This safety data sheet provides information on the product Cleanbreak. It contains hazards identification, composition, first aid measures, handling and storage guidelines. Cleanbreak is classified as harmful and dangerous. It contains hydrocarbons that are harmful if swallowed and may cause lung damage. Exposure can cause eye damage. Appropriate personal protective equipment should be worn when handling, including gloves, eye protection and respiratory protection.
This safety data sheet provides information on the product Cleanbreak. It contains hazards identification, composition, first aid measures, handling and storage guidelines. Cleanbreak is classified as harmful and dangerous. It contains hydrocarbons that are harmful if swallowed and may cause lung damage. Exposure can cause eye damage. Appropriate personal protective equipment should be worn when handling, including gloves, eye protection and respiratory protection.
This safety data sheet provides information on the product Cleanbreak. It contains hazards identification, composition, first aid measures, handling and storage guidelines. Cleanbreak is classified as harmful and dangerous. It contains hydrocarbons that are harmful if swallowed and may cause lung damage. Exposure can cause eye damage. Appropriate personal protective equipment should be worn when handling, including gloves, eye protection and respiratory protection.
This safety data sheet provides information on the product Cleanbreak. It contains hazards identification, composition, first aid measures, handling and storage guidelines. Cleanbreak is classified as harmful and dangerous. It contains hydrocarbons that are harmful if swallowed and may cause lung damage. Exposure can cause eye damage. Appropriate personal protective equipment should be worn when handling, including gloves, eye protection and respiratory protection.
SECTION 1 Identification of the substance/mixture and of the
company/undertaking
1.1 Product identifier
- Product Name: CLEANBREAK - Product Part Number: 571497 (25 liter), 571505 (210 liter) 1.2 Relevant identified uses of the substance or mixture and uses advised against - Cleaning agent 1.3 Details of the supplier of the safety data sheet Head Office: Wilhelmsen Ships Service AS Strandveien 20, N1324 Lysaker, Norway Tel: (47) 6349 440 35
Supplier: Wilhelmsen Ships Service AS Willem Barentszstraat 50 3165AB Rotterdam Telephone: +31 4877 777 Fax: +31 4877 888 The Netherlands
Other suppliers SEE SECTION 16!!!
For quotations contact your local Customer Services
- Responsible Person: Product HSE Manager, Tel.: +31 10 4877775 Email: WSS.GLOBAL.SDSINFO@wilhelmsen.com 1.4 Emergency telephone number - ****ONLY TO BE USED IN CASE OF AN INCIDENT**** - American 24hrs Emergency CHEMTREC (800) 424 9300 - American Chemistry Council 24hrs +1 703 527 3887 - China NRCC 24hrs emergency telephone number: +86-0532-8388 9090 - Greece: Poisoning emergency center, +30 210 7793777 - International 24hrs Emergency NCEC:+ 44 1865 407333 - Norway: Poison information centre, +47 22591300 - Sweden: Poison information centre, +46 08 33 12 31 - Wilhelmsen Ships Service, Melbourne, AUSTRALIA Emergency 24hrs: +61 3 9630 0998
SECTION 2 Hazards identification
2.1 Classification of the substance or mixture
- Counsil Directive 1999/45/EEC Classification, packing and labelling of dangerous preparations. - Refer to current The Dangerous Substances Directive (67/548/EEC) - Symbols: Xn - Harmful: may cause lung damage if swallowed (R65) - Repeated exposure may cause skin dryness or cracking (R66) - - Classification according to Regulation (EC) No 1272/2008 - Signal Word: Danger
- - Contains: - Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, <2% aromatics - Sodium petroleum sulphonate - Hazard phrases May be fatal if swallowed and enters airways (H304). Repeated exposure may cause skin dryness or cracking (EUH066). Causes serious eye damage (H318). - Precautionary Phrases Wear protective gloves/protective clothing/eye protection/face protection (P280). Avoid breathing dust/fume/gas/mist/vapours/spray (P261). IF SWALLOWED: rinse mouth. Do NOT induce vomiting (P301+P330+P331). Immediately call a POISON CENTER or doctor/physician (P310). IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing (P305+P351+P338). 2.3 Other hazards - Odour: Smells of hydrocarbon - Appearance: Liquid, light, yellow, insoluble in water - Inhalation: May cause chronic pneumonitis, May cause coughing, In cases of severe exposure, nausea/vomiting may develop - Not a PBT according to REACH Annex XIII
Prometheus version 1.4.1.3 CLEANBREAK Revision: 8/28/2014 SECTION 3 Composition/information on ingredients (....)
