, danger of entering the lungs
                  May be fatal if swallowed and enters airways.
                  A person vomiting while lying on their back should be turned onto their side.
                  Never give anything by mouth to an unconscious person.
                · Information for doctor treat symptomatically
                · 4.2 Most important symptoms and effects, both acute and delayed
                  Headache
                  At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the solvent.
                · 4.3 Indication of any immediate medical attention and special treatment needed
                  If swallowed or in case of vomiting, danger of entering the lungs
                  Subsequent observation for pneumonia and pulmonary oedema
          *       SECTION 5: Firefighting measures
                · 5.1 Extinguishing media
                · Suitable extinguishing agents
                  Fire-extinguishing powder
                  Alcohol-resistant foam
                  CO , sand.
                · For safety reasons unsuitable extinguishing agents Water with a full water jet.
                · 5.2 Special hazards arising from the substance or mixture
                  Formation of toxic gases is possible during heating or in case of fire.
                  Can be released in case of fire
                  Nitrogen oxides (NOx)
                  Products of incomplete combustion
                  Carbon monoxide and carbon dioxide
                  Hydrocarbons
                  silicon dioxide
                  Aldehyde
                  The product floats on water.and is insoluble or has a poor miscibility.
                · 5.3 Advice for firefighters
                · Protective equipment:
                  Do not inhale explosion gases or combustion gases.
                  Wear self-contained breathing apparatus.
                · Additional information
                  Cool endangered containers with water spray jet.
                                                                                                               (Contd. on page 4)
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                                                                                                                         Page 4/18
                                                           Safety data sheet
                                                 according to 1907/2006/EC, Article 31
              Printing date 14.11.2023           Version number 1.11 (replaces version 1.10)                Revision: 14.11.2023
              Trade name: Release agent f. double density Polyester-PU Concentrate of 1502/272
                                                                                                                  (Contd. of page 3)
                  Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
                  Suppress (knock down) gases/vapours/mists with a water spray jet.
                  In partly emptied containers formation of explosive mixtures is possible.
          *       SECTION 6: Accidental release measures
                · 6.1 Personal precautions, protective equipment and emergency procedures
                  Particular danger of slipping on leaked/spilled product.
                  Ensure adequate ventilation
                  Bring persons out of danger.
                  Keep away from ignition sources
                  Avoid contact with spilled material.
                  Avoid contact with the eyes and skin.
                · 6.2 Environmental precautions:
                  Prevent from spreading (e.g. by damming-in or oil barriers).
                  Do not allow to enter drainage system, surface or ground water.
                  Do not allow to enter the ground/soil.
                  Inform respective authorities in case product reaches water or sewage system.
                  If material reaches soil inform authorities responsible for such cases.
                · 6.3 Methods and material for containment and cleaning up:
                  Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
                  Contain larger amounts and pump up into suitable containers.
                  Stop leak if you can do so without risk.
                  Remove from the surface of water (e.g. skim or vacuum off)
                  Dispose of contents/container in accordance with local/regional/national/international regulations.
                · 6.4 Reference to other sections
                  See Section 7 for information on safe handling
                  See Section 8 for information on personal protection equipment.
                  See Section 13 for information on disposal.
          *       SECTION 7: Handling and storage
                · 7.1 Precautions for safe handling
                  Do not eat, drink or smoke while working.
                  Ensure good ventilation/exhaustion at the workplace.
                  Store in cool, dry place in tightly closed containers.
                  Open and handle container with care.
                  Work only in fume cupboard.
                  Carry out filling operations only at sites with extractors available.
                  Extractor required on object.
                  Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air).
                  Particular danger of slipping on leaked/spilled product.
                  Avoid contact with the eyes and skin.
                  The usual precautionary measures should be adhered to general rules for handling chemicals.
                  Keep away from ignition sources
                · Information about protection against explosions and fires:
                  Flammable mixtures may be formed in empty containers.
                  Keep ignition sources away - Do not smoke.
                · 7.2 Conditions for safe storage, including any incompatibilities
                · Storage
                · Requirements to be met by storerooms and containers:
                  Provide floor trough without outlet.
                  Prevent any penetration into the ground.
                  Store only in the original container.
                  Provide solvent resistant, sealed floor.
                  Suitable material for containers and pipes: High-grade steel.
                  EPDM rubber
                                                                                                                  (Contd. on page 5)
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                                                                                                                         Page 5/18
                                                            Safety data sheet
                                                  according to 1907/2006/EC, Article 31
              Printing date 14.11.2023           Version number 1.11 (replaces version 1.10)                  Revision: 14.11.2023
              Trade name: Release agent f. double density Polyester-PU Concentrate of 1502/272
                                                                                                                    (Contd. of page 4)
                · Information about storage in one common storage facility:
                  Store away from foodstuffs.
                  Store away from oxidising agents.
                · Further information about storage conditions:
                  Keep container tightly sealed.
                  Store in a locked cabinet or with access restricted to technical experts or their assistants.
                  Protect from heat and direct sunlight.
                  Store in a cool place.
                · Recommended storage temperature: 5 - 30°C
                · Storage class 10 (flammable liquids)
                · 7.3 Specific end use(s) No further relevant information available.
          *       SECTION 8: Exposure controls/personal protection
                · 8.1 Control parameters
                · Components with limit values that require monitoring at the workplace:
                                       10,0 mg/m³                 Aerosol - respirable fraction
                  The aerosol limit specified is a recommendation should aerosol be formed during processing.