Categories: Eye Dam. 1
SECTION 4 First aid measures
4.1 Description of first aid measures
- IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower (P303+P361+P353). - Contaminated clothing should be laundered before reuse - Seek medical attention if irritation persists - - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing (P305+P351+P338). - Irrigate eyes thoroughly whilst lifting eyelids - When in doubt or symptoms persist, seek medical attention - - IF SWALLOWED: rinse mouth. Do NOT induce vomiting (P301+P330+P331). - Do not induce vomiting because of risk of aspiration into the lungs. If aspiration is suspected obtain immediate medical attention - If vomiting occurs turn patient on side - Obtain immediate medical attention - - IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing (P304+P341). - Seek medical attention if irritation persists 4.2 Most important symptoms and effects, both acute and delayed - In cases of severe exposure, nausea/vomiting may develop - In cases of severe exposure, headache may develop - In cases of severe exposure, dizziness may develop - Possible redness and irritation of affected areas - Vapours or aerosols may cause irritation of eyes, nose and respiratory tract - The ingestion of significant quantities may cause chemical oedema 4.3 Indication of any immediate medical attention and special treatment needed - No information available
SECTION 5 Fire-fighting measures
5.1 Extinguishing media
- In case of fire: use dry sand or dry salt for extinction (P370+P378) - In case of fire: use foam, carbon dioxide or dry agent for extinction (P370+P378) - Do not use water jets 5.2 Special hazards arising from the substance or mixture - Decomposition products may include carbon dioxide - Decomposition products may include carbon monoxide - Vapours are heavier than air and may travel considerable distances to a source of ignition and flashback 5.3 Advice for firefighters - Prevent run off water from entering drains if possible - In the event of an adjacent fire, cool containers with water spray - Vapours are heavier than air and may travel considerable distances to a source of ignition and flashback - Wear Breathing Apparatus
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Prometheus version 1.4.1.3 CLEANBREAK Revision: 8/28/2014
SECTION 6 Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
- Wear protective clothing as per section 8 6.2 Environmental Precautions - Do not allow to enter public sewers and watercourses 6.3 Methods and material for containment and cleaning up - Absorb spillage in inert material and shovel up - Ventilate the area and wash spill site after material pick-up is complete 6.4 Reference to other sections - See Section 13
SECTION 7 Handling and storage
7.1 Precautions for safe handling
- Eyewash bottles should be available - Do not get in eyes, on skin, or on clothing (P262). - See Section 8 7.2 Conditions for safe storage, including any incompatibilities - Store in a dry place. Store in a closed container (P402+P404). - Store in a well-ventilated place (P403). - Keep away from open flames, hot surfaces and sources of ignition. 7.3 Specific end use(s) - Contact supplier for further information
TLV (TWA) 275 mg/m3 ( 8.2 Exposure controls - The undiluted product must not be used in a confined space without good ventilation - Ensure adequate ventilation 8.3 Occupational exposure controls
- In case of inadequate ventilation wear respiratory protection (P285).