                  8042-47-5 White mineral oil, petroleum
                  TWA (European Union) Long-term value: 5 mg/m³
                                              (in case of formation of 'fog' during application)
                  8002-74-2 Paraffin waxes and Hydrocarbon waxes
                  WEL (Great Britain)         Short-term value: 6 mg/m³
                                              Long-term value: 2 mg/m³
                  541-02-6 decamethylcyclopentasiloxane
                  TWA (European Union) Long-term value: 10 ppm
                                              Recommendation (Dow Corning)
                  556-67-2 octamethylcyclotetrasiloxane
                  TWA (European Union) Long-term value: 10 ppm
                                              Recommendation (Dow Corning)
                  100-41-4 ethylbenzene
                  WEL (Great Britain)         Short-term value: 552 mg/m³, 125 ppm
                                              Long-term value: 441 mg/m³, 100 ppm
                                              Sk
                  IOELV (European Union) Short-term value: 884 mg/m³, 200 ppm
                                              Long-term value: 442 mg/m³, 100 ppm
                                              Skin
                  STEL (European Union) Short-term value: 884 mg/m³, 200 ppm
                  TWA (European Union) Short-term value: 880 mg/m³, 200 ppm
                                              Long-term value: 442 mg/m³, 100 ppm
                · DNELs
                  8042-47-5 White mineral oil, petroleum
                  Dermal     long-term, systemic effects 220 mg/kg bw/day (human)
                                                          (8 h)
                  Inhalative long-term, systemic effects 160 mg/m³ (human)
                                                          (8 h)
                  541-02-6 decamethylcyclopentasiloxane
                  Oral       short-term, systemic effects 5 mg/kg bw/day (consumer)
                             long-term, systemic effects 5 mg/kg bw/day (consumer)
                  Inhalative short-term, local effects    4.3 mg/m³ (consumer)
                                                          24.2 mg/m³ (worker)
                             short-term, systemic effects 17.3 mg/m³ (consumer)
                                                          97.3 mg/m³ (worker)
                                                                                                                   (Contd. on page 6)
57.0.12
                                                                                                             Page 6/18
                                                     Safety data sheet
                                            according to 1907/2006/EC, Article 31
          Printing date 14.11.2023          Version number 1.11 (replaces version 1.10)           Revision: 14.11.2023
          Trade name: Release agent f. double density Polyester-PU Concentrate of 1502/272
                                                                                                        (Contd. of page 5)
                        long-term, local effects      4.3 mg/m³ (consumer)
                                                      24.2 mg/m³ (worker)
                         long-term, systemic effects 17.3 mg/m³ (consumer)
                                                      97.3 mg/m³ (worker)
              556-67-2 octamethylcyclotetrasiloxane
              Oral       short-term, systemic effects 3.7 mg/kg bw/day (consumer)
                         long-term, systemic effects 3.7 mg/kg bw/day (consumer)
              Inhalative short-term, local effects    13 – 61 mg/m³ (consumer)
                                                      73 mg/m³ (worker)
                         short-term, systemic effects 13 – 305 mg/m³ (consumer)
                                                      73 mg/m³ (worker)
                         long-term, local effects     13 mg/m³ (consumer)
                                                      73 mg/m³ (worker)
                         long-term, systemic effects 13 mg/m³ (consumer)
                                                      73 mg/m³ (worker)
              100-41-4 ethylbenzene
              Oral       long-term, systemic effects 1.6 mg/kg bw/day (consumer)
              Dermal     long-term, local effects     180 mg/kg bw/day (worker)
              Inhalative short-term, local effects    293 mg/m³ (worker)
                         long-term, systemic effects 15 mg/m³ (consumer)
                                                      77 mg/m³ (worker)
            · PNECs
              hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics
              PNEC (Predicted No Effect Concentration) mg/l (sewage treatment plant)
                                                       n.v.
                                                       mg/l (marine water)
                                                       n.v.
                                                       mg/l (fresh water)
                                                       n.v.
                                                       mg/l (intermittent release)
                                                       n.v.
              PNEC (Predicted No Effect Concentration) mg/kg (soil (dry matter))
                                                       n.v.
                                                       mg/kg (marine sediment (dry matter))
                                                       n.v.
                                                       mg/kg (fresh water sediment (dry matter))
                                                       n.v.
              541-02-6 decamethylcyclopentasiloxane
              PNEC (Predicted No Effect Concentration) > 10 mg/l (sewage treatment plant)
                                                       > 0.00012 mg/l (marine water)
                                                       > 0.0012 mg/l (fresh water)
              PNEC (Predicted No Effect Concentration) 1.1 mg/kg (soil (dry matter))
                                                       0.239 mg/kg (marine sediment (dry matter))
                                                       2.39 mg/kg (fresh water sediment (dry matter))
              556-67-2 octamethylcyclotetrasiloxane
              PNEC (Predicted No Effect Concentration) 10 mg/l (sewage treatment plant)
                                                       0.00015 mg/l (marine water)
                                                       0.0015 mg/l (fresh water)
              PNEC (Predicted No Effect Concentration) 0.54 mg/kg (soil (dry matter))
                                                                                                        (Contd. on page 7)
57.0.12
                                                                                                                   Page 7/18
                                                      Safety data sheet
                                            according to 1907/2006/EC, Article 31
          Printing date 14.11.2023          Version number 1.11 (replaces version 1.10)                 Revision: 14.11.2023
          Trade name: Release agent f. double density Polyester-PU Concentrate of 1502/272
                                                                                                              (Contd. of page 6)
                                                          41 mg/kg (oral, secondary poisoning)
                                                          0.3 mg/kg (marine sediment (dry matter))
                                                          3 mg/kg (fresh water sediment (dry matter))
              100-41-4 ethylbenzene
              PNEC (Predicted No Effect Concentration) 9.6 mg/l (sewage treatment plant)
                                                           0.01 mg/l (marine water)
                                                           0.1 mg/l (fresh water)
                                                           0.1 mg/l (consumer)
                                                           0.1 mg/l (intermittent release)
              PNEC (Predicted No Effect Concentration) 2.68 mg/kg (soil (dry matter))
                                                           0.02 mg/kg (oral, secondary poisoning)
                                                           1.37 mg/kg (marine sediment (dry matter))
                                                           13.7 mg/kg (fresh water sediment (dry matter))
            · Additional information:
              The lists that were valid during the compilation were used as basis.
              Note: Information about recommended monitoring procedures can be obtained from the relevant agency(ies)/
              institute(s): for the United Kingdom: UK Health and Safety Executive (HSE)
            · 8.2 Exposure controls
            · Appropriate engineering controls No further data; see section 7.
            · Individual protection measures, such as personal protective equipment
            · General protective and hygienic measures
              The usual precautionary measures should be adhered to general rules for handling chemicals.
              Wash hands during breaks and at the end of the work.
              Do not eat, drink or smoke while working.
              Avoid contact with the eyes and skin.
              Do not inhale gases / fumes / aerosols.
              Avoid close or long term contact with the skin.
            · Breathing equipment: Filter A/P2.
            · Hand protection
              Protective gloves.
              Only use chemical-protective gloves with CE-labelling of category III.
              Check protective gloves prior to each use for their proper condition.
              The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
              Preventive skin protection by use of skin-protecting agents is recommended.
              After use of gloves apply skin-cleaning agents and skin cosmetics.
              Protective gloves should be replaced at first signs of wear.
            · Material of gloves
              Nitrile rubber, NBR
              Recommended thickness of the material: >0,5 mm
              The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
              and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
              resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
              application.
            · Penetration time of glove material
              The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
              observed.
            · As protection from splashes gloves made of the following materials are suitable: Nitrile rubber, NBR
            · Not suitable are gloves made of the following materials:
              Strong gloves
              Leather gloves
            · Eye/face protection
              Face protection
              Safety glasses
            · Body protection: Protective work clothing.
            · Environmental exposure controls
              Do not allow to enter drainage system, surface or ground water.
                                                                                                             (Contd. on page 8)
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                                                          Safety data sheet
                                                according to 1907/2006/EC, Article 31
              Printing date 14.11.2023          Version number 1.11 (replaces version 1.10)            Revision: 14.11.2023
              Trade name: Release agent f. double density Polyester-PU Concentrate of 1502/272
                                                                                                             (Contd. of page 7)
                  Do not allow to enter the ground/soil.
                  Prevent from spreading (e.g. by damming-in or oil barriers).
          *       SECTION 9: Physical and chemical properties
                · 9.1 Information on basic physical and chemical properties
                · General Information
                · Physical state                                     Fluid
                · Colour:                                            Whitish
                · Odour:                                             Light
                · Odour threshold:                                   Not determined.
                · Melting point/freezing point:                      Not determined.
                · Boiling point or initial boiling point and boiling
                  range                                              180 °C (hydrocarbons, C11-C14, n-alkanes, isoalkanes,
                                                                     cyclics, < 2% aromatics)
                · Lower and upper explosion limit
                · Lower:                                             0.5 Vol % (hydrocarbons, C11-C14, n-alkanes,
                                                                     isoalkanes, cyclics, < 2% aromatics)
                · Upper:                                             5 Vol % (hydrocarbons, C11-C14, n-alkanes, isoalkanes,
                                                                     cyclics, < 2% aromatics)
                · Minimum ignition energy:
                · Flash point:                                       62 °C (hydrocarbons, C11-C14, n-alkanes, isoalkanes,
                                                                     cyclics, < 2% aromatics)
                · Auto-ignition temperature:                         228 °C (hydrocarbons, C11-C14, n-alkanes, isoalkanes,
                                                                     cyclics, < 2% aromatics)
                · Decomposition temperature:                         Not determined.
                · pH                                                 Not determined.
                · Viscosity:
                · Kinematic viscosity at 20 °C                       12 s (DIN 53211/4)
                · dynamic:                                           Not determined.
                · Solubility
                · Water:                                             Not miscible or difficult to mix
                · Partition coefficient n-octanol/water (log value) See section 12
                · Vapour pressure at 20 °C:                          0.6 hPa (hydrocarbons, C11-C14, n-alkanes, isoalkanes,
                                                                     cyclics, < 2% aromatics)
                · (50°C):
                · Density and/or relative density
                · Density at 20 °C                                   0.815 g/cm³
                · Relative density                                   Not determined.
                · Vapour density                                     Not determined.
                · 9.2 Other information
                · Appearance:
                · Form:                                             Fluid
                · Important information on protection of health and
                  environment, and on safety.
                · Explosive properties:                             Product is not explosive.
                · Organic solvents:
                · VOC (EU):                                         502.1 g/l
                · VOC (%):                                          61.6 %
                · Solids content:                                   38.4 %
                · Change in condition
                · Evaporation rate                                  Not determined.
                · Information with regard to physical hazard classes
                · Explosives                                         Void
                · Flammable gases                                    Void
                · Aerosols                                           Void
                · Oxidising gases                                    Void
                · Gases under pressure                               Void
                                                                                                             (Contd. on page 9)
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                                                         Safety data sheet
                                               according to 1907/2006/EC, Article 31
              Printing date 14.11.2023         Version number 1.11 (replaces version 1.10)              Revision: 14.11.2023
              Trade name: Release agent f. double density Polyester-PU Concentrate of 1502/272
                                                                                                              (Contd. of page 8)
                · Flammable liquids                                 Void
                · Flammable solids                                  Void
                · Self-reactive substances and mixtures             Void
                · Pyrophoric liquids                                Void
                · Pyrophoric solids                                 Void
                · Self-heating substances and mixtures              Void
                · Substances and mixtures, which emit flammable
                  gases in contact with water                       Void
                · Oxidising liquids                                 Void
                · Oxidising solids                                  Void
                · Organic peroxides                                 Void
                · Corrosive to metals                               Void
                · Desensitised explosives                           Void
          *       SECTION 10: Stability and reactivity
                · 10.1 Reactivity No further relevant information available.
                · 10.2 Chemical stability
                · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
                · 10.3 Possibility of hazardous reactions
                  Can form explosive mixtures in air if heated above flash point and/or when sprayed or atomised
                  Reacts with strong oxidizing agents
                  Reacts with fabric soaked in the product (e.g. cleaning wool): self ignition is possible.