- Wear suitable respiratory protection. Gas cartridge (organic substances). - Wear suitable protective clothing, including eye/face protection and gloves (neoprene or nitrile are recommended) - Penetration time of glove material: The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
SECTION 9 Physical and chemical properties
9.1 Information on basic physical and chemical properties
- Odour: Smells of hydrocarbon - Appearance: Liquid, yellow, insoluble in water
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Prometheus version 1.4.1.3 CLEANBREAK Revision: 8/28/2014 SECTION 9 Physical and chemical properties (....) - Boiling point 160 °C to 245 °C at 760 mm /Hg - Vapour density (air = 1) >1 - Density 0,785 - 0,810 g/cm3 at 20 deg C - Flash point >61 deg C (CC) - Auto-ignition point >200 deg C - Lower flammability limit 0,6%(in air) - Upper flammability limit 7%(in air) 9.2 Other information - None
SECTION 10 Stability and reactivity
10.1 Reactivity - This article is considered stable under normal conditions 10.2 Chemical stability - Considered stable under normal conditions 10.3 Possibility of hazardous reactions - No hazardous reactions known if used for its intended purpose 10.4 Conditions to avoid - Avoid overheating - Keep away from naked flames, incandescent or hot surfaces 10.5 Incompatible materials - None 10.6 Hazardous Decomposition Products - Decomposition products may include carbon oxides
SECTION 11 Toxicological information
11.1 Information on toxicological effects
- LD50 (oral,rat) (Sodiumpetroleum sulphonate) >2000 mg/kg - LD50 (oral,rat) (Hydrocarbones) >5000 mg/kg 11.2 Contact with eyes - May cause redness and irritation 11.3 Contact with skin - Prolonged skin contact will result in defatting of the skin, leading to irritation, and in some cases, dermatitis 11.4 Ingestion - The ingestion of significant quantities may cause gastro-intestinal disturbances - Aspiration hazard - The ingestion of significant quantities may cause chemical oedema 11.5 Inhalation - Inhalation of solvent vapours may give rise to nausea, headaches and dizziness
Prometheus version 1.4.1.3 CLEANBREAK Revision: 8/28/2014 SECTION 12 Ecological information (....)
12.2 Persistence and degradability
- Readily biodegradable 12.3 Bioaccumulation Potential - Hydrocarbon solvents have the potential to bioaccumilate. 12.4 Mobility in soil - Insoluble in water 12.5 Results of PBT and vPvB assessment - Not a PBT according to REACH Annex XIII 12.6 Other Adverse Effects - No environmental problems are expected when the product is used / handled correctly. In its intended use, the product will not be released into the environment.
SECTION 13 Disposal considerations
13.1 Waste treatment methods
- Do not discharge into drains or the environment, dispose to an authorised waste collection point - Disposal should be in accordance with local, state or national legislation 13.2 Classification - EU Waste class: 07 01 04
SECTION 14 Transport information
Not classified as hazardous for transport
14.1 UN - UN No.: Not applicable - Proper Shipping Name: Not applicable - Hazard Class: Not applicable - Packing Group: Not applicable 14.2 Environmental hazards - Not Classified 14.3 Special precautions for user - Not classified as hazardous for transport 14.4 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code - Not applicable 14.5 Road/Rail (ADR/RID) - ADR UN No.: Not applicable - Proper Shipping Name: Not applicable - ADR Hazard Class: Not applicable - ADR Packing Group: Not applicable 14.6 Sea (IMDG) - IMDG UN No.: Not applicable - Proper Shipping Name: Not applicable - IMDG Hazard Class: Not applicable - IMDG Pack Group.: Not applicable - IMDG EmS: Not applicable 14.7 Air (ICAO/IATA)
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Prometheus version 1.4.1.3 CLEANBREAK Revision: 8/28/2014 SECTION 14 Transport information (....)