                  Used empty containers may contain product gases which form explosive mixtures with air
                · 10.4 Conditions to avoid No further relevant information available.
                · 10.5 Incompatible materials: strong oxidizing agents
                · 10.6 Hazardous decomposition products:
                  No hazardous decomposition products if stored and handled as prescribed/indicated.
          *       SECTION 11: Toxicological information
                · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
                · Acute toxicity No toxicological test data are available for the whole product.
                · LD/LC50 values that are relevant for classification:
                  * No mortality was observed.
                  *¹ Toxicological studies of a comparable product.
                  hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics
                  Oral       LD Acute toxicity:                     > 5,000 mg/kg (rat) (OECD Guideline 401)
                  Dermal     LD Acute toxicity, dermal:             > 2,000 mg/kg (canine) (OECD Guideline 402)
                                                                    *¹
                  Inhalative LC (4 h) Acute toxicity, inhalative: > 1,200 mg/l (rat)
                                                                    *¹
                  8042-47-5 White mineral oil, petroleum
                  Oral       LD Acute toxicity:                     > 5,000 mg/kg (rat) (OECD Guideline 401)
                  Dermal     LD Acute toxicity, dermal:             > 2,000 mg/kg (canine) (OECD Guideline 402)
                  Inhalative LC Acute toxicity, inhalative:         > 5.53 mg/l (rat) (OECD Guideline 403)
                                                                    (4 h)
                  541-02-6 decamethylcyclopentasiloxane
                  Oral       LD Acute toxicity:                     > 24,134 mg/kg (rat) (Limittest)
                                                                    *
                  Dermal     LD Acute toxicity, dermal:             > 2,000 mg/kg (canine, male/female)
                                                                    *
                                                                                                             (Contd. on page 10)
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                                                    Safety data sheet
                                           according to 1907/2006/EC, Article 31
          Printing date 14.11.2023        Version number 1.11 (replaces version 1.10)              Revision: 14.11.2023
          Trade name: Release agent f. double density Polyester-PU Concentrate of 1502/272
                                                                                                         (Contd. of page 9)
                                                                > 15,000 mg/kg (rat)
                                                                (Limittest)
              Inhalative LC (4 h) Acute toxicity, inhalative: 8.67 mg/l (rat, male/female)
                                                                *
              556-67-2 octamethylcyclotetrasiloxane
              Oral        LD Acute toxicity:                    > 4,800 mg/kg (rat)
                                                                *
              Dermal      LD Acute toxicity, dermal:            > 2,400 mg/kg (rat, male/female)
                                                                *
              Inhalative LC (4 h) Acute toxicity, inhalative: 36 mg/l (rat, male/female) (OECD Guideline 403)
                                                                *
              100-41-4 ethylbenzene
              Oral        LD Acute toxicity:                    3,500 mg/kg (rat)
              Dermal      LD Acute toxicity, dermal:            15,000 mg/kg (canine)
              Inhalative LC (4 h) Acute toxicity, inhalative: 17.2 mg/l (rat)
                          LCL                                   4,000 ppm (rat)
                                                                (4 h)
            · Skin corrosion/irritation
              Classification: No skin irritation
              At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the solvent.
              The product has not been tested. The statement has been derived from the properties of the individual
              components.
              Repeated exposure may cause skin dryness or cracking.
              *¹ Toxicological studies of a comparable product.
              hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics
              Irritation of skin Skin corrosion: neg. (canine) (OECD Guideline 404)
                                                 *¹
              8042-47-5 White mineral oil, petroleum
              Irritation of skin -               neg. (canine) (OECD Guideline 404)
              541-02-6 decamethylcyclopentasiloxane
              Irritation of skin Skin corrosion: neg. (canine)
              556-67-2 octamethylcyclotetrasiloxane
              Irritation of skin Skin corrosion: neg. (canine)
            · Serious eye damage/irritation
              Classification: No eye irritation
              The product has not been tested. The statement has been derived from the properties of the individual
              components.
              *¹ Toxicological studies of a comparable product.
              hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics
              Irritation of eyes Serious eye damage/irritation: neg. (canine) (OECD Guideline 405)
                                                                 *¹
              8042-47-5 White mineral oil, petroleum
              Irritation of eyes -                               neg. (canine) (OECD Guideline 405)
              541-02-6 decamethylcyclopentasiloxane
              Irritation of eyes Serious eye damage/irritation: neg. (canine)
              556-67-2 octamethylcyclotetrasiloxane
              Irritation of eyes Serious eye damage/irritation: neg. (canine)
            · Respiratory or skin sensitisation
              No sensitizing effect known.
              The product has not been tested. The statement has been derived from the properties of the individual
              components.
                                                                                                        (Contd. on page 11)
57.0.12
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                                                       Safety data sheet
                                             according to 1907/2006/EC, Article 31
          Printing date 14.11.2023           Version number 1.11 (replaces version 1.10)              Revision: 14.11.2023
          Trade name: Release agent f. double density Polyester-PU Concentrate of 1502/272
                                                                                                            (Contd. of page 10)
              8042-47-5 White mineral oil, petroleum
              Sensitization -                                       neg (guinea pig) (OECD Guideline 406)
              541-02-6 decamethylcyclopentasiloxane
              Sensitization Skin sensitisation:                     neg. (mouse)
                            Local Lymph Node Assay (LLNA)           neg. (mouse)
              556-67-2 octamethylcyclotetrasiloxane
              Sensitization Skin sensitisation:                     neg. (human)
                            Skin sensitisation (maximizing test):   neg. (guinea pig)
            · Germ cell mutagenicity
              8042-47-5 White mineral oil, petroleum
              Chromosome Aberration Test       neg. (not specified) (OECD-Guideline 474)
              541-02-6 decamethylcyclopentasiloxane
              Chromosome Aberration Test       neg. (OECD Guideline 473)
              Micronucleustest                 neg. (rat, male/female) (OECD-Guideline 474)
              Mutagenicity                     neg. (rat)
              Unscheduled DNA synthesis test (mammalian liver cells in vivo)
                                               neg.
              556-67-2 octamethylcyclotetrasiloxane
              Chromosome Aberration Test       neg. (in vitro)
              Mutagenicity                     neg. (Mammalian Cell Gene Mutation Test)
            · Carcinogenicity
              *¹ Toxicological studies of a comparable product.
              hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics
                         Carcinogenicity neg. (human)
                                           *¹
              8042-47-5 White mineral oil, petroleum
              Inhalative Carcinogenicity neg. (not specified) (OECD Guideline 453)
            · Reproductive toxicity
              541-02-6 decamethylcyclopentasiloxane
              Reproductive toxicity neg. (fertility, rat (male/female)) (two-generation reproduction toxicity study)
                                     Application Route: Inhalation
                                     No effects on fertility
              556-67-2 octamethylcyclotetrasiloxane
              Reproductive toxicity 700 ppm (female rat)
                                     (Inhalation)
                                     Suspected of damaging fertility.
            · STOT-single exposure
              Inhalation of concentrated vapours as well as oral intake will lead to anaesthesia-like conditions and
              headache, dizziness, etc.
            · STOT-repeated exposure
              *¹ Toxicological studies of a comparable product.
              hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics
              Oral      NOAEL (oral)                         5,000 mg/kg bw/day (rat)
                                                          (90 d) *¹
              8042-47-5 White mineral oil, petroleum
              Oral      NOAEC (chronic)                   > 1,200 mg/kg bw/day (rat) (OECD Guideline 453)
              Dermal    NOAEL (subacute)                  1,000 (canine) (OECD 410)
                        NOAEL (subchronic)                   2,000 mg/kg (rat) (OECD 411)
                                                                                                            (Contd. on page 12)
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                                                                                                               Page 12/18
                                                      Safety data sheet
                                            according to 1907/2006/EC, Article 31
          Printing date 14.11.2023          Version number 1.11 (replaces version 1.10)             Revision: 14.11.2023
          Trade name: Release agent f. double density Polyester-PU Concentrate of 1502/272
                                                                                                          (Contd. of page 11)
              541-02-6 decamethylcyclopentasiloxane
              Oral      NOEL (chronic, oral)                1,000 mg/kg (rat)
                                                          (7d / w)
                          Specific target organ toxicity 100 mg/kg (rat)
              Dermal      NOAEL                             1,600 mg/kg bw/day (rat)
                                                          (5d / w, 6h / d)
                          Specific target organ toxicity 200 mg/kg bw/day (rat)
              Inhalative NOEC                               160 mg/l (rat)
                                                          (5d / w, 6h / d)*
                          Specific target organ toxicity 1,000 mg/m³ (rat) (6h/d)
              556-67-2 octamethylcyclotetrasiloxane
              Inhalative NOEC                             0.36 mg/l (rat, male/female)
                                                          (5d / w, 6h / d)*
            · Aspiration hazard May be fatal if swallowed and enters airways.
            · Other information (about experimental toxicology):
              Inhalable aerosols containing aminofunctional polysiloxanes may cause harmful effects in the lung in animal
              experiments. Due to the large number of influencing parameters (e.g. amine function, degree of substitution,
              viscosity, composition) an estimation of the toxicological effect on the lung is not possible for untested
              products of this category.
              In such cases exposure to inhalable aerosols must be prevented by adequate technical measures.
            · Additional toxicological information:
              If swallowed or in case of vomiting, danger of entering the lungs
              May be fatal if swallowed and enters airways.
              Product may emit formaldehyde vapour at temperatures above 150ºC in the presence of air. Formaldehyde
              vapour is a suspected carcinogen, toxic by inhalation and irritating to eyes and the respiratory system.
              Exposure limits should be strictly respected.
            · Acute effects (acute toxicity, irritation and corrosivity)
              Inhalation of concentrated vapours as well as oral intake will lead to anaesthesia-like conditions and
              headache, dizziness, etc.
              May be fatal if swallowed and enters airways.
            · Repeated dose toxicity No further relevant information available.
            ·
              No toxicological test data are available for the whole product.
              8042-47-5 White mineral oil, petroleum
              Ames test (bacteria) (OECD Guideline 471)
              541-02-6 decamethylcyclopentasiloxane
              Ames test (bacteria)
                         neg.
              556-67-2 octamethylcyclotetrasiloxane
              Ames test neg. (bacteria)
            · Developmental toxicity (teratogenicity)
              541-02-6 decamethylcyclopentasiloxane
              Inhalative Teratogenicity neg. (rat) (two-generation reproduction toxicity study)
                                        No effects on foetal development.
            · 11.2 Information on other hazards
            · Endocrine disrupting properties
              540-97-6 dodecamethylcyclohexasiloxane                                                           List II
              541-02-6 decamethylcyclopentasiloxane                                                            List II
              556-67-2 octamethylcyclotetrasiloxane                                                            List II; III
                                                                                                          (Contd. on page 13)
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                                                                                                                 Page 13/18
                                                        Safety data sheet
                                               according to 1907/2006/EC, Article 31
              Printing date 14.11.2023        Version number 1.11 (replaces version 1.10)             Revision: 14.11.2023
              Trade name: Release agent f. double density Polyester-PU Concentrate of 1502/272
                                                                                                            (Contd. of page 12)
          *       SECTION 12: Ecological information
                · 12.1 Toxicity
                · Aquatic toxicity:
                  Harmful to aquatic life with long lasting effects.