- ICAO UN No.: Not applicable
- Proper Shipping Name: Not applicable - ICAO Hazard Class: Not applicable - ICAO Packing Group: Not applicable 14.8 DOT / CFR (US Department of Transportation) - Identification Number: Not applicable - DOT Proper Shipping Name: Not applicable - DOT Labels: Not applicable - Product RQ (lbs): Not applicable
SECTION 15 Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture - Composition information in accordance with EC Regulation 648/2004 of the European Parliament and of the Council of 31st March 2004 on detergents: - Aliphatic hydrocarbons >30 % - Anionic surfactants <5 % - - This composition meets the criteria for not being harmful to the marine environment according to MARPOL Annex V and may be discharged into the sea when used to clean cargo holds and external surfaces on ships. - Counsil Directive 1999/45/EEC Classification, packing and labelling of dangerous preparations. - Refer to The Dangerous Substances Directive (67/548/EEC) - This Safety Data Sheet is provided in compliance with the EC Directive 1907/2006- 453/2010 - Regulations 1272/2008/EEC. Classification, labeling and packing of dangerous substances and preparations - IMO -approved; Tank Cleaning. - Norwegian Productregistration no: 18210 - Danish PR number: 1540384 15.2 Chemical Safety Assessment - None
SECTION 16 Other information
Text not given with phrase codes where they are used elsewhere in this safety data sheet:- EUH066: Repeated exposure may cause skin dryness or cracking. H304: May be fatal if swallowed and enters airways. H318: Causes serious eye damage. R36: Irritating to eyes. R65: Harmful: may cause lung damage if swallowed. R66: Repeated exposure may cause skin dryness or cracking.
The information provided about the product on this Safety Data Sheet has been compiled from knowledge of the individual constituents The data given here only applies when product used for proper application(s). The product is not sold as suitable for other applications - usage in such may cause risks not mentioned in this sheet. Do not use for other application(s) without seeking advice from manufacturer The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in terms of safety requirements and does not signify any warranty with regard to the product's properties The most up-to-date version of this MSDS can be found on www.wilhelmsen.com/shipsservice
OTHER CONTACT INFORMATION MAJOR CHEMICAL OFFICES
Datasheet Number 571497-r - v11.0.0 7
Prometheus version 1.4.1.3 CLEANBREAK Revision: 8/28/2014 SECTION 16 Other information (....)
Wilhelmsen Ships Service Level 17, 636 St Kilda Road Melbourne Vic 3004 AUSTRALIA Tel: +61 3 9630 0900 Emergency 24hrs: +61 3 9630 0998 Wilhelmsen Ships Service INC 210 Edgewater Street US-10305 Staten Island New York United States Telephone daytime: (+1) 718 815 1310 Fax: (+1) 718 233 3268 Wilhelmsen Ships Service INC 2200 W. Pacific Coast Highway US-90810 Long Beach California, United States Tel (+1) 562 624 8888 Fax (+1) 562 624 1011 Wilhelmsen Ships Service INC 701 Ashland Ave. Ashland Center Two, Bay 12 US- 19032 Folcroft Pennsylvania United States Tel (+1) 610 586 7801 Fax (+1) 215 701 0646 Wilhelmsen Ships Service INC. 9400 New Century Drive US-77507 Pasadena Texas United States Telephone daytime: (+1) 281 867 2000 Fax: (+1) 281 867 2800 Wilhelmsen Ships Service Ltd. Unit 3A NewtonsCourt Crossways DA2 6QL Dartford, Kent United Kingdom Tel (+44) 1322 282 412 Fax (+44) 1322 284 774 Wilhelmsen Ships Service Ltda Rua Bispo Lacerda nos.61/67 Del Catilho BR 21051120 Rio de Janeiro Brazil Tel (+55) 21 25 82 8000 Fax (+55) 21 25 82 8001 Wilhelmsen Ships Service (S) Pte Ltd 186 Pandan Loop Singapore 128376 Tel (+65) 6395 4545 Wilhelmsen Ships Service Co., Ltd 12-31 Torihama-cho Kanazawa-ku Yokohama-shi JP-236 0002, Japan Tel (+81) 45 775 0012 Fax (+81) 45 775 0070 Wilhelmsen Ships Service Hellas SA 100, D. Moutsopoulou & Serifou str GR-185 41 Piraeus Greece Tel (+ 30) 210 4239100 Fax (+ 30) 210 4212480 Wilhelmsen Ships Service AS U.A.E . Fl 24 Executive Heights, Tecom C Sheikh Zayed Road (East) Dubai United Arab Emirates Tel (+971) 4 382 3888 Wilhelmsen Ships Service AS, Willem Barentszstraat 50 3165 AB Rotterdam-Albrandswaard, the Netherlands. Tel (+31) 10 4877 777