                  * Studies of a comparable product.
                  hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics
                  EC -Toxicity for daphnia                       > 1,000 mg/l (daphnia (Daphnia magna))
                                                                 (48 h) *
                  LC -Fish toxicity                              > 1,000 mg/l (rainbow trout (Oncorhynchus mykiss))
                                                                 (96 h) *
                  EC -Toxicity for algae                         > 1,000 mg/l (Pseudokirchneriella subcapitata)
                                                                 (72 h) *
                  LC -Toxicity for daphnia                       > 81,000 mg/l (Mysidopsis bahia)
                                                                 (96 h) *
                  8042-47-5 White mineral oil, petroleum
                  EC -Toxicity for daphnia                       > 10,000 mg/l (daphnia (Daphnia magna))
                  LC -Fish toxicity                              > 100 mg/l (fish (not specified))
                  EC -Toxicity for algae                         > 100 mg/l (algae)
                                                                 (72h)
                  NOEC (aquatic)                                     100 mg/l (Pseudokirchneriella subcapitata) (OECD
                                                                 Guideline 201)
                                                                 (72 h)
                  541-02-6 decamethylcyclopentasiloxane
                  EC -Toxicity for daphnia                       > 2.9 mg/l (daphnia (Daphnia magna)) (OECD Guideline 202)
                                                                 (48 h)
                  LC -Fish toxicity                              > 3,000 mg/l (ide (Leuciscus idus))
                                                                 (96h)
                                                                 > 0.016 mg/l (rainbow trout (Oncorhynchus mykiss)) (OECD
                                                                 204)
                                                                 *¹
                  ErC -Toxicity for algae (growth inhibition) > 0.012 mg/l (Pseudokirchneriella subcapitata)
                                                                 (96 h) *¹
                  LC -Fish toxicity                              200 mg/l (ide (Leuciscus idus))
                                                                 (96h)
                  NOEC (chronic)                                 0.015 mg/l (daphnia (Daphnia magna))
                                                                 (21 d) *¹
                                                                    0.014 mg/l (rainbow trout (Oncorhynchus mykiss))
                                                                 (90d) *¹
                  NOEC (aquatic)                                    0.017 mg/l (rainbow trout (Oncorhynchus mykiss))
                                                                 (45d) *¹
                                                                 0.012 mg/l (Pseudokirchneriella subcapitata)
                                                                 (96 h) *¹
                  556-67-2 octamethylcyclotetrasiloxane
                  EC -Toxicity for daphnia (static)              > 0.015 mg/l (daphnia (Daphnia magna))
                                                                 (48h) *¹
                                                                 > 0.0091 mg/l (Mysidopsis bahia)
                                                                 (96h) *¹
                  LC -Fish toxicity (dynamic)                    > 0.0063 mg/l (sheepshead minnow(Cyprinodon variegatus))
                                                                 (14d) *¹
                                                                 > 0.022 mg/l (rainbow trout (Oncorhynchus mykiss))
                                                                 (96h) *¹
                                                                                                           (Contd. on page 14)
57.0.12
                                                                                                              Page 14/18
                                                     Safety data sheet
                                           according to 1907/2006/EC, Article 31
          Printing date 14.11.2023         Version number 1.11 (replaces version 1.10)              Revision: 14.11.2023
          Trade name: Release agent f. double density Polyester-PU Concentrate of 1502/272
                                                                                                         (Contd. of page 13)
              EC -Toxicity for algae                         0.022 mg/l (Pseudokirchneriella subcapitata)
                                                           (96h) *¹
              ErC -Toxicity for algae (growth inhibition) > 0.022 mg/l (Pseudokirchneriella subcapitata)
                                                           (96h) *¹
              NOEC (aquatic)                               0.022 mg/l (algae)
                                                           (96 h) *¹
                                                             0.0079 mg/l (daphnia (Daphnia magna))
                                                           (21 d)
                                                             0.0044 mg/l (rainbow trout (Oncorhynchus mykiss))
                                                           (93d) *¹
              100-41-4 ethylbenzene
              EC -Toxicity for daphnia                     2.1 mg/l (daphnia (Daphnia magna))
                                                           (48 h)
              EC -Bacterial toxicity                       12 mg/l (Pseudomonas putida)
                                                           (16 h)
              LC -Fish toxicity                            32 mg/l (bluegill (Lepomis macrochirus))
                                                           (96 h)
                                                           12.1 mg/l (fathead minnow (Pimephales promelas))
                                                           (96 h)
              EC -Toxicity for algae                       4.6 mg/l (Pseudokirchneriella subcapitata)
                                                           (72 h)
                                                           4.6 mg/l (green algae (Selenastrum capricornutum))
                                                           (72 h)
            · 12.2 Persistence and degradability
              No data on the mixture is available.
              Polydimethylsiloxanes are degradable to a certain extent in abiotic processes.
              Silicone content: biologically not degradable.
              hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics
              CO -evolution-test 20.62 % (31d)
              556-67-2 octamethylcyclotetrasiloxane
              Half-life            (OECD 111)
                                  Hydrolysis, DT50, 3,9 d, pH 7, 25°C
                                  Hydrolysis, DT50, 16,7 d, pH 7, 12°C
                                  Hydrolysis, DT50, 0,075 d, pH 4, 25°C
            · Degree of elimination:
              8042-47-5 White mineral oil, petroleum
              Biodegradability 31.3 % (28 days) (OECD 301 F)
              541-02-6 decamethylcyclopentasiloxane
              Biodegradability 0.14 % (28 days) (OECD 310)
                                Material is expected to biodegrade very slowly (in the environment). Fails to pass OECD/
                                EEC tests for ready biodegradability.
                                10-day Window: Not applicable
              556-67-2 octamethylcyclotetrasiloxane
              Biodegradability 3.7 % (28 days) (OECD 310)
              100-41-4 ethylbenzene
              Biodegradability 70 – 80 % (28 days)
            · Behaviour in environmental systems:
              Water:
              Not miscible or difficult to mix
            · Components: The product floats on water.and is insoluble or has a poor miscibility.
                                                                                                         (Contd. on page 15)
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                                                                                                           Page 15/18
                                                      Safety data sheet
                                            according to 1907/2006/EC, Article 31
          Printing date 14.11.2023          Version number 1.11 (replaces version 1.10)         Revision: 14.11.2023
          Trade name: Release agent f. double density Polyester-PU Concentrate of 1502/272
                                                                                                      (Contd. of page 14)
            · Toxicity to soil dwelling organisms:
              541-02-6 decamethylcyclopentasiloxane
              NOEC 76 mg/kg (redworm (Eisenia fetida))
            · 12.3 Bioaccumulative potential No further relevant information available.
            · Partition coefficient, n-octanol/water (log Pow):
              556-67-2 octamethylcyclotetrasiloxane
              log Pow 6.48 (25°C)
            · Bioconcentration factor (BCF):
              541-02-6 decamethylcyclopentasiloxane
              Bioconcentration factor (BCF): 2,010 (fish (not specified)) (estimated)
              556-67-2 octamethylcyclotetrasiloxane
              Bioconcentration factor (BCF): 12,400 (fathead minnow (Pimephales promelas))
            · 12.4 Mobility in soil
              541-02-6 decamethylcyclopentasiloxane
              Partition coefficient soil/water > 5,000 (estimated)
              556-67-2 octamethylcyclotetrasiloxane
              Partition coefficient soil/water 16,596 (OECD 106)
            · 12.40.23.1 Partition coefficient, soil organic carbon/water (log Koc):
              541-02-6 decamethylcyclopentasiloxane             > 5000
            · 12.5 Results of PBT and vPvB assessment
            · PBT: Not applicable.
            · vPvB: Not applicable.
            · 12.6 Endocrine disrupting properties For information on endocrine disrupting properties see section 11.
            · 12.7 Other adverse effects
            · Remark: Harmful to fish
            · Respiratory inhibition of communal activated sludge EC 20 (mg/l according to ISO 8192 B):
              8042-47-5 White mineral oil, petroleum
              EC -Bacterial toxicity > 1,000 mg/l (calculated) (QSAR Software Model)
                                       (40 h)
              556-67-2 octamethylcyclotetrasiloxane
              EC -Bacterial toxicity > 10,000 mg/l (activated sludge) (ISO 8192)
                                       (3 h)
              100-41-4 ethylbenzene
              EC -Bacterial toxicity 4.6 mg/l (Pseudokirchneriella subcapitata)
                                       (72 h)
            · Additional ecological information:
            · BSB5-value:
              hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics
              Biochemical Oxygen demand (BOD) [% of the ThOD] 89.8 % (28 days)
            · According to recipe contains the following heavy metals and compounds according to EC guideline NO.
              76/464 EC:
              Contains no adsorbable organically bound halogens (AOX)
            · General notes:
              Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water.
              Avoid transfer into the environment.
              Do not allow product to reach ground water, water bodies or sewage system.
              Harmful to aquatic organisms
              Danger to drinking water if even small quantities leak into soil.
                                                                                                     (Contd. on page 16)
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                                                                                                                   Page 16/18
                                                         Safety data sheet
                                                according to 1907/2006/EC, Article 31
              Printing date 14.11.2023          Version number 1.11 (replaces version 1.10)              Revision: 14.11.2023
              Trade name: Release agent f. double density Polyester-PU Concentrate of 1502/272
                                                                                                              (Contd. of page 15)
          *       SECTION 13: Disposal considerations
                · 13.1 Waste treatment methods
                · Recommendation
                  Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
                  Disposal must be made according to official regulations.
                  None disposal into waste water.
                · Waste disposal key number:
                  For disposal within the EC, the appropriate code according to the European Waste Catalogue (EWC) should
                  be used.
                · Uncleaned packagings:
                · Recommendation:
                  Disposal must be made according to official regulations.
                  Empty contaminated packagings thoroughly. They can be recycled after thorough and proper cleaning.
                  Packagings that cannot be cleaned are to be disposed of in the same manner as the product.
                  Flammable mixtures may be formed in empty containers.
                  DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH
                  CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
                  THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
          *       SECTION 14: Transport information
                · 14.1 UN number or ID number
                · ADR, ADN, IMDG, IATA                              Void
                · 14.2 UN proper shipping name
                · ADR, ADN, IMDG, IATA                              Void
                · 14.3 Transport hazard class(es)
                · ADR, ADN, IMDG, IATA
                · Class                                             Void
                · 14.4 Packing group
                · ADR, IMDG, IATA                                   Void
                · 14.5 Environmental hazards:
                · Marine pollutant:                                 No
                · 14.6 Special precautions for user                 Not applicable.
                · 14.7 Maritime transport in bulk according to IMO
                  instruments                                      Not applicable.
                · Transport/Additional information:
                · ADR
                · Excepted quantities (EQ)                          NOT SUBJECT TO ADR
                · IMDG
                · Limited quantities (LQ)                           -
                · Excepted quantities (EQ)                          Code: -
                · UN "Model Regulation":                            Void
          *       SECTION 15: Regulatory information
                · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
                · Labelling according to Regulation (EC) No 1272/2008
                  The product is classified and labelled according to the GB CLP regulation.
                · Hazard pictograms GHS08
                · Signal word Danger
                                                                                                              (Contd. on page 17)
57.0.12
                                                                                                                           Page 17/18
                                                           Safety data sheet
                                                according to 1907/2006/EC, Article 31
          Printing date 14.11.2023             Version number 1.11 (replaces version 1.10)                      Revision: 14.11.2023
          Trade name: Release agent f. double density Polyester-PU Concentrate of 1502/272
                                                                                                                      (Contd. of page 16)
            · Hazard-determining components of labelling:
              hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics
            · Hazard statements
              H304 May be fatal if swallowed and enters airways.
              H412 Harmful to aquatic life with long lasting effects.
            · Precautionary statements
              P273        Avoid release to the environment.
              P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
              P331        Do NOT induce vomiting.
              P405        Store locked up.
              P501        Dispose of contents/container in accordance with local/regional/national/international
                          regulations.
            · Directive 2012/18/EU
            · Named dangerous substances - ANNEX I None of the ingredients is listed.
            · National regulations
            · Technical instructions (air):
               Class Share in %
                III        <5
                NK       50 – 100
            · Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water.
            · Other regulations, limitations and prohibitive regulations
              EU. UK REACH, Annex XVII, Marketing and Use Restrictions (Regulation 1907/2006/EC)
              Listed Point Nos.: 3
              TRGS 500: "precautions: minimum standards"
              TRGS 600 "Substitution"
              TRGS 510 "Storage of hazardous substances in non-stationary containers "
              Directive 2012/18/EU
            · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
              SECTION 16: Other information
              These data are based on our present knowledge. However, they shall not constitute a guarantee for any
              specific product features and shall not establish a legally valid contractual relationship.
            · Relevant phrases
              H225     Highly flammable liquid and vapour.
              H226     Flammable liquid and vapour.
              H304     May be fatal if swallowed and enters airways.
              H332     Harmful if inhaled.
              H361f Suspected of damaging fertility.
              H373     May cause damage to organs through prolonged or repeated exposure.
              H410     Very toxic to aquatic life with long lasting effects.
              H412     Harmful to aquatic life with long lasting effects.
              EUH066 Repeated exposure may cause skin dryness or cracking.
            · Department issuing data specification sheet: Laboratory
            · Contact:
              Monday - Thursday: 8 a.m. - 3 p.m.,
                           Friday: 8 a.m. - 1 p.m.
              Mr. Eric Zimmer Tel.: +49 6331 537 0
                                  Fax.: +49 6331 537 211
            · Abbreviations and acronyms:
              ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the
              International Carriage of Dangerous Goods by Road)
              IMDG: International Maritime Code for Dangerous Goods
              IATA: International Air Transport Association
              GHS: Globally Harmonised System of Classification and Labelling of Chemicals
              EINECS: European Inventory of Existing Commercial Chemical Substances
              ELINCS: European List of Notified Chemical Substances
                                                                                                                     (Contd. on page 18)
57.0.12
                                                                                                                                         Page 18/18
                                                                 Safety data sheet
                                                     according to 1907/2006/EC, Article 31
          Printing date 14.11.2023                  Version number 1.11 (replaces version 1.10)                              Revision: 14.11.2023
          Trade name: Release agent f. double density Polyester-PU Concentrate of 1502/272
                                                                                                                                     (Contd. of page 17)
              CAS: Chemical Abstracts Service (division of the American Chemical Society)
              ISO: International Organisation for Standardisation
              DNEL: Derived No-Effect Level (UK REACH)
              bw: bodyweight
              Langz., Langzeit: chronical exposure,
              akut: acute (exposure)
              lokal: local effects
              system., systemisch: systemic effects
              PNEC (Predicted No-EffectConcentration)
              LC : lethal concentration for 50 percent of the animals, bacteria or plants used for testing
              LD : lethal dose for 50 percent of the animals used for testing
              LD : lethal concentration for 0 percent of the animals, bacteria or plants used for testing
              LD : lethal dose for 0 percent of the animals, bacteria or plants used for testing
              nb / n.b. : not determined
              gamete mutagenic. : gamete/germ cell mutagenicity
              carcinogen. : carcinogeniticity
              theoret. O -Bedarf: theoretical oxigen demand
              biolog. O -Bedarf: biological oxigen demand
              AOX: adsorbable organically bound halogens
              TRGS: technische Regeln für Gefahrstoffe (technical rules for dealing with dangerous substances)
              Merkblatt BG-Chemie: datasheet of the "Berufsgenossenschaft Rohstoffe und chemische Industrie" (former: "Berufgenossenschaft
              Chemie") (German insurance in case of accidents at work)
              Langz., Langzeit: Long-term exposure
              akut: Acute / short-term exposure
              systemisch: systemic
              lokal: local
              n.a.: not applicable
              (derived fr.data f.similar substances,intern.rep.) = derived from data from tests with similar substances, internal reports, not published
              Vert.koeff.Bod./Wass = Partition Coefficient soil / water
              n.v.: no data available
              Susp.: suspension
              H: the product is skin-resorbing
              Algentoxizität: toxicity for algae
              Bakterientoxizität: toxicity for bacteria
              Daphnientoxizität: toxicity for Daphnia
              Fischtoxizität: toxicity for fishes
              biologische Abbaubarkeit: Biodegradation
              DOC: dissolved organic carbon
              Halbwertszeit: half-life
              h: hour(s)
              d: day(s)
              w: week(s)
              m: montht(s)
              y: year(s)
              DIN: Norm des Deutschen Instituts für Normung = standard of the German Institute for Standardization
              EN: Europäische Norm = standard of the European Committee for Standardization (CEN)
              OECD: OECD Test Guideline
              pos. : positive
              neg. : negative
              inh., inhal. : inhalative
              NOEC (No Observed Effect Concentration),
              NOEL (No Observed Effect Level),
              NOAEL (No Observed Adverse Effect Level): denotes the level of exposure of an organism at which there is no effect in the exposed
              population.
              NOELR (No-Observed-Effect-Loading Rate)
              ATE (Acute Toxicity Estimates)
              Flam. Liq. 2: Flammable liquids – Category 2
              Flam. Liq. 3: Flammable liquids – Category 3
              Acute Tox. 4: Acute toxicity – Category 4
              Repr. 2: Reproductive toxicity – Category 2
              STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2
              Asp. Tox. 1: Aspiration hazard – Category 1
              Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1
              Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
            · Sources http://www.dguv.de/ifa/en/gestis/stoffdb/index.jsp
            · * Data compared to the previous version altered.
57.0.12